CN101214387B - Method for preparing film for eliminate peculiar smell in hair-dyeing operating room - Google Patents
Method for preparing film for eliminate peculiar smell in hair-dyeing operating room Download PDFInfo
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- CN101214387B CN101214387B CN 200710060588 CN200710060588A CN101214387B CN 101214387 B CN101214387 B CN 101214387B CN 200710060588 CN200710060588 CN 200710060588 CN 200710060588 A CN200710060588 A CN 200710060588A CN 101214387 B CN101214387 B CN 101214387B
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- film
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- forming agent
- eliminating
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- 238000004043 dyeing Methods 0.000 title claims abstract description 6
- 238000000034 method Methods 0.000 title claims description 10
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical group OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 14
- 239000003463 adsorbent Substances 0.000 claims abstract description 12
- 239000002250 absorbent Substances 0.000 claims abstract description 11
- 230000002745 absorbent Effects 0.000 claims abstract description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000004744 fabric Substances 0.000 claims abstract description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 5
- 229920000742 Cotton Polymers 0.000 claims abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 5
- 239000006229 carbon black Substances 0.000 claims abstract description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 5
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 5
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 5
- 239000005909 Kieselgur Substances 0.000 claims abstract description 4
- 229920002472 Starch Polymers 0.000 claims abstract description 4
- 239000008107 starch Substances 0.000 claims abstract description 4
- 235000019698 starch Nutrition 0.000 claims abstract description 4
- 239000000835 fiber Substances 0.000 claims abstract description 3
- 238000002360 preparation method Methods 0.000 claims abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 8
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 229910021529 ammonia Inorganic materials 0.000 abstract description 4
- -1 alcohol amines Chemical class 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 235000019645 odor Nutrition 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 150000004982 aromatic amines Chemical class 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
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- Cosmetics (AREA)
Abstract
本发明涉及的是一种消除染发操作间内异味膜的制备方法。特征是用化学吸收剂、物理吸附剂、成膜剂和支撑体组成的膜体系，对氨类和醇胺类物质产生的异味具有良好祛除作用。化学吸收剂为乙醛酸，在体系中其重量百分比5％-15％。物理吸附剂为白碳黑、硅藻土、碳酸钙等高比表面积无机吸附剂。在体系中其重量百分比30％-40％。成膜剂是聚乙烯醇、聚醋酸乙烯酯、淀粉、羧甲基纤维素等高分子化合物及其混合物。在体系中其重量百分比5％-10％。支撑体是各类棉布和纤维布。将化学吸收剂、物理吸附剂、成膜剂混合均匀后涂布在支撑体上，涂膜厚度0.02-0.2mm。The invention relates to a preparation method of an odor-eliminating film in a hair dyeing operation room. It is characterized by a film system composed of chemical absorbents, physical adsorbents, film-forming agents and supports, which has a good effect on eliminating the odor produced by ammonia and alcohol amines. The chemical absorbent is glyoxylic acid, and its weight percentage in the system is 5%-15%. The physical adsorbent is a high specific surface area inorganic adsorbent such as white carbon black, diatomaceous earth, and calcium carbonate. Its weight percentage in the system is 30%-40%. The film forming agent is polyvinyl alcohol, polyvinyl acetate, starch, carboxymethyl cellulose and other polymer compounds and their mixtures. Its weight percentage in the system is 5%-10%. Supports are various types of cotton cloth and fiber cloth. The chemical absorbent, the physical adsorbent, and the film-forming agent are evenly mixed and then coated on the support body with a film thickness of 0.02-0.2mm.
Description
技术领域technical field
本发明涉及的是一种消除染发操作间内异味膜的制备方法，特征是用化学吸收剂、物理吸附剂、成膜剂和支撑体组成的膜体系，对氨类和醇胺类物质产生的异味具有良好祛除作用。属于精细化工领域。The present invention relates to a method for preparing an odor-eliminating film in a hair-dyeing operation room. Odor has a good dispelling effect. It belongs to the field of fine chemicals.
背景技术Background technique
许多染发剂在使用过程中释放出氨类、醇胺类和芳香胺类物质，操作间内产生令人不愉快的气味。采用通风方式不能完全消除残留气味，特别是在带有空调器的操作间。如何祛除这类异味，改善工作和服务环境受到普遍关注。中国专利CN031074995提出用配制和喷撒特有的香水来掩盖这种异味，但不能消除这类物质对身体潜在的损害，随着人们对环境和健康问题的高度重视，用物理和化学方法处理这些物质是未来发展方向。Many hair dyes release ammonia, alcoholamines and aromatic amines during use, causing unpleasant odors in the operating room. Residual odors cannot be completely eliminated by means of ventilation, especially in operating rooms with air conditioners. How to get rid of this kind of peculiar smell and improve the working and service environment has received widespread attention. Chinese patent CN031074995 proposes to cover up this peculiar smell by preparing and spraying special perfume, but it cannot eliminate the potential damage of this kind of substance to the body. As people attach great importance to environmental and health problems, these substances are treated with physical and chemical methods is the direction of future development.
发明内容Contents of the invention
本发明筛选出一些自身无毒、无味和不挥发，但对氨类、醇胺类和芳香胺类具有良好吸收作用的化学吸收剂作为染发操作间内异味吸收剂。为了有效吸收这些令人不愉快的气体，又把化学吸收剂分散在多孔的物理吸附剂上。为了进一步提高吸收效率，在化学吸收剂和物理吸附剂中加入成膜剂，使其有巨大的气体接触表面积。为了方便使用，将其涂布在各类薄膜支撑体上构成由化学吸收剂、物理吸附剂、成膜剂和支撑体组成的膜体系。The present invention screens out some chemical absorbents which are non-toxic, odorless and non-volatile, but have a good absorption effect on ammonia, alcohol amines and aromatic amines as odor absorbers in the hair dyeing operation room. In order to effectively absorb these unpleasant gases, chemical absorbents are dispersed on porous physical adsorbents. In order to further improve the absorption efficiency, a film-forming agent is added to the chemical absorbent and physical adsorbent to make it have a huge gas contact surface area. For the convenience of use, it is coated on various film supports to form a film system composed of chemical absorbents, physical adsorbents, film-forming agents and supports.
本发明选择的化学吸收剂为乙醛酸，其自身无毒、无味和不挥发。乙醛酸分子中含有的醛基与氨类和醇胺类物质接触迅速生成稳定化合物，从而消除了其产生的异味。乙醛酸作为一个双官能团化合物，也可以和染发过程中挥发和释放出的一些芳香胺类物质反应生成稳定化合物，消除其可能存在的异味。在体系中其重量百分比5％-15％。The selected chemical absorbent of the present invention is glyoxylic acid, which itself is non-toxic, tasteless and non-volatile. The aldehyde group contained in the glyoxylic acid molecule reacts with ammonia and alcohol amines to quickly form a stable compound, thereby eliminating the odor it produces. Glyoxylic acid, as a bifunctional compound, can also react with some aromatic amines volatilized and released during the hair dyeing process to form a stable compound, eliminating its possible odor. Its weight percentage in the system is 5%-15%.
本发明选择的物理吸附剂为白碳黑、硅藻土、碳酸钙等高比表面积无机吸附剂。在体系中其重量百分比30％-40％。The physical adsorbent selected in the present invention is a high specific surface area inorganic adsorbent such as white carbon black, diatomaceous earth, and calcium carbonate. Its weight percentage in the system is 30%-40%.
本发明选择的成膜剂是聚乙烯醇、聚醋酸乙烯酯、淀粉、羧甲基纤维素等高分子化合物及其混合物。在体系中其重量百分比5％-10％。The film-forming agent selected in the present invention is polyvinyl alcohol, polyvinyl acetate, starch, carboxymethyl cellulose and other polymer compounds and mixtures thereof. Its weight percentage in the system is 5%-10%.
本发明选择的支撑体是各类棉布和纤维布。将化学吸收剂、物理吸附剂、成膜剂混合均匀后涂布在支撑体上，涂膜厚度0.02-0.2mm。The supporting bodies selected in the present invention are various types of cotton cloth and fiber cloth. The chemical absorbent, the physical adsorbent, and the film-forming agent are evenly mixed and then coated on the support body with a film thickness of 0.02-0.2mm.
具体实施方式Detailed ways
本发明的目的是采用以下方式实现的，下面结合实施例详细说明：The object of the present invention is to be achieved in the following manner, which will be described in detail below in conjunction with the embodiments:
实施例1Example 1
在装有搅拌器的500ml三口瓶中加入180ml去离子水和10g聚乙烯醇和2g羧甲基纤维素，用电热套加热到85℃，使聚乙烯醇全部溶解。冷却后在搅拌下加入40％乙醛酸溶液30g，白碳黑50g，甘油10g，搅拌均匀得到粘稠胶液。将胶液用刮浆法涂布在裁好的棉布上，膜厚度0.2mm，风干即可使用。Add 180ml of deionized water, 10g of polyvinyl alcohol and 2g of carboxymethyl cellulose into a 500ml three-necked flask equipped with a stirrer, and heat to 85°C with an electric heating mantle to completely dissolve the polyvinyl alcohol. After cooling, add 30 g of 40% glyoxylic acid solution, 50 g of white carbon black, and 10 g of glycerin under stirring, and stir evenly to obtain a viscous glue. Apply the glue solution on the cut cotton cloth with a squeegee method, the film thickness is 0.2mm, and it can be used after air drying.
实施例2Example 2
在装有搅拌器的500ml三口瓶中加入100ml去离子水和20g聚醋酸乙烯酯胶乳，在搅拌下加入40％乙醛酸溶液20g，超细碳酸钙80g，甘油10g，搅拌均匀得到粘稠胶液。将胶液用刮浆法涂布在裁好的棉布上，膜厚度0.5mm，风干即可使用。Add 100ml of deionized water and 20g of polyvinyl acetate latex into a 500ml three-necked bottle equipped with a stirrer, add 20g of 40% glyoxylic acid solution, 80g of superfine calcium carbonate, and 10g of glycerin under stirring, and stir evenly to obtain a viscous glue liquid. Apply the glue solution on the cut cotton cloth with a squeegee method, the film thickness is 0.5mm, and it can be used after air drying.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710060588 CN101214387B (en) | 2007-12-29 | 2007-12-29 | Method for preparing film for eliminate peculiar smell in hair-dyeing operating room |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710060588 CN101214387B (en) | 2007-12-29 | 2007-12-29 | Method for preparing film for eliminate peculiar smell in hair-dyeing operating room |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101214387A CN101214387A (en) | 2008-07-09 |
| CN101214387B true CN101214387B (en) | 2013-04-03 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200710060588 Expired - Fee Related CN101214387B (en) | 2007-12-29 | 2007-12-29 | Method for preparing film for eliminate peculiar smell in hair-dyeing operating room |
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| Country | Link |
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| CN (1) | CN101214387B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6767521B1 (en) * | 1999-09-09 | 2004-07-27 | W.M. Barr & Company | System for hanging a dehumidifying and deodorizing pouch |
| CN2912643Y (en) * | 2006-06-13 | 2007-06-20 | 陈晓鹏 | Peculiar smell adsorption box |
| CN2922908Y (en) * | 2006-06-14 | 2007-07-18 | 浙江富来森中竹科技股份有限公司 | Self-activating-type air-odour adsorption bag |
-
2007
- 2007-12-29 CN CN 200710060588 patent/CN101214387B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6767521B1 (en) * | 1999-09-09 | 2004-07-27 | W.M. Barr & Company | System for hanging a dehumidifying and deodorizing pouch |
| CN2912643Y (en) * | 2006-06-13 | 2007-06-20 | 陈晓鹏 | Peculiar smell adsorption box |
| CN2922908Y (en) * | 2006-06-14 | 2007-07-18 | 浙江富来森中竹科技股份有限公司 | Self-activating-type air-odour adsorption bag |
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| Publication number | Publication date |
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| CN101214387A (en) | 2008-07-09 |
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Addressee: Tianjin City Vocational Univ. Document name: Notification of before Expiration of Request of Examination as to Substance |
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| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Li Jiansheng Inventor after: Zhu Hong Inventor after: Zhang Luyan Inventor after: Wang Gang Inventor after: Kong Lingling Inventor before: Zhang Luyan Inventor before: Zhu Hong Inventor before: Wang Gang Inventor before: Kong Lingling |
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| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: ZHANG LUYAN ZHU HONG WANG GANG KONG LINGLING TO: LI JIANSHENG ZHU HONG ZHANG LUYAN WANG GANG KONG LINGLING |
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Granted publication date: 20130403 Termination date: 20131229 |