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CN102010061A - Nitrification and denitrification sewage treatment device and system - Google Patents

Nitrification and denitrification sewage treatment device and system Download PDF

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CN102010061A
CN102010061A CN 201010526126 CN201010526126A CN102010061A CN 102010061 A CN102010061 A CN 102010061A CN 201010526126 CN201010526126 CN 201010526126 CN 201010526126 A CN201010526126 A CN 201010526126A CN 102010061 A CN102010061 A CN 102010061A
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anaerobic
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waste disposal
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CN102010061B (en
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荣宏伟
张朝升
张可方
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Guangzhou University
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Abstract

The invention discloses an anaerobic-aerobic nitrification sewage treatment device which is characterized in that an anaerobic reaction zone is arranged at the center, an aerobic biomembrane nitrification reaction zone is arranged at the periphery, a sludge concentration A zone is arranged at the lower part of the aerobic biomembrane nitrification reaction zone, a supernatant liquid collecting A zone is arranged outside the upper part of the aerobic biomembrane nitrification reaction zone, and simultaneously, and a sludge rectifying A zone is additionally arranged between the anaerobic reaction zone and the aerobic biomembrane nitrification reaction zone. The invention also discloses an anaerobic-aerobic denitrification sewage treatment device which is characterized in that an aerobic reaction zone and an anaerobic reaction zone are respectively arranged at the upper part and the lower part of the center, a sludge rectifying B zone is arranged at the periphery, a sludge concentration B zone is arranged at the lower part of the sludge rectifying B zone, a supernatant liquid collecting B zone is arranged outside the upper part of the sludge rectifying B zone, and simultaneously, and an isolated drum B is additionally arranged in the sludge rectifying B zone so that an annular up-flow channel is formed between the isolated drum B and a cylindrical drum B. The invention also discloses a nitrification and denitrification sewage treatment system formed by sequentially connecting the two devices.

Description

一种硝化和反硝化污水处理装置及系统 A nitrification and denitrification sewage treatment device and system

技术领域technical field

本发明涉及污水的多级处理,具体涉及至少有一个物理处理步骤的污水的多级处理。The invention relates to multistage treatment of sewage, in particular to multistage treatment of sewage with at least one physical treatment step.

背景技术Background technique

现有生物污水处理方法主要有除磷、脱氮效果的吸附-生物降解法(AB法)、厌氧-好氧法(AO法)、厌氧一缺氧-好氧法(A2O法)、氧化沟法和SBR序批式活性污泥法,其中,SBR序批式活性污泥法是一种简易、快速且低耗的污水处理工艺,非常适用于水质水量变化大的中小城镇的生活污水处理,以及易生物降解的工业废水处理。但是,该方法在生物硝化和反硝化及除磷过程中仍然存在以下需要解决的问题:1、硝化菌与聚磷菌的不同泥龄之争;2、硝化要求低有机物浓度,反硝化要求较高有机物浓度;3、硝化要求高氧,反硝化要求低氧;4、硝化过程为反硝化过程提供硝酸盐,但硝化过程本身的硝酸盐过多时,又对硝化过程产生抑制而使全过程不能继续进行;5、硝化过程是产酸耗碱的,而反硝化过程则是产碱的。The existing biological sewage treatment methods mainly include adsorption-biodegradation method (AB method) with phosphorus and nitrogen removal effects, anaerobic-aerobic method (AO method), anaerobic-anoxic-aerobic method (A 2 O method ), oxidation ditch method and SBR sequenced batch activated sludge method, among which, SBR sequenced batch activated sludge method is a simple, fast and low-consumption sewage treatment process, which is very suitable for small and medium-sized towns with large changes in water quality and quantity Domestic sewage treatment, and easily biodegradable industrial wastewater treatment. However, this method still has the following problems to be solved in the process of biological nitrification, denitrification and phosphorus removal: 1. The difference in sludge age between nitrifying bacteria and phosphorus accumulating bacteria; 2. Nitrification requires low organic matter concentration, and denitrification requires relatively low High organic matter concentration; 3. Nitrification requires high oxygen, and denitrification requires low oxygen; 4. The nitrification process provides nitrate for the denitrification process, but when the nitrification process itself has too much nitrate, it inhibits the nitrification process and makes the whole process impossible. Continue; 5. The nitrification process produces acid and consumes alkali, while the denitrification process produces alkali.

国家知识产权局专利局2004年10月27日公开了一种“序批式生物膜系统反硝化除磷脱氮处理城市污水的方法”(公开号为CN 1539769A),该方法披露以下工艺步骤:(1)进水期:原水间隔4小时交替进入第一级反应器A和B;(2)厌氧期:原水在A和B中进行厌氧循环2小时,进行磷的释放;(3)静置内换水期:第一级反应器经过厌氧循环后,静置沉淀0.5小时,将具有高浓度磷的上清液排入第二级反应器;(4)硝化反应期:在第二级反应器中,来自第一级反应器静置沉淀后的高磷水经过好氧曝气3.5小时,进行硝化反应;(5)硝化液内回流:第二级反应器在硝化反应结束后,静置沉淀30min,将上清液(硝化液)回流至第一级反应器;(6)反硝化聚磷期:在第一级反应器中,对来自第二级反应器的硝化液进行缺氧循环1.0小时,主要利用反硝化聚磷菌除磷脱氮;(7)好氧反应期:在第一级反应器中,缺氧1.0小时后,进行好氧曝气4.0小时,主要进行好氧吸磷和BOD、COD的去除及残留NH3-N的硝化;(8)沉淀排水期:第一级反应器在好氧结束后,静置沉淀0.5小时后,将处理完达标的上清液排放。上述专利申请所述的方法尽管解决了现有技术所存在的问题,但整个系统至少需要3台生物反应器,而且需要仍然需要采用间歇式工作,其系统之复杂和水力停留时间之长是可以预见的。On October 27, 2004, the Patent Office of the State Intellectual Property Office disclosed a "method for denitrification, denitrification, denitrification, and denitrification of urban sewage in a batch-type biofilm system" (the publication number is CN 1539769A), which discloses the following process steps: (1) Water intake period: raw water alternately enters first-stage reactors A and B at intervals of 4 hours; (2) Anaerobic period: raw water undergoes anaerobic circulation in A and B for 2 hours to release phosphorus; (3) Static internal water change period: after the first-stage reactor passes through the anaerobic cycle, it is left to settle for 0.5 hours, and the supernatant with high concentration of phosphorus is discharged into the second-stage reactor; (4) Nitrification reaction period: In the secondary reactor, the high-phosphorus water from the first-stage reactor was subjected to aerobic aeration for 3.5 hours to carry out nitrification reaction; (5) reflux in the nitrification liquid: the second-stage reactor was , standing for precipitation for 30min, and returning the supernatant (nitration solution) to the first-stage reactor; (6) denitrification and phosphorus accumulation period: in the first-stage reactor, the nitrification solution from the second-stage reactor is carried out Anoxic cycle for 1.0 hours, mainly using denitrifying phosphorus accumulating bacteria to remove phosphorus and nitrogen; (7) Aerobic reaction period: In the first-stage reactor, after 1.0 hours of anoxic, aerobic aeration is carried out for 4.0 hours, mainly Aerobic phosphorus uptake, removal of BOD and COD, and nitrification of residual NH3-N; (8) Sedimentation and drainage period: After the first stage reactor is left to settle for 0.5 hours after the aerobic end, the supernatant that meets the standard will be processed liquid discharge. Although the method described in the above-mentioned patent application has solved the existing problems of the prior art, the whole system requires at least 3 bioreactors, and still needs to adopt intermittent work, the complexity of the system and the long hydraulic retention time can be foreseeable.

