Background technology
Owing to membrane science and the development of technology and the update of water technology, the product of membrane separation technique and employing membrane separation technique is applied to water treatment field more and more in recent years.Along with the continuous maturation of popularizing gradually of using of engineering and production technology, the price of film product descends to some extent.But in general, the one-time investment of embrane method water technology and operating cost are still apparently higher than other comparatively ripe conventional water technologies, especially the short partially replacement cycle that brings of film life of product is short, make actual embrane method engineering of water treatment bear higher depreciable cost, this has limited membrane technology to a great extent and has further enlarged range of application in water treatment field.
Scientific research personnel and film product development manufacturing enterprise think that the film life of product mainly comes from film than weak point and pollutes at present.Film pollutes materials such as being defined as particle, colloid, emulsion, suspension, big molecule and salt on the film surface or the reversible and irreversible deposition of fenestra inside, and this deposition comprises absorption, obstruction, precipitation, formation filter cake etc.The development that film pollutes makes the strainability of film descend gradually, and the water-yielding capacity of film is decay thereupon also, when serious even lose water-yielding capacity substantially, has greatly influenced the stable operation of water processing establishment.The phenomenon of film film pollution in use is inevitably, so the researcher pays close attention to inhibition and removing means that film pollutes more except the formation mechanism and influence factor of deeply investigating the film pollution.At present in the middle of actual engineering, when the film pollution develops into to a certain degree, will take the chemical agent of online or off-line to clean measure to it, though this can recover the strainability of film to a great extent, but clean used chemical agent and all membrane material is caused to a certain degree damage, Chemical cleaning has equally also shortened the actual life of film product continually.
In fact, in use the wasting phenomenon of membrane material also is the assignable cause that the film life of product is short, depreciable cost is high.In the middle of several membrane component forms such as flat sheet membrane, tubular membrane and hollow-fibre membrane, hollow-fibre membrane has obtained because loading density is big, cost is low using widely.The hollow fiber film assembly made from hollow fibre membrane component has curtain formula, bundle formula and three kinds of basic forms of pillar.Relevant doughnut curtain type film assembly can be referring to Chinese patent and patent application 00102210.5,01820629.8,03803307.0,200410098416.8,200420029295.7,200510013293.8,200510015570.9,200510116589.2,200520123501.5,200610104225.7.Relevant hollow fiber bundle formula membrane module can be referring to Chinese patent and patent application 02158708.6,02158711.6,03822704.5,200420029337.7,200420109650.1,200510049324.5,200580025651.5,200610065807.9,200620039621.1,200710056641.9.Relevant doughnut pillar membrane module can be referring to Chinese patent and patent application 99800749.8,01229169.2,01229790.9,03121949.7,200310100565.9,200420056864.7,200420056865.1,200480028264.2,200510015346.X and 200520027729.4,200610129352.2.Problem of the equal ubiquity of above-mentioned these hollow fiber film assemblies, the promptly undue loading density of pursuing, a large amount of hollow-fibre membrane silks, usually thousands of even up to ten thousand hollow-fibre membrane silk, by potting in a stiff end, this not only causes membrane module potting operation in process of production difficulty of processing big, the percent defective height, in case and part film silk fracture in the process of using, even if other most of film silks still structure are intact and have a good strainability, but because together with the film silk potting of having ruptured, film silk in can not carrying out is among a small circle changed, therefore whole intrafascicular hollow fiber film or whole membrane module just can't continue to use, and have caused unnecessary waste, have increased the depreciable cost of film product.
Summary of the invention
An object of the present invention is to provide a kind of hollow fiber film assembly, this membrane module can improve the utilization rate of hollow-fibre membrane silk and the service life of hollow fiber film assembly.
