CN101967419A - Ceramic alloy lubricating oil special for dredging workboat engine and preparation method thereof - Google Patents
Ceramic alloy lubricating oil special for dredging workboat engine and preparation method thereof Download PDFInfo
- Publication number
- CN101967419A CN101967419A CN201010529140XA CN201010529140A CN101967419A CN 101967419 A CN101967419 A CN 101967419A CN 201010529140X A CN201010529140X A CN 201010529140XA CN 201010529140 A CN201010529140 A CN 201010529140A CN 101967419 A CN101967419 A CN 101967419A
- Authority
- CN
- China
- Prior art keywords
- lubricating oil
- ceramic alloy
- ceramal
- percent
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 39
- 229910002110 ceramic alloy Inorganic materials 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 230000000994 depressogenic effect Effects 0.000 claims abstract description 12
- 239000002199 base oil Substances 0.000 claims abstract description 9
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- 239000010703 silicon Substances 0.000 claims abstract description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000011195 cermet Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 2
- 238000005461 lubrication Methods 0.000 abstract description 8
- 229910052751 metal Inorganic materials 0.000 abstract description 8
- 239000002184 metal Substances 0.000 abstract description 8
- 239000000956 alloy Substances 0.000 abstract description 2
- 230000008878 coupling Effects 0.000 abstract description 2
- 238000010168 coupling process Methods 0.000 abstract description 2
- 238000005859 coupling reaction Methods 0.000 abstract description 2
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 238000005551 mechanical alloying Methods 0.000 abstract description 2
- 230000009467 reduction Effects 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000008139 complexing agent Substances 0.000 abstract 1
- 239000007822 coupling agent Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 17
- 239000000654 additive Substances 0.000 description 11
- 230000000996 additive effect Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 239000005069 Extreme pressure additive Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000012169 petroleum derived wax Substances 0.000 description 3
- 235000019381 petroleum wax Nutrition 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- -1 tripolyphosphate compound Chemical class 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010020843 Hyperthermia Diseases 0.000 description 1
- 241000532030 Menesia Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009102 absorption Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- UBPKTWNLRVFGJE-UHFFFAOYSA-N dialuminum benzene oxygen(2-) Chemical compound C1=CC=CC=C1.[O-2].[Al+3].[O-2].[O-2].[Al+3] UBPKTWNLRVFGJE-UHFFFAOYSA-N 0.000 description 1
- 239000010710 diesel engine oil Substances 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000036031 hyperthermia Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 230000009347 mechanical transmission Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention relates to ceramic alloy lubricating oil special for a dredging workboat engine, which consists of the following components in percentage by weight: 1 to 6 percent of ceramic alloy coupling agent, 75 to 85 percent of base oil, 0.1 to 0.5 percent of pour point depressant, 7 to 13 percent of viscosity index improver, 4 to 7 percent of complexing agent and 200 to 400ppm of non-silicon anti-foaming agent. In addition, the invention also discloses a preparation method thereof. The ceramic alloy lubricating oil forms a ceramic alloy material layer on the metal friction surface in a high-energy mechanical alloying ceramic alloy coupling mode, improves extreme pressure abrasive resistance of the lubricating oil, and has excellent functions of lubrication, protection, energy conservation and emission reduction, and the oil-saving rate of 3 to 8 percent.
Description
Technical field
The present invention relates to lubrication technical field, particularly relate to a kind of dredging engineering ship engine dedicated ceramic alloy lubricating oil and preparation method thereof.
Background technology
Galling, metallic corrosion, metal fatigue are the three big reasons that cause mechanical means to damage, internal authority mechanism statistics is thought " metallic substance three lossies account for gross industrial output value 30% ", the financial loss that the depreciation that produces because of the mechanical transmission frictional wear, maintenance, maintaining etc. cause be equivalent at present (?) Chinese whole GDP 10%.
