CN102388892B - Pesticide composition containing chlorantraniliprole and thiocyclam - Google Patents
Pesticide composition containing chlorantraniliprole and thiocyclam Download PDFInfo
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Abstract
The invention relates to a pesticide composition taking chlorantraniliprole and thiocyclam as active ingredient, wherein the weight ratio of chlorantraniliprole and thiocyclam is 1-100: 100-1. The mass percentage of the active ingredient in the pesticide composition is 5 to 70%, wherein the mass percentage of chlorantraniliprole is 0.5 to 50%, and the mass percentage of thiocyclam is 0.5 to 50%; and the pesticide composition can be added with an assistant or an excipient to be manufactured into an aqueous emulsion or a suspending agent, wettable powder and water dispersible granules. The composition has a remarkable synergized action in poisoning insects, has the characteristics of wide insecticidal spectrum, high efficiency, high speed of action, durative efficacy, low toxicity, low pesticide consumption and agricultural cost, no cross resistance among the agents, and the like, and overcomes and suspends pesticide resistance of pests. The composition can effectively prevent and treat agricultural pests and is particularly suitable for preventing and treating rice pests.
Description
Technical field
The present invention relates to a kind of Pesticidal combination that contains chlorantraniliprole and thiocyclam and preparation method thereof.
Background technology
chlorantraniliprole (chlorantraniliprole), the experiment code name is DPX-E2Y45, chemical name is 3-bromo-N-(4-chloro-2-methyl-6-(amino-carbonyl phenyl)-1-3 Chloro-2-Pyridyle)-1H-pyrazoles-5-carboxylic acid amides, belong to insect ryanodine receptor inhibitor, mainly discharge by the intracellular calcium ion of inducing the regulation and control of insect ryanodine receptor and show insecticidal action, have and tag and stomach poison function, show efficient, wide spectrum, the characteristics such as holding effect and mechanism of action novelty, can be used for preventing and treating each Species of Lepidopterous Insect Pests, other commercialization insecticide varieties that its control efficiency obviously is better than using in current production, there is not cross resistance in other insecticides, and to natural enemy insect safety, can be used for vegetables, beet, the crops such as cotton control beet armyworm, tomato moth, diamond-back moth, imported cabbageworm, cotton bollworm, the various insects such as pink bollworm, each instar larvae there is good control efficiency.But this medicament is not very good to the control efficiency of rice leaf roller, striped rice borer, paddy stem borer because of the pesticide resistance problem, and agricultural cost is high.
Thiocyclam (thiocyclam), chemical name is N, N dimethylamine base-1,2,3-, three thias oneself-5-base amine, be a kind of nAChR inhibitor, insect is had strong tag, stomach toxicity, stifling and systemic action, the various pests such as the snout moth's larva of rice (striped rice borer, paddy stem borer, rice leaf roller), leafhopper class, plant hopper are had good effect, are the specific drugs of the snout moth's larva of rice, and production cost and agricultural cost all very low.But the thiocyclam dosage is large, quick-acting is relatively poor, and some regional insects have produced serious pesticide resistance to this medicament.
Chlorantraniliprole (chlorantraniliprole) is as follows with the chemical structural formula of thiocyclam (thiocyclam):
Good to control efficiency such as pest such as armyworm and the snout moth's larvas of rice in order to invent, synergistic effect is remarkable, and have that insecticidal spectrum is wide, efficient, speed of action is fast,, dosage low to the toxicity of mammal and natural enemy insect and agricultural cost is low and medicament between without the new medicament that is mixed of the characteristics such as cross resistance, find through lot of experiments research, chlorantraniliprole and two kinds of active ingredients of thiocyclam are mixed, single dose characteristics separately both can have been brought into play, also can overcome the shortcoming that single dose exists separately, effectively delay insect to the drug-fast generation of single medicament.There is no at present the mixture preparation of relevant chlorantraniliprole and thiocyclam and the report of control pest thereof both at home and abroad.
Summary of the invention
The object of the invention is to deficiency and defective for the prior art existence, provide a kind of co-toxicity coefficient significantly greater than 100, have the Pesticidal combination that contains chlorantraniliprole and thiocyclam of notable synergistic effect.
The present invention adopts Sun Y P﹠amp; Johnson E R (1960) method filters out the Pesticidal combination take chlorantraniliprole and thiocyclam as active insecticidal components, the weight ratio of chlorantraniliprole and thiocyclam is 1～100: 100～1, active insecticidal components accounts for 5～70% of composition total weight, wherein chlorantraniliprole accounts for 0.5～50% of composition total weight, and thiocyclam accounts for 0.5～50% of composition total weight.
