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CN101104130A - Device and method for seawater washing treatment of ship exhaust gas - Google Patents

Device and method for seawater washing treatment of ship exhaust gas Download PDF

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Publication number
CN101104130A
CN101104130A CNA2007100123711A CN200710012371A CN101104130A CN 101104130 A CN101104130 A CN 101104130A CN A2007100123711 A CNA2007100123711 A CN A2007100123711A CN 200710012371 A CN200710012371 A CN 200710012371A CN 101104130 A CN101104130 A CN 101104130A
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seawater
hollow fiber
water quality
fiber membrane
monitor
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宋永欣
尹峰
池华方
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Dalian Maritime University
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Dalian Maritime University
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Abstract

本发明的对船舶尾气进行海水洗涤处理的装置及方法属于船舶尾气处理技术领域。在作为洗涤器的中空纤维膜接触器内,对经过除尘预处理的船舶尾气进行海水洗涤处理,由SO2浓度监测仪、水质监测仪和PLC可编程控制器组成的控制系统,实现对处理后的船舶尾气中的SO2浓度、废水水质的实时检测和存储以及对排水的控制。本发明的有益效果在于:采用中空纤维膜接触器作为洗涤器,需水量少,可以有效地去除船舶尾气中的硫氧化物和颗粒物质;采用PLC可编程控制器对船舶尾气和海水的处理效果进行实时监测、采集和存储,方便港口国检查。

Figure 200710012371

The device and method for washing ship tail gas with seawater according to the invention belong to the technical field of ship tail gas treatment. In the hollow fiber membrane contactor used as a scrubber, seawater washing treatment is performed on the ship tail gas that has undergone dust removal pretreatment. The control system composed of SO 2 concentration monitor, water quality monitor and PLC programmable controller realizes the post-treatment Real-time detection and storage of SO 2 concentration in ship exhaust, waste water quality and control of discharge. The beneficial effects of the present invention are: the hollow fiber membrane contactor is used as the scrubber, which requires less water and can effectively remove sulfur oxides and particulate matter in the exhaust gas of the ship; the treatment effect of the exhaust gas and seawater by the PLC Real-time monitoring, collection and storage for port state inspection.

Figure 200710012371

Description

对船舶尾气进行海水洗涤处理的装置及方法 Device and method for seawater washing treatment of ship exhaust gas

技术领域technical field

本发明涉及船舶尾气处理技术领域,尤其涉及对船舶尾气进行海水洗涤处理的装置及方法。The invention relates to the technical field of ship tail gas treatment, in particular to a device and method for washing ship tail gas with seawater.

背景技术Background technique

现有的远洋船舶大多数使用重质燃料油作为燃料,其燃烧产物,即船舶尾气中含有大量的有害气体,例如二氧化碳、氮氧化物、硫氧化物等,这些有害气体若不进行处理而直接排放,则会污染大气,从而对自然环境造成诸多危害。为有效降低船舶尾气对大气造成的污染,国际海事组织(IMO)制定了MARPOL公约附则VI,对船舶尾气中的氮氧化物和硫氧化物的排量进行了规定。Most of the existing ocean-going ships use heavy fuel oil as fuel, and its combustion products, namely ship exhaust, contain a large amount of harmful gases, such as carbon dioxide, nitrogen oxides, sulfur oxides, etc. If these harmful gases are not treated, they will be directly Emissions will pollute the atmosphere and cause many harms to the natural environment. In order to effectively reduce the pollution caused by ship exhaust to the atmosphere, the International Maritime Organization (IMO) has formulated Annex VI of the MARPOL Convention, which regulates the emissions of nitrogen oxides and sulfur oxides in ship exhaust.

