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CN100501460C - Composite triangular pyramid type cube-corner retroreflection sheet and retroreflection object - Google Patents

Composite triangular pyramid type cube-corner retroreflection sheet and retroreflection object Download PDF

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CN100501460C
CN100501460C CNB2005800380508A CN200580038050A CN100501460C CN 100501460 C CN100501460 C CN 100501460C CN B2005800380508 A CNB2005800380508 A CN B2005800380508A CN 200580038050 A CN200580038050 A CN 200580038050A CN 100501460 C CN100501460 C CN 100501460C
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CN101088032A (en
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三村育夫
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/12Reflex reflectors
    • G02B5/122Reflex reflectors cube corner, trihedral or triple reflector type
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Abstract

A composite cube-corner retroreflection element comprising at least two groups of sub retroreflection elements which are divided by three side surfaces mutually crossing at almost right angles by means of 3-directional V-shaped parallel groove groups that mutually cross and have substantially symmetrical sections, and which are disposed in the most densely filled state so as to project toward one side on a common sub plane (SH-SH'), wherein the groups of sub retroreflection elements are disposed on one main retroreflection element that is divided by three side surfaces mutually crossing at almost right angles by means of 3-directional V-shaped parallel groove groups that are disposed on a main plane (S-S'), mutually cross and have substantially symmetrical sections.

Description

复合三角锥型立方隅角回射片及回射物 Composite triangular pyramid cube corner retroreflective sheeting and retroreflector

技术领域 technical field

本发明涉及新型结构的三角锥型立方隅角回射片及回射物。具体而言,本发明涉及将新型结构的三角锥型反射元件最密集填充地配置的立方隅角型回射片及回射物。The invention relates to a triangular pyramid cube corner retroreflective sheet and a retroreflective object with a novel structure. Specifically, the present invention relates to a cube-corner retroreflective sheeting and a retroreflective object in which triangular pyramid-shaped reflective elements of a novel structure are arranged in the most densely packed manner.

详细地说,本发明涉及由道路标识(一般的交通标识及反光标牌)、路面标识(pavement maker)、工程标识等标识类、汽车及摩托车等车辆的号码牌类、贴在货车及拖车的车体的反射胶带、衣料、救生器具等安全器材类以及广告牌等标志、可见光、激光或红外光反射型传感器类的反射板等中有用的三角锥型立方隅角回射元件(下面也简单称作三角锥型反射元件)构成的立方隅角型回射片及回射物。In detail, the present invention relates to road signs (general traffic signs and reflective signs), pavement markers (pavement maker), engineering signs and other signs, number plates of vehicles such as automobiles and motorcycles, and stickers attached to trucks and trailers. Triangular pyramid cube corner retroreflective elements useful in reflective tapes for car bodies, clothing, life-saving appliances and other safety equipment, signs such as billboards, visible light, laser or infrared light reflective sensors, etc. Cube-corner retroreflective sheeting and retroreflectors composed of triangular pyramidal reflective elements).

具体而言,涉及一种三角锥型立方隅角回射片及回射物,其特征在于:它包含按以下方式构成复合立方隅角回射元件,即通过断面基本为对称形的3个方向的V字形平行槽群互相交叉,将由3个大致以直角互相交叉的反射侧面划分的至少2个以上的三角锥型立方隅角回射元件群最密集填充地配置成向共有的副平面(SH-SH)上的一侧突出,并通过在主平面(S-S)上配置的、断面基本为对称形的3个方向的V字形平行槽群的互相交叉,将该副反射元件群配置在由3个大致以直角互相交叉的反射侧面划分的1个主反射元件上。Specifically, it relates to a triangular-pyramidal cube corner retroreflective sheeting and retroreflective object, which is characterized in that it includes a composite cube corner retroreflective element formed in the following manner, that is, three directions through which the section is basically symmetrical The V-shaped parallel groove groups intersect each other, and at least two or more triangular pyramid cube corner retroreflective element groups divided by three reflective sides that cross each other approximately at right angles are arranged in the most densely packed manner toward the shared subplane (SH -SH) protrudes on one side, and by intersecting the V-shaped parallel groove groups arranged in the main plane (S-S) and having a substantially symmetrical cross-section in three directions, the sub-reflecting element group is arranged in three directions. On a main reflective element divided by reflective sides that cross each other approximately at right angles.

背景技术 Background technique

传统技术中,将入射的光向光源反射的回射片及回射物已众所周知,利用其回射性的这种薄片可广泛用于上述的应用领域。其中,与使用传统的微型玻珠的回射片及回射物相比,利用三角锥型反射元件等立方隅角回射元件的回射原理的立方隅角型回射片及回射物,其光的回射效率特别优良,由于其优良的回射性能,其用途正逐年扩大。Conventionally, retroreflective sheeting and retroreflective objects that reflect incident light toward a light source are known, and such sheets utilizing their retroreflective properties can be widely used in the above-mentioned application fields. Among them, compared with retroreflective sheeting and retroreflective objects using traditional miniature glass beads, cube corner retroreflective sheeting and retroreflective objects using the retroreflective principle of cube corner retroreflective elements such as triangular pyramid reflective elements, Its light retroreflection efficiency is particularly excellent, and its use is expanding year by year due to its excellent retroreflection performance.

但是,以小于满足由构成回射元件的透明介质的折射率与空气的折射率之比决定的内部全反射条件的临界角的角入射至反射侧面的光,在该反射侧面的界面上不被全反射,而会透过该反射侧面的背面,所以存在的缺点是使用三角锥型立方隅角回射元件的回射片及回射物的入射角特性通常会劣化。也就是说,在回射片的表面与入射光线构成的入射角小的角度范围内,显示良好的回射效率,但随着入射角增大,将发生回射效率急剧下降的问题。However, light incident on the reflective side surface at an angle smaller than the critical angle satisfying the internal total reflection condition determined by the ratio of the refractive index of the transparent medium constituting the retroreflective element to the refractive index of air is not reflected at the interface of the reflective side surface. Total reflection, and will pass through the back of the reflective side, so there is a disadvantage that the incident angle characteristics of retroreflective sheeting and retroreflective objects using triangular pyramid cube corner retroreflective elements will usually be deteriorated. That is to say, good retroreflective efficiency is shown in the range of small angles between the surface of the retroreflective sheeting and the incident light, but with the increase of the incident angle, the retroreflective efficiency will drop sharply.

另外,因为三角锥型回射元件能够在该元件的大致整个面上使光沿光入射的方向反射,由于不会象微型玻珠型反射元件那样,反射光因球面像差等原因而过度发散,因此具有优良的回射性能。In addition, because the triangular pyramid type retroreflective element can reflect the light along the direction of light incident on almost the entire surface of the element, because the reflected light will not be excessively divergent due to spherical aberration and other reasons like the micro glass bead type reflective element , so it has excellent retroreflective properties.

但是,在实用方面,当汽车的前灯发出的光在交通标识上回射时,易出现过窄的发散角的回射光难以达到处于离开其光轴位置上的驾驶员的眼睛这一不良情况。这种不良情况在汽车与交通标识的距离特别接近时,因为由光线的入射轴与连接驾驶员及反射点的观察轴构成的角所规定的观测角增大,所以特别地显著。也就是说存在以下的问题点,即公知的传统三角锥型立方隅角回射元件的观测角特性通常会劣化。However, in terms of practicality, when the light emitted by the headlights of the car is retroreflected on the traffic sign, it is easy to appear that the retroreflected light with too narrow divergence angle is difficult to reach the driver's eyes at a position away from its optical axis. . This disadvantage is particularly noticeable when the distance between the vehicle and the traffic sign is particularly close, because the viewing angle defined by the angle formed by the incident axis of the light and the viewing axis connecting the driver and the reflection point increases. That is to say, there is a problem that the viewing angle characteristics of known conventional triangular pyramid type cube corner retroreflective elements are generally deteriorated.

另外,三角锥型立方隅角回射元件是由三个反射侧面形成,其回射性能随着入射的光在反射侧面的哪个方向(称作方位角)入射而变化,所以在设置回射片时,元件的方向必须一定。如此,三角锥型立方隅角回射元件的回射性能存在方位角依存性,即存在方位角特性上的问题。In addition, the triangular pyramid cube corner retroreflective element is formed by three reflective sides, and its retroreflective performance changes with the direction (called azimuth) of the incident light on the reflective side, so when setting the retroreflective sheet , the orientation of the component must be constant. In this way, the retroreflective performance of the triangular pyramid cube corner retroreflective element is dependent on the azimuth angle, that is, there is a problem in the azimuth angle characteristic.

另外,公知的传统三角锥型立方隅角回射元件具有光轴,该光轴定义为通过三角锥型立方隅角回射元件的顶点、与构成该回射元件的大致以直角互相交叉的3个反射侧面等距的轴。In addition, conventional triangular pyramidal cube corner retroreflective elements are known to have an optical axis defined as passing through the apex of the triangular pyramidal cube corner retroreflective element and the three intersecting surfaces forming the retroreflective element at approximately right angles. axes equidistant from the reflection sides.

关于这种立方隅角型回射片及回射物,特别是三角锥型立方隅角回射片及回射物休的入射角特性或观测角特性的改进,迄今已提出许多方案,进行了各种改进研究。Regarding the improvement of the incident angle characteristics or observation angle characteristics of such cube corner retroreflective sheeting and retroreflective objects, especially triangular pyramidal cube corner retroreflective sheeting and retroreflective objects, many schemes have been proposed so far, and research has been carried out. Various research improvements.

例如,在杨格森(Jungersen)的美国专利第2,481,757号中,记载了在薄片上设置各种形状的回射元件。上述美国专利中例示的三角锥型反射元件是顶点位于底面三角形中心的光轴不倾斜的三角锥型反射元件以及顶点位置不位于底面三角形中心的光轴有倾斜的三角锥型反射元件,记载了使光有效地对正在接近的汽车反射(入射角特性的改善)的情况。For example, in US Pat. No. 2,481,757 to Jungersen, retroreflective elements of various shapes are provided on a sheet. The triangular pyramid reflective elements exemplified in the above-mentioned U.S. patents are triangular pyramid reflective elements whose apex is located at the center of the triangle on the bottom surface and whose optical axis is not inclined, and triangular pyramid reflectors whose apex is not located at the center of the triangle on the bottom surface and whose optical axis is inclined. It is a case of efficiently reflecting light to an approaching car (improvement of the incident angle characteristic).

另外,记载了作为三角锥型反射元件的尺寸,元件的深度在1/10英寸(2.540μm)以内。另外,在该美国专利的附图15中图示了光轴(如下所述)向正(+)方向倾斜的三角锥型反射元件对,根据图示的三角锥型反射元件的底面三角形的长边与短边之长度比值求其光轴的倾斜角(θ),推断为约6.5°。In addition, as the dimensions of the triangular pyramid reflective element, the depth of the element is stated to be within 1/10 inch (2.540 μm). In addition, in the accompanying drawing 15 of this U.S. patent, the pair of triangular pyramid reflective elements whose optical axis (as described below) is inclined to the positive (+) direction is illustrated. The inclination angle (θ) of the optical axis was obtained from the ratio of the length of the side to the short side, and it was estimated to be about 6.5°.

但是,在上述Jungersen的美国专利中没有具体公开后述的极小三角锥型反射元件,另外,关于为了提供优良的观测角特性或入射角特性三角锥型反射元件应具有何种尺寸和光轴倾斜,该文献未作记载也没有提示。However, in the U.S. patent of Jungersen mentioned above, there is no specific disclosure of the minimal triangular pyramid reflective element mentioned later. In addition, in order to provide excellent observation angle characteristics or incident angle characteristics, what size and optical axis inclination the triangular pyramid reflective element should have , which is neither documented nor suggested.

另外,在斯塔姆(Stamm)的美国专利第3,712,706号中记载的回射片及回射物,是将薄片上的底面三角形形状为正三角形的所谓正三角锥型立方隅角回射元件加以配置,使其底面在共用面上成为最密集填充状。在Stamm的该美国专利中,对反射元件的反射面用例如铝等金属进行蒸镀处理,使入射光进行镜面反射,并使入射角增大,从而改善了回射效率下降的问题以及以未满足内部全反射条件的角度入射的光透过元件的界面而不回射的不良情况。In addition, the retroreflective sheeting and retroreflective objects described in U.S. Patent No. 3,712,706 of Stamm are a so-called regular triangular pyramidal cube corner retroreflective element whose base triangular shape on the sheet is an equilateral triangle. Configured so that its bottom surface is most densely packed on the shared surface. In the U.S. patent of Stamm, the reflective surface of the reflective element is vapor-deposited with metal such as aluminum, so that the incident light is specularly reflected, and the incident angle is increased, thereby improving the problem of retroreflective efficiency decline and the future An undesirable condition in which light incident at an angle satisfying the condition of total internal reflection passes through the interface of a component without being retroreflected.

但是,在上述Stamm的提案中,作为广角性的改善手段,易出现以下的不良情况,即因为在反射侧面上设有镜面反射层,所以所得到的回射片及回射物的外观变暗,镜面反射层中采用的铝、银等金属使用中由于水及空气的浸入而发生氧化以及易于出现反射亮度下降等。另外,关于通过光轴的倾斜而改善广角性的手段完全未作记载。However, in the above-mentioned Stamm's proposal, as a means for improving the wide-angle performance, the following disadvantages are likely to occur, that is, the appearance of the obtained retroreflective sheeting and retroreflective objects becomes dark because the specular reflection layer is provided on the reflective side. , Aluminum, silver and other metals used in the specular reflection layer are oxidized due to the immersion of water and air during use, and are prone to decrease in reflective brightness. In addition, nothing is described about means for improving wide-angle performance by inclination of the optical axis.

另外,在霍普曼(Hoopman)的欧洲专利第137,736B1中记载的回射片及回射物是将在薄片上的底面三角形的形状为二等边三角形的一对倾斜三角锥型立方隅角回射元件以互相旋转180°的形式、使其底面在共用面上最密集填充的而排列。该专利中记载的三角锥型立方隅角回射元件的光轴的倾斜是向本说明书中记载的负(-)方向倾斜,倾斜角约7°~13°。In addition, the retroreflective sheeting and retroreflective objects described in European Patent No. 137,736B1 by Hoopman are a pair of inclined triangular pyramidal cube corners in which the shape of the base triangle on the sheeting is an equilateral triangle. The retroreflective elements are arranged rotated 180° relative to each other with their base surfaces most densely packed on the common surface. The inclination of the optical axis of the triangular pyramid cube corner retroreflective element described in this patent is in the negative (-) direction described in this specification, and the inclination angle is about 7° to 13°.

另外,在斯切杰科(Szczech)的美国专利第5,138,488号中公开的回射片及回射物是:同样地将在薄片上的底面三角形的形状为二等边三角形的倾斜三角锥型立方隅角回射元件,使其底面在共用面上为最密集填充地排列。在该美国专利中,该三角锥型反射元件的光轴是向相互面对而成对的二个三角锥型反射元件互相共有的边方向,即后述的正(+)方向倾斜,规定其倾斜角约2°~5°,元件的尺寸为25μm~100μm。In addition, the retroreflective sheeting and retroreflective objects disclosed in U.S. Patent No. 5,138,488 of Szczech are: similarly, the shape of the base triangle on the sheet is an inclined triangular pyramidal cube of two equilateral triangles. The corner retroreflective elements are arranged such that their bases are most densely packed on the common plane. In this U.S. patent, the optical axis of the triangular pyramidal reflective element is inclined to the side direction shared by two triangular pyramidal reflective elements facing each other, that is, the positive (+) direction described later. The inclination angle is about 2°-5°, and the size of the element is 25 μm-100 μm.

另外,在对应于上述专利的欧洲专利第548,280B1中记载了光轴的倾斜方向的倾斜角为约2°~5°,包含构成一对的二个元件的共用边且垂直于共有平面的面与元件顶点的距离与元件的光轴与共有平面的交叉点与上述垂直面的距离不等,元件的尺寸为25μm至100μm。In addition, in European Patent No. 548,280B1 corresponding to the above-mentioned patent, it is described that the inclination angle of the inclination direction of the optical axis is about 2° to 5°, including the common side of the two elements constituting a pair and perpendicular to the common plane. The distance from the apex of the element and the intersection point of the optical axis of the element and the common plane and the above-mentioned vertical plane are not equal, and the size of the element is 25 μm to 100 μm.

如上述一样,在Szczech的欧洲专利第548,280B1中,光轴的倾斜为包含正(+)及负(-)两者的约2°~5°的范围。但是,在Szczech的上述美国专利及欧洲专利的实施例中仅公开了光轴的倾斜角为(-)8.2°、(-)9.2°及(-)4.3°,元件的高度(h)为87.5μm的三角锥型反射元件。As mentioned above, in Szczech's European Patent No. 548,280B1, the inclination of the optical axis is in the range of about 2° to 5° including both positive (+) and negative (−). But, in the embodiment of above-mentioned U.S. patent and European patent of Szczech, only disclosed that the inclination angle of optical axis is (-) 8.2 °, (-) 9.2 ° and (-) 4.3 °, the height (h) of element is 87.5 μm triangular pyramid reflective element.

另外,作为改善观测角特性的提案,例如在艾波道恩(Appeldorn)的美国专利第4,775,219号中,形成元件的V字形槽呈现非对称形,相对于形成立方隅角的理论V字形槽的角度有微小的偏差。另外,试验了通过使导致与邻接的V字形槽的非对称性的偏差周期性地变化来改善观测角特性。In addition, as a proposal to improve the viewing angle characteristics, for example, in U.S. Patent No. 4,775,219 of Appeldorn, the V-shaped grooves forming the elements are asymmetrical, compared to the theoretical V-shaped grooves forming the cube corners. There is a slight deviation in the angle. In addition, it was tested to improve the observation angle characteristic by periodically changing the deviation that causes asymmetry with the adjacent V-shaped grooves.

但是,使邻接的V字形槽的角度周期性地变化会增加模具加工的难度。即使能克服此难度,但所能给以的偏差组合是有限的,仍然不能使反射光均匀扩散。另外,即使对于一个V字形的槽方向,也需要准备多种形成V字形槽的金刚石刀头等加工工具。另外,在以非对称形式形成V字形槽时还需要高精度的加工技术。However, periodically changing the angles of adjacent V-shaped grooves increases the difficulty of mold processing. Even if this difficulty can be overcome, the deviation combinations that can be given are limited, and the reflected light cannot be uniformly diffused. In addition, even for one V-shaped groove direction, it is necessary to prepare a plurality of processing tools such as diamond tips for forming V-shaped grooves. In addition, high-precision processing technology is required to form V-shaped grooves in an asymmetric form.

另外,在瓦特尔(Walter)的美国专利第5,171,624号中,公开的是使用具有说明曲面状的断面形状的加工工具,形成具有一定的2次曲面的断面形状的反射侧面的三角锥型回射元件。在形成具有这种2次曲面的反射侧面的三角锥型回射元件中,能使回射光适当发散,能改善观测角特性,但制成具有这种曲面的断面形状的加工工具是非常难的。所以,考虑到工具的加工困难性,基于所构思的设计的2次曲面是难以获得的。In addition, U.S. Patent No. 5,171,624 of Walter discloses a triangular pyramidal retroreflective method that uses a processing tool having a curved cross-sectional shape to form a reflective side surface having a constant quadratic curved cross-sectional shape. element. In the triangular pyramid retroreflective element formed with such a quadratic curved reflective side surface, the retroreflected light can be appropriately diffused and the observation angle characteristics can be improved, but it is very difficult to manufacture a processing tool with such a curved cross-sectional shape . Therefore, considering the machining difficulty of the tool, it is difficult to obtain the quadratic surface based on the conceived design.

在尼尔森(Nilsen)的美国专利第5,565,151号尝试改善观测角特性,其中,切除反射侧面的一部分,由此形成三角柱形状的部分和新的反射侧面,从而促进回射光的发散。Improvement of viewing angle characteristics is attempted in US Patent No. 5,565,151 by Nilsen, in which part of the reflective side is cut away, thereby forming a triangular prism-shaped part and a new reflective side, thereby promoting divergence of retroreflected light.

但是,在尼尔森的发明中,很少具体描述优选哪种形状的三角柱状的设置或者优选以哪个角度形成新的反射侧面。另外,为切除部分反射侧面而形成三角柱状部分需要特殊的工具。另外,新形成的三角柱形状的元件不具有回射功能,而仅为使光线向各个方向简单地分散而得到回射光的扩散。However, in Nielsen's invention, there is little specific description of which shape of the triangular prism arrangement is preferred or at which angle the new reflective side is preferably formed. In addition, special tools are required to cut away part of the reflective sides to form the triangular prisms. In addition, the newly formed triangular prism-shaped element does not have a retroreflective function, but simply disperses light in various directions to obtain diffusion of retroreflected light.

另外,在布尔克(Bruke)的美国专利第4,202,600号和内斯特加德(Nestegard)等人的美国专利第5,706,132号中公开的试验是通过将配置具有不同方向的方位角(azimuthal orientation)的元件群的区域进行组合,使以不同方位角入射的光的回射性变得均匀。Additionally, tests disclosed in U.S. Patent No. 4,202,600 to Bruke and U.S. Patent No. 5,706,132 to Nestegard et al. The regions of the element group are combined so that the retroreflection of light incident at different azimuth angles becomes uniform.

总之,如本发明的图6所示,公知的Jungersen的美国专利第2,481,757号、Stamm的美国专利第3,712,706号、Hoopman的欧洲专利第137,736B1以及Szczech的美国专利第5,138,488号、欧洲专利第548,280B1等传统的三角锥型立方隅角回射元件均具有以下缺点,即在构成光的入射及反射的核心部的多个三角锥型反射元件的底面位于同一平面上的点以及相对的一对元件构成相似形的形状、且元件的高度相等的点是共有的,这样采用底面位于同一平面的三角锥型反射元件构成的回射片及回射物,如果其任何一个入射角特性劣化,即如果光线对于该三角锥型反射元件的入射角增大,则回射亮度急剧减少。In summary, as shown in FIG. 6 of the present invention, well-known U.S. Patent No. 2,481,757 to Jungersen, U.S. Patent No. 3,712,706 to Stamm, European Patent No. 137,736B1 to Hoopman, and U.S. Patent No. 5,138,488 to Szczech, European Patent No. 548,280B1 and other conventional triangular pyramidal cube corner retroreflective elements all have the following disadvantages, that is, the points where the bottom surfaces of the plurality of triangular pyramidal reflective elements that constitute the core portion of light incidence and reflection are located on the same plane and the opposing pair of elements The points that form a similar shape and have the same height of the elements are common, so if any of the incident angle characteristics of the retroreflective sheeting and retroreflective objects composed of triangular pyramidal reflective elements with the bottom surface on the same plane are degraded, that is, if As the incident angle of light on the triangular pyramid reflective element increases, the retroreflected brightness decreases sharply.

另外,在以上所述的公知的Appeldorn的美国专利第4,775,219号、Walter的美国专利第5,171,624号以及Nilsen的美国专利第5,565,151号中,同样地提出了采用各种办法来改善观测角特性的方案,但其中任何一项发明都存在工具制造及模具加工困难等缺点。In addition, in the above-mentioned well-known U.S. Patent No. 4,775,219 of Appeldorn, U.S. Patent No. 5,171,624 of Walter, and U.S. Patent No. 5,565,151 of Nilsen, it is also proposed to use various methods to improve the observation angle characteristics. But wherein any invention all has shortcoming such as tool manufacture and mold processing difficulty.

发明内容 Contents of the invention

本发明课题是改善上述公知的传统三角锥型立方隅角回射片及回射物所存在的入射角特性、观测角特性及方位角特性上的问题。The object of the present invention is to improve the problems of the above-mentioned known traditional triangular pyramid cube corner retroreflective sheeting and retroreflectors in the characteristics of incident angle, observation angle and azimuth angle.

本发明的另一课题在于:改善采用三角锥型立方隅角回射片及回射物的道路标识(一般的交通标识及反光标牌)、路面标识(pavementmaker)、工程标识等标识类、汽车及摩托车等车辆的号码牌类、贴在货车及拖车的车体的反射胶带、衣料、救生器具等安全器材类以及广告牌等标志、可见光、激光或红外光反射型传感器类的反射板等的回射性能。Another subject of the present invention is to improve road signs (general traffic signs and reflective signs), pavement markers (pavement maker), engineering signs, etc. Number plates of motorcycles and other vehicles, reflective tapes attached to the body of trucks and trailers, safety equipment such as clothing, life-saving appliances, signs such as billboards, reflectors such as visible light, laser or infrared light reflective sensors, etc. retroreflective properties.

本发明在进行上述的公知的传统回射元件具有的入射角特性、观测角特性及方位角特性的改善时,通过具有复合立方隅角回射元件实现,其形成方式如下:通过断面基本为对称形的3个方向的V字形平行槽群互相交叉,将由3个大致以直角互相交叉的反射侧面划分的至少2个以上的三角锥型立方隅角回射元件群最密集填充地配置成向共有副平面(SH-SH)上的一侧突出,并通过配置于主平面(S-S)上的、断面基本为对称形的3个方向的V字形平行槽群互相交叉,将该副反射元件群配置在由3个大致以直角互相交叉的反射侧面划分的1个三角锥型立方隅角回射元件上。采用这种复合元件特别能促进观测角特性的改善。When the present invention improves the incident angle characteristics, observation angle characteristics and azimuth characteristics of the above-mentioned known traditional retroreflective elements, it is realized by having a composite cube corner retroreflective element, and its formation method is as follows: the passing section is basically symmetrical The V-shaped parallel groove groups in three directions of the shape intersect each other, and at least two or more triangular pyramid cube corner retroreflective element groups divided by three reflective sides that cross each other approximately at right angles are arranged in the most densely packed manner to share One side of the sub-plane (SH-SH) protrudes, and the group of V-shaped parallel grooves arranged on the main plane (S-S) and having a substantially symmetrical cross-section in three directions cross each other, and the sub-reflector group is arranged On a triangular pyramidal cube corner retroreflective element divided by three reflective sides that cross each other approximately at right angles. The use of such composite elements facilitates in particular the improvement of the viewing angle characteristics.

另外,上述改善通过使用该副平面(SH-SH)与该主平面(S-S)平行的上述复合立方隅角回射元件实现,采用这种复合元件特别能促进观测角特性的改善。In addition, the aforementioned improvements are achieved by the use of the aforementioned composite cube corner retroreflective elements in which the secondary plane (SH-SH) is parallel to the primary plane (S-S), the use of which composite elements particularly facilitates improved viewing angle characteristics.

另外,通过使用该副反射元件和/或该主反射元件具有的光轴有倾斜的上述复合立方隅角回射元件实现的这种复合元件也特别能促进入射角特性的改善。In addition, such composite elements realized by using the above-mentioned composite cube-corner retroreflective elements with the secondary reflective element and/or the primary reflective element having an inclined optical axis also contribute particularly to an improved angle of incidence characteristic.

另外,上述改善通过使用形成该主反射元件的3个方向的底边与形成该副反射元件的其它3个方向的底边的至少一组方向的底边都不平行,最好用一组方向的底边为垂直的上述复合立方隅角回射元件来实现,采用这种复合元件特别能促进方位角特性的改善。In addition, the above-mentioned improvements are not parallel to at least one group of the bottom edges of the three directions forming the main reflector element and the bottom edges of the other three directions forming the sub-reflector element, preferably one group of directions This is achieved by the aforementioned composite cube-corner retroreflective elements whose bottom edge is perpendicular, the use of which composite elements particularly facilitates improved azimuth characteristics.

另外,上述改善通过与上述公知的传统改善技术组合,也能够有效地改善入射角特性、观察角特性及方位角特性中的任一特性。In addition, the above-mentioned improvement can effectively improve any one of the incident angle characteristics, observation angle characteristics, and azimuth angle characteristics by combining the above-mentioned known conventional improvement techniques.

包含本发明中的复合立方隅角回射元件而形成的三角锥型立方隅角回射片及回射物能够获得公知的传统回射元件中无法获得的优良入射角特性、观察角特性及方位角特性。The triangular-pyramidal cube-corner retroreflective sheeting and retroreflective objects formed by the composite cube-corner retroreflective element of the present invention can obtain excellent incident angle characteristics, observation angle characteristics and azimuths that cannot be obtained in known traditional retroreflective elements corner properties.

附图说明 Description of drawings

图1是表示公知的传统回射元件的图。FIG. 1 is a diagram showing a known conventional retroreflective element.

图2是表示公知的传统回射元件的图。Fig. 2 is a diagram showing a known conventional retroreflective element.

图3是表示本发明的回射元件的图。Fig. 3 is a diagram showing a retroreflective element of the present invention.

图4是表示本发明的回射元件的集合的图。Fig. 4 is a diagram showing a collection of retroreflective elements of the present invention.

图5是表示本发明的回射元件的图。Fig. 5 is a diagram showing a retroreflective element of the present invention.

图6是表示本发明的回射元件的图。Fig. 6 is a diagram showing a retroreflective element of the present invention.

图7是表示本发明的回射元件的图。Fig. 7 is a diagram showing a retroreflective element of the present invention.

图8是表示本发明的回射元件的集合的图。Fig. 8 is a diagram showing a collection of retroreflective elements of the present invention.

图9是表示本发明的回射元件的图。Fig. 9 is a diagram showing a retroreflective element of the present invention.

图10是表示本发明的回射元件的集合的图。Fig. 10 is a diagram showing a collection of retroreflective elements of the present invention.

图11是表示本发明的回射元件的图。Fig. 11 is a diagram showing a retroreflective element of the present invention.

具体实施方式 Detailed ways

在说明用于实施本发明的最佳方式时,同时对公知的传统三角锥型立方隅角回射元件(下面也称作回射元件),参照附图进行说明。In describing the best mode for carrying out the present invention, a known conventional triangular pyramid type cube corner retroreflective element (hereinafter also referred to as a retroreflective element) will be described with reference to the accompanying drawings.

图1是说明公知的传统三角锥型立方隅角回射元件的图,表示的是共有底边(A-B)而相对的一对回射元件(A-B-C1-H1、A-B-C2-H2)。图1所示的反射元件是其底面形状(A-B-C1、A-B-C2)为正三角形的所谓正规三角锥型立方隅角回射元件对,由断面基本为对称形的3个方向的V字形平行槽群(x、y及z方向)以60°的角度互相交叉的3个由大致以直角互相交叉的同一形状的直角等边三角形的反射侧面(a1、b1、c1及a2、b2、c2)划分开,这些反射元件对配置在共有平面(S-S)上。FIG. 1 is a diagram illustrating a known conventional triangular-pyramidal cube corner retroreflective element, showing a pair of retroreflective elements (A-B-C1-H1, A-B-C2-H2) sharing a base (A-B) but facing each other. The reflective element shown in Figure 1 is a pair of so-called regular triangular pyramidal cube corner retroreflective elements whose bottom surface shape (A-B-C1, A-B-C2) is an equilateral triangle. Parallel groove groups (x, y, and z directions) intersect each other at an angle of 60°, and three reflective sides (a1, b1, c1 and a2, b2, c2) of the same shape that cross each other at approximately right angles are right-angled equilateral triangles. ) are divided, and these reflective element pairs are arranged on a common plane (S-S).

图1中的回射元件的光轴与共有平面(S-S)垂直相交而不倾斜。The optical axis of the retroreflective element in FIG. 1 intersects the common plane (S-S) perpendicularly without being inclined.

另外,因为元件的形状通常是三角形,所以其回射性能随着光在哪个方向(也称作方位角)入射而变化。在图1中以平行于底边(A-B)的方向入射时的回射性能与以直角入射时的回射性能不同。如此,回射性能的方位角依存性是三角锥型立方隅角反射元件存在的问题。Also, because the shape of the element is typically triangular, its retroreflective properties vary depending on which direction (also called azimuth) the light is incident. The retroreflective performance at incidence parallel to the base (A-B) in FIG. 1 is different from that at right angles. As such, the azimuthal dependence of retroreflective performance is a problem with triangular pyramid cube corner reflective elements.

另外,图1中元件的尺寸能够由顶点至共有平面(S-S)的高度(h,下面也称作元件高度)代表。在入射到反射元件的光回射时,通过按元件的尺寸而定的衍射效果所引起的发散,以扩散方式回射。也就是说,元件高度(h)越小,衍射效果越大,能够使回射光扩散,获得观察角特性的改善,但在具有过小的元件高度(h)的反射元件中发散效果会变得过大,其回射性能会下降。In addition, the size of the element in FIG. 1 can be represented by the height (h, also referred to as element height hereinafter) from the vertex to the common plane (S-S). When light incident on a reflective element is retroreflected, it is retroreflected in a diffuse manner due to divergence caused by a diffraction effect depending on the size of the element. In other words, the smaller the element height (h), the greater the diffraction effect, which can diffuse the retroreflected light and obtain an improvement in the viewing angle characteristics, but the divergence effect will become smaller in a reflective element with an excessively small element height (h). If it is too large, its retroreflection performance will be reduced.

另外,可在反射元件的反射侧面(a1、b1、c1及a2、b2、c2)上设置镜面反射层。在镜面反射层上能够采用各种金属制反射物质,例如铝、银、镍及铜等。在设有这种镜面反射层的反射元件中会产生以下缺点:由于在反射侧面上以大于临界角的角入射的光也能反射,虽然能够改善入射角特性,但回射片及回射物的外观变暗。In addition, a specular reflective layer may be provided on the reflective side surfaces (a1, b1, c1 and a2, b2, c2) of the reflective element. Various metallic reflective substances, such as aluminum, silver, nickel, and copper, can be used on the specular reflection layer. The following disadvantages will occur in the reflective element provided with such a specular reflective layer: since the incident light at an angle greater than the critical angle on the reflective side can also be reflected, although the incident angle characteristics can be improved, the retroreflective sheet and the retroreflective The appearance is darkened.

图2同样地是说明公知的传统的光轴倾斜的三角锥型立方隅角回射元件(下面也称作倾斜反射元件)的图。FIG. 2 is likewise a diagram illustrating a known conventional triangular-pyramidal cube-corner retroreflective element with a tilted optical axis (hereinafter also referred to as a tilted reflective element).

在图2所示的倾斜回射元件中,表示的是顶点至共有平面(S-S)的垂线交点(P)与底边(A-B)的距离(p)以及光轴与共有平面(S-S)相交的点(Q)与底边(A-B)的距离(q)之差(q-p)不为零的元件。In the angled retroreflective element shown in Figure 2, the distance (p) between the apex and the intersection point (P) of the perpendicular to the common plane (S-S) and the base (A-B) and the intersection of the optical axis and the common plane (S-S) are shown A component whose difference (q-p) between the distance (q) of the point (Q) and the base (A-B) is not zero.

特别地,在图2中表示的是(q-p)为正的所谓正倾斜元件,因为这种倾斜反射元件使方向朝倾斜的光轴的回射性能改善,所以入射角特性优良。无论(q-p)为正(正倾斜反射元件)或为负(负倾斜反射元件),都能实现按照这种光轴的倾斜原理的入射角特性改善。In particular, what is shown in FIG. 2 is a so-called positively inclined element in which (q-p) is positive. Since such an inclined reflective element improves retroreflection performance toward an inclined optical axis, the incident angle characteristic is excellent. Regardless of whether (q-p) is positive (positively inclined reflective element) or negative (negatively inclined reflective element), the improvement of the incident angle characteristic according to the principle of such an inclination of the optical axis can be realized.

图3表示的是本发明的一种底面形状为正三角形、光轴不倾斜的复合三角锥型立方隅角回射元件形式。Fig. 3 shows a composite triangular-pyramid cube-corner retroreflective element of the present invention whose bottom surface is an equilateral triangle and whose optical axis is not inclined.

图3中,通过将断面基本为对称形的3个方向的V字形平行槽群互相交叉,由3个大致以直角互相交叉的反射侧面划分的4个副反射元件群最密集填充地配置,使其向共有的副平面(SH-SH)上的一侧突出。由这些副反射元件的顶点至共有的副平面(SH-SH)的距离所规定的元件的高度是以hs表示。In Fig. 3, by crossing V-shaped parallel groove groups in three directions with substantially symmetrical cross-sections, the four sub-reflecting element groups divided by three reflective side surfaces crossing each other at approximately right angles are arranged in the most densely packed manner, so that It protrudes to one side on the common secondary plane (SH-SH). The element height defined by the distance from the vertices of these secondary reflective elements to the common secondary plane (SH-SH) is denoted by hs.

该副反射元件群配置在1个主反射元件上,该主反射元件在底面上具有正三角形(A-B-C1、A-B-C2),通过配置于主平面(S-S)上的断面基本为对称形的3个方向的V字形平行槽群互相交叉而由3个大致以直角互相交叉的反射侧面划分开。The sub-reflecting element group is arranged on one main reflecting element, and the main reflecting element has an equilateral triangle (A-B-C1, A-B-C2) on the bottom surface, and the cross-section arranged on the main plane (S-S) is basically symmetrical. Groups of V-shaped parallel grooves in three directions intersect each other and are divided by three reflective side surfaces that intersect each other approximately at right angles.

对于该主反射元件,形成该元件的3个反射侧面的延长面相交而形成的假想顶点(Hm)至该主平面(S-S)的距离为hm。另外,副反射元件群共有的副平面(SH-SH)处于距假想顶点(Hm)的距离为hp的位置上。For the main reflective element, the distance from the imaginary vertex (Hm) formed by the intersection of the extended surfaces of the three reflective side surfaces forming the element to the main plane (S-S) is hm. In addition, the sub-plane (SH-SH) shared by the sub-reflector group is located at a distance of hp from the imaginary vertex (Hm).

在图3中,形成该主反射元件的3个方向的底边与形成该副反射元件的其它3个方向的底边都是平行的,形成底边的三角形是相似形,在任一个元件中光轴的倾斜角都是0°。In Fig. 3, the bases of the three directions forming the main reflective element are all parallel to the bases of the other three directions forming the sub-reflecting element, and the triangles forming the bases are similar in shape. The inclination angles of the axes are all 0°.

在图3所示的复合反射元件中通过主反射元件表示有效的回射性能,同时通过副反射元件,根据折射效果,产生反射光的发散,实现观测角特性的改善。In the composite reflective element shown in Fig. 3, effective retroreflective performance is represented by the main reflective element, and at the same time, the divergence of reflected light is generated by the sub-reflective element according to the refraction effect, and the observation angle characteristic is improved.

图4是图3所示复合三角锥型立方隅角回射元件共有主反射元件的底边,同时最密集填充地配置。主反射元件是通过断面基本为对称形的3个方向的V字形平行槽群(x、y、z)而形成,形成副反射元件的3个方向的V字形平行槽群也与形成主反射元件的V字形平行槽群(x、y、z)平行,这些V字形槽的底边位于共有的副平面(SH-SH)上。Fig. 4 is the composite triangular pyramidal cube corner retroreflective elements shown in Fig. 3 sharing the bottom edge of the main reflective element while being most densely packed. The main reflective element is formed by V-shaped parallel groove groups (x, y, z) in three directions that are substantially symmetrical in cross-section, and the V-shaped parallel groove groups in three directions forming the sub-reflective element are also similar to those used to form the main reflective element. The V-shaped parallel groove groups (x, y, z) are parallel, and the bases of these V-shaped grooves are located on the common sub-plane (SH-SH).

图5表示的复合回射元件是在光轴(q-p)向正方向倾斜的正倾斜的主反射元件上设有具有同一光轴倾斜的元件高度小的4个副反射元件。在这种复合回射元件中能够通过光轴的倾斜,实现入射角特性的改善,通过副反射元件,实现观测角特性的改善。In the composite retroreflective element shown in FIG. 5 , four sub-reflective elements with the same optical axis inclination and a smaller element height are provided on a positively inclined main reflective element whose optical axis (q-p) is inclined to the positive direction. In such a composite retroreflective element, it is possible to improve the incident angle characteristic by the inclination of the optical axis, and to realize the improvement of the observation angle characteristic by the sub-reflective element.

在图5的复合回射元件中,光轴的倾斜方向无论(q-p)为正或为负都能实现入射角特性的改善,但其倾斜角度最好是,该副反射元件和/或该主反射元件的光轴倾斜1~13°,优选光轴倾斜1.5~7°。In the compound retroreflective element of Fig. 5, no matter the inclination direction of the optical axis (q-p) is positive or negative, the improvement of the incident angle characteristic can be realized, but the inclination angle is preferably such that the secondary reflective element and/or the main reflective element The optical axis of the reflective element is inclined by 1° to 13°, preferably by 1.5° to 7°.

在光轴的倾斜角小于1°时,入射角特性的改善不显著,在具有大于13°的大倾斜的反射元件中易产生正面方向的回射性下降这一不良情况。When the inclination angle of the optical axis is less than 1°, the improvement of the incident angle characteristic is not significant, and the retroreflectivity in the front direction tends to be degraded in a reflective element having a large inclination of more than 13°.

与图3相同,图6表示的是本发明的一种底面形状为正三角形、光轴不倾斜的复合三角锥型立方隅角回射元件形式,但一个主反射元件上的副反射元件的数量是16个,它们是高度小于图3所示的副反射元件的元件。Same as Fig. 3, what Fig. 6 shows is a kind of bottom surface shape of the present invention is regular triangle, optical axis is not inclined compound triangular pyramid cube corner retroreflective element form, but the quantity of secondary reflective element on a main reflective element There are 16 elements, and they are elements whose height is smaller than that of the sub-reflecting element shown in FIG. 3 .

与图3所示的复合反射元件一样,图6的复合反射元件中形成该主反射元件的3个方向的底边与形成该副反射元件的其它3个方向的底边均平行,形成底边的三角形是相似形,在任一个元件中光轴的倾斜角都是0°。Like the composite reflective element shown in Figure 3, in the composite reflective element of Figure 6, the bases in the three directions forming the main reflective element are all parallel to the bases in the other three directions forming the sub-reflective element, forming the base The triangles of are similar shapes, and the inclination angle of the optical axis in any element is 0°.

另外,图7表示本发明的一种底面形状为正三角形、光轴不倾斜的复合三角锥型立方隅角回射元件形式,但一个主反射元件上的完整形状的副反射元件的数量是6个,其它的副反射元件由主反射元件的反射侧面切除。In addition, Fig. 7 shows a compound triangular pyramidal cube corner retroreflective element of the present invention whose base shape is an equilateral triangle and the optical axis is not inclined, but the number of secondary reflective elements with complete shapes on one main reflective element is 6 One, the other secondary reflective elements are cut off from the reflective sides of the primary reflective element.

另外,形成该主反射元件的3个方向的底边和形成该副反射元件的另3个方向的底边的一组方向的底边相互垂直,主反射元件相对的底边的配置方向与副反射元件相对的底边的配置方向相互垂直。In addition, the bases in three directions forming the base of the main reflector and the bases in a group of directions forming the bases in the other three directions of the sub-reflector are perpendicular to each other. The arrangement directions of the opposite bottom sides of the reflective elements are perpendicular to each other.

图8表示图7所示的复合三角锥型立方隅角回射元件共有主反射元件的底边而最密集填充地配置。主反射元件由断面基本为对称形的3个方向的V字形平行槽群(x、y、z)形成。形成副反射元件的任一3个方向的V字形平行槽群与形成主反射元件的V字形平行组(x、y、z)都不平行,这些V字形槽的底边位于共有的副平面(SH-SH)上。另外,形成副反射元件的一个V字形槽的底边与形成主反射元件的V字形平行槽群(x)垂直。Figure 8 shows the most densely packed arrangement of the composite triangular pyramidal cube corner retroreflective elements shown in Figure 7 sharing the base of the main reflective element. The main reflection element is formed by a group of V-shaped parallel grooves (x, y, z) in three directions with a substantially symmetrical cross section. The V-shaped parallel groove groups forming any three directions of the sub-reflector element are not parallel to the V-shaped parallel groups (x, y, z) forming the main reflector element, and the bottom edges of these V-shaped grooves are located in a common sub-plane ( SH-SH). In addition, the base of one V-shaped groove forming the sub-reflecting element is perpendicular to the group (x) of V-shaped parallel grooves forming the main reflecting element.

图7及图8所示的由元件的配置方向是直角的主反射元件与副反射元件组合而形成的复合反射元件,可改善回射性能的方位角特性和观测角特性。另外,如果主反射元件及副反射元件都采用光轴有倾斜的反射元件,则也能实现入射角的改善而优选。另外,形成该主反射元件的3个方向的底边与形成该副反射元件的其它3个方向的底边的任一方向组的底边也可不平行。The composite reflective elements shown in Figures 7 and 8 are formed by combining the main reflective element and the secondary reflective element whose arrangement direction is at right angles, which can improve the azimuth angle characteristics and observation angle characteristics of the retroreflection performance. In addition, if both the main reflection element and the sub-reflection element use a reflection element with an inclined optical axis, it is also possible to improve the incident angle, which is preferable. In addition, the bases of the three directions forming the main reflector may not be parallel to the bases of any direction group forming the bases of the other three directions of the sub-reflecting element.

图7及图8所示的复合回射元件光轴的倾斜方向无论(q-p)为正或为负,都能实现入射角特性的改善,但对于其倾斜角度,优选该副反射元件和/或该主反射元件具有的光轴倾斜1~13°的复合回射元件,光轴最好倾斜1.5~7°。No matter whether (q-p) is positive or negative, the inclination direction of the optical axis of the composite retroreflective element shown in Fig. 7 and Fig. 8 can realize the improvement of the incident angle characteristic, but for its inclination angle, preferably the sub-reflective element and/or The main reflective element has a compound retroreflective element whose optical axis is inclined by 1-13°, preferably the optical axis is inclined by 1.5-7°.

图9表示的是本发明中的复合回射元件对的另一形式。与图3和图6一样,图9表示的是本发明的一种底面形状为正三角形、光轴不倾斜的复合三角锥型立方隅角回射元件形式,但在主反射元件(A-C1-B及A-C2-B)上形成的副反射元件的数量是4个。Fig. 9 shows another form of the composite retroreflective element pair in the present invention. Same as Fig. 3 and Fig. 6, what Fig. 9 shows is that a kind of bottom surface shape of the present invention is equilateral triangle, optical axis is not inclined compound triangular pyramid cube corner retroreflective element form, but in the main reflective element (A-C1 -B and A-C2-B) The number of sub-reflective elements formed is four.

图9中的主反射元件(A-C1-B及A-C2-B)在由多个V字形槽(x、y、z)所确定的共有平面(S-S)上形成。另外,多个副反射元件由多个V字形槽(xh、yh、zh)而形成,存在于由多个V字形槽(xh、yh、zh)确定的共有的另一平面(SH-SH)上。另外,共有平面(S-S)存在于比另一共有平面(SH-SH)低的位置上。该多个V字形槽(x、y、z)与其它多个V字形槽(xh、yh、zh)的间隔相等地形成,仅槽的深度有不同。The main reflection elements (A-C1-B and A-C2-B) in FIG. 9 are formed on a common plane (S-S) defined by a plurality of V-shaped grooves (x, y, z). In addition, a plurality of sub-reflective elements are formed by a plurality of V-shaped grooves (xh, yh, zh), and exist on another shared plane (SH-SH) defined by the plurality of V-shaped grooves (xh, yh, zh). superior. In addition, the shared plane (S-S) exists at a lower position than the other shared plane (SH-SH). The plurality of V-shaped grooves (x, y, z) are formed at equal intervals to the other plurality of V-shaped grooves (xh, yh, zh), and only the depth of the grooves is different.

与图3及图6所示的复合反射元件一样,图9的复合反射元件形成为该主反射元件的3个方向的底边与形成该副反射元件的其它3个方向的底边均平行,形成底边的三角形是相似形,在任一个元件中光轴的倾斜角都是0°。Like the composite reflective element shown in Fig. 3 and Fig. 6, the composite reflective element in Fig. 9 is formed such that the bases of the main reflective element in three directions are parallel to the bases of the other three directions forming the sub-reflective element, The triangles forming the bases are similar shapes, and the inclination angle of the optical axis is 0° in either element.

在图10中表示的是图9所示的复合回射元件对的集合图。图10中,图9所示的复合三角锥型立方隅角回射元件共有主反射元件的底边而最密集填充地配置。形成图10所示的多个副反射元件的多个V字形槽(xh、yh、zh)未形成连续的直线及曲线轨迹。该轨迹可以选择与邻接的主反射元件上形成的其它副反射元件不同的轨迹。这样,能采用各种轨迹在改善观测角特性方面是有效的。Shown in FIG. 10 is an assembly diagram of the pair of composite retroreflective elements shown in FIG. 9 . In FIG. 10, the composite triangular pyramidal cube corner retroreflective elements shown in FIG. 9 share the base of the main reflective element and are most densely packed. The multiple V-shaped grooves (xh, yh, zh) forming the multiple sub-reflectors shown in FIG. 10 do not form continuous straight and curved tracks. The trajectory can be selected to be different from that of other secondary reflective elements formed on the adjacent primary reflective element. Thus, being able to adopt various trajectories is effective in improving the observation angle characteristic.

图11表示的是本发明的复合回射元件对的另一形式。与图9一样,图11表示的是本发明的一种底面形状为正三角形、光轴不倾斜的复合三角锥型立方隅角回射元件形式,但在主反射元件(A-C1-B及A-C2-B)上形成的副反射元件的数量是9个。Fig. 11 shows another form of the pair of composite retroreflective elements of the present invention. Same as Fig. 9, what Fig. 11 represented is a kind of bottom surface shape of the present invention is regular triangle, optical axis is not inclined compound triangular pyramid cube corner retroreflective element form, but in the main reflective element (A-C1-B and The number of sub-reflective elements formed on A-C2-B) is nine.

图11中的主反射元件(A-C1-B及A-C2-B)在由多个V字形槽(x、y、z)所确定的共有平面(S-S)上形成。另外,多个副反射元件由多个V字形槽(xh、yh、zh)形成,存在于由多个V字形槽(xh、yh、zh)所确定的共有的另一平面(SH-SH)上。另外,共有平面(S-S)存在于比另一共有平面(SH-SH)低的位置上。另外,多个V字形槽(x、y、z)与其它的多个V字形槽(xh、yh、zh)的间隔相等地形成,仅槽的深度有不同。The main reflection elements (A-C1-B and A-C2-B) in FIG. 11 are formed on a common plane (S-S) defined by a plurality of V-shaped grooves (x, y, z). In addition, a plurality of sub-reflective elements are formed by a plurality of V-shaped grooves (xh, yh, zh), and exist on another common plane (SH-SH) defined by the plurality of V-shaped grooves (xh, yh, zh). superior. In addition, the shared plane (S-S) exists at a lower position than the other shared plane (SH-SH). In addition, a plurality of V-shaped grooves (x, y, z) and other plurality of V-shaped grooves (xh, yh, zh) are formed at equal intervals, and only the depth of the grooves is different.

与图9所示的复合反射元件一样,图11的复合反射元件中,形成该主反射元件的3个方向的底边与形成该副反射元件的其它3个方向的底边都是平行的,形成底边的三角形是相似形,在任一个元件中光轴的倾斜角都是0°。Like the composite reflective element shown in Figure 9, in the composite reflective element shown in Figure 11, the bases in three directions forming the main reflective element are parallel to the bases in the other three directions forming the sub-reflective element, The triangles forming the bases are similar shapes, and the inclination angle of the optical axis is 0° in either element.

图9~图11所示的复合反射元件以及形成该复合反射元件的主元件和副反射元件的光轴的倾斜角是0°。但是,图9~图11所示的复合反射元件以及形成该复合反射元件的主元件和副反射元件的光轴也可以向正方向或负方向倾斜。光轴的倾斜角最好倾斜1~13°的复合回射元件,优选光轴倾斜1.5~7°。形成光轴的倾斜角为0°的副元件的V字形槽(xh、yh、zh)的深度最好相等。The inclination angle of the optical axis of the composite reflective element shown in FIGS. 9 to 11 and the main element and sub-reflective element forming the composite reflective element is 0°. However, the optical axes of the composite reflective elements shown in FIGS. 9 to 11 and the main elements and sub-reflective elements forming the composite reflective elements may be inclined in the positive or negative direction. The inclination angle of the optical axis is preferably a compound retroreflective element in which the inclination angle is 1-13°, and the inclination angle of the optical axis is preferably 1.5-7°. It is preferable that the depths of the V-shaped grooves (xh, yh, zh) forming the sub-element whose optical axis has an inclination angle of 0° be equal.

另外,形成光轴有倾斜的副反射元件的V字形槽(xh、yh、zh)的深度也可不相等。光轴为反向倾斜的副反射元件中最好使xh方向的V字形槽的深度比yh、zh方向的V字形槽的深度更浅地形成,光轴正方向倾斜的副反射元件中xh方向的V字形槽的深度最好形成得比yh、zh方向的V字形槽的深度更深。In addition, the depths of the V-shaped grooves (xh, yh, zh) forming the sub-reflector with an inclined optical axis may not be equal. In the sub-reflector whose optical axis is inclined in the opposite direction, it is preferable to form the depth of the V-shaped grooves in the xh direction to be shallower than the depths of the V-shaped grooves in the yh and zh directions. The depth of the V-shaped grooves is preferably formed deeper than the depths of the V-shaped grooves in the yh and zh directions.

本发明中的复合反射元件的副平面(SH-SH)与主平面(S-S)不必特别要是平行的,在形成大型复合反射元件时,也可制成不平行的形状,但在形成用于回射片的小型复合反射元件时,副平面(SH-SH)最好与主平面(S-S)平行,因为可使元件的形成容易。The secondary plane (SH-SH) and the main plane (S-S) of the composite reflective element in the present invention do not need to be parallel in particular. When forming a large composite reflective element, it can also be made into a non-parallel shape. When shooting a small compound reflective element, it is preferable that the secondary plane (SH-SH) is parallel to the main plane (S-S), because it can facilitate the formation of the element.

本发明的复合反射元件的主反射元件的尺寸最好这样,形成该主反射元件的3个反射侧面的延长面相交而成的假想顶点(Hm)至该主平面(S-S)的距离(hm)大于50μm。在主反射元件的距离(hm)小于50μm时,因为主反射元件上能形成的副反射元件的尺寸变得过小或者反射光的发散变得过大,回射性能下降,所以不优选。The size of the main reflective element of the composite reflective element of the present invention is preferably such that the distance (hm) from the imaginary vertex (Hm) formed by the intersection of the extended planes of the three reflective side surfaces of the main reflective element to the main plane (S-S) Greater than 50 μm. When the distance (hm) of the main reflector is less than 50 μm, the size of the sub-reflector that can be formed on the main reflector becomes too small or the divergence of reflected light becomes too large, and the retroreflection performance decreases, which is not preferable.

另外,在回射片使用的复合反射元件的场合,优选距离(hm)50μm以上,更优选80~300μm。在主反射元件的距离(hm)大于300μm时,回射片的厚度增大,得不到柔软的薄片。In addition, in the case of a composite reflective element used in a retroreflective sheeting, the distance (hm) is preferably 50 μm or more, more preferably 80 to 300 μm. When the distance (hm) of the main reflective elements exceeds 300 μm, the thickness of the retroreflective sheeting increases, and a flexible sheet cannot be obtained.

本发明中的副反射元件的顶点(Hs)至该副平面(SH-SH)的距离(hs)与该主反射元件的假想顶点(Hm)至该主平面(S-S)的距离(hm)之比(hs/hm)优选0.1~0.5,更优选0.1~0.3。The difference between the distance (hs) from the vertex (Hs) of the secondary reflective element to the secondary plane (SH-SH) in the present invention and the distance (hm) from the imaginary vertex (Hm) of the main reflective element to the main plane (S-S) The ratio (hs/hm) is preferably 0.1 to 0.5, more preferably 0.1 to 0.3.

当比值(hs/hm)小于0.1时,副反射元件的尺寸变得过小,在大于0.5时,副反射元件的尺寸变得过大,同时主反射元件的有效反射侧面的面积比例变得过小,所以会产生回射性下降。When the ratio (hs/hm) is less than 0.1, the size of the secondary reflective element becomes too small, and when it is greater than 0.5, the size of the secondary reflective element becomes too large, and the area ratio of the effective reflective side of the main reflective element becomes too large. Small, so there will be a decrease in retroreflection.

主反射元件的假想顶点(Hm)至主平面(S-S)的距离(hm)与主反射元件的假想顶点(Hm)至该副平面(SH-SH)的距离(hp)之比(hp/hm)优选0.1~0.9,更优选0.3~0.5。The ratio of the distance (hm) from the imaginary vertex (Hm) of the main reflective element to the main plane (S-S) to the distance (hp) from the imaginary vertex (Hm) of the main reflective element to the secondary plane (SH-SH) (hp/hm ) is preferably 0.1 to 0.9, more preferably 0.3 to 0.5.

当比值(hp/hm)小于0.1时,副元件的形状变得过小,通过副反射元件产生的观测角特性难以得到改善,在大于0.9时,主反射元件的反射侧面的面积比率变得过小,所以会产生回射性能下降。When the ratio (hp/hm) is less than 0.1, the shape of the sub-element becomes too small, and it is difficult to improve the observation angle characteristics produced by the sub-reflection element. When it is greater than 0.9, the area ratio of the reflection side of the main reflection element becomes too high. Small, so there will be a decrease in retroreflection performance.

作为可用于本发明中的复合反射元件的三角锥型立方隅角回射元件,采用背景技术中详细说明的各种回射元件或其他公知的回射元件,从而能够得到回射性能的进一步改善。As the triangular-pyramid cube-corner retroreflective element that can be used in the composite reflective element of the present invention, various retroreflective elements described in detail in the background art or other known retroreflective elements can be used, thereby further improving the retroreflective performance. .

另外,本发明中的复合反射元件能够采用公知的传统飞旋切削法、划线法及刨削法等制作。制作反射元件的方法可通过采用上述机械加工法而形成3个方向的V字形槽而制作。制作的顺序也可以是以下任一种方法,即在形成副反射元件后,再形成深的槽而形成主元件的方法以及在形成主反射元件后,再在主反射元件中形成浅的槽而形成副元件的方法。In addition, the composite reflective element in the present invention can be produced by the known traditional spinning method, scribing method and planing method. The method of producing the reflective element can be produced by forming V-shaped grooves in three directions by the above-mentioned machining method. The order of manufacture can also be any of the following methods, that is, after forming the secondary reflective element, then form a deep groove to form the main element, or after forming the main reflective element, then form a shallow groove in the main reflective element. Method for forming subcomponents.

形成本发明中的复合反射元件的各立方隅角反射元件的3个反射侧面最好基本上垂直地相互交叉,但从通过使反射光微小地发散而改善观测角特性之目的看,也能够对互相垂直的角度给以偏差(棱镜顶角偏差)。为此,能够采用以下方法:对各方向的V字形槽的槽角给以偏差、将V字形槽的侧壁设置成微小地弯曲的曲线状断面、使V字形槽的底部轨迹按弯折线状移动而将反射侧面做成多面体、或者使V字形槽的底部轨迹按弯折线状移动而将反射侧面做成曲面等方法。It is preferable that the three reflective side surfaces of each cube corner reflective element forming the composite reflective element of the present invention intersect each other substantially perpendicularly, but from the viewpoint of improving the observation angle characteristics by making the reflected light diverge slightly, it is also possible to The angles perpendicular to each other are given a deviation (prism apex angle deviation). To this end, the following methods can be adopted: giving deviations to the groove angles of the V-shaped grooves in each direction, providing the side walls of the V-shaped grooves in slightly curved curved cross-sections, and making the bottom traces of the V-shaped grooves in a bent line shape. There are methods such as moving and making the reflective side surface into a polyhedron, or moving the bottom track of the V-shaped groove in a curved line to make the reflective side surface into a curved surface.

形成本发明所示的多个副反射元件的多个V字形槽(xh、yh、zh)未形成连续的直线及曲线的轨迹。该轨迹可选择与邻接的主反射元件上已形成的其它的副反射元件不同的轨迹。这样,可采用各种轨迹,这在改善观测角特性的方面是有效的。形成主反射元件上形成的副反射元件的多个V字形槽(xh、yh、zh)可以分别采用不同的方法,对各方向的V字形槽的槽角给以偏差,可独立地采用以下方法:按各种反射元件对各方向的V字形槽的槽角给以偏差、采用使V字形槽的断面形状微小地弯曲的曲线状断面、使V字形槽的底部轨迹按弯折线状移动而将反射侧面做成多面体或者使V字形槽的底部轨迹按曲线状移动而将反射侧面做成曲面的方法等。The plurality of V-shaped grooves (xh, yh, zh) forming the plurality of sub-reflectors shown in the present invention do not form continuous straight and curved trajectories. The trajectory may be selected to be different from that of other secondary reflective elements formed on the adjacent primary reflective element. In this way, various trajectories can be employed, which is effective in improving the observation angle characteristics. A plurality of V-shaped grooves (xh, yh, zh) forming the sub-reflective element formed on the main reflective element can adopt different methods respectively, and give deviations to the groove angles of the V-shaped grooves in each direction, and the following methods can be independently adopted : The groove angle of the V-shaped groove in each direction is deviated according to various reflective elements, the cross-sectional shape of the V-shaped groove is slightly curved, and the bottom trajectory of the V-shaped groove is moved in a curved line. The reflective side is made into a polyhedron, or the bottom track of the V-shaped groove is moved in a curved shape to make the reflective side into a curved surface, etc.

特别是最好将形成副反射面的V字形槽的底部轨迹弯折线状移动而将反射侧面做成多面体。或特别是最好采用使形成副反射面的V字形槽的底部轨迹按曲线状移动而将反射侧面做成曲面等方法。In particular, it is preferable to make the reflective side surface into a polyhedron by moving the bottom track of the V-shaped groove forming the sub-reflective surface in a curved line. Or in particular, it is preferable to use a method such as moving the bottom track of the V-shaped groove forming the sub-reflecting surface in a curved shape to make the reflecting side surface into a curved surface.

另外,形成一个主反射元件所含的该副反射元件的3个方向的V字形槽的底部轨迹的至少1个方向的轨迹,最好不同于形成邻接的主反射元件所含副反射元件的同一方向的V字形槽的轨迹。可以列举以下的方法:例如使一个主反射元件中包含的副反射元件的V字形槽的底部轨迹按弯折线状移动而将反射侧面做成多面体以及使邻接的主反射元件中包含的形成副反射元件的同一方向的V字形槽的底部轨迹按曲线状移动而将反射侧面做成曲面的等方法。具有这种形状的回射元件的观测角特性优良。在槽底部的轨迹设为弯折线或曲线时,最好对直线给以相对于反射元件的底边长度为0.05~1%左右的偏差。In addition, at least one direction of the track of the bottom of the V-shaped groove in three directions forming the sub-reflecting element contained in one main reflecting element is preferably different from the same one forming the sub-reflecting element contained in the adjacent main reflecting element. The track of the V-shaped groove in the direction. The following methods can be enumerated: for example, the bottom track of the V-shaped groove of the sub-reflector included in one main reflector is moved in a bent line shape to make the reflective side into a polyhedron and make the sub-reflector included in the adjacent main reflector. The bottom track of the V-shaped groove in the same direction of the component moves in a curved shape and the reflective side is made into a curved surface. A retroreflective element having such a shape is excellent in viewing angle characteristics. When the track of the bottom of the groove is a meander line or a curved line, it is preferable to give the straight line a deviation of about 0.05 to 1% from the length of the bottom of the reflective element.

另外,形成该副反射元件的3个方向的V字形槽中至少1个方向的槽断面形状最好不同于形成邻接的主反射元件所含副反射元件的同一方向的V字形槽的断面形状。这里提到的所谓断面形状是指对V字形的断面形状的槽角度给以微小的偏差,或者在V字形断面上形成给以微小弯曲的设成曲面的形状等。可以有例如将一个主反射元件中包含的副反射元件的V字形的断面形状与形成邻接的主反射元件所含副反射元件的同一方向的V字形槽的断面形状做成不同的形状等方法。具有这种形状的回射元件的观测角特性优良。In addition, the cross-sectional shape of at least one of the three directions of the V-shaped grooves forming the sub-reflecting element is preferably different from the cross-sectional shape of the V-shaped grooves in the same direction forming the sub-reflecting elements included in the adjacent main reflecting element. The so-called cross-sectional shape mentioned here refers to a V-shaped cross-sectional shape with a slight deviation in the groove angle, or a V-shaped cross-sectional shape that is slightly curved and curved. For example, there may be a method of making the V-shaped cross-sectional shape of a sub-reflecting element included in one main reflecting element different from the cross-sectional shape of a V-shaped groove in the same direction forming a sub-reflecting element included in an adjacent main reflecting element. A retroreflective element having such a shape is excellent in viewing angle characteristics.

另外,可用于本发明中的复合反射元件的树脂和着色剂为传统产品,可适当采用,并无特别限制。另外,作为回射片及回射物而使用时的回射片及回射物的结构也可适当采用公知的传统制品结构。In addition, the resins and colorants that can be used in the composite reflective element in the present invention are conventional products and can be appropriately used without any particular limitation. In addition, the structure of the retroreflective sheeting and the retroreflective material when used as the retroreflective sheeting and the retroreflective material can also appropriately adopt known conventional product structures.

实施例Example

下面按照实施例,更具体地说明本发明的详细内容,但不言而喻,本发明并不仅限定于实施例。Hereinafter, the details of the present invention will be described in more detail based on examples, but it goes without saying that the present invention is not limited to the examples.

<回射系数><Coefficient of retroreflection>

从实施例开始,本说明书中记载的回射系数采用下面说明的方法进行测定。使用ガンマ-サイエンテイフイツク公司制的「Model920」作为回射系数测定器,按照ASTM E810-91,在观测角为0.2°及0.5°、入射角为5°、10°、20°及30°的角度条件下,对5个适当的位置测定10Omm×100mm的回射片的回射系数,以其平均值作为回射片的回射系数。The coefficient of retroreflection described in this specification was measured by the method demonstrated below from an Example. Using the "Model 920" manufactured by Gunma-Syenty Figure Co., Ltd. as a retroreflection coefficient measuring device, according to ASTM E810-91, at observation angles of 0.2° and 0.5°, and incident angles of 5°, 10°, 20° and 30° Under the angle condition, measure the retroreflection coefficient of the 100mm×100mm retroreflective sheeting for 5 appropriate positions, and take the average value as the retroreflective coefficient of the retroreflective sheeting.

<比较例1><Comparative example 1>

在形成具有图2所示的形状的光轴倾斜+7°的倾斜的三角锥型立方隅角回射元件,即元件高度(h)为130μm、x方向的平行V字形槽的内角为56.5°、重复节距为311.7μm、y和z方向的平行V字形槽的内角为77.0°、重复节距为266.8μm、x方向与y、z方向的相交角度为64.7°的加工要求下,使用飞旋切削法,形成配置多个倾斜三角锥型立方隅角回射元件的黄铜制模具。Forming a tilted triangular pyramid cube corner retroreflective element having the shape shown in Fig. 2 with the optical axis tilted +7°, that is, the element height (h) is 130 μm, and the inner angle of the parallel V-shaped grooves in the x direction is 56.5° , the repetition pitch is 311.7μm, the internal angle of the parallel V-shaped grooves in the y and z directions is 77.0°, the repetition pitch is 266.8μm, and the intersection angle between the x direction and the y and z directions is 64.7°. Cutting method to form a brass mold with a plurality of inclined triangular pyramid cube corner retroreflective elements.

使用此黄铜制母模,采用浓度为55%的氨基磺酸镍溶液,通过电镀法,制成材质为镍、形状被反转的凹状立方隅角成形用模具。回射片(对照样品1)的制作如下:使用此成形用模具,在成形温度200℃、成形压力50kg/cm2的条件下,将厚度200μm的聚碳酸酯树脂片(三菱工程塑料制品株式会社制「ユ—ピロンH3000」)压缩成形后,再在加压下冷却至30℃后,取出树脂片,制成在表面上将多个聚碳酸酯树脂制的复合立方隅角回射元件最密集填充地配置而成的回射片(比较样品1)。Using this brass master, a nickel sulfamate solution with a concentration of 55% was used for electroplating to form a mold for forming concave cube corners made of nickel and whose shape was reversed. The production of the retroreflective sheeting (comparative sample 1) is as follows: Using this molding die, under the conditions of molding temperature 200 ° C and molding pressure 50 kg/cm2, a polycarbonate resin sheet (manufactured by Mitsubishi Engineering Plastics Co., Ltd.) "U-Piron H3000") is compression molded, cooled to 30°C under pressure, and the resin sheet is taken out to make the most densely packed composite cube corner retroreflective elements made of polycarbonate resin on the surface. A retroreflective sheeting (comparative sample 1) configured in the ground.

<实施例1><Example 1>

采用与比较例1相同的方法,得到将图3所示的形状,即在光轴的倾斜角为+7°、由形成主反射元件的3个反射侧面的延长面相交而形成的假想顶点(Hm)至该主平面(S—S)的距离(hm)为130μm的主反射元件上设置4个元件光轴的倾斜角为+7°、高度(hs)为30μm的副元件群的复合回射元件。Adopt the method identical with comparative example 1, obtain the shape shown in Fig. 3, promptly be +7 ° at the inclination angle of optical axis, the imaginary vertex ( Hm) to the main plane (S—S) distance (hm) is 130 μm on the main reflective element, the composite circuit of 4 sub-element groups with an inclination angle of the optical axis of +7° and a height (hs) of 30 μm radio components.

该复合反射元件中的副反射元件的顶点(Hs)至该副平面(SH—SH)的距离(hs)与该主反射元件的假想顶点(Hm)至该主平面(S—S)的距离(hm)之比(hs/hm)为0.23,该主反射元件的假想顶点(Hm)至该副平面(SH—SH)的距离(hp)为50μm,比值(hp/hm)为0.385。The distance (hs) from the vertex (Hs) of the secondary reflective element in the composite reflective element to the secondary plane (SH-SH) and the distance from the imaginary vertex (Hm) of the main reflective element to the main plane (S-S) The ratio (hs/hm) of (hm) is 0.23, the distance (hp) from the imaginary vertex (Hm) of the main reflective element to the secondary plane (SH-SH) is 50 μm, and the ratio (hp/hm) is 0.385.

采用与比较例1相同的压缩成形法,制成将多个聚碳酸酯制的复合立方隅角回射元件最密集填充地配置而成的回射片(发明样品1)。Using the same compression molding method as in Comparative Example 1, a retroreflective sheeting (invention sample 1) in which a plurality of composite cube-corner retroreflective elements made of polycarbonate were arranged in the most densely packed manner was manufactured.

<实施例2><Example 2>

采用与比较例1相同的方法,得到在图6所示的形状,即在光轴的倾斜角为+7°、由形成主反射元件的3个反射侧面的延长面相交而形成的假想顶点(Hm)至该主平面(S—S)的距离(hm)为130μm的主反射元件上设置16个元件光轴的倾斜角为+7°、高度(hs)为30μm的副元件群的复合回射元件。Adopt the method identical with comparative example 1, obtain the shape shown in Fig. 6, promptly be +7 ° at the inclination angle of optical axis, the imaginary vertex ( Hm) to the main plane (S—S) distance (hm) is 130 μm on the main reflective element, set 16 sub-element groups with an inclination angle of the optical axis of +7° and a height (hs) of 30 μm. radio components.

该复合反射元件中的副反射元件的顶点(Hs)至该副平面(SH—SH)的距离(hs)与该主反射元件的假想顶点(Hm)至该主平面(S—S)的距离(hm)之比(hs/hm)为0.23,该主反射元件的假想顶点(Hm)至该副平面(SH-SH)的距离(hp)为65μm,比值(hp/hm)为0.5。The distance (hs) from the vertex (Hs) of the secondary reflective element in the composite reflective element to the secondary plane (SH-SH) and the distance from the imaginary vertex (Hm) of the main reflective element to the main plane (S-S) The ratio (hs/hm) of (hm) is 0.23, the distance (hp) from the imaginary vertex (Hm) of the main reflector to the sub-plane (SH-SH) is 65 μm, and the ratio (hp/hm) is 0.5.

采用与比较例1相同的压缩成形法,制成将多个聚碳酸酯制的复合立方隅角回射元件最密集填充地配置而成的回射片(发明样品2)。Using the same compression molding method as in Comparative Example 1, a retroreflective sheeting (invention sample 2) in which a plurality of composite cube-corner retroreflective elements made of polycarbonate were arranged in the most densely packed manner was produced.

<实施例3><Example 3>

采用与比较例1相同的方法,得到在图9所示的形状,即在光轴的倾斜角为-6°、由形成主反射元件的3个反射侧面的延长面相交而形成的假想顶点(Hm)至该主平面(S-S)的距离(hm)为180μm的主反射元件上设置4个元件光轴的倾斜角为-6°、高度(hs)为70μm的副元件群的复合回射元件。再有,形成的4个副反射元件的高度稍有不同,所以将位于中央的最高的副反射元件的顶点与副平面(SH-SH)之间的高度作为hs。Adopt the method identical with comparative example 1, obtain the shape shown in Fig. 9, be that the inclination angle of optical axis is-6 °, the imaginary vertex ( A composite retroreflective element in which four sub-element groups with an inclination angle of -6° of the optical axis of the element and a height (hs) of 70 μm are installed on the main reflective element whose distance (hm) from the main plane (S-S) is 180 μm . Note that the heights of the four sub-reflectors formed are slightly different, so the height between the apex of the tallest sub-reflector located in the center and the sub-plane (SH-SH) is defined as hs.

该复合反射元件中的副反射元件的顶点(Hs)至该副平面(SH-SH)的距离(hs)与主反射元件的假想顶点(Hm)至主平面(S-S)的距离(hm)之比(hs/hm)为0.39,该主反射元件的假想顶点(Hm)至该副平面(SH-SH)的距离(hp)为160m,比值(hp/hm)为0.89。The difference between the distance (hs) from the vertex (Hs) of the secondary reflective element in the composite reflective element to the secondary plane (SH-SH) and the distance (hm) from the imaginary vertex (Hm) of the main reflective element to the main plane (S-S) The ratio (hs/hm) is 0.39, the distance (hp) from the imaginary vertex (Hm) of the main reflecting element to the sub-plane (SH-SH) is 160m, and the ratio (hp/hm) is 0.89.

采用与比较例1相同的压缩成形法,制成将多个聚碳酸酯制的复合立方隅角回射元件最密集填充地配置而成的回射片(发明样品3)。Using the same compression molding method as in Comparative Example 1, a retroreflective sheeting (invention sample 3) in which a plurality of composite cube-corner retroreflective elements made of polycarbonate were arranged in the most densely packed manner was produced.

将上述实施例1~3中制成的多个复合立方隅角回射元件最密集填充地配置而成的回射片(发明样品1、2及3)以及比较例1中制成的三角锥型立方隅角型回射片(对照样品1)的回射系数的值示于表1。将基于本发明的实施例1和实施例2的回射片的回射系数与基于传统技术的比较例1的三角锥型立方隅角型回射片的回射系数相比较,在特别大的观测角下,在入射角大的方向上的回射特性更优良。Retroreflective sheetings (invention samples 1, 2 and 3) in which a plurality of composite cube corner retroreflective elements produced in Examples 1 to 3 were arranged in the most densely packed manner and triangular pyramids produced in Comparative Example 1 Table 1 shows the values of the retroreflective coefficients of the cube corner type retroreflective sheeting (comparative sample 1). Comparing the retroreflective coefficients of the retroreflective sheetings based on Embodiment 1 and Embodiment 2 of the present invention with the retroreflective coefficients of the triangular pyramid cube corner type retroreflective sheeting of Comparative Example 1 based on the conventional technology, in particularly large Under the observation angle, the retroreflection characteristic is better in the direction with a larger incident angle.

表1Table 1

  观测角 入射角 发明样品1 发明样品2 发明样品3 对照样品1 0.5° 650 587 620 750 0.5° 10° 576 535 528 651 0.5° 20° 417 466 494 447 0.5° 30° 377 400 422 324 1.0° 350 375 366 436 1.0° 10° 302 335 334 315 1.0° 20° 152 198 252 94 1.0° 30° 96 147 157 45 Observation angle angle of incidence Invention Sample 1 Invention Sample 2 Invention Sample 3 Control sample 1 0.5° 650 587 620 750 0.5° 10° 576 535 528 651 0.5° 20° 417 466 494 447 0.5° 30° 377 400 422 324 1.0° 350 375 366 436 1.0° 10° 302 335 334 315 1.0° 20° 152 198 252 94 1.0° 30° 96 147 157 45

产业上的可应用性Industrial Applicability

本发明的三角锥型立方隅角回射片及回射物可用于道路标识(一般的交通标识及反光标牌)、路面标识(pavement maker)、工程标识等标识类、汽车及摩托车等车辆的号码牌类、贴在货车及拖车的车体上的反射胶带、衣料、救生器具等安全器材类以及广告牌等标志、可见光、激光或红外光反射型传感器类的反射板等,能够改善这些制品的回射性能。The triangular pyramid cube corner retroreflective sheeting and retroreflective objects of the present invention can be used for markings such as road signs (general traffic signs and reflective signs), pavement markers (pavement maker), engineering signs, and vehicles such as automobiles and motorcycles. Number plates, reflective tapes attached to the body of trucks and trailers, safety equipment such as clothing, life-saving appliances, signs such as billboards, reflectors such as visible light, laser or infrared light reflective sensors, etc., can improve these products retroreflective performance.

Claims (34)

1.一种回射物,其特征在于包含复合立方隅角回射元件,其形成方式如下:通过断面基本为对称形的3个方向的V字形平行槽群互相交叉,将由3个大致以直角互相交叉的反射侧面划分的至少2个以上的被称为副反射元件的三角锥型立方隅角回射元件的副反射元件群最密集填充地配置成向共有的副平面(SH—SH)上的一侧突出,并通过配置于主平面(S—S)上的、断面基本为对称形的3个方向的V字形平行槽群互相交叉,将所述副反射元件群配置在由3个大致以直角互相交叉的反射侧面划分的1个被称为主反射元件的三角锥型立方隅角回射元件上。1. A retroreflector is characterized in that it comprises a composite cube corner retroreflective element, and its formation method is as follows: the V-shaped parallel groove groups passing through the 3 directions of the symmetrical cross section cross each other, and the 3 roughly at right angles are formed. At least two or more triangular-pyramid cube corner retroreflective elements called sub-reflective elements divided by intersecting reflective sides are most densely packed and arranged on a common sub-plane (SH-SH) One side protrudes, and through the V-shaped parallel groove groups arranged on the main plane (SS) and the cross-section is basically symmetrical in three directions, intersect each other, and the sub-reflector group is arranged in three roughly On a triangular-pyramidal cube corner retroreflective element called the main reflective element divided by reflective sides that intersect each other at right angles. 2.如权利要求项1记载的回射物,其特征在于:所述副平面(SH—SH)与所述主平面(S—S)平行。2. Retroreflector according to claim 1, characterized in that said secondary plane (SH-SH) is parallel to said main plane (S-S). 3.如权利要求项1或2中记载的回射物,其特征在于:所述副反射元件和/或所述主反射元件具有的光轴倾斜。3. The retroreflective object according to claim 1 or 2, characterized in that the optical axis of the secondary reflective element and/or the primary reflective element is inclined. 4.如权利要求项3记载的回射物,其特征在于:所述副反射元件和/或所述主反射元件具有的光轴倾斜1~13°。4. The retroreflective object according to claim 3, characterized in that: the optical axis of the secondary reflective element and/or the main reflective element is inclined by 1-13°. 5.如权利要求项3记载的回射物,其特征在于:所述副反射元件和/或所述主反射元件具有的光轴倾斜1.5~7°。5 . The retroreflective object according to claim 3 , wherein the optical axis of the secondary reflective element and/or the main reflective element is inclined by 1.5° to 7°. 6.如权利要求项1或2记载的回射物,其特征在于:形成所述主反射元件的3个反射侧面的延长面交叉而形成的假想顶点(Hm)至所述主平面(S—S)的距离hm为50μm以上。6. The retroreflective object as claimed in claim 1 or 2, characterized in that: the imaginary vertex (Hm) formed by the intersection of the extended planes of the three reflective side surfaces forming the main reflector element to the main plane (S— The distance hm of S) is 50 μm or more. 7.如权利要求项6记载的回射物,其特征在于:形成所述主反射元件的3个反射侧面的延长面交叉而形成的假想顶点(Hm)至所述主平面(S—S)的距离hm为80~300μm。7. The retroreflective object as claimed in claim 6, characterized in that: the imaginary vertex (Hm) formed by the intersection of the extended planes of the three reflective side surfaces forming the main reflector element to the main plane (S—S) The distance hm is 80-300 μm. 8.如权利要求项6记载的回射物,其特征在于:所述副反射元件的顶点(Hs)至所述副平面(SH—SH)的距离hs与所述主反射元件的假想顶点(Hm)至所述主平面(S—S)的距离hm之比hs/hm为0.1~0.5。8. The retroreflector as claimed in claim 6, characterized in that: the distance hs from the vertex (Hs) of the secondary reflective element to the secondary plane (SH-SH) is the same as the imaginary vertex (Hs) of the main reflective element ( The ratio hs/hm of the distance hm from Hm) to the main plane (S—S) is 0.1˜0.5. 9.如权利要求项8记载的回射物,其特征在于:所述副反射元件的顶点(Hs)至所述副平面(SH—SH)的距离hs与所述主反射元件的假想顶点(Hm)至所述主平面(S—S)的距离hm之比hs/hm为0.1~0.3。9. The retroreflector as claimed in claim 8, characterized in that: the distance hs from the vertex (Hs) of the secondary reflective element to the secondary plane (SH-SH) is the same as the imaginary vertex (Hs) of the main reflective element ( The ratio hs/hm of the distance hm from Hm) to the main plane (S—S) is 0.1˜0.3. 10.如权利要求项6记载的回射物,其特征在于:所述主反射元件的假想顶点(Hm)至所述副平面(SH—SH)的距离hp与所述假想顶点(Hm)至所述主平面(S—S)的距离hm之比hp/hm为0.1~0.9。10. The retroreflector as claimed in claim 6, characterized in that: the distance hp from the imaginary vertex (Hm) of the main reflective element to the secondary plane (SH-SH) is the same as the distance hp from the imaginary vertex (Hm) to The ratio hp/hm of the distance hm of the main plane (S—S) is 0.1˜0.9. 11.如权利要求项10记载的回射物,其特征在于:所述主反射元件的假想顶点(Hm)至所述副平面(SH—SH)的距离hp与所述假想顶点(Hm)至所述主平面(S—S)的距离hm之比hp/hm为0.3~0.5。11. The retroreflector as claimed in claim 10, characterized in that: the distance hp from the imaginary vertex (Hm) of the main reflective element to the secondary plane (SH-SH) is the same as the distance hp from the imaginary vertex (Hm) to The ratio hp/hm of the distance hm of the main plane (S—S) is 0.3˜0.5. 12.如权利要求项1或2记载的回射物,其特征在于:形成所述主反射元件的3个方向的底边与形成所述副反射元件的另3个方向的底边中的至少一组方向的底边平行。12. The retroreflective object as claimed in claim 1 or 2, wherein at least one of the bottom edges in three directions forming the main reflective element and the bottom edges in the other three directions forming the secondary reflective element A set of directions whose bases are parallel. 13.如权利要求项1或2记载的回射物,其特征在于:形成所述主反射元件的3个方向的底边与形成所述副反射元件的另3个方向的底边中的任一组方向的底边都不平行。13. The retroreflective object as claimed in claim 1 or 2, characterized in that: any of the bottom edges in three directions forming the main reflective element and the bottom edges in the other three directions forming the secondary reflective element The bases of a set of directions are all non-parallel. 14.如权利要求项1或2记载的回射物,其特征在于:形成所述主反射元件的3个方向的底边与形成所述副反射元件的另3个方向的底边中的一组方向的底边构成30°~60°的角度。14. The retroreflective object as claimed in claim 1 or 2, wherein one of the bases forming the three directions of the main reflective element and the bases forming the other three directions of the secondary reflective element The bases of the group directions form an angle of 30° to 60°. 15.如权利要求项1或2记载的回射物,其特征在于:形成所述主反射元件的3个方向的底边与形成所述副反射元件的另3个方向的底边中的一组方向的底边成直角。15. The retroreflective object as claimed in claim 1 or 2, wherein one of the bases forming the three directions of the main reflective element and the bases forming the other three directions of the sub-reflecting element The bases of the group directions are at right angles. 16.如权利要求项1或2记载的回射物,其特征在于:形成所述副反射元件的3个方向的V字形槽的底部的轨迹中的至少1个方向的轨迹,不同于形成邻接的主反射元件所含副反射元件的同一方向的V字形槽的轨迹。16. The retroreflective object as claimed in claim 1 or 2, characterized in that: the track of at least one direction in the track of the bottom of the V-shaped groove forming the three directions of the sub-reflecting element is different from the track of forming the adjacent The tracks of the V-shaped grooves in the same direction as the sub-reflective elements contained in the main reflective element. 17.如权利要求项1或2记载的回射物,其特征在于:形成所述副反射元件的3个方向的V字形槽的至少1个方向的槽的断面形状,不同于形成邻接的主反射元件所含副反射元件的同一方向的V字形槽的断面形状。17. The retroreflective material according to claim 1 or 2, wherein the cross-sectional shape of at least one of the V-shaped grooves in three directions forming the sub-reflector is different from that of the adjacent main groove. The cross-sectional shape of the V-shaped grooves in the same direction of the sub-reflective element included in the reflective element. 18.一种三角锥型立方隅角回射片,其特征在于包含复合立方隅角回射元件,其形成方式如下:通过断面基本为对称形的3个方向的V字形平行槽群互相交叉,将由3个大致以直角互相交叉的反射侧面划分的至少2个以上的被称为副反射元件的三角锥型立方隅角回射元件的副反射元件群最密集填充地配置成向共有的副平面(SH—SH)上的一侧突出,并通过配置于主平面(S—S)上的、断面基本为对称形的3个方向的V字形平行槽群互相交叉,将所述副反射元件群配置在由3个大致以直角互相交叉的反射侧面划分的1个被称为主反射元件的三角锥型立方隅角回射元件上。18. A triangular pyramidal cube corner retroreflective sheeting, characterized in that it comprises a composite cube corner retroreflective element, and its formation method is as follows: the V-shaped parallel groove groups in 3 directions whose cross-section is basically symmetrical cross each other, At least two or more triangular pyramidal cube corner retroreflective elements called sub-reflective elements divided by three reflective side surfaces that cross each other at approximately right angles are arranged in the most densely packed manner toward a common sub-plane One side of (SH—SH) protrudes, and the group of V-shaped parallel grooves arranged on the main plane (SS) and having a substantially symmetrical cross-section in three directions intersect each other, and the group of sub-reflecting elements It is arranged on a triangular pyramid-shaped cube corner retroreflective element called a main reflective element divided by three reflective side surfaces crossing each other approximately at right angles. 19.如权利要求项18记载的三角锥型立方隅角回射片,其特征在于:所述副平面(SH—SH)与所述主平面(S—S)平行。19. The triangular pyramid cube corner retroreflective sheeting according to claim 18, wherein said secondary plane (SH-SH) is parallel to said main plane (S-S). 20.如权利要求项18或19中记载的三角锥型立方隅角回射片,其特征在于:所述副反射元件和/或所述主反射元件具有的光轴倾斜。20. The triangular pyramid cube corner retroreflective sheeting according to claim 18 or 19, wherein the optical axis of the secondary reflective element and/or the primary reflective element is inclined. 21.如权利要求项20记载的三角锥型立方隅角回射片,其特征在于:所述副反射元件和/或所述主反射元件具有的光轴倾斜1~13°。21. The triangular pyramid cube corner retroreflective sheeting according to claim 20, wherein the optical axis of the secondary reflective element and/or the primary reflective element is inclined by 1-13°. 22.如权利要求项20记载的三角锥型立方隅角回射片,其特征在于:所述副反射元件和/或所述主反射元件具有的光轴倾斜1.5~7°。22. The triangular pyramid cube corner retroreflective sheeting according to claim 20, wherein the optical axis of the secondary reflective element and/or the primary reflective element is inclined by 1.5° to 7°. 23.如权利要求项18或19记载的三角锥型立方隅角回射片,其特征在于:形成所述主反射元件的3个反射侧面的延长面交叉而形成的假想顶点(Hm)至所述主平面(S—S)的距离hm为50μm以上。23. The triangular pyramid cube corner retroreflective sheeting as claimed in claim 18 or 19, characterized in that: the imaginary vertex (Hm) formed by the crossing of the extended planes of the three reflective side surfaces forming the main reflective element reaches the The distance hm between the main planes (S—S) is 50 μm or more. 24.如权利要求项23记载的三角锥型立方隅角回射片,其特征在于:形成所述主反射元件的3个反射侧面的延长面交叉而形成的假想顶点(Hm)至所述主平面(S—S)的距离hm为80~300μm。24. The triangular pyramid cube corner retroreflective sheeting as claimed in claim 23, characterized in that: the imaginary vertex (Hm) formed by the intersection of the extended planes of the three reflective side surfaces forming the main reflective element reaches to the main reflective element. The distance hm of the plane (S—S) is 80-300 μm. 25.如权利要求项23记载的三角锥型立方隅角回射片,其特征在于:所述副反射元件的顶点(Hs)至所述副平面(SH—SH)的距离hs与所述主反射元件的假想顶点(Hm)至所述主平面(S—S)的距离hm之比hs/hm为0.1~0.5。25. The triangular pyramid cube corner retroreflective sheeting as claimed in claim 23, wherein the distance hs from the apex (Hs) of the secondary reflective element to the secondary plane (SH-SH) is the same as that of the main The ratio hs/hm of the distance hm from the imaginary vertex (Hm) of the reflective element to the main plane (S—S) is 0.1˜0.5. 26.如权利要求项25记载的三角锥型立方隅角回射片,其特征在于:所述副反射元件的顶点(Hs)至所述副平面(SH—SH)的距离hs与所述主反射元件的假想顶点(Hm)至所述主平面(S—S)的距离hm之比hs/hm为0.1~0.3。26. The triangular pyramid cube corner retroreflective sheeting as claimed in claim 25, wherein the distance hs from the apex (Hs) of the secondary reflective element to the secondary plane (SH-SH) is the same as that of the primary reflector. The ratio hs/hm of the distance hm from the imaginary vertex (Hm) of the reflective element to the main plane (S—S) is 0.1˜0.3. 27.如权利要求项23记载的三角锥型立方隅角回射片,其特征在于:所述主反射元件的假想顶点(Hm)至所述副平面(SH—SH)的距离hp与所述假想顶点(Hm)至所述主平面(S—S)的距离hm之比hp/hm为0.1~0.9。27. The triangular pyramid cube corner retroreflective sheeting as claimed in claim 23, wherein the distance hp from the imaginary vertex (Hm) of the main reflective element to the secondary plane (SH-SH) is equal to the distance hp of the The ratio hp/hm of the distance hm from the imaginary vertex (Hm) to the main plane (S—S) is 0.1˜0.9. 28.如权利要求项27记载的三角锥型立方隅角回射片,其特征在于:所述主反射元件的假想顶点(Hm)至所述副平面(SH—SH)的距离hp与所述假想顶点(Hm)至所述主平面(S—S)的距离hm之比hp/hm为0.3~0.5。28. The triangular pyramid cube corner retroreflective sheeting as claimed in claim 27, wherein the distance hp from the imaginary vertex (Hm) of the main reflective element to the secondary plane (SH-SH) is equal to the distance hp of the The ratio hp/hm of the distance hm from the imaginary vertex (Hm) to the main plane (S—S) is 0.3˜0.5. 29.如权利要求项18或19记载的三角锥型立方隅角回射片,其特征在于:形成所述主反射元件的3个方向的底边与形成所述副反射元件的另3个方向的底边中的至少一组方向的底边平行。29. The triangular-pyramid cube corner retroreflective sheeting according to claim 18 or 19, wherein the bases of the three directions forming the main reflective element and the other three directions forming the secondary reflective element The bases of at least one set of orientations of the bases are parallel. 30.如权利要求项18或19记载的三角锥型立方隅角回射片,其特征在于:形成所述主反射元件的3个方向的底边与形成所述副反射元件的另3个方向的底边中的任一组方向的底边都不平行。30. The triangular-pyramid cube corner retroreflective sheeting as claimed in claim 18 or 19, wherein the bases of the three directions forming the main reflective element and the other three directions forming the secondary reflective element The bases of any set of directions in the bases of are not parallel. 31.如权利要求项18或19记载的三角锥型立方隅角回射片,其特征在于:形成所述主反射元件的3个方向的底边与形成所述副反射元件的另3个方向的底边中的一组方向的底边构成30°~60°的角度。31. The triangular-pyramid cube corner retroreflective sheeting according to claim 18 or 19, wherein the bases of the three directions forming the main reflective element and the other three directions forming the secondary reflective element The bases of a group of directions in the bases form an angle of 30° to 60°. 32.如权利要求项18或19记载的三角锥型立方隅角回射片,其特征在于:形成所述主反射元件的3个方向的底边与形成所述副反射元件的另3个方向的底边中的一组方向的底边成直角。32. The triangular-pyramid cube corner retroreflective sheeting according to claim 18 or 19, wherein the bases of the three directions forming the main reflective element and the other three directions forming the secondary reflective element The bases of a set of directions in the bases of are at right angles. 33.如权利要求项18或19记载的三角锥型立方隅角回射片,其特征在于:形成所述副反射元件的3个方向的V字形槽的底部的轨迹中的至少1个方向的轨迹,不同于形成邻接的主反射元件所含副反射元件的同一方向的V字形槽的轨迹。33. The triangular-pyramid cube corner retroreflective sheeting according to claim 18 or 19, wherein at least one of the tracks of the bottom of the V-shaped groove in three directions forming the sub-reflective element is The track is different from the track of V-shaped grooves in the same direction that form the sub-reflective elements included in the adjacent main reflective elements. 34.如权利要求项18或19记载的三角锥型立方隅角回射片,其特征在于:形成所述副反射元件的3个方向的V字形槽的至少1个方向的槽的断面形状,不同于形成邻接的主反射元件所含副反射元件的同一方向的V字形槽的断面形状。34. The triangular pyramid cube corner retroreflective sheeting according to claim 18 or 19, wherein the cross-sectional shape of at least one of the V-shaped grooves in three directions forming the sub-reflector element is It is different from the cross-sectional shape of the V-shaped grooves in the same direction that form the sub-reflective elements included in the adjacent main reflective elements.
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Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7938549B2 (en) * 2005-11-30 2011-05-10 Nippon Carbide Industries Co., Inc. Retroreflective article
KR20090067654A (en) * 2007-12-21 2009-06-25 김봉주 Retroreflective element and retroreflective body having same
JP4980950B2 (en) * 2008-02-22 2012-07-18 日本カーバイド工業株式会社 Triangular pyramid cube corner retroreflective article
US8662682B2 (en) * 2008-11-04 2014-03-04 Susanna Sidoti Gorodisher Magnetically repositionable reflective safety devices
WO2010120845A2 (en) 2009-04-15 2010-10-21 3M Innovative Properties Company Backlight and display system incorporating same
JP5727460B2 (en) 2009-04-15 2015-06-03 スリーエム イノベイティブ プロパティズ カンパニー Optical film for preventing optical coupling
US9291752B2 (en) 2013-08-19 2016-03-22 3M Innovative Properties Company Retroreflecting optical construction
US8534849B2 (en) 2009-04-15 2013-09-17 3M Innovative Properties Company Retroreflecting optical construction
TWI605276B (en) 2009-04-15 2017-11-11 3M新設資產公司 Optical construction and display system incorporating same
JP5526125B2 (en) * 2009-05-11 2014-06-18 日本カーバイド工業株式会社 Hexagonal cube corner retroreflective article
US9507050B2 (en) * 2009-12-14 2016-11-29 Montel Inc. Entity detection system and method for monitoring an area
US20110216412A1 (en) * 2010-03-05 2011-09-08 David Reed Master tools with selectively orientable regions for manufacture of patterned sheeting
KR101960149B1 (en) 2010-04-15 2019-03-19 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Retroreflective articles including optically active areas and optically inactive areas
KR101954456B1 (en) 2010-04-15 2019-03-05 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Retroreflective articles including optically active areas and optically inactive areas
KR101954457B1 (en) 2010-04-15 2019-03-05 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Retroreflective articles including optically active areas and optically inactive areas
KR20140035454A (en) 2011-05-31 2014-03-21 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Method for making microstructured tools having discontinuous topographies, articles produced therefrom
EP2714358B1 (en) 2011-05-31 2020-02-19 3M Innovative Properties Company Methods for making differentially pattern cured microstructured articles
US8783880B2 (en) * 2011-11-01 2014-07-22 Avery Dennison Corporation Rulable multi-directional prism cluster retroreflective sheeting
JP6452815B2 (en) * 2015-06-12 2019-01-16 日本カーバイド工業株式会社 Image display device
US10444615B2 (en) 2017-08-29 2019-10-15 Avery Dennison Corporation Retroreflective sheeting for projector-based display system
CN107957605A (en) * 2018-01-12 2018-04-24 上海午井光电科技有限公司 Speculum
DE102018117569B4 (en) 2018-07-20 2023-09-07 Hans-Erich Gubela Retroreflector, injection mold and use of a retroreflector
CN109031510B (en) * 2018-08-24 2020-06-30 京东方科技集团股份有限公司 A light guide plate and its manufacturing method, a backlight module and a display device
KR20230056694A (en) 2020-08-27 2023-04-27 오러 옵티칼 시스템즈, 엘피 Microprism retroreflective mold, sheet and article and method for manufacturing the same

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2481757A (en) * 1945-05-23 1949-09-13 Thoger G Jungersen Optical reflecting material
JPS5040953Y1 (en) * 1969-10-15 1975-11-21
US3712706A (en) * 1971-01-04 1973-01-23 American Cyanamid Co Retroreflective surface
SE402628B (en) 1973-04-24 1978-07-10 Pengilly Eric Alecander GEAR GEAR WITH SEVERAL SECOND AXLES AND LOAD EQUALIZATION
US4202600A (en) * 1978-04-24 1980-05-13 Avery International Corporation Diced retroreflective sheeting
AU560276B2 (en) 1983-09-12 1987-04-02 Minnesota Mining And Manufacturing Company Cube-corner retroreflective articles
US4775219A (en) * 1986-11-21 1988-10-04 Minnesota Mining & Manufacturing Company Cube-corner retroreflective articles having tailored divergence profiles
US5171624A (en) * 1990-06-01 1992-12-15 Reflexite Corporation Retroreflective microprismatic material and method of making same
US5138488A (en) * 1990-09-10 1992-08-11 Minnesota Mining And Manufacturing Company Retroreflective material with improved angularity
JPH06273608A (en) 1993-03-22 1994-09-30 Olympus Optical Co Ltd Reversing reflector
US5759468A (en) * 1993-10-20 1998-06-02 Minnesota Mining And Manufacturing Company Raised zone retroreflective cube corner article and method of manufacture
CN1040693C (en) 1993-10-20 1998-11-11 美国3M公司 Raised zone retroreflective cube corner article and method of manufacture
US5565151A (en) 1994-09-28 1996-10-15 Reflexite Corporation Retroreflective prism structure with windows formed thereon
US5706132A (en) * 1996-01-19 1998-01-06 Minnesota Mining And Manufacturing Company Dual orientation retroreflective sheeting
US6036322A (en) * 1997-12-01 2000-03-14 Reflexite Corporation Multi-orientation retroreflective structure
JP4225602B2 (en) 1998-04-22 2009-02-18 日本カーバイド工業株式会社 Triangular pyramid cube corner retroreflective sheet
JP3975001B2 (en) * 1998-04-22 2007-09-12 日本カーバイド工業株式会社 Triangular pyramid cube corner retroreflective sheet
KR100373209B1 (en) 1999-09-11 2003-02-25 주식회사 엘지화학 Retroreflective article
US6626544B2 (en) * 2001-03-28 2003-09-30 Reflexite Corporation Prismatic retroreflector having a multi-plane facet

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