In order to realize the foregoing invention purpose, the present invention adopts following technical scheme:
The invention provides a kind of hollow fiber film assembly, comprise the hollow fiber membrane bundle of forming by the hollow-fibre membrane silk, the termination and the water producing pipe of hollow fiber membrane bundle one or both ends, it is characterized in that: described hollow-fibre membrane silk number is less than or equal to 500, the cross-sectional area sum of described hollow-fibre membrane silk accounts on the termination casting end face has the percentage of the area in hollow-fibre membrane silk zone to be less than or equal to 40%, the termination of described hollow fiber membrane bundle one or both ends refers to, and an end of hollow fiber membrane bundle has termination or two ends that the termination is all arranged.
This paper hollow-fibre membrane silk is also referred to as the film silk, and hollow fiber membrane bundle is also referred to as the film bundle.
When described hollow-fibre membrane silk number during greater than 500, if the fracture of part hollow-fibre membrane silk is arranged, even if other most of film silks still structure are intact and have a good strainability, but because together with the film silk potting of having ruptured, film silk in can not carrying out is among a small circle changed, therefore whole hollow fiber film assembly just can't normally use, so the number of hollow-fibre membrane silk can not be too big, so just can reduce unnecessary waste.And the cross-sectional area sum of hollow-fibre membrane silk accounts for has the percentage of the area in hollow-fibre membrane silk zone can not be greater than 40% on the termination casting end face.
In the research and use of traditional hollow fiber film assembly, researcher and engineers and technicians pursue the hollow-fibre membrane silk that comprises as much as possible always in a hollow fiber film assembly, the number of the hollow-fibre membrane silk that a common assembly comprises is thousands of even up to ten thousand, Duo hollow-fibre membrane silk is in the process of boundling like this, and the percentage that the cross-sectional area sum of inevitable requirement hollow-fibre membrane silk accounts for this region area is also very big.The inventor is on the basis of a large amount of research and analysis, think that the hollow fiber film assembly that satisfies following condition can overcome above-mentioned technical problem, be that hollow-fibre membrane silk number is less than or equal to 500, the cross-sectional area sum of described hollow-fibre membrane silk accounts on the termination casting end face has the percentage of the area in hollow-fibre membrane silk zone to be less than or equal to 40%.
There is hollow-fibre membrane silk zone to determine on the described termination casting end face: on the casting end face of termination by following method, line with a sealing forms a closed area, this zone can all be enclosed in all hollow-fibre membrane silks in this closed area, and requires the distance of this boundary line, closed area and nearest each hollow-fibre membrane silk to be less than or equal to 0.5mm.If it is not that the structural member of hollow-fibre membrane silk passes or other structural reason that pipeline or other are arranged in above-mentioned closed area, can form an inner no hollow-fibre membrane silk zone on termination casting end face, this area is not counted in the area that hollow-fibre membrane silk zone is arranged on the termination casting end face.The area in inner no hollow-fibre membrane silk zone is determined by following method: on the casting end face of termination, line with a sealing forms a closed area, no hollow-fibre membrane silk in this zone, but by around the hollow-fibre membrane silk surround, and require the distance of this boundary line, closed area and nearest each hollow-fibre membrane silk to be less than or equal to 0.5mm.
When film silk quantity surpasses 500, the damage of part film silk will cause the film silk of a greater number can not continue simultaneously to use, and cause unnecessary waste.When the cross-sectional area sum of described hollow-fibre membrane silk accounts for the percentage that the area in hollow-fibre membrane silk zone is arranged on the termination casting end face and surpasses 40%, film bundle inner membrance silk will be too intensive, potting operation difficulty of processing increases, the percent defective height, especially be not easy to control the shape of casting end face, and the film easy deposition of silk root and be not easy to remove when using, also stick together easily between the film silk simultaneously.As preferably, the cross-sectional area sum of described hollow-fibre membrane silk accounts for that on the termination casting end face percentage of the area in hollow-fibre membrane silk zone to be arranged be 10~40%.
In the above-mentioned hollow fiber film assembly, also comprise air inlet pipe.Air inlet pipe can be for providing aeration gas flow in the hollow fiber film assembly course of work, and aeration gas flow can effectively suppress the development that film pollutes for the hollow-fibre membrane silk provides the energy and the surperficial cross-flow of turbulent fluctuation in water.