国家知识产权局专利局2005年8月10日公开了“一种A2N反硝化除磷污水处理方法及装置”(公开号为CN 1651343A)的专利申请,该申请中所述的装置(实际上是一个污水处理系统)由水管、水箱、泵、厌氧池、中沉池、好氧生物膜硝化池、缺氧池、快速曝气池、终沉池、出水管顺序串连组成,其中,所述的中沉池底部与缺氧池底部之间连接有超越污泥管;所述的终沉池底部和厌氧池底部之间连通有回流污泥管。由上述专利申请所述的系统可见,其使用的设备之多、工艺路线之长和占地面积之大是显然的。The Patent Office of the State Intellectual Property Office disclosed a patent application for "a kind of A 2 N denitrification and phosphorus removal sewage treatment method and device" (publication number is CN 1651343A) on August 10, 2005. The device (actually The above is a sewage treatment system) is composed of water pipes, water tanks, pumps, anaerobic tanks, intermediate sedimentation tanks, aerobic biofilm nitrification tanks, anoxic tanks, rapid aeration tanks, final sedimentation tanks, and outlet pipes in series. , A transcending sludge pipe is connected between the bottom of the intermediate sedimentation tank and the bottom of the anoxic tank; a return sludge pipe is connected between the bottom of the final sedimentation tank and the bottom of the anaerobic tank. As can be seen from the system described in the above-mentioned patent application, it is obvious that there are many devices used, the length of the process route and the size of the occupied area.

发明内容Contents of the invention

鉴于现有技术的不足,本发明所要解决的技术问题是提供一种集成的反硝和反硝化污水处理装置及其组成的污水处理系统。In view of the deficiencies in the prior art, the technical problem to be solved by the present invention is to provide an integrated denitrification and denitrification sewage treatment device and a sewage treatment system composed thereof.

本发明解决上述问题的技术方案如下:The technical scheme that the present invention solves the above problems is as follows:

一种厌氧-好氧硝化污水处理装置,其特征在于,该装置具有A反应罐,该A反应罐自上而下由A圆柱筒和A圆锥筒连接构成;所述的A反应罐的A圆柱筒内的中心设有上端敞的A圆柱形容器,A圆柱形容器外套设有A隔离筒,从而,在A圆柱形容器内形成圆柱形的厌氧反应区,在A圆柱形容器与A隔离筒之间形成环形的A污泥整流区,在A隔离筒与A圆柱筒之间形成环形的好氧生物膜硝化反应区;所述的A反应罐的A圆锥筒内形成锥形的A污泥浓缩区;所述的A反应罐的A圆柱筒的上端口的外侧设有横断面为L形的A群边,该A群边与A圆柱筒外壁之间形成环形的A上清液汇集区;横断面为L形的A群边的上口设有A罐盖,其上部的中心设有A电机,该A电机的输出轴连接一延伸至所述A圆柱形容器下部的A搅拌轴,所述A搅拌轴下部设有A搅拌叶;所述A罐盖上设有环形的A空气分配管,该A空气分配管上均布有若干根垂直向下的A曝气管,每根A曝气管延伸至所述好氧生物膜硝化反应区的下部,端头设有A曝气头,中部套设有载有好氧菌填料环;所述的A反应罐下部设有与A圆柱形容器下部连通的A进水管;所述的横断面为L形的A群边的底部设有A出水管;所述的A圆锥筒的底部设有A排泥管。An anaerobic-aerobic nitrification sewage treatment device is characterized in that the device has an A reaction tank, and the A reaction tank is composed of an A cylinder and an A cone from top to bottom; the A of the A reaction tank The center of the cylindrical barrel is provided with a cylindrical container A with an open upper end, and the outer layer of the cylindrical container A is provided with an isolation tube A, so that a cylindrical anaerobic reaction zone is formed in the cylindrical container A, and between the cylindrical container A and A An annular A sludge rectification zone is formed between the isolation cylinders, and an annular aerobic biofilm nitrification reaction zone is formed between the A isolation cylinder and the A cylindrical cylinder; the A conical cylinder of the A reaction tank forms a conical A Sludge concentration area; the outer side of the upper port of the A cylinder of the A reaction tank is provided with an L-shaped cross-section A group edge, and an annular A supernatant is formed between the A group edge and the A cylinder outer wall Convergence area; the cross-section is L-shaped A tank cover is provided on the upper mouth of the A group side, and the center of the upper part is provided with an A motor. Shaft, the lower part of the A stirring shaft is provided with an A stirring blade; the A tank cover is provided with an annular A air distribution pipe, and the A air distribution pipe is evenly distributed with a number of vertically downward A aeration pipes, each The root A aeration pipe extends to the lower part of the aerobic biofilm nitrification reaction zone, the end is provided with an A aeration head, and the middle part is provided with a packing ring carrying aerobic bacteria; the lower part of the A reaction tank is provided with a A water inlet pipe connected to the lower part of the cylindrical container; A water outlet pipe is provided at the bottom of the L-shaped side of the A group; the A mud discharge pipe is provided at the bottom of the A conical cylinder.