现有处理船舶尾气的技术有很多,其中,氮氧化物的处理技术主要有燃烧处理、选择性催化还原两大类;硫氧化物的处理技术有使用低硫燃料油的前处理技术和干法脱硫/海水洗涤的后处理技术。但是,现有海水洗涤处理的洗涤器大都采用喷嘴直接进行喷水处理,这种海水洗涤处理工艺的处理效果差且能耗大。There are many existing technologies for treating ship exhaust. Among them, the treatment technologies of nitrogen oxides mainly include combustion treatment and selective catalytic reduction; the treatment technologies of sulfur oxides include pre-treatment technology using low-sulfur fuel oil and dry method. Post-treatment technology for desulfurization/seawater washing. However, most of the existing scrubbers for seawater washing treatment use nozzles to directly spray water. This seawater washing treatment process has poor treatment effect and high energy consumption.

发明内容Contents of the invention

本发明的目的是提供一种对船舶尾气进行海水洗涤处理的装置及方法,可以有效地去除船舶尾气中的硫氧化物和颗粒物质,还可以实时监测、采集、存储船舶尾气和海水的处理效果,方便港口国检查。The purpose of the present invention is to provide a device and method for washing ship tail gas with seawater, which can effectively remove sulfur oxides and particulate matter in ship tail gas, and can also monitor, collect and store the treatment effect of ship tail gas and seawater in real time , to facilitate port state inspection.

为了达到上述目的,本发明的技术方案如下:In order to achieve the above object, technical scheme of the present invention is as follows:

对船舶尾气进行海水洗涤处理的装置,主要由海水泵1、电磁流量计2、中空纤维膜接触器3、静电除尘器4、轴流风机5、固液旋流分离器6、SO2浓度监测仪7、PLC可编程控制器8、水质监测仪9和电磁阀10组成,海水泵1通过钢管与电磁流量计2连接,电磁流量计2通过钢管与中空纤维膜接触器3的海水入口连接,静电除尘器4通过铝合金管与轴流风机5连接,用于对船舶尾气进行预处理;轴流风机5通过铝合金管与中空纤维膜接触器3气体入口连接,用于将预处理后的船舶尾气输入中空纤维膜接触器3内;SO2浓度监测仪7通过钢管与中空纤维膜接触器3的气体出口连接,用于监测处理后的船舶尾气中SO2的浓度,并将监测结果传送给PLC可编程控制器8;固液旋流分离器6通过钢管与中空纤维膜接触器3的海水出口连接,用于将从中空纤维膜接触器3流出的海水进行油渣与水的分离;水质监测仪9通过钢管与固液旋流分离器6连接,用于监测经固液旋流分离器6处理后的海水的水质,并将监测结果传送给PLC可编程控制器8;PLC可编程控制器8分别与SO2浓度监测仪7、水质监测仪9、电磁阀10连接,用于实时检测并存储SO2浓度监测仪7和水质监测仪9传送的监测信号,并根据检测到的水质监测信号控制电磁阀10动作;电磁阀10通过钢管与水质监测仪9连接,用于控制流经水质监测仪9的海水的流向。The device for seawater washing treatment of ship exhaust gas is mainly composed of seawater pump 1, electromagnetic flowmeter 2, hollow fiber membrane contactor 3, electrostatic precipitator 4, axial flow fan 5, solid-liquid cyclone separator 6, and SO2 concentration monitoring Instrument 7, PLC programmable controller 8, water quality monitor 9 and solenoid valve 10, seawater pump 1 is connected to electromagnetic flowmeter 2 through steel pipe, electromagnetic flowmeter 2 is connected to seawater inlet of hollow fiber membrane contactor 3 through steel pipe, The electrostatic precipitator 4 is connected to the axial flow fan 5 through an aluminum alloy tube for pretreatment of ship exhaust; the axial flow fan 5 is connected to the gas inlet of the hollow fiber membrane contactor 3 through an aluminum alloy tube for the pretreated The exhaust gas from the ship is input into the hollow fiber membrane contactor 3; the SO2 concentration monitor 7 is connected to the gas outlet of the hollow fiber membrane contactor 3 through a steel pipe, and is used to monitor the concentration of SO2 in the treated ship exhaust gas and transmit the monitoring results To the PLC programmable controller 8; the solid-liquid cyclone separator 6 is connected to the seawater outlet of the hollow fiber membrane contactor 3 through a steel pipe, and is used to separate oil residue and water from the seawater flowing out of the hollow fiber membrane contactor 3; The water quality monitor 9 is connected with the solid-liquid cyclone separator 6 through a steel pipe, and is used to monitor the water quality of the seawater treated by the solid-liquid cyclone separator 6, and transmit the monitoring results to the PLC programmable controller 8; the PLC programmable The controller 8 is connected with the SO2concentration monitor 7, the water quality monitor 9, and the solenoid valve 10 respectively, and is used for real-time detection and storage of the monitoring signals transmitted by the SO2concentration monitor 7 and the water quality monitor 9, and according to the detected water quality The monitoring signal controls the action of the solenoid valve 10; the solenoid valve 10 is connected to the water quality monitor 9 through a steel pipe, and is used to control the flow of seawater flowing through the water quality monitor 9.

