CN101031852B - Process device with diagnostic notification - Google Patents
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Abstract
Description
技术领域 technical field
本发明涉及一种在工业过程中使用的类型的过程装置。更具体地,本发明涉及诊断信息的通信。The invention relates to a process plant of the type used in industrial processes. More specifically, the present invention relates to the communication of diagnostic information.
背景技术 Background technique
在过程控制工业中使用例如过程控制器、监视器和变送器的现场装置以便遥控、监视和传感过程变量。例如,可以由变送器将过程变量发送到控制室,以便用于控制过程和用于向控制器提供关于过程操作的信息。例如,与过程流体的压力有关的信息可以传送到控制室并用于例如石油炼制的控制过程。Field devices such as process controllers, monitors and transmitters are used in the process control industry to remotely control, monitor and sense process variables. For example, process variables may be sent by transmitters to a control room for use in controlling the process and for providing information to the controller regarding the operation of the process. For example, information about the pressure of a process fluid can be communicated to a control room and used to control a process such as a petroleum refinery.
用于传送例如过程变量的一种典型的在先技术包括控制流过过程控制回路的功率值。电流从控制室内的电流源供给,且变送器控制来自现场中它的位置的电流。例如,4mA的信号可以用于表示零读数(或称之为起点读数),且20mA信号可以用于表示满刻度读数。近来,变送器已经采用数字电路,所述数字电路使用数字信号与控制室通信,所述数字信号叠加到流过过程控制回路的模拟电流信号上。这种技术的一个示例是由Rosemount公司研发的通信协议。协议和其它这样的协议典型地包括一组命令或指令,所述一组命令或指令可以被发送到变送器以引起想要的响应,例如变送器控制或询问。A typical prior art technique for communicating eg a process variable involves controlling the amount of power flowing through a process control loop. Current is supplied from a current source in the control room, and the transmitter controls the current from its location in the field. For example, a 4mA signal can be used to represent a zero reading (or what is called a starting point reading), and a 20mA signal can be used to represent a full scale reading. More recently, transmitters have employed digital circuitry that communicates with the control room using digital signals superimposed on the analog current signal flowing through the process control loop. An example of this technique is developed by the Rosemount Corporation letter of agreement. Protocols and other such protocols typically include a set of commands or instructions that can be sent to the transmitter to cause a desired response, such as transmitter control or interrogation.
Fieldbus是由Fieldbus Foundation提出的通信协议,并且用于限定用于在过程控制回路上传送信息的通信层或通信协议。在Fieldbus协议中,流过回路的电流没有用于传送模拟信号。相反,所有的信息通过调制在过程控制回路中流动的电流以数字传送。此外,Fieldbus标准,以及已知为Profibus的标准,允许变送器构造为多点结构,在所述多点结构中,多于一个的变送器连接在相同的过程控制回路上。其它通信协议包括协议和Ethernet。在一些构造中,可以使用两个、三个、四个或任何数量的电线连接到过程装置,包括例如RF(射频)的非物理连接。Fieldbus is a communication protocol proposed by the Fieldbus Foundation and is used to define a communication layer or communication protocol for transferring information on a process control loop. In the Fieldbus protocol, the current flowing through the loop is not used to transmit analog signals. Instead, all information is transmitted digitally by modulating the current flowing in the process control loop. Furthermore, the Fieldbus standard, also known as Profibus, allows transmitters to be constructed in a multidrop configuration in which more than one transmitter is connected to the same process control loop. Other communication protocols include Protocol and Ethernet. In some configurations, two, three, four, or any number of wires may be used to connect to the process device, including non-physical connections such as RF (radio frequency).
一些过程变送器也可以传送报警信号,所述报警信号可以提供过程变量测量值饱和(即,process upset)的指示。一种类型的报警信号将通过回路的电流固定在预定电平或在预定阈值之外。例如,一种类型的报警信号为电流电平,所述电流电平大于21mA或小于3.8mA就可以用于分别发送“高报警”和“低报警”。当发生报警条件时报警信号可以由变送器发送。Some process transmitters may also transmit an alarm signal that may provide an indication that a process variable measurement is saturated (ie, a process upset). One type of alarm signal fixes the current through the loop at a predetermined level or outside a predetermined threshold. For example, one type of alarm signal is a current level that is greater than 21 mA or less than 3.8 mA and can be used to signal "high alarm" and "low alarm", respectively. An alarm signal can be sent by the transmitter when an alarm condition occurs.