一种缺氧-好氧反硝化污水处理装置,其特征在于,该装置具有B反应罐,该B反应罐自上而下由B圆柱筒和B圆锥筒连接构成;所述的B反应罐的B圆柱筒内的中心设有上端敞的B圆柱形容器,B圆柱形容器外套设有B隔离筒,其中B圆柱形容器的中部设有带升流孔的水平隔板,从而,在B圆柱形容器内下部形成圆柱形的缺氧反应区,在B圆柱形容器内上部形成圆柱形的好氧反应区,在B圆柱形容器与B隔离筒之间形成环形的B污泥整流区,在B隔离筒与B圆柱筒之间形成环形的升流通道;所述的B反应罐的B圆锥筒内形成锥形的B污泥浓缩区;所述的B反应罐的B圆柱筒的上端口的外侧设有横断面为L形的B群边,该B群边与B圆柱筒外壁之间形成环形的B上清液汇集区;横断面为L形的B群边的上口设有B罐盖,其上部的中心设有B电机,该B电机的输出轴连接一延伸至所述B圆柱形容器下部的缺氧反应区的B搅拌轴,所述B搅拌轴在位于的缺氧反应区的一段上设有B搅拌叶;所述B罐盖上设有环形的B空气分配管,该B空气分配管上均布有若干根垂直向下B曝气管,每根B曝气管延伸至所述好氧反应区的下部,端头设有B曝气头;所述的B反应罐下部设有B进水管,该进水管的前端可与上述厌氧-好氧硝化污水处理装置的A出水管匹配连接,后端延伸至B圆柱形容器下部与缺氧反应区连通;所述的横断面为L形的B群边的底部设有B出水管;所述的B圆锥筒的底部设有B排泥管。An anoxic-aerobic denitrification sewage treatment device is characterized in that the device has a B reaction tank, which is composed of a B cylinder and a B cone connection from top to bottom; the B reaction tank The center of the B cylinder is provided with a B cylinder with an open upper end, and the B cylinder is provided with a B isolation cylinder, wherein the middle of the B cylinder is provided with a horizontal partition with a flow hole, so that the B cylinder A cylindrical anoxic reaction zone is formed in the lower part of the container, a cylindrical aerobic reaction zone is formed in the upper part of the B cylindrical container, and an annular B sludge rectification zone is formed between the B cylindrical container and the B isolation cylinder. An annular ascending passage is formed between the B isolation cylinder and the B cylinder; a conical B sludge concentration zone is formed in the B conical cylinder of the B reaction tank; the upper port of the B cylinder of the B reaction tank There is an L-shaped cross-section on the outside of the B group edge, and an annular B supernatant collection area is formed between the B group edge and the outer wall of the B cylinder; the cross-section is an L-shaped B group edge. Tank cover, the center of its upper part is provided with a B motor, the output shaft of the B motor is connected to a B agitating shaft extending to the anoxic reaction zone at the lower part of the B cylindrical container, and the B agitating shaft is located in the anoxic reaction zone. One section of the zone is equipped with B stirring blades; the B tank cover is provided with annular B air distribution pipes, and several B aeration pipes are evenly distributed on the B air distribution pipes, and each B aeration pipe Extending to the bottom of the aerobic reaction zone, the end is provided with a B aeration head; the bottom of the B reaction tank is provided with a B water inlet pipe, and the front end of the water inlet pipe can be connected with the above-mentioned anaerobic-aerobic nitrification sewage treatment device The A water outlet pipe is matched and connected, and the rear end extends to the lower part of the B cylindrical container to communicate with the anoxic reaction zone; the bottom of the L-shaped B group edge is provided with a B water outlet pipe; the B conical cylinder There is a B discharge pipe at the bottom.

本发明所述的厌氧-好氧硝化污水处理装置,其中,所述的A圆柱形容器和A隔离筒由设在A污泥整流区的支撑杆固定在一起,A隔离筒可直接固定在A罐盖的下表面,也可使用设在好氧生物膜硝化反应区的支撑杆固定在A圆柱筒的内壁上。The anaerobic-aerobic nitrification sewage treatment device according to the present invention, wherein, the A cylindrical container and the A isolation cylinder are fixed together by a support rod arranged in the A sludge rectification area, and the A isolation cylinder can be directly fixed on the The lower surface of the A tank cover can also be fixed on the inner wall of the A cylinder using a support rod located in the aerobic biofilm nitrification reaction zone.

本发明所述的缺氧-好氧反硝化污水处理装置,其中,所述的B圆柱形容器和B隔离筒由设在B污泥整流区的支撑杆固定在一起,B隔离筒可直接固定在B罐盖的下表面,也可使用设在升流通道内的支撑杆固定在B圆柱筒的内壁上。The anoxic-aerobic denitrification sewage treatment device according to the present invention, wherein, the B cylindrical container and the B isolation cylinder are fixed together by a support rod arranged in the B sludge rectification area, and the B isolation cylinder can be directly fixed On the lower surface of the B tank cover, also can use the support rod that is located in the upflow channel to be fixed on the inner wall of the B cylinder.

本发明所述的缺氧-好氧反硝化污水处理装置,其中,所述的B圆柱形容器内的水平隔板上所设的升流孔位于水平隔板的中心,所述的B搅拌轴经升流孔延伸至缺氧反应区。The anoxic-aerobic denitrification sewage treatment device of the present invention, wherein, the upflow hole set on the horizontal partition in the cylindrical container of B is located at the center of the horizontal partition, and the stirring shaft of B is It extends to the anoxic reaction zone through the upwelling hole.

一种反硝和反硝化污水处理系统,其特征在于该系统由上述的厌氧-好氧硝化污水处理装置和缺氧-好氧反硝化污水处理装置通过下述方式连接组成:A denitrification and denitrification sewage treatment system is characterized in that the system is composed of the above-mentioned anaerobic-aerobic nitrification sewage treatment device and anoxic-aerobic denitrification sewage treatment device connected in the following manner:

厌氧-好氧硝化污水处理装置的A出水管直接与缺氧-好氧反硝化污水处理装置的B进水管连通,厌氧-好氧硝化污水处理装置的A排泥管串联污泥提升泵后并联在缺氧-好氧反硝化污水处理装置的B进水管上;缺氧-好氧反硝化污水处理装置的B排泥管串联污泥回流泵与厌氧-好氧硝化污水处理装置的A进水管连通。The outlet pipe A of the anaerobic-aerobic nitrification sewage treatment plant is directly connected to the B water inlet pipe of the anoxic-aerobic denitrification sewage treatment plant, and the sludge discharge pipe A of the anaerobic-aerobic nitrification sewage treatment plant is connected in series with the sludge lift pump Afterwards, it is connected in parallel on the B inlet pipe of the anoxic-aerobic denitrification sewage treatment device; the sludge discharge pipe B of the anoxic-aerobic denitrification sewage treatment device is connected in series with the sludge return pump and the anaerobic-aerobic nitrification sewage treatment device A water inlet pipe is connected.

