A kind of water bath of acid-resistant and anti-high-temperature and processing method thereof
Technical field
The present invention relates to the water bath and the processing method thereof of water bath and processing method, particularly a kind of acid-resistant and anti-high-temperature that a kind of storage battery changes into.
Background technology
In lead acid accumulator production process, change into is one important operation; Storage battery internal temperature when energising changes into can raise, and changes into the middle and later periods temperature and can surpass 75 ℃, and too high change into temperature and can strengthen fluid loss; Unfavorable to the pole plate life-span, the battery initial capacity is also low.Temperature when generally adopting at present the method control storage battery that storage battery is put into the electrolytic bath water-bath to change in the industry.And contain dilute sulfuric acid in the battery liquid, and also unavoidable on the surface of storage battery remainingly have dilute sulfuric acid, thereby also can contain dilute sulfuric acid in the cooling water in the cooling water service area, and this acid cooling water has very strong corrosivity to equipment and ground.The accumulator plate electrolytic bath is generally taked ceramic trough, plank, rubber frame, and this groove, frame heaviness, labor strength is big, and useful life is short, and frock consumption is big, and can not adapt to does not have the new technology that welding changes into this international popular.Most of in recent years electrolytic bath adopts the engineering plastics injection mo(u)lding or adopts the PVC plastic board to be welded.Such water bath in the vitriolated water with high temperature under easy ageing with leak, the general life-span is 1 year.
Summary of the invention
For addressing the above problem, the present invention is a raw material with SMC or GMT, invents a kind of acidproofly, high temperature resistant, one-body molded, and intensity is good, uses 10 years indeformable water baths.
The SMC composite material is the abbreviation of Sheet molding compound, i.e. sheet molding compound.Primary raw material is made up of GF (special yarn), UP (unsaturated-resin), low shrinkage additive, MD (filler) and various auxiliary agent.The SMC composite material has excellent electrical insulation capability, mechanical performance, thermal stability, chemically-resistant anti-corrosive properties.
GMT (Glass Mat reinforced Thermoplastics) is glass-fiber reinforced thermoplastics.GMT is matrix with the thermoplastic resin; With the glass mat is the composite material that strengthens skeleton; Its specific strength height, high rigidity, impact property are good, lightweight, energy-conservation, have advantages such as molding cycle is short, impact property good, and reproducible utilization and storage cycle are long.
With them is that the acidproof and heat-resisting ability of the water bath that obtains of raw material is fine, is suitable for the requirement to water bath that is internalized in the process of battery.
Technical scheme of the present invention is:
A kind of water bath of acid-resistant and anti-high-temperature, it is a raw material with SMC or GMT, the utilization moulding technology; One-body molded; Comprise left frid, right frid, preceding frid, drop end and bottom cut board, described left frid, right frid upper edge are respectively arranged with left overlap and right overlap, and the upper edge of described preceding frid, drop end is respectively arranged with preceding stiffener, back stiffener; Described bottom cut board is provided with many protruding bars; Between left frid and protruding bar, be provided with a left side at a distance from baffle plate, between right frid and protruding bar, be provided with right at a distance from baffle plate, about design height when the height of baffle plate cool off according to battery definite; Bottom cut board between protruding bar and the right separated baffle plate is provided with priming hole, and right bottom cut board between baffle plate and right frid is provided with apopore.
Further, a described left side is the structure of progressive additive from top to following at a distance from baffle plate with right separated baffle plate.
Further, described protruding bar is semicircular, and along laterally arranging on the length direction of water bath, the distance between two protruding bar centers is 37mm.