所述的中空纤维膜接触器3内的中空纤维材质为聚丙烯,且编成纤维织物。The hollow fiber material in the hollow fiber membrane contactor 3 is polypropylene, and is woven into a fiber fabric.

对船舶尾气进行海水洗涤处理的方法,包括如下步骤:海水通过海水泵1流经电磁流量计2而泵入中空纤维膜接触器3内,船舶尾气经静电除尘器4预处理后通过轴流风机5输入中空纤维膜接触器3内;在中空纤维膜接触器3内,海水对船舶尾气进行洗涤处理;SO2浓度监测仪7对洗涤处理后的船舶尾气进行SO2浓度监测,并将监测结果传送给PLC可编程控制器8;固液旋流分离器6对中空纤维膜接触器3内流出的海水进行固液分离处理,将分离出的油渣排入油渣柜11;水质监测仪9对固液旋流分离器6分离出的海水进行水质监测,并将监测结果传送给PLC可编程控制器8;PLC可编程控制器8存储SO2浓度监测仪7和水质监测仪9传送的监测结果,并根据接收到的水质监测结果,控制电磁阀10将海水排入船舱污水井12或大海中。The method for washing ship tail gas with seawater comprises the following steps: sea water flows through a sea water pump 1 through an electromagnetic flowmeter 2 and is pumped into a hollow fiber membrane contactor 3, and ship tail gas is pretreated by an electrostatic precipitator 4 and then passed through an axial flow fan 5 is input into the hollow fiber membrane contactor 3; in the hollow fiber membrane contactor 3, seawater washes the exhaust gas of the ship; the SO2 concentration monitor 7 monitors the SO2 concentration of the washed ship exhaust gas, and reports the monitoring results Sent to the PLC programmable controller 8; the solid-liquid cyclone separator 6 performs solid-liquid separation treatment on the seawater flowing out of the hollow fiber membrane contactor 3, and discharges the separated oil residue into the oil residue tank 11; the water quality monitor 9 Monitor the water quality of the seawater separated by the solid-liquid cyclone separator 6, and transmit the monitoring results to the PLC programmable controller 8; the PLC programmable controller 8 stores the monitoring data transmitted by the SO2 concentration monitor 7 and the water quality monitor 9 As a result, and according to the received water quality monitoring results, the solenoid valve 10 is controlled to discharge seawater into the bilge well 12 or the sea.

本发明的有益效果如下:采用中空纤维膜接触器作为洗涤容器,需水量少,可以有效地去除船舶尾气中的硫氧化物和颗粒物质;采用PLC可编程控制器对船舶尾气和海水的处理效果进行实时监测、采集和存储,方便港口国检查。The beneficial effects of the present invention are as follows: the hollow fiber membrane contactor is used as the washing container, which requires less water and can effectively remove sulfur oxides and particulate matter in the tail gas of the ship; the treatment effect of the tail gas of the ship and seawater by the PLC programmable controller Real-time monitoring, collection and storage for port state inspection.

