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CN101967419A - Ceramic alloy lubricating oil special for dredging workboat engine and preparation method thereof - Google Patents

Ceramic alloy lubricating oil special for dredging workboat engine and preparation method thereof Download PDF

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Publication number
CN101967419A
CN101967419A CN201010529140XA CN201010529140A CN101967419A CN 101967419 A CN101967419 A CN 101967419A CN 201010529140X A CN201010529140X A CN 201010529140XA CN 201010529140 A CN201010529140 A CN 201010529140A CN 101967419 A CN101967419 A CN 101967419A
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lubricating oil
ceramic alloy
ceramal
percent
preparation
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Inventor
朱文彬
程志林
吴以舜
柴重豪
张德友
言永祥
冯志国
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TIANJIN SURE ENERGY LUBRICATION MATERIAL CO Ltd
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TIANJIN SURE ENERGY LUBRICATION MATERIAL CO Ltd
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Abstract

The invention relates to ceramic alloy lubricating oil special for a dredging workboat engine, which consists of the following components in percentage by weight: 1 to 6 percent of ceramic alloy coupling agent, 75 to 85 percent of base oil, 0.1 to 0.5 percent of pour point depressant, 7 to 13 percent of viscosity index improver, 4 to 7 percent of complexing agent and 200 to 400ppm of non-silicon anti-foaming agent. In addition, the invention also discloses a preparation method thereof. The ceramic alloy lubricating oil forms a ceramic alloy material layer on the metal friction surface in a high-energy mechanical alloying ceramic alloy coupling mode, improves extreme pressure abrasive resistance of the lubricating oil, and has excellent functions of lubrication, protection, energy conservation and emission reduction, and the oil-saving rate of 3 to 8 percent.