发明内容 Contents of the invention
一种用于连接到两线过程控制回路的过程装置,包括诊断电路,所述诊断电路构造成诊断过程装置的操作。连接到两线过程控制回路的输出部构造成提供回路上与诊断条件相关的输出,其中模拟电流电平具有多于两个的值,每一所述值指示一个不同的诊断条件。本发明也提出了一种方法和接口电路。A process device for connection to a two-wire process control loop includes a diagnostic circuit configured to diagnose operation of the process device. An output connected to the two-wire process control loop is configured to provide an output on the loop related to a diagnostic condition, wherein the analog current level has more than two values, each said value indicating a different diagnostic condition. The invention also proposes a method and an interface circuit.
附图说明 Description of drawings
图1是图示过程控制系统的示意图,所述过程控制系统包括连接到过程控制回路的过程装置;1 is a schematic diagram illustrating a process control system including process devices connected to a process control loop;
图2是图示图1中的过程装置的内部的透视图;Figure 2 is a perspective view illustrating the interior of the process device in Figure 1;
图3是过程装置中的电路的简化框图;和Figure 3 is a simplified block diagram of the circuitry in the process device; and
图4是图示接口电路的简化框图,所述接口电路用于将过程装置连接到控制室电路。4 is a simplified block diagram illustrating interface circuitry for connecting a process device to control room circuitry.
具体实施方式 Detailed ways
本发明提出了通过使用两线过程控制在回路上传送的模拟信号、通知诊断信息的方法和设备。典型地,两线过程控制回路采用用于代表过程变量的4至20毫安培的信号。然而,在很多例子中,过程装置也能够产生诊断信息。本发明涉及用于通信这些信息的技术。The present invention proposes a method and apparatus for announcing diagnostic information by using an analog signal transmitted over a loop using a two-wire process control. Typically, two-wire process control loops employ a 4 to 20 milliampere signal representing the process variable. However, in many instances the process device is also capable of generating diagnostic information. The present invention relates to techniques for communicating such information.
存在对过程装置中应该包括诊断能力的不断增加的需要。特别地,存在对提供预测诊断的能力的需要,所述预测诊断产生对未来故障的可能性的指示。对即将发生的故障的认知使得将维护行为列入时间表,并在装置的最终故障出现前实施。这获得更高的工厂利用率和增加的效率。There is an ever-increasing demand that diagnostic capabilities should be included in process installations. In particular, there is a need for the ability to provide predictive diagnostics that yield an indication of the likelihood of future failures. Awareness of impending failure allows maintenance actions to be scheduled and implemented before eventual failure of the device occurs. This results in higher plant utilization and increased efficiency.
将诊断能力落实到过程装置中的一个障碍是用于通知诊断结果的方法。新的过程装置可以提供通信技术,通过所述通信技术可以将诊断信息发送到其它装置或位置例如到控制室。这些通信技术的示例包括使用Fieldbus、Profibus、Modbus、Internet、Ethernet、RS-485、无线通信技术和其它。这些技术为过程装置提供了开始消息传递和传送诊断信息的能力。然而,过程控制工业中的很多继续使用老的通信技术,例通信标准和/或4至20毫安培标准。One obstacle to implementing diagnostic capabilities into process devices is the method used to communicate the diagnostic results. New process devices can provide communication technology by means of which diagnostic information can be sent to other devices or locations, for example to a control room. Examples of these communication technologies include the use of Fieldbus, Profibus, Modbus, Internet, Ethernet, RS-485, wireless communication technologies and others. These techniques provide process devices with the ability to initiate messaging and transmit diagnostic information. However, much of the process control industry continues to use older communication technologies such as communication standard and/or 4 to 20 mA standard.
当前,在有些构造中,使用在正常的4至20毫安培运行电流范围外的报警值,以用信号通知报警条件。另一技术是使用通信轮询技术询问装置。过程装置然后可以使用数字通信协议用数字通信诊断结果。Currently, in some configurations, alarm values outside the normal 4 to 20 milliampere operating current range are used to signal an alarm condition. Another technique is to use Communication polling technology interrogation device. The process device can then use the The digital communication protocol communicates diagnostic results digitally.