附图说明Description of drawings

图1是本发明的对船舶尾气进行海水洗涤处理的装置示意图。Fig. 1 is a schematic diagram of a device for washing ship tail gas with seawater according to the present invention.

图中:1、海水泵,2、电磁流量计,3、中空纤维膜接触器,4、静电除尘器,5、轴流风机,6、固液旋流分离器,7、SO2浓度监测仪,8、PLC可编程控制器,9、水质监测仪,10、电磁阀,11、油渣柜,12、船舱污水井。In the figure: 1. Seawater pump, 2. Electromagnetic flowmeter, 3. Hollow fiber membrane contactor, 4. Electrostatic precipitator, 5. Axial flow fan, 6. Solid-liquid cyclone separator, 7. SO2 concentration monitor , 8, PLC programmable controller, 9, water quality monitor, 10, solenoid valve, 11, oil residue tank, 12, cabin sewage well.

具体实施方式Detailed ways

下面结合附图对本发明做进一步详细地描述:The present invention is described in further detail below in conjunction with accompanying drawing:

如图1所示,本发明的对船舶尾气进行海水洗涤处理的装置,主要由海水泵1、电磁流量计2、中空纤维膜接触器3、静电除尘器4、轴流风机5、固液旋流分离器6、SO2浓度监测仪7、PLC可编程控制器8、水质监测仪9和电磁阀10组成。As shown in Figure 1, the device of the present invention that carries out seawater washing treatment to ship tail gas mainly consists of seawater pump 1, electromagnetic flow meter 2, hollow fiber membrane contactor 3, electrostatic precipitator 4, axial flow fan 5, solid-liquid cyclone Flow separator 6, SO2 concentration monitor 7, PLC programmable controller 8, water quality monitor 9 and solenoid valve 10.

来自船舶烟囱的船舶尾气经静电除尘器4的预处理后,通过轴流风机5送入中空纤维膜接触器3即洗涤器的纤维管中。在洗涤器内,由海水对船舶尾气进行洗涤处理。用于洗涤船舶尾气的海水由专用的海水泵1,经电磁流量计2计量后泵入洗涤器中。After being pretreated by the electrostatic precipitator 4, the exhaust gas from the ship chimney is sent to the fiber tube of the hollow fiber membrane contactor 3, that is, the scrubber, through the axial flow fan 5. In the scrubber, the exhaust gas from the ship is scrubbed by seawater. The seawater used for washing ship exhaust is pumped into the scrubber after being metered by the electromagnetic flowmeter 2 by a special seawater pump 1 .

洗涤后的船舶尾气流经SO2浓度监测仪7,最终排入大气中,SO2浓度监测仪7将监测到的洗涤后的船舶尾气中SO2的浓度实时传送给PLC可编程控制器8。The washed ship tail gas flows through the SO2 concentration monitor 7 and is finally discharged into the atmosphere. The SO2 concentration monitor 7 transmits the monitored SO2 concentration in the washed ship tail gas to the PLC programmable controller 8 in real time.

