CN102423627B - Method and device for intelligent air purification - Google Patents
Method and device for intelligent air purification Download PDFInfo
- Publication number
- CN102423627B CN102423627B CN201110228063.9A CN201110228063A CN102423627B CN 102423627 B CN102423627 B CN 102423627B CN 201110228063 A CN201110228063 A CN 201110228063A CN 102423627 B CN102423627 B CN 102423627B
- Authority
- CN
- China
- Prior art keywords
- air
- dust
- air purification
- valve
- catalyst filter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000004887 air purification Methods 0.000 title claims description 53
- 239000000428 dust Substances 0.000 claims abstract description 124
- 239000003054 catalyst Substances 0.000 claims abstract description 79
- 239000000376 reactant Substances 0.000 claims abstract description 52
- 239000003344 environmental pollutant Substances 0.000 claims abstract description 37
- 231100000719 pollutant Toxicity 0.000 claims abstract description 37
- 238000001914 filtration Methods 0.000 claims abstract 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 26
- 238000004140 cleaning Methods 0.000 claims description 24
- 239000007800 oxidant agent Substances 0.000 claims description 18
- 239000002808 molecular sieve Substances 0.000 claims description 17
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical group [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 15
- 230000001590 oxidative effect Effects 0.000 claims description 13
- 239000004408 titanium dioxide Substances 0.000 claims description 13
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 12
- 150000002894 organic compounds Chemical class 0.000 claims description 9
- 238000011144 upstream manufacturing Methods 0.000 claims description 9
- 238000000605 extraction Methods 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 238000009825 accumulation Methods 0.000 claims 5
- 239000012716 precipitator Substances 0.000 claims 5
- 239000011859 microparticle Substances 0.000 claims 4
- 230000001580 bacterial effect Effects 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000003517 fume Substances 0.000 claims 1
- 230000002070 germicidal effect Effects 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 239000002957 persistent organic pollutant Substances 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000002386 air freshener Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 23
- 239000012717 electrostatic precipitator Substances 0.000 description 21
- 235000019645 odor Nutrition 0.000 description 12
- 241000894006 Bacteria Species 0.000 description 9
- 238000000746 purification Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000000809 air pollutant Substances 0.000 description 2
- 231100001243 air pollutant Toxicity 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
Images
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
Abstract
Description
【技术领域】【Technical field】
本发明专利涉及环保领域,更加具体地说,涉及一种可用于空气净化的智能装置。The patent of the present invention relates to the field of environmental protection, and more specifically, relates to an intelligent device that can be used for air purification.
【背景技术】【Background technique】
空气中的污染物主要是分两个形态组成,一是如灰尘、细菌、霉菌等形状较大的微粒,其分子结构复杂,由多种不同的物质或成份结合而成,大约百分之一微米至微米大小;一是如气体、臭味、挥发性有机化学物等化学份子,其化学结构简单,由数种化学元素组成,且十分细小,只有埃米至纳米的大小。Pollutants in the air are mainly composed of two forms. One is larger particles such as dust, bacteria, and mold. Their molecular structure is complex and they are composed of many different substances or components. Micron to micron in size; one is chemical molecules such as gases, odors, and volatile organic chemicals, which have a simple chemical structure and are composed of several chemical elements, and are very small, only in the size of angstroms to nanometers.
要处理灰尘或形状较大的微粒是,一般是使用静电除尘或利用高效能的尘粒过滤网。效果往往可达百分之八十,甚至是百分之九十九点九以上。但是,要处理长度只有埃米至纳米大的挥发性有机化学物,并不是这么容易。To deal with dust or larger particles, electrostatic precipitators or high-efficiency dust filters are generally used. The effect can often reach 80%, or even more than 99.9%. However, it is not so easy to deal with VOCs with lengths ranging from angstroms to nanometers.
由臭氧产生器或负离子机产生的氧化剂,如臭氧或氢氧游离基等,都是非常有用的反应剂,属于氧化剂类,它们可分解有害而细小至化学分子大的物质,所以被广泛用于净化空气。但是,这些氧化剂的净化效率通常是与臭氧或氢氧游离基于流体内的浓度有关。如果直接释放臭氧或氢氧游离基于空气内,其浓度将立即被稀释;而且,他们往往会击中流体内非目标性的媒介分子,并容易衰竭,而不能有效地氧化污染物及有机化合物。正因为这个原因,一般的负离子机并不是有效的空气清洁系统,要达到非常高的臭氧浓度才可有效地净化空气。为解决以上问题,有空气净化机利用了催化剂,如二氧化钛于紫外光灯照射下,产生氧化剂,氧化或还完氧化气体污染物。也有根据不同污染物及有机化合物的形状、取向、大小及亲水性的分子筛,一并地吸附目标性的有机化合物分子及氧化剂。再在分子筛里的纳米小孔内,进行化学反影,氧化污染物。Oxidants produced by ozone generators or negative ion machines, such as ozone or hydroxyl radicals, are very useful reactants and belong to the oxidant category. They can decompose harmful substances from small to large chemical molecules, so they are widely used Purifying air. However, the purification efficiency of these oxidants is usually related to the concentration of ozone or free hydrogen in the fluid. If ozone or hydrogen are released directly into the air, their concentration will be diluted immediately; moreover, they tend to hit untargeted mediator molecules in the fluid and are prone to exhaustion instead of effectively oxidizing pollutants and organic compounds. Because of this reason, the general negative ion machine is not an effective air cleaning system, and it needs to reach a very high ozone concentration to effectively purify the air. In order to solve the above problems, some air purifiers use catalysts, such as titanium dioxide, to generate oxidants under the irradiation of ultraviolet light, and oxidize or completely oxidize gas pollutants. There are also molecular sieves based on the shape, orientation, size and hydrophilicity of different pollutants and organic compounds, which can simultaneously adsorb targeted organic compound molecules and oxidants. Then, in the nanometer pores in the molecular sieve, chemical reflection is carried out to oxidize pollutants.