Dispersiveness, emulsibility, wettability, stability and the permeability etc. of the present invention in order to strengthen said composition, according to formulating, in active ingredient formula according to the known processing method of those skilled in the art of the present technique, add emulsifier, dispersant, antifreezing agent, defoamer, thickener, stabilizing agent, disintegrant, adhesive, the solvent of Different Weight, be mixed with different formulations for example aqueous emulsion (EW) or suspending agent (SC), wetting powder (WP), water-dispersible granules (WDG).These preparations can be watered the form that is diluted to water dispersible solution, adopt spraying, atomizing, dust, spread fertilizer over the fields or the mode such as irrigation imposes on Different Crop and occasion pest control.
When Pesticidal combination of the present invention is formulated as aqueous emulsion (EW):
The emulsifier that adds is one or more the mixture in alkyl polyglycol ether, alkyl phenyl polyglycol ether, polyoxyethylene sorbitol acid anhydride ester, polyoxyethylene fatty acid ester, alkylphenol polyoxyethylene phosphate, ethoxyquin alkyl phenylate, ethoxyquin alkyl ether, ethylene oxide-propylene oxide block copolymer, polyoxyethylene polyoxypropylene block copolymer, phenethyl phenol polyethenoxy polyethenoxy ether, alkylbenzenesulfonate, lignosulfonates, and consumption accounts for 10～30% (percetages by weight);
The dispersant that adds is polyvinyl alcohol, gum Arabic or its mixture, and consumption accounts for 5～10% of composition total weight;
The antifreezing agent that adds is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, sorbierite, and general consumption accounts for 1～8% of composition total weight;
The defoamer that adds is one or more the mixture in organic silicone oil, methyl alcohol, ethanol, epoxidized soybean oil, and general consumption accounts for 0.5～8% of composition total weight;
The thickener that adds is one or more the mixture in polyacrylate, cluck xanthan, Magnesiumaluminumsilicate, urea, natural polysaccharide, and general consumption accounts for 0.2～5% of composition total weight;
The stabilizing agent that adds is one or more the mixture in urea, methyl alcohol, soluble starch, sodium sorbate, pyrogallic acid, aminobenzoic acid, cresyl glycidyl ether, phenyl glycidyl ether, and general consumption accounts for 0.5～10% of composition total weight;
The solvent that adds is one or more the mixture in methyl alcohol, ethanol, butanols, ethylene glycol, propane diols, glycerine, polyethylene glycol, dimethylbenzene, acetone, cyclohexanone, N-chain alkyl pyrrolidones, ethyl acetate, dimethyl formamide (DMF), dimethyl sulfoxide (DMSO) (DMSO), and general consumption accounts for 20～60% of composition total weight;
When Pesticidal combination of the present invention is formulated as suspending agent (SC):
The wetting dispersing agent that adds is one or more the mixture in lignosulfonates, alkylsulfonate, aliphatic alcohol sulfate, alkylaryl sulfonates, polyaryl phenol polyoxy ethyl ether phosphate alkylamine salt, polyoxyethylene fatty acid ester, alkylphenol polyoxyethylene phosphate, Fluhyzon formaldehyde condensation products, polyoxyethylene polyoxypropylene block copolymer, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, CMC (CMC), polyvinyl alcohol (PVA), and consumption accounts for 0.5～40% of composition total weight;
The thickener that adds is one or more the mixture in CMC, polyvinyl alcohol, xanthans, gum Arabic, sodium alginate, polyvinylpyrrolidone, bentonite, aluminium-magnesium silicate, gypsum, and consumption accounts for 0.2～5% of composition total weight;
The stabilizing agent that adds is acidic isopropyl phosphate (PAP), 2, one or more mixture of 6-di-tert-butyl-4-sylvan (BHT), pyrogallol, cresyl glycidyl ether, phenyl glycidyl ether, polyethylene glycol diglycidyl ether, chloropropylene oxide, sodium sorbate, pyrogallic acid, aminobenzoic acid, epoxidised soybean oil, linseed oil, castor oil, soluble starch, consumption accounts for 0.1～10% of composition total weight;
The defoamer that adds is one or more the mixture in organic silicone oil, methyl alcohol, ethanol, epoxidized soybean oil, and consumption accounts for 0.5～8% of composition total weight;
The stabilizing agent that adds is one or more the mixture in urea, methyl alcohol, soluble starch, sodium sorbate, pyrogallic acid, aminobenzoic acid, cresyl glycidyl ether, phenyl glycidyl ether, and consumption accounts for 0.5～10% of composition total weight;
The antifreezing agent that adds is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, sorbierite, and consumption accounts for 0.1～5% of composition total weight;
The solvent that adds is one or more the mixture in water, methyl alcohol, ethanol, butanols, ethylene glycol, propane diols, glycerine, polyethylene glycol, acetone, cyclohexanone, pyrrolidones, toluene, dimethylbenzene, ethyl acetate, dimethyl formamide (DMF), dimethyl sulfoxide (DMSO) (DMSO), and consumption accounts for 10～80% of composition total weight.