According to " the national coasting port allocation plan " of the up-to-date promulgation of the Ministry of Communications, the Chinese Port construction is the Eleventh Five-Year Plan period entering great-leap-forward development period, and to 2010, the coasting port handling capacity reached 3,000,000,000 tons.But the coastal natural deep water coastline resource of China is in short supply at present, and the port and harbour construction room for development is little, and deep-cutting to build the berth or build man-made island on the shoal becomes a megatrend.Following 10 years or be the peak time of coastal area of china harbor approach enlarging more over a long time, from current coasting port planning and engineering progress, the dredging engineering amount was the gesture of further expansion.According to incompletely statistics, to 2010, the coastal area of china principal port needed to carry out the navigation channel with trailing suction hopper dredger and opens up the year capital construction of dark and port engineering and safeguard that the dredging amount is at 1.8~2 billion cubic meters.
Snagboat is mainly used in the sea of blowing at harbour and builds up fields and build and the waterway dredging engineering.Each busy harbour in the world, the snagboat of multiple shape on the job is digging water channel and rivers and creeks clearly, so that other boats and ships pass through smoothly.Along with China becomes world's major trading nation, the port construction development rapidly, the snagboat business spreads all over the country coastal and the inner hargour, the economic worth that its day creates is huge, created 1,000,000 yuan of the output values in average day, the whole nation has 400 snagboats that moving approximately, and an average snagboat year consumes 40 tons of lubricating oil, 6000 tons of oil fuel belong to high oil consumption, high profit industry.Past, the manufacturing of snagboat is mainly monopolized by American-European developed country, cost is very expensive, raising along with domestic shipbuilding technology, the Made in China shipyard is by the import, digestion and absorption technology, grasped the construction of snagboat gradually, but because the limitation of manufacturing process and material, no matter homemade snagboat core component-engine is in manufacturing technology level, still on the material horizontal, external gap is bigger, and itself belongs to high energy consumption snagboat, excessive risk, high profit, and it is heavy to be in load, move in the working condition bad working environment, although used the conventional lubrication oil production (as shell, Mobil, Great Wall, the Kunlun etc.), but because of conventional lubrication oil can't fundamentally change the defective of engine material itself, therefore, outstanding subject matter is embodied in: engine noise and vibration are bigger, serious wear, power output is relatively poor, and oil consumption is big, and maintenance is frequent, seriously reduce working efficiency, influenced economic benefit of enterprises.
Adding the performance that suitable anti-wear agent improves lubricating oil in lubricating oil is one of main path that addresses the above problem.Have the bibliographical information of ceramal lubricating oil additive research aspect at present both at home and abroad, for example, Chinese invention patent publication number CN1346873 discloses a kind of lubricating oil additive of based on cermet lubrication mechanism, it consists of the compound that contains molybdenum, boron, sulphur, phosphorus etc., though this additive has abrasion resistance preferably, it contains objectionable impuritiess such as a large amount of sulphur and phosphorus.Chinese invention patent publication number CN1765803 discloses a kind of metal/ceramic nano composite additive of self-rehabilitation and preparation method thereof, belong to the nanoparticle suspension technology, in addition, Chinese invention patent publication number CN101186856 discloses a kind of be used for lubricating oil nano-stage ceramic metal additive and preparation; Chinese invention patent publication number CN1324922 discloses a kind of sintering metal lubricant and manufacture method thereof, this lubricant is made up of 5~15% slip additive and 85~95% carrier fluid, wherein slip additive is to be formed by Nano metal powder, nano-ceramic powder and dispersion agent uniform mixing, therefore these three kinds of methods all remain further to be improved because the dispersion technology of nanoparticle in lubricating oil remains in big defective.U.S. Pat 4,844,825 disclose a kind of extreme-pressure additive based on the chlorination petroleum wax, can effectively improve the lubricated anti-friction performance of oil engine, but in and the metallic corrosion that causes of muriate, must add a large amount of alkaline sulfonates, make sulphur content can't be lower than 1%.U.S. Pat 7,423,000 discloses a kind of extreme-pressure additive of not phosphorous and metallic compound, but can't use the sulfur-bearing additive with avoiding.U.S. Pat 6,588,393 disclose the metal tripolyphosphate compound extreme-pressure additive of a kind of low sulfur content (5-250ppm), though sulphur content is extremely low, phosphorus content can't reach GF-4, the GF-5 standard.