一般在这类系统中,空气中两个主要形态的污染物(微粒及气体污染物),都一次性一并被吸进系统中。污染的空气先经过微粒过滤,才进入处理气体污染物的催化滤芯,进行化学反应,分解气体污染物。由于非常高效能的微粒过滤网亦不是百分之百可以去除空气中的微粒。于非常污染的空气情况下,如吸烟场所,强迫所有污染的空气及氧化剂一次性先经过微粒过滤装置才到分子筛滤芯,污染空气中的微粒不能一次性的被去除(见图一),残余而带有气味的微粒(如尼古丁烟油微粒等)便会积聚在催化剂的表面,堵塞了进行催化反应的活跃基位,令后来的气体污染物或及氧化剂不能有效地进行化学反应。久而久之,这空气净化系统不单不能有效去除空气中的味道污染物,积聚于催化剂表面的灰尘更成为细菌的温床,启动该催化剂表面附存着细菌及累积灰尘的空气净化机,尤如启动一部有如会释放出污染物(细菌、味道、微尘等)的机器。除了频密更换催化剂滤芯外,没有更好的解决方法,这样,不单达不到环保的目的,还会制造大量废催化剂滤芯的二次污染。Typically in such systems, the two main forms of pollutants in the air (particulate and gaseous pollutants) are sucked into the system at one time. The polluted air is first filtered by particulates before it enters the catalytic filter element for processing gas pollutants, where it undergoes a chemical reaction and decomposes gas pollutants. Due to the very high efficiency of the particle filter, it is not 100% able to remove the particles in the air. In the case of very polluted air, such as smoking places, all polluted air and oxidants are forced to pass through the particle filter device at one time before reaching the molecular sieve filter element. The particles in the polluted air cannot be removed at one time (see Figure 1), and the residual Odor-bearing particles (such as nicotine e-liquid particles, etc.) will accumulate on the surface of the catalyst, blocking the active base of the catalytic reaction, so that the subsequent gas pollutants or oxidants cannot effectively carry out chemical reactions. Over time, this air purification system not only cannot effectively remove odor pollutants in the air, but the dust accumulated on the surface of the catalyst has become a breeding ground for bacteria. Starting the air purifier with bacteria and accumulated dust on the surface of the catalyst is like starting an air purifier. There are machines that release pollutants (germs, odors, dust, etc.). Apart from frequent replacement of catalyst filter elements, there is no better solution. This will not only fail to achieve the purpose of environmental protection, but also create secondary pollution of a large number of spent catalyst filter elements.
【发明内容】【Content of invention】
有鉴于此,本发明提供一种可有效防止催化剂失效的空气净化方法。In view of this, the present invention provides an air purification method that can effectively prevent catalyst failure.
一种使空气中的微粒污染物和气体污染物先后次序地被分开净化的空气净化方法,包括如下步骤:An air purification method for separately purifying particulate pollutants and gaseous pollutants in the air sequentially, comprising the following steps:
在空气净化装置内设置除尘装置、催化剂滤芯及用于控制空气在所述空气净化装置内流动方向的活门;打开或关闭所述活门,以控制空气在净化装置内流动方向,使高灰尘浓度的空气不经过风阻较大的所述催化剂滤芯。A dust removal device, a catalyst filter element and a valve for controlling the flow direction of air in the air purification device are arranged in the air purification device; open or close the valve to control the flow direction of the air in the purification device, so that the high dust concentration The air does not pass through the catalyst filter element with relatively large wind resistance.
上述空气净化方法,控制活门的开关控制空气于空气清新机中流动的路程,从而防止堵塞催化剂滤芯的以致使催化剂失效。In the above-mentioned air purification method, the switch of the valve is controlled to control the path of air flowing in the air purifier, so as to prevent the blockage of the catalyst filter element and cause the catalyst to fail.
进一步地,当空气中的灰尘浓度高于默认值时,所述活门会打开,空气经过所述除尘装置,而不经过催化剂滤芯直接从没有风阻的出口排出,使空气中的微粒先被处理;直至灰尘浓度低于默认值,所述活门会被关闭,空气必须经过所述除尘装置及催化剂滤芯才排出,从而处理气体污染物。Further, when the dust concentration in the air is higher than the default value, the valve will be opened, and the air will pass through the dust removal device and be directly discharged from the outlet without wind resistance without passing through the catalyst filter element, so that the particles in the air will be processed first; Until the dust concentration is lower than the default value, the valve will be closed, and the air must pass through the dust removal device and the catalyst filter element to be discharged, so as to deal with the gaseous pollutants.
进一步地,所述活门打开时,造成没有风阻的入口。Further, when the valve is opened, an entrance without wind resistance is created.
进一步地,所述活门关闭时与催化剂滤芯紧凑成连成一块,使空气经过所述除尘装置后,必须经过催化剂滤芯才排出。Further, when the valve is closed, it is compactly connected with the catalyst filter element, so that after the air passes through the dust removal device, it must pass through the catalyst filter element before being discharged.
进一步地,所述的空气净化装置还设置有灰尘传感器及中央处理器。Further, the air purification device is also provided with a dust sensor and a central processing unit.
进一步地,所述活门的开关,由所述灰尘传感器及中央处理器控制。Further, the switch of the valve is controlled by the dust sensor and the central processing unit.