A kind of processing method of water bath of acid-resistant and anti-high-temperature, it may further comprise the steps:
One, raw material is prepared:
Counting yield spare volume is confirmed feeding quantity, and SMC is with 1.85-2.2 g/cm
3Calculate feeding quantity, GMT is with 1.15-1. 3/cm
3Calculate feeding quantity; Then according to the planform of goods, feed location, flow path decision plastic shape and size are made model and press model again and cut out and expect;
Two, the preparation of mould:
Mold cleaning is clean, smear release agent 1-2 time at mould inner surface, under the mold hot state, be coated with external release agent at mold outer surface, and definite die pressure;
Three, raw material and mould heat up:
The SMC sheet molding compound is warmed up to more than 15 ℃, and GMT is warmed up to 160 ℃ ~ 170 ℃, and patrix is warmed up to 165 ℃ ~ 175 ℃, and counterdie is warmed up to 160 ℃ ~ 170 ℃;
Four, reinforced preceding preparation:
Put into to give and bury nut, on counterdie, spread cloth;
Five, reinforced:
Mold heated is added to the raw material after the heating in the mould to the temperature that needs;
Six, matched moulds pressurization and pressurize moulding:
After raw material adds, matched moulds pressurization rapidly, when mould contact material, pressing speed slows down, and prevents that material from extruding or it is uneven to flow, and keeps a period of time to make the water bath moulding then;
Seven, the demoulding:
Just during membrane, goods should smooth discharging can not be piled pressure, in order to avoid cause distortion, cool offs stacking again after 6 hours;
Eight, finishing overlap and punching:
Remove overlap and burr on the water bath,, promptly obtain water bath by the correction of punching of preformed hole position on the mould.
Further, the die pressure in described second step is confirmed as: the general goods of SMC are by the calculation of pressure of 500 Dun/㎡-600 Dun/㎡, and the high strength goods are according to the calculation of pressure of 800 Dun/㎡-1000 Dun/㎡; GMT presses 800-1200 ton/m
2Calculation of pressure.
Further, the external release agent in described second step is acid of triangle ester or silicone oil etc.
Further, the embedded nut in said the 4th step will eliminate rust before putting into mould, oil removal treatment, and add antirust coat.
Further, the cloth area in described the 4th step accounts for the 60%-70% of the counterdie gross area.
Further, the matched moulds time in described the 6th step is 12 seconds.
Further, the pressurize molding time in described the 6th step is pressed product thickness 0.8-1min/mm calculating.
Beneficial effect
(1) water bath of the inventive method preparation is raw material with GTM or SMC material, and one-body molded, processing method is simple, and the water bath quality of production is light and handy, is easy to carrying, has reduced labour intensity.
(2) material performance of water bath of the present invention is good, has given that water bath is acidproof, high temperature resistant, intensity is good, uses the indeformable premium properties of Denging for a long time.
(3) water bath of the present invention is reasonable in design, bottom cut board increase protruding bar and about at a distance from the utilization of baffle plate, it is high to have improved the cooling water utilization ratio, good cooling results.
Description of drawings
Fig. 1 is the structural representation of water bath of the present invention.
Fig. 2 is that the A-A of Fig. 1 is to sketch map.
Fig. 3 is that the B-B of Fig. 1 is to sketch map.
Embodiment
Further specify content of the present invention below in conjunction with concrete embodiment.
Shown in Fig. 1 ~ 3, a kind of water bath of acid-resistant and anti-high-temperature:
With SMC or GMT is raw material; The utilization moulding technology; One-body molded; Comprise left frid (1), right frid (4), preceding frid (6), drop end (2) and bottom cut board (9), be respectively arranged with left overlap (7) and right overlap (12) in left frid (1), right frid (4) upper edge, left overlap (7) and right overlap (12) can be selected to keep or remove as required.
Be respectively arranged with preceding stiffener (13), back stiffener (14) in the upper edge of preceding frid (6), drop end (2), be used to strengthen the intensity of water bath.
Bottom cut board (9) is provided with 9 protruding bars (3); Protruding bar is semicircular; Along laterally arranging on the length direction of water bath, the distance between two protruding bar centers is 37mm, and protruding bar (a 3) tool left side is 16mm at a distance from baffle plate with right distance at a distance from baffle plate.The effect of protruding bar (3) is to be beneficial to cooling water above storage battery is placed on to flow through from the bottom, accelerates cooling effect; Strengthen the intensity effect.
Between left frid (1) and protruding bar (3), be provided with the separated baffle plate (8) in a left side, its effect is to flow to a left side at a distance from baffle plate (8) when water, because water is evenly flowed to the right, it is even to be beneficial to temperature.
Between right frid (4) and protruding bar (8), be provided with rightly, act as and be decided to be height of water level at a distance from baffle plate (11), also be battery need cool off design height, just excessive to the right if water surpasses this height, guarantee the circulation cooling.The design height of a left side when the height of baffle plate (8) and right separated baffle plate (11) cools off according to battery confirms that a left side is the structure of progressive additive from top to following at a distance from baffle plate (8) and right separated baffle plate (11).