Description

Dredging engineering ship engine dedicated ceramic alloy lubricating oil and preparation method thereof
Technical field
The present invention relates to lubrication technical field, particularly relate to a kind of dredging engineering ship engine dedicated ceramic alloy lubricating oil and preparation method thereof.
Background technology
Galling, metallic corrosion, metal fatigue are the three big reasons that cause mechanical means to damage, internal authority mechanism statistics is thought " metallic substance three lossies account for gross industrial output value 30% ", the financial loss that the depreciation that produces because of the mechanical transmission frictional wear, maintenance, maintaining etc. cause be equivalent at present (?) Chinese whole GDP 10%.
According to " the national coasting port allocation plan " of the up-to-date promulgation of the Ministry of Communications, the Chinese Port construction is the Eleventh Five-Year Plan period entering great-leap-forward development period, and to 2010, the coasting port handling capacity reached 3,000,000,000 tons.But the coastal natural deep water coastline resource of China is in short supply at present, and the port and harbour construction room for development is little, and deep-cutting to build the berth or build man-made island on the shoal becomes a megatrend.Following 10 years or be the peak time of coastal area of china harbor approach enlarging more over a long time, from current coasting port planning and engineering progress, the dredging engineering amount was the gesture of further expansion.According to incompletely statistics, to 2010, the coastal area of china principal port needed to carry out the navigation channel with trailing suction hopper dredger and opens up the year capital construction of dark and port engineering and safeguard that the dredging amount is at 1.8~2 billion cubic meters.
Snagboat is mainly used in the sea of blowing at harbour and builds up fields and build and the waterway dredging engineering.Each busy harbour in the world, the snagboat of multiple shape on the job is digging water channel and rivers and creeks clearly, so that other boats and ships pass through smoothly.Along with China becomes world's major trading nation, the port construction development rapidly, the snagboat business spreads all over the country coastal and the inner hargour, the economic worth that its day creates is huge, created 1,000,000 yuan of the output values in average day, the whole nation has 400 snagboats that moving approximately, and an average snagboat year consumes 40 tons of lubricating oil, 6000 tons of oil fuel belong to high oil consumption, high profit industry.Past, the manufacturing of snagboat is mainly monopolized by American-European developed country, cost is very expensive, raising along with domestic shipbuilding technology, the Made in China shipyard is by the import, digestion and absorption technology, grasped the construction of snagboat gradually, but because the limitation of manufacturing process and material, no matter homemade snagboat core component-engine is in manufacturing technology level, still on the material horizontal, external gap is bigger, and itself belongs to high energy consumption snagboat, excessive risk, high profit, and it is heavy to be in load, move in the working condition bad working environment, although used the conventional lubrication oil production (as shell, Mobil, Great Wall, the Kunlun etc.), but because of conventional lubrication oil can't fundamentally change the defective of engine material itself, therefore, outstanding subject matter is embodied in: engine noise and vibration are bigger, serious wear, power output is relatively poor, and oil consumption is big, and maintenance is frequent, seriously reduce working efficiency, influenced economic benefit of enterprises.
Adding the performance that suitable anti-wear agent improves lubricating oil in lubricating oil is one of main path that addresses the above problem.Have the bibliographical information of ceramal lubricating oil additive research aspect at present both at home and abroad, for example, Chinese invention patent publication number CN1346873 discloses a kind of lubricating oil additive of based on cermet lubrication mechanism, it consists of the compound that contains molybdenum, boron, sulphur, phosphorus etc., though this additive has abrasion resistance preferably, it contains objectionable impuritiess such as a large amount of sulphur and phosphorus.Chinese invention patent publication number CN1765803 discloses a kind of metal/ceramic nano composite additive of self-rehabilitation and preparation method thereof, belong to the nanoparticle suspension technology, in addition, Chinese invention patent publication number CN101186856 discloses a kind of be used for lubricating oil nano-stage ceramic metal additive and preparation; Chinese invention patent publication number CN1324922 discloses a kind of sintering metal lubricant and manufacture method thereof, this lubricant is made up of 5~15% slip additive and 85~95% carrier fluid, wherein slip additive is to be formed by Nano metal powder, nano-ceramic powder and dispersion agent uniform mixing, therefore these three kinds of methods all remain further to be improved because the dispersion technology of nanoparticle in lubricating oil remains in big defective.U.S. Pat 4,844,825 disclose a kind of extreme-pressure additive based on the chlorination petroleum wax, can effectively improve the lubricated anti-friction performance of oil engine, but in and the metallic corrosion that causes of muriate, must add a large amount of alkaline sulfonates, make sulphur content can't be lower than 1%.U.S. Pat 7,423,000 discloses a kind of extreme-pressure additive of not phosphorous and metallic compound, but can't use the sulfur-bearing additive with avoiding.U.S. Pat 6,588,393 disclose the metal tripolyphosphate compound extreme-pressure additive of a kind of low sulfur content (5-250ppm), though sulphur content is extremely low, phosphorus content can't reach GF-4, the GF-5 standard.
Though what added above-mentioned additive in lubricating oil can reach anti-wear effect, the shortcoming that above-mentioned additive itself exists makes lubricating oil not reach national standard behind the adding lubricating oil, such as, easily precipitate, perishable, sulphur and phosphorus content are high.
Snagboat itself belongs to high energy consumption, excessive risk, high profit, and being in again in load weight, the working condition bad working environment and moving, although used conventional lubrication oil production (as shell, Mobil, Great Wall, the Kunlun etc.), but can't fundamentally change the defective of engine material itself because of conventional lubrication oil, therefore, outstanding subject matter is embodied in: engine noise and vibration are bigger, serious wear, power output is relatively poor, oil consumption is big, maintenance is frequent, has seriously reduced working efficiency, influences economic benefit of enterprises.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of dredging engineering ship engine dedicated ceramic alloy lubricating oil and preparation method thereof; by in plain oil, adding cermet couplant; utilize fricative heat to form the ceramal layer naturally at the facility surface of friction pair; make facility and lubricating oil be in the duplicate protection state; the function that has self-lubricating, selfreparing and maintain certainly; when effectively reducing friction, significantly reduce oil consumption.
For this reason, technical scheme of the present invention is as follows:
A kind of dredging engineering ship engine dedicated ceramic alloy lubricating oil, form by following components in weight percentage:
Cermet couplant 1~6%;
Base oil 75~85%;
Pour point depressant 0.1~0.5%;
Viscosity index improver 7~13%;
Recombiner 4~7%;
Non-silicon type antifoamer 200-400ppm (mg/kg).
Above-mentioned cermet couplant add-on is good with 2.0~5.5%, is the best with 4.5~5%.
Described base oil is the mixture of 150N, 500N base oil, and the weight ratio of the two is 1: 1.5~4.
Described pour point depressant is profit English connection V385 or V382.
Described viscosity index improver is homemade T614 or profit English connection SV261.
Described recombiner is sea connection 1185 recombiners.
A kind of preparation method of above-mentioned ceramal lubricating oil comprises:
Cermet couplant is mixed with base oil, pour point depressant, viscosity index improver, recombiner and non-silicon type antifoamer, stir, it is 60~80 ℃ that control mixes temperature, and churning time is 0.5~1.5h, prepares ceramal lubricating oil.
Above-mentioned preferably 65~75 ℃ of temperature, best results when temperature is 70~75 ℃ of mixing.
The mediation preparation time of above-mentioned dredging engineering ship engine dedicated ceramic alloy lubricating oil is 20~90 minutes, is good with 30~70 minutes, is the best with 40~50 minutes.
Cermet couplant is the extreme-pressure anti-friction additive that a kind of guide's thing that can form the ceramal structure is made, with the plain oil is carrier, because the coupling chemical structure has the interfacial activity functional group, can be adsorbed in to physical property the metallic surface, the localized hyperthermia that utilizes the friction high pressure of facility under the extreme pressure environment to cause drives chemical reaction, sharp impacts between the facility parts is impacted the dynamic conditions that guide's thing heat scission reaction is provided, form ceramic alloy material, and, make reaction propagate and proceed along with the constant impact of friction parts.Formed ceramal film has the characteristic of high rigidity, low frictional factor, and therefore after effect after a while, it is high lubricated that the surface of friction ceramalization is caused, and also reduced wearing and tearing because membrane stability is high.
Ceramal lubricating oil of the present invention is carrier with the lubricant; form the cermet material layer by mechanical alloying ceramal coupled modes at metal friction surface; can make the extreme pressure and antiwear behavior of plain oil improve more than 10 times; thereby realize lubricants performance and facility life-span duplicate protection effect; it has excellent lubrication, protection, energy-conservation, reduction of discharging effect, and rate of economizing gasoline reaches 3~8%.
Embodiment
The cermet couplant that uses among the present invention is the patented product of our company, and its patent No. is ZL200910067880.3, and its content comprises in the present invention.
Described cermet couplant is prepared from by following components in weight percentage: nano aluminum metal powder or aluminum contained compound 0.5~2%, magnesium-containing compound 0.25~2%, boronation alkylolamide 1~6%, titanium couplant 0.5~5% and stable dispersant 86~95%, wherein said aluminum contained compound are Burow Solution, tert.-butoxy aluminium, aluminum isopropylate, benzene aluminum oxide; Described magnesium-containing compound is magnesium hydroxide, alkanol magnesium, Menesia or Magnesium Stearate; Described stable dispersant is petroleum wax, chlorination petroleum wax or beeswax; Described titanium couplant is the silane alcohol base titanium.
The preparation method of above-mentioned cermet couplant comprises: the preparation of (1) boronation alkylolamide: by alkanolamine and boric acid with (2~4): 1 weight ratio 80~100 ℃, under nitrogen protection, react and made the boronation alkylolamide in 2~8 hours; (2) preparation of cermet couplant: under protection of inert gas nano aluminum metal powder or aluminum contained compound, magnesium-containing compound, boronation alkylolamide, titanium couplant and stable dispersant were reacted 0.5~3 hour under 50~80 ℃ of conditions, described rare gas element is nitrogen or argon gas.
Below by specific embodiment dredging engineering ship engine dedicated ceramic alloy lubricating oil of the present invention and preparation method thereof is described.
Embodiment 1
250 kilograms of cermet couplants, 1500 kilograms of 150N, 2750 kilograms of 500N, 20 kilograms of pour point depressant V382,495 kilograms of viscosity index improver T614,250 kilograms of recombiners 1185 and 200ppm kilfoam mixed stir, it is 75 ℃ that control mixes temperature, churning time is 120 minutes, prepares the dredging engineering ship engine dedicated ceramic alloy lubricating oil that meets national standard.
Embodiment 2
200 kilograms of cermet couplants, 1400 kilograms of 150N, 2800 kilograms of 500N, 15 kilograms of pour point depressant V385,510 kilograms of viscosity index improver T614,250 kilograms of recombiners 1185, the 400ppm kilfoam, it is 65 ℃ that control mixes temperature, and churning time is 150 minutes, prepares the dredging engineering ship engine dedicated ceramic alloy lubricating oil that meets national standard.
Embodiment 3
150 kilograms of cermet couplants, 1500 kilograms of 150N, 2750 kilograms of 500N, 20 kilograms of pour point depressant V382,495 kilograms of viscosity index improver profit English connection SV261,250 kilograms of recombiners 1185, the 200ppm kilfoam, it is 60 ℃ that control mixes temperature, and churning time is 60 minutes, prepares the dredging engineering ship engine dedicated ceramic alloy lubricating oil that meets national standard.
Embodiment 4
240 kilograms of cermet couplants, 1200 kilograms of 150N, 3050 kilograms of 500N, 25 kilograms of pour point depressant V382,460 kilograms of viscosity index improver T614,250 kilograms of recombiners 1185, the 300ppm kilfoam, it is 60 ℃ that control mixes temperature, and churning time is 60 minutes, prepares the dredging engineering ship engine dedicated ceramic alloy lubricating oil that meets national standard.
Embodiment 5
250 kilograms of cermet couplants, 1300 kilograms of 150N, 2950 kilograms of 500N, 20 kilograms of pour point depressant V382,495 kilograms of viscosity index improver T614,250 kilograms of recombiners 1185, the 200ppm kilfoam, it is 60 ℃ that control mixes temperature, and churning time is 60 minutes, prepares the dredging engineering ship engine dedicated ceramic alloy lubricating oil that meets national standard.
Wear-resistant, energy-saving and emission-reduction test condition:
1, the physicochemical property of lubricating oil test
Diesel engine oil standard GB 11122-2006, third-party test unit: oil inspection institute of the Dalian Maritime University (China Classification Society is specified feeler mechanism).
Test result:
Figure BDA0000030543330000061
The experiment proved that the above-mentioned lubricating oil that makes all meets national standard.
2, saving energy test
Third-party test unit: middle common factor is rolled into a ball Tianjin Navigation Bureau's snagboat.
Test result:
Oil consumption (ton/ten thousand stere) Rate of economizing gasoline %
Plain oil 3.59
Embodiment 1 3.34 7.0
Embodiment 2 3.47 3.3
Embodiment 3 3.42 4.7
Embodiment 4 3.44 4.2
Embodiment 5 3.37 6.1
Above-mentioned test is by the unified operating area and the time of dredging, finishes the basic identical statistical of carrying out for contrast base figure of earth volume.But because the difference of operating mode can cause the difference of oil consumption, after having considered factors such as operating mode, ship condition, meteorology, actual rate of economizing gasoline should be between 3%~5%.

