CN101781452A - Product of polyurethane-glass fiber resin compound material and method for preparing same - Google Patents
Product of polyurethane-glass fiber resin compound material and method for preparing same Download PDFInfo
- Publication number
- CN101781452A CN101781452A CN201010122412A CN201010122412A CN101781452A CN 101781452 A CN101781452 A CN 101781452A CN 201010122412 A CN201010122412 A CN 201010122412A CN 201010122412 A CN201010122412 A CN 201010122412A CN 101781452 A CN101781452 A CN 101781452A
- Authority
- CN
- China
- Prior art keywords
- glass fiber
- fiber resin
- polyurethane
- product
- urethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011347 resin Substances 0.000 title claims abstract description 54
- 229920005989 resin Polymers 0.000 title claims abstract description 54
- 239000003365 glass fiber Substances 0.000 title claims abstract description 50
- 239000000463 material Substances 0.000 title claims abstract description 24
- 150000001875 compounds Chemical class 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title description 6
- 229920005830 Polyurethane Foam Polymers 0.000 claims abstract description 15
- 239000011496 polyurethane foam Substances 0.000 claims abstract description 15
- 229920002635 polyurethane Polymers 0.000 claims abstract description 13
- 239000004814 polyurethane Substances 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000006260 foam Substances 0.000 claims abstract description 6
- 238000005187 foaming Methods 0.000 claims abstract description 5
- 238000005507 spraying Methods 0.000 claims abstract description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 24
- 239000007921 spray Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 239000003973 paint Substances 0.000 claims description 3
- 229920006305 unsaturated polyester Polymers 0.000 claims description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000007592 spray painting technique Methods 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 239000011152 fibreglass Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000009527 percussion Methods 0.000 description 1
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 description 1
Images
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention discloses a product of polyurethane-glass fiber resin compound material, which comprises a polyurethane foam layer and a glass fiber resin layer, wherein the glass fiber resin layer forms a hollow cavity, and the polyurethane foam layer is filled in the hollow cavity after the polyurethane is foamed by a chemical reaction. The preparation method comprises the following steps of: spraying a mold releasing agent in a mould of a prefabricated model; uniformly spraying the glass fiber resin on the inner surface of the mould, and forming the glass fiber resin layer provided with the hollow cavity after the glass fiber resin is cured; injecting a low-density polyurethane raw material in the mould, and foaming the polyurethane raw material by performing the chemical reaction to fill the polyurethane in the hollow cavity of the glass fiber resin layer to obtain the polyurethane foam layer; and after foaming formation, opening the mould to take the product out, and performing repairing and external spray-painting to complete the manufacturing. The product of the invention possesses dual-characteristics of hardness of glass steel as well as strength of low-density polyurethane inner core foam and is low in overall density and high in impact strength, so that the product wins wide markets.
Description
Technical field
The present invention relates to the building fittings adornment field, especially relate to urethane and glass fiber resin compound material product and manufacture method thereof.
Background technology
Polyurethane material is to be widely used in industry-by-industry, also be traditional formed materials such as architectural Rome commonly used column cap and ornament, urethane is divided into low-density polyurethane (150～250 kilograms per cubic meter) and high density polyurethane (300～500 kilograms per cubic meter) according to the density size.Resin then is toy, mould traditional materials such as product, artwork.
At present, FRP Columns goods and ornament on the market all are to be made by pure urethane material, about 300～500 kilograms per cubic meter of density, belong to high density polyurethane, be characterized in that density is big, the price height, but surperficial resistance to impact shock is low, is subjected to percussion damaged easily.
In view of having the defective that FRP Columns goods and ornament exist price height, cracky now, the inventor develops a kind of matrix material specially, and this case produces thus.
Summary of the invention
One of purpose of the present invention provides a kind of urethane and glass fiber resin compound material product, to reduce cost, improves the product shock resistance.
Two of purpose of the present invention provides a kind of method of making urethane and glass fiber resin compound material product.
In order to reach above-mentioned purpose, the present invention by the following technical solutions:
Urethane and glass fiber resin compound material product comprise polyurethane foam and glass fiber resin layer, and the glass fiber resin layer forms hollow cavity, and polyurethane foam is foam filled in hollow cavity through chemical reaction by urethane.
Further, the thickness of described glass fiber resin layer is 2～3mm.
Further, the blending ratio of resin and glass fibre is 100: 2 in the described glass fiber resin.
Further, described resin is a unsaturated polyester.
A kind of method of making urethane and glass fiber resin compound material product, its step is as follows:
The first step: in the mould of preset model, spray parting agent (claiming releasing agent again);
Second step: glass fiber resin be coated with equably be sprayed on the mould inner surface, wait glass fiber resin to solidify after, form glass fiber resin layer with hollow cavity;
The 3rd step: in the low-density polyurethane material injecting mould, foam, make the hollow cavity of urethane filled glass fiber resin layer, form polyurethane foam through chemical reaction;
The 4th step: after waiting foaming, product is taken out in die sinking, through studying for a second time courses one has flunked, spraying paint, finishes the processing and fabricating of whole prod outward again.