Though what added above-mentioned additive in lubricating oil can reach anti-wear effect, the shortcoming that above-mentioned additive itself exists makes lubricating oil not reach national standard behind the adding lubricating oil, such as, easily precipitate, perishable, sulphur and phosphorus content are high.
Snagboat itself belongs to high energy consumption, excessive risk, high profit, and being in again in load weight, the working condition bad working environment and moving, although used conventional lubrication oil production (as shell, Mobil, Great Wall, the Kunlun etc.), but can't fundamentally change the defective of engine material itself because of conventional lubrication oil, therefore, outstanding subject matter is embodied in: engine noise and vibration are bigger, serious wear, power output is relatively poor, oil consumption is big, maintenance is frequent, has seriously reduced working efficiency, influences economic benefit of enterprises.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of dredging engineering ship engine dedicated ceramic alloy lubricating oil and preparation method thereof; by in plain oil, adding cermet couplant; utilize fricative heat to form the ceramal layer naturally at the facility surface of friction pair; make facility and lubricating oil be in the duplicate protection state; the function that has self-lubricating, selfreparing and maintain certainly; when effectively reducing friction, significantly reduce oil consumption.
For this reason, technical scheme of the present invention is as follows:
A kind of dredging engineering ship engine dedicated ceramic alloy lubricating oil, form by following components in weight percentage:
Cermet couplant 1~6%;
Base oil 75~85%;
Pour point depressant 0.1~0.5%;
Viscosity index improver 7~13%;
Recombiner 4~7%;
Non-silicon type antifoamer 200-400ppm (mg/kg).
Above-mentioned cermet couplant add-on is good with 2.0~5.5%, is the best with 4.5~5%.
Described base oil is the mixture of 150N, 500N base oil, and the weight ratio of the two is 1: 1.5~4.
Described pour point depressant is profit English connection V385 or V382.
Described viscosity index improver is homemade T614 or profit English connection SV261.
Described recombiner is sea connection 1185 recombiners.
A kind of preparation method of above-mentioned ceramal lubricating oil comprises:
Cermet couplant is mixed with base oil, pour point depressant, viscosity index improver, recombiner and non-silicon type antifoamer, stir, it is 60~80 ℃ that control mixes temperature, and churning time is 0.5~1.5h, prepares ceramal lubricating oil.
Above-mentioned preferably 65~75 ℃ of temperature, best results when temperature is 70~75 ℃ of mixing.
The mediation preparation time of above-mentioned dredging engineering ship engine dedicated ceramic alloy lubricating oil is 20~90 minutes, is good with 30~70 minutes, is the best with 40~50 minutes.
Cermet couplant is the extreme-pressure anti-friction additive that a kind of guide's thing that can form the ceramal structure is made, with the plain oil is carrier, because the coupling chemical structure has the interfacial activity functional group, can be adsorbed in to physical property the metallic surface, the localized hyperthermia that utilizes the friction high pressure of facility under the extreme pressure environment to cause drives chemical reaction, sharp impacts between the facility parts is impacted the dynamic conditions that guide's thing heat scission reaction is provided, form ceramic alloy material, and, make reaction propagate and proceed along with the constant impact of friction parts.Formed ceramal film has the characteristic of high rigidity, low frictional factor, and therefore after effect after a while, it is high lubricated that the surface of friction ceramalization is caused, and also reduced wearing and tearing because membrane stability is high.
Ceramal lubricating oil of the present invention is carrier with the lubricant; form the cermet material layer by mechanical alloying ceramal coupled modes at metal friction surface; can make the extreme pressure and antiwear behavior of plain oil improve more than 10 times; thereby realize lubricants performance and facility life-span duplicate protection effect; it has excellent lubrication, protection, energy-conservation, reduction of discharging effect, and rate of economizing gasoline reaches 3~8%.
Embodiment
The cermet couplant that uses among the present invention is the patented product of our company, and its patent No. is ZL200910067880.3, and its content comprises in the present invention.