When Pesticidal combination of the present invention is formulated as wetting powder (WP):
The dispersant that adds is one or more the mixture in lignosulfonates, fatty acid amide N methyl taurine sodium salt, alkylphenol polyoxyethylene sulphate, lignosulfite, fatty acid ester sulphate, polyoxyethylene polyoxypropylene block copolymer, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, and consumption accounts for 5～35% of composition total weight;
The wetting agent that adds is dodecyl benzene sulfonate, agriculture breast 2000 series, SOPA230, SOPA270, SOPA235, the withered powder of tea, spaonin powder, pull open one or several the mixture in powder, wetting and penetrating agent F, and consumption accounts for 5～30% of composition total weight;
The carrier that adds is one or more the mixture in kaolin, diatomite, atlapulgite, White Carbon black, clay, precipitated calcium carbonate, talcum powder, and general consumption accounts for 15～75% of composition total weight.
When Pesticidal combination of the present invention is mixed with water-dispersible granules (WDG):
The wetting agent that adds is one or more the mixture in fatty acid amide N methyl taurine sodium salt, lignosulfonates, alkylphenol polyoxyethylene sulphate, petroleum sodium sulfonate, alkylnaphthalene sulfonate, fatty acid ester sulphate, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, lignosulfite, the withered powder of tea, spaonin powder, and consumption accounts for 5～30% of composition total weight;
The dispersant that adds is one or several the mixture in ethoxylated dodecyl alcohol, naphthalenesulfonic acid-formaldehyde condensate, dioctyl sodium sulphosuccinate, acrylate homopolymer sodium salt, and consumption accounts for 5～10% of composition total weight;
The binding agent that adds is one or more the mixture in starch, polyvinyl acetate, polyvinyl alcohol, polyethylene glycol, sodium silicate, gelatin, soybean lecithin, cyclodextrin, gum Arabic, and consumption accounts for 1～10% of composition total weight;
The disintegrant that adds is one or more the mixture in urea, magnesium chloride, aluminium chloride, sodium chloride, ammonium sulfate, bentonite, and consumption accounts for 5～10% of composition total weight;
The carrier that adds is one or more the mixture in kaolin, diatomite, atlapulgite, White Carbon black, clay, precipitated calcium carbonate, talcum powder, montmorillonite, and consumption accounts for 15～70% of composition total weight.
Pesticidal combination dosage of the present invention obviously reduces, kind according to crop, pest population generation density, tillage method and weather and method of application etc. are carried out the various dose dispenser, effective ingredient consumption is in 5～20 g/acres, can effectively prevent and treat paddy rice, vegetables, tea tree, cotton, gardening, insect on the Important Agricultural crops such as fruit tree, as rice leaf roller, striped rice borer, paddy stem borer, the rice stinkbug, thrips, leafhopper, plant hopper, aphid, beet armyworm, tomato moth, diamond-back moth, imported cabbageworm, cotton bollworm, pink bollworm, tea geometrid, euproctis pseudoconspersa, fruit eats into moth, leaf miner etc.
Compared with prior art, Pesticidal combination of the present invention has following features: 1. compare with single dose, have obvious synergistic effect, significantly improved the effect of the control snout moth's larva of rice; 2. a medicine is controlled more, can prevent and treat simultaneously various pests, has reduced cost accounting and cost; 3. substituted the high-toxic pesticide kind, and decrease field consumption, the residue of pesticide in environmental pollution and rice effectively reduced; 4. have quick-acting and holding effect concurrently, after a drug, the field lasting period is more than 20 days; 5. delay harmful insect to the drug-fast generation of single medicament; 6. with the chlorantraniliprole ratio, Pesticidal combination of the present invention has not only strengthened quick-acting, and decrease application cost.