如果4至20毫安培回路电流用于传送报警信号,那么就不能向时发送过程变量,因为模拟输出功能从表示过程变量改变到表示诊断信息。此外,因为报警信号只在报警条件已经出现之后才被发送,所以这种技术并不特别适于预测诊断。更进一步的,报警不能以连续的方式且没有过程变量丢失地进行发送。尽管信息可以根据通信标准从过程装置进行通信,此方法还是限于存在主机、且构造成接收诊断信息的装置。此外,在存在主机的装置中,与诊断相关的轮询相关联的额外通信量可能会不利地影响系统的带宽。If the 4 to 20 milliampere loop current is used to convey the alarm signal, then the process variable cannot be sent to the clock because the analog output function changes from representing the process variable to representing diagnostic information. Furthermore, this technique is not particularly suitable for predictive diagnostics because the alarm signal is only sent after the alarm condition has occurred. Furthermore, alarms cannot be sent in a continuous manner without loss of process variables. Although information can be based on communication standard to communicate from process devices, this method is still limited to existing host and configured to receive diagnostic information. In addition, in the presence of In the host's device, the extra traffic associated with diagnostic-related polling may adversely affect the bandwidth of the system.
本发明提出了一种方法和设备,所述方法和设备用于以在两线过程控制回路上传送的模拟电流的形式从过程装置发送诊断信息。模拟输出可以是任何数量的形式。在一个示例中,电流电平在过程控制回路上被设定或控制,表示诊断条件,且电流电平具有多于两个的值。特定的电流电平可以映射特定的诊断条件,以便提供诊断信息。相似地,另外的过程装置可以连接到提供诊断的过程装置。此另外的过程装置可以接收诊断条件的数字表示,且可以将数字表示转换为4至20毫安培的模拟电流信号。此4至20毫安培电流信号可以与现有的控制室装置一起使用。这种可以将数字过程变量转换为4至20毫安培模拟信号的装置被示出并在1997年7月22日授权的美国专利No.5650777(所述专利的名称为CONVERSION CIRCUIT FORPROCESS CONTROL SYSTEM)中得到描述。The present invention presents a method and apparatus for transmitting diagnostic information from a process device in the form of an analog current carried on a two-wire process control loop. The analog output can be in any number of forms. In one example, the current level is set or controlled on the process control loop, indicates a diagnostic condition, and the current level has more than two values. Specific current levels can be mapped to specific diagnostic conditions to provide diagnostic information. Similarly, further process devices may be connected to the process device providing diagnostics. This additional process device can receive a digital representation of the diagnostic condition and can convert the digital representation to an analog current signal of 4 to 20 milliamps. This 4 to 20 mA current signal can be used with existing control room installations. Such a device that can convert a digital process variable to a 4 to 20 milliampere analog signal is shown and in U.S. Patent No. 5,650,777, issued July 22, 1997 (the title of the patent is CONVERSION CIRCUIT FORPROCESS CONTROL SYSTEM) get described.
当用于提供预测诊断时,回路中的电流电平可以被控制为表示诊断结果中的变化。例如,可以通过沿着预定轮廓逐渐增加(或降低)模拟值来表示逐渐恶化的成分或其它诊断指示。当模拟值超出预定阈值时,控制室内的设备可以提供故障即将发生的指示。相似地,监视诊断模拟电流输出的主系统可以构造成基于用户限定的阈值执行例外处理(或异常处理)策略。如果模拟数值超出阈值,就可以实施特定的控制配置。这可以用于安全地停止过程操作。在另一示例中,除了模拟过程变量输出之外,过程装置提供了第二模拟输出。通过遥控输入/输出装置(例如装置集线器或相似的装置)也可以产生模拟输出。在另一示例中,过程装置不是提供单个预估电流电平来表示诊断条件,而是可以提供特定模式的电流电平以代表特定的过程条件。When used to provide predictive diagnostics, the current level in the loop can be controlled to represent changes in diagnostic results. For example, a progressively deteriorating composition or other diagnostic indication may be indicated by gradually increasing (or decreasing) the analog value along a predetermined profile. When the simulated values exceed predetermined thresholds, equipment in the control room can provide an indication that a fault is imminent. Similarly, the host system monitoring the diagnostic analog current output may be configured to implement an exception handling (or exception handling) policy based on user-defined thresholds. If the simulated value exceeds a threshold, a specific control configuration can be implemented. This can be used to safely stop process operation. In another example, the process device provides a second analog output in addition to the analog process variable output. Analog outputs may also be generated by remote input/output devices such as device hubs or similar devices. In another example, rather than providing a single estimated current level to represent a diagnostic condition, a process device may provide a particular pattern of current levels to represent a particular process condition.