Described cermet couplant is prepared from by following components in weight percentage: nano aluminum metal powder or aluminum contained compound 0.5~2%, magnesium-containing compound 0.25~2%, boronation alkylolamide 1~6%, titanium couplant 0.5~5% and stable dispersant 86~95%, wherein said aluminum contained compound are Burow Solution, tert.-butoxy aluminium, aluminum isopropylate, benzene aluminum oxide; Described magnesium-containing compound is magnesium hydroxide, alkanol magnesium, Menesia or Magnesium Stearate; Described stable dispersant is petroleum wax, chlorination petroleum wax or beeswax; Described titanium couplant is the silane alcohol base titanium.
The preparation method of above-mentioned cermet couplant comprises: the preparation of (1) boronation alkylolamide: by alkanolamine and boric acid with (2~4): 1 weight ratio 80~100 ℃, under nitrogen protection, react and made the boronation alkylolamide in 2~8 hours; (2) preparation of cermet couplant: under protection of inert gas nano aluminum metal powder or aluminum contained compound, magnesium-containing compound, boronation alkylolamide, titanium couplant and stable dispersant were reacted 0.5~3 hour under 50~80 ℃ of conditions, described rare gas element is nitrogen or argon gas.
Below by specific embodiment dredging engineering ship engine dedicated ceramic alloy lubricating oil of the present invention and preparation method thereof is described.
Embodiment 1
250 kilograms of cermet couplants, 1500 kilograms of 150N, 2750 kilograms of 500N, 20 kilograms of pour point depressant V382,495 kilograms of viscosity index improver T614,250 kilograms of recombiners 1185 and 200ppm kilfoam mixed stir, it is 75 ℃ that control mixes temperature, churning time is 120 minutes, prepares the dredging engineering ship engine dedicated ceramic alloy lubricating oil that meets national standard.
Embodiment 2
200 kilograms of cermet couplants, 1400 kilograms of 150N, 2800 kilograms of 500N, 15 kilograms of pour point depressant V385,510 kilograms of viscosity index improver T614,250 kilograms of recombiners 1185, the 400ppm kilfoam, it is 65 ℃ that control mixes temperature, and churning time is 150 minutes, prepares the dredging engineering ship engine dedicated ceramic alloy lubricating oil that meets national standard.
Embodiment 3
150 kilograms of cermet couplants, 1500 kilograms of 150N, 2750 kilograms of 500N, 20 kilograms of pour point depressant V382,495 kilograms of viscosity index improver profit English connection SV261,250 kilograms of recombiners 1185, the 200ppm kilfoam, it is 60 ℃ that control mixes temperature, and churning time is 60 minutes, prepares the dredging engineering ship engine dedicated ceramic alloy lubricating oil that meets national standard.
Embodiment 4
240 kilograms of cermet couplants, 1200 kilograms of 150N, 3050 kilograms of 500N, 25 kilograms of pour point depressant V382,460 kilograms of viscosity index improver T614,250 kilograms of recombiners 1185, the 300ppm kilfoam, it is 60 ℃ that control mixes temperature, and churning time is 60 minutes, prepares the dredging engineering ship engine dedicated ceramic alloy lubricating oil that meets national standard.
Embodiment 5
250 kilograms of cermet couplants, 1300 kilograms of 150N, 2950 kilograms of 500N, 20 kilograms of pour point depressant V382,495 kilograms of viscosity index improver T614,250 kilograms of recombiners 1185, the 200ppm kilfoam, it is 60 ℃ that control mixes temperature, and churning time is 60 minutes, prepares the dredging engineering ship engine dedicated ceramic alloy lubricating oil that meets national standard.
Wear-resistant, energy-saving and emission-reduction test condition:
1, the physicochemical property of lubricating oil test
Diesel engine oil standard GB 11122-2006, third-party test unit: oil inspection institute of the Dalian Maritime University (China Classification Society is specified feeler mechanism).
Test result:
The experiment proved that the above-mentioned lubricating oil that makes all meets national standard.
2, saving energy test
Third-party test unit: middle common factor is rolled into a ball Tianjin Navigation Bureau's snagboat.