本发明较现有技术具有下列优点和效果:Compared with the prior art, the present invention has the following advantages and effects:

1、本发明根据硝化和反硝化的工艺特点将整个工艺所需要的水运容器集成为两个处理装置,从而极大减少了整个污水处理工艺的占地面积,同时使所有的工艺设备能够工厂化生产,既可降低设备投资,又可缩短建设周期。1. According to the process characteristics of nitrification and denitrification, the present invention integrates the water transport container required by the whole process into two treatment devices, thereby greatly reducing the floor area of the whole sewage treatment process, and at the same time making all the process equipment factory-like Production can not only reduce equipment investment, but also shorten the construction period.

2、本发明利用同时利用硝化和反硝化的工艺特点以及水与污泥的物理特性对反应的各区域进行合理安排,有效地解决了集成化时各反应相互干扰的技术难题。具体是,在厌氧-好氧硝化污水处理装置中,巧妙地将厌氧反应区设在中心,好氧生物膜硝化反应区设在四周,A污泥浓缩区设在好氧生物膜硝化反应区的下部,A上清液汇集区设在好氧生物膜硝化反应区上部的外侧,同时在厌氧反应区和好氧生物膜硝化反应区之间增设一A污泥整流区,从而既能将硝化过程必需具备的厌氧、好氧生物膜硝化反应区和沉淀区有效隔离,也能进一步改善了泥水的分离效果;在缺氧-好氧反硝化污水处理装置中,巧妙地将好氧反应区和缺氧反应区设在中心的上部和下部,B污泥整流区设在四周,B污泥浓缩区设在B污泥整流区的下部,B上清液汇集区设在B污泥整流区上部的外侧,同时在B污泥整流区内增设一B隔离筒,使B隔离筒与B圆柱筒之间形成一环形的升流通道,从而既能将反硝化过程必须具备的缺氧、好氧反应区和沉淀区能有效隔离,也能进一步改善了泥水的分离效果。2. The present invention uses the process characteristics of nitrification and denitrification and the physical characteristics of water and sludge to rationally arrange the reaction areas, effectively solving the technical problem of mutual interference of the reactions during integration. Specifically, in the anaerobic-aerobic nitrification sewage treatment device, the anaerobic reaction zone is cleverly set in the center, the aerobic biofilm nitrification reaction zone is set around, and the A sludge concentration zone is set in the aerobic biofilm nitrification reaction zone. In the lower part of the area, the A supernatant collection area is set outside the upper part of the aerobic biofilm nitrification reaction area. At the same time, an A sludge rectification area is added between the anaerobic reaction area and the aerobic biofilm nitrification reaction area, so that both The effective isolation of the anaerobic and aerobic biofilm nitrification reaction zone and the sedimentation zone, which are necessary for the nitrification process, can further improve the separation effect of mud and water; in the anoxic-aerobic denitrification sewage treatment device, the aerobic The reaction zone and anoxic reaction zone are set in the upper and lower parts of the center, the B sludge rectification zone is set around, the B sludge concentration zone is set in the lower part of the B sludge rectification zone, and the B supernatant collection zone is set in the B sludge On the outer side of the upper part of the rectification area, a B isolation cylinder is added in the B sludge rectification area at the same time, so that an annular upflow channel is formed between the B isolation cylinder and the B cylinder, so that the anoxic gas necessary for the denitrification process can be eliminated. , The aerobic reaction zone and the sedimentation zone can be effectively isolated, and the separation effect of mud and water can be further improved.

附图说明Description of drawings

图1、图2和图3为本发明所述的厌氧-好氧硝化污水处理装置的一个具体实施例的结构示意图,其中图1为主视图(沿中轴线纵剖),图2为俯视图,图3为图1的A-A剖视图。Fig. 1, Fig. 2 and Fig. 3 are the structural representations of a specific embodiment of the anaerobic-aerobic nitrification sewage treatment device of the present invention, wherein Fig. 1 is a front view (longitudinal section along the central axis), and Fig. 2 is a top view , FIG. 3 is a sectional view of A-A in FIG. 1 .

图4、图5、图6和图7为本发明所述的缺氧-好氧反硝化污水处理装置的一个具体实施例的结构示意图,其中图4为主视图(沿中轴线纵剖),图5为俯视图,图6为图4的B-B剖视图,图7为图4的C-C剖视放大图。Fig. 4, Fig. 5, Fig. 6 and Fig. 7 are the structural representations of a specific embodiment of the anoxic-aerobic denitrification sewage treatment device of the present invention, wherein Fig. 4 is the main view (longitudinal section along the central axis), Fig. 5 is a plan view, Fig. 6 is a sectional view along B-B of Fig. 4 , and Fig. 7 is an enlarged view of a sectional view along C-C of Fig. 4 .

图8为本发明所述反硝和反硝化污水处理系统的一个具体实施例的工艺流程图。Fig. 8 is a process flow chart of a specific embodiment of the denitrification and denitrification sewage treatment system of the present invention.

具体实施方式Detailed ways

图1~图3为本发明所述的厌氧-好氧硝化污水处理装置的一个具体实施例,其结构如下所述。1 to 3 are a specific embodiment of the anaerobic-aerobic nitrification sewage treatment device according to the present invention, and its structure is as follows.