In the above-mentioned hollow fiber film assembly, described hollow fiber membrane bundle is made up of 10~500 hollow-fibre membrane silks, and described hollow-fibre membrane silk number is preferably and is less than or equal to 400, more preferably is less than or equal to 300.The length of described hollow-fibre membrane silk can be 0.1m~3.0m, is preferably 1m~2m.When film filament length degree surpassed 3.0m, the uniformity that the film silk filters was relatively poor, and film silk effective filtration area is less, causes the waste of material equally.
In the above-mentioned hollow fiber film assembly, the cross-sectional area sum of described hollow-fibre membrane silk accounts for the percentage that the area in hollow-fibre membrane silk zone is arranged on the termination casting end face and is preferably and is less than or equal to 35%, more preferably is less than or equal to 30%.
Described hollow-fibre membrane silk can have and only have end casting sealed knot to be provided with within the termination of producing the water collecting chamber in one, and the other end can freely swing, and adopt known any way to make closed pore state, for example by using the resin adhesive liquid sealing, resin can select for use thermoplastic resin also can select thermosetting resin for use, the preferred thermosetting resin that uses, thermosetting resin can be selected epoxy resin for use, unsaturated polyester resin, resinous type such as acrylic resin, thermosetting resin preferably uses flexible resin, flexible-epoxy for example, select for use flexible resin-sealed can so that the hollow-fibre membrane silk in the process of distortion, a well buffering is arranged, be unlikely brittle fracture.Also can cast sealed knot respectively within two terminations in two ends, and have at least an inside should be provided with product water collecting chamber in two terminations.Be provided with the outside, termination of producing the water collecting chamber and should be provided with water producing pipe, producing the water collecting chamber should be connected with water producing pipe.Cast sealed knot when being provided with within the termination of producing the water collecting chamber for one when described hollow-fibre membrane silk has and only have an end, and during its work, this termination can be the top at hollow fiber membrane bundle, also can be the bottom at hollow fiber membrane bundle.During preferred use work, the termination is in the hollow fiber film assembly of hollow fiber membrane bundle bottom, can avoid when film silk lower end freely swings film silk that the rising because of the air water two-phase flow occurs the easily problem of winding mutually like this.
Among the present invention, upper end generally refers to membrane module in the water treatment course of work, and near the termination of the water surface, lower end refers near water-bed termination; In engineering reality, membrane module also may be a horizontal positioned, this moment, the termination did not then have branch up and down up and down, if those skilled in the art are according to the actual conditions needs, setting is put upside down in the termination up and down, the perhaps modification of other simple set-up mode so also is construed as and is utilizing technical scheme of the present invention.Upper end and lower end can exist simultaneously, also can have and only have one.
In the above-mentioned hollow fiber film assembly, can near or be close to the hollow fiber membrane bundle upper end or/and lower end casting end face is provided with the distribution device of band qi-emitting hole, this distribution device is communicated with air inlet pipe.As preferably, described distribution device is close to the hollow fiber membrane bundle upper end or/and the setting of lower end casting end face, when sealed knot is all cast within the termination time in the hollow fiber membrane bundle two ends, on the casting end face of the upper end of hollow fiber membrane bundle and lower end, described distribution device is set simultaneously.
The aperture of the qi-emitting hole of described distribution device is towards level, vertically up, vertically down, obliquely and oblique inferior multiple choices can be arranged, the aperture of preferred qi-emitting hole is towards horizontal direction or oblique down towards casting end face direction, more thorough for washing away of hollow-fibre membrane silk root like this, can avoid the phenomenon of film silk root deposition in the use well.
Above-mentioned arbitrary hollow fiber film assembly is all cast sealed knot within the termination time when the hollow fiber membrane bundle two ends, the distribution device of band qi-emitting hole can all be set on the casting end face of two terminations, and these two distribution devices is communicated with by a hollow tube.The effect of hollow tube comprises: the first, supply with up and down two distribution devices with air-flow, make hollow fiber membrane bundle up and down the root at two ends can directly be purged by aeration gas flow and wash away, to prevent film silk root generation deposition; The second, up and down two terminations couple together, and the length of flexible pipe is slightly less than the length of hollow-fibre membrane silk, and the pulling force when playing the gravity of bearing lower end and swing is broken to avoid hollow-fibre membrane silk load.