Embodiment
In order to understand better essence of the present invention, below in conjunction with embodiment, the Pesticidal combination that the present invention contains chlorantraniliprole and thiocyclam is described further, but the present invention never is limited to following embodiment.
Embodiment 1: first take chlorantraniliprole 1g, thiocyclam 20g, lignosulfonates 10g, polyoxyethylene polyoxypropylene block copolymer 10g, urea 1g, propane diols 2g, polyvinyl alcohol 3g, dimethyl formamide 2g and deionized water 51g.Then, under normal temperature and high speed shear stir, oil phase is added aqueous phase, mix and make its average liquid footpath less than 2 μ m, namely obtain 21% chlorantraniliprole thiocyclam aqueous emulsion product.
Embodiment 2: first take chlorantraniliprole 1g, thiocyclam 10g, lignosulfonates 15g, phenethyl phenol polyethenoxy polyethenoxy ether 15g, urea 1g, ethyl acetate 1g, polyvinyl alcohol 3g, organic silicone oil 1g and deionized water 53g.Then, under normal temperature and high speed shear stir, oil phase is added aqueous phase, mix and make its average liquid footpath less than 2 μ m, namely obtain 11% chlorantraniliprole thiocyclam aqueous emulsion product.
Embodiment 3: first take chlorantraniliprole 0.5g, thiocyclam 40g, lignosulfonates 8g, phenethyl phenol polyethenoxy polyethenoxy ether 6g, polyoxyethylene sorbitol acid anhydride ester 6g, urea 1g, ethyl acetate 1g, polyvinyl alcohol 3g, organic silicone oil 1g and deionized water 33.5g.Then, under normal temperature and high speed shear stir, oil phase is added aqueous phase, mix and make its average liquid footpath less than 2 μ m, namely obtain 40.5% chlorantraniliprole thiocyclam aqueous emulsion product.
Embodiment 4: first take chlorantraniliprole 0.5g, thiocyclam 50g, lignosulfonates 4g, alkylbenzenesulfonate 4g, polyoxyethylene polyoxypropylene block copolymer 8g, Magnesiumaluminumsilicate 1g, gum Arabic 1g, polyethylene glycol 3g, methyl alcohol 2g and deionized water 26.5g.Then, under normal temperature and high speed shear stir, oil phase is added aqueous phase, mix and make its average liquid footpath less than 2 μ m, namely obtain 50.5% chlorantraniliprole thiocyclam aqueous emulsion product.
Embodiment 5: take chlorantraniliprole 2.5g, thiocyclam 2.5g, polyaryl phenol polyoxy ethyl ether phosphate alkylammonium salt 6g, polyoxyethylene polyoxypropylene block copolymer 6g, CMC 8g, aluminium-magnesium silicate 1g, polyethylene glycol 5g, DMF4g and water 65g.Above-mentioned each component is mixed and in ball mill ball mill grinding formed thick dispersion liquid in 4 hours, then make its average grain diameter can obtain 5% required chlorantraniliprole thiocyclam suspending agent product less than 5 μ m through soybean dietary fiber.
Embodiment 6: take chlorantraniliprole 10g, thiocyclam 1g, sodium lignin sulfonate 10g, polyaryl phenol polyoxy ethyl ether phosphate alkylamine salt 10g, bentonite 1g, gum Arabic 1g, polyvinylpyrrolidone 2g and water 65g.Above-mentioned each component is mixed and in ball mill ball mill grinding formed thick dispersion liquid in 4 hours, then make its average grain diameter can obtain 11% required chlorantraniliprole thiocyclam suspending agent product less than 5 μ m through soybean dietary fiber.
Embodiment 7: take chlorantraniliprole 0.5g, thiocyclam 25g, sodium lignin sulfonate 8g, polyoxyethylene polyoxypropylene block copolymer 12g, cresyl glycidyl ether 1g, polyvinyl alcohol 2g, methyl alcohol 3g, ethyl acetate 3g and water 45.5g.Above-mentioned each component is mixed and in ball mill ball mill grinding formed thick dispersion liquid in 4 hours, then make its average grain diameter can obtain 25.5% required chlorantraniliprole thiocyclam suspending agent product less than 5 μ m through soybean dietary fiber.
