CN101725843B - System and method for configuring LED backlight module with high color saturation - Google Patents
System and method for configuring LED backlight module with high color saturation Download PDFInfo
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Abstract
Description
技术领域 technical field
本发明涉及一种发光二极管背光模块,尤其涉及一种具有高色彩饱和度的发光二极管背光模块的配置系统与方法。The invention relates to a light-emitting diode backlight module, in particular to a configuration system and method for a light-emitting diode backlight module with high color saturation.
背景技术 Background technique
发光二极管(Light Emitting Diode;简称LED),是一种可将电能转化为光能的电子零件,并同时具备二极管的特性。一般给予直流电时,发光二极管会稳定地发光,但如果接上交流电,发光二极管会呈现闪烁的形态,闪烁的频率依据输入交流电的频率而定。发光二极管的发光原理是外加电压,使得电子与空穴在半导体内结合后,将能量以光的形式释放。Light Emitting Diode (LED for short) is an electronic component that can convert electrical energy into light energy, and also has the characteristics of a diode. Generally, when DC power is supplied, the LEDs will emit light steadily, but if AC power is connected, the LEDs will flash, and the frequency of the flashing depends on the frequency of the input AC power. The light-emitting principle of light-emitting diodes is to apply an external voltage to make electrons and holes combine in the semiconductor to release energy in the form of light.
目前发光二极管芯片的组成主要包含三族砷化物、三族磷化物、三族氮化物或是II-VI族的半导体化合物等。伴随着发光二极管芯片制造材料的不同,产生出来的光子拥有的能量也不同,因此通过制造材料来控制发光二极管片发光的波长,进而生产出不同光谱与颜色的各种发光二极管芯片。目前全球产业发展出不同种类的发光二极管芯片已能够发射出从红外线到蓝色光之间不同波长的光线,而紫色至紫外线的发光二极管芯片的技术也正在成熟中。上述的发光二极管主要重点是在单色光,或是单一频率的发光二极管。白光发光二极管的发光频谱,不再是集中在某一单色光上,而是在可见光的频谱中有一个分布。目前用来形成白光发光二极管的组合主要分为多芯片型及单芯片型两种类型。At present, the composition of the light emitting diode chip mainly includes group III arsenide, group III phosphide, group III nitride or semiconductor compound of group II-VI. With the different manufacturing materials of LED chips, the energy of photons produced is also different. Therefore, the wavelength of light-emitting diode chips is controlled by manufacturing materials, and various LED chips with different spectra and colors can be produced. At present, the global industry has developed different types of light-emitting diode chips that can emit light of different wavelengths from infrared to blue light, and the technology of light-emitting diode chips from purple to ultraviolet light is also maturing. The main focus of the above LEDs is on monochromatic light, or LEDs of a single frequency. The light-emitting spectrum of white light-emitting diodes is no longer concentrated on a certain monochromatic light, but has a distribution in the spectrum of visible light. At present, the combinations used to form white light emitting diodes are mainly divided into two types: multi-chip type and single-chip type.
多芯片类型以红色、绿色及蓝色三色的发光二极管芯片,借助透镜混合此三种光,进而产生我们所见的白光。其优点为高发光率及光色可调,缺点为须三种芯片,各芯片间有个别电路设计且三种芯片的衰减速率及寿命不尽相同,难以控制白光发光二极管的寿命。The multi-chip type uses red, green and blue light-emitting diode chips to mix the three kinds of light with the help of a lens to produce the white light we see. Its advantages are high luminous efficiency and adjustable light color. The disadvantage is that three types of chips are required, each chip has its own circuit design, and the attenuation rate and lifespan of the three chips are not the same. It is difficult to control the lifespan of white light emitting diodes.
另外,以单芯片类型产生白光则可分为三种方式。第一种方式,也是主流的方式,以蓝色发光二极管芯片照射黄色荧光粉,将荧光粉激发而发出白光。这样的产品在调整发光二极管的CIE值时,只需选对蓝光发光二极管的波长与黄色荧光粉的激发频谱后,只要调整蓝光发光二极管的发光强度与黄色荧光粉的浓度即可。这样的白光发光二极管所产生的光谱,红色区域的光度太弱而导致平均演色系数(General Color Rendering Index;Ra)值偏低。例如,将这种产品应用在背光源时,则显示出来的图案往往没有红色。因此,目前高演色性白光发光二极管成为现阶段各界追求的方向。In addition, there are three ways to generate white light in a single-chip type. The first way, which is also the mainstream way, is to irradiate yellow phosphor powder with a blue light-emitting diode chip to excite the phosphor powder to emit white light. For such products, when adjusting the CIE value of the light-emitting diode, it is only necessary to select the wavelength of the blue light-emitting diode and the excitation spectrum of the yellow phosphor, and then adjust the luminous intensity of the blue light-emitting diode and the concentration of the yellow phosphor. In the spectrum generated by such a white light emitting diode, the luminosity in the red region is too weak, resulting in a low average color rendering coefficient (General Color Rendering Index; Ra). For example, when this product is applied to a backlight, the displayed pattern often has no red color. Therefore, white light-emitting diodes with high color rendering have become the direction pursued by all walks of life at this stage.
为了弥补红色区域的光度,后续衍生以蓝色发光二极管芯片照射绿色及红色荧光粉或以蓝色发光二极管芯片照射绿色及黄色荧光粉产生白光提高平均演色系数为第二种方式。第三种方式则以紫外光发光二极管芯片照射绿色、红色及蓝色三种荧光粉产生白光。In order to make up for the luminosity in the red area, the second way is to irradiate green and red phosphors with blue LED chips or irradiate green and yellow phosphors with blue LED chips to generate white light and improve the average color rendering coefficient. The third way is to irradiate green, red and blue three kinds of phosphors with ultraviolet light-emitting diode chips to generate white light.
在上述的方式中,想要达成高色彩饱和度发光二极管背光模块的制作方式可为增加红色的荧光粉或是使用两种以上的荧光粉等。然而,当使用两种荧光粉混光让发光二极管产生特定的CIE值的光源时,总共有三种参数需要同时进行调整,也就是发光二极管的发光强度与两个荧光粉的浓度。为了提升使用发光二极管作为背光源的色彩饱和度,需要进行多次的尝试错误(trial-and-error)的方式去调整不同的荧光粉之间的浓度比例以及蓝光发光二极管的发光强度。In the above method, the LED backlight module that wants to achieve high color saturation can be manufactured by adding red phosphor or using more than two phosphors. However, when two kinds of phosphors are used to mix light to make the light emitting diode produce a light source with a specific CIE value, there are a total of three parameters that need to be adjusted at the same time, that is, the luminous intensity of the light emitting diode and the concentration of the two phosphors. In order to improve the color saturation of using the LED as the backlight source, several trial-and-error methods are required to adjust the concentration ratio of different phosphors and the luminous intensity of the blue LED.
另外,发光二极管的发光频谱会与温度有关。当所谓的接合温度(junctiontemperature)愈高,发光二极管的发光频谱的峰値波长也会跟着向长波长漂移。随着发光二极管的操作时间增加,元件的温度也会跟着增加。因此在长时间的操作下,发光二极管的发光频率也会跟着改变。另外,发光二极管的制作过程会有频谱的分布因而会对发光二极管进行分区段(bin),这会大幅增加发光二极管的制造成本。In addition, the light emission spectrum of the light emitting diode will be related to the temperature. When the so-called junction temperature is higher, the peak wavelength of the light emitting spectrum of the light emitting diode will also shift to longer wavelength. As the operating time of the LED increases, the temperature of the element also increases. Therefore, under long-term operation, the light-emitting frequency of the light-emitting diode will also change accordingly. In addition, the manufacturing process of the LEDs will have spectrum distribution, so the LEDs will be binned, which will greatly increase the manufacturing cost of the LEDs.
美国专利公告号US2006/0290624,主要是针对这个问题进行解决。该项技术的方式是先针对三原色的其中一个颜色进行校调,例如针对绿色,至少会提供两个发光二极管,其中一个发光二极管波长比绿光稍微高,另一个发光二极管波长比绿光稍微低。然后使用控制电路使得两个发光二极管混光后可以得到所需要的正确的绿光的波长。当操作的时间增加后,两个发光二极管的发光频谱有可能改变,这时的传感器如果检测出激发频谱的改变,则由控制电路会控制两个发光二极管的发光强度使得最终的混光频谱仍然维持不变。当三原色的其中一个颜色可以进行调整,则三原色的发光二极管都可以分别进行调整。The US Patent Publication No. US2006/0290624 mainly aims to solve this problem. The method of this technology is to calibrate one of the three primary colors first. For example, for green, at least two light-emitting diodes will be provided, one of which has a slightly higher wavelength than green light, and the other light-emitting diode has a slightly lower wavelength than green light. . Then use the control circuit to make the two light-emitting diodes mix the light to get the correct wavelength of green light required. When the operating time increases, the luminous spectrum of the two LEDs may change. If the sensor detects the change of the excitation spectrum, the control circuit will control the luminous intensity of the two LEDs so that the final mixed light spectrum remains the same. stay the same. When one of the three primary colors can be adjusted, the light-emitting diodes of the three primary colors can be adjusted respectively.
整个技术在理论上是可行的,但是在商业上这样的设计会大幅增加制作成本。首先是针对三原色就需要三个控制电路以及三个传感器。另外,每个颜色的发光二极管会需要至少两种发光二极管。三原色的发光二极管就需要六种发光二极管来进行校调,这还会大幅增加发光二极管的制造与管理的成本。再者,每个发光二极管的寿命不相同的问题也会再次增加产品在寿命上的问题。The whole technology is theoretically feasible, but commercially such a design will greatly increase the production cost. First of all, three control circuits and three sensors are required for the three primary colors. Additionally, at least two types of LEDs would be required for each color LED. The LEDs of three primary colors need six kinds of LEDs to be calibrated, which will greatly increase the cost of manufacturing and managing the LEDs. Furthermore, the problem that the lifetime of each light-emitting diode is not the same will increase the problem of the lifetime of the product again.
另外一种方式是使用发光二极管来激发荧光粉发光。荧光粉相对于使用三原色的发光二极管而言有下面的优势。当发光二极管的发光频谱改变时,对于荧光粉而言只是吸收光谱的改变。只要发光二极管的激发光谱仍然落在荧光粉的吸收光谱,则荧光粉的激发光谱就不会跟着改变。似乎,使用荧光粉是很好的选择。Another way is to use light-emitting diodes to excite phosphors to emit light. Phosphor powder has the following advantages over light-emitting diodes using three primary colors. When the emission spectrum of the light-emitting diode changes, only the absorption spectrum changes for the phosphor. As long as the excitation spectrum of the light-emitting diode still falls within the absorption spectrum of the phosphor, the excitation spectrum of the phosphor will not change accordingly. It seems that using phosphor is a good choice.
