Summary of the invention
The object of the present invention is to provide the casting technique of the solid manganese steel frog foundry goods of a kind of long-life, grain refining, solve problems such as the solid manganese steel frog casting crystalline grain is thick, shrinkage cavity, micro-crack, produced the solid manganese steel frog of grain refinement, intensity height, long service life; Adopt advanced refining techniques and alloying process to improve material property, railway solid manganese steel frog mechanical property has had large increase, σ b 〉=910MPa, ak 〉=190J/cm
2, δ 〉=46%.
Technical scheme of the present invention is:
The present invention has developed the casting technique of a kind of long-life, grain refining solid manganese steel frog, comprises the steps:
1) rising head adopts insulated feeder, and the rising head ratio of height to diameter is (2.5~3.5): 1.0;
2) molten steel high temperature is come out of the stove, and tapping temperature is 1600 ± 25 ℃, carries out blowing argon gas refining outside the stove in the refining bag, strict control phosphorus, sulfur content, P≤0.025%, S≤0.010%;
3) carry out microalloying in the refining bag, add molybdenum, niobium, vanadium, titanium, addition is respectively 0.10~0.05% of a molten steel weight;
4) the interior microalloying temperature of refining bag is 1560 ± 20 ℃, and pouring temperature is 1500 ± 25 ℃, and cast is applying argon gas in die cavity before, pours into a mould under argon shield;
5) adopt hot shake-out technology, after casting pouring finished, foundry goods solidified shake out in the 20~60min of back fully; And heat cuts rising head, and the cutting after heat is fed into heat treatment kiln, carries out homogenising and handles, and homogenization temperature is 1050 ± 10 ℃, and temperature retention time is 4~6h.
Described step 1), insulated feeder are column type, insulated feeder wall thickness 〉=25mm.
Described step 2), in the refining process, argon pressure is 0.1~0.5MPa, pressure pipeline internal diameter Φ 10~20mm, and 0.5~1 minute/ton molten steel of argon blowing time is fed the silk amount and is 0.3~1% of pour steel gross weight.
Described step 3), the alloy that adds in the refining bag are common molybdenum-iron, ferro-niobium, vanadium iron and ferrotianium.
The alloy size of adding in the described step 3), refining bag should be controlled at the block structure within 15~25mm.
Described step 4), alloy should be baked to 120~150 ℃ before adding the refining bag to, baking 20~40min.
Described step 4) during alloying, should evenly be placed on alloy the middle and lower part of refining bag, forbids and will throw still alloy.
Described step 5) adopts hot shake-out technology, and the foundry goods body temperature is not less than 700 ℃ during shake out, and heat is cut the rising head temperature and is not less than 500 ℃.
The present invention is applicable to below 2 tons, the manufacture process of the solid manganese steel frog of various models and specification.
The present invention has following beneficial effect:
1. the present invention comes out of the stove by high temperature, has reduced gas and the field trash in the molten metal by technology such as Argon, hello silks, makes pureization of molten metal, significantly improves the quality of solid manganese steel frog.
2. the present invention is by carrying out alloying to potassium steel, significantly refinement the crystal grain of high manganese steel casting, reduce the field trash size simultaneously, make field trash be disperse and distribute, help simultaneously suppressing separating out of grain boundary carbide, significantly improved casting quality.
3. the present invention pours into a mould under argon shield by applying argon gas in the die cavity, has significantly alleviated the secondary oxidation of solid manganese steel frog, alleviates the secondary inclusion thing in the foundry goods greatly.
4. solid manganese steel frog is because crystal grain is thick, and shrinkage cavity, casting flaw such as loose in use, are easy to wearing and tearing, and generally speaking, the goods of solid manganese steel frog is no more than 1.2 hundred million tons by gross weight.Adopt the solid manganese steel frog goods of grain refining of the present invention can reach 200,000,000 tons by gross weight.Therefore, this technology has obtained railway user's abundant affirmation.
The specific embodiment
A kind of long-life of the present invention, the concrete operations of grain refining potassium steel block cast process for manufacturing cast article are as follows:
1) material is prepared: common molybdenum-iron, ferro-niobium, vanadium iron and ferrotianium, alloy size are in the block structure of 15~25mm, and alloy should be baked to 120~150 ℃ before adding the refining bag to, baking 20~40min.
2) equipment is prepared: the special-purpose microalloy of throwing in is thrown instrument and roasting plant.
3) molten steel is smelted: molten steel high temperature is come out of the stove, and tapping temperature is 1600 ± 25 ℃, carries out blowing argon gas refining outside the stove in the refining bag, strict control phosphorus, sulfur content, P≤0.025%, S≤0.010%.