Test result:
| Oil consumption (ton/ten thousand stere) | Rate of economizing gasoline % | |
| Plain oil | 3.59 | |
| Embodiment 1 | 3.34 | 7.0 |
| Embodiment 2 | 3.47 | 3.3 |
| Embodiment 3 | 3.42 | 4.7 |
| Embodiment 4 | 3.44 | 4.2 |
| Embodiment 5 | 3.37 | 6.1 |
Above-mentioned test is by the unified operating area and the time of dredging, finishes the basic identical statistical of carrying out for contrast base figure of earth volume.But because the difference of operating mode can cause the difference of oil consumption, after having considered factors such as operating mode, ship condition, meteorology, actual rate of economizing gasoline should be between 3%~5%.
Claims (10)
1. dredging engineering ship engine dedicated ceramic alloy lubricating oil, form by following components in weight percentage:
Cermet couplant 1~6%;
Base oil 75~85%;
Pour point depressant 0.1~0.5%;
Viscosity index improver 7~13%;
Recombiner 4~7%;
Non-silicon type antifoamer 200~400ppm
2. ceramal lubricating oil according to claim 1 is characterized in that, described cermet couplant add-on is 2.0~5.5%.
3. ceramal lubricating oil according to claim 2 is characterized in that, described cermet couplant add-on is 4.5~5%.
4. ceramal lubricating oil according to claim 1 is characterized in that, described base oil is the mixture of 150N, 500N base oil, and the weight ratio of the two is 1: 1.5~4.
5. ceramal lubricating oil according to claim 1 is characterized in that, described pour point depressant is profit English connection V385 or V382.
6. ceramal lubricating oil according to claim 1 is characterized in that, described viscosity index improver is homemade T614 or profit English connection SV261.
7. ceramal lubricating oil according to claim 1 is characterized in that, described recombiner is sea connection 1185 recombiners.
8. the preparation method of the described ceramal lubricating oil of claim 1 comprises: described cermet couplant and described base oil, pour point depressant, viscosity index improver, recombiner and non-silicon type antifoamer are stirred 0.5~1.5h down at 60~80 ℃.
9. preparation method according to claim 8 is characterized in that, 65~75 ℃ of described whipping temps.
10. preparation method according to claim 8 is characterized in that, described churning time is 30~70 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010529140XA CN101967419A (en) | 2010-11-02 | 2010-11-02 | Ceramic alloy lubricating oil special for dredging workboat engine and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010529140XA CN101967419A (en) | 2010-11-02 | 2010-11-02 | Ceramic alloy lubricating oil special for dredging workboat engine and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101967419A true CN101967419A (en) | 2011-02-09 |
Family
ID=43546645
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010529140XA Pending CN101967419A (en) | 2010-11-02 | 2010-11-02 | Ceramic alloy lubricating oil special for dredging workboat engine and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101967419A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525507A (en) * | 2013-10-11 | 2014-01-22 | 程志林 | Metal surface alloying agent and preparation method thereof |
| CN103725370A (en) * | 2012-10-15 | 2014-04-16 | 姚芳飞 | Pure petroleum base based energy-saving anti-friction novel lubricating oil and preparation method |
| CN104099157A (en) * | 2013-04-02 | 2014-10-15 | 杨伟光 | Metal ceramic lubricating oil couplant |
| CN107698972A (en) * | 2017-10-18 | 2018-02-16 | 徐宏伟 | A kind of joint of robot self-lubricating material and its preparation technology |
| CN114437856A (en) * | 2021-12-28 | 2022-05-06 | 河南产学研创能源研究院有限公司 | Methanol gasoline engine lubricating oil friction improver and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020072479A1 (en) * | 1999-01-19 | 2002-06-13 | Will F. Williamson | Non-phosphorous, non-metallic anti-wear compound and friction modifier |
| CN1523089A (en) * | 2003-09-08 | 2004-08-25 | 张汝春 | Graphite lubricating oil and its preparing method |
| CN101503645A (en) * | 2009-02-18 | 2009-08-12 | 天津东方舜能润滑材料有限公司 | Cermet couplant and preparation thereof |
-
