CN101104130A - Device and method for seawater washing treatment of ship exhaust gas - Google Patents
Device and method for seawater washing treatment of ship exhaust gas Download PDFInfo
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- CN101104130A CN101104130A CNA2007100123711A CN200710012371A CN101104130A CN 101104130 A CN101104130 A CN 101104130A CN A2007100123711 A CNA2007100123711 A CN A2007100123711A CN 200710012371 A CN200710012371 A CN 200710012371A CN 101104130 A CN101104130 A CN 101104130A
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- 239000013535 sea water Substances 0.000 title claims abstract description 49
- 238000005406 washing Methods 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000012510 hollow fiber Substances 0.000 claims abstract description 32
- 239000012528 membrane Substances 0.000 claims abstract description 31
- 238000012544 monitoring process Methods 0.000 claims abstract description 26
- 239000007788 liquid Substances 0.000 claims description 18
- 229910000831 Steel Inorganic materials 0.000 claims description 12
- 239000010959 steel Substances 0.000 claims description 12
- 239000012717 electrostatic precipitator Substances 0.000 claims description 9
- 229910000838 Al alloy Inorganic materials 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- -1 polypropylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 235000012489 doughnuts Nutrition 0.000 claims 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052815 sulfur oxide Inorganic materials 0.000 abstract description 6
- 239000002351 wastewater Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 238000007689 inspection Methods 0.000 abstract description 3
- 239000013618 particulate matter Substances 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000011897 real-time detection Methods 0.000 abstract description 2
- 239000000428 dust Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 24
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- 239000003921 oil Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000010763 heavy fuel oil Substances 0.000 description 1
- 238000012806 monitoring device Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
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Abstract
本发明的对船舶尾气进行海水洗涤处理的装置及方法属于船舶尾气处理技术领域。在作为洗涤器的中空纤维膜接触器内,对经过除尘预处理的船舶尾气进行海水洗涤处理,由SO2浓度监测仪、水质监测仪和PLC可编程控制器组成的控制系统,实现对处理后的船舶尾气中的SO2浓度、废水水质的实时检测和存储以及对排水的控制。本发明的有益效果在于:采用中空纤维膜接触器作为洗涤器,需水量少,可以有效地去除船舶尾气中的硫氧化物和颗粒物质;采用PLC可编程控制器对船舶尾气和海水的处理效果进行实时监测、采集和存储,方便港口国检查。
The device and method for washing ship tail gas with seawater according to the invention belong to the technical field of ship tail gas treatment. In the hollow fiber membrane contactor used as a scrubber, seawater washing treatment is performed on the ship tail gas that has undergone dust removal pretreatment. The control system composed of SO 2 concentration monitor, water quality monitor and PLC programmable controller realizes the post-treatment Real-time detection and storage of SO 2 concentration in ship exhaust, waste water quality and control of discharge. The beneficial effects of the present invention are: the hollow fiber membrane contactor is used as the scrubber, which requires less water and can effectively remove sulfur oxides and particulate matter in the exhaust gas of the ship; the treatment effect of the exhaust gas and seawater by the PLC Real-time monitoring, collection and storage for port state inspection.
Description
技术领域technical field
本发明涉及船舶尾气处理技术领域,尤其涉及对船舶尾气进行海水洗涤处理的装置及方法。The invention relates to the technical field of ship tail gas treatment, in particular to a device and method for washing ship tail gas with seawater.
背景技术Background technique
现有的远洋船舶大多数使用重质燃料油作为燃料,其燃烧产物,即船舶尾气中含有大量的有害气体,例如二氧化碳、氮氧化物、硫氧化物等,这些有害气体若不进行处理而直接排放,则会污染大气,从而对自然环境造成诸多危害。为有效降低船舶尾气对大气造成的污染,国际海事组织(IMO)制定了MARPOL公约附则VI,对船舶尾气中的氮氧化物和硫氧化物的排量进行了规定。Most of the existing ocean-going ships use heavy fuel oil as fuel, and its combustion products, namely ship exhaust, contain a large amount of harmful gases, such as carbon dioxide, nitrogen oxides, sulfur oxides, etc. If these harmful gases are not treated, they will be directly Emissions will pollute the atmosphere and cause many harms to the natural environment. In order to effectively reduce the pollution caused by ship exhaust to the atmosphere, the International Maritime Organization (IMO) has formulated Annex VI of the MARPOL Convention, which regulates the emissions of nitrogen oxides and sulfur oxides in ship exhaust.