Further, described parting agent is a kind of organosilicon.
After adopting such scheme, the invention has the beneficial effects as follows: since with the strong fiber glass resin of rigidity height, hardness as product subsurface, with low density (150-250Kg/m
3) hard polyurethane foams fill as the product inner core, replace original high-density (300-500Kg/m thus
3) polyurethane products, reduce the raw-material consumption of urethane greatly, thereby reduced the cost of manufacturing product, has stronger supporting role again, so, product of the present invention not only has the hardness of glass fiber resin and polyurethane foam intensity, flexible double characteristic, and the product global density is low, impact strength good, and cost is also low.
Description of drawings
Fig. 1 is the structural representation of product of the present invention;
Fig. 2 is the process flow sheet of manufacture method of the present invention.
Embodiment
As shown in Figure 1, urethane and glass fiber resin compound material product that the present invention discloses comprise polyurethane foam 1 and glass fiber resin layer 2.
Glass fiber resin layer 2 constitutes the top layer of product (FRP Columns goods and ornament) and forms hollow cavity 21; The thickness of glass fiber resin layer 2 is 2～3mm, and glass fiber resin is the existing material of selling on the market, also can prepare voluntarily, and the blending ratio of resin and glass fibre is 100: 2; Resin is a unsaturated polyester.
Polyurethane foam 1 is foam filled in hollow cavity 21 through chemical reaction by urethane, constitutes the inner core of product.
The present invention makes the method for urethane and glass fiber resin compound material product, and as shown in Figure 2, step is as follows:
In the mould of preset model, spray parting agent (specifically be organosilicon, claim releasing agent again) earlier; With the resin of pre-designed set time, be added with corresponding glass fibre again, the mode with being coated with spray acts on the mould inner surface equably; After glass fiber resin curing, promptly constitute the top layer of product, form glass fiber resin layer 2 with hollow cavity 21; Then, in hard low-density polyurethane material injecting mould, urethane raw is chemical reaction under the effect of catalysis or temperature, and behind the foaming, the hollow cavity of urethane filled glass fiber resin layer forms polyurethane foam 1, promptly constitutes the inner core of product; Take out product at last, through studying for a second time courses one has flunked, spraying paint, finish the product processing and fabricating outward again.
The foregoing description products obtained therefrom not only has the hardness of glass reinforced plastic and polyurethane foam intensity, flexible double characteristic, and the product global density is low, impact strength good.
Claims (6)
1. urethane and glass fiber resin compound material product, it is characterized in that: comprise polyurethane foam and glass fiber resin layer, the glass fiber resin layer forms hollow cavity, and polyurethane foam is foam filled in hollow cavity through chemical reaction by urethane.
2. according to described urethane of claim 1 and glass fiber resin compound material product, it is characterized in that: the thickness of described glass fiber resin layer is 2～3mm.
3. according to described urethane of claim 1 and glass fiber resin compound material product, it is characterized in that: the blending ratio of resin and glass fibre is 100: 2 in the described glass fiber resin.
4. according to described urethane of claim 1 and glass fiber resin compound material product, it is characterized in that: described resin is a unsaturated polyester.
5. method of making urethane and glass fiber resin compound material product is characterized in that step is as follows:
The first step: in the mould of preset model, spray parting agent;
Second step: glass fiber resin be coated with equably be sprayed on the mould inner surface, wait glass fiber resin to solidify after, form glass fiber resin layer with hollow cavity;
The 3rd step: in the low-density polyurethane material injecting mould, foam, make the hollow cavity of urethane filled glass fiber resin layer, form polyurethane foam through chemical reaction;
The 4th step: after waiting foaming, product is taken out in die sinking, through studying for a second time courses one has flunked, spraying paint, finishes the processing and fabricating of whole prod outward again.