此构造允许现有的控制室设备利用过程装置中的诊断能力。现有的控制室设备可被容易地编程以监视模拟电流电平和采取想要的步骤,例如在超出阈值的情况下发出报警信号。本发明可以构造成允许同时获取到测量的过程变量以及诊断结果。此外,可呈现多值的模拟输出可以用于提供在诊断结果(例如代表装置或构件运转正常的诊断结果)的连续区域上的指示,。与简单提供预估报警值相比,这为控制室提供了更多的信息。此外,此构造不需要装置的额外轮询或其它复杂的基础结构。This configuration allows existing control room equipment to take advantage of the diagnostic capabilities in the process installation. Existing control room equipment can be easily programmed to monitor analog current levels and take desired steps, such as signaling an alarm if a threshold is exceeded. The present invention can be configured to allow simultaneous acquisition of measured process variables and diagnostic results. In addition, an analog output, which may take on multiple values, may be used to provide an indication on a continuum of diagnostic results, eg, diagnostic results representing proper functioning of a device or component. This provides the control room with more information than simply providing estimated alarm values. Furthermore, this configuration does not require additional polling of devices or other complex infrastructure.
图1是过程控制系统10的示意图,所述过程控制图10包括连接到过程管道16的变送器12。变速器12连接到两线过程控制回路18,所述两线过程控制回路18根据想要的协议例如标准或4至20毫安培模拟标准操作。然而,本发明不限于这些标准或两线构造。两线过程控制回路18在变送器12与控制室20之间延伸。在其中回路18根据协议运行的一个实施例中,回路18可以传送代表传感的过程变量的电流I。例如,传感器21可以传感用于在回路18上传送的过程变量。另外,协议允许数字信号叠加在通过回路18的电流上,从而数字信息可以被发送到变送器12或从变送器12接收。在一个实施例中,回路18中输送的电流I不是代表过程变量,而是代表诊断条件。例如,电流I可以在4毫安培与20毫安培之间,且代表由过程装置12中的电路确定的特定的诊断条件。在另一示例中,电流I可以被设定成任何数量的值(包括在连续范围内的任何数值),所述任何数量的值代表诊断确定(diagnostic determination)。例如,4毫安培电流可以代表特定诊断条件,而5毫安培可以代表另一诊断条件等。如果使用连续的值,电流I可以在两个端点之间值域内,且电流I值可以代表连续变化的诊断条件。在另一示例中,电流I可以被设定为代表诊断条件的三个或更多不同的电流电平。在控制室20内的电路可以监视回路18中的输送的电流电平I。例如,传统的控制室构件可以监视电流电平、并在电流电平I超出或达到特定阈值的情况下发出报警或提供其它输出。FIG. 1 is a schematic diagram of a
图1也图示了任选的第二过程控制回路26。在采用过程控制回路26的实施例中,过程控制回路18可以传送标准的过程变量,例如使用过程变量传感器21测量的一个过程变量。第二过程变量控制回路26可以与上述讨论的方式相似的方式输送代表诊断信息的电流ID。然而,也可以使用其它输送技术。这种构造允许过程控制回路18可以连续地输送主要过程变量,同时在第二过程控制回路26上提供诊断信息。在一个构造中,第二过程控制回路26运送与诊断条件相关的数字信息。FIG. 1 also illustrates an optional second
图2是变送器12的透视图,所述变送器12显示了在其内携带的电路块的一个示范性构造。在此示范性实施例中,变送器12包括连接到传感模块42的特征模块40。所述传感模块42通过集管过程连接件44连接到过程管道16(图1中示出)。FIG. 2 is a perspective view of
特征模块40包括特征模块电子电路50,所述特征模块电子电路50连接到携带在传感模块42内的传感模块电子电路52。典型地,传感模块电子电路52连接到过程变量传感器,例如图1中示出的传感器21,所述传感器21用于传感与过程操作相关的过程变量。特征模块电子电路50包括输出电路60、过程变量电路62、和诊断电路64。电路60、62和64可以硬件、软件或硬件和软件的组合进行实施,且可以位于变送器12内的任何位置。此外,各种电路60、62和64可以共用构件。The signature module 40 includes a signature module electronics circuit 50 connected to a sensing
在操作中,输出电路60控制流过回路18的电流I的值,以代表例如测量的过程变量或诊断条件。这可以用于监视或控制工业过程操作。在一些应用中,输出电路60也用于向变送器12内的电路提供电力,所述电力使用通过回路18和/或回路26接收的电力产生。如果使用第二回路26,输出电路60就也构造成控制电流电平。输出电路60可以由单个输出电路或多个输出电路组成。In operation,