现有处理船舶尾气的技术有很多,其中,氮氧化物的处理技术主要有燃烧处理、选择性催化还原两大类;硫氧化物的处理技术有使用低硫燃料油的前处理技术和干法脱硫/海水洗涤的后处理技术。但是,现有海水洗涤处理的洗涤器大都采用喷嘴直接进行喷水处理,这种海水洗涤处理工艺的处理效果差且能耗大。There are many existing technologies for treating ship exhaust. Among them, the treatment technologies of nitrogen oxides mainly include combustion treatment and selective catalytic reduction; the treatment technologies of sulfur oxides include pre-treatment technology using low-sulfur fuel oil and dry method. Post-treatment technology for desulfurization/seawater washing. However, most of the existing scrubbers for seawater washing treatment use nozzles to directly spray water. This seawater washing treatment process has poor treatment effect and high energy consumption.
发明内容Contents of the invention
本发明的目的是提供一种对船舶尾气进行海水洗涤处理的装置及方法,可以有效地去除船舶尾气中的硫氧化物和颗粒物质,还可以实时监测、采集、存储船舶尾气和海水的处理效果,方便港口国检查。The purpose of the present invention is to provide a device and method for washing ship tail gas with seawater, which can effectively remove sulfur oxides and particulate matter in ship tail gas, and can also monitor, collect and store the treatment effect of ship tail gas and seawater in real time , to facilitate port state inspection.
为了达到上述目的,本发明的技术方案如下:In order to achieve the above object, technical scheme of the present invention is as follows:
对船舶尾气进行海水洗涤处理的装置,主要由海水泵1、电磁流量计2、中空纤维膜接触器3、静电除尘器4、轴流风机5、固液旋流分离器6、SO2浓度监测仪7、PLC可编程控制器8、水质监测仪9和电磁阀10组成,海水泵1通过钢管与电磁流量计2连接,电磁流量计2通过钢管与中空纤维膜接触器3的海水入口连接,静电除尘器4通过铝合金管与轴流风机5连接,用于对船舶尾气进行预处理;轴流风机5通过铝合金管与中空纤维膜接触器3气体入口连接,用于将预处理后的船舶尾气输入中空纤维膜接触器3内;SO2浓度监测仪7通过钢管与中空纤维膜接触器3的气体出口连接,用于监测处理后的船舶尾气中SO2的浓度,并将监测结果传送给PLC可编程控制器8;固液旋流分离器6通过钢管与中空纤维膜接触器3的海水出口连接,用于将从中空纤维膜接触器3流出的海水进行油渣与水的分离;水质监测仪9通过钢管与固液旋流分离器6连接,用于监测经固液旋流分离器6处理后的海水的水质,并将监测结果传送给PLC可编程控制器8;PLC可编程控制器8分别与SO2浓度监测仪7、水质监测仪9、电磁阀10连接,用于实时检测并存储SO2浓度监测仪7和水质监测仪9传送的监测信号,并根据检测到的水质监测信号控制电磁阀10动作;电磁阀10通过钢管与水质监测仪9连接,用于控制流经水质监测仪9的海水的流向。The device for seawater washing treatment of ship exhaust gas is mainly composed of
所述的中空纤维膜接触器3内的中空纤维材质为聚丙烯,且编成纤维织物。The hollow fiber material in the hollow
对船舶尾气进行海水洗涤处理的方法,包括如下步骤:海水通过海水泵1流经电磁流量计2而泵入中空纤维膜接触器3内,船舶尾气经静电除尘器4预处理后通过轴流风机5输入中空纤维膜接触器3内;在中空纤维膜接触器3内,海水对船舶尾气进行洗涤处理;SO2浓度监测仪7对洗涤处理后的船舶尾气进行SO2浓度监测,并将监测结果传送给PLC可编程控制器8;固液旋流分离器6对中空纤维膜接触器3内流出的海水进行固液分离处理,将分离出的油渣排入油渣柜11;水质监测仪9对固液旋流分离器6分离出的海水进行水质监测,并将监测结果传送给PLC可编程控制器8;PLC可编程控制器8存储SO2浓度监测仪7和水质监测仪9传送的监测结果,并根据接收到的水质监测结果,控制电磁阀10将海水排入船舱污水井12或大海中。The method for washing ship tail gas with seawater comprises the following steps: sea water flows through a
本发明的有益效果如下:采用中空纤维膜接触器作为洗涤容器,需水量少,可以有效地去除船舶尾气中的硫氧化物和颗粒物质;采用PLC可编程控制器对船舶尾气和海水的处理效果进行实时监测、采集和存储,方便港口国检查。The beneficial effects of the present invention are as follows: the hollow fiber membrane contactor is used as the washing container, which requires less water and can effectively remove sulfur oxides and particulate matter in the tail gas of the ship; the treatment effect of the tail gas of the ship and seawater by the PLC programmable controller Real-time monitoring, collection and storage for port state inspection.