进一步地,所述除尘装置还包括静电集尘器,所述灰尘传感器用于量度周围环境里的灰尘浓度,再计算所述静电集尘器已容纳累积灰尘量,当已容纳累积灰尘量高于可以累积灰尘预设数值,中央处理器会发出须要清洁静电集尘器的警告。Further, the dust removal device also includes an electrostatic precipitator, and the dust sensor is used to measure the dust concentration in the surrounding environment, and then calculate the amount of accumulated dust contained in the electrostatic precipitator. When the accumulated dust amount is higher than A preset amount of dust can be accumulated, and the CPU will issue a warning that the electrostatic precipitator needs to be cleaned.
进一步地,所述已容纳累积灰尘量是这样计算的:Further, the amount of accumulated dust that has been accommodated is calculated as follows:
已容纳累积灰尘量=(风速速度x空气净化装置启动时间x已量度周围环境里的灰尘浓度)+上次启动空气净化装置已容纳累积灰尘量。Accommodated accumulated dust amount = (wind speed x air purification device start-up time x measured dust concentration in the surrounding environment) + the accumulated accumulated dust amount that the air purification device was started last time.
进一步地,所述静电集尘器可从整个空气净化装置中拆出清洁。Furthermore, the electrostatic precipitator can be removed from the entire air cleaning device for cleaning.
进一步地,所述催化剂滤芯为处理气味或气体污染物的催化剂滤芯。Further, the catalyst filter element is a catalyst filter element for treating odor or gas pollutants.
进一步地,所述空气净化装置还设置有反应物产生器,所述除尘装置设置在所述反应物产生器上游位置,所述活门及所述催化剂滤芯置设在所述反应物产生器下游位置。Further, the air purification device is also provided with a reactant generator, the dust removal device is arranged at the upstream position of the reactant generator, and the valve and the catalyst filter element are arranged at the downstream position of the reactant generator .
进一步地,所述活门打开时,所述反应物产生器必须同时关闭,以防止在没有催化剂配合使用下,导致反应物外泄。Further, when the valve is opened, the reactant generator must be closed at the same time, so as to prevent the reactant from leaking out without the cooperation of the catalyst.
进一步地,所述的空气净化装置还设抽气风扇,用于带动空气在所述空气净化装置内从上游至下游流动。Further, the air purification device is further provided with an air extraction fan, which is used to drive air to flow from upstream to downstream in the air purification device.
进一步地,所述除尘装置用于除掉百分之一微米或以上大小的微粒。Further, the dust removal device is used to remove particles with a size of one hundredth of a micron or more.
进一步地,所述除尘装置包括静电集尘器。Further, the dust removal device includes an electrostatic precipitator.
进一步地,所述除尘装置包括高效能微粒过滤网。Further, the dust removal device includes a high-efficiency particulate filter.
进一步地,所述催化剂滤芯是二氧化钛。Further, the catalyst filter element is titanium dioxide.
进一步地,所述催化剂滤芯是分子筛滤芯。Further, the catalyst filter element is a molecular sieve filter element.
进一步地,所述反应物产生器是产生臭氧及发出可杀菌波长的紫外光灯。Further, the reactant generator is an ultraviolet lamp that generates ozone and emits bactericidal wavelengths.
进一步地,所述的反应物产生器是还原氧化剂产生器。Further, the reactant generator is a reducing oxidant generator.
进一步地,所述的反应物产生器是氧化剂产生器。Further, the reactant generator is an oxidant generator.
进一步地,所反述的应物产生器可以是发出有效波长,且可照射的二氧化钛表面的紫外光灯。Further, the reactant generator mentioned above can be an ultraviolet lamp that emits an effective wavelength and can irradiate the surface of titanium dioxide.
进一步地,所述的催化剂滤芯前面还可设置高效能微粒过滤网。Further, a high-efficiency particle filter can also be arranged in front of the catalyst filter element.
进一步地,所述紫外光灯还照射所述的高效能微粒过滤网,以防黏附于高效能微粒过滤网上面的灰尘有机会发生细菌繁殖。Further, the ultraviolet light also irradiates the high-efficiency particulate filter to prevent the dust adhering to the high-efficiency particulate filter from multiplying bacteria.
进一步地,所述的空气净化装置还包括气味传感器及中央处理器。Further, the air purification device also includes an odor sensor and a central processing unit.
进一步地,所述气味传感器用于量度周围环境里的有机化合物的浓度,再把数据传输致所述中央处理器,所述中央处理器再判断所述风扇的速度。Further, the odor sensor is used to measure the concentration of organic compounds in the surrounding environment, and then transmit the data to the central processing unit, and the central processing unit judges the speed of the fan.
进一步地,所述的静电集尘器可从整个空气净化装置中拆出清洁。Further, the electrostatic precipitator can be removed from the whole air cleaning device for cleaning.
在本智能空气净化系统中,空气中的污染物会先后次序地被分开净化,首先是处理体积较大的微粒,使其在处理的空间中浓度降至理想水平,最后才处理细小至分子结构的气体污染物。跟传统的一次性迫使空气经过高效能微粒过滤网及除味滤芯,以致残余微尘堵除味塞滤芯,令除味滤芯容易失效。而提供一种高效、环保、减低制造二次污染的空气清净化装置。In this intelligent air purification system, the pollutants in the air will be separated and purified sequentially. Firstly, the larger particles are treated to reduce their concentration in the treatment space to an ideal level, and finally the finer particles are treated. gas pollutants. Compared with the traditional one-time forcing of air through the high-efficiency particulate filter and deodorizing filter element, the residual dust will block the deodorizing filter element, making the deodorizing filter element prone to failure. To provide an air cleaning device that is highly efficient, environmentally friendly, and reduces secondary pollution.