Protruding bar (3) and right be provided with priming hole (10) at a distance from the bottom cut board (9) between the baffle plate (11), effect is to install to draw water pipe: finishing in battery charge, need put water dried, is exactly to lean on this hole dirty.This hole is to be in normal off status.
Right at a distance between baffle plate (11) and the right frid (4), lean on the bottom cut board of into preceding frid (6) to be provided with apopore (5), effect is that cooling water overflows, and releases from apopore (5) when cooling water is higher than the height of the separated baffle plate (11) in the right side.
A kind of production method of water bath of acid-resistant and anti-high-temperature:
Selecting GTM of factory of building materials portion " 253 " or SMC sheet molding compound for use is raw material, by following explained hereafter water bath.
One, moulding is prepared
1. feeding quantity confirms
1.1 counting yield spare volume, to confirm feeding quantity, SMC calculates feeding quantity, GMT1.15-1. 3/cm with 1.85-2.2 g/cm
3, calculate feeding quantity.
1.2 cutting
According to the planform of goods, feed location, flow path decision plastic shape and size are made model and are pressed model sanction material again.Necessary environment health during operation is in order to avoid influence the presentation quality of goods.
1.3 the preparation of equipment
Be familiar with the various operating parameters of press, adjust the speed of service of operating pressure and press and the depth of parallelism of press table top, mould is installed must level, and guarantees the center of installation site at the press table top.
1.4 pressure testing: according to the integrality correction feeding quantity of goods spare
2, release agent smears
2.1 new die and long-term obsolete mould must be clean with mold cleaning before using, and smear release agent 1-2 time at mould inner surface.
2.2 external release agent will be coated with evenly (must be hot down at mould), uses external release agent less, smears when generally being the beginning moulding, no longer smears during ordinary production as far as possible.External release agent can be used the acid of triangle ester, silicone oil etc.
3, die pressure is confirmed
The general goods of SMC are by the calculation of pressure of 500 Dun/㎡-600 Dun/㎡, and the high strength goods are according to the calculation of pressure of 800 Dun/㎡-1000 Dun/㎡.GMT presses 800-1200 ton/m
2Calculation of pressure.
4, moulding production temperature
165 ℃ ~ 175 ℃ of patrixes, 160 ℃ ~ 170 ℃ of counterdies.
5, pressurize molding time is confirmed
Press product thickness and calculate 0.8-1min/mm calculating
6, give and bury nut and prepare
To give and bury nut and eliminate rust, oil removal treatment, and add antirust coat;
Two, moulding
1, dress mould
1.1 the temperature of sheet molding compound is more than 15 ℃ before the dress mould, the temperature before the GMT dress mould is at 160 ℃ ~ 170 ℃.
1.2 mould must be heated to the temperature that needs.
Bury nut 1.3 put into to give, want accurately the position.
1.4 when going into mould, the cloth area accounts for the 60%-70% of the gross area, the too little corner of causing easily lacks material, causes surface quality that pin trachoma etc. is arranged too greatly.
1.5 after SMC, GMT put into mould, answer chi to pressurize soon, prevent that material and mould are oversize time of contact, material solidifies, and influences flowing of material.
, matched moulds
2.1 matched moulds requires in 12 seconds, to close reality rapidly, when mould contact material, pressing speed slows down, and prevents that material from extruding or it is uneven to flow.
2.2 in the matched moulds process, generally do not need venting, complicated to die cavity, there are the goods of protruding part should stay gas vent.
, the demoulding
3.1 mould should be able to eject certain altitude, the convenient goods that take out.
3.2 eject have to fast speed in order to avoid the goods cracking.
3.3 stack: just during membrane, goods should smooth discharging can not be piled pressure, in order to avoid cause distortion, cool offs stacking again after 6 hours.
Three, finishing overlap and punching
1, remove overlap and burr with carefully frustrating cutter and blade, frustrating cutter should be vertical with cut surface, damage goods corner, and burr can be polished with spun yarn.
2, by giving the position of the boxing out correction of punching on the mould.
The technological parameter of specific embodiment is seen table 1.
The performance index of the water bath of specifically processing are seen table 2.
Can find out the water bath of being produced by this processing method by table 2, water bath is acidproof, high temperature resistant, intensity is good, uses the indeformable premium properties of Denging for a long time.