Embodiment 8: take chlorantraniliprole 20g, thiocyclam 1g, lignosulfonates 8g, alkylphenol polyoxyethylene 8g, fatty alcohol-polyoxyethylene ether 6g, acidic isopropyl phosphate 1g, polyvinyl alcohol 1g, bentonite 1g, glycerine 3g, ethyl acetate 3g and water 48g.Above-mentioned each component is mixed and in ball mill ball mill grinding formed thick dispersion liquid in 4 hours, then make its average grain diameter can obtain 21% required chlorantraniliprole thiocyclam suspending agent product less than 5 μ m through soybean dietary fiber.
Embodiment 9: take chlorantraniliprole 50g, thiocyclam 0.5g, lignosulfonates 10g, pelopon A 10g, polyoxyethylene polyoxypropylene block copolymer 10g, wetting and penetrating agent F 2g and atlapulgite 17.5g, it is fully mixed, and mixture is pulverized in airslide disintegrating mill and can be made the 50.5% chlorantraniliprole thiocyclam wetting powder product that average grain diameter is 20 μ m.
Embodiment 10: take chlorantraniliprole 30g, thiocyclam 0.5g, fatty acid amide N methyl taurine sodium salt 10g, alkylphenol polyoxyethylene sulphate 10g, wetting and penetrating agent F 2g, kaolin 27.5g and atlapulgite 20g; it is fully mixed, and mixture is pulverized in airslide disintegrating mill and can be made the 30.5% chlorantraniliprole thiocyclam wetting powder product that average grain diameter is 20 μ m.
Embodiment 11: take chlorantraniliprole 30g, thiocyclam 40g, sodium lignin sulfonate 5g, dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene sulphate 5g, wetting and penetrating agent F 2g and white carbon 13g, it is fully mixed, and mixture is pulverized in airslide disintegrating mill and can be made the 70% chlorantraniliprole thiocyclam wetting powder product that average grain diameter is 20 μ m.
Embodiment 12: take chlorantraniliprole 40g, thiocyclam 0.5g, alkylphenol polyoxyethylene sulphate 10g, ethoxylated dodecyl alcohol 10g, sodium silicate 2g, polyethylene glycol 3g, starch 1.5g, diatomite 13g, atlapulgite 20g.Mixture is carried out granulation after ultra-fine grinding, drying, screening namely obtain the 40.5% chlorantraniliprole thiocyclam dispersibility granula product that average grain diameter is 4 μ m left and right.
Embodiment 13: take chlorantraniliprole 20g, thiocyclam 1g, sodium lignin sulfonate 10g, alkylphenol polyoxyethylene 10g, naphthalenesulfonic acid-formaldehyde condensate 8g, polyvinyl alcohol 5g, urea 2g, magnesium chloride 3g, kaolin 20g, White Carbon black 21g.The above-mentioned substance stirring and dissolving is mixed, and grinding in sand mill and making its average grain diameter is about 4 μ m, then can obtain required product 21% chlorantraniliprole thiocyclam dispersibility granula product by the bed spray drying.
Embodiment 14: take chlorantraniliprole 25g, thiocyclam 0.5g, lignosulfonates 5g, fatty acid amide-N methyl taurine sodium salt 5g, ethoxylated dodecyl alcohol 8g, starch 0.5g, polyethylene glycol 4g, bentonite 5g, atlapulgite 20g, kaolin 27g.Mixture is carried out granulation after ultra-fine grinding, drying, screening namely obtain the 25.5% chlorantraniliprole thiocyclam dispersibility granula product that average grain diameter is 4 μ m left and right.
Embodiment 15: chlorantraniliprole and thiocyclam are mixed combination to the toxicity test of armyworm and brown plant-hopper
Mythimna separata adopts infusion process that reagent agent is made into certain density mother liquor, then it is stand-by to be diluted to 5 concentration with clear water, establishes clear water and is contrast.Get fresh and tender maize leaves and be cut into the long big or small basically identical fragment of about 50mm, with the blade that shears prepare for reagent liquid in dipping 10 seconds, after taking-up allows it naturally dry, put into the culture dish (Φ 90mm) that is lined with in advance filter paper.Then access mythimna separata 3 instar larvaes in ware, 10, every ware, every concentration repeats for 3 times.Be disposed, cover the ware lid, be placed in recovery room and cultivate, routine observation, inspection record death condition after 48hr is calculated lethality (%), and is obtained virulence regression equation formula, correlation coefficient (r) and the lethal concentration of 50 (LC according to probit analysis
50).
