CN100541845C - Light emitting device and lighting device - Google Patents
Light emitting device and lighting device Download PDFInfo
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Abstract
本发明的课题是提供与以往的器件相比能实现高功率、高输出的器件特性的发光器件及其制造方法以及提高了散热性且可靠性高的照明装置。本发明的发光器件的特征在于:具备陶瓷构件1、发光元件2、透光性构件4和金属构件5,用粘接剂相互粘接了陶瓷构件1与透光性构件4和陶瓷构件1与金属构件5,该粘接剂是被构成为在固化粘接状态下显示出柔软性的热熔材料6,陶瓷构件1至少在供电粘接区域的表面部分上具有气孔h,同时将热熔材料6浸渍于该气孔h中。
An object of the present invention is to provide a light-emitting device capable of achieving higher power and higher output device characteristics than conventional devices, a manufacturing method thereof, and a highly reliable lighting device with improved heat dissipation. The light-emitting device of the present invention is characterized in that it includes a ceramic member 1, a light-emitting element 2, a translucent member 4, and a metal member 5, and the ceramic member 1 and the translucent member 4 are bonded to each other with an adhesive. The metal member 5, the adhesive is a hot-melt material 6 that is configured to exhibit flexibility in a cured bonded state, and the ceramic member 1 has pores h at least on the surface portion of the power supply bonding area, and the hot-melt material 6 is immersed in the pores h.
Description
技术领域 technical field
本发明涉及发光二极管或激光二极管等的发光器件及其制造方法,例如涉及作为设置了高功率、高输出的发光元件的发光二极管而被构成的、在散热性方面良好的发光器件及其制造方法,还涉及使用该发光器件而被构成的照明装置。The present invention relates to a light-emitting device such as a light-emitting diode or a laser diode, and a method for manufacturing the same, for example, to a light-emitting device configured as a light-emitting diode provided with a high-power, high-output light-emitting element and having excellent heat dissipation, and a method for manufacturing the same , and also relates to a lighting device constructed using the light emitting device.
背景技术 Background technique
作为发光器件,代表性地可举出发光二极管或激光二极管等的电子器件。其中,对于发光二极管(以下也称为LED)来说,通过设置发光元件并对该发光元件供给规定的功率,从该发光元件射出光。此时,发光元件伴随该发光而发热,由此,LED的温度上升了。Representative examples of the light emitting device include electronic devices such as light emitting diodes and laser diodes. Among them, in light emitting diodes (hereinafter also referred to as LEDs), light is emitted from the light emitting elements by providing a light emitting element and supplying predetermined power to the light emitting element. At this time, the light emitting element generates heat along with the light emission, thereby increasing the temperature of the LED.
近年来,随着蓝色LED及白色LED的实用化,越来越多地将LED利用于电气制品的指示灯或携带电话机的液晶背照光源等的显示,进而,随着高的发光效率及亮度的提高,预期将广泛地利用于室内照明、汽车用照明、信号机等的照明等。在以这种方式利用于照明等的情况下,今后要求更高的输出的LED,此时,对发光元件供给更高的功率,相应地LED的温度上升得更多。In recent years, with the practical use of blue LEDs and white LEDs, more and more LEDs are used in the display of indicator lights of electrical products or liquid crystal backlights of mobile phones. Furthermore, with the high luminous efficiency And the improvement of brightness is expected to be widely used in indoor lighting, automotive lighting, signal lighting, etc. In the case of using it for lighting in this way, higher output LEDs are required in the future, and at this time, higher power is supplied to the light-emitting element, and the temperature of the LEDs increases accordingly.
在这样的高功率、高输出的LED等的发光器件中,有时采用由陶瓷构成的封装用陶瓷构件作为能耐受上述那样的温度上升的封装用构件。In light-emitting devices such as such high-power, high-output LEDs, a packaging ceramic member made of ceramics is sometimes used as a packaging member that can withstand the above-mentioned temperature rise.
在具备这样的封装用陶瓷构件的发光器件中,例如在封装用陶瓷构件上设置由金属构成的散热用金属构件,以便将发光元件等的半导体元件的温度抑制在规定的工作保证温度以下,利用热传导使来自半导体元件的热迅速地从陶瓷构件朝向金属构件移动,同时用该金属构件使其分散,高效地进行了从金属构件表面至散热部的散热。In a light-emitting device including such a ceramic member for packaging, for example, a metal member for heat dissipation made of metal is provided on the ceramic member for packaging in order to suppress the temperature of semiconductor elements such as light-emitting elements below a predetermined guaranteed operating temperature. Heat conduction quickly moves heat from the semiconductor element from the ceramic member to the metal member, and at the same time disperses it with the metal member, thereby efficiently dissipating heat from the surface of the metal member to the heat dissipation portion.
在具备这样的散热用金属构件和封装用陶瓷构件的发光器件中,通常用粘接剂相互粘接了金属构件与陶瓷构件。以往,通过用一般使用的银(Ag)、金(Au)、铜(Cu)、Zn(锌)、Cd(镉)等的焊接材料作为这样的粘接剂进行带焊料焊接,进行了这样的金属构件与陶瓷构件的粘接。In a light emitting device including such a metal member for heat dissipation and a ceramic member for packaging, the metal member and the ceramic member are usually bonded to each other with an adhesive. Conventionally, such soldering has been performed by using generally used solder materials such as silver (Ag), gold (Au), copper (Cu), Zn (zinc), and Cd (cadmium) as such adhesives. Bonding of metal components to ceramic components.
但是,在上述那样的具备散热用金属构件和封装用陶瓷构件并用焊接相互粘接了金属构件与陶瓷构件的发光器件中,如果在金属构件与陶瓷构件的线膨胀系数中存在差异,则相应地在金属构件和陶瓷构件中产生伴随温度上升的应力,容易发生翘曲、陶瓷构件的破损(裂纹)等。为了避免该问题,以往在陶瓷构件和金属构件的粘接中使用了各自的线膨胀系数近似的材料作为陶瓷材料和金属材料。However, in the above-mentioned light-emitting device including the metal member for heat dissipation and the ceramic member for packaging, and the metal member and the ceramic member are bonded to each other by welding, if there is a difference in the linear expansion coefficients of the metal member and the ceramic member, then correspondingly Stress accompanying temperature rise occurs in metal members and ceramic members, and warping, breakage (cracks) of ceramic members, and the like are likely to occur. In order to avoid this problem, conventionally, materials having similar coefficients of linear expansion have been used as ceramic materials and metal materials for bonding ceramic members and metal members.
作为上述的陶瓷材料,一般使用氮化铝(AlN)、氧化铝(Al2O3)等,作为上述的金属材料,一般使用铜-钨复合材料(CuW)、铜-钼复合材料(CuMo、CuMoCu)等。以下,示出各材料的线膨胀系数。Aluminum nitride (AlN), aluminum oxide (Al 2 O 3 ), etc. are generally used as the above-mentioned ceramic material, and copper-tungsten composite material (CuW), copper-molybdenum composite material (CuMo, CuMoCu) etc. The coefficients of linear expansion of the respective materials are shown below.
陶瓷材料 AlN 4.5×10-6 Ceramic material AlN 4.5×10 -6
Al2O3 6.7×10-6 Al 2 O 3 6.7×10 -6
金属材料 CuW 6.5×10-6(W-10:89W,11Cu)Metal material CuW 6.5×10 -6 (W-10: 89W, 11Cu)
CuMo 7.0×10-6(CM-15:85Mo,15Cu)CuMo 7.0×10 -6 (CM-15: 85Mo, 15Cu)
CuMoCu 8.9×10-6(CMC111)CuMoCu 8.9×10 -6 (CMC111)
再有,上述的CuMoCu(CMC111)是用2片Cu板夹住Mo板并进行了压接的材料,3层比定为Cu∶Mo∶Cu=1∶1∶1。In addition, the above-mentioned CuMoCu (CMC111) is a material obtained by sandwiching a Mo plate between two Cu plates and press-bonding, and the three-layer ratio is set to be Cu:Mo:Cu=1:1:1.
但是,上述的CuW、CuMo、CuMoCu等的金属材料的热传导率相对于热传导率比较良好的金属材料的热传导率(代表性地为Cu(393W/mk))来说,是比较差的,即CuW(180W/mk)、CuMo(160W/mk)、CuMoCu(232W/mk)。因而,在与被利用于照明等的现有的器件相比为高功率、高输出的LED等的发光器件中,作为散热用金属构件,虽然希望使用Cu那样的热传导率比较良好的金属材料,但Cu(线膨胀系数为17.0×10-6)那样的金属材料的线膨胀系数相对于陶瓷材料的线膨胀系数来说,其差异较大,容易发生上述那样的起因于伴随金属构件和陶瓷构件的温度上升的应力的翘曲、陶瓷构件的破损(裂纹)等的问题。However, the thermal conductivity of metal materials such as CuW, CuMo, and CuMoCu mentioned above is relatively poor compared to the thermal conductivity of metal materials with relatively good thermal conductivity (typically Cu (393W/mk)), that is, CuW (180W/mk), CuMo (160W/mk), CuMoCu (232W/mk). Therefore, in light-emitting devices such as LEDs with high power and high output compared with conventional devices used for lighting, it is desirable to use a metal material with relatively good thermal conductivity such as Cu as a metal member for heat dissipation. However, the linear expansion coefficient of metallic materials such as Cu (the coefficient of linear expansion is 17.0×10 -6 ) is relatively different from that of ceramic materials, and the above-mentioned problems are likely to occur due to the accompanying metal components and ceramic components. Problems such as warping due to stress caused by temperature rise, and breakage (cracks) of ceramic components.
另一方面,在高功率、高输出的LED中,有以下的要求。即,在LED中,一般来说,难以利用从发光元件的侧方射出的光,相应地难以高效地射出光。例如,在使用陶瓷构件作为封装用构件的情况下,由于从发光元件的侧方射出的光被陶瓷构件反射而向外部发出,故相应地不能高效地利用光。此外,例如在将LED利用于照明等的情况下,如果用透镜等对来自发光元件的光进行聚光,则因从发光元件侧方被陶瓷构件反射的反射光的缘故而导致聚光不匀。以往设置多个LED作为多个光源,以减少因该聚光不匀产生的影响。但是,与现有的器件相比为高功率、高输出的LED可作为单一的光源来利用。因而,在与现有的器件相比为高功率、高输出的LED中,特别要求高效地且以聚光不匀少的方式有效地利用从发光元件侧方射出的光。On the other hand, high-power, high-output LEDs have the following requirements. That is, in LEDs, it is generally difficult to utilize the light emitted from the side of the light emitting element, and accordingly it is difficult to efficiently emit light. For example, when a ceramic member is used as the packaging member, the light emitted from the side of the light emitting element is reflected by the ceramic member and emitted to the outside, so the light cannot be used efficiently accordingly. In addition, for example, in the case of using LEDs for lighting, etc., if the light from the light emitting element is condensed by a lens or the like, the light will be unevenly concentrated due to the reflected light reflected by the ceramic member from the side of the light emitting element. . In the past, a plurality of LEDs were installed as a plurality of light sources to reduce the influence of the uneven concentration of light. However, LEDs that have higher power and higher output than conventional devices can be used as a single light source. Therefore, in LEDs having higher power and higher output than conventional devices, it is particularly required to efficiently utilize light emitted from the side of the light emitting element with less unevenness in light concentration.
此外,在利用了上述现有的LED等的发光器件的照明装置中,利用锡焊或引线框的夹紧等的方法进行了与发光器件的电连接和固定。因而,由于利用了该发光器件的照明装置经锡焊的部分或引线框进行从发光器件至外部的布线基板的散热,故在热移动量方面存在极限,不能充分地确保散热性。因此,不能对照明装置投入大电流,不能作成高亮度的照明装置。In addition, in the illuminating device using the above-mentioned conventional light-emitting devices such as LEDs, electrical connection and fixation to the light-emitting devices are performed by methods such as soldering or clamping of lead frames. Therefore, since the soldered part or the lead frame of the lighting device using the light emitting device dissipates heat from the light emitting device to the external wiring board, there is a limit in the amount of heat transfer, and sufficient heat dissipation cannot be ensured. Therefore, a large current cannot be injected into the lighting device, and a high-brightness lighting device cannot be produced.
此外,如果一度利用与外部的布线基板的锡焊或夹紧将现有的发光器件装入照明装置的一部分中,则难以只取下发光器件的部分来进行修复。In addition, once an existing light-emitting device is incorporated into a part of the lighting device by soldering or clamping with an external wiring board, it is difficult to remove only the part of the light-emitting device for repair.
再者,将在发光器件的主面上设置的导电性图形的一部分与外部的布线基板进行锡焊或夹紧而构成的现有的照明装置的发光器件容易受到因来自外部的机械振动引起的不良影响。即,如果进行夹紧的话,则容易产生因发光器件在照明装置内转动引起的光学特性的变化,如果进行锡焊的话,则容易产生发光器件与外部的电路基板的电连接不良。Furthermore, the light-emitting device of the existing lighting device, which is formed by soldering or clamping a part of the conductive pattern provided on the main surface of the light-emitting device and an external wiring substrate, is susceptible to vibration caused by mechanical vibration from the outside. adverse effects. That is, if clamping is performed, changes in optical characteristics due to rotation of the light emitting device in the lighting device are likely to occur, and if soldering is performed, poor electrical connection between the light emitting device and an external circuit board is likely to occur.
发明内容 Contents of the invention
本发明是为了解决以上的问题而进行的,其第1目的在于提供以下的发光器件及其制造方法:本发明的发光器件具备由金属构成的散热用金属构件和由陶瓷构成的封装用陶瓷构件,用粘接剂相互粘接了上述金属构件与上述陶瓷构件,可抑制起因于伴随上述金属构件和上述陶瓷构件的温度上升的应力的翘曲、上述陶瓷构件的破损(裂纹)等的因上述金属构件与上述陶瓷构件的线膨胀系数的差异引起的温度变化时的问题的发生,因而,可用热传导率比较良好的金属材料作为上述金属构件的材料,可实现与现有的器件相比为高功率、高输出的器件特性。The present invention was made to solve the above problems, and its first object is to provide the following light-emitting device and its manufacturing method. The light-emitting device of the present invention includes a metal member for heat dissipation made of metal and a ceramic member for packaging made of ceramics. The above-mentioned metal member and the above-mentioned ceramic member are bonded to each other with an adhesive, and the warpage caused by the stress accompanying the temperature rise of the above-mentioned metal member and the above-mentioned ceramic member, and the damage (crack) of the above-mentioned ceramic member can be suppressed. The occurrence of problems caused by the difference in the linear expansion coefficient of the metal member and the above-mentioned ceramic member when the temperature changes, therefore, a metal material with a relatively good thermal conductivity can be used as the material of the above-mentioned metal member, and a higher temperature than the existing device can be realized. Power, high output device characteristics.
此外,本发明的第2目的在于提供以下的发光器件:本发明的发光器件具备由金属构成的散热用金属构件和由陶瓷构成的封装用陶瓷构件,用粘接剂相互粘接了上述金属构件与上述陶瓷构件,例如在作为设置了发光元件的发光二极管而被构成的情况下,可高效地且以聚光不匀少的方式有效地利用从上述发光元件侧方射出的光。In addition, a second object of the present invention is to provide a light-emitting device that includes a metal member for heat dissipation made of metal and a ceramic member for packaging made of ceramics, wherein the metal members are bonded to each other with an adhesive. When the above-mentioned ceramic member is configured as a light-emitting diode provided with a light-emitting element, for example, light emitted from the side of the light-emitting element can be efficiently used with less unevenness in light concentration.
再者,本发明的第3目的在于提供以下的照明装置:该照明装置是提高了散热性且可靠性高的照明装置,可置换现有的电灯泡、荧光灯等。Furthermore, a third object of the present invention is to provide an illuminating device with improved heat dissipation and high reliability, which can replace existing light bulbs, fluorescent lamps, and the like.