一种空气净化装置,包括壳体,所述壳体上带有流体的入口和出口,所述壳体内设置有An air cleaning device, comprising a housing with a fluid inlet and an outlet, the housing is provided with
(i)除尘装置(i) Dust removal device
(ii)控制空气于净化装置内流动方向的活门(ii) The valve controlling the flow direction of air in the purification device
(iii)反应物产生器(iii) Reactant Generator
(iv)催化剂滤芯(iv) Catalyst filter element
(v)抽气风扇(v) Exhaust fan
(vi)灰尘传感器(vi) Dust sensor
(vii)中央处理器(vii) CPU
其特征在于,所述除尘装置设置在所述反应物产生器上游位置,所述活门及所述催化剂滤芯置设在所述反应物产生器下游位置,所述的抽气风扇设置在任何位置,带动空气从上游至下游流动。所述活门关闭时与催化剂滤芯紧凑成连成一块,使空气经过所述的除尘装置后及所述反应物产生器,必须经过催化剂滤芯才排出。It is characterized in that the dust removal device is arranged at the upstream position of the reactant generator, the valve and the catalyst filter element are arranged at the downstream position of the reactant generator, and the exhaust fan is arranged at any position, Drive the air flow from upstream to downstream. When the valve is closed, it is compactly connected with the catalyst filter element, so that the air must pass through the catalyst filter element to be discharged after passing through the dust removal device and the reactant generator.
所述活门打开时,造成没有风阻的入口,空气经过所述的静电集尘器后及所述反应物产生器后,不经催化剂滤芯而从没有风阻的出口排出。由于带有高灰尘浓度的空气不会经过风阻较大的催化剂滤芯,催化剂滤芯免了被灰尘污染,其生命周期得以延长。When the valve is opened, an inlet without wind resistance is formed, and after the air passes through the electrostatic precipitator and the reactant generator, it is discharged from the outlet without wind resistance without passing through the catalyst filter element. Because the air with high dust concentration will not pass through the catalyst filter element with large wind resistance, the catalyst filter element is prevented from being polluted by dust, and its life cycle can be extended.
所述活门打开时,所述反应物产生器必须同时关闭,以防在没有催化剂配合使用下,导致反应物外泄。这样,即使反应物产生器是臭氧发生器,亦不会因此而导致臭氧外泄。When the valve is opened, the reactant generator must be closed at the same time, so as to prevent the reactant from leaking out without the cooperation of the catalyst. In this way, even if the reactant generator is an ozone generator, the leakage of ozone will not be caused.
所述活门的开关,由所述的灰尘传感器及中央处理器控制。The switch of the valve is controlled by the dust sensor and the central processing unit.
所述的除尘装置,指用作除掉百分之一微米或以上大小的微粒。The dust removal device is used to remove particles with a size of one hundredth of a micron or more.
所述的除尘装置,还包括电集尘器。The dust removal device also includes an electric dust collector.
所述的除尘装置,还包括高效能微粒过滤网。The dust removal device also includes a high-efficiency particulate filter.
所述的催化剂滤芯是分子筛滤芯时,所述的反应物产生器可以是产生臭氧及发出可杀菌波长的紫外光灯。这样,除了可产生氧化剂予分子筛滤芯作氧化反应,亦可有加强杀菌的效用。When the catalyst filter element is a molecular sieve filter element, the reactant generator can be an ultraviolet lamp that generates ozone and emits a bactericidal wavelength. In this way, in addition to generating an oxidizing agent for the molecular sieve filter element for oxidation reaction, it can also have the effect of strengthening sterilization.
所述的催化剂滤芯是分子筛滤芯时,所述的反应物产生器可以是氧化剂产生器。因为部份气体污染物必须经过氧化作用才可以分解。When the catalyst filter element is a molecular sieve filter element, the reactant generator may be an oxidant generator. Because some gaseous pollutants must be oxidized before they can be decomposed.
所述的催化剂滤芯是分子筛滤芯时,所述的反应物产生器可以是还原氧化剂产生器。因为部份气体污染物必须经过还原氧化作用才可以分解。When the catalyst filter element is a molecular sieve filter element, the reactant generator may be a reducing oxidant generator. Because some gaseous pollutants must undergo reduction and oxidation before they can be decomposed.
所述的催化剂滤芯是二氧化钛时,所述的反应物产生器可以是氧化剂产生器。When the catalyst filter element is titanium dioxide, the reactant generator may be an oxidant generator.
所述的催化剂滤芯是二氧化钛时,所述的反应物产生器可以是发出有效波长,且可照射的二氧化钛表面的紫外光灯,这样,紫外光灯可以提供足够的能量予二氧化钛作氧化气体污染物化学反应。When the catalyst filter element is titanium dioxide, the reactant generator can be an ultraviolet light lamp that emits an effective wavelength and can be irradiated on the surface of titanium dioxide, so that the ultraviolet light lamp can provide enough energy to titanium dioxide as an oxidizing gas pollutant chemical reaction.
所述的分子筛滤芯前面还可设置高效能微粒过滤网。当活门关闭时,所有空气被迫经过分子筛滤芯,高效能微粒过滤网可以为分子筛滤芯作终的保护。所述紫外光灯还照射所述的高效能微粒过滤网,以防黏附于高效能微粒过滤网上面的灰尘有机会发生细菌繁殖。A high-efficiency particle filter can also be arranged in front of the molecular sieve filter element. When the valve is closed, all air is forced through the molecular sieve filter, and the HEPA filter provides final protection for the molecular sieve filter. The ultraviolet lamp also irradiates the high-efficiency particulate filter to prevent the dust adhering to the high-efficiency particulate filter from multiplying bacteria.