In the refining process, argon pressure is 0.1~0.5MPa, pressure pipeline internal diameter Φ 10~20mm, and 0.5~1 minute/ton molten steel of argon blowing time is fed the silk amount and is 0.3~1% of pour steel gross weight, feeds silk and is refining Si-Ca silk commonly used, and its effect is deoxidation, refining.
4) strict control pouring temperature, pouring temperature is 1500 ± 25 ℃.High manganese steel frog is when selecting pouring temperature, and the short and small fusion cast frog pouring temperature of size is taken off limit, larger-size complicated fusion cast frog pouring temperature capping.
5) microalloy addition: when refining, add element wt content and be 0.05~0.1%, 1560 ± 20 ℃ of refining temperatures.
6) microalloy adding method: use to throw funnel alloy evenly is placed on the middle and lower part of refining bag, evenly place, forbid and to throw still alloy.
7) foundry goods is handled: adopt hot shake-out technology, in order to reduce the tension of foundry goods, casting temperature is not less than 700 ℃ during shake out.Adopt Methods of OFC-A to carry out heat and cut rising head, cutting temperature is not less than 500 ℃, and the cutting after heat is fed into heat treatment kiln, carries out homogenising and handles, and homogenization temperature is 1050 ± 10 ℃, and temperature retention time is 4~6h.
Below in conjunction with drawings and Examples in detail the present invention is described in detail.
Embodiment 1
The molten steel tapping temperature is 1590 ℃, 10.1 tons of casting of molten metal weight, in the refining bag, carry out refining, in the refining process, argon pressure is 0.2MPa, pressure pipeline internal diameter Φ 10mm, 1 minute/ton molten steel of argon blowing time, feed the silk amount and be 0.4% of pour steel gross weight, feed silk and be refining Si-Ca silk commonly used.Remove to be mingled with and then carry out microalloying under 1550 ℃ of temperature, add molybdenum, niobium, vanadium, titanium, the addition element weight ratio is respectively 0.05%.5 of railway frogs of cast, railway frog casting technique schematic diagram as shown in Figure 1, cast gate 1 and the cross gate 13 that is communicated with cast gate 1 are positioned at foundry goods one side, need the position of feeding that insulated feeder 2,3,4,5,6,7,8,9,10,11,12 is set in cast top.1490 ℃ of pouring temperatures, cast be applying argon gas in die cavity before, pours into a mould under argon shield, and the employing ratio of height to diameter is 2.5: 1 a insulated feeder, insulated feeder wall thickness 30mm, and riser height is 250mm.Foundry goods adopts hot shake-out technology, and foundry goods solidifies shake out in the 20~60min of back fully, carries out heat with Methods of OFC-A and cuts rising head, heat is cut 500 ℃ of rising head temperature, and the cutting after heat is fed into heat treatment kiln, carries out homogenising and handles, homogenization temperature is 1050 ℃, and temperature retention time is 4.5h.Mainly adopt high temperature to come out of the stove, helped the alloying and the refinery practice of molten metal.Utilize the computer simulation means reasonably to design rising head shape and rising head position.Carry out microalloying in the refining bag, the refinement casting crystalline grain reduces field trash size and disperse field trash and distributes, and improves casting quality.The high manganese steel frog foundry goods has several places sand holes at gate end, and has pore, but these defectives are all within the range of work of foundry goods, and genus can be removed defective.Foundry goods after the processing does not have defective through flaw detection, and casting quality is good.
In the present embodiment, the alloy ultimate constituent is as follows: C:1.1%; Si:0.46%; Mn:12.8%; Mo:0.05%; Nb:0.051%; V:0.053%:Ti:0.052%; S:0.008%; P:0.022%; Al:0.012%; All the other are Fe.
Among the present invention, adopt the computer simulation means reasonably to design rising head shape and rising head position." computer modeling technique " can be referring to Chinese invention patent application (publication number: a kind of mold filling process of casting analogy method of CN 1388444A) mentioning.And, Chinese invention patent application (publication number: a kind of high manganese steel casting grain refinement casting technique of 200810011501.4) mentioning.
The present invention adopts microalloying and refinery practice, and solid manganese steel frog foundry goods field trash size significantly reduces, and pureization of foundry goods significantly improves, and the railway frog field trash that Fig. 2 produces for common process distributes, and the field trash size is big, skewness.The high manganese steel frog field trash distribution situation of Fig. 3 for adopting the present invention to produce, field trash is tiny, and disperse distributes.The crystallite dimension of foundry goods significantly reduces in addition, uniform crystal particles.Thereby the performance of high manganese steel casting is significantly improved, σ b 〉=910MPa, ak 〉=190J/cm
2, δ 〉=46%.The railway frog casting crystalline grain pattern that Fig. 4 (a)-Fig. 4 (b) produces for common process, crystal grain is thick.The grain refining casting crystalline grain pattern of Fig. 5 (a)-Fig. 5 (b) for adopting the present invention to produce, crystal grain is tiny, even.