在本发明者为了实现上述第1目的而重复进行锐意研究时,发现了以下的情况。即,在用粘接剂相互粘接了由金属构成的散热用金属构件与由陶瓷构成的封装用陶瓷构件的发光器件中,在使用焊接材料作为上述粘接剂并用焊接进行上述金属构件与上述陶瓷构件的粘接的情况下,该焊接材料的伴随上述金属构件和上述陶瓷构件的温度上升的应力的缓冲性差,由此,容易发生翘曲、上述陶瓷构件的破损(裂纹)等的因上述金属构件与上述陶瓷构件的线膨胀系数的差异引起的温度变化时的问题。因此,如果使用被构成为在固化粘接状态下显示出柔软性的热熔材料作为上述粘接剂来粘接上述金属构件与上述陶瓷构件,则利用该热熔材料来缓和伴随上述金属构件和上述陶瓷构件的温度上升的应力,由此,可抑制翘曲、陶瓷构件的破损(裂纹)等的因上述金属构件与上述陶瓷构件的线膨胀系数的差异引起的温度变化时的问题的发生。The inventors of the present invention have found the following when they have repeatedly studied intensively in order to achieve the above-mentioned first object. That is, in a light-emitting device in which a metal member for heat dissipation made of metal and a ceramic member for packaging made of ceramics are bonded to each other with an adhesive, the metal member and the above-mentioned metal member are bonded together by welding using a solder material as the adhesive. In the case of adhesion of ceramic members, the welding material has poor buffering properties of the stress accompanying the temperature rise of the metal member and the ceramic member, thus easily causing warping, breakage (crack) of the ceramic member, etc. due to the above-mentioned Problems caused by temperature changes due to differences in linear expansion coefficients between metal members and the above-mentioned ceramic members. Therefore, if the above-mentioned metal member and the above-mentioned ceramic member are bonded using a hot-melt material configured to exhibit flexibility in a cured and bonded state as the above-mentioned adhesive, the hot-melt material will relax the accompanying pressure between the above-mentioned metal member and the above-mentioned ceramic member. The stress caused by the temperature rise of the ceramic member can suppress the occurrence of problems caused by temperature changes such as warpage and breakage (cracks) of the ceramic member due to the difference in linear expansion coefficient between the metal member and the ceramic member.
此外,本发明者在上述的研究过程中还得到了以下的见解。即,在陶瓷材料中,从脆度、加工性等的观点来看,有具有气孔的材料。如果利用该气孔,将上述热熔材料浸渍于上述陶瓷构件的表面的气孔中,将该热熔材料结合到该气孔中,则提高了该陶瓷构件与该热熔材料的粘接力,由此,即使粘接状态下的上述热熔材料的厚度比较薄,也可良好地保持粘接性,相应地提高了上述热熔材料的热传导性。In addition, the present inventors obtained the following findings during the course of the above-mentioned studies. That is, among ceramic materials, some have pores from the viewpoint of brittleness, workability, and the like. If the pores are used to impregnate the above-mentioned hot-melt material into the pores on the surface of the above-mentioned ceramic member, and the hot-melt material is incorporated into the pores, the adhesive force between the ceramic member and the hot-melt material is improved, thereby Even if the thickness of the above-mentioned hot-melt material in the bonded state is relatively thin, the adhesiveness can be maintained well, and the thermal conductivity of the above-mentioned hot-melt material is correspondingly improved.
本发明是基于这样的见解的发明,为了实现上述第1目的,提供以下的发光器件和发光器件的制造方法。The present invention is based on such knowledge, and in order to achieve the above-mentioned first object, the following light-emitting device and a method for manufacturing the light-emitting device are provided.
(1)发光器件(1) Light emitting devices
一种发光器件,具备由金属构成的散热用金属构件和由陶瓷构成的封装用陶瓷构件,用粘接剂相互粘接了上述金属构件与上述陶瓷构件,其特征在于:上述粘接剂是被构成为在比规定的温度高的熔融温度下加热熔融的同时在固化粘接状态下显示出柔软性的热熔材料,上述陶瓷构件至少在规定的粘接区域的表面部分中具有气孔,同时将上述热熔材料浸渍于该气孔中。A light-emitting device comprising a metal member for heat dissipation made of metal and a ceramic member for packaging made of ceramics, wherein the metal member and the ceramic member are bonded to each other with an adhesive, wherein the adhesive is A hot-melt material that exhibits flexibility in a solidified and bonded state while heating and melting at a melting temperature higher than a predetermined temperature, the above-mentioned ceramic member has pores at least in a surface portion of a predetermined bonding region, and simultaneously The aforementioned hot-melt material is impregnated in the pores.
(2)发光器件的制造方法(2) Manufacturing method of light-emitting device
一种发光器件的制造方法,该发光器件具备由金属构成的散热用金属构件和由陶瓷构成的封装用陶瓷构件,用粘接剂相互粘接了上述金属构件与上述陶瓷构件,其特征在于,包含下述工序:使溶解于水或水溶性有机溶剂中并在比规定的温度高的熔融温度下加热熔融的同时在固化粘接状态下显示出柔软性的树脂材料溶解于上述水或上述水溶性有机溶剂中以作成热熔材料作为上述粘接剂的粘接剂作成工序;采用至少在规定的粘接区域的表面部分上具有气孔的陶瓷构件作为上述陶瓷构件、在上述陶瓷构件的上述粘接区域的表面部分上涂敷用上述粘接剂作成工序作成的上述热熔材料、同时在规定的真空状态下使该热熔材料浸渍于上述陶瓷构件的上述粘接区域的表面部分中的气孔中的粘接剂涂敷浸渍工序;以及在用上述粘接剂涂敷浸渍工序涂敷浸渍了上述热熔材料的上述陶瓷构件与上述金属构件之间在上述熔融温度以上的粘接温度下熔接上述热熔材料从而相互粘接上述陶瓷构件与上述金属构件的陶瓷-金属粘接工序。A method of manufacturing a light emitting device comprising a metal member for heat dissipation made of metal and a ceramic member for packaging made of ceramics, wherein the metal member and the ceramic member are bonded to each other with an adhesive, characterized in that: It includes the step of dissolving in water or a water-soluble organic solvent and dissolving a resin material that exhibits flexibility in a cured and bonded state while being heated and melted at a melting temperature higher than a predetermined temperature in the water or the water-soluble organic solvent. The process of making a hot-melt material in a non-toxic organic solvent as the adhesive agent; using a ceramic member having pores at least on the surface of the predetermined bonding area as the ceramic member, and the above-mentioned adhesive on the ceramic member Coating the hot-melt material produced in the above-mentioned adhesive preparation process on the surface portion of the bonding area, and impregnating the hot-melt material in the pores in the surface portion of the bonding area of the ceramic member under a predetermined vacuum state The adhesive coating and dipping step in the above-mentioned adhesive agent coating and dipping step; and between the above-mentioned ceramic member coated and impregnated with the above-mentioned hot-melt material in the above-mentioned adhesive agent coating and dipping step and the above-mentioned metal member by welding at a bonding temperature above the melting temperature A ceramic-metal bonding process in which the hot-melt material is used to bond the ceramic member and the metal member to each other.
按照本发明的发光器件,由于粘接上述金属构件与上述陶瓷构件的粘接剂是被构成为在固化粘接状态下显示出柔软性的热熔材料,故利用该热熔材料可缓和伴随上述金属构件和上述陶瓷构件的温度上升的应力,由此,可抑制翘曲、上述陶瓷构件的破损(裂纹)等的因上述金属构件与上述陶瓷构件的线膨胀系数的差异引起的温度变化时的问题的发生,因而,可使用热传导率比较良好的金属材料(代表性地是铜(Cu))作为上述金属构件的材料,可实现与现有的器件特性相比为高功率、高输出的器件特性。此外,由于将上述热熔材料浸渍于上述陶瓷构件的上述粘接区域的表面部分中的气孔中,故可将上述热熔材料结合到上述气孔中,由此,可提高该陶瓷构件与该热熔材料的粘接力。因而,即使粘接状态下的上述热熔材料的厚度比较薄,也可良好地保持粘接性,相应地可提高上述热熔材料的热传导性。According to the light-emitting device of the present invention, since the adhesive for bonding the above-mentioned metal member and the above-mentioned ceramic member is a hot-melt material that exhibits flexibility in a cured and bonded state, the hot-melt material can alleviate the above-mentioned problems. The stress of the temperature rise of the metal member and the above-mentioned ceramic member can be suppressed, thereby suppressing the temperature change caused by the difference in the linear expansion coefficient of the above-mentioned metal member and the above-mentioned ceramic member, such as warping and breakage (cracks) of the above-mentioned ceramic member. Therefore, a metal material (typically copper (Cu)) with relatively good thermal conductivity can be used as the material of the above-mentioned metal member, and a device with high power and high output can be realized compared with the existing device characteristics. characteristic. In addition, since the above-mentioned hot-melt material is impregnated into the pores in the surface portion of the above-mentioned bonding region of the above-mentioned ceramic member, the above-mentioned hot-melt material can be bonded into the above-mentioned pores, thereby, the thermal bonding of the ceramic member can be improved. Adhesion of molten materials. Therefore, even if the thickness of the hot-melt material in the bonded state is relatively thin, good adhesiveness can be maintained, and the thermal conductivity of the hot-melt material can be improved accordingly.
在与本发明有关的发光器件的制造方法中,作为上述粘接剂被作成的上述热熔材料被涂敷在上述陶瓷构件的上述粘接区域的表面部分上,在上述规定的真空状态下被浸渍于上述陶瓷构件的上述粘接区域的表面部分中的气孔中。由于该热熔材料是将上述树脂材料溶解于上述水或上述水溶性有机溶剂中的热熔材料,故在室温(例如25℃)下粘性小,可均匀地浸渍于该气孔中,作为该规定的真空状态中的真空气氛气压,可例示约1kPa以下。其后,在被涂敷浸渍了上述热熔材料的上述陶瓷构件与上述金属构件之间在上述熔融温度以上的粘接温度下上述热熔材料因加热熔融而被激活,从而相互粘接上述陶瓷构件与上述金属构件。这样,通过将上述热熔材料真空浸渍于上述陶瓷构件的上述粘接区域的表面部分中的气孔中,可良好地结合该热熔材料与该气孔。这样,可制造上述与本发明有关的发光器件。In the method of manufacturing a light-emitting device according to the present invention, the hot-melt material prepared as the adhesive is applied to the surface portion of the bonding region of the ceramic member, and is heated in the predetermined vacuum state. impregnated into pores in the surface portion of the above-mentioned bonding region of the above-mentioned ceramic member. Since the hot-melt material is a hot-melt material in which the above-mentioned resin material is dissolved in the above-mentioned water or the above-mentioned water-soluble organic solvent, it has low viscosity at room temperature (for example, 25° C.) and can be uniformly impregnated in the pores. The pressure of the vacuum atmosphere in the vacuum state is, for example, about 1 kPa or less. Thereafter, the above-mentioned hot-melt material is activated by heating and melting between the above-mentioned ceramic member and the above-mentioned metal member coated with and impregnated with the above-mentioned hot-melt material at a bonding temperature equal to or higher than the above-mentioned melting temperature, thereby bonding the above-mentioned ceramics to each other. Components and the aforementioned metal components. In this way, by vacuum-impregnating the above-mentioned hot-melt material into the pores in the surface portion of the above-mentioned bonding region of the above-mentioned ceramic member, the hot-melt material and the pores can be well bonded. In this way, the above-mentioned light-emitting device related to the present invention can be manufactured.
这样,由于按照与本发明有关的发光器件的制造方法来制造上述与本发明有关的发光器件,故可抑制起因于伴随上述金属构件和上述陶瓷构件的温度上升的应力的翘曲、上述陶瓷构件的破损(裂纹)等的因上述金属构件与上述陶瓷构件的线膨胀系数的差异引起的温度变化时的问题的发生,因而,热传导率比较良好的金属材料作为上述金属构件的材料,可实现与现有的器件相比为高功率、高输出的器件特性,此外,由于将上述热熔材料浸渍于上述陶瓷构件的上述粘接区域的表面部分中的气孔中,故可将上述热熔材料结合到上述气孔中,由此,可提高该陶瓷构件与该热熔材料的粘接力。因而,即使粘接状态下的上述热熔材料的厚度比较薄,也可良好地保持粘接性,可提供相应地可提高上述热熔材料的热传导性的发光器件。In this way, since the above-mentioned light-emitting device according to the present invention is manufactured according to the method for manufacturing a light-emitting device according to the present invention, it is possible to suppress warping of the above-mentioned metal member and the stress caused by the temperature rise of the above-mentioned ceramic member, and the above-mentioned ceramic member. The occurrence of problems such as breakage (cracks) due to the temperature change caused by the difference in the linear expansion coefficient between the above-mentioned metal member and the above-mentioned ceramic member, therefore, a metal material with relatively good thermal conductivity can be used as the material of the above-mentioned metal member. Compared with existing devices, the device characteristics are high power and high output. In addition, since the above-mentioned hot-melt material is impregnated in the pores in the surface portion of the above-mentioned bonding region of the above-mentioned ceramic member, the above-mentioned hot-melt material can be combined. Into the above-mentioned pores, thereby, the adhesive force between the ceramic member and the hot-melt material can be improved. Therefore, even if the thickness of the hot-melt material in the bonded state is relatively thin, good adhesiveness can be maintained, and a light-emitting device in which the thermal conductivity of the hot-melt material can be improved correspondingly can be provided.
作为上述金属构件的材料,热传导率比较良好的金属材料,例如除了已叙述的Cu(铜)外,还可举出金(Au)、银(Ag)等。特别是,Cu在热传导性方面良好且比较廉价,由于与CuW、CuMo、CuMoCu等那样的复合材料相比,加工性良好,故可合适地使用。As the material of the metal member, a metal material having relatively good thermal conductivity includes, for example, gold (Au) and silver (Ag) in addition to the above-mentioned Cu (copper). In particular, Cu is good in thermal conductivity, is relatively inexpensive, and can be suitably used because it has good workability compared to composite materials such as CuW, CuMo, and CuMoCu.
作为上述陶瓷构件的材料,虽然不限定于此,但例如可举出氮化铝(AlN)、氧化铝(Al2O3)等。上述陶瓷构件也可由多个陶瓷构件来讲构成。此时,可用上述热熔材料互相粘接各陶瓷构件。作为上述陶瓷构件,从脆度、加工性等的观点来看,可例示整体地形成了表面部分包含气孔的陶瓷材料的材料。作为上述陶瓷构件中的气孔的气孔率,可例示约5%~20%。如果该气孔比约5%少,则难以进行热熔材料至该气孔的浸渍,如果比约20%多,则热传导率容易下降。作为上述陶瓷构件中的气孔的孔径,虽然不限定于此,但可例示约0.01mm~0.15mm。再有,在本发明的发光器件的制造方法的上述粘接剂涂敷浸渍工序中,由于上述树脂材料溶解于上述水或上述水溶性有机溶剂中,故也可均匀地浸渍于例如约0.01mm~0.15mm的微细的气孔中。The material of the ceramic member is not limited thereto, but examples thereof include aluminum nitride (AlN), aluminum oxide (Al 2 O 3 ), and the like. The above-mentioned ceramic member may also be composed of a plurality of ceramic members. At this time, the ceramic members can be bonded to each other with the above hot-melt material. As the above-mentioned ceramic member, from the viewpoint of brittleness, workability, etc., a material in which a ceramic material including pores in the surface portion is integrally formed can be exemplified. As the porosity of the pores in the ceramic member, about 5% to 20% can be exemplified. If the pores are less than about 5%, it becomes difficult to impregnate the pores with the hot-melt material, and if the pores are more than about 20%, the thermal conductivity tends to decrease. The diameter of the pores in the ceramic member is not limited thereto, but about 0.01 mm to 0.15 mm can be exemplified. Furthermore, in the above-mentioned adhesive coating and dipping step of the manufacturing method of the light-emitting device of the present invention, since the above-mentioned resin material is dissolved in the above-mentioned water or the above-mentioned water-soluble organic solvent, it can also be uniformly dipped in, for example, about 0.01 mm ~0.15mm fine pores.