参见图1和图3,A反应罐1由A圆柱筒1-1和A圆锥筒1-2上下连接构成,其中,A圆柱筒1-1的上端口的外侧设有横断面为L形的A群边2,A群边2的上口设有A罐盖4,底部设有A出水管20,A群边2与A圆柱筒1-1外壁之间形成环形的A上清液汇集区3;A圆柱筒1-1内的中心设有上端敞口的A圆柱形容器5,A圆柱形容器5外套设设有A隔离筒6,从而,在A圆柱形容器5内形成圆柱形的厌氧反应区7,在A圆柱形容器5与A隔离筒6之间形成环形的A污泥整流区8,在A隔离筒6与A圆柱筒1-1之间形成环形的好氧生物膜硝化反应区9;A圆锥筒1-2的底部设有A排泥管21,内部形成锥形的A污泥浓缩区10。上述的A反应罐1下部的A圆锥筒1-2上设有与A圆柱形容器5下部连通的A进水管19。上述的A隔离筒6直接焊接固定在A罐盖4的下表面,A圆柱形容器5由设在A污泥整流区8内的支撑杆15固定在A隔离筒6的内壁上。Referring to Fig. 1 and Fig. 3, A reaction tank 1 is composed of A cylindrical barrel 1-1 and A conical barrel 1-2 connected up and down, wherein, the outer side of the upper port of A cylindrical barrel 1-1 is provided with an L-shaped cross section. Group A side 2, the upper opening of group A side 2 is provided with A tank cover 4, and the bottom is provided with A outlet pipe 20, and an annular A supernatant liquid collection area is formed between A group side 2 and the outer wall of A cylinder 1-1 3; A cylindrical container 5 with an open upper end is provided in the center of the A cylindrical container 1-1, and the A cylindrical container 5 is provided with an A isolation tube 6, so that a cylindrical container 5 is formed in the A cylindrical container 5. Anaerobic reaction zone 7, an annular A sludge rectification area 8 is formed between A cylindrical container 5 and A isolation cylinder 6, and an annular aerobic biofilm is formed between A isolation cylinder 6 and A cylinder 1-1 Nitrification reaction zone 9; A sludge discharge pipe 21 is provided at the bottom of A conical cylinder 1-2, and a conical A sludge concentration zone 10 is formed inside. A water inlet pipe 19 communicating with the lower part of the A cylindrical container 5 is provided on the A conical cylinder 1-2 at the bottom of the above-mentioned A reaction tank 1 . The above-mentioned A isolation cylinder 6 is directly welded and fixed on the lower surface of the A tank cover 4, and the A cylindrical container 5 is fixed on the inner wall of the A isolation cylinder 6 by the support rod 15 arranged in the A sludge rectification area 8 .

参见图1、图2和图3,上述的A罐盖4上部的中心设有A电机11,A电机11的输出轴连接一延伸至A圆柱形容器5下部的A搅拌轴12,A搅拌轴12下部设有A搅拌叶13。上述A罐盖4上还设有环形的A空气分配管14,A空气分配管14上均布有六根垂直向下的A曝气管16,每根A曝气管16延伸至所述好氧生物膜硝化反应区9的下部,端头设有A曝气头17,中部套设有载有好氧菌填料环18。Referring to Fig. 1, Fig. 2 and Fig. 3, the center of the above-mentioned A tank cover 4 top is provided with A motor 11, and the output shaft of A motor 11 is connected with an A stirring shaft 12 extending to the bottom of A cylindrical container 5, and the A stirring shaft 12 bottoms are provided with A stirring blade 13. The above-mentioned A tank cover 4 is also provided with an annular A air distribution pipe 14, and the A air distribution pipe 14 is evenly distributed with six vertically downward A aeration pipes 16, and each A aeration pipe 16 extends to the aerobic In the lower part of the biofilm nitrification reaction zone 9, an aeration head 17 is provided at the end, and a packing ring 18 carrying aerobic bacteria is set in the middle part.

图4~图7为本发明所述的缺氧-好氧反硝化污水处理装置的一个具体实施例,其结构如下所述。4 to 7 are a specific embodiment of the anoxic-aerobic denitrification sewage treatment device according to the present invention, and its structure is as follows.

参见图4~图7,B反应罐22由B圆柱筒22-1和B圆锥筒22-2上下连接构成,其中,B圆柱筒22-1的上端口的外侧设有横断面为L形的B群边23,B群边23的上口设有B罐盖24,底部设有B出水管25,B群边23与B圆柱筒22-1外壁之间形成环形的B上清液汇集区26;B圆柱筒22-1的中心设有上端敞的B圆柱形容器27,B圆柱形容器27外套设设有B隔离筒28,其中B圆柱形容器27的中部设有中心带升流孔29的水平隔板30,从而,在B圆柱形容器27内下部形成圆柱形的缺氧反应区31,在B圆柱形容器27内上部形成圆柱形的好氧反应区32,在B圆柱形容器27与B隔离筒28之间形成环形的B污泥整流区33,在B隔离筒28与B圆柱筒22-1之间形成环形的升流通道34;B圆锥筒22-2的底部设有B排泥管35,内部形成锥形的B污泥浓缩区36。上述的B反应罐22下部的B圆锥筒22-2上设有B进水管44,该进水管44的前端可与上述厌氧-好氧硝化污水处理装置的A出水管20匹配连接,后端延伸至B圆柱形容器27下部与缺氧反应31区连通。上述的B隔离筒28直接焊接固定在B罐盖24的下表面,B圆柱形容器27由设在B污泥整流区33内的支撑杆37固定在B隔离筒28的内壁上。Referring to Figures 4 to 7, the B reaction tank 22 is composed of a B cylindrical barrel 22-1 and a B conical barrel 22-2 connected up and down, wherein, the outer side of the upper port of the B cylindrical barrel 22-1 is provided with an L-shaped cross section. B group side 23, the upper mouth of B group side 23 is provided with B tank cover 24, and the bottom is provided with B outlet pipe 25, forms the ring-shaped B supernatant liquid collection area between B group side 23 and B cylindrical tube 22-1 outer wall 26; The center of the B cylindrical tube 22-1 is provided with a B cylindrical container 27 with an open upper end, and a B cylindrical container 27 is provided with a B isolation tube 28, wherein the middle part of the B cylindrical container 27 is provided with a center belt upflow hole 29 horizontal partitions 30, thereby, form the anoxic reaction zone 31 of cylindrical shape at the bottom in B cylindrical container 27, form the aerobic reaction zone 32 of cylindrical shape at the top in B cylindrical container 27, in B cylindrical container An annular B sludge rectification area 33 is formed between 27 and B isolation cylinder 28, and an annular upflow passage 34 is formed between B isolation cylinder 28 and B cylindrical cylinder 22-1; the bottom of B conical cylinder 22-2 is provided with The B sludge discharge pipe 35 forms a conical B sludge concentration zone 36 inside. The B conical cylinder 22-2 at the bottom of the above-mentioned B reaction tank 22 is provided with a B water inlet pipe 44, and the front end of the water inlet pipe 44 can be matched with the A water outlet pipe 20 of the above-mentioned anaerobic-aerobic nitrification sewage treatment device, and the rear end Extending to the lower part of the B cylindrical container 27 communicates with the anoxic reaction zone 31. The B isolation cylinder 28 mentioned above is directly welded and fixed on the lower surface of the B tank cover 24, and the B cylindrical container 27 is fixed on the inner wall of the B isolation cylinder 28 by the support rod 37 arranged in the B sludge rectification area 33.