所述灰尘传感器,量度周围环境里的灰尘浓度,再把数据传输致中央处理器,中央处理器再判断所述活门的开关。中央处理器的判断,仍跟据比较灰尘浓度及,当灰尘浓度高于默认值时,表示灰尘浓度非常高,静电集尘器或高效能微粒过滤网不能一次性处理空气中的灰尘,使其不会影响催化剂滤芯。因此,有必要开启所述活门,先处理灰尘污染物。当灰尘浓度低于默认值时,表示灰尘浓度理想,静电集尘器或高效能微粒过滤网可以一次性处理空气中的灰尘,因此,可以关闭所述活门,集中处理气体染物。The dust sensor measures the dust concentration in the surrounding environment, and then transmits the data to the central processing unit, and the central processing unit judges the switch of the shutter. The judgment of the central processing unit is still based on the comparison of the dust concentration and the dust concentration. When the dust concentration is higher than the default value, it means that the dust concentration is very high. Catalyst cartridges will not be affected. Therefore, it is necessary to open the valve and deal with dust contamination first. When the dust concentration is lower than the default value, it means that the dust concentration is ideal, and the electrostatic precipitator or the high-efficiency particulate filter can treat the dust in the air at one time, so the valve can be closed to concentrate on treating the gaseous pollutants.
所述空气净化装置,还包括了气味传感器及中央处理器。The air purification device also includes an odor sensor and a central processing unit.
所述气味传感器,量度周围环境里的有机化合物的浓度,再把数据传输致中央处理器,中央处理器再判断所述风扇的速度。这样,针对不同空气污染物浓度,智能地净化空气。The odor sensor measures the concentration of organic compounds in the surrounding environment, and then transmits the data to the central processing unit, and the central processing unit judges the speed of the fan. In this way, the air is intelligently purified according to the concentration of different air pollutants.
所述灰尘传感器,量度周围环境里的灰尘浓度,再计算所述静电集尘器已容纳累积灰尘量,当累积灰尘量高于可以累积灰尘预设数值,中央处理器会发出须要清洁静电集尘器的警告。The dust sensor measures the dust concentration in the surrounding environment, and then calculates the amount of accumulated dust that the electrostatic precipitator has accommodated. When the accumulated dust amount is higher than the preset value that can accumulate dust, the central processing unit will send out the need to clean the electrostatic dust collector device warning.
所述已容纳累积灰尘量是这样计算的:The amount of accumulated dust contained is calculated as follows:
已容纳累积灰尘量=(风速速度x空气净化装置启动时间x已量度周围环境里的灰尘浓度)+上次启动空气净化装置已容纳累积灰尘量。Accommodated accumulated dust amount = (wind speed x air purification device start-up time x measured dust concentration in the surrounding environment) + the accumulated accumulated dust amount that the air purification device was started last time.
所述除尘装置是静电集尘器时,是可以从整个空气净化装置中拆出清洁。When the dust removal device is an electrostatic precipitator, it can be removed from the whole air cleaning device for cleaning.
由于对于不同的空气质素环境,不同人有不同的感测度,在特殊情况下,部份人对灰尘或气味浓度比较敏感,因此所述的控制空气净化装置,除了利用灰尘传感器及中央处理器控制活门开关外,在任何情况下,使用者可以利用本身的臭觉代替所述灰尘传感器,利用本身的判断代替所述中央处理器,手动控制活门开关。Since different people have different sensitivity to different air quality environments, in special cases, some people are more sensitive to dust or odor concentration. In addition to controlling the valve switch, in any case, the user can use his own sense of smell to replace the dust sensor, and use his own judgment to replace the central processing unit to manually control the valve switch.
本发明的空气净化装置,控制活门的开关控制空气于空气清新机中流动的路程,从而防止堵塞催化剂滤芯的以致使催化剂失效。活门开关,乃通过传感器及中央处理器对空气的质素作出评估而定。当空气中的灰尘浓度高至超出良好级水平时,中央处理器发出指令把所述活门打开,同时亦会暂时性关闭反应物产生器,此举亦可防止反应物在未有经过催化剂的情况下外泄。直至当空气中的灰尘浓度达致出良好级水平时,中央处理器发出指令把所述活门关闭,同时亦启动所述的反应物产生器,使其可以产生反应物,与气体有机污染物一同于催化剂的表面,进行分解。本实发明智能地及有次序地处理污染空气中灰尘及气体污染物,有利延长催化剂的寿命,减少二次污染,达致真正环保的目的。The air purification device of the present invention controls the switch of the valve to control the path of air flowing in the air purifier, so as to prevent the blockage of the catalyst filter element and cause the catalyst to fail. The valve switch is determined by evaluating the quality of the air through the sensor and the central processing unit. When the dust concentration in the air is high enough to exceed the good level, the central processing unit sends an instruction to open the valve, and also temporarily closes the reactant generator, which also prevents the reactant from passing through the catalyst. The next leak. Until the dust concentration in the air reaches a good level, the central processing unit issues an instruction to close the valve, and at the same time activate the reactant generator so that it can generate reactants, which together with the gaseous organic pollutants decomposes on the surface of the catalyst. The present invention intelligently and orderly treats the dust and gas pollutants in the polluted air, which is beneficial to prolong the life of the catalyst, reduce secondary pollution, and achieve the goal of true environmental protection.