In the described termination one or two can be provided with air inlet pipe.Air inlet pipe and water producing pipe be can be provided with simultaneously in described arbitrary termination, air inlet pipe or water producing pipe perhaps only are provided with.The quantity of water producing pipe or air inlet pipe can be selected according to the engineering actual conditions, an air inlet pipe or a water producing pipe both can have been selected, also can select two or more air inlet pipe, perhaps select two or more water producing pipes, perhaps select two or more air inlet pipe and water producing pipe simultaneously.Described air inlet pipe and water producing pipe can be rigidity, also can be flexible, preferred flexible, its material can be silicon rubber, fluorubber, soft PVC, polyurethane etc.
Above-mentioned hollow fiber film assembly can adopt known arbitrary mode to link to each other with fixture by arbitrary termination.Described upper end also can link to each other with fixture by the mode that soft rope or flexible pipe etc. are flexible coupling or/and lower end can pass through dismountable hardwired modes such as socket joint, screw thread, loose joint links to each other with fixture.As preferably, described upper end or/and lower end link to each other with fixture by the mode that soft rope or flexible pipe etc. are flexible coupling.Soft rope can be corrosion resistant rope, steel wire or spring etc.Soft rope makes membrane module be in overhang in liquid to be filtered, can swing be arranged with current.When upper end is provided with air inlet pipe or water producing pipe and air inlet pipe or water producing pipe and is flexible pipe, also can membrane module be suspended on the fixture by air inlet pipe or water producing pipe.
All cast sealed knot within the termination time when the hollow fiber membrane bundle two ends, between two terminations, tube connector can be set, connect two terminations.
Described tube connector connects into an integral body with upper end and lower end, and its length can be identical with hollow fiber membrane bundle, also can slightly be shorter than the film bundle.As preferably, the length of described tube connector is slightly less than the length of hollow fiber membrane bundle.Can prevent like this that the termination amplitude of fluctuation is excessive and make the film filament length time stressed, film is done up protective effect.
The diameter range of described air inlet pipe, water producing pipe and tube connector is 1mm~50mm, preferred 5mm~20mm.
Described hollow-fibre membrane silk is a kind of doughnut that has micropore, and the material of making the hollow-fibre membrane silk can be selected from materials such as Kynoar, polyethylene, polypropylene, polyether sulfone.At first by using casting resins such as epoxy resin, polyurethane to carry out the end-blocking casting, re-use flexible resins such as silicon rubber, polyurethane carries out second casting to hollow-fibre membrane silk root to the hollow-fibre membrane silk, to reduce the probability of film silk root fracture.As preferably, the material of described hollow-fibre membrane silk is a Kynoar.The average membrane pore size of described hollow-fibre membrane silk is 0.01 μ m~5 μ m.
When sealed knot is all cast within the termination time in the hollow fiber membrane bundle two ends, the length of described hollow fiber membrane bundle can and up and down the distance between two terminations equate, also can be slightly larger than this distance.As preferably, the length of described hollow fiber membrane bundle is greater than the distance between two terminations up and down.
All cast sealed knot within the termination time when the hollow fiber membrane bundle two ends, and the shape of described upper end and lower end can be identical, also can be different.
Described upper end is or/and the lower end monnolithic case can be cylinder, cone, basin shape, shape such as cup-shaped.As preferably, described upper end is or/and the monnolithic case of lower end is a basin shape or cup-shaped.
Hollow fiber film assembly of the present invention compared with prior art, the cross-sectional area sum of hollow-fibre membrane silk number and hollow-fibre membrane silk accounts for the percentage that the area in hollow-fibre membrane silk zone is arranged on the termination casting end face, the two collocation rationally, can either keep suitable loading density, guarantee space availability ratio, can improve the stock utilization of hollow-fibre membrane silk again, prolong the service life of film product on the whole.When fracture of part film silk or forfeiture water-yielding capacity in use appear in hollow fiber film assembly of the present invention, it can be disassembled and be changed, be unlikely the waste that causes material like this.
