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CN100483760C - Method of packaging white LED - Google Patents

Method of packaging white LED Download PDF

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Publication number
CN100483760C
CN100483760C CNB2007100324918A CN200710032491A CN100483760C CN 100483760 C CN100483760 C CN 100483760C CN B2007100324918 A CNB2007100324918 A CN B2007100324918A CN 200710032491 A CN200710032491 A CN 200710032491A CN 100483760 C CN100483760 C CN 100483760C
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China
Prior art keywords
light
emitting diode
packaging method
phosphor
diode chip
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Expired - Fee Related
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CNB2007100324918A
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Chinese (zh)
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CN101183698A (en
Inventor
王浩
蔡继业
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Jinan University
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Jinan University
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Abstract

本发明公开了一种白色发光二极管的封装方法:将发光二极管芯片及其支架浸入到掺杂了或涂敷有荧光粉和光聚合引发剂的光敏树脂中,把工作电流通入到发光二极管管芯中,使得管芯发光,进而激发光敏树脂发生聚合将二极管芯片及其支架封装起来。本发明在制备发光二极管时所需时间非常短,且不需模具、不需高温,达到既提高效率又节约能源的效果,而且所用技术可以根据芯片的发光特性主动调解荧光粉的分布,能容易的实现荧光粉的特异性涂敷,以实现均匀性的白光发射或者光谱的特异性发射。

The invention discloses a packaging method of a white light-emitting diode: the light-emitting diode chip and its support are immersed in a photosensitive resin doped or coated with fluorescent powder and a photopolymerization initiator, and the working current is passed into the light-emitting diode tube core In the process, the tube core is made to emit light, and then the photosensitive resin is excited to polymerize to package the diode chip and its bracket. The invention requires very short time for preparing light-emitting diodes, and does not require molds and high temperatures, thereby achieving the effect of improving efficiency and saving energy, and the technology used can actively adjust the distribution of phosphor powder according to the light-emitting characteristics of the chip, which can be easily The realization of the specific coating of phosphors to achieve uniform white light emission or spectral specific emission.