根据本发明的一个方面,诊断电路64执行用于检测或预测变送器12和/或其它过程装置或构件的故障模式的任何类型的诊断。诊断电路64启动输出电路60,且输出电路60将诊断电流电平放置在回路18或26上。例如,输出电路60可以将回路电流设定到预定值。在4至20毫安培电流回路中,在一个示例中,电流I可以通过输出电路60设定到小于3.8mA或大约21mA的值,从而在回路18或26上发送报警。这些电流电平被分别称之为“低报警”和“高报警”。然而,电流电平需要时可以设定到任何电平。例如,如上所讨论的,电流可以设定成不止三个的不同电平,所述不同电平中的每一个表示诊断条件。在另一示例中,电流电平可以设定到4毫安培与20毫安培之间的值,以便代表诊断条件。电流电平的连续值也可以用于提供表示连续的诊断条件的输出。此外,电流电平可以预定模式随时间改变,以便表示特定的诊断条件。According to one aspect of the present invention,
图3是变送器12的简化框图。如图3中所示,变送器12包括测量电路62,所述测量电路62连接到过程变量传感器21。测量电路62可以包括在图2中示出的传感器模块电路电子装置52上。电路60连接到测量电路62,且构造成用于在过程控制回路18和任选回路26上发送(和在一些实施例中,接收)信息。输出电路60包括第一回路输出电路60A和任选的第二回路输出电路60B。然而,电路60A和60B可以根据其它实施例构造。测量电路62构造成提供对由传感器21传感的过程变量的初始处理。测量电路62的执行经常包括微处理器。所述微处理器也可以用于执行在装置中示出的其它电路功能。FIG. 3 is a simplified block diagram of
在正常操作中,由传感器21传感的过程变量被转换成模拟电流电平或数字信号,以便使用输出电路60在过程控制回路18上输送。然而,当诊断条件由诊断电路64传感时,输出电路60构造成以例如高于或低于阈值电平的预定电流电平提供回路18或26上的电流电平输出。输出电路60A、60B可以与其它电路串联连接或并联连接。也可以使用其它构造。在一些实施例中,第二输出电路60B构造成在没有使用、不活动或功率降低时,切断或另外断开或断电。In normal operation, the process variable sensed by
图4是过程控制系统100的简化框图,所述过程控制系统100包括过程装置102、接口电路104和控制室电路106。过程装置102显示为连接到单个过程控制回路110上。此过程控制回路构造成承载多于一种类型的信息。例如,主要过程变量可以由在回路110上运送的电流I代表,且其它信息可以被数字调制到回路110上。在另一示例中,所有的信息数字调制到控制回路110上。FIG. 4 is a simplified block diagram of a
控制回路110连接到接口电路104,所述接口电路104通过第一过程控制回路112和第二过程回路114连接到控制室电路106。接口电路104通过回路100从过程装置102接收多于一种类型的信息。由接口电路104接收的至少一种类型的信息与诊断相关。接口电路104构造成在回路114上提供电流电平ID,所述电流电平ID与接收的诊断信息相关。电流电平由控制室电路106接收,从而控制室电路106接收诊断信息。接口电路104可以连接到其它过程控制回路例如图示为运送IPV的回路112。例如,回路112中的电流电平可以代表从过程装置102接收的过程变量。在一些构造中,接口电路104只向控制室电路106提供诊断信息。在这种构造中,例如通过例如回路110的独立的回路之上可以提供过程变量信息。
尽管单个过程装置102显示为连接到回路110,且单个回路110显示作为输入连接到接口电路104,但是任何数量的过程装置和/或过程控制回路可以连接到接口电路104。相似地,接口电路104可以控制电流或数字信号,所述电流或数字信号在任何数量的过程控制回路中运送。此外,例如使用从回路接收的输入数据,通过与接口电路104关联的电路可以执行诊断。Although a
使用图4中示出的构造,控制室电路106可以根据传统的技术运行。例如,控制室电路106可以简单地监视在回路114内运送的电流电平ID,且如果电流电平超过预定阈值就发出报警或其它输出。接口电路104允许通过控制电路106以传统形式获取到来自过程装置的信息,这与根据新近的标准需要电路106被升级相反。接口电路基于特定的诊断条件可以将诊断信息映射到特定的电流电平。接口电路可以提供作为连续或半连续的值的电流电平,或可以提供电流电平输出的模式以指示诊断条件。接口电路可以在物理上位于系统100内任何合适的位置,例如在控制室内部、控制室外部没有危险的区域、或在其中电路必须满足固有的安全标准的危险区域内。回路接口电路104可以完全从连接到电路104的一个或更多过程控制回路供电。然而,在这种构造中,接口电路会需要足够的电力以给过程控制回路110和(在一些构造中)过程装置102供电。可选地,单独的电源可以用于给接口电路104供电。Using the configuration shown in FIG. 4, the
如在此所使用的,任何过程装置可以产生包括连接到过程控制回路的控制器、定位器、过程变量测量装置、接口电路或其它装置的诊断信息。诊断信息可以在本地产生和/或基于从其它源(例如在过程控制回路之上)接收的数据产生。诊断信息可以是任何类型的诊断信息,包括与即时事件的出现有关的诊断信息、或与出现未来事件的可能性相关的预测信息。任何想要的诊断技术可以与本发明一起使用。