Plant hopper is adopted and to soak seedling and connect worm method reagent agent to be mixed with 5～6 concentration by design stand-by, establishes clear water and is contrast.Choose two leaf one core rice seedling 15 strains,, taking out nature and drying after 10 seconds for the molten middle dipping of reagent, (in Φ 200 * 30mm), every concentration repeats for 3 times to be put into teat glass.Then 15 of every pipe access leafhopper nymphs in 3 age, the mouth of pipe is tightened with white gauze.Be disposed, be placed in observation ward, make regular check on and record examination worm situation anyway, calculate lethality (%), obtain toxicity regression formula, correlation coefficient (r) and the lethal concentration of 50 (LC according to probit analysis
50).
Sun﹠amp is adopted in the synergy evaluation; Co-toxicity coefficient (CTC) method that Johnson (1960) proposes.Usually, co-toxicity coefficient obviously represented to have synergistic effect greater than 100 o'clock, and co-toxicity coefficient represents that close to 100 o'clock tool summation action, co-toxicity coefficient are significantly less than at 100 o'clock and are expressed as antagonism.The computing formula of co-toxicity coefficient is as follows:
The percentage composition of B in ATI * mixture of the percentage composition of A+medicament B in ATI * mixture of theoretical toxicity index (TTI)=medicament A
The toxicity test that chlorantraniliprole and thiocyclam are mixed to armyworm the results are shown in Table 1.As seen, chlorantraniliprole and thiocyclam are mixed with the ratio of 1: 1,1: 10,1: 20,1: 50,1: 80,1: 100,100: 1,80: 1,50: 1,20: 1,10: 1 armyworm and plant hopper are all shown as obvious synergistic effect, and its co-toxicity coefficient is all obviously greater than 100.
Table 1 chlorantraniliprole and thiocyclam are mixed to the toxicity test result (72hr) of armyworm and brown plant-hopper
Embodiment 16: the field control test of pesticide effectiveness of chlorantraniliprole-thiocyclam mixture control rice grub
Result of the test sees Table 2～4.As seen, chlorantraniliprole-thiocyclam mixture is watered spraying with every mu of active ingredient 5,10,20 grams, after medicine 2～7 days, to the insecticidal effect of rice leaf folder, paddy stem borer and brown planthopper all the utmost point be significantly higher than the effect of independent use chlorantraniliprole or thiocyclam; After dispenser 20 days, to the insecticidal effect of rice leaf folder, paddy stem borer and brown planthopper all apparently higher than the effect of independent use chlorantraniliprole or thiocyclam.The characteristics such as it has synergy, doublely controls, quick-acting and holding effect are described.
The field efficacy fruit (Yongzhou City, 2010.9) of table 2 chlorantraniliprole-thiocyclam mixture to rice leaf folder
Annotate: in table, data are to repeat mean values 3 times, and are not remarkable with being illustrated respectively on P=0.01 and 0.05 level difference with identical lower case and upper case letter person after column of figure.Following table is same.
The field efficacy fruit (Yongzhou City, 2010.9) of table 3 chlorantraniliprole-thiocyclam mixture to Yellow Rice Borer
The field efficacy fruit (Yongzhou City, 2010.9) of table 4 chlorantraniliprole-thiocyclam mixture to water rice hopper
Claims (7)
1. Pesticidal combination that contains chlorantraniliprole and thiocyclam, it is characterized in that with chlorantraniliprole [3-bromo-N-(4-chloro-2-methyl-6-(amino-carbonyl phenyl)-the 1-3 Chloro-2-Pyridyle)-1H-pyrazoles-5-carboxylic acid amides] and thiocyclam [N, N dimethylamine base-1,2,3-three thias oneself-5-base amine] be active insecticidal components, the weight ratio of chlorantraniliprole and thiocyclam is 1～100: 100～1, active insecticidal components accounts for 5～70% of composition total weight, wherein chlorantraniliprole accounts for 0.5～50% of composition total weight, and thiocyclam accounts for 0.5～50% of composition total weight.
2. the Pesticidal combination that contains chlorantraniliprole and thiocyclam according to claim 1, it is characterized in that adding emulsifier, dispersant, antifreezing agent, defoamer, thickener, stabilizing agent, disintegrant, adhesive or solvent, be mixed with aqueous emulsion or suspending agent, wetting powder, water-dispersible granules.