附图说明Description of drawings
图1是本发明的对船舶尾气进行海水洗涤处理的装置示意图。Fig. 1 is a schematic diagram of a device for washing ship tail gas with seawater according to the present invention.
图中:1、海水泵,2、电磁流量计,3、中空纤维膜接触器,4、静电除尘器,5、轴流风机,6、固液旋流分离器,7、SO2浓度监测仪,8、PLC可编程控制器,9、水质监测仪,10、电磁阀,11、油渣柜,12、船舱污水井。In the figure: 1. Seawater pump, 2. Electromagnetic flowmeter, 3. Hollow fiber membrane contactor, 4. Electrostatic precipitator, 5. Axial flow fan, 6. Solid-liquid cyclone separator, 7. SO2 concentration monitor , 8, PLC programmable controller, 9, water quality monitor, 10, solenoid valve, 11, oil residue tank, 12, cabin sewage well.
具体实施方式Detailed ways
下面结合附图对本发明做进一步详细地描述:The present invention is described in further detail below in conjunction with accompanying drawing:
如图1所示,本发明的对船舶尾气进行海水洗涤处理的装置,主要由海水泵1、电磁流量计2、中空纤维膜接触器3、静电除尘器4、轴流风机5、固液旋流分离器6、SO2浓度监测仪7、PLC可编程控制器8、水质监测仪9和电磁阀10组成。As shown in Figure 1, the device of the present invention that carries out seawater washing treatment to ship tail gas mainly consists of
来自船舶烟囱的船舶尾气经静电除尘器4的预处理后,通过轴流风机5送入中空纤维膜接触器3即洗涤器的纤维管中。在洗涤器内,由海水对船舶尾气进行洗涤处理。用于洗涤船舶尾气的海水由专用的海水泵1,经电磁流量计2计量后泵入洗涤器中。After being pretreated by the
洗涤后的船舶尾气流经SO2浓度监测仪7,最终排入大气中,SO2浓度监测仪7将监测到的洗涤后的船舶尾气中SO2的浓度实时传送给PLC可编程控制器8。The washed ship tail gas flows through the
海水在中空纤维膜接触器3的纤维管外自上往下流动,在海水出口处变为废水,并流至固液旋流分离器6,固液旋流分离器6对废水中的固体颗粒物杂质进行分离,分离出来的杂质送入油渣柜7中,清洁的废水流经水质监测仪9进行监测,水质监测仪9是由工业用pH计和油分浓度监测装置集成在一起而组成的,水质监测仪9将水质监测结果实时传送给PLC可编程控制器8。若水质监测仪9检测的水质符合要求,即pH为7-8,油分浓度小于5ppm,则PLC可编程控制器8发出信号,控制电磁阀10动作,将此清洁废水经海水泵1泵入的海水稀释后排入大海;若水质监测仪9检测的水质超标,即pH<7,油分浓度>5mg/L,则PLC可编程控制器8发出信号,控制电磁阀10动作,将此清洁废水送入船舱污水井12中进行处理。The seawater flows from top to bottom outside the fiber tube of the hollow
在上述洗涤处理过程中,所有的监测结果均被实时传送给PLC可编程控制器8,以方便技术人员对监测数据进行存储和打印。During the above-mentioned washing process, all the monitoring results are transmitted to the PLC
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101757846A (en) * | 2010-02-10 | 2010-06-30 | 青岛海德威科技有限公司 | Novel method and device for processing boat exhaust gas |
| US8038774B2 (en) | 2008-06-13 | 2011-10-18 | Sigan Peng | Ship flue gas desulphurization method and equipment |
| CN102363541A (en) * | 2011-06-28 | 2012-02-29 | 顾忠华 | Dust and oil removing device for stern exhaust treatment system |
| CN102485320A (en) * | 2010-12-05 | 2012-06-06 | 国家海洋局天津海水淡化与综合利用研究所 | Device for desulfurizing flue gas by seawater through membrane absorption and its process |
| US8500893B2 (en) | 2008-06-13 | 2013-08-06 | Sigan Peng | Ship flue gas scrubbing equipment and method |
| WO2014197977A1 (en) * | 2013-06-14 | 2014-12-18 | Ionada Incorporated | Membrane-based exhaust gas scrubbing method and system |
| US9387438B2 (en) | 2014-02-14 | 2016-07-12 | Tenneco Automotive Operating Company Inc. | Modular system for reduction of sulphur oxides in exhaust |
| US9757686B2 (en) | 2008-06-13 | 2017-09-12 | Sigan Peng | Ship flue gas scrubbing apparatus and method |
| EP2788104B1 (en) | 2012-02-13 | 2017-12-13 | Langh Patents OY AB | Method for treating impurities contained in exhaust gases of ships, ship with exhaust gas scrubber |
| KR20190051249A (en) * | 2017-11-06 | 2019-05-15 | 한국에너지기술연구원 | Apparatus of desulfurization from marine exhaust gas using membranes |