Description

A kind of method for packing of white light-emitting diode
Technical field
The invention belongs to the encapsulation technology field of light-emitting diode, particularly a kind of method for packing of white light-emitting diode.
Background technology
Because the technological break-through of light-emitting diode, particularly along with the breakthrough of GaN crystal extension technology of preparing, the quality of light-emitting diode, brightness have all had important breakthrough, make to adopt light-emitting diode to replace the trend of current indoor illumination more obvious.In the process of present light source revolution, the method for preparing light-emitting diode is quite important.Because varying environment requires difference to the characteristics of luminescence of light-emitting diode, so requirement can be produced the light-emitting diode of the various different parameters of preparation fast, cheaply.
Adopting the encapsulation LED that photosensitive resin can be quick, economic, is exactly to adopt the method as the patent 6958250 (Yang equals application in 2005) of the U.S..But the encapsulation process that the process of encapsulation and current LED are commonly used is similar, and all will use mould.
The encapsulation of white light-emitting diode has a lot of patents at present in the world, as the patent 3,691,482 (1970) of the U.S., 6,600,175 and Osram that Cree applied in 1996 are in 6,245 of application in 2000,259 and Nicha in 1997 the application 5,998,925, or the like.They adopt traditional method for packing, and the encapsulation process that the process of encapsulation and current LED are commonly used is similar.Current LED production technology is that the tube core of light-emitting diode and support thereof are put in the mould, then resin is poured into mould, adopts the method for heating to make resin polymerization again, and general heating-up temperature surpasses 100 degrees centigrade, and heating time was above 1 hour.Therefore, there is the problem of time consumption and energy consumption in the production technology of existing light-emitting diode.
Summary of the invention
The present invention is directed to packaging technology that light emitter diode seal method of the prior art exists consuming time long, need problem such as high temperature, a kind of method for packing of white light-emitting diode is provided.
The present invention can be achieved by the following technical programs: a kind of method for packing of white light-emitting diode: light-emitting diode chip for backlight unit and support thereof are immersed in have mixed or be coated with in the photosensitive resin of fluorescent material and Photoepolymerizationinitiater initiater, operating current is passed in the LED core, make tube core luminous, and then excite photosensitive resin generation polymerization that diode chip for backlight unit and support thereof are encapsulated, finally form light-emitting diode.
Packaged type of the present invention adopts individual layer encapsulation or multilayer encapsulation.
Diode chip for backlight unit of the present invention is inorganic, organic or high molecular conventional lattice, powerful, illuminating or shows the semiconductive luminescent materials of usefulness.
Operating current of the present invention is the electric current of direct current, interchange, pulse, intensity gradual change or sudden change.
Photosensitive resin of the present invention is epoxy resin or silicones.
Fluorescent material of the present invention is inorganic, organic, metal or biological.
Fluorescent material of the present invention can be solid-state, liquid state or gaseous state.
The application pattern of fluorescent material of the present invention adopts individual layer coating or multilayer coated.
Compared with prior art, the present invention has the following advantages: the present invention's required time when the preparation light-emitting diode is very short, and do not need high temperature, do not need mould, reach and not only raise the efficiency but also the effect of energy savings, and used technology can initiatively be reconciled the distribution of fluorescent material according to the characteristics of luminescence of chip, can be easy to realize the specificity coating of fluorescent material, to realize inhomogeneity white light emission, the perhaps specificity of spectrum emission.
Description of drawings
Fig. 1 is an encapsulation process schematic diagram of the present invention.
Embodiment
As shown in Figure 1, encapsulation process of the present invention is as follows: light-emitting diode chip for backlight unit 3 and support 1 thereof are immersed in have mixed or be coated with in the photosensitive resin 2 of fluorescent material and Photoepolymerizationinitiater initiater, operating current 4 is passed in the LED core 3, make tube core luminous, and then excite photosensitive resin 2 polymerization to take place with diode chip for backlight unit 3 and support 1 encapsulation thereof, finally form light-emitting diode.
The present invention realizes adjusting the uniformity of luminance of light-emitting diode by the uniformity of adjusting fluorescent material.Can realize adjusting the self luminous characteristic of LED core by time, the electric current of adjusting chip light emitting, as uniformity of luminance, fluorescent lifetime, luminous intensity etc., thereby realize inhomogeneity adjustment, make the diode of gained can launch white light fluorescent material.The method is equally applicable to realize that different colours distributes on same light-emitting diode.
Chip of the present invention can be that inorganic semiconductor also can be organic or semiconducting polymer's luminescent material, can be conventional specification, also can be powerful, can be illuminating, also can be to show usefulness.And the self luminous operating current of chip for driving can be direct current, can be to exchange, and can be pulse, can be also can suddenling change of intensity gradual change.
The used potting resin of the present invention is photosensitive, promptly to the photaesthesia of certain wavelength, can be under the irradiation of certain light polymerization reaction take place, and the wavelength of photosensitive wavelength and chip light emitting is close or consistent.Used potting resin is that conventional epoxy resin also can be silicones, perhaps other suitable resins.The component of potting resin all comprises or part comprises following several composition: oligomer, monomer, Photoepolymerizationinitiater initiater, filler, colouring agent and plasticizer.
The used Photoepolymerizationinitiater initiater of the present invention can be carbazoles or pyridine-fluorenes class initator, can be cationic, free radical type, and as acylphosphine oxide, salt, salt compounded of iodine, lithium series initiators or the like.
Fluorescent material of the present invention can be inorganic matter, organic substance, metal or biology, can be with solid-state, liquid and even gaseous state, it can be single variety, also can be that multiple different fluorescent material separates or mixing and doping, as yttrium-aluminium-garnet (YAG) and improvement kind thereof, 8-hydroxyquinoline aluminum, golden nanometer particle, fluorescent RE powder, quantum dot, nanocrystal, nanotube, nano belt or alkaline earth sulfide have bioprotein, DNA and composite construction thereof of biological nature or the like, and its size can be nano level, micron-sized and even the millimeter magnitude.In addition, fluorescent material can with mixed with resin polymerization together, also can apply separately, its application pattern can adopt individual layer coating or multilayer coated.
Adopting the resulting integral device structure of method for packing of white light-emitting diode of the present invention can be macro-size, as millimeter, centimetre size, also can be microscopic dimensions, as nanometer, micron size.And resulting structure can be the individual layer encapsulation, also can be the multilayer encapsulating structure.
Adopt the present invention can adjust the inhomogeneity method for packing of lumination of light emitting diode simply and rapidly, thereby provide new method for illumination revolution, luminous demonstration industry and bioscience life science.