海水在中空纤维膜接触器3的纤维管外自上往下流动,在海水出口处变为废水,并流至固液旋流分离器6,固液旋流分离器6对废水中的固体颗粒物杂质进行分离,分离出来的杂质送入油渣柜7中,清洁的废水流经水质监测仪9进行监测,水质监测仪9是由工业用pH计和油分浓度监测装置集成在一起而组成的,水质监测仪9将水质监测结果实时传送给PLC可编程控制器8。若水质监测仪9检测的水质符合要求,即pH为7-8,油分浓度小于5ppm,则PLC可编程控制器8发出信号,控制电磁阀10动作,将此清洁废水经海水泵1泵入的海水稀释后排入大海;若水质监测仪9检测的水质超标,即pH<7,油分浓度>5mg/L,则PLC可编程控制器8发出信号,控制电磁阀10动作,将此清洁废水送入船舱污水井12中进行处理。The seawater flows from top to bottom outside the fiber tube of the hollow fiber membrane contactor 3, becomes waste water at the outlet of the seawater, and flows to the solid-liquid cyclone separator 6, and the solid-liquid cyclone separator 6 treats the solid particles in the waste water The impurities are separated, and the separated impurities are sent to the oil residue tank 7, and the clean wastewater flows through the water quality monitor 9 for monitoring. The water quality monitor 9 is composed of an industrial pH meter and an oil concentration monitoring device. The water quality monitoring instrument 9 transmits the water quality monitoring results to the PLC programmable controller 8 in real time. If the water quality detected by the water quality monitor 9 meets the requirements, that is, the pH is 7-8, and the oil concentration is less than 5ppm, then the PLC programmable controller 8 sends a signal to control the action of the solenoid valve 10, and the clean waste water is pumped in by the seawater pump 1 The seawater is diluted and discharged into the sea; if the water quality detected by the water quality monitor 9 exceeds the standard, that is, the pH<7 and the oil concentration>5mg/L, the PLC programmable controller 8 sends a signal to control the action of the solenoid valve 10, and the clean wastewater is sent to the sea. Enter the cabin sewage well 12 for processing.

在上述洗涤处理过程中,所有的监测结果均被实时传送给PLC可编程控制器8,以方便技术人员对监测数据进行存储和打印。During the above-mentioned washing process, all the monitoring results are transmitted to the PLC programmable controller 8 in real time, so that technicians can store and print the monitoring data conveniently.

Claims (3)

1. ship tail gas is carried out the device that seawer washing is handled, it is characterized in that this installs mainly by sea water pump (1), electromagnetic flowmeter (2), hollow fiber membrane contactors (3), electrostatic precipitator (4), axial flow blower (5), solid-liquid cyclone separator (6), SO 2Concentration monitor (7), PLC Programmable Logic Controller (8), water quality monitor (9) and magnetic valve (10) are formed, sea water pump (1) is connected with electromagnetic flowmeter (2) by steel pipe, electromagnetic flowmeter (2) is connected with the seawater inlet of hollow fiber membrane contactors (3) by steel pipe, electrostatic precipitator (4) is connected with axial flow blower (5) by aluminium-alloy pipe, is used for ship tail gas is carried out preliminary treatment; Axial flow blower (5) is connected with hollow fiber membrane contactors (3) gas access by aluminium-alloy pipe, is used in the pretreated ship tail gas input hollow fiber membrane contactors (3); SO 2Concentration monitor (7) is connected by the gas vent of steel pipe with hollow fiber membrane contactors (3), is used for monitoring the ship tail gas SO after the processing 2Concentration, and send monitoring result to PLC Programmable Logic Controller (8); Solid-liquid cyclone separator (6) is connected by the seawer outlet of steel pipe with hollow fiber membrane contactors (3), is used for carrying out from the seawater that hollow fiber membrane contactors (3) flows out separating of the dregs of fat and water; Water quality monitor (9) is connected with solid-liquid cyclone separator (6) by steel pipe, is used for the water quality of the seawater of monitoring after solid-liquid cyclone separator (6) is handled, and sends monitoring result to PLC Programmable Logic Controller (8); PLC Programmable Logic Controller (8) respectively with SO 2Concentration monitor (7), water quality monitor (9), magnetic valve (10) connect, and are used for detecting in real time and storage SO 2The monitor signal that concentration monitor (7) and water quality monitor (9) transmit, and move according to detected water quality monitoring signal controlling magnetic valve (10); Magnetic valve (10) is connected with water quality monitor (9) by steel pipe, is used for the flow through flow direction of seawater of water quality monitor (9) of control.
2. the device that ship tail gas is carried out the seawer washing processing as claimed in claim 1 is characterized in that the doughnut material in the described hollow fiber membrane contactors (3) is to weave into the polypropylene of fabric.
3. ship tail gas is carried out the method that seawer washing is handled, it is characterized in that, this method comprises the steps: that seawater passes through sea water pump (1) electromagnetic flowmeter (2) of flowing through and pumps in the hollow fiber membrane contactors (3), ship tail gas after electrostatic precipitator (4) preliminary treatment by in axial flow blower (5) the input hollow fiber membrane contactors (3); In hollow fiber membrane contactors (3), seawater carries out carrying out washing treatment to ship tail gas; SO 2Concentration monitor (7) carries out SO to the ship tail gas after the carrying out washing treatment 2Concentration monitor, and send monitoring result to PLC Programmable Logic Controller (8); Solid-liquid cyclone separator (6) carries out Separation of Solid and Liquid to the seawater that flows out in the hollow fiber membrane contactors (3) to be handled, and the isolated dregs of fat are entered dregs of fat cabinet (11); Water quality monitor (9) carries out water quality monitoring to the isolated seawater of solid-liquid cyclone separator (6), and sends monitoring result to PLC Programmable Logic Controller (8); PLC Programmable Logic Controller (8) storage SO 2The monitoring result that concentration monitor (7) and water quality monitor (9) transmit, and according to the water quality monitoring result who receives, control magnetic valve (10) enters cabin bilge well (12) or marine greatly with seawater.
CNA2007100123711A 2007-08-01 2007-08-01 Device and method for seawater washing treatment of ship exhaust gas Pending CN101104130A (en)