这里所说的气孔率,是作为由JIS R1634(精细陶瓷的烧结体密度、开气孔率的测定方法、陶瓷的开气孔率的计算方法)规定的开气孔率由下述的计算式计算出的值,是基于阿基米德法那样的计算方法得出的:The porosity mentioned here is calculated from the following calculation formula as the open porosity stipulated in JIS R1634 (Measurement method of density and open porosity of fine ceramics, calculation method of open porosity of ceramics) The value is based on a calculation method like Archimedes' method:
Pb=((W3-W1)/(W3-W2))×100Pb=((W3-W1)/(W3-W2))×100
Pb:开气孔率(%)Pb: open porosity (%)
〔在此,W1:干燥质量(g)(用110±5℃的恒温器进行了干燥后,在干燥器中放置冷却并测定了质量的值)[Here, W1: dry mass (g) (after drying with a thermostat at 110±5°C, leave to cool in a desiccator and measure the mass)
W2:水中质量(g)(在用金属丝在水中悬垂了浸水样品的原有状态下测定质量并校正了夹具的质量的值)W2: Mass in water (g) (measured in the original state where the water-immersed sample is suspended in water with a wire and corrected for the mass of the jig)
W3:浸水质量(g)(从水中取出浸水样品,用湿的纱布除去了表面的水滴并测定了质量的值)。W3: water immersion mass (g) (a water immersion sample was taken out of water, water droplets on the surface were removed with wet gauze, and the mass was measured).
此外,气孔的孔径是利用在微细的气孔中压入水银、根据压入压力和被压入的水银的体积来计算气孔的容积的水银压入法计算的值,具体地说,使用水银孔度计(例如,岛津制作所制的自动孔径9200型等)计算气孔的孔径。In addition, the pore diameter of the pores is a value calculated by the mercury intrusion method in which mercury is injected into the fine pores, and the volume of the pores is calculated from the intrusion pressure and the volume of the mercury injected. Specifically, the mercury pore size is used. The pore diameter of the pores is calculated using a meter (for example, Auto Aperture Model 9200 manufactured by Shimadzu Corporation, etc.).
在与本发明有关的发光器件的制造方法中,作为在比上述规定的温度高的熔融温度下加热熔融的同时在固化粘接状态下显示出柔软性的上述树脂材料,虽然不限定于此,但例如可举出热可塑性弹性体和包含乙烯/醋酸乙烯酯和丙烯酸或甲基丙烯酸共聚物的树脂组合物。在与本发明有关的发光器件中,作为被构成为在比上述规定的温度高的熔融温度下加热熔融的同时在固化粘接状态下显示出柔软性的上述热熔材料,可例示弹性系数约为0.2×108Pa~13.0×108Pa的热熔材料,如果如后述那样从有助于弹性系数的材料选定的观点来看,则可例示更为理想的是约为0.25×108Pa~5.0×108Pa的热熔材料,最为理想的是约为1.9×108Pa~3.3×108Pa的热熔材料。这样的热熔材料与现有的焊接材料、例如In the method of manufacturing a light-emitting device related to the present invention, as the above-mentioned resin material that exhibits flexibility in a cured and bonded state while heating and melting at a melting temperature higher than the above-mentioned predetermined temperature, although not limited thereto, However, thermoplastic elastomers and resin compositions comprising ethylene/vinyl acetate and acrylic acid or methacrylic acid copolymers may be mentioned, for example. In the light-emitting device related to the present invention, as the above-mentioned hot-melt material that is configured to exhibit flexibility in a cured and bonded state while being heated and melted at a melting temperature higher than the above-mentioned predetermined temperature, an elastic modulus of about For the hot-melt material of 0.2×10 8 Pa to 13.0×10 8 Pa, from the point of view of material selection contributing to the elastic coefficient as described later, it can be exemplified that about 0.25×10 Pa is more desirable. 8 Pa to 5.0×10 8 Pa hot-melt material, the most ideal is about 1.9×10 8 Pa to 3.3×10 8 Pa hot-melt material. Such hot-melt materials are compatible with existing welding materials such as
弹性系数PaElastic coefficient Pa
Ag 827.7×108 Ag 827.7×10 8
Au 780.6×108 Au 780.6×10 8
Cu 1274.9×108 Cu 1274.9×10 8
Zn 760.0×108 Zn 760.0×10 8
Cd 489.4×108 Cd 489.4×10 8
相比,很明显在柔软性方面良好。In comparison, it is obvious that it is good in softness.
上述热可塑性弹性体例如是天然橡胶、合成橡胶等那样具有长的分子链以复杂的方式络合起来的分子结构的材料,具有作为伴随上述金属构件和上述陶瓷构件的温度上升的应力的缓和剂的作用。作为上述热可塑性弹性体,可例示苯乙烯弹性体、烯烃弹性体、聚酯弹性体、氯乙烯弹性体、聚酰胺弹性体等。其中,如果使用苯乙烯和烯烃热可塑性弹性体,则由于热熔材料的弹性系数大致可包含在上述的「作为更为理想的范围的0.25×108Pa~5.0×108Pa」中,故是较为理想的。The above-mentioned thermoplastic elastomer is, for example, a material having a molecular structure in which long molecular chains are complexly entangled, such as natural rubber and synthetic rubber, and has a stress relieving agent accompanying the temperature rise of the above-mentioned metal member and the above-mentioned ceramic member. role. As said thermoplastic elastomer, a styrene elastomer, an olefin elastomer, a polyester elastomer, a vinyl chloride elastomer, a polyamide elastomer, etc. are illustrated. Among them, if styrene and olefin thermoplastic elastomers are used, since the coefficient of elasticity of the hot-melt material can be roughly included in the above-mentioned "0.25×10 8 Pa to 5.0×10 8 Pa as a more ideal range", is more ideal.
上述乙烯/醋酸乙烯酯和丙烯酸或甲基丙烯酸的共聚物具有能提高上述金属构件和上述陶瓷构件的粘接强度的作用。The above-mentioned copolymer of ethylene/vinyl acetate and acrylic acid or methacrylic acid has an effect of improving the bonding strength between the above-mentioned metal member and the above-mentioned ceramic member.
上述树脂材料也可包含聚乙烯。作为该聚乙烯,可使用低密度、高密度聚乙烯,具有可提高上述热熔材料的润湿性的作用。从上述热熔材料的润湿性的方面来看,上述树脂材料以这种方式包含聚乙烯是较为理想的。The aforementioned resin material may also contain polyethylene. As the polyethylene, low-density polyethylene and high-density polyethylene can be used, which have the effect of improving the wettability of the above-mentioned hot-melt material. From the viewpoint of the wettability of the above-mentioned hot-melt material, it is desirable that the above-mentioned resin material contains polyethylene in this manner.
在上述树脂组合物包含热可塑性弹性体、乙烯/醋酸乙烯酯和丙烯酸或甲基丙烯酸的共聚物和聚乙烯中至少热可塑性弹性体、乙烯/醋酸乙烯酯和丙烯酸或甲基丙烯酸的共聚物的情况下,作为各成分的比例,例如,可举出In the above resin composition comprising a thermoplastic elastomer, a copolymer of ethylene/vinyl acetate and acrylic acid or methacrylic acid and polyethylene, at least a thermoplastic elastomer, a copolymer of ethylene/vinyl acetate and acrylic acid or methacrylic acid In this case, as the ratio of each component, for example,
热可塑性弹性体 :约20重量%~80重量%Thermoplastic elastomer: about 20% to 80% by weight
乙烯/醋酸乙烯酯Ethylene/vinyl acetate
和丙烯酸或甲基丙烯酸的共聚物:约10重量%~60重量%Copolymer with acrylic acid or methacrylic acid: about 10% by weight to 60% by weight
聚乙烯 :约0重量%~40重量%Polyethylene: about 0% by weight to 40% by weight
其中,通过适当地至少配制热可塑性弹性体的成分比例,可调整固化粘接状态下的上述热熔材料的弹性系数。例如,如果减少热可塑性弹性体,则弹性系数增加,如果增加热可塑性弹性体,则弹性系数减少。Wherein, the elastic coefficient of the above-mentioned hot-melt material in the cured and bonded state can be adjusted by appropriately formulating at least the composition ratio of the thermoplastic elastomer. For example, if the thermoplastic elastomer is decreased, the modulus of elasticity increases, and if the thermoplastic elastomer is increased, the modulus of elasticity decreases.
此外,在上述树脂材料中,可适当地配制在耐热性方面良好的热硬化性树脂、例如聚酰亚胺树脂、BT树脂、聚硅氧烷等热硬化性树脂。作为该热硬化性树脂的配制比例,例如可举出约0.01重量%~10重量%。将这样的热硬化性树脂浸渍于上述陶瓷构件的上述粘接区域的表面部分中的气孔内,具有例如即使成为约上述规定的温度也能维持上述金属构件和上述陶瓷构件的粘接强度的作用。In addition, among the aforementioned resin materials, thermosetting resins having good heat resistance, for example, thermosetting resins such as polyimide resins, BT resins, and polysiloxanes, can be appropriately formulated. As a compounding ratio of this thermosetting resin, about 0.01 weight% - 10 weight% is mentioned, for example. Impregnation of such a thermosetting resin into pores in the surface portion of the above-mentioned bonding region of the above-mentioned ceramic member has, for example, an effect of maintaining the bonding strength between the above-mentioned metal member and the above-mentioned ceramic member even at about the above-mentioned predetermined temperature. .
在将上述树脂材料溶解于上述水溶性有机溶剂中的情况下,作为该水溶性有机溶剂,虽然不限定于此,但例如可举出二甲基乙酮和二甲基甲酰胺的混合溶剂等。When the above-mentioned resin material is dissolved in the above-mentioned water-soluble organic solvent, the water-soluble organic solvent is not limited thereto, but examples thereof include a mixed solvent of dimethyl ethyl ketone and dimethylformamide, etc. .
在与本发明有关的发光器件的制造方法中,作为在上述陶瓷构件上涂敷的上述热熔材料的厚度,可例示约20μm~200μm。在与本发明有关的发光器件中,作为固化粘接状态的上述热熔材料的厚度,可例示约0.01mm~0.10mm。如果该厚度比约0.01mm小,则上述热熔材料的粘接性容易下降,如果比约0.10mm大,则上述热熔材料的热传导性容易下降。此外,在与本发明有关的发光器件的制造方法中,也可还包含使用上述粘接剂涂敷浸渍工序涂敷浸渍了上述热熔材料的上述陶瓷构件干燥的粘接剂干燥工序。In the method of manufacturing a light-emitting device according to the present invention, the thickness of the hot-melt material coated on the ceramic member is, for example, approximately 20 μm to 200 μm. In the light-emitting device according to the present invention, the thickness of the above-mentioned hot-melt material in a cured and adhered state can be, for example, about 0.01 mm to 0.10 mm. If the thickness is smaller than approximately 0.01 mm, the adhesiveness of the hot-melt material is likely to decrease, and if it is greater than approximately 0.10 mm, the thermal conductivity of the hot-melt material is likely to decrease. In addition, the method of manufacturing a light-emitting device according to the present invention may further include an adhesive drying step of applying and drying the ceramic member impregnated with the hot-melt material using the adhesive coating and dipping step.
与本发明有关的发光器件也可作为在上述金属构件或上述陶瓷构件上设置了发光元件的发光二极管而被构成。此外,与本发明有关的发光器件的制造方法也可还包含在上述金属构件或上述陶瓷构件上设置发光元件的工序,以制造作为发光二极管而被构成的发光器件。以这种方式作为发光二极管而被构成的发光器件,例如通过使用已叙述的Cu那样的热传导率比较良好的金属材料作为上述金属构件的材料,作为与现有的器件相比为高功率、高输出的发光二极管,可实现更高亮度的发光特性。The light-emitting device according to the present invention may also be configured as a light-emitting diode in which a light-emitting element is provided on the metal member or the ceramic member. In addition, the method of manufacturing a light-emitting device according to the present invention may further include a step of disposing a light-emitting element on the metal member or the ceramic member to manufacture a light-emitting device configured as a light-emitting diode. A light-emitting device configured as a light-emitting diode in this way, for example, uses a metal material with relatively good thermal conductivity such as Cu as the material of the above-mentioned metal member, and can be used as a high-power, high-power device compared with existing devices. The output light-emitting diode can realize higher brightness light-emitting characteristics.
此外,与本发明有关的发光器件(例如,作为发光二极管而被构成的发光器件)也可还具备透光性构件(例如由玻璃构成的光学构件、更具体地说,玻璃透镜),用上述热熔材料相互粘接上述陶瓷构件与上述透光性构件(例如,上述光学构件)。此时,上述热熔材料包含粘接了上述金属构件与上述陶瓷构件的第1热熔材料和粘接了上述透光性构件(例如,上述光学构件)与上述陶瓷构件的第2热熔材料,例如考虑在粘接上述金属构件与上述陶瓷构件并设置了半导体元件(例如,发光元件)之后粘接上述透光性构件(例如,上述光学构件)与上述陶瓷构件的情况,最好将上述第1热熔材料的熔融温度a与上述第2热熔材料的熔融温度b的关系定为a>b。通过这样做,即使在利用上述第1热熔材料粘接了上述金属构件与上述陶瓷构件之后利用上述第2热熔材料粘接了上述透光性构件(例如,上述光学构件)与上述陶瓷构件,在由上述第2热熔材料进行的上述透光性构件(例如,上述光学构件)与上述陶瓷构件的粘接时,也能防止粘接了上述金属构件与上述陶瓷构件的上述第1热熔材料的熔融。In addition, the light-emitting device related to the present invention (for example, a light-emitting device configured as a light-emitting diode) may further include a light-transmitting member (for example, an optical member made of glass, more specifically, a glass lens). The hot-melt material bonds the above-mentioned ceramic member and the above-mentioned translucent member (for example, the above-mentioned optical member) to each other. In this case, the hot-melt material includes a first hot-melt material bonded to the metal member and the ceramic member, and a second hot-melt material bonded to the translucent member (for example, the optical member) and the ceramic member. For example, considering the case of bonding the above-mentioned light-transmitting member (for example, the above-mentioned optical member) and the above-mentioned ceramic member after bonding the above-mentioned metal member and the above-mentioned ceramic member and setting a semiconductor element (for example, a light-emitting element), it is preferable to combine the above-mentioned The relationship between the melting temperature a of the first hot-melt material and the melting temperature b of the second hot-melt material is a>b. By doing so, even if the above-mentioned translucent member (for example, the above-mentioned optical member) and the above-mentioned ceramic member are bonded by the above-mentioned second hot-melt material after the above-mentioned metal member and the above-mentioned ceramic member are bonded by the above-mentioned first hot-melt material, When the above-mentioned translucent member (for example, the above-mentioned optical member) and the above-mentioned ceramic member are bonded by the above-mentioned second hot-melt material, the above-mentioned first heat that has bonded the above-mentioned metal member and the above-mentioned ceramic member can also be prevented. melting of molten material.
在与本发明有关的发光器件的制造方法中,发光器件(例如,作为发光二极管而被构成的发光器件)也可还具备透光性构件(例如由玻璃构成的光学构件、更具体地说,玻璃透镜),可还包含在用上述粘接剂涂敷浸渍工序涂敷浸渍了上述热熔材料的上述陶瓷构件与上述透光性构件(例如,上述光学构件)之间在上述熔融温度以上的粘接温度下使上述热熔材料熔接从而相互粘接上述陶瓷构件与上述透光性构件(例如,上述光学构件)的陶瓷-透光性构件粘接工序。In the method for manufacturing a light-emitting device related to the present invention, the light-emitting device (for example, a light-emitting device configured as a light-emitting diode) may further include a light-transmitting member (for example, an optical member made of glass, more specifically, glass lens) may further include the above-mentioned melting temperature between the above-mentioned ceramic member coated and impregnated with the above-mentioned hot-melt material in the above-mentioned adhesive agent coating and dipping step and the above-mentioned light-transmitting member (for example, the above-mentioned optical member). A ceramic-translucent member bonding step of bonding the ceramic member and the translucent member (for example, the optical member) to each other by fusing the hot-melt material at a bonding temperature.