【附图说明】【Description of drawings】
图1是一般空气体净化装置的净化的结构示意图;Fig. 1 is the structural representation of the purification of general air purification device;
图2是发明的中央处理器对活门开关的程序作业图;Fig. 2 is the program operation diagram of central processing unit of invention to valve switch;
图3是发明的空气净化装置的实施例的结构示意图;Fig. 3 is the structural representation of the embodiment of the air cleaning device of invention;
图4是发明的空气净化装置的另一实施例的结构示意图;Fig. 4 is the structural representation of another embodiment of the air cleaning device of invention;
图5是本发明对比同类型但没有活门控制流程空气净化技术的气体污染物净化效果;Fig. 5 is the gas pollutant purification effect of the present invention compared with the same type but without valve control process air purification technology;
图6是本发明的其中一个实物结构示意图。Fig. 6 is a schematic diagram of the physical structure of the present invention.
【具体实施方式】【Detailed ways】
如图1所示,一般空气净化装置包括了壳体(15),其中主要有除尘部份(14),例如静电集尘器、或高效能静电除尘网,反应物产生器(16)及催化剂滤心(17)。所述的催化剂滤芯(17)是分子筛滤芯时,所述的反应物产生器(16)可以是产生氧及发出可杀菌波长的紫外光灯或氧化剂产生器。所述的催化剂滤芯(17)是二氧化钛时,所述的反应物产生器(16)可以是氧化剂产生器或发出有效波长,且可照射的二氧化钛(17)表面的紫外光灯。装置设置抽气风扇于任何位置,带动空气从上游(12)至下游(20)流动。大部份的灰尘或微粒(11),已于空气经过电集尘器、或高效能静电除尘网(14)时已除掉(13),余下小重的灰尘或微粒,经过反应物产生器(16),依附催化剂滤心(17)的表面(18)。使催化剂滤心(17)因受污染而失效。最后,只有小数的灰尘或微粒,混杂空气中大部份的灰尘或微粒(11),再进入空气净化装置。时间久了,积聚于催化剂表面的灰尘(18)更成为细菌的温床,启动该催化剂表面附存着细菌及累积灰尘(18)的空气净化机,尤如启动一部有如会释放出污染物(细菌、味道、微尘等)的机器。除了频密更换催化滤芯(17)外,没有更好的解决方法。As shown in Figure 1, the general air cleaning device includes a housing (15), which mainly contains a dust removal part (14), such as an electrostatic precipitator, or a high-efficiency electrostatic precipitator, a reactant generator (16) and a catalyst filter core (17). When the catalyst filter element (17) is a molecular sieve filter element, the reactant generator (16) can be an ultraviolet lamp or an oxidant generator that generates oxygen and emits a sterilizable wavelength. When the catalyst filter element (17) is titanium dioxide, the reactant generator (16) can be an oxidant generator or an ultraviolet lamp that emits an effective wavelength and can irradiate the surface of the titanium dioxide (17). The device is provided with an exhaust fan at any position to drive air to flow from upstream (12) to downstream (20). Most of the dust or particles (11) have been removed (13) when the air passes through the electrostatic precipitator or high-efficiency electrostatic precipitator (14), and the remaining small and heavy dust or particles pass through the reactant generator (16), attached to the surface (18) of the catalyst filter core (17). Make the catalyst filter core (17) fail due to contamination. Finally, only a small amount of dust or particles, mixed with most of the dust or particles (11) in the air, enters the air purification device. After a long time, the dust (18) accumulated on the surface of the catalyst has become a breeding ground for bacteria. Starting the air purifier with bacteria and accumulated dust (18) on the surface of the catalyst is like starting a machine that will release pollutants ( bacteria, odors, dust, etc.). In addition to frequently changing the catalytic filter element (17), there is no better solution.
如图2所示本空气净化装置的中央处理器对活门开关的程序作业图,As shown in Figure 2, the central processing unit of the air cleaning device is to the program operation diagram of the valve switch,
灰尘传感器,量度周围环境里的灰尘浓度,再计算所述静电集尘器可容纳累积灰尘量,当累积灰尘量高于一定预设数值,中央处理器会发出须要清洁静电集尘器的警告。然后中央处理器会比较周遭的积灰尘量及默认值,灰尘量浓度高于默认值时,活门会被打开及反应物产生器会被关掉,空气净化装置会继续把空从上游抽至下游,直至灰尘量浓度低于默认值。这时,有机化合物传感器收集空气净化装置的周围环境的有机化合物浓度数据,再跟据有机化合物的浓度,预算在催化剂需要进行分解气体污染物的化学反应时间,调节空气净化装置的抽风速度。但至针对不同空气污染物浓度,智能地净化空气。The dust sensor measures the dust concentration in the surrounding environment, and then calculates the amount of accumulated dust that the electrostatic precipitator can accommodate. When the accumulated dust amount is higher than a certain preset value, the central processing unit will issue a warning that the electrostatic precipitator needs to be cleaned. Then the central processing unit will compare the amount of dust in the surrounding area with the default value. When the dust concentration is higher than the default value, the valve will be opened and the reactant generator will be turned off. The air purification device will continue to pump air from upstream to downstream. , until the dust concentration is lower than the default value. At this time, the organic compound sensor collects the concentration data of organic compounds in the surrounding environment of the air purification device, and then according to the concentration of organic compounds, estimates the chemical reaction time that the catalyst needs to decompose the gas pollutants, and adjusts the ventilation speed of the air purification device. But it can intelligently purify the air according to the concentration of different air pollutants.