Embodiment 2
The molten steel tapping temperature is 1600 ℃, 10.3 tons of casting of molten metal weight, in the refining bag, carry out refining, in the refining process, argon pressure is 0.3MPa, pressure pipeline internal diameter Φ 15mm, 0.6 minute/ton molten steel of argon blowing time, feed the silk amount and be 0.5% of pour steel gross weight, feed silk and be refining Si-Ca silk commonly used.Remove to be mingled with and then carry out microalloying under 1560 ℃ of temperature, add molybdenum, niobium, vanadium, titanium, the addition element weight ratio is respectively 0.08%.5 of cast railway frogs, railway frog casting technique schematic diagram as shown in Figure 1.1500 ℃ of pouring temperatures, cast be applying argon gas in die cavity before, pours into a mould under argon shield, and the employing ratio of height to diameter is 3: 1 a insulated feeder, insulated feeder wall thickness 35mm, riser height 220mm.Foundry goods adopts hot shake-out technology, and foundry goods solidifies shake out in the 20~60min of back fully, carries out heat with Methods of OFC-A and cuts rising head, heat is cut 550 ℃ of rising head temperature, and the cutting after heat is fed into heat treatment kiln, carries out homogenising and handles, homogenization temperature is 1040 ℃, and temperature retention time is 5h.Mainly adopt high temperature to come out of the stove, helped the alloying and the refinery practice of molten metal.Utilize the computer simulation means reasonably to design rising head shape and rising head position.Carry out microalloying in the refining bag, the refinement casting crystalline grain reduces field trash size and disperse field trash and distributes, and improves casting quality.The high manganese steel frog foundry goods has several places sand holes at gate end and end, but these defectives are all within the range of work of foundry goods, and genus can be removed defective.
In the present embodiment, the alloy ultimate constituent is as follows: C:1.05%; Si:0.44%; Mn:13.2%; Mo:0.078%; Nb:0.082%; V:0.083%:Ti:0.084%; S:0.007%; P:0.021%; Al:0.013%; All the other are Fe.
Embodiment 3
The molten steel tapping temperature is 1610 ℃, 10.2 tons of casting of molten metal weight, in the refining bag, carry out refining, in the refining process, argon pressure is 0.5MPa, pressure pipeline internal diameter Φ 20mm, 0.5 minute/ton molten steel of argon blowing time, feed the silk amount and be 1% of pour steel gross weight, feed silk and be refining Si-Ca silk commonly used.Remove to be mingled with and then carry out microalloying under 1570 ℃ of temperature, add molybdenum, niobium, vanadium, titanium, the addition element weight ratio is respectively 0.1%.5 of cast railway frogs, railway frog casting technique schematic diagram as shown in Figure 1.1480 ℃ of pouring temperatures, cast be applying argon gas in die cavity before, pours into a mould under argon shield, and the employing ratio of height to diameter is 3.5: 1 a insulated feeder, insulated feeder wall thickness 40mm, riser height 230mm.Foundry goods adopts hot shake-out technology, and foundry goods solidifies shake out in the 20~60min of back fully, carries out heat with Methods of OFC-A and cuts rising head, heat is cut 530 ℃ of rising head temperature, and the cutting after heat is fed into heat treatment kiln, carries out homogenising and handles, homogenization temperature is 1060 ℃, and temperature retention time is 4h.Mainly adopt high temperature to come out of the stove, helped the alloying and the refinery practice of molten metal.Utilize the computer simulation means reasonably to design rising head shape and rising head position.Carry out microalloying in the refining bag, the refinement casting crystalline grain reduces field trash size and disperse field trash and distributes, and improves casting quality.High manganese steel frog cast(ing) surface, subsurface all are mingled with less than finding, surface quality of continuous castings is good.Foundry goods is not found defective through flaw detection, and casting quality is intact.
In the present embodiment, the alloy ultimate constituent is as follows: C:1.04%; Si:0.45%; Mn:13.2%; Mo:0.09%; Nb:0.10%; V:0.12%:Ti:0.11%; S:0.009%; P:0.021%; Al:0.013%; All the other are Fe.
The course of work of the present invention and result:
In smelting process, carry out external refining and alloying because the present invention adopts, reduced being mingled with and gas in the molten metal, in casting process, carried out argon shield, reduced the secondary inclusion thing in the foundry goods, guaranteed the pure of molten metal; Utilize the rising head of computer modeling technique design to play the feeding effect effectively, eliminated defectives such as the shrinkage cavity in the foundry goods, crackle, produced high-performance foundry goods, see Fig. 6 (a)-Fig. 6 (b) without any defective.