在台湾专利公告号200627678中已经提到使用紫外光或是紫光的发光二极管进行激发三原色荧光粉。这样的方式可以大幅增加发光二极管光源的演色性以及作为液晶显示器的背光时,可以提供较佳的NTSC的色度。In Taiwan Patent Publication No. 200627678, it has been mentioned that ultraviolet light or purple light emitting diodes are used to excite three primary color phosphors. Such a method can greatly increase the color rendering of the LED light source and provide better NTSC chromaticity when used as a backlight of a liquid crystal display.
台湾公告号200830508,提出使用红光的荧光粉增加NTSC,使用的红色荧光粉为CaAlSiN3:Eu,绿色荧光粉(BaxSr1-x)2SiO4:Eu(x≧0.5)。Taiwan announcement number 200830508 proposes to use red phosphor to increase NTSC. The red phosphor used is CaAlSiN 3 : Eu, and the green phosphor (Ba x Sr 1-x ) 2 SiO 4 : Eu (x≧0.5).
上述的方式皆有提到使用多重的荧光粉提升发光二极管的NTSC。然而,有几点问题需要解决。第一,荧光粉的调配比例,多是采用尝试错误的方式,这会增加不少的研发时间;第二,各家的彩色滤镜的滤光光谱并不相同,对于发光二极管的制造商而言,需要不同的荧光粉的调配比例才会提升色彩饱和度,这会增加更多的尝试错误的时间。The above-mentioned methods all mention the use of multiple phosphors to enhance the NTSC of the light-emitting diode. However, there are a few issues that need to be addressed. First, the mixing ratio of phosphor powder is mostly a trial and error method, which will increase a lot of research and development time; second, the filter spectrum of each color filter is not the same, for LED manufacturers In other words, different phosphor ratios are required to improve color saturation, which will add more trial and error time.
当市面上开发出来的荧光粉种类愈来愈多的时候,或是希望使用两种以上的荧光粉进行混光,调配不同种类的荧光粉而达到高色彩饱和度发光二极管背光模块的开发时间也愈来愈长。对于产品的上市而言无疑是相当大的挑战。When more and more types of phosphors are developed on the market, or it is desired to use more than two types of phosphors for mixed light, the development time of the LED backlight module is also short. longer and longer. It is undoubtedly a considerable challenge for the launch of the product.
发明内容 Contents of the invention
本发明的一目的是利用软件的计算可以快速调配出使用多种荧光粉混成高色彩饱和度发光二极管背光模块的方法与系统,以降低尝试错误的时间成本。An object of the present invention is to use software calculations to quickly deploy a method and system for mixing a variety of fluorescent powders into a high-color-saturation light-emitting diode backlight module, so as to reduce the time cost of trial and error.
鉴于上述的发明背景中,为了符合产业利益的需求,本发明提供一种配置高色彩饱和度发光二极管背光模块的方法,其步骤包含先计算一标准频谱,其中标准频谱在一第一色温下的黑体辐射所发射的可见光频谱。之后,提供一发光二极管的发射频谱、一第一荧光粉的发射频谱及一第二荧光粉的发射频谱。借助上述标准频谱调整第一荧光粉与第二荧光粉的浓度而得到一第一混光频谱,使得第一混光频谱与标准频谱接近。然后,将第一混光频谱通过一彩色滤镜分色成三原色的色坐标,并计算三原色的色坐标所组成的面积,以及计算由三原色所组成的白光的色坐标位置。In view of the above-mentioned background of the invention, in order to meet the needs of industrial interests, the present invention provides a method for configuring a high-color-saturation light-emitting diode backlight module. The steps include first calculating a standard spectrum, wherein the standard spectrum is at a first color temperature. The spectrum of visible light emitted by blackbody radiation. Afterwards, an emission spectrum of the LED, an emission spectrum of the first phosphor and an emission spectrum of the second phosphor are provided. A first mixed light spectrum is obtained by adjusting the concentration of the first phosphor and the second phosphor according to the standard spectrum, so that the first mixed light spectrum is close to the standard spectrum. Then, the first mixed light spectrum is separated into the color coordinates of the three primary colors through a color filter, and the area formed by the color coordinates of the three primary colors is calculated, and the color coordinate position of the white light composed of the three primary colors is calculated.
本发明也提供一种配置高色彩饱和度发光二极管背光模块的方法,其步骤包含先计算一标准频谱,而标准频谱在一第一色温下的黑体辐射所发射的可见光频谱。之后,提供一发光二极管的发射频谱、一第一荧光粉的发射频谱及一第二荧光粉的发射频谱。借助标准频谱调整第一荧光粉与第二荧光粉的浓度而得到一第一混光频谱。混光后的频谱通过一彩色滤镜后分色成红色、绿色与蓝色的色度坐标,之后,计算红色、绿色与蓝色的色度坐标所组成的面积,并且合成红色,绿色,与蓝色的白光的色度坐标位置。The present invention also provides a method for configuring a high-color-saturation LED backlight module. The steps include first calculating a standard spectrum, and the standard spectrum is a visible light spectrum emitted by black body radiation at a first color temperature. Afterwards, an emission spectrum of the LED, an emission spectrum of the first phosphor and an emission spectrum of the second phosphor are provided. A first mixed light spectrum is obtained by adjusting the concentration of the first phosphor and the second phosphor with the help of the standard spectrum. The mixed light spectrum is separated into red, green and blue chromaticity coordinates through a color filter, and then the area formed by the red, green and blue chromaticity coordinates is calculated, and red, green, and blue are synthesized The chromaticity coordinate position of blue white light.
本发明也提供一种配置高色彩饱和度发光二极管背光模块的系统,包含一第一数据库、一标准频谱产生器、一第一混色单元、一第二混色单元、一频谱比较单元、一第二数据库、一过滤单元以及一色彩饱和度计算单元。上述的第一数据库用以提供一发光二极管发光频谱、一第一荧光粉发光频谱与一第二荧光粉发光频谱。上述的标准频谱产生器用以产生在一第一色温下的黑体辐射所发射的可见光频谱。上述的第一混色单元用以计算在第一数据库中的发光二极管、第一荧光粉及第二荧光粉的混光频谱,其中混光频谱为一第一混光频谱。上述的频谱比较单元用以比对第一混光频谱与标准色温频谱产生器所产生的标准频谱。上述的第二数据库用以存储一彩色滤镜的滤光频谱。上述的过滤单元借助第二数据库的滤光频谱计算第一混光频谱的三原色的色坐标。上述的色彩饱和度计算单元用以计算三原色的色坐标所组成的面积。上述的第二混色单元用以计算三原色混色后的白光的色坐标。The present invention also provides a system for configuring a high-color-saturation light-emitting diode backlight module, including a first database, a standard spectrum generator, a first color mixing unit, a second color mixing unit, a spectrum comparison unit, and a second database, a filter unit and a color saturation calculation unit. The above-mentioned first database is used to provide a light emission spectrum of an LED, a light emission spectrum of a first phosphor, and a light emission spectrum of a second phosphor. The above-mentioned standard spectrum generator is used to generate the visible light spectrum emitted by the black body radiation at a first color temperature. The above-mentioned first color mixing unit is used to calculate the light mixing spectrum of the light emitting diode, the first phosphor and the second phosphor in the first database, wherein the light mixing spectrum is a first light mixing spectrum. The above spectrum comparison unit is used for comparing the first mixed light spectrum with the standard spectrum generated by the standard color temperature spectrum generator. The above-mentioned second database is used to store a filter spectrum of a color filter. The above-mentioned filtering unit calculates the color coordinates of the three primary colors of the first light mixing spectrum with the aid of the filtering spectrum of the second database. The above-mentioned color saturation calculation unit is used to calculate the area formed by the color coordinates of the three primary colors. The above-mentioned second color mixing unit is used to calculate the color coordinates of the white light after the three primary colors are mixed.
本发明也提供一种计算多重荧光粉浓度以得到高色彩饱和度发光二极管背光模块的方法,包含调整多重荧光粉的浓度使得与一发光二极管混光后的频谱接近在一第一色温下的黑体辐射发光频谱,并且经由一彩色滤镜将混光后的频谱分色成三原色后,使得三原色的色度坐标所组成的面积与白光色坐标可满足要求。The present invention also provides a method for calculating the concentration of multiple phosphors to obtain a high color saturation LED backlight module, including adjusting the concentration of multiple phosphors so that the spectrum after mixing with an LED is close to a blackbody at a first color temperature The luminescence spectrum is radiated, and the mixed light spectrum is separated into three primary colors through a color filter, so that the area formed by the chromaticity coordinates of the three primary colors and the white light color coordinates can meet the requirements.
本发明也提供一种使用两阶段的近似找出各种荧光粉在高色彩饱和度发光二极管背光模块的调配比例的方法,包含调配出接近黑体辐射的各种荧光粉的混合比例,以及从一彩色滤镜分色出的三原色中的色坐标的组成面积与白光的色坐标修正所述各种荧光粉的调配比例。The present invention also provides a method of using a two-stage approximation to find out the blending ratio of various phosphors in a high-color-saturation light-emitting diode backlight module, including blending the blending ratio of various phosphors close to black body radiation, and from a The composition area of the color coordinates of the three primary colors separated by the color filter and the color coordinates of the white light correct the blending ratio of the various phosphors.
其中上述的计算该标准频谱的步骤、手段、或系统,是利用普朗克(Planck)方程式计算而得。上述的第一混光频谱由发光二极管,第一荧光粉,与第二荧光粉激发辐射后得到。其中上述的第一荧光粉可为CaSc2O4:Ce、(MgCaSrBa)2SiO4:Eu、Ca3Sc2Si3Ol2:Ce、(Ca1.47Mg1.5Ce0.03)(Sc1.5Y0.5)Si3Ol2或(Ca2.97Ce0.03)Sc2(Si,Ge)3O12。其中上述的第二荧光粉可为CaAlSiN3:Eu、(CaEu)AlSiN3、(SrCa)AlSiN3:Eu或SrGa2S4:Eu。本发明可包含一第三荧光粉及其发射光谱。Wherein the above-mentioned steps, means, or systems for calculating the standard spectrum are calculated by using Planck's equation. The above-mentioned first mixed light spectrum is obtained by excitation and radiation of the light-emitting diode, the first phosphor, and the second phosphor. Wherein the above-mentioned first phosphor can be CaSc 2 O 4 : Ce, (MgCaSrBa) 2 SiO 4 : Eu, Ca 3 Sc 2 Si 3 Ol 2 : Ce, (Ca 1.47 Mg 1.5 Ce 0.03 )(Sc 1.5 Y 0.5 ) Si 3 Ol 2 or (Ca 2.97 Ce 0.03 )Sc 2 (Si, Ge) 3 O 12 . The above-mentioned second phosphor can be CaAlSiN 3 :Eu, (CaEu)AlSiN 3 , (SrCa)AlSiN 3 :Eu or SrGa 2 S 4 :Eu. The present invention may include a third phosphor and its emission spectrum.
利用本发明的手段,可达成可快速的调配出高色彩饱和度的发光二极管背光模块的功效,并且可大幅降低尝试错误的时间成本。Utilizing the means of the present invention can achieve the effect of quickly deploying the LED backlight module with high color saturation, and can greatly reduce the time cost of trial and error.
附图说明 Description of drawings
图1显示CIE1931色度的示意图;Figure 1 shows a schematic diagram of CIE1931 chromaticity;
图2显示NTSC标准与一般背光的CIE1931色度坐标示意图;Figure 2 shows a schematic diagram of CIE1931 chromaticity coordinates of NTSC standard and general backlight;
图3显示本发明的一种计算多重荧光粉浓度以得到高色彩饱和度发光二极管背光模块的方法流程图;Fig. 3 shows a flow chart of a method for calculating the concentration of multiple phosphors of the present invention to obtain a high color saturation LED backlight module;
图4显示本发明的一种配置高色彩饱和度发光二极管背光模块的方法流程图;Fig. 4 shows a flow chart of a method for configuring a high-color-saturation light-emitting diode backlight module of the present invention;
图5显示本发明的一种配置高色彩饱和度发光二极管背光模块的系统方框图;Fig. 5 shows a system block diagram of a configuration of a high-color-saturation light-emitting diode backlight module of the present invention;
图6显示本发明的高演色性白光发光二极管的配制方法流程图;Fig. 6 shows the flow chart of the preparation method of the high color rendering white light emitting diode of the present invention;
图7显示本发明的发射频谱相似度比较的高演色性白光发光二极管的配制系统方框图;Fig. 7 shows the block diagram of the preparation system of high color rendering white light-emitting diodes according to the present invention for comparison of emission spectrum similarity;
图8显示发光二极管芯片及两种不同荧光粉浓度的混合发射频谱的示意图;Fig. 8 shows a schematic diagram of a light-emitting diode chip and a mixed emission spectrum of two different phosphor concentrations;
图9显示彩色滤镜的滤光频谱图;Fig. 9 shows the filter spectrogram of color filter;
图10显示演色系数比对的高演色性白光发光二极管的配制系统方框图;以及FIG. 10 shows a block diagram of a preparation system of a high color rendering white light emitting diode with a color rendering coefficient ratio; and
图11显示本发明的配置高演色性白光发光二极管的系统方框图;以及Fig. 11 shows a system block diagram of a configuration of high color rendering white light emitting diodes of the present invention; and
图12显示本发明的高色彩饱和度发光二极管背光模块,NTSC标准,与一般背光的CIE1931色度坐标示意图。FIG. 12 shows a schematic diagram of CIE1931 chromaticity coordinates of the high color saturation LED backlight module of the present invention, NTSC standard, and a general backlight.
其中,附图标记说明如下:Wherein, the reference signs are explained as follows:
0完成 31-32步骤0 completed 31-32 steps
41-45步骤 51第一数据库Steps 41-45 51 First database
52第一混色单元 53标准色温频谱产生器52 The first
54频谱比较单元 55第二数据库54
56过滤单元 57色彩饱和度计算单元56
58第二混色单元 61-65步骤58 Second color mixing unit 61-65 steps
71目标色温的黑体辐射产生器 72第一数据库71 Black body radiation generator for
73频谱计算单元 74频谱比较单元73
76调整荧光粉的浓度 77重新选择荧光粉76 Adjust the concentration of
100目标色温的黑体辐射产生 101第一数据库100 target color temperature black body radiation generation 101 first database
器device
102频谱计算单元 103第二数据库102 spectrum computing unit 103 second database
104色彩饱和度计算单元 105混色计算单元104 color saturation computing units 105 color mixing computing units
106比较单元 108调整荧光粉的浓度106 Comparing unit 108 Adjusting the concentration of fluorescent powder
109重新选择荧光粉109 reselect phosphor
110目标色温的黑体辐射的频谱产生器Spectrum Generator for Black Body Radiation at 110 Target Color Temperature
111第一数据库 112频谱计算单元111 First database 112 Spectrum calculation unit
113频谱比较单元 114第一阶近似113 Spectrum comparison unit 114 First-order approximation
115分色单元 116第二数据库115 color separation unit 116 second database
117三原色色度坐标计算单元 118三原色混光单元117 Three primary color chromaticity coordinate calculation unit 118 Three primary color light mixing unit
119第二阶近似119 Second order approximation
具体实施方式 Detailed ways
本发明在此所探讨的方向为一种高色彩饱和度发光二极管背光模块的方法与系统。为了能彻底地了解本发明,将在下列的描述中提出详尽的步骤及其组成。显然地,本发明的施行并未限定于高色彩饱和度发光二极管背光模块的方法与系统的普通技术人员所熟习的特殊细节。另一方面,众所周知的组成或步骤并未描述于细节中,以避免造成本发明不必要的限制。本发明的优选实施例会详细描述如下,然而除了这些详细描述之外,本发明还可以广泛地施行在其他的实施例中,且本发明的范围不受限定,其以之后的权利要求为准。The direction of the present invention discussed here is a method and system for a high-color-saturation light-emitting diode backlight module. In order to provide a thorough understanding of the present invention, detailed steps and components thereof will be set forth in the following description. Obviously, the implementation of the present invention is not limited to specific details familiar to those of ordinary skill in the method and system of high color saturation LED backlight modules. On the other hand, well-known components or steps have not been described in detail so as not to unnecessarily limit the invention. Preferred embodiments of the present invention are described in detail below, however, the present invention can be widely practiced in other embodiments besides these detailed descriptions, and the scope of the present invention is not limited, which is subject to the following claims.
由上述可知,产生白光的重要元素其中的一为荧光材料。而荧光材料发光即为荧光体经过光、电场、电子束等不同激发源的激发后,可让荧光体的电子获得足够能量,由基态能阶跃迁至较高能量的激发态能阶。由于处于高能阶激发态的电子较不稳定,又会以缓解(relaxation)的方式回到低能阶的基态。在缓解过程中,若是以非辐射(non-radiative)方式释放能量,将产生晶格的振动,使能量以“热”的形式消耗。如果是以电磁辐射(radiative)方式释放,则以光的形式放出能量。若发出的光波长落在可见光范围,则人眼可以看到荧光体所放射出的光。在此荧光体所发的光,只跟电子在高低能阶间跃迁有关。It can be seen from the above that one of the important elements for generating white light is a fluorescent material. The luminescence of fluorescent materials means that after the phosphor is excited by different excitation sources such as light, electric field, and electron beam, the electrons of the phosphor can obtain enough energy to transition from the ground state energy level to a higher energy excited state energy level. Since the electrons in the high-energy excited state are relatively unstable, they will return to the low-energy ground state in a relaxation manner. During the mitigation process, if the energy is released in a non-radiative way, the vibration of the crystal lattice will be generated, and the energy will be consumed in the form of "heat". If released in the form of electromagnetic radiation (radiative), the energy is released in the form of light. If the wavelength of the emitted light falls within the range of visible light, the human eye can see the light emitted by the phosphor. The light emitted by the phosphor is only related to the transition of electrons between high and low energy levels.
发光二极管所使用的荧光粉由主体晶格(host lattice,H)为主要的组成成分,例如ZnS:Cu2+,其中ZnS即为主体晶格。荧光体中发光中心借助少量添加或掺杂(dope)异种离子于主体晶格中所构成,例如ZnS:Cu2+中的Cu2+。由此异种离子为可被激发并产生荧光的中心体,也称为活化中心(activator)或活化剂。有时荧光材料中也会于主体晶格中添加第二种异种离子,作用为将其所吸收的激发能量传递至活化中心离子并发光,称为增感剂(sensitizer)或辅助活化剂(co-activator)。故可借助控制主体晶格及活化中心而设计各式各样具发射各种波长的荧光粉。目前,市面上可见到的荧光粉的主体材料多由硫化物(Sulfides)、氧化物(Oxides)、硫氧化物(Oxysulfides)、氮化物(Nitrides)、氮氧化物(Oxynitrides)、石榴石(Garnet)及硅酸盐(Silicates)类等所构成。Phosphor powder used in light emitting diodes is mainly composed of host lattice (H), such as ZnS:Cu 2+ , wherein ZnS is the host lattice. The luminescent center in the phosphor is formed by adding or doping a small amount of different ions in the host lattice, such as Cu 2+ in ZnS:Cu 2+ . Thus, the heterogeneous ions are centrosomes that can be excited and generate fluorescence, also known as activators or activators. Sometimes in fluorescent materials, a second heterogeneous ion is added to the host lattice to transfer the absorbed excitation energy to the active center ion and emit light, which is called a sensitizer or an auxiliary activator (co- activator). Therefore, it is possible to design various phosphors emitting various wavelengths by controlling the host lattice and the active center. At present, the main materials of fluorescent powders available on the market are mostly composed of sulfides, oxides, oxysulfides, nitrides, oxynitrides, garnet ) and silicates (Silicates) and so on.
一般人所指的白光是指白天所看到的太阳光,经过学理上分析后发现其白光包含400nm~700nm范围的连续光谱。以目视的颜色而言,可分解成红、橙、黄、绿、蓝、靛、紫等七色。根据发光二极管的发光原理,一般只能发出单色光。为了让它能够发出白光,技术上必须混合两种以上互补色的光而达到白光的目的。白光发光二极管除了产生白光以外,是否能展现物体颜色的忠实度的能力即称为演色性(Color Rendering)也是技术上必须考虑的部分。演色性高的光源对于物体颜色的表现较为逼真,被照明物在人类的眼睛所呈现的物体颜色也比较接近自然的原色。白光发光二极管的演色系数(Color Rendering Index;CRI)与发光二极管芯片、荧光粉及材料有关。在不同色温下,使用的荧光粉或发光二极管芯片会有所不同。The white light that most people refer to refers to the sunlight seen during the day. After theoretical analysis, it is found that the white light contains a continuous spectrum in the range of 400nm to 700nm. In terms of visual color, it can be broken down into seven colors: red, orange, yellow, green, blue, indigo, and purple. According to the light-emitting principle of light-emitting diodes, generally only monochromatic light can be emitted. In order for it to emit white light, it is technically necessary to mix two or more complementary colors of light to achieve the purpose of white light. In addition to producing white light, the ability of white light-emitting diodes to show the fidelity of the object's color is called color rendering (Color Rendering) is also a part that must be considered technically. The light source with high color rendering performance is more realistic to the color of the object, and the object color presented by the illuminated object to the human eye is also closer to the natural primary color. The color rendering index (CRI) of white light-emitting diodes is related to the LED chips, phosphors and materials. Under different color temperatures, the phosphors or LED chips used will be different.
色温(Color Temperature)的定义是依据黑体(Black body)辐射,把金属(接近黑体)加热到一定温度时,会呈现出有颜色的可见光。这种光随着温度的升高而变化,而影响这种光源的温度就叫该光源的色温。例如当一块铁被升温时,开始的时候铁会变得通红,之后会变得橙色,之后是黄色,再之后是蓝白色。研究人员利用一列连续光谱来验证其温度与颜色之间的关系。设x轴是波长,y轴就代表辐射流量,当y轴是反映不同波长放射的量,即可画出不同温度时铁所放出能量的曲线。故,当铁变成红色时,并不表示它只发红光,只是它放射的红光比其他波长的波多。由此试验发现三个特质:1.曲线有一个高峰点;2.当温度增高时,高峰点会向短波方向移动;3.当温度增高时,所有波长的辐射流量都会增加。例如铁在4200K发放红光最多,辐射流量高峰点在红光处,所以我们见到铁呈红色,在4800K时,辐射流量高峰点在橙黄色。所以我们见到铁呈橙黄色,是由于当温度增高时,高峰点会向短波方向移动,所以在5800K时,高峰点会移到黄绿色。The definition of color temperature (Color Temperature) is based on the black body (Black body) radiation, when the metal (close to the black body) is heated to a certain temperature, it will show colored visible light. This light changes as the temperature increases, and the temperature that affects this light source is called the color temperature of the light source. For example, when a piece of iron is heated, at first the iron will turn red, then orange, then yellow, and then blue-white. The researchers used a continuous spectrum to verify the relationship between its temperature and color. Suppose the x-axis is the wavelength, and the y-axis represents the radiation flux. When the y-axis reflects the amount of radiation of different wavelengths, the curve of the energy released by iron at different temperatures can be drawn. Therefore, when iron turns red, it does not mean that it only emits red light, but that it emits more red light than other wavelengths. From this experiment, three characteristics are found: 1. The curve has a peak point; 2. When the temperature increases, the peak point will move to the short-wave direction; 3. When the temperature increases, the radiation flux of all wavelengths will increase. For example, iron emits the most red light at 4200K, and the peak point of radiation flow is at the red light, so we see iron as red, and at 4800K, the peak point of radiation flow is orange-yellow. So we see that iron is orange-yellow, because when the temperature increases, the peak point will move to the short wave direction, so at 5800K, the peak point will move to yellow-green.
在色温的计算上,是以绝对温度Kelvin(K)为单位,黑体幅射以Kelvin=摄氏+273作为计算的起点。假定某一纯黑物体,能够将落在其上的所有热量吸收,而没有损失,同时又能够将热量生成的能量全部以“光”的形式释放出来的话,它便会因受到热力的高低而变成不同的颜色。例如,当黑体受到的热力相当于500—550℃时,就会变成暗红色,达到1050—1150℃时,就变成黄色。因此,光源的颜色成分是与该黑体所受的热力温度相对应的。只不过色温是用开尔文(K)色温单位来表示,而不是用摄氏温度单位元。当黑体受到的热力使它能够放出光谱中的全部可见光波时它就变成白色,而我们所用灯泡内的钨丝就相当接近这个黑体。色温计演算法就是根据上述原理,以K来表示受热钨丝所放射出光线的色K温度单位来表示受热钨丝所放射出光线的色温。根据这一原理,任何光线的色温是相当于上述黑体散发出同样颜色时所受到的“温度”。此温度可以在色度图的普朗克轨迹上找到其对应点,黑体的曲线只会受温度而改变,不会受其他因素如黑体的成份而改变,所以无论是任何成份的黑体,只要是同一温度,都会有同一曲线。In the calculation of color temperature, the absolute temperature Kelvin (K) is used as the unit, and the black body radiation is calculated with Kelvin = Celsius + 273 as the starting point. Assuming that a pure black object can absorb all the heat falling on it without loss, and at the same time release all the energy generated by the heat in the form of "light", it will be affected by the level of heat. into different colors. For example, when the black body receives heat equivalent to 500-550°C, it will turn dark red, and when it reaches 1050-1150°C, it will turn yellow. Therefore, the color composition of the light source corresponds to the thermal temperature of the black body. It's just that the color temperature is represented by the Kelvin (K) color temperature unit instead of the Celsius temperature unit. When a black body is heated so that it can emit all visible light waves in the spectrum, it becomes white, and the tungsten filament in the bulb we use is quite close to this black body. The algorithm of the color temperature meter is based on the above principle, using K to represent the color of the light emitted by the heated tungsten wire. The K temperature unit represents the color temperature of the light emitted by the heated tungsten wire. According to this principle, the color temperature of any light is equivalent to the "temperature" received by the above-mentioned black body emitting the same color. This temperature can find its corresponding point on the Planck locus of the chromaticity diagram. The curve of the black body will only be changed by the temperature, not by other factors such as the composition of the black body. Therefore, no matter the black body of any composition, as long as it is At the same temperature, there will be the same curve.
由于自然光源、色、时间、天候、观察方向、季节及地理位置等条件影响而变化很大,对色彩的评定极不方便,因此国际照明委员会(CommissionInternational de 1′Eclairage,简称CIE)。于1930年订定各种极为接近自然光的标准光源。Due to the great changes in natural light source, color, time, weather, observation direction, season and geographical location, it is extremely inconvenient to evaluate the color, so the International Commission on Illumination (Commission International de 1′Eclairage, referred to as CIE). In 1930, various standard light sources that were very close to natural light were established.
另外,国际照明委员会根据视觉的数学模型和颜色匹配实验结果制定了一个称为“1931CIE标准观察者”的规范,实际上是用三条曲线表示的一套颜色匹配函数,因此许多文献中也称为“CIE1931标准匹配函数”,如图1所示。CIE1931色度图是用标称值表示的CIE色度图,x表示红色分量,y表示绿色分量。在色度图(chromaticity diagram)中马蹄形范围内为可见光谱的所有颜色,马蹄形边缘则为饱和的单色波长。此系统以光色坐标(x,y,z)标示可由三原色组合成某一色的相对比例(图上仅有x及y坐标,由恒等式x+y+z=1可导出z)。中间的白光,它的坐标为(0.33,0.33)。环绕在颜色空间边沿的颜色是光谱色,边界代表光谱色的最大饱和度,边界上的数字表示光谱色的波长,其轮廓包含所有的感知色调。所有单色光都位于舌形曲线上,这条曲线就是单色轨迹,曲线旁标注的数字是单色(或称光谱色)光的波长值。自然界中各种实际颜色都位于这条闭合曲线内。In addition, the International Commission on Illumination formulated a specification called "1931CIE Standard Observer" based on the mathematical model of vision and the results of color matching experiments. In fact, it is a set of color matching functions represented by three curves, so many documents are also called "CIE1931 standard matching function", as shown in Figure 1. The CIE1931 chromaticity diagram is a CIE chromaticity diagram represented by nominal values, where x represents the red component and y represents the green component. In the chromaticity diagram (chromaticity diagram), the range of the horseshoe is all the colors of the visible spectrum, and the edge of the horseshoe is the saturated monochromatic wavelength. This system uses light color coordinates (x, y, z) to indicate the relative proportion of a certain color that can be combined from the three primary colors (there are only x and y coordinates in the figure, and z can be derived from the identity x+y+z=1). The white light in the middle has coordinates of (0.33, 0.33). The colors surrounding the edge of the color space are the spectral colors, the border represents the maximum saturation of the spectral color, the numbers on the border represent the wavelength of the spectral color, and its outline contains all the perceived hues. All monochromatic light is located on the tongue-shaped curve, this curve is the monochromatic locus, and the numbers marked beside the curve are the wavelength values of monochromatic (or called spectral color) light. Every actual color in nature lies within this closed curve.
NTSC是1952年12月由美国国家电视标准委员会(National TelevisionSystem Committee,缩写为NTSC)制定的彩色电视广播标准。NTSC属于同时制,帧频为每秒29.97fps,扫描线为525,逐行扫描,画面比例为4:3,解析度为720x480。这种制式的色度信号调制包括了平衡调制和正交调制两种,解决了彩色黑白电视广播兼容问题。NTSC is a color television broadcast standard formulated by the National Television System Committee (National Television System Committee, abbreviated as NTSC) in December 1952. NTSC belongs to the simultaneous system, the frame rate is 29.97fps per second, the scanning line is 525, progressive scanning, the aspect ratio is 4:3, and the resolution is 720x480. The chrominance signal modulation of this system includes balanced modulation and quadrature modulation, which solves the compatibility problem of color black and white TV broadcasting.
在图2中显示NTSC标准与一般背光的CIE1931色度坐标示意图。在图2中可以看出NTSC所定义的色彩可以在CIE中以三原色的三个坐标所围成的面积表示。在图2中,是由三个方形的点所围成的面积。目前一般的以白光发光二极管作为液晶显示器的背光源,可以提供的色彩饱和度,在图2中,相较于NTSC的标准面积是较小的。因此可以提供的色彩饱和度较差。FIG. 2 shows a schematic diagram of CIE1931 chromaticity coordinates of NTSC standard and general backlight. It can be seen in Figure 2 that the colors defined by NTSC can be represented in CIE by the area enclosed by the three coordinates of the three primary colors. In Figure 2, it is the area surrounded by three square points. At present, white light-emitting diodes are generally used as the backlight source of liquid crystal displays, and the color saturation that can be provided is smaller than the standard area of NTSC in FIG. 2 . Therefore, the color saturation that can be provided is poor.
黑体辐射的计算,是在1879年由J.Stefan提出黑体辐射的总能量(E)和绝对温度(T)的四次方成正比,E=aT4,即所谓的斯蒂芬-玻尔兹曼定律(Stefan-Boltzmann law)。The calculation of black body radiation was proposed by J. Stefan in 1879. The total energy (E) of black body radiation is proportional to the fourth power of absolute temperature (T), E=aT 4 , which is the so-called Stephen-Boltzmann law (Stefan-Boltzmann law).
1893年Wien还进一步计算出辐射能波长的变化,发现波长λ的变化与温度成正比,若再引Stefan-Boltzmann law,及热力学中的绝热过程公式,可得Wien displacement law,Tλmax=常数。In 1893, Wien further calculated the change of the wavelength of radiant energy, and found that the change of wavelength λ is proportional to the temperature. If we quote Stefan-Boltzmann law and the adiabatic process formula in thermodynamics, we can get Wien displacement law, Tλ max = constant.
1896年Wien从热力学普遍理论考虑及分析实验数据得出一个半经验公式为In 1896, Wien obtained a semi-empirical formula from the consideration of the general theory of thermodynamics and the analysis of experimental data as
ρv=αv3exp(βv/T) ρv = αv 3 exp(βv/T)
其中ρv为辐射能密度(radiant energy density),v是频率,T是绝对温度,α和β是常数。Where ρv is the radiant energy density, v is the frequency, T is the absolute temperature, and α and β are constants.
1900年,J.W.Rayleigh,J.H.Jeans根据古典电动力学和统计物理理论,推导出一黑体辐射公式,即Rayleigh-Jeans law:In 1900, J.W.Rayleigh and J.H.Jeans derived a black body radiation formula based on classical electrodynamics and statistical physics theory, namely Rayleigh-Jeans law:
其中c是光速,k=Boltzmann′s constant。但此公式谨在低频部分与实验曲线符合,而当v→∞时,ρv→∞,发散,与实验明显不符,即古典物理中的“紫外灾难”。Where c is the speed of light, k=Boltzmann's constant. But this formula is consistent with the experimental curve in the low frequency part, but when v→∞, ρv →∞ diverges, which obviously does not match the experiment, which is the "ultraviolet disaster" in classical physics.
后来更精细和全面的实验表明,Wien公式并非与所有实验数据都符合很好。在长波段,Wien公式与实验有明显的偏离。德国物理学家普朗克(M.Planck)在1900年底找到一个可以和实验数据吻合的公式,即Later, more detailed and comprehensive experiments showed that the Wien formula did not agree well with all experimental data. In the long wave band, the Wien formula deviates significantly from the experiment. At the end of 1900, the German physicist M. Planck found a formula that can be consistent with the experimental data, namely
或or
其中h为普朗克常数,大小为h=6.626x10-34J·s。由普朗克的假设可成功解释并推导Rayleigh-Jeans law,Wien displacement law,Stefan-Boltzmann law。Wherein h is Planck's constant, the size is h=6.626x10-34J·s. Rayleigh-Jeans law, Wien displacement law, and Stefan-Boltzmann law can be successfully explained and derived from Planck's hypothesis.
由于不同的色温,发光二极管芯片及荧光粉等因素皆影响白光发光光谱的演色性,在试验过程中常需多次交叉测试各影响因素,得到一高演色性的白光发光二极管实需花费大量时间及成本。发明人为解决前述的问题,以高效率方式达到高演色性的白光发光二极管,依上述黑体辐射的原理及由其推导出的普朗克方程式(Planck’s law)进一步创作并发明一种可以快速调配出使用多种荧光粉混合成高演色性的白光发光二极管的配制方法与系统。Due to different color temperatures, factors such as LED chips and phosphors all affect the color rendering of the white light emission spectrum, it is often necessary to cross test the various influencing factors many times during the test process, and it takes a lot of time and effort to obtain a white light emitting diode with high color rendering performance. cost. In order to solve the above-mentioned problems, the inventor further created and invented a white light-emitting diode with high color rendering performance in a high-efficiency manner based on the above-mentioned principle of black body radiation and the derived Planck's law. A preparation method and system for white light emitting diodes with high color rendering performance by using a variety of fluorescent powders mixed.
本发明的手段在于使用两阶段的近似找出各种荧光粉在高色彩饱和度发光二极管背光模块的调配比例。第一阶段的近似主要是调配出接近黑体辐射的各种荧光粉的混合比例,而第二阶段的近似主要是从彩色滤镜的分色之后判断色彩饱和度以及白光的色坐标位置。The method of the present invention is to use two-stage approximation to find out the deployment ratio of various phosphors in the high color saturation LED backlight module. The first-stage approximation is mainly to adjust the mixing ratio of various phosphors close to black body radiation, while the second-stage approximation is mainly to judge the color saturation and the color coordinate position of white light from the color separation of the color filter.
请参阅图3,是显示本发明的一种计算多重荧光粉浓度以得到高色彩饱和度发光二极管背光模块的方法。第一步骤(31),首先调整多重荧光粉的浓度使得与一发光二极管混光后的频谱接近在一第一色温下的黑体辐射发光频谱。上述的发光二极管可以是紫外光发光二极管,紫光发光二极管,或是蓝光发光二极管。多重荧光粉可以有两种或是两种以上的荧光粉,由发光二极管的色光作决定。例如,使用紫外光或是紫光发光二极管时,至少需要同时使用三色的荧光粉才能混成白光。当使用蓝光发光二极管时,需至少选择两种颜色的荧光粉才能混成高演色性的白光。之后,第二步骤(32)找出混光后的频谱通过彩色滤镜后分成三原色的色坐标,检验三原色的色坐标所组成的面积以及三原色所合成白光的色坐标位置。Please refer to FIG. 3 , which shows a method of calculating the concentration of multiple phosphors to obtain a high color saturation LED backlight module according to the present invention. In the first step (31), the concentration of the multiple fluorescent powders is firstly adjusted so that the spectrum after mixing with a light emitting diode is close to the black body radiation emission spectrum at a first color temperature. The aforementioned light emitting diodes may be ultraviolet light emitting diodes, purple light emitting diodes, or blue light emitting diodes. Multiple phosphors can have two or more phosphors, which are determined by the color light of the light-emitting diodes. For example, when using ultraviolet light or violet light-emitting diodes, at least three colors of phosphors need to be used at the same time to mix white light. When using blue light-emitting diodes, at least two colors of phosphors need to be selected to mix white light with high color rendering. Afterwards, the second step (32) finds out the color coordinates of the three primary colors after the mixed light spectrum passes through the color filter, and checks the area formed by the color coordinates of the three primary colors and the color coordinate position of the white light synthesized by the three primary colors.
在参考图3的流程中,本发明也提供一种配置高色彩饱和度发光二极管背光模块的方法,详细流程请参阅图4。首先,第一步骤(41)计算一标准频谱,其中标准频谱在一第一色温下的黑体辐射所发射的可见光频谱。同时,在第二步骤(42)中,提供一发光二极管的发射频谱、一第一荧光粉的发射频谱及一第二荧光粉的发射频谱。之后,在第三步骤(43)中,借助上述的标准频谱调整第一荧光粉与第二荧光粉的浓度而得到一第一混光频谱,使得第一混光频谱与标准频谱接近。接着,请参阅第四步骤(44),将第一混光频谱通过一彩色滤镜分色成三原色的色坐标,并计算三原色色坐标所组成的面积。彩色滤镜是液晶显示器所使用的分成三原色的滤镜。当三原色的色坐标所组成的面积愈大,则液晶显示器的画面色彩饱和度愈佳。这个步骤是用来检测色彩饱和度。如果色彩饱和度不佳,会重新调整荧光粉的浓度。然后,在第五步骤(45)中,计算由三原色所组成的白光的色坐标位置。当白光的色坐标位置错误时,就必须重新调整荧光粉的比例。甚至是,可以调整白光的色坐标位于某一色温的黑体辐射的色坐标位置。在图4中,只有用两种荧光粉来表示本发明的实施例。然而,可以同时使用第三荧光粉,第四荧光粉,甚至是第五荧光粉应用到本发明。In the process referring to FIG. 3 , the present invention also provides a method for configuring a high color saturation LED backlight module. Please refer to FIG. 4 for the detailed process. Firstly, the first step (41) calculates a standard spectrum, wherein the standard spectrum is the visible light spectrum emitted by black body radiation at a first color temperature. Meanwhile, in the second step (42), an emission spectrum of a light emitting diode, an emission spectrum of a first phosphor and an emission spectrum of a second phosphor are provided. Afterwards, in the third step (43), the concentration of the first phosphor and the second phosphor is adjusted by means of the standard spectrum to obtain a first mixed light spectrum, so that the first mixed light spectrum is close to the standard spectrum. Next, please refer to the fourth step (44), the first mixed light spectrum is separated into the color coordinates of the three primary colors through a color filter, and the area formed by the color coordinates of the three primary colors is calculated. Color filters are filters used in liquid crystal displays that divide into three primary colors. The larger the area formed by the color coordinates of the three primary colors, the better the color saturation of the LCD screen. This step is used to detect color saturation. If the color saturation is not good, the concentration of the phosphor is readjusted. Then, in the fifth step (45), the color coordinate position of the white light composed of three primary colors is calculated. When the color coordinates of white light are in the wrong position, the ratio of phosphors must be readjusted. Even, it is possible to adjust the color coordinate position of black body radiation whose color coordinates of white light are at a certain color temperature. In FIG. 4, only two kinds of phosphors are used to represent the embodiment of the present invention. However, the third phosphor, the fourth phosphor, and even the fifth phosphor can be applied to the present invention at the same time.
依照图4的流程,本发明也提供一种配置高色彩饱和度发光二极管背光模块的系统,详细说明请参阅图5。一第一数据库(51),用以存储一发光二极管的发射频谱、一第一荧光粉发射频谱及一第二荧光粉发射频谱。一第一混色单元(52),用以计算在第一数据库(51)中的发光二极管、第一荧光粉及第二荧光粉的混光频谱,其中混光频谱为一第一混光频谱。一标准色温频谱产生器(53),用以产生在一第一色温下的黑体辐射所发射的可见光频谱。一频谱比较单元(54),用以比对第一混光频谱与标准色温频谱产生器(53)所产生的标准频谱。当频谱比较单元(54)的判断是第一混光频谱接近在第一色温下的黑体辐射所发射的可见光频谱,则将第一混光频谱的数据往下一阶段传送。如果比对结果不接近,则会由第一混色单元(52)重新计算出第一混色频谱,直到比对结果接近为止。According to the flow chart in FIG. 4 , the present invention also provides a system for configuring a high-color-saturation LED backlight module. Please refer to FIG. 5 for details. A first database (51) is used to store an emission spectrum of a light emitting diode, a first phosphor emission spectrum and a second phosphor emission spectrum. A first color mixing unit (52) is used to calculate the light mixing spectrum of the light emitting diode, the first phosphor and the second phosphor in the first database (51), wherein the light mixing spectrum is a first light mixing spectrum. A standard color temperature spectrum generator (53), used to generate the visible light spectrum emitted by black body radiation at a first color temperature. A spectrum comparison unit (54), used for comparing the first mixed light spectrum with the standard spectrum generated by the standard color temperature spectrum generator (53). When the spectrum comparison unit (54) judges that the first mixed light spectrum is close to the visible light spectrum emitted by black body radiation at the first color temperature, the data of the first mixed light spectrum is sent to the next stage. If the comparison result is not close, the first color mixing unit (52) will recalculate the first color mixing spectrum until the comparison result is close.
请继续参照图5,一第二数据库(55),用以存储一彩色滤镜的滤光频谱,其中彩色滤镜是作为液晶显示器的分色滤镜。一过滤单元(56),借助第二数据库的滤光频谱计算第一混光频谱的三原色的色坐标。色彩饱和度计算单元(57),用以计算三原色的色坐标所组成的面积。当面积相较于NTSC所定义的面积为小,或是相较于商业上定义的色彩饱和度的规格为小,则重回到第一混色单元(52)重新计算出第一混色频谱,直到可以通过色彩饱和度计算单元(57)的要求为止。第二混色单元(58)用以计算三原色混色后的白光的色坐标。当白光的色坐标位置离开一般定义的白光色坐标的时候,也必须回到第一混色单元(52)重新计算出第一混色频谱,直到可以通过第二混色单元(58)的要求为止。在本发明中,还可以设定白光的色坐标必须落在设定的黑体辐射的色温,例如色温为6500K的白光色坐标。Please continue to refer to FIG. 5 , a second database ( 55 ) is used to store a filter spectrum of a color filter, wherein the color filter is used as a dichroic filter of a liquid crystal display. A filtering unit (56), which calculates the color coordinates of the three primary colors of the first mixed light spectrum by means of the filtered light spectrum of the second database. A color saturation calculation unit (57), used for calculating the area formed by the color coordinates of the three primary colors. When the area is small compared to the area defined by NTSC, or compared to the standard of commercially defined color saturation, then return to the first color mixing unit (52) to recalculate the first color mixing spectrum until Can meet the requirements of the color saturation calculation unit (57). The second color mixing unit (58) is used for calculating the color coordinates of the white light after the three primary colors are mixed. When the color coordinate position of white light deviates from the generally defined white light color coordinate, it is necessary to return to the first color mixing unit (52) to recalculate the first color mixing spectrum until the requirement of the second color mixing unit (58) can be passed. In the present invention, it can also be set that the color coordinates of white light must fall within the set color temperature of black body radiation, for example, the color coordinates of white light with a color temperature of 6500K.
下列各相关图示将用以详细说明本发明各优选实施例。图6为高演色性白光发光二极管的配制方法流程图。第一步骤(61),计算出在某一特定色温下黑体辐射的可见光频谱。在本实施例中,是以普朗克方程式The following related diagrams will be used to describe various preferred embodiments of the present invention in detail. Fig. 6 is a flowchart of a preparation method of a high color rendering white light emitting diode. In the first step (61), the visible light spectrum radiated by the black body at a specific color temperature is calculated. In this example, the Planck equation
计算目标色温的黑体辐射的可见光频谱。然而,从上述黑体辐射的发展背景中,也可以应用Rayleigh-Jeans方程式,Stefan-Boltzmann方程式,或是Wien方程式作为简化的黑体辐射的频谱。设定一目标色温并以普朗克方程式(Planck’s Law),计算出色温的频谱(色温范围可从2500K~8000K),即为目标色温的黑体辐射的可见光频谱。在本步骤中,目标色温的黑体辐射的可见光频谱是由Ta(λ)表示。Calculates the visible spectrum of black body radiation for the target color temperature. However, from the development background of the above-mentioned black body radiation, the Rayleigh-Jeans equation, the Stefan-Boltzmann equation, or the Wien equation can also be applied as the spectrum of the simplified black body radiation. Set a target color temperature and use Planck's Law to calculate the spectrum of the color temperature (the color temperature can range from 2500K to 8000K), which is the visible light spectrum of the black body radiation of the target color temperature. In this step, the visible light spectrum of the black body radiation at the target color temperature is represented by T a (λ).
第二步骤(62)即提供已知发光二极管芯片的发射频谱、第一荧光粉发射频谱及第二荧光粉发射频谱。当有两种以上的荧光粉,就需要提供所有荧光粉的发射频谱。在本步骤中,发光二极管芯片测量的发射频谱是由L(λ)表示;第一荧光粉测量的发射频谱是由P1(λ)表示;以及第二荧光粉测量的发射频谱是由P2(λ)表示。The second step (62) is to provide the emission spectrum of the known LED chip, the emission spectrum of the first phosphor powder and the emission spectrum of the second phosphor powder. When there are more than two kinds of phosphors, it is necessary to provide the emission spectra of all phosphors. In this step, the emission spectrum measured by the LED chip is represented by L(λ); the emission spectrum measured by the first phosphor is represented by P1(λ); and the emission spectrum measured by the second phosphor is represented by P2(λ )express.
第三步骤(63)依照第一步骤所计算出在某一特定色温下黑体辐射的可见光频谱,调配出所有荧光粉的浓度,然后计算出发光二极管芯片、第一荧光粉浓度及第二荧光粉浓度混合后的混合发射频谱。一种计算方式如方程式(2)所述:The third step (63) is to adjust the concentration of all phosphors according to the visible light spectrum radiated by the black body at a certain color temperature calculated in the first step, and then calculate the concentration of the light-emitting diode chip, the first phosphor and the second phosphor Mixed emission spectrum after concentration mixing. One calculation method is described in equation (2):
Ca(λ)=a×L(λ+Δλ)+b×P1(λ+Δλ)+c×P2(λ+Δλ)C a (λ)=a×L(λ+Δλ)+b×P1(λ+Δλ)+c×P2(λ+Δλ)
求
(2) (2)
其中,混合发射频谱由Ca(λ)表示;Wherein, the hybrid emission spectrum is represented by C a (λ);
发光二极管芯片的发光强度由a表示;The luminous intensity of the light emitting diode chip is represented by a;
第一荧光粉的浓度由b表示;以及The concentration of the first phosphor is represented by b; and
第二荧光粉的浓度由c表示。The concentration of the second phosphor is represented by c.
上述的方式是其中一种计算方式,然而任何本领域普通技术人员理应可以使用其他的方程式计算出各荧光粉的浓度。依照上述方式计算出来的混光频谱Ca(λ)为第一混光频谱。The above method is one of the calculation methods, but anyone skilled in the art should be able to use other equations to calculate the concentration of each phosphor. The light mixing spectrum C a (λ) calculated in the above manner is the first light mixing spectrum.
第四步骤(64)计算第一混光频谱在一彩色滤镜下分色成红色,绿色,与蓝色三原色的色度坐标所组成的面积。首先依照彩色滤镜的滤光频谱将第一混光频谱分色成红色、绿色与蓝色。然后,计算红色、绿色与蓝色在CIE的色坐标。有了红色、绿色与蓝色的色坐标,可以计算由红色、绿色与蓝色在CIE坐标所围成的面积。这个面积可以与NTSC所定义的面积相比较。例如当计算出来的三原色的色坐标所围成的面积约为75%的NTSC所定义的面积,就表示色彩饱和度为75%的NTSC。以本发明的演算法,可以规定要求白光发光二极管的光源必须达到90%的NTSC、95%的NTSC或是100%的NTSC。否则必须回到第三步骤(63)重新调配荧光粉的浓度或是比例等。The fourth step (64) is to calculate the area formed by the chromaticity coordinates of the first mixed light spectrum separated into red, green, and blue primary colors by a color filter. First, the first mixed light spectrum is color-separated into red, green and blue according to the filtering spectrum of the color filter. Then, calculate the color coordinates of red, green and blue in CIE. With the color coordinates of red, green and blue, the area enclosed by the CIE coordinates of red, green and blue can be calculated. This area can be compared with the area defined by NTSC. For example, when the area enclosed by the calculated color coordinates of the three primary colors is about 75% of the area defined by NTSC, it means that the color saturation is 75% of NTSC. According to the algorithm of the present invention, it can be stipulated that the light source of the white light emitting diode must meet 90% NTSC, 95% NTSC or 100% NTSC. Otherwise, it is necessary to go back to the third step (63) to readjust the concentration or ratio of the phosphor powder.
第五步骤(65)计算分色后的红色、绿色与蓝色的色度坐标所组成的白光的色度坐标。经过彩色滤镜分色后的三原色,所组成的白光的色坐标有可能离开标准的白光或是商业规格所要求的白光,所以必须同时检验混色后的白光是否可以达到要求。商业上的规格,可以要求白光的色坐标是位于某一黑体辐射的色温,例如可以要求白光的色温是6500K的白光色坐标或是6000K的白光色坐标。The fifth step (65) is to calculate the chromaticity coordinates of the white light composed of the chromaticity coordinates of red, green and blue after color separation. After the three primary colors are separated by the color filter, the color coordinates of the white light formed may deviate from the standard white light or the white light required by commercial specifications, so it is necessary to check whether the white light after color mixing can meet the requirements. Commercial specifications may require that the color coordinates of white light be at the color temperature radiated by a certain black body. For example, the color temperature of white light may be required to be 6500K or 6000K.
搭配图6的流程图,本发明同时提供一种高演色性白光发光二极管的配制的方框图。请参阅图7,一目标色温的黑体辐射产生器(71)可以提供某一特定色温的黑体辐射的可见光频谱,其中色温的范围可从1500K~8000K之间。一第一数据库(72),用来存储各种发光二极管芯片及荧光粉的发射频谱。长波紫外光发光二极管芯片发射范围为365nm~380nm、紫光发光二极管芯片发射范围为380nm~420nm及蓝光发光二极管芯片发射范围为420nm~470nm。荧光粉的发光波长范围可介于480~580nm之间,组成可以为硅酸盐类,或是氧化物族系,例如:Together with the flow chart in FIG. 6 , the present invention also provides a block diagram for preparing a high color rendering white light emitting diode. Please refer to FIG. 7 , a black body radiation generator ( 71 ) of a target color temperature can provide a visible spectrum of black body radiation of a specific color temperature, wherein the color temperature ranges from 1500K to 8000K. A first database (72), used to store emission spectrums of various LED chips and phosphors. The emission range of the long-wave ultraviolet light-emitting diode chip is 365nm-380nm, the emission range of the purple-light light-emitting diode chip is 380nm-420nm, and the emission range of the blue-light light-emitting diode chip is 420nm-470nm. The emission wavelength range of phosphor powder can be between 480-580nm, and the composition can be silicate or oxide family, for example:
CaSc2O4:Ce(516nm); CaSc2O4 :Ce ( 516nm );
(MgCaSrBa)2SiO4:Eu(525nm);(MgCaSrBa) 2 SiO 4 :Eu (525nm);
Ca3Sc2Si3O12:Ce(455-507nm);Ca 3 Sc 2 Si 3 O 12 :Ce (455-507nm);
(Ca1.47Mg1.5Ce0.03)(Sc1.5Y0.5)Si3O12(455nm);(Ca 1.47 Mg 1.5 Ce 0.03 )(Sc 1.5 Y 0.5 )Si 3 O 12 (455nm);
(Ca2.97Ce0.03)Sc2(Si,Ge)3O12。(Ca 2.97 Ce 0.03 )Sc 2 (Si, Ge) 3 O 12 .
以及荧光粉的发光波长范围介于600~650nm之间,主要为氮化物族系以及硫化物族系,例如:And the emission wavelength range of the phosphor is between 600-650nm, mainly nitride and sulfide groups, for example:
CaAlSiN3:Eu(650nm);CaAlSiN 3 :Eu (650nm);
(CaEu)AlSiN3(648nm);(CaEu)AlSiN 3 (648nm);
(SrCa)AlSiN3:Eu(630nm);(SrCa)AlSiN 3 :Eu (630nm);
SrGa2S4:Eu(645nm)。SrGa 2 S 4 :Eu (645nm).
任何本领域普通技术人员,理应理解可以有其他种的荧光粉可以应用到本发明中,例如石榴石族系,氮氧化物等。Anyone skilled in the art should understand that other kinds of phosphors can be used in the present invention, such as garnet series, oxynitride and so on.
频谱计算单元(73)从第一数据库(72)中得到发光二极管芯片及两种不同荧光粉的发射频谱,并且先判断荧光粉浓度。经由频谱计算单元(73)得一混光频谱。请参阅图8,为发光二极管芯片与两种不同荧光粉混合的混光频谱。在图8中,曲线A为发光二极管芯片的发射频谱,曲线B及曲线C为荧光粉的发射频谱,曲线D为混合后的混合发射频谱。The spectrum calculation unit (73) obtains the emission spectrum of the light-emitting diode chip and two different phosphors from the first database (72), and first determines the concentration of the phosphors. Obtain a mixed light spectrum through the spectrum calculation unit (73). Please refer to Figure 8, which is the mixed light spectrum of LED chips mixed with two different phosphors. In FIG. 8 , curve A is the emission spectrum of the light-emitting diode chip, curves B and C are the emission spectrum of phosphor powder, and curve D is the mixed emission spectrum after mixing.
频谱比较单元(74)比较目标色温的黑体辐射的可见光频谱与混光频谱的频谱相似度。如混光频谱达到频谱比对相似(Yes),则得到一合适的白光发射频谱;如混合发射频谱不达到频谱比对相似(No),则需调整荧光粉的浓度(76)或是重新选择荧光粉(77),直到目标色温的黑体辐射的可见光频谱与混合发射频谱的频谱比对达到相似为止。The spectrum comparison unit (74) compares the spectrum similarity between the visible light spectrum and the mixed light spectrum of the blackbody radiation of the target color temperature. If the mixed light spectrum reaches the spectral comparison similarity (Yes), then a suitable white light emission spectrum is obtained; if the mixed emission spectrum does not reach the spectral comparison similarity (No), it is necessary to adjust the concentration of the phosphor (76) or re-select Phosphor powder (77), until the spectrum ratio of the visible light spectrum of the blackbody radiation of the target color temperature and the mixed emission spectrum reaches similarity.
本发明同时提供一种高演色性白光发光二极管的配制的方框图,请参阅图10。一目标色温的黑体辐射产生器(100)可以提供某一特定色温的黑体辐射的可见光频谱,其中色温的范围可在1500K~8000K之间。一第一数据库(101),用来存储各种发光二极管芯片及荧光粉的发射频谱。长波紫外光发光二极管芯片发射范围为365nm~380nm、紫光发光二极管芯片发射范围为380nm~420nm及蓝光发光二极管芯片发射范围为420nm~470nm。荧光粉的发光波长范围可介于480~580nm之间,组成可以为硅酸盐类,或是氧化物族系,例如:The present invention also provides a configuration block diagram of a high color rendering white light emitting diode, please refer to FIG. 10 . A black body radiation generator (100) of a target color temperature can provide a visible spectrum of black body radiation of a specific color temperature, wherein the range of the color temperature can be between 1500K-8000K. A first database (101), used to store emission spectra of various LED chips and phosphors. The emission range of the long-wave ultraviolet light-emitting diode chip is 365nm-380nm, the emission range of the purple-light light-emitting diode chip is 380nm-420nm, and the emission range of the blue-light light-emitting diode chip is 420nm-470nm. The emission wavelength range of phosphor powder can be between 480-580nm, and the composition can be silicate or oxide family, for example:
CaSc2O4:Ce(516nm); CaSc2O4 :Ce ( 516nm );
(MgCaSrBa)2SiO4:Eu(525nm);(MgCaSrBa) 2 SiO 4 :Eu (525nm);
Ca3Sc2Si3O12:Ce(455-507nm);Ca 3 Sc 2 Si 3 O 12 :Ce (455-507nm);
(Ca1.47Mg1.5Ce0.03)(Sc1.5Y0.5)Si3O12(455nm);(Ca 1.47 Mg 1.5 Ce 0.03 )(Sc 1.5 Y 0.5 )Si 3 O 12 (455nm);
(Ca2.97Ce0.03)Sc2(Si,Ge)3O12。(Ca 2.97 Ce 0.03 )Sc 2 (Si, Ge) 3 O 12 .
以及荧光粉的发光波长范围介于600~650nm之间,主要为氮化物族系以及硫化物族系,例如:And the emission wavelength range of the phosphor is between 600-650nm, mainly nitride and sulfide groups, for example:
CaAlSiN3:Eu(650nm);CaAlSiN 3 :Eu (650nm);
(CaEu)AlSiN3(648nm);(CaEu)AlSiN 3 (648nm);
(SrCa)AlSiN3:Eu(630nm);(SrCa)AlSiN 3 :Eu (630nm);
SrGa2S4:Eu(645nm)。SrGa 2 S 4 :Eu (645nm).
任何本领域普通技术人员,理应理解可以有其他种的荧光粉可以应用到本发明中,例如石榴石族系,氮氧化物等。Anyone skilled in the art should understand that other kinds of phosphors can be used in the present invention, such as garnet series, oxynitride and so on.
频谱计算单元(102)从第一数据库(101)中得到的发光二极管芯片及两种不同荧光粉的发射频谱,并且借助比较从目标色温的黑体辐射产生器(100)产升目标色温的黑体辐射的可见光频谱,判断荧光粉浓度。经由频谱计算单元(102)得一混光频谱。The spectrum calculation unit (102) obtains the emission spectra of the light-emitting diode chip and two different phosphors from the first database (101), and compares the black body radiation of the target color temperature from the black body radiation generator (100) of the target color temperature. Visible light spectrum to judge phosphor concentration. Obtain a mixed light spectrum through the spectrum calculation unit (102).
第二数据库(103)存储且提供彩色滤镜的滤光频谱。请参阅图9,显示一种彩色滤镜的频谱,其中各色滤镜的滤光频谱会有一部分的交错。由于各色滤镜的滤光频谱的交错,即使是高演色性的白光发光二极管的光源,通过这样的滤光频谱也会降低色彩的饱和度。这是因为蓝色光源经过这样的滤光频谱后会有一部分的绿色光,这表示原始的各色光的光源均会对最后的色彩产生影响。当计算后的混光频谱进入到第二数据库(103)之后会分色成红色,绿色,与蓝色的三原色。这三原色的数据进入到色彩饱和度计算单元(104)与混色计算单元(105)后,分别计算出经过分色后的三原色的色彩饱和度与分色后的三原色所组成的白光的色坐标。The second database (103) stores and provides filter spectra of color filters. Please refer to FIG. 9 , which shows a frequency spectrum of a color filter, in which the filtering spectrum of each color filter has a part of interlacing. Due to the interlacing of the filter spectrums of the filters of various colors, even for a light source of a white light-emitting diode with high color rendering, the color saturation will be reduced through such filter spectrums. This is because the blue light source will have a part of green light after passing through such a filter spectrum, which means that the original light source of each color light will have an impact on the final color. After the calculated mixed light spectrum is entered into the second database (103), it will be separated into three primary colors of red, green and blue. After the data of the three primary colors enter the color saturation calculation unit (104) and the color mixing calculation unit (105), the color saturation of the three primary colors after color separation and the color coordinates of white light composed of the three primary colors after color separation are calculated respectively.
计算的结果进入到比较单元(107)后,会判断色彩饱和度与分色后的三原色所组成的白光的色坐标是否满足要求。当其中之一不满足时均可会回到第一数据库(101)重新选择荧光粉或是频谱计算单元(102)重新调配荧光粉的浓度,使得色彩饱和度计算单元(104)与混色计算单元(105)的结果均满足要求。色彩饱和度的条件,可以定为90%的NTSC、95%的NTSC或是100%的NTSC。而混色后的白光可以要求标准的白光或是商业规格所要求的白光,其中商业上的规格,可以要求白光的色坐标是位于某一黑体辐射的色温,例如可以要求白光的色温是6500K的白光色坐标或是6000K的白光色坐标。After the calculation result enters the comparison unit (107), it will be judged whether the color coordinates of the white light composed of the color saturation and the three primary colors after color separation meet the requirements. When one of them is not satisfied, it can return to the first database (101) to reselect the phosphor or the spectrum calculation unit (102) to re-allocate the concentration of the phosphor, so that the color saturation calculation unit (104) and the color mixing calculation unit The results of (105) all meet the requirements. The condition of color saturation can be set as 90% NTSC, 95% NTSC or 100% NTSC. The white light after color mixing can require standard white light or white light required by commercial specifications. Among them, commercial specifications can require the color coordinates of white light to be at the color temperature of a certain black body radiation. For example, white light with a color temperature of 6500K can be required. Color coordinates or white light color coordinates of 6000K.
图11显示本发明的配置高演色性白光发光二极管的系统方框图。一目标色温的黑体辐射的频谱产生器(110),可以提供某一特定色温的黑体辐射的可见光频谱,其中色温的范围可在1500K~8000K之间。FIG. 11 shows a block diagram of a system configured with high color rendering white light emitting diodes of the present invention. A blackbody radiation spectrum generator (110) of a target color temperature can provide a blackbody radiation visible light spectrum of a specific color temperature, wherein the color temperature can range from 1500K to 8000K.
第一数据库(111),用来存储各种发光二极管芯片及荧光粉的发射频谱。长波紫外光发光二极管芯片发射范围为365nm~380nm、紫光发光二极管芯片发射范围为380nm~420nm及蓝光发光二极管芯片发射范围为420nm~470nm。荧光粉的发光波长范围可介于480~580nm之间,组成可以为硅酸盐类,或是氧化物族系,例如:The first database (111) is used to store emission spectra of various LED chips and phosphors. The emission range of the long-wave ultraviolet light-emitting diode chip is 365nm-380nm, the emission range of the purple-light light-emitting diode chip is 380nm-420nm, and the emission range of the blue-light light-emitting diode chip is 420nm-470nm. The emission wavelength range of phosphor powder can be between 480-580nm, and the composition can be silicate or oxide family, for example:
CaSc2O4:Ce(516nm); CaSc2O4 :Ce ( 516nm );
(MgCaSrBa)2SiO4:Eu(525nm);(MgCaSrBa) 2 SiO 4 :Eu (525nm);
Ca3Sc2Si3O12:Ce(455-507nm);Ca 3 Sc 2 Si 3 O 12 :Ce (455-507nm);
(Ca1.47Mg1.5Ce0.03)(Sc1.5Y0.5)Si3O12(455nm);(Ca 1.47 Mg 1.5 Ce 0.03 )(Sc 1.5 Y 0.5 )Si 3 O 12 (455nm);
(Ca2.97Ce0.03)Sc2(Si,Ge)3O12。(Ca 2.97 Ce 0.03 )Sc 2 (Si, Ge) 3 O 12 .
以及荧光粉的发光波长范围介于600~650nm之间,主要为氮化物族系以及硫化物族系,例如:And the emission wavelength range of the phosphor is between 600-650nm, mainly nitride and sulfide groups, for example:
CaAlSiN3:Eu(650nm);CaAlSiN 3 :Eu (650nm);
(CaEu)AlSiN3(648nm);(CaEu)AlSiN 3 (648nm);
(SrCa)AlSiN3:Eu(630nm);(SrCa)AlSiN 3 :Eu (630nm);
SrGa2S4:Eu(645nm)。SrGa 2 S 4 :Eu (645nm).
任何本领域普通技术人员,理应理解可以有其他种的荧光粉可以应用到本发明中,例如石榴石族系、氮氧化物等。Anyone skilled in the art should understand that other kinds of phosphors can be used in the present invention, such as garnet series, oxynitride and so on.
频谱计算单元(112)从第一数据库(111)中得到发光二极管芯片及两种不同荧光粉的发射频谱,并且先判断荧光粉浓度。经由频谱计算单元(112)得一混光频谱。The spectrum calculation unit (112) obtains the emission spectrum of the LED chip and two different phosphors from the first database (111), and first determines the concentration of the phosphors. Obtain a mixed light spectrum through the spectrum calculation unit (112).
频谱比较单元(113)比较目标色温的黑体辐射的可见光频谱与混光频谱的频谱相似度。比较结果为第一阶近似(114)。当第一阶近似的结果是可以的(Yes),则往下一阶段进行。当第一阶近似的结果是不行的(No),则回到频谱计算单元(112),重新找出其他的荧光粉的浓度,直到第一阶近似(114)的结果是可以的(Yes)为止。The spectrum comparison unit (113) compares the spectrum similarity between the visible light spectrum and the mixed light spectrum of the blackbody radiation of the target color temperature. The result of the comparison is a first order approximation (114). When the result of the first-order approximation is acceptable (Yes), proceed to the next stage. When the result of the first-order approximation is not possible (No), then return to the spectrum calculation unit (112), and find out the concentration of other phosphors again, until the result of the first-order approximation (114) is acceptable (Yes) until.
第二数据库(116)存储且提供彩色滤镜的滤光频谱。当计算后的混光频谱进入到分色单元(115)之后会分色成红色、绿色与蓝色的三原色。这三原色的数据进入到色彩饱和度计算单元(117)与三原色混色计算单元(118)后,分别计算出经过分色后的三原色的色彩饱和度与分色后的三原色所组成的白光的色坐标。A second database (116) stores and provides filter spectra of color filters. When the calculated mixed light spectrum enters the color separation unit (115), it will be separated into three primary colors of red, green and blue. After the data of the three primary colors enter the color saturation calculation unit (117) and the three primary color mixing calculation unit (118), respectively calculate the color saturation of the three primary colors after color separation and the color coordinates of the white light formed by the three primary colors after color separation .
计算的结果进入到比较单元(119)后,会判断色彩饱和度与分色后的三原色所组成的白光的色坐标是否满足要求。当其中之一不满足时均可会回到频谱计算单元(112)重新调配荧光粉的浓度,使得色彩饱和度计算单元(117)与三原色混色计算单元(118)的结果均满足要求。色彩饱和度的条件,可以定为90%的NTSC、95%的NTSC或是100%的NTSC。而混色后的白光可以要求标准的白光或是商业规格所要求的白光,其中商业上的规格,可以要求白光的色坐标是位于某一黑体辐射的色温,例如可以要求白光的色温是6500K的白光色坐标或是6000K的白光色坐标。After the calculation result enters the comparison unit (119), it will judge whether the color coordinates of the white light composed of the color saturation and the three primary colors after color separation meet the requirements. When one of them is not satisfied, it will return to the spectrum calculation unit (112) to re-adjust the concentration of phosphor, so that the results of the color saturation calculation unit (117) and the three primary color mixing calculation unit (118) all meet the requirements. The condition of color saturation can be set as 90% NTSC, 95% NTSC or 100% NTSC. The white light after color mixing can require standard white light or white light required by commercial specifications. Among them, commercial specifications can require the color coordinates of white light to be at the color temperature of a certain black body radiation. For example, white light with a color temperature of 6500K can be required. Color coordinates or white light color coordinates of 6000K.
图12显示本发明的高色彩饱和度发光二极管背光模块,NTSC标准,与一般背光的CIE1931色度坐标示意图。当使用本发明的方法或是系统,相较于一般的白光发光二极管的光源可以提升色彩饱和度。在图12中,使用本发明的方式的三原色是用三角型所标示的,其中色彩饱和度可以由三角型所围成的三角形面积表示。相较于由○所围成的三角形面积,更接近由正方形所围成的三角形面积。这表示本发明可以具有更佳的色彩饱和度。FIG. 12 shows a schematic diagram of CIE1931 chromaticity coordinates of the high color saturation LED backlight module of the present invention, NTSC standard, and a general backlight. When using the method or system of the present invention, the color saturation can be improved compared with the general white light-emitting diode light source. In FIG. 12 , the three primary colors using the method of the present invention are marked by triangles, wherein the color saturation can be represented by the area of the triangle enclosed by the triangles. Compared with the area of the triangle surrounded by ○, it is closer to the area of the triangle surrounded by squares. This means that the present invention can have better color saturation.
本发明除可为上述实施例所述混合两种荧光粉之外,前述混合的荧光粉数量也可增加为三种,如此可使本发明更能符合实际应用的所需。当然实际运用时并不局限上述两种或三种荧光粉的实施方式,必要时可使用三种以上的荧光粉达到使用者的需求。In addition to mixing two phosphor powders as described in the above embodiments, the present invention can also increase the number of phosphor powders mixed to three, so that the present invention can better meet the needs of practical applications. Of course, the actual application is not limited to the above-mentioned two or three types of phosphors, and more than three types of phosphors can be used to meet the needs of users if necessary.
从上述实施例中可看出本发明的手段,是使用Planck方程式计算设定温度的黑体辐射的频谱,用此频谱计算出多种荧光粉的第一近似浓度。依照各荧光粉的第一近似浓度调配后计算出发光二极管混色后的发光频谱,并且依此发光频谱计算经过彩色滤镜后的色彩饱和度以及再混光成白光的色坐标,借以修正荧光粉的浓度,或是选择其他的荧光粉。It can be seen from the above embodiments that the means of the present invention is to use the Planck equation to calculate the spectrum of black body radiation at a set temperature, and use this spectrum to calculate the first approximate concentration of various phosphors. According to the first approximate concentration of each phosphor powder, the emission spectrum of the light-emitting diode after color mixing is calculated, and the color saturation after the color filter and the color coordinates of the mixed light into white light are calculated based on the emission spectrum, so as to correct the phosphor powder concentration, or choose other phosphors.
利用本发明的手段,可达成可快速的调配出高色彩饱和度的发光二极管背光模块的功效,并且可大幅降低尝试错误的时间成本。Utilizing the means of the present invention can achieve the effect of quickly deploying the LED backlight module with high color saturation, and can greatly reduce the time cost of trial and error.
从本发明手段与具有的功效中,可以得到本发明具有诸多的优点。首先,不需要经由尝试错误的方式即可找出荧光粉的调配比例。同时,当有多种类的荧光粉可供调配时,可大幅降低研发时间。From the means and effects of the present invention, it can be obtained that the present invention has many advantages. First, it is not necessary to find out the mixing ratio of the phosphor powder by trial and error. At the same time, when there are many types of phosphors available for deployment, the development time can be greatly reduced.
显然地,依照上面实施例中的描述,本发明可能有许多的修正与差异。因此需要在其附加的权利要求项的范围内加以理解,除了上述详细的描述外,本发明还可以广泛地在其他的实施例中施行。上述仅为本发明的优选实施例而已,并非用以限定本发明的权利要求书的范围;凡其它在未脱离本发明所揭示的精神下所完成的等效改变或修饰,均应包含在下述权利要求书的范围内。Obviously, according to the description in the above embodiments, the present invention may have many modifications and differences. It is therefore to be understood, within the scope of the appended claims, that the invention may be practiced broadly in other embodiments than the foregoing detailed description. The above are only preferred embodiments of the present invention, and are not intended to limit the scope of the claims of the present invention; all other equivalent changes or modifications that do not deviate from the spirit disclosed in the present invention should be included in the following within the scope of the claims.
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