As used herein, any process device may generate diagnostic information including a controller, positioner, process variable measurement device, interface circuit, or other device connected to a process control loop. Diagnostic information may be generated locally and/or based on data received from other sources (eg, over a process control loop). The diagnostic information may be any type of diagnostic information, including diagnostic information relating to the occurrence of an immediate event, or predictive information relating to the likelihood of a future event occurring. Any desired diagnostic technique can be used with the present invention.
尽管本发明已经参照优选实施例得到描述,但是本领域普通技术人员将理解的是,在没有偏离本发明的精神和保护范围的情况下可以做出形式和细节上的变化。上述描述以一个示例构造说明了本发明,但是可以使用任何适当的过程控制回路,例如4至20mA,2、3或4线回路,多点回路和根据Fieldbus、Profibus、或其它通信协议(所述通信协议通过控制过程控制回路中的电流传送与过程有关的信息)运行的回路。本发明在安全仪表系统(SIS)构造中特别有用,所述安全仪表系统构造为过程控制回路提供附加的安全层(safety layer)。通过提供附加的诊断通知能力,本发明可以提供改进过程装置的安全整体性水平(SIL)等级的技术。在一个示例中,报警电平(或报警级;alarm levels)是诊断条件的通知。Although the present invention has been described with reference to preferred embodiments, workers skilled in the art will understand that changes may be made in form and detail without departing from the spirit and scope of the invention. The above description illustrates the invention with an example configuration, but any suitable process control loop may be used, such as a 4 to 20 mA, 2, 3 or 4 wire loop, a multipoint loop, and according to Fieldbus, Profibus, or other communication protocols that communicate process-related information by controlling the electrical current in the process control loop. The invention is particularly useful in safety instrumented system (SIS) configurations that provide an additional safety layer for process control loops. By providing additional diagnostic notification capabilities, the present invention may provide techniques for improving the Safety Integrity Level (SIL) rating of a process device. In one example, alarm levels (or alarm levels; alarm levels) are notifications of diagnostic conditions.
Claims (46)
Applications Claiming Priority (3)
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| PCT/US2005/033893 WO2006039170A2 (en) | 2004-09-30 | 2005-09-20 | Process device with diagnostic annunciation |
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- 2005-09-20 RU RU2007116117/09A patent/RU2380732C2/en not_active IP Right Cessation
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| RU2007116117A (en) | 2008-11-20 |
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| JP2008515098A (en) | 2008-05-08 |
| JP4916445B2 (en) | 2012-04-11 |
| RU2380732C2 (en) | 2010-01-27 |
| WO2006039170A3 (en) | 2006-06-01 |
| EP1803041B1 (en) | 2019-06-26 |
| BRPI0515937A (en) | 2008-08-12 |
| WO2006039170A2 (en) | 2006-04-13 |
| US20060069455A1 (en) | 2006-03-30 |
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