Claims (10)

1、一种白色发光二极管的封装方法,其特征在于:将发光二极管芯片及其支架浸入到掺杂了或涂敷有荧光粉和光聚合引发剂的光敏树脂中,把工作电流通入到发光二极管管芯中,使得管芯发光,进而激发光敏树脂发生聚合将二极管芯片及其支架封装起来。1. A packaging method for a white light-emitting diode, characterized in that: the light-emitting diode chip and its support are immersed in a photosensitive resin doped or coated with phosphor powder and a photopolymerization initiator, and the working current is passed into the light-emitting diode In the tube core, the tube core is made to emit light, and then the photosensitive resin is stimulated to polymerize to package the diode chip and its bracket. 2、根据权利要求1所述的封装方法,其特征在于:所述的封装方式采用单层封装或多层封装。2. The encapsulation method according to claim 1, wherein the encapsulation method adopts single-layer encapsulation or multi-layer encapsulation. 3、根据权利要求1或2所述的封装方法,其特征在于:所述的二极管芯片是无机的或有机的半导体发光材料。3. The packaging method according to claim 1 or 2, characterized in that: said diode chip is an inorganic or organic semiconductor light-emitting material. 4、根据权利要求3所述的封装方法,其特征在于:所述的二极管芯片是照明用的或显示用的。4. The packaging method according to claim 3, wherein said diode chip is used for lighting or display. 5、根据权利要求4所述的封装方法,其特征在于:所述的工作电流是直流、交流、强度渐变或突变的电流。5. The packaging method according to claim 4, characterized in that: the working current is direct current, alternating current, current with gradual or sudden change in intensity. 6、根据权利要求5所述的封装方法,其特征在于:所述的光敏树脂是环氧树脂或硅树脂。6. The packaging method according to claim 5, wherein the photosensitive resin is epoxy resin or silicone resin. 7、根据权利要求6所述的封装方法,其特征在于:所述的荧光粉是无机荧光粉、有机荧光粉、金属荧光粉或生物荧光粉。7. The packaging method according to claim 6, wherein the phosphor is inorganic phosphor, organic phosphor, metal phosphor or biological phosphor. 8、根据权利要求7所述的封装方法,其特征在于:所述的荧光粉呈固态、液态或气态。8. The encapsulation method according to claim 7, wherein the fluorescent powder is in solid, liquid or gaseous state. 9、根据权利要求8所述的封装方法,其特征在于:所述的荧光粉的涂敷方式采用单层涂敷或多层涂敷。9. The packaging method according to claim 8, characterized in that: the phosphor powder is coated in a single-layer coating or multi-layer coating. 10、根据权利要求5所述的封装方法,其特征在于:所述的二极管芯片是高分子半导体发光材料;所述的工作电流是脉冲电流。10. The packaging method according to claim 5, characterized in that: said diode chip is a polymer semiconductor luminescent material; said working current is a pulse current.
CNB2007100324918A 2007-12-14 2007-12-14 Method of packaging white LED Expired - Fee Related CN100483760C (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104253195A (en) * 2013-06-27 2014-12-31 凌敬平 Method for making white light LED
CN103666448A (en) * 2013-12-04 2014-03-26 广西玖典电子新材料有限公司 LED organic fluorescent powder sizing material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3691482A (en) * 1970-01-19 1972-09-12 Bell Telephone Labor Inc Display system
US6958250B2 (en) * 2003-08-26 2005-10-25 Yung-Shu Yang Light-emitting diode encapsulation material and manufacturing process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3691482A (en) * 1970-01-19 1972-09-12 Bell Telephone Labor Inc Display system
US6958250B2 (en) * 2003-08-26 2005-10-25 Yung-Shu Yang Light-emitting diode encapsulation material and manufacturing process

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