Claims (10)

1. dredging engineering ship engine dedicated ceramic alloy lubricating oil, form by following components in weight percentage:
Cermet couplant 1~6%;
Base oil 75~85%;
Pour point depressant 0.1~0.5%;
Viscosity index improver 7~13%;
Recombiner 4~7%;
Non-silicon type antifoamer 200~400ppm
2. ceramal lubricating oil according to claim 1 is characterized in that, described cermet couplant add-on is 2.0~5.5%.
3. ceramal lubricating oil according to claim 2 is characterized in that, described cermet couplant add-on is 4.5~5%.
4. ceramal lubricating oil according to claim 1 is characterized in that, described base oil is the mixture of 150N, 500N base oil, and the weight ratio of the two is 1: 1.5~4.
5. ceramal lubricating oil according to claim 1 is characterized in that, described pour point depressant is profit English connection V385 or V382.
6. ceramal lubricating oil according to claim 1 is characterized in that, described viscosity index improver is homemade T614 or profit English connection SV261.
7. ceramal lubricating oil according to claim 1 is characterized in that, described recombiner is sea connection 1185 recombiners.
8. the preparation method of the described ceramal lubricating oil of claim 1 comprises: described cermet couplant and described base oil, pour point depressant, viscosity index improver, recombiner and non-silicon type antifoamer are stirred 0.5~1.5h down at 60~80 ℃.
9. preparation method according to claim 8 is characterized in that, 65~75 ℃ of described whipping temps.
10. preparation method according to claim 8 is characterized in that, described churning time is 30~70 minutes.
CN201010529140XA 2010-11-02 2010-11-02 Ceramic alloy lubricating oil special for dredging workboat engine and preparation method thereof Pending CN101967419A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103525507A (en) * 2013-10-11 2014-01-22 程志林 Metal surface alloying agent and preparation method thereof
CN103725370A (en) * 2012-10-15 2014-04-16 姚芳飞 Pure petroleum base based energy-saving anti-friction novel lubricating oil and preparation method
CN104099157A (en) * 2013-04-02 2014-10-15 杨伟光 Metal ceramic lubricating oil couplant
CN107698972A (en) * 2017-10-18 2018-02-16 徐宏伟 A kind of joint of robot self-lubricating material and its preparation technology
CN114437856A (en) * 2021-12-28 2022-05-06 河南产学研创能源研究院有限公司 Methanol gasoline engine lubricating oil friction improver and preparation method thereof

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CN1523089A (en) * 2003-09-08 2004-08-25 张汝春 Graphite lubricating oil and its preparing method
CN101503645A (en) * 2009-02-18 2009-08-12 天津东方舜能润滑材料有限公司 Cermet couplant and preparation thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103725370A (en) * 2012-10-15 2014-04-16 姚芳飞 Pure petroleum base based energy-saving anti-friction novel lubricating oil and preparation method
CN104099157A (en) * 2013-04-02 2014-10-15 杨伟光 Metal ceramic lubricating oil couplant
CN103525507A (en) * 2013-10-11 2014-01-22 程志林 Metal surface alloying agent and preparation method thereof
CN103525507B (en) * 2013-10-11 2015-04-29 程志林 Metal surface alloying agent and preparation method thereof
CN107698972A (en) * 2017-10-18 2018-02-16 徐宏伟 A kind of joint of robot self-lubricating material and its preparation technology
CN114437856A (en) * 2021-12-28 2022-05-06 河南产学研创能源研究院有限公司 Methanol gasoline engine lubricating oil friction improver and preparation method thereof

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Application publication date: 20110209