6. according to the described a kind of method of making urethane and glass fiber resin compound material product of claim 5, it is characterized in that: described parting agent is a kind of organosilicon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010122412A CN101781452A (en) | 2010-03-05 | 2010-03-05 | Product of polyurethane-glass fiber resin compound material and method for preparing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010122412A CN101781452A (en) | 2010-03-05 | 2010-03-05 | Product of polyurethane-glass fiber resin compound material and method for preparing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101781452A true CN101781452A (en) | 2010-07-21 |
Family
ID=42521610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010122412A Pending CN101781452A (en) | 2010-03-05 | 2010-03-05 | Product of polyurethane-glass fiber resin compound material and method for preparing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101781452A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103866961A (en) * | 2012-12-13 | 2014-06-18 | 飞虎(厦门)聚氨酯制品有限公司 | Composite material polyurethane rigid foam decorative marble pillar |
| CN107096882A (en) * | 2017-06-13 | 2017-08-29 | 柳州智云科技有限公司 | Preparation method based on the casting molds of 3D printing and the mould |
| CN111961324A (en) * | 2020-08-28 | 2020-11-20 | 荆州市梅氏实业有限公司 | Enhanced glass fiber reinforced plastic and compression molding process thereof |
| CN116852780A (en) * | 2022-11-07 | 2023-10-10 | 马彦珍 | A method for preparing special-shaped composite panels |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62275133A (en) * | 1987-02-07 | 1987-11-30 | Toho Rayon Co Ltd | Carbon fiber reinforced thermoplastic resin composition |
| CN1228369A (en) * | 1998-03-11 | 1999-09-15 | 四川康达建材工业(集团)公司 | Glass fiber reinforced plastics insulating board and its making method |
| CN2859882Y (en) * | 2005-07-01 | 2007-01-17 | 苏峰 | Glass fiber reinforced plastic interlayer cable protection pipe |
| CN201050132Y (en) * | 2007-04-16 | 2008-04-23 | 肖中发 | Environment-friendly light packing member with double layer structure |
| CN201330728Y (en) * | 2008-12-05 | 2009-10-21 | 江苏中联风能机械有限公司 | Large-scale air cooling fan blade |
-
2010
- 2010-03-05 CN CN201010122412A patent/CN101781452A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62275133A (en) * | 1987-02-07 | 1987-11-30 | Toho Rayon Co Ltd | Carbon fiber reinforced thermoplastic resin composition |
| CN1228369A (en) * | 1998-03-11 | 1999-09-15 | 四川康达建材工业(集团)公司 | Glass fiber reinforced plastics insulating board and its making method |
| CN2859882Y (en) * | 2005-07-01 | 2007-01-17 | 苏峰 | Glass fiber reinforced plastic interlayer cable protection pipe |
| CN201050132Y (en) * | 2007-04-16 | 2008-04-23 | 肖中发 | Environment-friendly light packing member with double layer structure |
| CN201330728Y (en) * | 2008-12-05 | 2009-10-21 | 江苏中联风能机械有限公司 | Large-scale air cooling fan blade |
Non-Patent Citations (1)
| Title |
|---|
| 王禹阶等: "《玻璃钢与复合材料的生产及应用》", 30 November 2005, article ""玻璃钢与复合材料的生产及应用"", pages: 265 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103866961A (en) * | 2012-12-13 | 2014-06-18 | 飞虎(厦门)聚氨酯制品有限公司 | Composite material polyurethane rigid foam decorative marble pillar |
| CN107096882A (en) * | 2017-06-13 | 2017-08-29 | 柳州智云科技有限公司 | Preparation method based on the casting molds of 3D printing and the mould |
| CN107096882B (en) * | 2017-06-13 | 2023-03-21 | 柳州智云科技有限公司 | Casting mold based on 3D printing and preparation method of casting mold |
| CN111961324A (en) * | 2020-08-28 | 2020-11-20 | 荆州市梅氏实业有限公司 | Enhanced glass fiber reinforced plastic and compression molding process thereof |
| CN116852780A (en) * | 2022-11-07 | 2023-10-10 | 马彦珍 | A method for preparing special-shaped composite panels |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW201414600A (en) | Forming method of composite material | |
| CN101781452A (en) | Product of polyurethane-glass fiber resin compound material and method for preparing same | |
| CN102848510B (en) | A kind of preparation method of polyurethane material modeling | |
| CN101973101A (en) | Manufacturing process of recreation vehicle head | |
| CN203267335U (en) | Bathroom equipment | |
| CN101475738B (en) | Glass fibre reinforced plastic and leisure seat made thereof | |
| CN101824882B (en) | Manufacturing process of thermal insulating decorative panel of exterior wall | |
| CN102166409A (en) | Carbon fiber golf club shaft and formation method | |
| CN111251519B (en) | High-simulation manufacturing method of ornamental product with more than two shapes | |
| KR101340683B1 (en) | Manufacturing method of casting wooden pattern and the pattern obtaining the same method | |
| KR101280697B1 (en) | Manufacturing method of casting wooden pattern and the pattern obtaining the same method | |
| CN108032529A (en) | A kind of thermoplasticity answers material molding component core preparation method | |
| KR20110136460A (en) | Method for manufacturing street lamps made of reinforced plastics and structures thereof | |
| CN103192481A (en) | Method for producing double-material injection molding micro-foaming light-mass automobile decoration | |
| CN105965704B (en) | Processing of stone is combined lines method | |
| CN100482436C (en) | Fortified polyurethane foamed body and its manufacturing method | |
| CN103042631A (en) | rapid moulding method for mould | |
| CN101664357A (en) | Manufacturing process of molding art architecture urn or tomb | |
| CN101733640A (en) | Processing method for integrated Fiber Reinforced Plastic (FRP) mould of rail headstock | |
| CN201301534Y (en) | Novel stone-like decorative section bar | |
| CN2496682Y (en) | Artificial mountain karst cave structural member | |
| CN106217898A (en) | The production technology of glass toughening manure pit | |
| KR20190010953A (en) | Artificial formwork made from reinforced styrofoam and reinforced concrete and its manufacturing method | |
| CN1331648C (en) | Preparation method of imitation sandstone product | |
| CN201301550Y (en) | Novel decorative beam |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20100721 |