In use and installation process, hollow fiber film assembly of the present invention can be connected by the various modes that are easy to dismantle, can better bring into play advantage of the present invention like this.Can utilize above-mentioned hollow fiber film assembly, a kind of hollow-fiber membrane bioreactor or water treatment facilities are made in combination.
The specific embodiment
Below in conjunction with drawings and Examples, technical scheme of the present invention is described in further detail.
Embodiment 1
As shown in Figure 1; a kind of hollow fiber film assembly; comprise the hollow fiber membrane bundle of forming by 240 hollow-fibre membrane silks 12; the average pore size that is used for the micropore by liquid of hollow-fibre membrane silk 1 is 0.01 μ m (micron); the external diameter of hollow-fibre membrane silk is 1.2mm (millimeter), and material is a Kynoar, and two ends come together among upper end 3 and the lower end 4 with the epoxy resin casting; and with polyurethane it is carried out second casting, so that film silk root is protected.The monnolithic case of upper end 3 and lower end 4 is cup-shaped, and diameter of a circle suitable for reading is 50mm.Be the perforate state in the product water collecting chamber 5 of hollow-fibre membrane silk 1 in upper end 3, in lower end 4, be closed pore state, upper end 3 is provided with the water producing pipe 6 that external diameter is Φ 8mm, lower end 4 is provided with the air inlet pipe 7 that external diameter is Φ 8mm, two terminations are that the tube connector 8 of Φ 6mm connects into an integral body by external diameter, and hollow-fibre membrane silk 1 evenly distributes round tube connector 8.Water producing pipe 6, air inlet pipe 7 and tube connector 8 are the hollow plastic flexible pipe.Tube connector 8 is offering qi-emitting hole near film silk root, and the opening of qi-emitting hole is towards the root of hollow-fibre membrane silk.Tube connector 8 passes lower end 4 and is connected with air inlet pipe 7, and 6 of water producing pipes are connected with product water collecting chamber 5 in the upper end 3.
The average length of hollow fiber membrane bundle 2 is 1.2m (rice), and upper end 3 is 1.12m together with the total length of tube connector 8 and lower end 4.The length of water producing pipe 6 and air inlet pipe 7 is 150mm.The exit branch that water producing pipe 6 and is positioned at the membrane module top is connected, the aeration arm that air inlet pipe 7 and is positioned at the membrane module below is connected, the vertical range of exit branch and aeration arm is 1.3m, makes whole membrane module that the space of the suspension activity of 120mm up and down can be arranged.
Exit branch and one can provide the suction hose of the water pump of negative pressure to be connected, and water to be clean enters film silk inside through the micropore on hollow-fibre membrane silk 1 wall, and confluxes into product water collecting chamber 5, flows into exit branch through water producing pipe 6 again, extracts out by water pump at last.The aeration arm is connected with a source of the gas, and the compressed air that source of the gas provides enters air inlet pipe 7 through the aeration arm, and the qi-emitting hole on the distribution device of tube connector 8 one or both ends comes out directly to purge the root of hollow-fibre membrane silk again.
Be illustrated in figure 3 as the schematic diagram of the lower end of hollow fiber film assembly among Fig. 1.As can be seen, the closed area that is formed by closed line 9 is enclosed in all hollow-fibre membrane silks in this closed area from the figure, and the distance of boundary line, closed area and nearest each hollow-fibre membrane silk is less than 0.5mm.This closed area is a circle that diameter is 46mm, when the cross-sectional area sum of calculating hollow-fibre membrane silk accounts for the percentage of the area that hollow-fibre membrane silk zone is arranged on the termination casting end face, need deduct the area in the zone of inner no hollow-fibre membrane silk, promptly deduct the aperture area of air inlet pipe on end face, the aperture area of air inlet pipe on end face is that diameter is the circle of 8mm in the present embodiment.Can obtain thus: the cross-sectional area sum of 240 hollow-fibre membrane silks accounts for that on the termination casting end face percentage of the area in hollow-fibre membrane silk zone to be arranged be 16.8%.