如图3所示,本发明的空气净化装置的结构示意图如下:As shown in Figure 3, the structural representation of air cleaning device of the present invention is as follows:
空气净化装置包括了壳体(15),其中主要有除尘部份(14),例如静电集尘器、或高效能静电除尘网,控制空气于净化装置内流动方向的活门(22)反应物产生器(16)、催化剂滤心(17),灰尘传感器(23)及中央处理器(24)。所述灰尘传感器(23)连接中央处理器(24),所述的中央处理器(24)连接活门(22),控制其开关。的所述的催化剂滤芯(17)是分子筛滤芯时,所述的反应物产生器(16)可以是产生臭氧及发出可杀菌波长的紫外光灯或氧化剂产生器。分子筛滤芯(17)前面还可设置高效能微粒过滤网,所述紫外光灯(16)还照射所述的高效能微粒过滤网,以防黏附于高效能微粒过滤网上面的灰尘有机会发生细菌繁殖。所述的催化剂滤芯(17)是二氧化钛时,所述的反应物产生器(16)可以是氧化剂产生器或发出有效波长,且可照射的二氧化钛(17)表面的紫外光灯。The air purification device includes a housing (15), which mainly includes a dust removal part (14), such as an electrostatic precipitator, or a high-efficiency electrostatic dust removal net, and a valve (22) that controls the flow direction of the air in the purification device. Device (16), catalyst filter core (17), dust sensor (23) and central processing unit (24). The dust sensor (23) is connected to the central processing unit (24), and the central processing unit (24) is connected to the valve (22) to control its switch. When the catalyst filter element (17) is a molecular sieve filter element, the reactant generator (16) can be an ultraviolet lamp or an oxidant generator that generates ozone and emits a sterilizable wavelength. A high-efficiency particulate filter can also be arranged in front of the molecular sieve filter element (17), and the ultraviolet lamp (16) also irradiates the high-efficiency particulate filter to prevent bacteria from adhering to the dust on the high-efficiency particulate filter. reproduce. When the catalyst filter element (17) is titanium dioxide, the reactant generator (16) can be an oxidant generator or an ultraviolet lamp that emits an effective wavelength and can irradiate the surface of the titanium dioxide (17).
装置设置抽气风扇于任何位置,带动空气从上游(12)至下游(20)流动。大部份的灰尘或微粒(11),已于空气经过电集尘器、或高效能静电除尘网(14)时已除掉(13),余下小重的灰尘或微粒,经过反应物产生器(16),再从活门(22)离开,不会依附催化剂滤心(17)的表面(18),及不会使催化剂滤心(17)因受污染而失效。The device is provided with an exhaust fan at any position to drive air to flow from upstream (12) to downstream (20). Most of the dust or particles (11) have been removed (13) when the air passes through the electrostatic precipitator or high-efficiency electrostatic precipitator (14), and the remaining small and heavy dust or particles pass through the reactant generator (16), leave from valve (22) again, can not adhere to the surface (18) of catalyst filter core (17), and can not make catalyst filter core (17) lose efficacy because of being polluted.
如图4所示本发明的空气净化装置的另一结构示意图如下:Another structural representation of the air cleaning device of the present invention as shown in Figure 4 is as follows:
当灰尘传感器(23)量度出空气中的微粒浓度达致理想水平时(11a),中央处理器(24)发出指令把所述活门(22)关闭,使活门(22)与催化剂滤芯(17)紧凑成连成一块,同时亦启动的反应物产生器(16),使空气经过所述的静电集尘器(14)及反应物产生器后(16),必须经过催化剂滤芯(17)才排出。反应物与气体有机污染物一同于催化剂滤芯(17)进行分解。When the dust sensor (23) measures the particle concentration in the air and reaches the ideal level (11a), the central processing unit (24) sends an instruction to close the valve (22), so that the valve (22) and the catalyst filter element (17) The reactant generator (16) that is compacted into one piece and also starts at the same time makes the air pass through the electrostatic dust collector (14) and the reactant generator (16) before being discharged through the catalyst filter element (17) . The reactant and gaseous organic pollutants are decomposed in the catalyst filter element (17).
如图5所示图本发明专利对比同类型但没有活门控制流程空气净化技术的气体污染物净化效果。此测试于—吸烟房间二百平方尺,楼层高三米进行行,在使用如图1所示的空气净化装置,空气净化装置去除有机污染物的效能于第十枝香烟燃点时开始失效,并放出积聚于滤芯里的污染物,使污染物增加。如果使用本发明的空气净化装置(即图3及图4显示的空空气净化装置),由于可以有效及有次序地先后处理空气中的污染物,处理气味的催化剂滤芯不受污染至失效,所以空气净化装置可以持久处理气体污染物。As shown in Figure 5, the invention patent compares the gas pollutant purification effect of the same type but without the valve control process air purification technology. This test was carried out in a smoking room of 200 square feet and a floor height of 3 meters. Using the air purification device shown in Figure 1, the effectiveness of the air purification device in removing organic pollutants began to fail when the tenth cigarette was lit, and emitted The pollutants accumulated in the filter element will increase the pollutants. If the air purification device of the present invention (i.e. the empty air purification device shown in Fig. 3 and Fig. 4) is used, since the pollutants in the air can be treated effectively and in an orderly manner, the catalyst filter element for treating odor will not be polluted to failure, so Air purification units can permanently treat gaseous pollutants.