此时,例如考虑在粘接上述金属构件与上述陶瓷构件并设置了半导体元件(例如,发光元件)之后粘接上述透光性构件(例如,上述光学构件)与上述陶瓷构件的情况,在上述粘接剂作成工序中,使溶解于水或水溶性有机溶剂中并在比上述规定的温度高的第1和第2熔融温度a、b(a>b)下加热熔融的同时在固化粘接状态下显示出柔软性的第1和第2树脂材料溶解于上述水或上述水溶性有机溶剂中以分别作成第1和第2热熔材料作为上述粘接剂,在上述粘接剂涂敷浸渍工序中,采用上述粘接区域的表面部分包含第1和第2粘接区域的表面部分的陶瓷构件作为上述陶瓷构件、在上述陶瓷构件的上述第1和第2粘接区域的表面部分上分别涂敷用上述粘接剂作成工序作成的上述第1和第2热熔材料、同时在规定的真空状态下使该第1和第2热熔材料分别浸渍于上述陶瓷构件的上述第1和第2粘接区域的表面部分中的气孔中,在上述陶瓷-金属粘接工序中,在用上述粘接剂涂敷浸渍工序涂敷浸渍了上述第1热熔材料的上述陶瓷构件与上述金属构件之间在上述第1熔融温度a以上的第1粘接温度下熔接该第1热熔材料从而相互粘接上述陶瓷构件与上述金属构件,在上述陶瓷-透光性构件粘接工序中,在用上述陶瓷-金属粘接工序粘接了上述陶瓷构件与上述金属构件之后,在用上述粘接剂涂敷浸渍工序涂敷浸渍了上述第2热熔材料的上述陶瓷构件与上述透光性构件(例如,上述光学构件)之间在上述第2熔融温度b以上而不到上述第1熔融温度a的第2粘接温度下熔接该第2热熔材料从而相互粘接上述陶瓷构件与上述透光性构件(例如,上述光学构件)。通过这样做,即使在利用上述第1热熔材料粘接了上述金属构件与上述陶瓷构件之后利用上述第2热熔材料粘接了粘接上述透光性构件(例如,上述光学构件)与上述陶瓷构件,在由上述第2热熔材料进行的上述透光性构件(例如,上述光学构件)与上述陶瓷构件的粘接时,也能防止粘接了上述金属构件与上述陶瓷构件的上述第1热熔材料的熔融。At this time, for example, after bonding the metal member and the ceramic member and installing a semiconductor element (for example, a light-emitting element), the case where the light-transmitting member (for example, the optical member) and the ceramic member are bonded together is considered. In the adhesive preparation process, dissolve in water or a water-soluble organic solvent and heat and melt at the first and second melting temperatures a and b (a>b) higher than the above-mentioned predetermined temperature while curing and bonding The first and second resin materials showing flexibility in the state are dissolved in the above-mentioned water or the above-mentioned water-soluble organic solvent to make the first and second hot-melt materials respectively as the above-mentioned adhesive agent, and the above-mentioned adhesive agent is coated and impregnated In the process, a ceramic member whose surface portion of the bonding region includes the surface portions of the first and second bonding regions is used as the ceramic member, and the surface portions of the first and second bonding regions of the ceramic member are respectively Coating the above-mentioned first and second hot-melt materials prepared in the above-mentioned adhesive agent preparation step, and simultaneously impregnating the first and second hot-melt materials in the first and second hot-melt materials of the above-mentioned ceramic member respectively under a predetermined vacuum state. 2 In the pores in the surface portion of the bonded region, in the above-mentioned ceramic-metal bonding step, the above-mentioned ceramic member impregnated with the above-mentioned first hot-melt material and the above-mentioned metal member are coated in the above-mentioned adhesive agent coating and dipping step The first hot-melt material is welded at a first bonding temperature above the first melting temperature a to bond the ceramic member and the metal member to each other, and in the ceramic-translucent member bonding step, After the above-mentioned ceramic member and the above-mentioned metal member are bonded by the above-mentioned ceramic-metal bonding process, the above-mentioned ceramic member impregnated with the above-mentioned second hot-melt material and the above-mentioned light-transmitting member are coated in the above-mentioned adhesive coating and dipping process. (For example, the above-mentioned optical members) are fused with the second hot-melt material at a second bonding temperature above the above-mentioned second melting temperature b but below the above-mentioned first melting temperature a to bond the above-mentioned ceramic member and the above-mentioned transparent material to each other. An optical member (for example, the above-mentioned optical member). By doing so, even if the above-mentioned light-transmitting member (for example, the above-mentioned optical member) and the above-mentioned The ceramic member can also prevent the above-mentioned second metal member and the ceramic member from being bonded together when the above-mentioned translucent member (for example, the above-mentioned optical member) and the above-mentioned ceramic member are bonded by the above-mentioned second hot-melt material. 1 Melting of hot melt materials.
作为上述规定的温度,希望在发光器件中设置的半导体元件(例如,发光器件作为发光二极管而被构成的情况,发光元件)的工作保证温度以下,例如,可举出约100℃~150℃。此时,可将上述熔融温度定为比约100℃~150℃高的温度。此外,作为上述熔融温度以上的上述粘接温度,例如,可例示约180℃~300℃。如果上述粘接温度超过约300℃,则存在导致构成上述热熔材料的树脂的特性恶化的可能性。再有,在用现有的焊接材料的粘接中,一般来说,在约500℃~800℃的加热状态下进行了粘接。关于这一点,由于在本发明中可用比以往的约500℃~800℃的温度充分低的温度(例如,180℃~300℃)来粘接,故可提高发光器件的生产效率,相应地可将制造成本抑制得较低。As the above-mentioned predetermined temperature, it is desirable that the semiconductor element provided in the light-emitting device (for example, when the light-emitting device is constituted as a light-emitting diode, the light-emitting element) be lower than the guaranteed operation temperature, for example, about 100°C to 150°C. In this case, the above-mentioned melting temperature may be set to be higher than about 100°C to 150°C. Moreover, as the said bonding temperature more than the said melting temperature, about 180 degreeC - 300 degreeC can be illustrated, for example. If the above-mentioned bonding temperature exceeds about 300° C., there is a possibility that the properties of the resin constituting the above-mentioned hot-melt material will be deteriorated. In addition, in the bonding using conventional soldering materials, bonding is generally carried out in a heated state of about 500°C to 800°C. In this regard, since the present invention can be bonded at a sufficiently lower temperature (for example, 180°C to 300°C) than the conventional temperature of about 500°C to 800°C, the production efficiency of light emitting devices can be improved, and accordingly Manufacturing costs are kept low.
在与本发明有关的发光器件的制造方法中,在上述陶瓷-金属粘接工序中,可在上述陶瓷构件与上述金属构件之间在上述粘接温度下且在规定的压力下使上述热熔材料熔接从而相互粘接上述陶瓷构件与上述金属构件,在上述陶瓷构件的上述粘接区域表面部分包含上述第1粘接区域表面部分的情况下,在上述陶瓷-金属粘接工序中,可在上述陶瓷构件与上述金属构件之间在上述第1粘接温度下且在规定的压力下使该第1热熔材料熔接从而相互粘接上述陶瓷构件与上述金属构件。In the method of manufacturing a light-emitting device according to the present invention, in the above-mentioned ceramic-metal bonding step, the above-mentioned thermal fusion may be performed between the above-mentioned ceramic member and the above-mentioned metal member at the above-mentioned bonding temperature and under a predetermined pressure. Materials are welded to bond the above-mentioned ceramic member and the above-mentioned metal member to each other. In the case where the surface portion of the above-mentioned bonding region of the above-mentioned ceramic member includes the surface portion of the first bonding region, in the above-mentioned ceramic-metal bonding step, The ceramic member and the metal member are bonded to each other by fusing the first hot-melt material at the first bonding temperature and a predetermined pressure between the ceramic member and the metal member.
此外,在上述陶瓷-透光性构件粘接工序中,可在上述陶瓷构件与上述透光性构件(例如,上述光学构件)之间在上述粘接温度下且在规定的压力下使上述热熔材料熔接从而相互粘接上述陶瓷构件与上述透光性构件(例如,上述光学构件),在上述陶瓷构件的上述粘接区域表面部分包含上述第2粘接区域表面部分的情况下,在上述陶瓷-透光性构件粘接工序中,可在上述陶瓷-金属粘接工序中粘接了上述陶瓷构件与上述金属构件后,在用上述粘接剂涂敷浸渍工序涂敷浸渍了上述第2热熔材料的上述陶瓷构件与上述透光性构件(例如,上述光学构件)之间在上述第2粘接温度下且在规定的压力下使该第2热熔材料熔接从而相互粘接上述陶瓷构件与上述透光性构件(例如,上述光学构件)。In addition, in the ceramic-translucent member bonding step, the heat may be applied between the ceramic member and the translucent member (for example, the optical member) at the bonding temperature and under a predetermined pressure. The melting material is fused to bond the above-mentioned ceramic member and the above-mentioned light-transmitting member (for example, the above-mentioned optical member) to each other. In the ceramic-light-transmitting member bonding step, after the above-mentioned ceramic member and the above-mentioned metal member are bonded in the above-mentioned ceramic-metal bonding step, the above-mentioned second adhesive is applied and impregnated in the above-mentioned adhesive coating and dipping step. The ceramic member of the hot-melt material and the above-mentioned light-transmitting member (for example, the optical member) are welded at the second bonding temperature and under a predetermined pressure by the second hot-melt material to bond the ceramics to each other. A member and the above-mentioned translucent member (for example, the above-mentioned optical member).
作为上述规定的压力,虽然不限定于此,但可例示约9.8×104Pa~294.2×104Pa(1kg/cm2~30kg/cm2)。The predetermined pressure is not limited thereto, but about 9.8×10 4 Pa to 294.2×10 4 Pa (1 kg/cm 2 to 30 kg/cm 2 ) can be exemplified.
在此,如果观察使用一般大多使用的2液式或热硬化性等的粘接剂作为粘接剂以真空方式浸渍于陶瓷材料气孔的情况,则由于该粘接剂的硬化在真空浸渍中开始,故必须在经该粘接剂将粘接物涂在陶瓷材料上的状态下进行真空浸渍,在以这种方式将粘接物涂在陶瓷材料上的状态下,发生空气从陶瓷材料的气孔脱离时的粘接剂层的不匀等,不能很好地进行真空浸渍,容易导致粘接性的下降。Here, if you look at the situation where a generally used two-component type or thermosetting adhesive is used as an adhesive to impregnate the pores of the ceramic material in a vacuum manner, the hardening of the adhesive begins during the vacuum impregnation. , so the vacuum impregnation must be carried out in the state where the adhesive is applied to the ceramic material through the adhesive. In the state where the adhesive is applied to the ceramic material in this way, air from the pores of the ceramic material The unevenness of the adhesive layer at the time of detachment, etc., cannot perform vacuum impregnation well, and it is likely to cause a decrease in adhesiveness.
关于这一点,在与本发明有关的发光器件的制造方法中,在以真空方式将上述热熔材料浸渍于上述陶瓷构件中后进而在包含上述粘接剂干燥工序的情况下,在对上述陶瓷构件进行了真空浸渍后干燥后,在设置上述金属构件(进而是上述透光性构件(例如,上述光学构件))的情况下,设置该透光性构件(例如,该光学构件),通过加热到上述粘接温度,在设置上述陶瓷构件和上述金属构件(进而是上述透光性构件(例如,上述光学构件))的情况下,可与该透光性构件(例如,该光学构件)进行粘接。In this regard, in the method of manufacturing a light-emitting device according to the present invention, after the above-mentioned hot-melt material is impregnated in the above-mentioned ceramic member in a vacuum system, when the above-mentioned adhesive agent drying step is included, the above-mentioned ceramic After vacuum impregnating and drying the member, in the case where the above-mentioned metal member (and further the above-mentioned light-transmitting member (for example, the above-mentioned optical member)) is provided, the light-transmitting member (for example, the above-mentioned optical member) is provided, and by heating To the above-mentioned bonding temperature, when the above-mentioned ceramic member and the above-mentioned metal member (and further the above-mentioned light-transmitting member (for example, the above-mentioned optical member)) are provided, it can be carried out with the light-transmitting member (for example, the optical member). bonding.
在与本发明有关的发光器件中,例如在作为设置了发光元件的发光二极管而被构成的情况下,为了实现上述第2目的,最好将上述发光元件设置成从上述金属构件或上述陶瓷构件的边缘部顶部起凸出0.5mm~2mm。通过这样做,容易对外部发出从上述发光元件侧方射出的光,相应地可高效地利用光。此外,例如在将上述发光二极管利用于照明等的情况下,即使用透镜等对来自上述发光元件的光进行聚光,也能充分地抑制从上述发光元件侧方被上述陶瓷构件反射的反射光,相应地可减少聚光不匀的发生。因而,能高效地且以聚光不匀少的方式有效地利用从发光元件侧方射出的光。In the light-emitting device according to the present invention, for example, when it is configured as a light-emitting diode provided with a light-emitting element, in order to achieve the second object above, it is preferable that the light-emitting element is provided from the metal member or the ceramic member 0.5mm to 2mm protrude from the top of the edge of the By doing so, the light emitted from the side of the light-emitting element can be easily emitted to the outside, and accordingly, the light can be efficiently used. In addition, for example, when the above-mentioned light-emitting diode is used for lighting or the like, even if the light from the above-mentioned light-emitting element is condensed by a lens or the like, the reflected light reflected by the above-mentioned ceramic member from the side of the above-mentioned light-emitting element can be sufficiently suppressed. , and accordingly the occurrence of uneven light concentration can be reduced. Therefore, it is possible to effectively use the light emitted from the side of the light emitting element efficiently and with little unevenness in light concentration.
也可经配置该发光元件的元件配置构件在上述金属构件或上述陶瓷构件上设置上述发光元件。作为该元件配置构件,代表性地称为子固定件。可例示包含形成了电路图形的小型电路的子固定件。该子固定件例如可用氮化铝(AlN)、氧化铝(Al2O3)等热传导性比较高的陶瓷材料构成。在用陶瓷材料构成上述子固定件的情况下,可将该子固定件作为上述陶瓷构件的一部分来构成。The above-mentioned light-emitting element may be provided on the above-mentioned metal member or the above-mentioned ceramic member via an element arrangement member for arranging the light-emitting element. This component arrangement member is typically referred to as a submount. A submount including a small circuit formed with a circuit pattern can be exemplified. The sub-fixer can be made of ceramic materials with relatively high thermal conductivity, such as aluminum nitride (AlN), aluminum oxide (Al 2 O 3 ), and the like. In the case where the submount is made of a ceramic material, the submount can be configured as a part of the ceramic member.
在单单经上述元件配置构件在上述金属构件或上述陶瓷构件上设置上述发光元件的情况下,导致热传导性的下降,于是对来自上述发光元件的热进行散热的散热性容易下降。由此,最好增加上述元件配置构件的与上述金属构件或上述陶瓷构件的相互接触面积。另一方面,在上述元件配置构件中,最好使从所配置的上述发光元件的侧方射出到该元件配置构件侧的光不被该元件配置构件遮蔽。如果考虑这些情况,则最好将上述元件配置构件形成为随着朝向上述发光元件的配置侧呈端部细的截锥形。作为此时的上述元件配置构件的形状,可例示侧面视图(从侧面看)为梯形的立方体形状或在这样的梯形的立方体形状中斜面部分被形成为阶梯状的形状。再有,上述元件配置构件的倾斜角度例如最好约为10°~30°。这里所说倾斜角度,指的是沿上述元件配置构件的顶面的各边相对于该顶面为垂直地延伸的面与斜面构成的角度。When the light-emitting element is provided on the metal member or the ceramic member through the element arrangement member alone, thermal conductivity decreases, and heat dissipation of heat from the light-emitting element tends to decrease. Therefore, it is preferable to increase the mutual contact area of the element arrangement member and the metal member or the ceramic member. On the other hand, in the element placement member, it is preferable that the light emitted from the side of the placed light emitting element to the side of the element placement member is not blocked by the element placement member. Taking these circumstances into consideration, it is preferable to form the element arrangement member into a truncated cone shape with tapered ends toward the side where the light emitting elements are arranged. As the shape of the element arrangement member at this time, a trapezoidal cubic shape in a side view (viewed from the side) or a shape in which slopes are formed in steps in such a trapezoidal cubic shape can be exemplified. In addition, the inclination angle of the above-mentioned element arrangement member is preferably about 10° to 30°, for example. The angle of inclination referred to here refers to an angle formed by a surface extending perpendicularly to the top surface along each side of the top surface of the element arrangement member and the slope.
此外,在上述元件配置构件中,为了使来自所配置的上述发光元件的侧方的光不被该元件配置构件遮蔽,最好使配置上述发光元件的面尽可能与上述发光元件的尺寸近似。例如,可举出上述元件配置构件具有在配置了上述发光元件时从该发光元件的边缘部起沿周边方向宽0.1mm~0.5mm的面并在该面上配置了上述发光元件的情况。通过这样做,可利用来自上述发光元件侧方的光(例如,从上述发光元件侧方在约5°的范围内射出到上述元件配置构件侧的光)。In addition, in the element arrangement member, it is preferable that the surface on which the light emitting elements are arranged be as close as possible to the size of the light emitting elements so that the light from the side of the arranged light emitting elements is not blocked by the element arrangement member. For example, the element arrangement member has a surface that is 0.1 mm to 0.5 mm wider in the peripheral direction from the edge of the light emitting element when the light emitting element is arranged, and the light emitting element is arranged on this surface. By doing so, light from the side of the light-emitting element (for example, light emitted from the side of the light-emitting element within a range of about 5° to the side of the element arrangement member) can be utilized.
如上所述,按照以下述方式构成发光器件:在上述元件配置构件被形成为随着朝向上述发光元件的配置侧呈端部细的截锥形的同时,上述元件配置构件具有在配置了上述发光元件时从该发光元件的边缘部起沿周边方向宽0.1mm~0.5mm的面并在该面上配置了上述发光元件,既可抑制来自上述发光元件的侧方的光的射出效率的下降,又可提高对来自上述发光元件的热进行散热的散热性。As described above, the light-emitting device is configured in such a manner that, while the element arrangement member is formed in a truncated cone shape with a tapered end portion toward the side where the light-emitting element is arranged, the element arrangement member has In the case of an element, a surface with a width of 0.1 mm to 0.5 mm in the peripheral direction from the edge of the light-emitting element and the above-mentioned light-emitting element are arranged on this surface can suppress the decline in the emission efficiency of light from the side of the above-mentioned light-emitting element, In addition, the heat dissipation performance for dissipating heat from the light emitting element can be improved.
作为上述发光元件,可例示具有面积约为1mm2~9mm2的正方形或长方形的发光面的立方体形状的发光元件。作为上述发光元件的大小,具体地说,如果将一对边的长度定为c’,另一对边的长度定为d’,则虽然不限于此,但可例示在c’=1mm时,d’=1mm~9mm,在c’=2mm时,d’=1mm~4mm,在c’=3mm时,d’=1mm~3mm等。Examples of the above-mentioned light-emitting element include a cube-shaped light-emitting element having a square or rectangular light-emitting surface with an area of about 1 mm 2 to 9 mm 2 . As the size of the above-mentioned light-emitting element, specifically, if the length of one pair of sides is defined as c' and the length of the other pair of sides is defined as d', although not limited thereto, it can be exemplified when c'=1 mm, d'=1mm-9mm, when c'=2mm, d'=1mm-4mm, when c'=3mm, d'=1mm-3mm, etc.
但是,使来自上述发光元件和上述元件配置构件的热经上述金属构件或上述陶瓷构件向外部散热的散热性相对于设置上述发光元件的上述金属构件或上述陶瓷构件的面的大小显示出饱和性。换言之,即使将上述金属构件或上述陶瓷构件的面的面积增加得很多,也只是增加封装尺寸难以有助于散热性的改善。因此,希望规定必要的最小限度的封装尺寸。However, the heat radiation from the light-emitting element and the element arrangement member to the outside through the metal member or the ceramic member exhibits saturation with respect to the size of the surface of the metal member or the ceramic member on which the light-emitting element is installed. . In other words, even if the surface area of the above-mentioned metal member or the above-mentioned ceramic member is greatly increased, it is difficult to improve the heat dissipation only by increasing the package size. Therefore, it is desirable to specify the necessary minimum package size.
例如,在与本发明有关的发光器件如已叙述的那样作为使用Cu那样的热传导率比较高的金属材料作为上述金属构件的材料的能进行高功率、高输出的发光二极管而被构成的情况且在采用具有面积约为1mm2~9mm2的正方形或长方形的发光面的立方体形状的发光元件作为上述发光元件的情况下,可例示上述金属构件或上述陶瓷构件具有面积为81mm2~144mm2且包含上述发光元件的上述发光面的形状那样的正方形或长方形的面,在该面上设置了上述发光元件的情况。按照以这种方式被构成的发光器件,既可维持使来自上述发光元件和上述元件配置构件的热经上述金属构件或上述陶瓷构件向外部散热的散热性,又可实现必要的最小限度的封装尺寸。作为上述金属构件或上述陶瓷构件的大小,具体地说,如果将一对边的长度定为c,另一对边的长度定为d,则虽然不限于此,但可例示在c=9mm~12mm时,d=9mm~12mm等。For example, when the light-emitting device related to the present invention is configured as a high-power, high-output light-emitting diode that uses a metal material with relatively high thermal conductivity such as Cu as the material of the above-mentioned metal member as described above and In the case of using a cube-shaped light-emitting element having a square or rectangular light-emitting surface with an area of about 1 mm 2 to 9 mm 2 as the above-mentioned light-emitting element, the above-mentioned metal member or the above-mentioned ceramic member has an area of 81 mm 2 to 144 mm 2 and A case where the light emitting element is provided on a square or rectangular surface including the shape of the light emitting surface of the light emitting element. According to the light emitting device constructed in this way, while maintaining the heat dissipation performance of dissipating heat from the light emitting element and the element placement member to the outside through the metal member or the ceramic member, the minimum required packaging can be realized. size. As the size of the above-mentioned metal member or the above-mentioned ceramic member, specifically, if the length of one pair of sides is defined as c, and the length of the other pair of sides is defined as d, then although it is not limited thereto, it can be exemplified in the range of c=9 mm to When 12mm, d = 9mm ~ 12mm and so on.
此外,为了实现上述第3目的,与本发明有关的照明装置具备上述本发明的发光器件或本发明的制造方法制造的发光器件和对该发光器件供电的至少正负一对端子,其特征在于:上述端子具有从侧方支撑上述发光器件的第一端子和/或从一个主面侧支撑上述发光器件的第二端子,上述第一端子和第二端子中的至少一方夹住上述发光器件。In addition, in order to achieve the third object above, the lighting device related to the present invention includes the above-mentioned light-emitting device of the present invention or the light-emitting device manufactured by the manufacturing method of the present invention and at least a pair of positive and negative terminals for supplying power to the light-emitting device, and is characterized in that The terminal has a first terminal for supporting the light emitting device from the side and/or a second terminal for supporting the light emitting device from one main surface side, and at least one of the first terminal and the second terminal sandwiches the light emitting device.
如果这样来构成,则由于端子与发光器件的主面侧和/或侧方端面接触,可牢固地支撑发光器件,故既可对发光器件进行供电,又可防止发光器件的转动。再者,由于与以往比较增加了发光器件与端子的接触面积,故可通过照明装置的散热性。此外,利用弹簧片夹住发光器件的主面或侧面,提高适当地调整弹簧片的弹性,发光器件的装卸变得容易。因而,可容易地进行照明装置中的发光器件的部分的修复。According to this configuration, since the terminals contact the main surface and/or side end surfaces of the light emitting device, the light emitting device can be firmly supported, so that the light emitting device can be supplied with power and the rotation of the light emitting device can be prevented. Furthermore, since the contact area between the light-emitting device and the terminal is increased compared with conventional ones, the heat dissipation of the lighting device can be passed. In addition, the main surface or the side surface of the light-emitting device is clamped by the spring piece, and the elasticity of the spring piece is properly adjusted, so that the light-emitting device can be easily attached and detached. Thus, partial repair of the light emitting device in the lighting device can be easily performed.
此外,从另一个主面侧利用热传递单元支撑上述发光器件。如果这样来构成,则由于进一步提高了发光器件的散热性,可作成高亮度的照明装置。In addition, the above-mentioned light emitting device is supported by the heat transfer unit from the other main surface side. According to this structure, since the heat dissipation of the light-emitting device is further improved, a high-brightness lighting device can be produced.
此外,上述发光器件的发光观察面侧与反射面对置。如果这样来构成,则可作成能在所希望的方向上照射来自发光器件的光的照明装置。In addition, the light-emitting observation surface side of the above-mentioned light-emitting device is opposite to the reflective surface. With such a configuration, a lighting device capable of irradiating light from the light emitting device in a desired direction can be produced.
此外,上述反射面由金属材料构成。如果这样来构成,则可进一步提高反射面中的反射率。In addition, the reflective surface is made of a metal material. According to such a configuration, the reflectance on the reflective surface can be further increased.
此外,上述反射面对由上述热传递单元传递的热进行散热。如果这样来构成,则可进一步提高照明装置的散热性。In addition, the reflective surface dissipates heat transferred by the heat transfer unit. According to such a configuration, the heat radiation performance of the lighting device can be further improved.
本发明的新的特征不外乎后附的技术方案的范围中特别记载的内容,但关于结构和内容这两者,通过与其它的目的或特征结合在一起并与附图一起阅读以下的详细的说明,可更好地理解本发明并对本发明作出评价。The new features of the present invention are nothing more than the content specifically described in the scope of the attached technical solutions, but regarding both the structure and the content, read the following detailed description together with other purposes or features together with the accompanying drawings. The description of the present invention can better understand and evaluate the present invention.
附图说明 Description of drawings
图1是作为与本发明有关的发光器件的一例的发光二极管的概略分解侧面图。FIG. 1 is a schematic exploded side view of a light emitting diode as an example of a light emitting device according to the present invention.
图2是图1中示出的发光二极管的概略分解斜视图。Fig. 2 is a schematic exploded perspective view of the light emitting diode shown in Fig. 1 .
图3是图1和图2中示出的发光二极管的概略剖面图。Fig. 3 is a schematic cross-sectional view of the light emitting diode shown in Figs. 1 and 2 .
图4(A)是说明子固定件的倾斜角度用的图,图4(B)是说明在实施例2中使用的发光元件用的图。FIG. 4(A) is a diagram for explaining an inclination angle of a submount, and FIG. 4(B) is a diagram for describing a light emitting element used in Example 2. FIG.
图5是示出子固定件的倾斜角度与温度上升值和Cu构件与子固定件的接触面积的特性的曲线图。5 is a graph showing the characteristics of the inclination angle of the submount versus the temperature rise value and the contact area of the Cu member and the submount.
图6是示出封装面积-温度特性的曲线图。FIG. 6 is a graph showing package area-temperature characteristics.
图7是与本发明的实施例1有关的照明装置中使用的发光器件100的示意性的斜视图。Fig. 7 is a schematic perspective view of the
图8是与该实施例有关的照明装置的端子20a、20b的示意性的斜视图。Fig. 8 is a schematic perspective view of the
图9是示出将发光器件100安装在与该实施例有关的照明装置的端子20a、20b上的状态的示意性的斜视图。Fig. 9 is a schematic oblique view showing a state where the
图10是从正面方向看与本发明的实施例2有关的照明装置40的示意性的斜视图。FIG. 10 is a schematic perspective view of the
图11是从背面方向看与该实施例有关的照明装置40的示意性的斜视图。FIG. 11 is a schematic perspective view of the
图12是与本发明的实施例3有关的照明装置60的示意性的斜视图。Fig. 12 is a schematic perspective view of a
图13是与本发明的另一实施例3有关的照明装置70的示意性的斜视图。FIG. 13 is a schematic perspective view of an illuminating
图14是与本发明的各实施例有关的照明装置中使用的发光器件100A的示意性的斜视图。Fig. 14 is a schematic oblique view of a
图15是使用了图14中示出的发光器件100A的照明装置80的示意性的斜视图。FIG. 15 is a schematic oblique view of a
附图的一部分或全部是根据以图示为目的的概要的表现来描绘的,不一定限于忠实地描写在该处示出的要素的实际的相对的大小或位置。Part or all of the drawings are drawn based on schematic representations for illustration purposes, and are not necessarily limited to faithfully depicting actual relative sizes or positions of elements shown therein.
具体实施方式 Detailed ways
以下,一边参照附图,一边说明与本发明有关的实施例。Hereinafter, embodiments related to the present invention will be described with reference to the drawings.
图1是作为与本发明有关的发光器件的一例的发光二极管10的概略分解侧面图,图2是图1中示出的发光二极管10的概略分解斜视图。此外,图3是图1和图2中示出的发光二极管10的概略剖面图。FIG. 1 is a schematic exploded side view of a
发光二极管(以下,也称为LED)10,如图1至图3中所示,具备封装用陶瓷构件1、发光元件2、透光性构件4、散热用金属构件5和热熔材料6。A light emitting diode (hereinafter, also referred to as LED) 10 includes, as shown in FIGS.
陶瓷构件1由相互重叠了分别由陶瓷(在本例中是AlN、Al2O3等)构成的第1和第2板状构件1a、1b的构件和子固定件(元件配置构件的一例)1c构成。第1板状构件1a是规定尺寸(在本例中,一个边(图2中e=)约9mm~12mm、另一个边(图2中f=)约9mm~12mm)的正方形或长方形的板状构件,具有比子固定件1c的底面1c”的尺寸大一些的矩形的第1开口部1a’,第2板状构件1b的相对的二边的尺寸与第1板状构件1a的对应的二边的尺寸相同,剩下的二边的尺寸比第1板状构件1a的对应的二边的尺寸小,具有比第1板状构件1a的第1开口部1a’的尺寸大的第2开口部1b’。再有,在本例中,第1和第2板状构件1a、1b的材质相同。The ceramic member 1 is composed of first and second plate-
在本例中,子固定件1c是包含被称为安装发光元件2的子固定件的形成了电路图形等的小型电路的固定件,用AlN、Al2O3等热传导性比较高的陶瓷材料来构成。将该子固定件1c形成为随着朝向发光元件2的安装侧呈端部细的截锥形,具体地说,是图1至图3中图示那样的侧面视图(从侧面看)为梯形的立方体形状或在这样的梯形的立方体形状中斜面部分被形成为阶梯状的形状。在本例中,子固定件1c的陶瓷材料和上述第1和第2板状构件1a、1b都是包含表面部分的陶瓷材料整体上形成了气孔h的多孔性的材料,气孔h的气孔率和孔径在本例中分别约为5%~20%和0.01mm~0.15mm。为了在该范围内最大程度地提高热传导率,最好使气孔率为5%。In this example, the
此外,如图3中所示,在本例中,子固定件1c具有在安装了发光元件2时从发光面2a的边缘部起沿周边方向宽了(图中距离i=)约0.1mm~0.5mm的面1c’,以免用子固定件1c遮蔽来自所安装的发光元件2的侧方的光L2,在该面1c’上安装了发光元件2。而且,贯通第1板状构件1a的第1开口部1a’在金属构件5上设置了子固定件1c。In addition, as shown in FIG. 3 , in this example, the
发光元件2在本例中是具有面积(图2中长度c’×d’)约为1mm2~9mm2(例如,在c’=2mm时,d’=1mm~4mm)的正方形或长方形的发光面2a的立方体形状的发光元件,如图3中所示,经所安装的子固定件1c在金属构件5上从陶瓷构件1的边缘部顶部A(换言之,是第2板状构件1b的顶部)起以凸出(图中距离g=)约0.5mm~2mm的方式分离地设置了该发光元件2。通过对该发光元件2供给规定的功率,光L1、L2分别从该发光元件2的发光面2a和发光侧面2b起被射出。此时,发光元件2伴随该发光而发热,由此,LED10的温度上升。In this example, the
透光性构件4,如图1至图3中所示,在本例中,是形成了中空的半球形状的圆顶状的玻璃透镜,在使透光性构件4成为球形时的大致中心部配置了光源的情况下,来自该光源的光经透光性构件4可大致呈放射状地射出。该透光性构件4在周端部上具有粘接部4a。在该粘接部4a中,从与第2热熔材料6b的粘接面对置的主面的边缘部顶部A算起的高度最好比成为发光元件2的安装面的子固定件1c的顶部的高度低。即,如图3中所示,最好设置距离h。由此,来自发光侧面2b的光L2从透光性构件4的圆顶状的玻璃透镜的部分射出而不被透光性构件4的粘接部4a和第2热熔材料6b遮蔽。因而,可有效地利用从发光元件2的侧方射出的光L2。此外,最好在氮气那样的惰性气体的气氛中利用第2热熔材料6b来粘接透光性构件4。由此,在透光性构件4的中空的部分中封入惰性气体,不会象在空气中粘接时那样在中空的部分中混入水分。因而,由于消除了水分对于发光元件2或作为该发光元件2的粘接剂的导电性构件(例如,银膏)的不良影响,故可作成可靠性高的发光器件。此外,如果透光性构件的材料具有透光性,则不作特别限定,除了玻璃透镜外,可使用硅凝胶等的在耐光性方面良好的无机物或聚硅氮烷树脂、环氧树脂、脲树脂、氟树脂和至少包含一种以上的这些树脂的混合树脂等在耐气候性方面良好的透光性树脂。此外,也可在透光性构件中根据使用用途添加粘度增量剂、光发散剂、颜料、荧光物质等所有的构件。例如,作为光发散剂,可举出钛酸钡、氧化钛、氧化铝、氧化硅、二氧化硅、重质碳酸钙、轻质碳酸钙和包含至少一种以上的这些物质的混合物。此外,透光性构件4的形状不限定于此,例如可作成凹凸透镜形状或从发光观察面侧看呈大致椭圆的形状或将多种这些形状组合起来的形状。The light-transmitting
在本例中,金属构件5由作为热传导率比较良好的金属材料的Cu构成,具有面积(图2中c×d)为81mm2~144mm2(c=9mm~12mm时,d=9mm~12mm)的面且包含发光元件2的发光面2a的形状那样的正方形或长方形的面5a,在该面5a上经子固定件1c设置了发光元件2。再有,在本例中,金属构件5的尺寸与陶瓷构件1的第1板状构件1a的尺寸相同。In this example, the
热熔材料6被构成为在比规定的温度(在本例中,约100℃~150℃)高的熔融温度下加热熔融的同时在固化粘接状态下显示出柔软性,包含粘接了金属构件5的面5a与陶瓷构件1的一个面(换言之,第1板状构件1a的一个面和子固定件1c的底面1c”)的第1热熔材料6a和粘接了透光性构件4的粘接部4a与陶瓷构件1的另一个面(换言之,第2板状构件1b的面)的第2热熔材料6b,第1热熔材料6a的熔融温度a与第2热熔材料6b的熔融温度b的关系为a>b。此外,在本例中,热熔材料6的弹性系数为0.2×108Pa~13.0×108Pa,厚度约为0.01mm~0.10mm。如果该厚度比约0.01mm小,则热熔材料6的粘接性容易下降,如果比约0.10mm大,则热熔材料6的热传导性容易下降。The hot-
而且,将第1热熔材料6a浸渍于陶瓷构件1的一个面的粘接区域的表面部分中的气孔h中,将第2热熔材料6b浸渍于陶瓷构件1的另一个面的粘接区域的表面部分中的气孔h中。此外,在第1板状构件1a的另一个面上形成了与外部电极连接的正侧供电部7和负侧供电部8。此外,用第1热熔材料6a互相粘接第1板状构件1a与第2板状构件1b,也可将第1热熔材料6a浸渍于该第1和第2板状构件1a、1b的粘接区域的表面部分的气孔h中。And, the first hot-
按照以上已说明的LED10,由于粘接金属构件5与陶瓷构件1的粘接剂是被构成为在固化粘接状态下显示出柔软性的热熔材料6,利用该热熔材料6,可缓和伴随金属构件5和陶瓷构件1的温度上升的应力,由此,可抑制翘曲、陶瓷构件1的破损(裂纹)等的因金属构件5与陶瓷构件1的线膨胀系数的差异引起的温度变化时的问题的发生,因而,作为金属材料,可使用热传导率比较良好的金属材料(在本例中,是Cu),作为与现有的器件相比为高功率、高输出的发光二极管,可实现更高亮度的发光特性。此外,由于将热熔材料6浸渍于陶瓷构件1的粘接区域的表面部分中的气孔h中,故可牢固地使热熔材料6与气孔h结合,由此,可提高陶瓷构件1与热熔材料6的粘接力。因而,即使固化粘接状态下的热熔材料6的厚度比较薄,也可良好地保持粘接性,相应地可提高热熔材料6的热传导性。According to the
此外,由于第1热熔材料6a的熔融温度a与第2热熔材料6b的熔融温度b的关系为a>b,故例如即使在利用第1热熔材料6a粘接金属构件5与陶瓷构件1并设置了发光元件2之后利用第2热熔材料6b粘接透光性构件4与陶瓷构件1,在由第2热熔材料6b进行的透光性构件4与陶瓷构件1的粘接时,也可防止粘接了金属构件5与陶瓷构件1的第1热熔材料6a的熔融。In addition, since the relationship between the melting temperature a of the first hot-
此外,在LED10中,由于从陶瓷构件1的边缘部顶部A起以凸出距离g=约0.5mm~2mm的方式分离地设置了该发光元件2,故从发光元件2的发光侧面2b射出的光L2容易直接向外部发出,相应地可高效地利用光。此外,例如在将LED10利用于照明等的情况下,即使用透光性构件4等对来自发光元件2的光L1、L2进行聚光,也能充分地抑制从发光元件2的发光侧面2b被陶瓷构件1反射的反射光,相应地可减少聚光不匀的发生。因而,能高效地且以聚光不匀少的方式有效地利用从发光元件2的侧方2b射出的光L2。In addition, in the
再者,按照LED10,由于将子固定件1c形成为随着朝向发光元件2的安装侧呈端部细的截锥形,同时具有在安装了发光元件2时从发光面2a的边缘部起沿周边方向宽了i=约0.1mm~0.5mm的面1c’,在该面1c’上安装了发光元件2,故例如可使用从发光元件2的侧方2b在约5°的范围内射出到子固定件1c侧的光L2。因而,既可抑制来自发光元件2的侧方2b的光的射出效率的下降,又可提高对来自发光元件2的热进行散热的散热性。Furthermore, according to the
再者,在LED10中,由于发光元件2是具有面积约为1mm2~9mm2的正方形或长方形的发光面的立方体形状的发光元件,由Cu构成的金属构件5具有面积为81mm2~144mm2的面且包含发光元件2的发光面2a的形状那样的正方形或长方形的面5a,在该面5a上设置了发光元件2,故既可维持使来自发光元件2和子固定件1c的热经金属构件5或陶瓷构件1向外部散热的散热性,又可实现必要的最小限度的封装尺寸。Furthermore, in the
其次,说明图1至图3中示出的LED10的制造例。Next, the manufacturing example of LED10 shown in FIGS. 1-3 is demonstrated.
在制造该LED10时,首先,使溶解于水或水溶性有机溶剂(例如,二甲基乙酮和二甲基甲酰胺的混合溶剂)中并在比规定的温度(在此,是150℃)高的熔融温度下加热熔融的同时在固化粘接状态下显示出预定柔软性的树脂材料溶解于上述水或上述水溶性有机溶剂中以作成热熔材料6作为上述粘接剂。如果进一步说明,则考虑粘接金属构件5与陶瓷构件1并设置了发光元件2后粘接透光性构件4与陶瓷构件1的情况,在此,将热可塑性弹性体、乙烯/醋酸乙烯酯和乙烯/丙烯酸共聚物和聚乙烯溶解于上述水或上述水溶性有机溶剂中,在其中加入作为热硬化性树脂的聚酰亚胺,均匀地搅拌混合,这样作成将在比150℃高的第1熔融温度a(=250℃)下加热熔融的同时在固化粘接状态下显示出柔软性的第1树脂组合物溶解于上述水或上述水溶性有机溶剂中的第1热熔材料6a。再者,将热可塑性弹性体、乙烯/醋酸乙烯酯共聚物和乙烯/丙烯酸共聚物和聚乙烯溶解于上述水或上述水溶性有机溶剂中,在其中加入作为热硬化性树脂的聚酰亚胺,均匀地搅拌混合,这样作成将在比150℃高且比第1熔融温度a(=250℃)低的第2熔融温度b(=180℃)(a>b)下加热熔融的同时在固化粘接状态下显示出柔软性的第2树脂组合物溶解于上述水或上述水溶性有机溶剂中的第2热熔材料6b。When manufacturing the
上述第1树脂组合物的各成分的比例,在此为,The ratio of each component of the above-mentioned 1st resin composition is here,
热可塑性弹性体 :约24.9重量%(极限粘度:1.2dl/g)Thermoplastic elastomer : about 24.9% by weight (limited viscosity: 1.2dl/g)
乙烯/醋酸乙烯酯共聚物 :约24.9重量%Ethylene/vinyl acetate copolymer: about 24.9% by weight
乙烯/丙烯酸共聚物 :约24.9重量%Ethylene/acrylic acid copolymer : about 24.9% by weight
聚乙烯 :约24.9重量%Polyethylene : about 24.9% by weight
聚酰亚胺 :约0.3重量%Polyimide : About 0.3% by weight
上述第2树脂组合物的各成分的比例,在此为,The ratio of each component of the above-mentioned 2nd resin composition is here,
热可塑性弹性体 :约24.9重量%(极限粘度:0.6dl/g)Thermoplastic elastomer : about 24.9% by weight (limited viscosity: 0.6dl/g)
乙烯/醋酸乙烯酯共聚物 :约24.9重量%Ethylene/vinyl acetate copolymer: about 24.9% by weight
乙烯/丙烯酸共聚物 :约24.9重量%Ethylene/acrylic acid copolymer: about 24.9% by weight
聚乙烯 :约24.9重量%Polyethylene: about 24.9% by weight
聚酰亚胺 :约0.3重量%Polyimide : About 0.3% by weight
在本例中,作为热可塑性弹性体,使用了苯乙烯类的热可塑性弹性体,更具体地说,该热可塑性弹性体是「苯乙烯-异戊二烯-苯乙烯嵌段共聚物」,作为第1树脂组合物,使用了极限粘度(η)1.2dl/g的树脂组合物,使用了极限粘度(η)0.6dl/g的树脂组合物作为第2树脂组合物。在此,在第1树脂组合物和第2树脂组合物中「熔融温度不同」,是由热可塑性弹性体的极限粘度(η)来决定的。换言之,「极限粘度(η)的小-大」的关系实现了「熔融温度的低-高」。这样,在本例中,在第1树脂组合物和第2树脂组合物中(在相同种类的材料的热可塑性弹性体中)通过改变极限粘度(η)实现了「熔融温度的低-高」,成为改变了极限粘度(η)的结构,但也可在第1树脂组合物和第2树脂组合物中通过改变热可塑性弹性体的材料的种类来实现。即,在第1树脂组合物和第2树脂组合物中,即使使用不同的材料的热可塑性弹性体,或(在相同种类的材料的热可塑性弹性体中)使用不同的极限粘度(η)的热可塑性弹性体,都能实现「熔融温度的低-高」。再有,上述的「极限粘度(η)」是由JIS K7367-3来决定的值,按照该JIS K7367-3,是「某个有机溶剂的135℃时的粘度」,可利用Ubbelohde粘度计来求出。In this example, as the thermoplastic elastomer, a styrene-based thermoplastic elastomer was used, and more specifically, the thermoplastic elastomer was "styrene-isoprene-styrene block copolymer", As the first resin composition, a resin composition with an intrinsic viscosity (η) of 1.2 dl/g was used, and a resin composition with an intrinsic viscosity (η) of 0.6 dl/g was used as the second resin composition. Here, the "different melting temperature" between the first resin composition and the second resin composition is determined by the intrinsic viscosity (η) of the thermoplastic elastomer. In other words, the relationship of "small-large intrinsic viscosity (η)" realizes "low-high melting temperature". Thus, in this example, "low-high melting temperature" was realized by changing the intrinsic viscosity (η) in the first resin composition and the second resin composition (in thermoplastic elastomers of the same kind of material) , becomes a structure in which the intrinsic viscosity (η) is changed, but it can also be realized by changing the type of thermoplastic elastomer material in the first resin composition and the second resin composition. That is, in the first resin composition and the second resin composition, even if thermoplastic elastomers of different materials are used, or (in thermoplastic elastomers of the same type of material) different intrinsic viscosities (η) are used Thermoplastic elastomers can achieve "low-high melting temperature". In addition, the above-mentioned "intrinsic viscosity (η)" is a value determined by JIS K7367-3. According to this JIS K7367-3, it is the "viscosity of a certain organic solvent at 135°C", which can be determined using an Ubbelohde viscometer. Find out.
其次,在陶瓷构件1的粘接区域的表面部分上涂敷热熔材料6,同时使该热熔材料6在规定的真空状态下浸渍于陶瓷构件1的上述粘接区域的表面部分中的气孔h中。如果进一步说明,则准备未图示的真空槽,在该真空槽中,在第1板状构件1a的一个面和子固定件1c的底面1c”的第1粘接区域的表面部分上涂敷第1热熔材料6a,同时在第2板状构件1b的面的第2粘接区域的表面部分上涂敷第2热熔材料6b,对该真空槽内进行减压,通过成为1kPa以下的真空气氛而成为规定的真空状态。然后,在上述规定的真空状态下分别使第1和第2热熔材料6a、6b浸渍于陶瓷构件1(1a、1b、1c)的上述第1和第2粘接区域的表面部分中的气孔h中。其后,使被涂敷热熔材料6(6a、6b)的陶瓷构件1干燥。Next, the hot-
在被涂敷浸渍第1热熔材料6a并使该第1热熔材料6a干燥了的第1板状构件1a的一个面和子固定件1c的底面1c”与金属构件5之间在第1熔融温度a(=250℃)以上的第1粘接温度(在此是250℃)下且在上述规定的压力下使该第1热熔材料6a熔接,相互粘接陶瓷构件1与金属构件5,进而在粘接了陶瓷构件1与金属构件5后,在被涂敷浸渍第2热熔材料6b并使该第2热熔材料6b干燥了的第2板状构件1b的面与透光性构件4之间在上述第2熔融温度b(=180℃)以上而不到上述第1熔融温度a(=250℃)的第2粘接温度(在此是180℃)下且在上述规定的压力下使该第2热熔材料6b熔接,相互粘接陶瓷构件1与透光性构件4。此时,在陶瓷构件1上涂敷的第1和第2热熔材料6a、6b的厚度定为20μm~200μm,上述规定压力定为9.8×104Pa~294.2×104Pa。Between one surface of the first plate-shaped member 1a that is coated with the first hot-melt material 6a and dried, and the bottom surface 1c" of the sub-fixer 1c and the metal member 5, the first melt The first hot-melt material 6a is welded at the first bonding temperature (here, 250°C) above the temperature a (=250°C) and under the above-mentioned predetermined pressure to bond the ceramic member 1 and the metal member 5 to each other, Furthermore, after the ceramic member 1 and the metal member 5 are bonded, the surface of the second plate-shaped member 1b which is coated with the second hot-melt material 6b and dried and the second hot-melt material 6b is dried, and the light-transmitting member 4 Between the above-mentioned second melting temperature b (= 180°C) and the second bonding temperature (here 180°C) that is above the above-mentioned first melting temperature a (= 250°C) and at the above-mentioned predetermined pressure Make this the 2nd hot-melt material 6b welding, mutually bonding ceramic member 1 and translucent member 4.At this moment, the thickness of the 1st and the 2nd hot-melt material 6a, 6b coated on ceramic member 1 is determined as 20 μm to 200 μm, the above specified pressure is set at 9.8×10 4 Pa to 294.2×10 4 Pa.
如以上已说明的那样,在该制造例中,作为粘接剂而被作成的热熔材料6被涂敷在陶瓷构件1的上述粘接区域的表面部分上,在上述规定的真空状态下被浸渍于陶瓷构件1的上述粘接区域的表面部分中的气孔h中。由于该热熔材料6是将上述树脂组合物溶解于上述水或上述水溶性有机溶剂中的材料,故在室温(例如,25℃)下粘性小,可均匀地浸渍于该气孔h中。其后,在被涂敷浸渍了热熔材料6的陶瓷构件1与金属构件5之间在上述熔融温度以上的粘接温度下热熔材料6因加热熔融而被激活,从而相互粘接陶瓷构件1与金属构件5。这样,通过将热熔材料6真空浸渍于陶瓷构件1的上述粘接区域的表面部分中的气孔h中,可良好地结合该热熔材料6与该气孔h。这样,可制造图1至图3中示出的LED10。As described above, in this production example, the hot-
按照上述制造例,由于制造图1至图3中示出的LED10,故可缓和伴随金属构件5和陶瓷构件1的温度上升的应力,由此,可抑制翘曲、陶瓷构件1的破损(裂纹)等的因金属构件5与陶瓷构件1的线膨胀系数的差异引起的温度变化时的问题的发生,因而,作为金属构件5的材料,可使用热传导率比较良好的金属材料(在本例中,是铜(Cu)),作为与现有的器件相比为高功率、高输出的发光二极管,可实现更高亮度的发光特性。此外,由于将热熔材料6浸渍于陶瓷构件1的粘接区域的表面部分中的气孔h中,故可牢固地使热熔材料6与气孔h结合,由此,可提高陶瓷构件1与热熔材料6的粘接力。因而,即使固化粘接状态下的热熔材料6的厚度比较薄,也可良好地保持粘接性,可提供相应地能提高热熔材料6的热传导性的发光器件10。According to the above-mentioned manufacturing example, since the
此外,在上述的制造例中,由于在上述第1熔融温度a以上的第1粘接温度(在此是250℃)下使该第1热熔材料6a熔接以相互粘接陶瓷构件1与金属构件5,在粘接了陶瓷构件1与金属构件5后,在上述第2熔融温度b以上而不到上述第1熔融温度a(a>b)的上述第2粘接温度(在此是180℃)下使该第2热熔材料6b熔接以相互粘接陶瓷构件1与透光性构件4,故即使在粘接金属构件5与陶瓷构件1之后粘接透光性构件4与陶瓷构件1,在由第2热熔材料6b进行的透光性构件4与陶瓷构件1的粘接时,也可防止粘接了金属构件5与陶瓷构件1的第1热熔材料6a的熔融。In addition, in the above-mentioned production example, since the first hot-
再者,在上述的制造例中,由于可在比以往的约500℃~800℃这样的温度充分低的温度(在此是180℃或250℃)下粘接,故可提高发光器件10的生产效率,相应地可将制造成本抑制得较低。Furthermore, in the above-mentioned production example, since it is possible to bond at a temperature (here, 180° C. or 250° C.) sufficiently lower than the conventional temperature of about 500° C. to 800° C., the
再者,在使用一般大多使用的2液式或热硬化性等的粘接剂作为粘接剂以真空方式浸渍于陶瓷材料的情况下,由于该粘接剂的硬化在真空浸渍中开始,故必须在经该粘接剂将粘接物涂在陶瓷材料上的状态下进行真空浸渍,在以这种方式将粘接物涂在陶瓷材料上的状态下,发生空气从陶瓷材料的气孔脱离时的粘接剂层的不匀等,不能很好地进行真空浸渍,容易导致粘接性的下降,但在上述的制造例中,对于热熔材料6来说,在真空浸渍于陶瓷构件1并进行了干燥后设置金属构件5和透光性构件4,通过加热到上述粘接温度,可粘接陶瓷构件1与金属构件5或透光性构件4。Furthermore, in the case of vacuum-impregnating a ceramic material using a generally used two-component type or thermosetting adhesive as an adhesive, since the hardening of the adhesive starts during vacuum impregnation, the Vacuum impregnation must be carried out in the state where the adhesive is applied to the ceramic material through the adhesive. In the state where the adhesive is applied to the ceramic material in this way, when air escapes from the pores of the ceramic material The unevenness of the adhesive layer, etc., can not be vacuum impregnated well, and it is easy to cause a decrease in adhesiveness. However, in the above-mentioned manufacturing example, for the hot-
(实施例1)(Example 1)
其次,由于使用图1至图3中示出的LED10,关于该LED10中的子固定件1c来说,研究LED10的温度上升和子固定件1c的底面1c”与Cu构件5的面5a的接触面积对于倾斜角度的关系,故以下进行说明。再有,子固定件1c的倾斜角度,如图4(A)中所示,是沿子固定件1c的顶面1c’的各边相对于该顶面1c’垂直地延伸的面R与斜面S构成的角度(图中为θ)。Next, since the
在此,陶瓷构件1的材料为AlN,尺寸e×f为9mm×12mm,发光元件2的尺寸c’×d’为1mm×2mm,高度r’定为100μm,子固定件1c的顶面1c’为从发光元件2的边缘部起沿周边方向宽了i=0.2mm,此外,粘接子固定件1c与Cu构件5的热熔材料6a的厚度定为15μm。再者,Cu构件5的尺寸c×d为9mm×12mm,高度r定为2mm,使子固定件1c的倾斜角度θ变化。此时,对发光元件2投入了2.5W。Here, the material of the ceramic member 1 is AlN, the dimension e×f is 9mm×12mm, the dimension c′×d′ of the
在图5中示出子固定件1c的倾斜角度θ与温度上升值和Cu构件5与子固定件1c的接触面积的特性。如图5中所示,随着倾斜角度θ变大,虽然散热性变得良好,但子固定件1c的底面1c”与Cu构件5的面5a的接触面积增加了。但是,从成本等的观点来看,子固定件1c的上述接触面积(换言之,是子固定件1c的大小)最好较小。如果考虑该散热性和接触面积,倾斜角度θ最好约为10°~30°。FIG. 5 shows the characteristics of the inclination angle θ of the
(实施例2)(Example 2)
其次,由于使用图1至图3中示出的LED10研究LED10的发光元件2与Cu构件5的温度差〔(发光元件2的温度Tj)-(Cu构件5的温度Tcu-plate)〕对于该LED10中的Cu构件5的尺寸c×d(换言之,是封装面积)的关系,故以下进行说明。在此,除了发光元件2、子固定件1c的倾斜角度θ和Cu构件5以及陶瓷构件1的尺寸以外,与实施例1是同样的。如图4(B)中所示,将发光元件2定为并排了纵横2个×4个的尺寸c”×d”=1mm×1mm、高度r’定为100μm的发光芯片(Dice),将子固定件1c的倾斜角度θ定为20°,作为封装面积,使Cu构件5的尺寸c×d和陶瓷构件1的尺寸e×f变化为5mm×5mm=25mm2、7mm×7mm=49mm2、9mm×9mm=81mm2、12mm×12mm=144mm2、15mm×15mm=225mm2。此时,对发光元件2投入了10W。Next, since the temperature difference between the light-emitting
在图6中示出封装面积-温度特性。如图6中所示,随着封装面积c×d的增加,虽然散热性变得良好,但即使封装面积c×d比约9mm见方=81mm2~12mm见方=144mm2大,散热性也没有很大变化。因而,可知封装面积c×d最好约为81mm2~144mm2。The package area-temperature characteristic is shown in FIG. 6 . As shown in Fig. 6, as the package area c×d increases, although the heat dissipation becomes better, even if the package area c×d is larger than approximately 9 mm square = 81 mm 2 to 12 mm square = 144 mm 2 , the heat dissipation is not good. Big changes. Therefore, it can be seen that the package area c×d is preferably about 81 mm 2 to 144 mm 2 .
如以上已说明的那样,按照本发明,可抑制翘曲、陶瓷构件的破损(裂纹)等的因上述金属构件与上述陶瓷构件的线膨胀系数的差异引起的温度变化时的问题的发生,因而,作为上述金属构件的材料,可使用热传导率比较良好的金属材料,可提供能实现与现有的器件相比为高功率、高输出的器件特性的发光器件及其制造方法。As described above, according to the present invention, it is possible to suppress occurrence of problems caused by temperature changes due to differences in the linear expansion coefficients of the metal member and the ceramic member, such as warpage and breakage (cracks) of the ceramic member. , As the material of the above-mentioned metal member, a metal material with relatively good thermal conductivity can be used, and a light-emitting device and a manufacturing method thereof capable of realizing device characteristics of high power and high output compared with conventional devices can be provided.
此外,本发明例如在作为设置了发光元件的发光二极管而被构成的情况下可提供能高效地且以聚光不匀少的方式有效地利用从发光元件的侧方射出的光的发光器件。Furthermore, the present invention can provide a light-emitting device that can efficiently utilize light emitted from the side of the light-emitting element with less unevenness in light concentration, for example, when it is configured as a light-emitting diode provided with a light-emitting element.
其次,说明与本发明有关的照明装置的实施方案。Next, an embodiment of the lighting device related to the present invention will be described.
《照明装置的实施方案1》"Implementation of Lighting Device 1"
图7示出在与本发明的实施方案1有关的照明装置中使用的发光器件100的外观斜视图。发光器件100是利用上述的与本发明有关的发光器件的制造方法制造的。此外本实施方案的发光器件100的正侧供电部7和负侧供电部8不仅被设置在第1板状构件1a的面一侧,而且也被分别设置在对应的侧面一侧。Fig. 7 is a perspective view showing the appearance of the
图8示出与本实施方案有关的端子20a、20b的示意性的斜视图。端子20a、20b是分别与发光器件100的正侧供电部7和负侧供电部8接触并对发光器件100供给功率用的至少正负一对由导电性材料构成的端子。再者,端子20a、20b至少具有作为从侧方夹住发光器件100的弹簧片的第一端子21a、21b和从一个主面侧支撑发光器件100的第二端子22a、22b。更详细地说,第一端子21a、21b和第二端子22a、22b在端子20a、20b的基部25a、25b处分支,分别在已被安装的发光器件100的方向上从各基部25a、25b起延伸。通过作成这样的结构,在对发光器件100供给功率的同时,可牢固地固定发光器件100。此外,本实施方案中的端子在一个端部上具有安装发光器件100的端子,在另一个端部上具有与外部电极连接的端子23a、23b。FIG. 8 shows a schematic oblique view of the
本实施方案的端子23a、23b,如图8中所示那样,按在相对于发光器件100的主面为垂直的方向上宽度较宽那样的形状来设置,但不限定于此,也可作成在相对于发光器件100的主面为水平的方向上宽度较宽那样的形状。此外,端子20a、20b在端子的一部分、例如如图8中所示那样在基部25a、25b附近的部分处具有在安装方向上能对发光器件100进行定位那样的形状24a、24b。The
图9是示意性地示出在与本实施方案有关的端子20a、20b上安装了发光器件100的照明装置30的斜视图。在图9中,作为弹簧片的第一端子21a、21b相对于夹住发光器件100的方向具有弹性,从侧方牢固地夹住发光器件100。此外,将发光器件100放置在板状的热传递单元31上,从发光器件100的背面一侧起进行散热。在此,最好在照明装置30的背面处对热传递单元31进行折弯,以便能在反射单元等的散热手段的方向上进行散热。通过这样做,可提高照明装置的散热性。Fig. 9 is a perspective view schematically showing a
《照明装置的实施方案2》"Implementation of
图10是示意性地示出从正面方向看与本实施方案2有关的照明装置40的形态的斜视图,图11是从背面方向看照明装置40的状态的斜视图。对于与本实施方案有关的照明装置40来说,利用成形树脂等的封装体41覆盖了端子的一部分和发光器件100。用图10和图11示出的照明装置40还作为与反射单元组合的照明装置来利用。此外,如图11中所示,热传递单元31的一部分在照明装置40的背面中露出,通过与在外部设置的反射单元连接,可在反射单元的反射面中散热。FIG. 10 is a perspective view schematically showing the state of the
此外,本实施例中使用的封装体41的成形材料不作特别限定,可使用液晶聚合物、聚邻苯二甲酰胺树脂、聚对苯二甲酸丁二醇酯(PBT)等迄今为止已知的所有的热可塑性树脂。此外,为了高效地反射来自发光器件的光,可在封装体成形构件中混合氧化钛等白色颜料等。In addition, the molding material of the
《照明装置的实施方案3》"Implementation of Lighting Device 3"
图12是示意性地示出与本实施方案3有关的照明装置60的斜视图。本实施方案中的照明装置60是除了端子60a、60b的结构外与上述实施方案1和2同样的照明装置。与本实施方案有关的端子60a、60b只从发光器件100的侧面一侧支撑发光器件100进行供电。FIG. 12 is a perspective view schematically showing a
如图12中所示,与本实施方案有关的照明装置60具有正负一对端子60a、60b,利用该两端子从侧方夹住发光器件100。端子60a、60b成为下述的形状:从基部65a、65b起弹簧片61a、61b和制动部64a、64b分别沿发光器件100的侧面和与该侧面邻接的侧面延伸,进而具有与制动部64a、64b连续、能与外部电极端子连接的端子部分63a、63b。能与外部电极端子连接的端子部分63a、63b的延伸方向相对于发光器件100的侧面为大致垂直。在此,将端子60a、60b的一部分作成作为在夹住发光器件100的方向上具有弹性那样的形状的弹簧片61a、61b,在端子60a、60b之间嵌入发光器件100。此外,正的端子(例如,60a)与在发光器件100的一个侧面上设置的正侧供电部7接触,负的端子(例如,60b)与在发光器件100的另一个侧面上设置的负侧供电部8接触。此外,60a、60b的每一个在与该侧面平行的方向上成为宽度较宽的形状,以便取得相对于发光器件100的侧面的较大的接触面积。此外,60a、60b的每一个与上述的实施方案1和2同样,具有能与外部电极连接的端子部分63a、63b,该端子部分在与发光器件100的主面垂直的方向上的宽度较宽。As shown in FIG. 12, the
(端子)(terminal)
与上述各实施方案有关的端子(20a、20b或60a、60b)与在发光器件的侧面一侧和主面一侧设置的供电部接触,是由在对照明装置供给功率的同时牢固地支撑该发光器件的导电性材料构成的构件。再者,设置正负一对端子,正的端子和负的端子分别具有作为使之具有弹性以便从侧面方向夹住发光器件的弹簧片的第一端子和从一个主面一侧支撑发光器件的第二端子。或者,正的端子和负的端子分别是具有使之具有弹性以便从侧面方向夹住并支撑发光器件的弹簧片的第一端子。通过以这种方式从主面方向和/或侧面方向支撑发光器件,可牢固地固定发光器件,可防止因来自外部的振动导致的转动。在此,不仅使第一端子具有弹性,而且使第二端子也具有弹性,利用该第二端子和放置发光器件的热传递单元,可作成从发光器件的主面方向夹住该发光器件的结构。通过作成这样的结构,可更加牢固地固定发光装置,可防止因来自外部的振动导致的转动。The terminal (20a, 20b or 60a, 60b) related to each of the above-mentioned embodiments is in contact with the power supply part provided on the side surface side and the main surface side of the light emitting device, so as to supply power to the lighting device while firmly supporting the light emitting device. A component made of a conductive material of a light-emitting device. Furthermore, a pair of positive and negative terminals are provided, and the positive terminal and the negative terminal respectively have a first terminal as a spring piece for making it elastic so as to clamp the light emitting device from the side direction and a support for the light emitting device from one main surface side. second terminal. Alternatively, the positive terminal and the negative terminal are respectively first terminals having spring pieces made elastic so as to clamp and support the light emitting device from a side direction. By supporting the light emitting device from the main surface direction and/or the side direction in this way, the light emitting device can be firmly fixed, and rotation due to vibration from the outside can be prevented. Here, not only the first terminal but also the second terminal are made elastic, and the light emitting device can be sandwiched from the main surface direction of the light emitting device by using the second terminal and the heat transfer unit on which the light emitting device is placed. . With such a structure, the light-emitting device can be fixed more firmly, and rotation due to vibration from the outside can be prevented.