参见图4图5和图6,上述B罐盖24上部的的中心设有B电机38,B电机38的输出轴连接一经水平隔板30上所设升流孔29延伸至B圆柱形容器27下部的缺氧反应区31的B搅拌轴39,B搅拌轴39在位于的缺氧反应区31的一段上设有B搅拌叶40;B罐盖24上还设有环形的B空气分配管41,B空气分配管41上均布有六根垂直向下B曝气管42,每根B曝气管42延伸至好氧反应区32的下部,端头设有B曝气头43。Referring to Fig. 4, Fig. 5 and Fig. 6, the center of the upper part of the B tank cover 24 is provided with a B motor 38, and the output shaft of the B motor 38 is connected to the B cylindrical container 27 through the upflow hole 29 provided on the horizontal partition 30. The B stirring shaft 39 of the anoxic reaction zone 31 of the lower part, the B stirring shaft 39 is provided with a B stirring blade 40 on a section of the anoxic reaction zone 31 located; the B tank cover 24 is also provided with an annular B air distribution pipe 41 , The B air distribution pipe 41 is evenly distributed with six vertically downward B aeration pipes 42, each B aeration pipe 42 extends to the lower part of the aerobic reaction zone 32, and the end is provided with a B aeration head 43.

图8为本发明所述反硝和反硝化污水处理系统的一个具体实施例,其工艺流程如下所述。Fig. 8 is a specific embodiment of the denitrification and denitrification sewage treatment system of the present invention, and its technological process is as follows.

参见图8,将图1~3所示的厌氧-好氧硝化污水处理装置45的A出水管20直接与图4~7所示的缺氧-好氧反硝化污水处理装置46的B进水管44连通,再将厌氧-好氧硝化污水处理装置的A排泥管21串联污泥提升泵47后并联在缺氧-好氧反硝化污水处理装置的B进水管44上,然后把缺氧-好氧反硝化污水处理装置46的B排泥管35串联污泥回流泵48与厌氧-好氧硝化污水处理装置45的A进水管19连通即可一种反硝和反硝化污水处理系统。Referring to Fig. 8, the A outlet pipe 20 of the anaerobic-aerobic nitrification sewage treatment device 45 shown in Figs. The water pipe 44 is connected, and then the A sludge discharge pipe 21 of the anaerobic-aerobic nitrification sewage treatment device is connected in parallel with the sludge lifting pump 47 on the B water inlet pipe 44 of the anoxic-aerobic denitrification sewage treatment device, and then the deficient The B sludge discharge pipe 35 of the oxygen-aerobic denitrification sewage treatment device 46 is connected in series with the sludge return pump 48 and the A water inlet pipe 19 of the anaerobic-aerobic denitrification sewage treatment device 45 is connected to one kind of denitrification and denitrification sewage treatment system.

以下结合附图和一个具体应用实施例对本发明所述的工作流程及效果进行进一步详细描述:The workflow and effects of the present invention will be described in further detail below in conjunction with the accompanying drawings and a specific application example:

接种污泥来自广州市沥滘污水处理厂的回流污泥,试验用水采用人工合成废水,该废水的指标为:COD为136-194mg/L,NH4 +为23.7-31.4mg/L,TP为4.14-7.95mg/L,TN为26.5-37.2mg/L,pH为6.8-7.2。试验中所采用的分析方法均按照国家环境保护局发布的标准方法。The inoculated sludge comes from the return sludge of Guangzhou Lijiao Sewage Treatment Plant. The test water is artificially synthesized wastewater. 4.14-7.95mg/L, TN is 26.5-37.2mg/L, pH is 6.8-7.2. The analytical methods used in the test were all in accordance with the standard methods issued by the State Environmental Protection Agency.