3. Pesticidal combination according to claim 1 and 2, when it is characterized in that preparing aqueous emulsion, the emulsifier that adds is alkyl polyglycol ether, the alkyl phenyl polyglycol ether, polyoxyethylene sorbitol acid anhydride ester, polyoxyethylene fatty acid ester, alkylphenol polyoxyethylene phosphate, ethoxyquin alkyl phenylate, the ethoxyquin alkyl ether, ethylene oxide-propylene oxide block copolymer, polyoxyethylene polyoxypropylene block copolymer, phenethyl phenol polyethenoxy polyethenoxy ether, alkylbenzenesulfonate, the mixture of one or more in lignosulfonates, consumption accounts for 10～30% of composition total weight, the dispersant that adds is polyvinyl alcohol, gum Arabic or its mixture, and consumption accounts for 5～10% of composition total weight, the antifreezing agent that adds is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, sorbierite, and consumption accounts for 1～8% of composition total weight, the defoamer that adds is one or more the mixture in organic silicone oil, methyl alcohol, ethanol, epoxidized soybean oil, and consumption accounts for 0.5～8% of composition total weight, the thickener that adds is one or more the mixture in polyacrylate, cluck xanthan, Magnesiumaluminumsilicate, urea, natural polysaccharide, and consumption accounts for 0.2～5% of composition total weight, the stabilizing agent that adds is one or more the mixture in urea, methyl alcohol, soluble starch, sodium sorbate, pyrogallic acid, aminobenzoic acid, cresyl glycidyl ether, phenyl glycidyl ether, and consumption accounts for 0.5～10% of composition total weight, the solvent that adds is one or more the mixture in methyl alcohol, ethanol, butanols, ethylene glycol, propane diols, glycerine, polyethylene glycol, dimethylbenzene, acetone, cyclohexanone, N-chain alkyl pyrrolidones, ethyl acetate, dimethyl formamide, dimethyl sulfoxide (DMSO), and consumption accounts for 20～60% of composition total weight.
4. Pesticidal combination according to claim 1 and 2, when it is characterized in that preparing suspending agent, the wetting dispersing agent that adds is lignosulfonates, alkylsulfonate, aliphatic alcohol sulfate, alkylaryl sulfonates, polyaryl phenol polyoxy ethyl ether phosphate alkylamine salt, polyoxyethylene fatty acid ester, the alkylphenol polyoxyethylene phosphate, the Fluhyzon formaldehyde condensation products, polyoxyethylene polyoxypropylene block copolymer, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, CMC, the mixture of one or more in polyvinyl alcohol, consumption accounts for 0.5～40% of composition total weight, the thickener that adds is one or more the mixture in CMC, polyvinyl alcohol, xanthans, gum Arabic, sodium alginate, polyvinylpyrrolidone, bentonite, aluminium-magnesium silicate, gypsum, and consumption accounts for 0.2～5% of composition total weight, the stabilizing agent that adds is acidic isopropyl phosphate, 2, one or more mixture of 6-di-tert-butyl-4-sylvan, pyrogallol, cresyl glycidyl ether, phenyl glycidyl ether, polyethylene glycol diglycidyl ether, chloropropylene oxide, sodium sorbate, pyrogallic acid, aminobenzoic acid, epoxidised soybean oil, linseed oil, castor oil, soluble starch, consumption accounts for 0.1～10% of composition total weight, the defoamer that adds is one or more the mixture in organic silicone oil, methyl alcohol, ethanol, epoxidized soybean oil, and consumption accounts for 0.5～8% of composition total weight, the stabilizing agent that adds is one or more the mixture in urea, methyl alcohol, soluble starch, sodium sorbate, pyrogallic acid, aminobenzoic acid, cresyl glycidyl ether, phenyl glycidyl ether, and consumption accounts for 0.5～10% of composition total weight, the antifreezing agent that adds is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, sorbierite, and consumption accounts for 0.1～5% of composition total weight, the solvent that adds is one or more the mixture in water, methyl alcohol, ethanol, butanols, ethylene glycol, propane diols, glycerine, polyethylene glycol, acetone, cyclohexanone, pyrrolidones, toluene, dimethylbenzene, ethyl acetate, dimethyl formamide, dimethyl sulfoxide (DMSO), and consumption accounts for 10～80% of composition total weight.
5. Pesticidal combination according to claim 1 and 2, when it is characterized in that preparing wetting powder, the dispersant that adds is one or more the mixture in lignosulfonates, fatty acid amide N methyl taurine sodium salt, alkylphenol polyoxyethylene sulphate, lignosulfite, fatty acid ester sulphate, polyoxyethylene polyoxypropylene block copolymer, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, and consumption accounts for 5～35% of composition total weight; The wetting agent that adds is dodecyl benzene sulfonate, agriculture breast 2000, the withered powder of tea, spaonin powder, pull open one or more the mixture in powder, wetting and penetrating agent F, and consumption accounts for 5～30%; The carrier that adds is one or more the mixture in kaolin, diatomite, atlapulgite, White Carbon black, clay, precipitated calcium carbonate, talcum powder, and consumption accounts for 15～75% of composition total weight.