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Cited By (11)

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CN101757846A (en) * 2010-02-10 2010-06-30 青岛海德威科技有限公司 Novel method and device for processing boat exhaust gas
US8038774B2 (en) 2008-06-13 2011-10-18 Sigan Peng Ship flue gas desulphurization method and equipment
CN102363541A (en) * 2011-06-28 2012-02-29 顾忠华 Dust and oil removing device for stern exhaust treatment system
CN102485320A (en) * 2010-12-05 2012-06-06 国家海洋局天津海水淡化与综合利用研究所 Device for desulfurizing flue gas by seawater through membrane absorption and its process
US8500893B2 (en) 2008-06-13 2013-08-06 Sigan Peng Ship flue gas scrubbing equipment and method
WO2014197977A1 (en) * 2013-06-14 2014-12-18 Ionada Incorporated Membrane-based exhaust gas scrubbing method and system
US9387438B2 (en) 2014-02-14 2016-07-12 Tenneco Automotive Operating Company Inc. Modular system for reduction of sulphur oxides in exhaust
US9757686B2 (en) 2008-06-13 2017-09-12 Sigan Peng Ship flue gas scrubbing apparatus and method
EP2788104B1 (en) 2012-02-13 2017-12-13 Langh Patents OY AB Method for treating impurities contained in exhaust gases of ships, ship with exhaust gas scrubber
KR20190051249A (en) * 2017-11-06 2019-05-15 한국에너지기술연구원 Apparatus of desulfurization from marine exhaust gas using membranes
KR20200108578A (en) * 2019-03-11 2020-09-21 한국에너지기술연구원 Secondary Desulfurization Method Using Membrane

Cited By (22)

* Cited by examiner, † Cited by third party
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US8500893B2 (en) 2008-06-13 2013-08-06 Sigan Peng Ship flue gas scrubbing equipment and method
US8038774B2 (en) 2008-06-13 2011-10-18 Sigan Peng Ship flue gas desulphurization method and equipment
EP2295130A4 (en) * 2008-06-13 2012-02-22 Sigan Peng A method and device for desulfurization of the smoke discharged from ship
US9757686B2 (en) 2008-06-13 2017-09-12 Sigan Peng Ship flue gas scrubbing apparatus and method
CN101757846B (en) * 2010-02-10 2012-04-11 青岛海德威科技有限公司 Ship tail gas treatment method and device
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