The water producing pipe 6 of the hollow fiber film assembly that several are above-mentioned, air inlet pipe 7 are connected in parallel to exit branch, aeration arm respectively, form the membrane module unit of a matrix form thus, as shown in Figure 4.Embodiment 2
As shown in Figure 2, a kind of hollow fiber film assembly comprises the hollow fiber membrane bundle of being made up of 300 hollow-fibre membrane silks 12, and the average pore size that is used for the micropore by liquid of hollow-fibre membrane silk 1 is 0.1 μ m, the external diameter of hollow-fibre membrane silk is 1.2mm, and material is a Kynoar.Hollow fiber membrane bundle 2 upper ends can freely swing, and every film silk all is closed pore state, utilizes the flexible-epoxy sealed knot, and the lower end comes together among the lower end 4 with the epoxy resin casting, and with polyurethane it are carried out second casting, so that film silk root is protected.The monnolithic case of lower end 4 is cup-shaped, and diameter of a circle suitable for reading is 62mm, and the round platform of a projection is arranged on the casting end face, and the outside diameter circle of round platform is 25mm.Be the perforate state in the product water collecting chamber 5 of hollow-fibre membrane silk 1 in lower end 4, the external diameter of being located at lower end 4 outsides is that the water producing pipe 6 of Φ 8mm is connected with product water collecting chamber 5.Upper end 3 is not set, air inlet pipe 7 and tube connector 8 in this embodiment.
The average length of hollow fiber membrane bundle 2 is 1.2m, and the total length of lower end 4 is 50mm.The length of water producing pipe 6 is 150mm.The exit branch that water producing pipe 6 and is positioned at the membrane module below is connected.
Exit branch and one can provide the suction hose of the water pump of negative pressure to be connected, and water to be clean enters film silk inside through the micropore on hollow-fibre membrane silk 1 wall, and confluxes into product water collecting chamber 5, flows into exit branch through water producing pipe 6 again, extracts out by water pump at last.
Be illustrated in figure 5 as the schematic diagram of the lower end of the described hollow fiber film assembly of present embodiment.When determining the closed area, the distance of the boundary line of closed area and nearest each hollow-fibre membrane silk is less than 0.5mm.From the figure as can be seen, the closed area that surrounds the hollow-fibre membrane silk can not be in a plane, when the cross-sectional area sum of calculating the hollow-fibre membrane silk accounts for the percentage of the area that hollow-fibre membrane silk zone is arranged on the termination casting end face, this closed area need be projected on the plane vertical, calculate then with the hollow-fibre membrane silk.It in the present embodiment circle that diameter is 58mm, need to deduct the area in the zone of inner no hollow-fibre membrane silk in addition, promptly deduct the shared area of casting end face bossing, casting end face bossing does not have the hollow-fibre membrane silk in the present embodiment, and shared area is that diameter is the circle of 25mm.Can obtain thus: the cross-sectional area sum of 300 hollow-fibre membrane silks accounts for that on the termination casting end face percentage of the area in hollow-fibre membrane silk zone to be arranged be 15.8%.These computational methods are equivalent to will be among Fig. 5 to be cut off perpendicular to the paper direction at the A-A place, and the cross-sectional area sum of calculating the hollow-fibre membrane silk according to the method for embodiment 1 accounts for the percentage that the area in hollow-fibre membrane silk zone is arranged on the termination casting end face then.
The water producing pipe 6 of the hollow fiber film assembly that several are above-mentioned is connected in parallel to exit branch respectively, forms the membrane module unit of a matrix form thus.
More than hollow fiber film assembly provided by the present invention is described in detail.Used specific embodiment in this specification principle of the present invention and embodiment have been set forth, for one of ordinary skill in the art, according to the thought of the present invention part that may in implementation process, can change in specific embodiments and applications.Therefore, the content of this specification record should not be construed as limitation of the present invention.