此外,本实施例中的端子在一个端部上具有安装发光器件的端子,在另一个端部上具有与外部的电极连接的端子。与一方端子相比,可改变与外部的电极连接的端子的形状来设置,以便与外部的电极的形状相对应。此外,端子在其一部分上具有在安装发光器件的方向上能进行定位那样的形状。例如,正负一对端子分别具有沿发光器件的侧面的制动部24a、24b、64a、64b,这样来固定和支撑发光器件,使其不在安装方向上移动。例如利用金属平板的冲切加工和折弯加工来形成这样的形状。In addition, the terminal in this embodiment has a terminal for mounting a light-emitting device at one end and a terminal for connecting to an external electrode at the other end. Compared with one terminal, the shape of the terminal connected to the external electrode may be changed so as to correspond to the shape of the external electrode. In addition, a part of the terminal has a shape that enables positioning in the direction in which the light emitting device is mounted. For example, the positive and negative pairs of terminals respectively have
对于端子来说,考虑到电传导性和弹性,可选择各种各样的材料,能以各种各样的大小来形成。作为这样的端子的材料,除了单独地使用铜外,也可适当地使用在铜或磷青铜板的表面上进行了银、钯或银、金等的金属电镀等的材料。在以这种方式进行了金属电镀的情况下,由于提高了从发光器件100发出的光的反射率,提高了照明装置的光取出效率,故是较为理想的。For the terminals, various materials can be selected in consideration of electrical conductivity and elasticity, and they can be formed in various sizes. As a material for such a terminal, in addition to using copper alone, a material obtained by plating silver, palladium, or silver, gold, or the like on the surface of a copper or phosphor bronze plate can be suitably used. When the metal plating is performed in this way, it is preferable because the reflectance of light emitted from the
(热传递单元)(heat transfer unit)
上述各实施方案中的热传递单元31是放置发光器件的、使从发光器件发生的热从发光器件的背面一侧朝向散热方向传递的构件。例如可将热传递单元作成铜或铝等的金属平板或热管。特别是在上述各实施方案中,可作为热传递单元使用的热管是例如在由铜或铝等的金属材料构成的金属管中封入了水、氯氟代烃、取代氯氟代烃、氟化物等的热输送用的工作液的材料,是通过重复进行下述工作而实现了极高的热传导性的热传递构件:在入热部(高温部)中工作液被加热而成为蒸汽,通过其蒸汽向散热部(低温侧)移动并液化而散热,该已液化的工作液利用毛细管现象而返回到入热部。The
在上述各实施方案中,可考虑被散热的方向或散热效果而将热传递单元的形状作成各种各样的形状和大小。例如,如图9中所示,被作成平板状的热传递单元31从与发光器件100的背面对置的位置起朝向能与外部电极端子连接的端子部分23a、23b的方向延伸,在中途朝向散热方向被折弯为直角。除此以外,也可象图13中示出的照明装置70那样,可作成在与发光器件100的背面对置的位置上被折弯180度的形状。In each of the above-mentioned embodiments, the shape of the heat transfer unit can be made into various shapes and sizes in consideration of the direction to be radiated and the effect of radiating heat. For example, as shown in FIG. 9 , the flat
(反射单元)(reflection unit)
在上述各实施方案中的照明装置中,对于具有能作为反射面使用的表面的反射单元来说,与发光器件的发光观察面对置地设置了该反射面,用反射面使从该发光器件照射的光在所希望的方向上反射。将反射单元的反射面加工为凹面形状,例如最好在以铝为材料的反射面或表面上进行银电镀等的金属电镀。通过进行银电镀,可提高光的反射率。此外,具有使从发光器件经热传递单元发出的热从照明装置的背后散热到照明装置的外部的功能。In the lighting device in each of the above-mentioned embodiments, for the reflective unit having a surface that can be used as a reflective surface, the reflective surface is provided opposite to the light-emitting observation surface of the light-emitting device, and the light emitted from the light-emitting device is illuminated by the reflective surface. The light is reflected in the desired direction. The reflective surface of the reflective unit is processed into a concave shape. For example, metal plating such as silver plating is preferably performed on the reflective surface or surface made of aluminum. By performing silver plating, the reflectance of light can be improved. In addition, it has a function of dissipating heat emitted from the light emitting device through the heat transfer unit from the back of the lighting device to the outside of the lighting device.
对于反射单元来说,考虑到散热性、在反射面中的反射率和发光器件的大小或输出等,可选择各种各样的材料,能以各种各样的大小来形成。即,发光器件的输出越高,则越能增大反射单元。将热传递单元的端部连接到反射单元上,由于使从发光器件发出的热高效地散热到外部,故热传导性好是较为理想的。这样的反射单元的具体的热传导度为0.01cal/(s)(cm2)(℃/cm)以上是较为理想的,更为理想的是0.5cal/(s)(cm2)(℃/cm)以上。Various materials can be selected for the reflector, and various sizes can be formed in consideration of heat dissipation, reflectivity on the reflective surface, and size or output of the light emitting device. That is, the higher the output of the light emitting device, the larger the reflection unit can be. Connecting the end portion of the heat transfer unit to the reflection unit is desirable because the heat emitted from the light emitting device is efficiently dissipated to the outside, so that the thermal conductivity is good. The specific thermal conductivity of such a reflection unit is preferably 0.01cal/(s)(cm 2 )(°C/cm) or more, more preferably 0.5cal/(s)(cm 2 )(°C/cm )above.
作为反射单元的材料,除了可单独地使用铝外,可适当地使用在铜、铝或磷青铜板的表面上进行了银、钯或银、金等的金属电镀或焊锡电镀等。在以这种方式进行了银电镀的情况下,由于提高了从发光器件发出的光的反射率,提高了照明装置的光取出效率,故是较为理想的。As the material of the reflector, besides aluminum alone, metal plating or solder plating of silver, palladium, silver, gold, etc. on the surface of copper, aluminum, or phosphor bronze plate can be suitably used. In the case where silver plating is performed in this manner, it is preferable because the reflectance of light emitted from the light-emitting device is improved and the light extraction efficiency of the lighting device is improved.
如以上已说明的那样,由于本发明的照明装置在散热性方面良好,故能以高亮度来照射。此外,由于抗来自外部的机械振动的性能也很强,故可作成可靠性高的照明装置。As described above, since the lighting device of the present invention is excellent in heat dissipation, it can illuminate with high brightness. In addition, since the performance against mechanical vibration from the outside is also strong, a highly reliable lighting device can be produced.
根据这样的原因,与本发明有关的照明装置不限定于一般的照明,例如也可作为车的灯等的车载用照明来利用。For this reason, the lighting device according to the present invention is not limited to general lighting, but can also be used as vehicle-mounted lighting such as a car lamp.
以上,以某种详细的程度对于适当的形态说明了本发明,但该适当的形态的目前公开的内容应当在结构的细节方面有所变化,在不脱离发明的范围和思想的情况下,可实现各要素的组合或顺序的变化。As above, the present invention has been described with respect to an appropriate form in some degree of detail, but the currently disclosed content of the appropriate form should be changed in the details of the structure, and can be changed without departing from the scope and spirit of the invention. Realize the combination or sequence change of each element.
例如,在上述照明装置的各实施方案(图9、图10、图12和图13)中,使用了与本发明有关的发光器件(发光器件100),但不限定于此,例如,也可使用图14中示出的发光器件100A。对于在图14中示出的发光器件100A来说,将发光元件固定在用绝缘隔离部101对正负一对导电性图形(正电极102和负电极103)彼此进行了绝缘隔离的基板的主面上,导电性地连接了该发光元件的电极与导电性图形。在此,利用例如以Au为材料的导电性引线进行发光元件与导电性图形的电连接,但也使可使在发光元件的同一面侧设置的正负一对电极与导电性图形对置,经导电性构件直接接合。此外,从作为基板的一个主面的发光观察面一侧到基板的侧面,对导电性构件彼此进行正负的绝缘隔离来配置导电性图形。此外,透光性构件104是将硬质性聚硅氧烷树脂成形为半球状的构件。这里所说的「主面」,对于发光器件、特别是对于基板来说,假定指的是发光观察面方向或发光器件的安装面,对于平板状的端子来说,假定指的是以宽度较宽的方式形成的一方的面。For example, in each embodiment of the above-mentioned lighting device (Fig. 9, Fig. 10, Fig. 12 and Fig. 13), the light-emitting device (light-emitting device 100) related to the present invention is used, but it is not limited thereto. A
如果更详细地说明发光器件100A,则对于由导电性构件加上了导电性图形的绝缘性基板来说,直接地或经作为子固定件的热传导性基板来安装发光元件。在此,作为导电性构件,例如使用金、银、铜等,利用金属电镀在绝缘性基板上作为导电性图形来形成。作为绝缘性基板,主要利用玻璃环氧树脂基板。此外,也可作成用绝缘性树脂接合了发光器件100A的基板的结构,以便对正负一对对置的金属平板进行绝缘隔离。When the light-emitting
此外,作为发光元件,使用LED芯片。可与发光器件100A的输出相一致地使用多个该LED芯片,可作成各种各样的形状和配置,以便能得到所希望的光学特性。In addition, as a light emitting element, an LED chip is used. A plurality of these LED chips can be used in accordance with the output of the
LED芯片的种类不作特别限定,但在共同使用荧光物质的情况下,最好是具有可发出能激励该荧光物质的波长的有源层的半导体发光元件。作为这样的半导体发光元件,可举出ZnSe或GaN等各种半导体,但可适当地举出可发出能高效地激励荧光物质的短波长能发光的氮化物半导体(InxAlyGa1-X-YN,0≤X,0≤Y,X+Y≤1)。上述氮化物半导体根据需要也可含有硼或磷。作为半导体的结构,可举出具有MIS结、PIN结或pn结等的同质结构、异质结构或双异质结构。根据半导体层的材料或其混晶度,可选择各种发光波长。此外,也可作成在有源层中产生量子效应的薄膜中形成的单一量子阱结构或多重量子阱结构。The type of the LED chip is not particularly limited, but when a fluorescent substance is used together, it is preferably a semiconductor light emitting element having an active layer that emits a wavelength that can excite the fluorescent substance. As such a semiconductor light-emitting element, various semiconductors such as ZnSe or GaN can be mentioned, but a nitride semiconductor ( InxAlyGa1 -XY) capable of emitting short-wavelength light that can efficiently excite fluorescent substances can be mentioned suitably. N, 0≤X, 0≤Y, X+Y≤1). The aforementioned nitride semiconductor may contain boron or phosphorus as necessary. Examples of semiconductor structures include homostructures, heterostructures, and double heterostructures having MIS junctions, PIN junctions, or pn junctions. Depending on the material of the semiconductor layer or its mixed crystallinity, various emission wavelengths can be selected. In addition, a single quantum well structure or a multiple quantum well structure formed in a thin film that produces quantum effects in the active layer can also be used.
在使用了氮化物半导体的情况下,可适当地使用蓝宝石、尖晶石、SiC、Si、ZnO、GaN等的材料作为半导体用基板。为了以良好的批量生产性形成结晶性良好的氮化物半导体,最好使用蓝宝石基板。在该蓝宝石基板上可使用MOCVD法等来形成氮化物半导体。例如,在蓝宝石基板上形成GaN、AlN、GaAlN等的缓冲层并在其上形成具有pn结的氮化物半导体。此外,对于基板来说,在层叠了半导体层后,也可将其除去。When a nitride semiconductor is used, a material such as sapphire, spinel, SiC, Si, ZnO, GaN, or the like can be suitably used as the semiconductor substrate. In order to form a nitride semiconductor having good crystallinity with good mass productivity, it is preferable to use a sapphire substrate. A nitride semiconductor can be formed on this sapphire substrate using MOCVD or the like. For example, a buffer layer of GaN, AlN, GaAlN, etc. is formed on a sapphire substrate and a nitride semiconductor having a pn junction is formed thereon. In addition, the substrate may be removed after laminating the semiconductor layer.
作为具有使用了氮化物半导体的pn结的发光元件的例子,可举出按顺序在缓冲层上层叠了用n型氮化钾形成的第1接触层、用n型氮化铝、钾形成的第1包层、用氮化铟、钾形成的有源层、用p型氮化铝、钾形成的第2包层和用p型氮化钾形成的第2接触层的双异质结构等。氮化物半导体在不掺杂的状态下显示出n型导电性。在形成使发光效率提高等的所希望的n型氮化物半导体的情况下,最好适当地导入Si、Ge、Se、Te、C作为n型掺杂剂。另一方面,在形成p型氮化物半导体的情况下,对作为p型掺杂剂的Zn、Mg、Be、Ca、Sr、Ba等进行掺杂。由于对于氮化物半导体来说只通过掺p型掺杂剂难以实现p型化,故在导入p型掺杂剂后,最好利用炉的加热或等离子体照射等使其低电阻化。在形成电极后,通过从半导体晶片切割成芯片状,可形成由氮化物半导体构成的发光元件。此外,如果利用构图形成由SiO2构成的绝缘性保护膜以便只使各电极的键合部露出而覆盖元件的整体,则能以高的可靠性形成小型化的发光器件。As an example of a light-emitting element having a pn junction using a nitride semiconductor, a first contact layer formed of n-type potassium nitride, n-type aluminum nitride, and potassium are stacked in this order on a buffer layer. The double heterostructure of the first cladding layer, the active layer formed of indium nitride and potassium, the second cladding layer of p-type aluminum nitride and potassium, and the second contact layer of p-type potassium nitride, etc. . A nitride semiconductor exhibits n-type conductivity in an undoped state. When forming a desired n-type nitride semiconductor to improve luminous efficiency, etc., it is preferable to introduce Si, Ge, Se, Te, and C as n-type dopants appropriately. On the other hand, in the case of forming a p-type nitride semiconductor, Zn, Mg, Be, Ca, Sr, Ba, etc. are doped as p-type dopants. Since it is difficult to achieve p-type conversion of nitride semiconductors only by doping p-type dopants, it is preferable to lower the resistance by furnace heating or plasma irradiation after introducing p-type dopants. After the electrodes are formed, the semiconductor wafer is diced into chips to form a light emitting element made of a nitride semiconductor. In addition, if an insulating protective film made of SiO 2 is formed by patterning so that only the bonding portion of each electrode is exposed and covers the entire element, a miniaturized light-emitting device can be formed with high reliability.
在发光器件100A中发出白色类的混色光的情况下,考虑到与来自荧光物质的发光波长的补色关系或透光性树脂的性能恶化等,发光元件的发光波长为400nm以上至530nm以下是较为理想的,420nm以上至490nm以下则更为理想。为了分别进一步提高发光元件和荧光物质的激励、发光效率,450nm以上至475nm以下最为理想。再有,利用与比较地难以因紫外线而性能恶化的构件的组合,也可使用以比400nm短的紫外线区域或可见光的短波长区域为主发光波长的发光元件。When the light-emitting
以上已说明的发光器件100A可在上述的各实施方案的照明装置中使用,但也可使用图15中示出的照明装置80作为其它的照明装置的实施方案。照明装置80具有从主面侧支撑发光器件100A的基板并对发光器件100A进行供电的正负一对端子。如果更详细地说明,则利用正负一对两端子的主面和放置发光器件的构件(例如热传递单元)的安装面从主面方向夹住发光器件100A的基板,特别是对于正负一对端子的每一个来说,支撑部82a、82b分别从基部85a、85b起沿发光器件100A的基板主面延伸,再者,制动部84a、84b分别沿发光器件100A的基板侧面延伸。再者,与制动部84a、84b连续地形成了能与外部电极端子连接的端子部分83a、83b。能与外部电极端子连接的端子部分83a、83b的延伸方向大致与发光器件100A的基板侧面垂直。在此,将正负一对端子的形状作成在夹住发光器件100A的基板的方向上具有弹性那样的弹簧形状,将发光器件100A的透光性构件104嵌入两端子间,以便进行定位。例如,正负一对端子具有各自的金属平板的一部分在发光器件100A的基板主面方向上被折弯而构成的弹簧片81a、81b,弹簧片81a、81b分别在彼此不同的方向上延伸。此外,在正端子上设置的弹簧片81a与在发光器件100A的基板上设置的主面侧的正电极102接触,另一方面,在负端子上设置的弹簧片81b与在相同的主面侧的负电极103接触。此外,将端子的形状分别形成为在与该主面平行的方向上宽度较宽的形状,以便增加对于发光器件100A的基板的接触面积。此外,与上述的照明装置的各实施方案同样,端子分别具有能与外部电极连接的端子部分83a、83b,该端子部分在与发光器件100A的基板主面平行的方向上宽度较宽。The light-emitting
此外,最好在热传递单元上经热传导性基板放置发光器件100A。热传导性基板具有将从发光器件100A发生的热传递给热传递单元的功能。考虑到散热性、光源的输出等,可将热传导性基板形成为各种大小。发光器件100A经热传导性基板与热传递单元接触。因而,为了使从发光器件100A发出的热高效地散热到热传递单元侧,热传导性基板的热传导性良好是较为理想的。具体的热传导度为0.01cal/(s)(cm2)(℃/cm)以上是较为理想的,更为理想的是0.5cal/(s)(cm2)(℃/cm)以上。In addition, it is preferable to place the
作为这样的热传导性基板的材料,除了单独地使用陶瓷、铜、铝或磷青铜板外,可适当地使用在这些金属的表面上进行了银、钯或银、金等的金属电镀或焊锡电镀等的材料。As a material for such a thermally conductive substrate, in addition to using ceramics, copper, aluminum, or phosphor bronze plates alone, metal plating or solder plating on the surface of these metals with silver, palladium, silver, gold, etc. can be suitably used. and other materials.
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