| KR20200108578A (en) * | 2019-03-11 | 2020-09-21 | 한국에너지기술연구원 | Secondary Desulfurization Method Using Membrane |
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| US8500893B2 (en) | 2008-06-13 | 2013-08-06 | Sigan Peng | Ship flue gas scrubbing equipment and method |
| US8038774B2 (en) | 2008-06-13 | 2011-10-18 | Sigan Peng | Ship flue gas desulphurization method and equipment |
| EP2295130A4 (en) * | 2008-06-13 | 2012-02-22 | Sigan Peng | A method and device for desulfurization of the smoke discharged from ship |
| US9757686B2 (en) | 2008-06-13 | 2017-09-12 | Sigan Peng | Ship flue gas scrubbing apparatus and method |
| CN101757846B (en) * | 2010-02-10 | 2012-04-11 | 青岛海德威科技有限公司 | Ship tail gas treatment method and device |
| CN101757846A (en) * | 2010-02-10 | 2010-06-30 | 青岛海德威科技有限公司 | Novel method and device for processing boat exhaust gas |
| CN102485320A (en) * | 2010-12-05 | 2012-06-06 | 国家海洋局天津海水淡化与综合利用研究所 | Device for desulfurizing flue gas by seawater through membrane absorption and its process |
| CN102485320B (en) * | 2010-12-05 | 2013-09-18 | 国家海洋局天津海水淡化与综合利用研究所 | Device for desulfurizing flue gas by seawater through membrane absorption and its process |
| CN102363541A (en) * | 2011-06-28 | 2012-02-29 | 顾忠华 | Dust and oil removing device for stern exhaust treatment system |
| US11273406B2 (en) | 2012-02-13 | 2022-03-15 | Oy Langh Tech Ab | Method for treating impurities contained in exhaust gases of ships, ship with exhaust gas scrubber, and purification unit |
| EP2788104B1 (en) | 2012-02-13 | 2017-12-13 | Langh Patents OY AB | Method for treating impurities contained in exhaust gases of ships, ship with exhaust gas scrubber |
| US9291083B2 (en) | 2013-06-14 | 2016-03-22 | Ionada Incorporated | Membrane-based exhaust gas scrubbing method and system |
| JP2016526477A (en) * | 2013-06-14 | 2016-09-05 | イオナダ インコーポレイテッド | Membrane-based exhaust gas cleaning method and system |
| EP3007804A4 (en) * | 2013-06-14 | 2017-02-22 | Ionada Incorporated | Membrane-based exhaust gas scrubbing method and system |
| CN104812465B (en) * | 2013-06-14 | 2017-03-15 | 江苏优拿大环保科技有限公司 | Membrane-based exhaust gas scrubbing method and system |
| CN104812465A (en) * | 2013-06-14 | 2015-07-29 | 优拿大有限公司 | Membrane-based exhaust gas scrubbing method and system |
| WO2014197977A1 (en) * | 2013-06-14 | 2014-12-18 | Ionada Incorporated | Membrane-based exhaust gas scrubbing method and system |
| US9387438B2 (en) | 2014-02-14 | 2016-07-12 | Tenneco Automotive Operating Company Inc. | Modular system for reduction of sulphur oxides in exhaust |
| KR20190051249A (en) * | 2017-11-06 | 2019-05-15 | 한국에너지기술연구원 | Apparatus of desulfurization from marine exhaust gas using membranes |
| KR102128754B1 (en) * | 2017-11-06 | 2020-07-01 | 한국에너지기술연구원 | Apparatus of desulfurization from marine exhaust gas using membranes |
| KR20200108578A (en) * | 2019-03-11 | 2020-09-21 | 한국에너지기술연구원 | Secondary Desulfurization Method Using Membrane |
| KR102165052B1 (en) | 2019-03-11 | 2020-10-13 | 한국에너지기술연구원 | Secondary Desulfurization Method Using Membrane |
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