参见图1和图4,试验前将接种污泥添加到厌氧-好氧硝化污水处理装置45和缺氧-好氧反硝化污水处理装置46内,并将单独利用接种污泥作为好氧菌载于好氧菌填料环18上,然后再安置于好氧生物膜硝化反应区9。参见图8并结合图1和图4,将原污水投加入水箱49中,启动进水泵50、污泥提升泵48和污泥回流泵48。污水和回流污泥在厌氧反应区7中停留时间为40-60分钟,由A搅拌叶13搅拌充分混合,回流污泥中的少量NO2 -和NO3 -快速被异养菌反硝化去除,聚磷菌吸收挥发性有机酸,并进行磷的释放。厌氧反应区7中排出的泥水进入到A污泥整流区8进行泥水分离,上清液随上升水流进入好氧生物膜硝化反应区9进行好氧硝化反应并汇集到A上清液汇集区3内,然后经A出水管20流入缺氧-好氧反硝化污水处理装置46的缺氧反应区31内;沉淀下来的释磷污泥在A污泥浓缩区10内浓缩,并由污泥提升泵47提升至缺氧-好氧反硝化污水处理装置46的缺氧反应区31内。在缺氧反应区31内经好氧硝化后的含有大量NO3 -的硝化液与浓缩后释磷污泥停留时间为60-90分钟进行充分混合,释磷污泥中的反硝化聚磷菌与硝化液中的NO3 -进行反硝化吸磷反应。反硝化吸磷反应后的泥水混合液经水平隔板30上所设的升流孔29进入好氧反应区32,在好氧状态下,异养菌氧化COD,硝化菌将NH4 +氧化为NO2 -和NO3 -,聚磷菌进行好氧吸收磷。上述好氧反应均通过气泵51进行曝气,曝气量的大小根据运行状态进出水情况进行调整,控制出水NH4 +在<5mg/L,TP<1.2mg/L即可。好氧反应区32溢出的泥水进入到B污泥整流区33进行泥水分离,上清液经升流通道34汇集到B上清液汇集区26,然后排出系统;沉淀下来的富磷污泥在B污泥浓缩区36浓缩,一部分由回流污泥泵48经A进水管19送回厌氧-好氧硝化污水处理装置45的厌氧反应区7,另一部分剩余的污泥经B排泥管35排除。Referring to Fig. 1 and Fig. 4, inoculation sludge is added in anaerobic-aerobic nitrification sewage treatment plant 45 and anoxic-aerobic denitrification sewage treatment plant 46 before the test, and will use inoculation sludge alone as aerobic bacteria Carried on the aerobic bacteria packing ring 18, and then placed in the aerobic biofilm nitrification reaction zone 9. Referring to FIG. 8 in combination with FIG. 1 and FIG. 4 , the raw sewage is put into the water tank 49 , and the water inlet pump 50 , the sludge lift pump 48 and the sludge return pump 48 are started. Sewage and return sludge stay in the anaerobic reaction zone 7 for 40-60 minutes, and are fully mixed by A stirring blade 13, and a small amount of NO 2 - and NO 3 - in the return sludge are quickly denitrified by heterotrophic bacteria , Phosphorus accumulating bacteria absorb volatile organic acids and release phosphorus. The muddy water discharged from the anaerobic reaction zone 7 enters the A sludge rectification zone 8 for mud-water separation, and the supernatant enters the aerobic biofilm nitrification reaction zone 9 with the rising water flow for aerobic nitrification reaction and collects into the A supernatant collection zone 3, and then flow into the anoxic reaction zone 31 of the anoxic-aerobic denitrification sewage treatment device 46 through the A outlet pipe 20; The lifting pump 47 is lifted into the anoxic reaction zone 31 of the anoxic-aerobic denitrification sewage treatment device 46 . In the anoxic reaction zone 31, the nitrification liquid containing a large amount of NO 3 - after aerobic nitrification is fully mixed with the concentrated phosphorus-releasing sludge for a residence time of 60-90 minutes, and the denitrifying phosphorus-accumulating bacteria in the phosphorus-releasing sludge and The NO 3 in the nitrification solution - carries out the denitrification phosphorus absorption reaction. The mud-water mixture after the denitrification phosphorus absorption reaction enters the aerobic reaction zone 32 through the upflow hole 29 set on the horizontal partition 30. Under the aerobic state, the heterotrophic bacteria oxidize COD, and the nitrifying bacteria oxidize NH 4 + to NO 2 - and NO 3 - , phosphorus accumulating bacteria perform aerobic phosphorus uptake. The above-mentioned aerobic reactions are aerated by the air pump 51, and the amount of aeration is adjusted according to the water inflow and outflow in the operating state, and the NH 4 + in the effluent should be controlled at <5mg/L, and TP<1.2mg/L. The muddy water overflowing from the aerobic reaction zone 32 enters the B sludge rectification zone 33 for sludge-water separation, and the supernatant is collected into the B supernatant collection zone 26 through the upflow channel 34, and then discharged from the system; The B sludge concentration zone 36 concentrates, a part is sent back to the anaerobic reaction zone 7 of the anaerobic-aerobic nitrification sewage treatment device 45 by the return sludge pump 48 through the A water inlet pipe 19, and another part of the remaining sludge passes through the B sludge discharge pipe 35 excluded.

经上述处理后,所排出的水中,COD、NH4 +、TP和TN的浓度分别为15.7-33.5mg/L,0-3.2mg/L,0.11-1.14mg/L和4.7-11.2mg/L,三项指标的平均值分别为22.3mg/L,1.4mg/L,0.58mg/L和7.6mg/L,。上述系统,COD,NH4+,TP和TN的平均去除率分别为87.8%,94.6%,89.4%和80.9%。After the above treatment, the concentrations of COD, NH 4 + , TP and TN in the discharged water are 15.7-33.5mg/L, 0-3.2mg/L, 0.11-1.14mg/L and 4.7-11.2mg/L respectively , the average values of the three indicators were 22.3mg/L, 1.4mg/L, 0.58mg/L and 7.6mg/L, respectively. For the above system, the average removal efficiencies of COD, NH4+, TP and TN were 87.8%, 94.6%, 89.4% and 80.9%, respectively.

Claims (6)