2010
- 2010-11-02 CN CN201010529140XA patent/CN101967419A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020072479A1 (en) * | 1999-01-19 | 2002-06-13 | Will F. Williamson | Non-phosphorous, non-metallic anti-wear compound and friction modifier |
| CN1523089A (en) * | 2003-09-08 | 2004-08-25 | 张汝春 | Graphite lubricating oil and its preparing method |
| CN101503645A (en) * | 2009-02-18 | 2009-08-12 | 天津东方舜能润滑材料有限公司 | Cermet couplant and preparation thereof |
Non-Patent Citations (1)
| Title |
|---|
| 程志林等: "新型节能环保型陶瓷合金抗磨剂的制备及性能", 《交通节能与环保》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103725370A (en) * | 2012-10-15 | 2014-04-16 | 姚芳飞 | Pure petroleum base based energy-saving anti-friction novel lubricating oil and preparation method |
| CN104099157A (en) * | 2013-04-02 | 2014-10-15 | 杨伟光 | Metal ceramic lubricating oil couplant |
| CN103525507A (en) * | 2013-10-11 | 2014-01-22 | 程志林 | Metal surface alloying agent and preparation method thereof |
| CN103525507B (en) * | 2013-10-11 | 2015-04-29 | 程志林 | Metal surface alloying agent and preparation method thereof |
| CN107698972A (en) * | 2017-10-18 | 2018-02-16 | 徐宏伟 | A kind of joint of robot self-lubricating material and its preparation technology |
| CN114437856A (en) * | 2021-12-28 | 2022-05-06 | 河南产学研创能源研究院有限公司 | Methanol gasoline engine lubricating oil friction improver and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Asnida et al. | Copper (II) oxide nanoparticles as additve in engine oil to increase the durability of piston-liner contact | |
| CN101967419A (en) | Ceramic alloy lubricating oil special for dredging workboat engine and preparation method thereof | |
| CN100445353C (en) | Metal/ ceramic nano composite additive of self-rehabilitation and its preparation method | |
| CN103589487B (en) | A kind of high-speed overload equipment compounded lubricant and preparation method thereof | |
| CN103589967B (en) | A kind of natural gas engine valve retainer Han rare earth powder metallurgy | |
| CN1944607A (en) | High performance nano metal/mine ore powder composite self repairing agent and its preparing method | |
| CN104593132A (en) | Metal cutting fluid containing graphene dispersion solution and preparation method thereof | |
| CN102344846B (en) | Lubricating oil with negative wear self-repair function and preparation method thereof | |
| CN107384512A (en) | Micro-nano intelligent Base Metal abrasion self-repair material and its preparation and application | |
| CN105112124B (en) | A kind of lubricant compositions based on graphene or graphene oxide and its preparation method and application | |
| CN106867604B (en) | Graphene-hydrotalcite-like compound and preparation method and application thereof | |
| CN104804799A (en) | Energy-saving emission-reducing type gasoline engine oil and preparation method thereof | |
| CN101070505A (en) | Anti-wear restoring agent and its preparing method and use | |
| CN101503645B (en) | Cermet couplant and preparation thereof | |
| CN106085551A (en) | A kind of graphene-based wear-resistant self-repair material of high molecular nanometer alloy and its preparation method and application | |
| CN204583543U (en) | A kind of metal surface renovation agent is with preparing spray equipment | |
| CN101144045B (en) | Nano lubricating oil additive, preparation method and application thereof | |
| CN106467767A (en) | A kind of preparation method of micro crystal graphite alkene lube oil additive | |
| Xu et al. | Study on the tribological behaviors of the cylinder liner-piston ring in the ammonia-fueled engine | |
| CN102071086A (en) | Energy-saving and synergistic nano graphite lubricant additive and preparation method thereof | |
| CN104694214A (en) | Lubricating oil for marine Internal combustion engine | |
| CN102041143A (en) | Two-film lubricating oil | |
| CN101747985A (en) | Lubricating oil additive containing Ni-P powder recovered from chemical plating waste liquid and preparation and application thereof | |
| CN110205186A (en) | A kind of diesel engine oil formula | |
| CN102010775B (en) | Hydraulic oil and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110209 |