如图6所示图本发明的一个实物结构图,机身包括了一个壳体(607),一个抽气风扇(606)、体一个静电除尘装置(601)作本装置的除尘装置、一个可以是产生臭氧及发出可杀菌波长的紫外光灯(604)作为本装置的反应物产生器,一个堆集密实的分子筛滤芯(603)作所述的催化剂滤芯、在分子筛滤芯前面还可设置高效能微粒过滤网(602)。紫外光灯还可以照射高效能微粒过滤网表面(602),加强杀菌,活门(605)设置于催化剂滤芯的同一水平。当灰尘污染物高浓度时,活门(605)开启,空气不会经过催化剂滤芯(603)而排出,好使空气净化装置先处理高浓度的灰尘污染物。As shown in Figure 6, a physical structure diagram of the present invention, the fuselage includes a housing (607), an exhaust fan (606), an electrostatic precipitator (601) as the dust removal device of the device, and a dust removal device that can An ultraviolet light lamp (604) that generates ozone and emits a bactericidal wavelength is used as the reactant generator of the device, and a densely packed molecular sieve filter element (603) is used as the catalyst filter element, and high-efficiency particles can also be arranged in front of the molecular sieve filter element. filter screen (602). The ultraviolet lamp can also irradiate the surface of the high-efficiency particulate filter (602) to strengthen sterilization, and the valve (605) is arranged at the same level of the catalyst filter element. When the concentration of dust pollutants is high, the valve (605) is opened, and the air will not be discharged through the catalyst filter element (603), so that the air purification device can process the high concentration of dust pollutants first.
Claims (18)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110228063.9A CN102423627B (en) | 2006-10-16 | 2006-10-16 | Method and device for intelligent air purification |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110228063.9A CN102423627B (en) | 2006-10-16 | 2006-10-16 | Method and device for intelligent air purification |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006101374089A Division CN101165417B (en) | 2006-10-16 | 2006-10-16 | Intelligent air purification method and device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102423627A CN102423627A (en) | 2012-04-25 |
| CN102423627B true CN102423627B (en) | 2014-02-19 |
Family
ID=45957708
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110228063.9A Expired - Fee Related CN102423627B (en) | 2006-10-16 | 2006-10-16 | Method and device for intelligent air purification |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102423627B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6653486B2 (en) * | 2015-07-30 | 2020-02-26 | パナソニックIpマネジメント株式会社 | Dust removal device and notification method |
| CN108496044A (en) * | 2016-01-22 | 2018-09-04 | 夏普株式会社 | air purifier |
| CN107449108B (en) * | 2017-07-22 | 2019-12-24 | 广州雅康净化工程有限公司 | Air purification method and air purification system |
| CN107355921B (en) * | 2017-07-22 | 2020-01-24 | 肇庆泰信环保新材料有限公司 | Environment-friendly air purification device |
| CN107238137B (en) * | 2017-08-13 | 2021-12-03 | 徐州百艾电子科技有限公司 | Environment-friendly air pollution purifier |
| KR102575475B1 (en) * | 2018-04-17 | 2023-09-07 | 서울바이오시스 주식회사 | Air cleaning module and refrigerator having the same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2633405Y (en) * | 2003-07-07 | 2004-08-18 | 中国航空工业规划设计研究院 | Novel dust remover |
| CN1625675A (en) * | 2002-04-29 | 2005-06-08 | 雅康国际科技有限公司 | Nano Catalytic Oxidation Air Filtration System |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3769595B2 (en) * | 1997-03-14 | 2006-04-26 | 川崎設備工業株式会社 | Air conditioner with sterilization / deodorization means |
| JP2006230626A (en) * | 2005-02-23 | 2006-09-07 | Matsushita Electric Works Ltd | Air cleaner |
-
2006
- 2006-10-16 CN CN201110228063.9A patent/CN102423627B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1625675A (en) * | 2002-04-29 | 2005-06-08 | 雅康国际科技有限公司 | Nano Catalytic Oxidation Air Filtration System |
| CN2633405Y (en) * | 2003-07-07 | 2004-08-18 | 中国航空工业规划设计研究院 | Novel dust remover |
Non-Patent Citations (2)
| Title |
|---|
| JP特开2006-230626A 2006.09.07 |
| JP特开平10-253096A 1998.09.25 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102423627A (en) | 2012-04-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101165417B (en) | Intelligent air purification method and device | |
| JP3773767B2 (en) | Air purifier and air conditioner equipped with an ion generator | |
| DK2307813T3 (en) | METHOD AND APPARATUS FOR AIR CLEANING | |
| DK2806903T3 (en) | A mobile disinfection device to disinfect a given facility or equipment and a method of using that device | |
| CN102423627B (en) | Method and device for intelligent air purification | |
| KR100807152B1 (en) | Filter of polluted air | |
| KR20120119475A (en) | Multiple air cleaning devices | |
| CN2747497Y (en) | Vertical photocatalysed air purifier | |
| CN206094328U (en) | An air purification device based on photocatalytic technology | |
| CN101590265A (en) | Horizontal indoor air UV sterilization and filtration purifier | |
| CN2639769Y (en) | Air sterilizing, dust removing and purifying equipment | |
| KR101463216B1 (en) | Apparatus for omitting bad smell having improved efficiency | |
| JP3000056B2 (en) | Air purifier | |
| CN201032232Y (en) | Indoor air pollution fast treating device | |
| KR20070046281A (en) | Industrial Combined Air Purifier | |
| KR100468224B1 (en) | Anion air-cleaning machine added photocatalyst sterilizing apparatus | |
| KR20050035921A (en) | The method of cleanning and sterilizing the air, and the apparatus for it | |
| KR100799106B1 (en) | Air cleaner with auxiliary sterilization and purification device | |
| KR200426286Y1 (en) | Filter of polluted air | |
| JP3749118B2 (en) | Air purifier | |
| KR200278597Y1 (en) | Anion air-cleaning machine added photocatalyst sterilizing apparatus | |
| KR20220056262A (en) | Portable sterilizer consisting of mixing module of negative ion output of high voltage generator | |
| CN118856483A (en) | A method for purifying polluted air | |
| JP2006075318A (en) | Dust collector | |
| CN109603534A (en) | A kind of air sterilization device based on photocatalysis technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140219 Termination date: 20181016 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |