Semiconductor device with polysilicon electrode
Technical field
The present invention relates to a kind of manufacturing has through the noncrystalline and method of the semiconductor device of the polysilicon electrode of crystallization treatment again.Specifically, but not uniquely, the present invention relates to the method that a kind of manufacturing has the MOS transistor of polygate electrodes.
Background technology
Need constantly reduce device size in field of manufacturing semiconductor devices.Thisly reduce to allow on the wafer of an intended size, to incorporate into more device.Equally, also need to keep the performance of (if can not improve) device.Along with the device size of component is done lessly, some undesirable electronic effect will become more obvious.
The good example that the device of this influence wherein takes place is MOSFET.Here, source electrode that distinguishes by semiconductor channel and drain extensions each doped portion of comprising doped semiconductor wafers.Mix if substrate is the N type, then implant P type dopant, for example boron.Mix if substrate is the p type, then implant N type dopant, for example phosphorus or arsenic.Therefore, provide a p-n junction, it is that the electric current that flows between described source electrode and drain region produces a potential barrier.Therefore be applied to the height of the described potential barrier of voltage control on the insulated gate electrodes that is arranged in above the raceway groove, and control flows is crossed the electric current of described channel region.
Expectation form have shallow but the source electrode that the knot of sudden change distributes with drain extensions so that avoid by the relative caused disadvantageous electronic effect of channel region of weak point.Knot forms in semiconductor wafer or the substrate by dopant is implanted to typically.By using the described channel region of the described grid cover that has formed that dopant is implanted in the end face of described semiconductor wafer.Activate described dopant by heating anneal then.To semi-conductive heating dopant deeper is diffused in the described semiconductor subsequently, can reduces to tie the sudden change of distribution thus.This is a generally acknowledged problem.
U.S. Patent application No.US-2004/0115889 has disclosed a kind of noncrystalline implantation that can carry out in the front and back of implanting dopant species and has handled.Implanting material (for example silicon or germanium) can make the upper area of described semiconductor chip become amorphous.After noncrystalline implantation and n type or p type doping implantation, carry out heating anneal to activate described dopant and to make the crystallization again of described noncrystalline domain.
Fig. 1 a is illustrated in the height constructed profile that is similar to the substrate during the noncrystalline step that discloses in US-2004/0115889.The gate electrode of being made up of polysilicon (polysilicon) 10 insulate with semiconductor chip 12 by gate-dielectric 14 at first.Shown in arrow 100, the exposed surface of described semiconductor chip is by the implanting germanium atom and by noncrystallineization.The energy that is carried by the germanium of described implantation is used to disintegrate the rule crystallization grid near described polysilicon surface, produces a noncrystalline domain thus.Then N type or p type dopant ion are implanted (not shown) in the amorphous regions of described substrate.
Carry out heating anneal with the solid phase epitaxial regrowth that drives described amorphous regions and together with activating described dopant.This noncrystalline and re-growth processes has been illustrated the dopant activation level and the abrupt junction that are used to provide outstanding and has distributed.With reference to Fig. 1 b, the source electrode of described activation and drain extended 22,24 are separated with the justified margin of described grid 10 and by described undoped channel region 26.The described noncrystalline amorphous/crystalline boundary that is used to produce, it forbids the diffusion of dopant ion, helps abrupt junction to form thus.
With carried out the relevant problem of noncrystalline implantation before dopant activates is that at least a portion of described polysilicon gate also becomes amorphous.Make grid the more required heat budget of crystallization be much higher than the required heat budget of bulk semiconductor.When using the low temperature budget, this will cause the part crystallization again of grid.As Fig. 1 b illustrated, the bottom of grid 10a is by successfully regrowth, and top 10b keeps noncrystalline attitude.
Fig. 2 is the curve chart of the result of the test of the resistivity value of the polysilicon gate of expression after the heating anneal (regrowth) of the noncrystalline in advance implantation (PAI) of germanium and 1 minute.' D02 ' figure that is represented by rhombus represents without the resistance of crossing PAI.The curve chart that can find out the PAI of the germanium that is used to have higher-energy shows at the resistance than the very big increase under the low heat budget.
Fig. 3 has represented to experience the PAI of germanium and has schemed at the cross section X-TEM of one minute grid of 680 ℃ of following heating anneals.This is represented by the data point of highlighted being shown as ' X ' in Fig. 2.The top of the described grid of being indicated by described arrow in Fig. 2 remains amorphous.The higher relatively resistance of this grid and the poor device performance that is caused are owing to this noncrystalline part.
Under about heat budget more than 780 ℃, described grid becomes perfect recrystallization, and therefore has lower, more favourable resistance.Yet under these high temperature, described source electrode and drain junction begin deactivation, and this is caused by the increase diffusion of dopant.Therefore, do not exist the grid can be by fully crystallization and described knot can be held sufficiently the process window (process window) of sudden change again.
Summary of the invention
An object of the present invention is to provide a kind of improving one's methods of semiconductor device of making.
Another object of the present invention provides a kind of manufacturing and comprises by the grid of crystallization and be held the method for semiconductor device of the knot of sufficient sudden change more fully.
According to the present invention, a kind of method of making semiconductor device is provided, described method comprises the steps: to form the gate electrode of polysilicon on semiconductor chip, make noncrystallineization of exposed surface of described semiconductor chip and gate electrode, mixed in zone in abutting connection with the semiconductor chip of described gate electrode, then, the top that makes the part of described gate electrode and described semiconductor chip carry out crystallization again and remove described gate electrode.By the top of after described crystallisation step again, removing described gate electrode, be improved for the selection degree of freedom of treatment temperature.Can freely use low heat budget to distribute with the knot of guaranteeing to expect and be held, the crystallization degree again of gate electrode is not critical simultaneously.Any residue amorphous silicon in the described gate electrode is removed easily to guarantee carrying out low resistance contact with it.
Term ' noncrystallineization ' means that the crystal region basically with material converts any processing of noncrystalline domain basically to.Relational language, for example ' noncrystalline ' and ' amorphous ' takes from employing the implication of above-mentioned definition afterwards.
Remove the upper amorphous part of gate electrode can be for example by the uppermost exposed surface of described electrode being polished or etching is carried out.These are handled, and each is all very simple, and need be except the extras the existing device in CMOS or advanced CMOS production line.
The surface, the top of about 20-50nm of described gate electrode is removed, even this will depend on the regrowth degree of silicon gate.As above-mentioned, the noncrystalline part of removing gate electrode subsequently will allow to utilize low temperature.For example, the solid phase epitaxial regrowth in noncrystallineization zone is to carry out by described substrate being heated to 600 ℃ of temperature in-750 ℃ of scopes.The duration of heating will be depended on the temperature of employing.
The high resistance portion of removing gate electrode allows and its generation low resistance contact.This contact can further be strengthened by form the silicide contacts district on described gate electrode.Preferably, it is following realization: promptly precipitating metal level on the described gate electrode, heating described substrate so that form the silicide contacts district on described gate electrode then after removing step described.
In a preferred embodiment, semiconductor device constructed in accordance is incorporated in the integrated circuit (IC) chip.CMOS or the advanced CMOS processing plant that it is good that this can use construction make.
Description of drawings
Only embodiments of the invention are described referring now to accompanying drawing in the mode of example, wherein:
Fig. 1 is illustrated in the grid that runs through MOS transistor in two stages of known fabrication processes and the height constructed profile of channel region;
Fig. 2 for expression with the heat budget that changes by the curve chart of the resistance of noncrystallineization and regrowth, described result obtains from experiment;
Fig. 3 be at 680 ℃ by the X-TEM image of noncrystallineization and one minute grid of regrowth; With
Fig. 4 represents to run through by the grid of MOS transistor made according to the method for the present invention and the constructed profile of channel region.
Be to be appreciated that described accompanying drawing only is a schematic diagram.Identical reference number is used to represent identical or similar part in the whole text.
Embodiment
The invention provides the straightforward procedure that MOS transistor simultaneous adaptation that a kind of manufacturing has the low resistance polysilicon grid forms noncrystalline and low-temp recovery long process shallow, that abrupt junction is required.Fig. 1 and 4 will be used to illustrate an example embodiment of the method according to this invention now.
With reference to figure 1a, a dielectric layer is deposited on the silicon chip 12.For example, described dielectric layer can be made up of silicon dioxide or silicon nitride.On described substrate, deposit the polysilicon layer 10 of a thick about 100nm then.
The precipitation of gate dielectric 14 and polysilicon layer 10 is to use known deposition technique (for example epitaxial growth, chemical vapor deposition (CVD) or ald (ALD)) to carry out.
Use molded described polysilicon layer of standard lithographic printing technology and described dielectric layer so that provide the gate stack with polygate electrodes 10 on described silicon chip 12 then, described polygate electrodes 10 is separated by a gate-dielectric 14 and described silicon chip 12.For example, can utilize photoresist to shield on the substrate and the corresponding a plurality of zones of desired locations that will form the isolated gate lamination.Can use etching step to remove the unnecessary zone of polysilicon layer 10 and dielectric layer 14 then.On substrate, remove described photoresist then to keep isolation gate stack.Be to be appreciated that and in a typical integrated circuit (IC)-components, on single wafer, will form the gate stack of many separation.Yet in order to keep illustrating simplicity of the present invention, only explanation is about the single gate lamination method of (as shown in Figure 1a).
Shown in arrow 100, carry out germanium and implant noncrystallineization of exposed surface that makes described silicon chip and described gate electrode 10 then.Described implantation is with 5e14 to 1e15at/cm
3Dosage carry out with 8 to 30kev energy.Atom bombardment action on highest face temperature is disintegrated described crystalline texture, and the amorphous silicon of finite depth is provided thus.This noncrystallineization is used to limit subsequently, and diffusion of dopant ions provides the shallow source/drain regions of expectation thus to the degree of depth of described silicon wafer 12.
Now, can form in abutting connection with each zone of insulation spacer (not shown) substrate below shielding in p type doping treatment subsequently of described gate electrode.
Refer again to Fig. 1 b, with 0.2-10keV, 5e14 and 5e15at/cm
3Between dosage boron implant ion.This boron is implanted and is used for mixing with the zone 22,24 of the silicon chip of described gate electrode 10 adjacency.Described doped region is the most at last as p type doped conductive source and drain region.In another embodiment, can provide the N type semiconductor device by in the zone of described substrate, implanting N type phosphonium ion on the contrary.
Carry out the solid phase epitaxial regrowth of process annealing then with the noncrystalline part 22,24 (part that comprises gate electrode) that activates described device.Except 10a part and described semiconductor chip 22,24 to described gate electrode carry out the crystallization again, described annealing also is used to activate the boron dope agent of described implantation.
One minute the heat budget of maintenance that (typically is 650 ℃) between 600-750 ℃ is used to carry out this annealing.Imagination is for using higher temperature between a short-term, only otherwise exceeding described temperature just can destroy described abrupt junction and distribute.With reference to figure 1b, provide again crystallization source electrode and drain region 22 and 24 and the two is separated thus by described undoped channel region 26.In addition, heating anneal can make the silicon of grid 10 crystallize to a degree again so that form polysilicon bottom 10a and amorphous silicon top 10b.
According to a preferred embodiment of the present invention, then by its uppermost exposed surface being polished to remove the top 10b of gate electrode.Can utilize chemico-mechanical polishing (CMP).CMP is used for removing top 20-50nm from the surface, the top of described grid 10.Yet, the thickness that imagination is removed part depend on described grid during described solid phase epitaxial regrowth by the degree of crystallization again.Advantageously, described polishing will be removed the whole noncrystalline high resistance area of described grid basically, allow to form low resistance contact thus.Because the character that CMP handles, the degree of polishing has on described wafer+/-change of 20nm.
In a further advantageous embodiment, remove the noncrystalline part of described polysilicon gate by selectable etching.In this case, for example can use based on the acid of HF and carry out Wet-type etching to remove the amorphous silicon part 10b of described gate electrode.Advantageously, have only the high resistance portion of grid to be removed.
In another embodiment, use plasma (dry type) etching to remove the top 10b of described gate electrode.
Fig. 4 represents to remove head portion 10b gate stack afterwards.
Use standard deposition technique deposit thickness on described gate electrode to be the nickel dam (not shown) of 20-40nm then.Heat described substrate then so that the part of described nickel and following polysilicon is transformed into the silicide contacts district.Described silicide advantageously provides the even low resistance contact with described device.For example use Wet-type etching to remove any useless nickel then.Though used nickel in the present embodiment, also can imagine and use other metal be suitable for forming silicide to replace.
The further front-end processing of carrying out substrate then is to provide the contact to described semiconductor device, and it then can be at the inner element of formation that continues of an integrated circuit (IC) chip.Yet, further processing will be described, because it is not directly related with the present invention.
Put it briefly, the method for a kind of manufacturing semiconductor device (for example MOS transistor) is provided.Described device comprises polysilicon gate and the doped region that forms in semiconductor chip, they by a channel region separately.The exposed surface of described semiconductor chip for example by ion bombardment by noncrystallineization, so that during thermal annealing, forbid the diffusion subsequently of dopant ion.Low heat budget is favourable for described activation and polysilicon regrowth, so that guarantee to be used for the sudden change dopant profile of described regions and source.Therefore the top of gate electrode keeps noncrystalline.The top of described gate electrode is removed so that allow and produces low resistance contact with described polysilicon bottom.
By reading the disclosure, other variation and modification will be conspicuous for those skilled in the art.This variation and revise can be included in semi-conductive design, manufacturing and the use known and except feature described herein or the equivalent and the further feature that replace described feature to use.Though claim is expressed as the particular combinations of feature in this application, but should be appreciated that described scope of disclosure also comprises in the literary composition or expresses or hint or summarize any novel characteristics and the combination thereof that draws, no matter and whether it can relax the handled any or whole constructed problem of the present invention.The applicant states at this, in the application or during being derived from the application's the accepting of further application, and can be according to this category feature and/or its combination constitute new claim arbitrarily.