6. Pesticidal combination according to claim 1 and 2, when it is characterized in that preparing water-dispersible granules, the wetting agent that adds is one or more the mixture in fatty acid amide N methyl taurine sodium salt, lignosulfonates, alkylphenol polyoxyethylene sulphate, petroleum sodium sulfonate, alkylnaphthalene sulfonate, fatty acid ester sulphate, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, lignosulfite, the withered powder of tea, spaonin powder, and consumption accounts for 5～30% of composition total weight; The dispersant that adds is one or more the mixture in ethoxylated dodecyl alcohol, naphthalenesulfonic acid-formaldehyde condensate, dioctyl sodium sulphosuccinate, acrylate homopolymer sodium salt, and consumption accounts for 5～10% of composition total weight; The binding agent that adds is one or more the mixture in starch, polyvinyl acetate, polyvinyl alcohol, polyethylene glycol, sodium silicate, gelatin, soybean lecithin, cyclodextrin, gum Arabic, and consumption accounts for 1～10% of composition total weight; The disintegrant that adds is one or more the mixture in urea, magnesium chloride, aluminium chloride, sodium chloride, ammonium sulfate, bentonite, and consumption accounts for 5～10% of composition total weight; The carrier that adds is one or more the mixture in kaolin, diatomite, atlapulgite, White Carbon black, clay, precipitated calcium carbonate, talcum powder, montmorillonite, and consumption accounts for 15～70% of composition total weight.
7. Pesticidal combination according to claim 1 and 2, is characterized in that described Pesticidal combination has synergistic effect to the control of rice grub.
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| CN103503876B (en) * | 2012-06-29 | 2016-08-03 | 陕西美邦农药有限公司 | A kind of brominated worm Benzoylamide and the Pesticidal combination of neires toxin |
| CN105519537A (en) * | 2014-10-25 | 2016-04-27 | 陕西美邦农药有限公司 | Pesticide insecticidal composition containing N-(2-(tert-butylaminoformyl)-4-chloro-6-methylphenyl)-1-(3-chloropyridin-2-yl)-3-fluoromethoxy-1H-pyrazolyl-5-formamide (ZJ3757) |
| US20180079739A1 (en) * | 2016-09-19 | 2018-03-22 | Arysta Lifescience North America, Llc. | Manufacturing Method For and Insecticidal Compositions Comprising Thiocyclam Hydrochloride |
| CN110140724A (en) * | 2018-02-13 | 2019-08-20 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| MA61493B1 (en) * | 2020-05-18 | 2024-10-31 | Upl Limited | STABILIZATION SYSTEM FOR AN AGROCHEMICAL COMPOSITION |
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| CN1678192A (en) * | 2001-08-13 | 2005-10-05 | 纳幕尔杜邦公司 | Arthropodicidal anthranilamides |
| CN101084751A (en) * | 2006-06-09 | 2007-12-12 | 梁建忠 | Method for preparing thiocyclam and fipronil composite micro emulsion |
| CN101268779A (en) * | 2008-05-08 | 2008-09-24 | 国家农药创制工程技术研究中心 | Insecticidal composition containing chlorantraniliprole and monosultap |
| CN101557710A (en) * | 2006-12-14 | 2009-10-14 | 石原产业株式会社 | Pesticide composition |
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| CN101084751A (en) * | 2006-06-09 | 2007-12-12 | 梁建忠 | Method for preparing thiocyclam and fipronil composite micro emulsion |
| CN101557710A (en) * | 2006-12-14 | 2009-10-14 | 石原产业株式会社 | Pesticide composition |
| CN101268779A (en) * | 2008-05-08 | 2008-09-24 | 国家农药创制工程技术研究中心 | Insecticidal composition containing chlorantraniliprole and monosultap |
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Application publication date: 20120328 Assignee: HUNAN HAILI HIGH-TECH INDUSTRY GROUP CO., LTD. Assignor: Hunan Chemical Engineering Inst. Contract record no.: 2014430000124 Denomination of invention: Pesticide composition containing chlorantraniliprole and thiocyclam Granted publication date: 20130619 License type: Exclusive License Record date: 20140708 |
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