1. the nitrated waste disposal plant of anaerobic-aerobic is characterized in that, this device has A retort (1), and this A retort (1) is connected and composed by A cylindrical drum (1-1) and A circular cone tube (1-2) from top to bottom; Wherein, center in the A cylindrical drum (1-1) of described A retort (1) is provided with the spacious A cylindrical vessel (5) in upper end, the outer A isolating cylinder (6) that is arranged with of A cylindrical vessel (5), thereby, in A cylindrical vessel (5), form columniform anaerobic reaction district (7), between A cylindrical vessel (5) and A isolating cylinder (6), form annular A mud commutating zone (8), between A isolating cylinder (6) and A cylindrical drum (1-1), form annular aerobic biologic membrane nitration reaction district (9); Form the A mud enrichment region (10) of taper in the A circular cone tube (1-2) of described A retort (1); It is L shaped A group limit (2) that the outside of the upper port of the A cylindrical drum (1-1) of described A retort (1) is provided with the transverse section, forms annular A supernatant liquor pooling zone (3) between this A group limit (2) and A cylindrical drum (1-1) outer wall; The transverse section is the A cover (4) that is provided with suitable for reading on L shaped A group limit (2), the center on its top is provided with A motor (11), the output shaft connection one of this A motor (11) extends to the A stir shaft (12) of described A cylindrical vessel (5) bottom, and described A stir shaft (12) bottom is provided with A paddle (13); Described A cover (4) is provided with annular A air distribution (14), be evenly equipped with some A aeration tubes (16) vertically downward on this A air distribution (14), every A aeration tube (16) extends to the bottom in described aerobic biologic membrane nitration reaction district (9), the termination is provided with A aeration head (17), and the middle part is arranged with and is loaded with aerobic bacteria packing ring (18); Described A retort (1) bottom is provided with the A water inlet pipe (19) that is communicated with A cylindrical vessel (5) bottom; The bottom on described A group limit (2) is provided with A rising pipe (20); The bottom of described A circular cone tube (1-2) is provided with A shore pipe (21).
2. an anaerobic-aerobic denitrification waste disposal plant is characterized in that, this device has B retort (22), and this B retort (22) is connected and composed by B cylindrical drum (22-1) and B circular cone tube (22-2) from top to bottom; Center in the B cylindrical drum (22-1) of described B retort (22) is provided with the spacious B cylindrical vessel (27) in upper end, the outer B isolating cylinder (28) that is arranged with of B cylindrical vessel (27), wherein the middle part of B cylindrical vessel (27) is provided with the horizontal baffle (30) in band up-flow hole (29), thereby, columniform hypoxia response district (31) is formed at the bottom in B cylindrical vessel (27), form columniform aerobic reactor zone (32) at B cylindrical vessel (27) internal upper part, between B cylindrical vessel (27) and B isolating cylinder (28), form annular B mud commutating zone (33), between B isolating cylinder (28) and B cylindrical drum (22-1), form annular upflow channel (34); Form the B mud enrichment region (36) of taper in the B circular cone tube (22-2) of described B retort (22); It is L shaped B group limit (23) that the outside of the upper port of the B cylindrical drum (22-1) of described B retort (22) is provided with the transverse section, forms annular B supernatant liquor pooling zone (26) between this B group limit (23) and B cylindrical drum (22-1) outer wall; The transverse section is the B cover (24) that is provided with suitable for reading on L shaped B group limit (23), the center on its top is provided with B motor (38), the output shaft connection one of this B motor (38) extends to the B stir shaft (39) in the hypoxia response district (31) of described B cylindrical vessel (27) bottom, and described B stir shaft (39) is provided with B paddle (40) on a section of the hypoxia response district (31) that is positioned at; Described B cover (24) is provided with annular B air distribution (41), be evenly equipped with some B aeration tubes (42) vertically downward on this B air distribution (41), every B aeration tube (42) extends to the bottom of described aerobic reactor zone (32), and the termination is provided with B aeration head (43); Described B retort (22) bottom is provided with B water inlet pipe (44), the front end of this water inlet pipe (44) can be connected with A rising pipe (20) coupling of the nitrated waste disposal plant of the described anaerobic-aerobic of claim 1, and the rear end extends to B cylindrical vessel (27) bottom and is communicated with hypoxia response district (31); The bottom on described B group limit (23) is provided with B rising pipe (25); The bottom of described B circular cone tube (22-2) is provided with B shore pipe (35).
3. the nitrated waste disposal plant of a kind of anaerobic-aerobic according to claim 1, it is characterized in that, described A cylindrical vessel (5) and A isolating cylinder (6) are fixed together by the support bar (15) that is located at A mud commutating zone (8), and A isolating cylinder (6) directly is fixed on the lower surface of A cover (4).
4. a kind of anaerobic-aerobic denitrification waste disposal plant according to claim 2, it is characterized in that, described B cylindrical vessel (27) and B isolating cylinder (28) are fixed together by the support stick (37) that is located at B mud commutating zone (33), and B isolating cylinder (28) directly is fixed on the lower surface of B cover (24).
5. according to claim 2 or 4 described a kind of anaerobic-aerobic denitrification waste disposal plants, it is characterized in that, horizontal baffle (30) in the described B cylindrical vessel (27) is gone up the center that set up-flow hole (29) is positioned at horizontal baffle (30), and described B stir shaft (39) extends to hypoxia response district (31) through up-flow hole (29).
6. anti-nitre and denitrification Sewage treatment systems is characterized in that this system is connected to form by following manner by nitrated waste disposal plant of the described anaerobic-aerobic of claim 1 and the described anaerobic-aerobic denitrification of claim 2 waste disposal plant:
The A rising pipe (20) of the nitrated waste disposal plant of anaerobic-aerobic (45) directly is communicated with the B water inlet pipe (44) of anaerobic-aerobic denitrification waste disposal plant (46), is connected in parallel on the B water inlet pipe (44) of anaerobic-aerobic denitrification waste disposal plant (46) behind A shore pipe (21) the series connection mud lift pump (47) of the nitrated waste disposal plant of anaerobic-aerobic (45); B shore pipe (35) the series connection sludge reflux pump (48) of anaerobic-aerobic denitrification waste disposal plant (46) is communicated with the A water inlet pipe (19) of the nitrated waste disposal plant of anaerobic-aerobic (45).
CN2010105261264A 2010-10-28 2010-10-28 Nitrification and denitrification sewage treatment device and system Expired - Fee Related CN102010061B (en)

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Publication number Priority date Publication date Assignee Title
CN104609551A (en) * 2013-11-05 2015-05-13 中国石油化工股份有限公司 Synchronous nitrification and denitrification treatment method of ammonia-containing wastewater
CN104609540A (en) * 2013-11-05 2015-05-13 中国石油化工股份有限公司 Ammonia-containing wastewater treatment method
CN118324301A (en) * 2024-04-24 2024-07-12 昆明佩奇环保科技有限公司 Sewage treatment system based on nitration

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CN1626460A (en) * 2003-12-09 2005-06-15 中国科学院成都生物研究所 Bioreactor for treating wastewater
CN1789172A (en) * 2005-12-24 2006-06-21 重庆大学 Integrated multi-stage biofilm sewage treatment equipment
CN1887739A (en) * 2006-07-28 2007-01-03 重庆大学 Active sludge-biomembrane compounding integral sewage treating method and apparatus

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US6007720A (en) * 1998-03-11 1999-12-28 Organo Corp. Process for treatment of organic wastewater
CN1301673A (en) * 1999-12-29 2001-07-04 孙复华 Vertical sectional integrated waste water biochemical treatment method and device
CN1626460A (en) * 2003-12-09 2005-06-15 中国科学院成都生物研究所 Bioreactor for treating wastewater
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104609551A (en) * 2013-11-05 2015-05-13 中国石油化工股份有限公司 Synchronous nitrification and denitrification treatment method of ammonia-containing wastewater
CN104609540A (en) * 2013-11-05 2015-05-13 中国石油化工股份有限公司 Ammonia-containing wastewater treatment method
CN118324301A (en) * 2024-04-24 2024-07-12 昆明佩奇环保科技有限公司 Sewage treatment system based on nitration
CN118324301B (en) * 2024-04-24 2025-02-25 昆明佩奇环保科技有限公司 A sewage treatment system based on nitrification reaction

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