CN102697670B - Foaming agent type shampoo - Google Patents
Foaming agent type shampoo Download PDFInfo
- Publication number
- CN102697670B CN102697670B CN201210195508.2A CN201210195508A CN102697670B CN 102697670 B CN102697670 B CN 102697670B CN 201210195508 A CN201210195508 A CN 201210195508A CN 102697670 B CN102697670 B CN 102697670B
- Authority
- CN
- China
- Prior art keywords
- percent
- solid content
- foaming agent
- shampoo
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 61
- 239000004088 foaming agent Substances 0.000 title claims abstract description 25
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000008367 deionised water Substances 0.000 claims abstract description 31
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 31
- 229920001577 copolymer Polymers 0.000 claims abstract description 28
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims abstract description 19
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000001540 sodium lactate Substances 0.000 claims abstract description 16
- 229940005581 sodium lactate Drugs 0.000 claims abstract description 16
- 235000011088 sodium lactate Nutrition 0.000 claims abstract description 16
- 239000010692 aromatic oil Substances 0.000 claims abstract description 12
- -1 polyoxyethylene lauryl ether sulfosuccinic acid Polymers 0.000 claims description 33
- 239000007787 solid Substances 0.000 claims description 24
- 108700004121 sarkosyl Proteins 0.000 claims description 18
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 18
- 230000002421 anti-septic effect Effects 0.000 claims description 17
- 239000000470 constituent Substances 0.000 claims description 14
- OVBJJZOQPCKUOR-UHFFFAOYSA-L EDTA disodium salt dihydrate Chemical compound O.O.[Na+].[Na+].[O-]C(=O)C[NH+](CC([O-])=O)CC[NH+](CC([O-])=O)CC([O-])=O OVBJJZOQPCKUOR-UHFFFAOYSA-L 0.000 claims 5
- 150000003863 ammonium salts Chemical group 0.000 claims 5
- 210000004761 scalp Anatomy 0.000 abstract description 19
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 abstract description 11
- 239000006260 foam Substances 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 7
- 241000195940 Bryophyta Species 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 235000011929 mousse Nutrition 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 210000003128 head Anatomy 0.000 abstract description 3
- 231100000957 no side effect Toxicity 0.000 abstract description 2
- VKELSQNRSVJHGR-UHFFFAOYSA-N 4-oxo-4-sulfooxybutanoic acid Chemical compound OC(=O)CCC(=O)OS(O)(=O)=O VKELSQNRSVJHGR-UHFFFAOYSA-N 0.000 abstract 1
- FXALIOUHXMVTMJ-UHFFFAOYSA-N CCCCCCCCCCCC([Na])=O Chemical compound CCCCCCCCCCCC([Na])=O FXALIOUHXMVTMJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 abstract 1
- 108010077895 Sarcosine Proteins 0.000 abstract 1
- 230000036621 balding Effects 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 abstract 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 229940048098 sodium sarcosinate Drugs 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 20
- 210000004209 hair Anatomy 0.000 description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 238000004140 cleaning Methods 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 10
- 201000004384 Alopecia Diseases 0.000 description 9
- 231100000360 alopecia Toxicity 0.000 description 9
- 208000001840 Dandruff Diseases 0.000 description 6
- 238000007599 discharging Methods 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 210000003491 skin Anatomy 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 210000003780 hair follicle Anatomy 0.000 description 4
- 206010061218 Inflammation Diseases 0.000 description 3
- 230000004054 inflammatory process Effects 0.000 description 3
- 206010002198 Anaphylactic reaction Diseases 0.000 description 2
- 230000036783 anaphylactic response Effects 0.000 description 2
- 208000003455 anaphylaxis Diseases 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 229940095673 shampoo product Drugs 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- JHDBMHFWQRTXLV-UHFFFAOYSA-N 1-dodecoxydodecane;2-sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC JHDBMHFWQRTXLV-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 206010040943 Skin Ulcer Diseases 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 239000004288 Sodium dehydroacetate Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 241000863032 Trieres Species 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000003648 hair appearance Effects 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 231100000019 skin ulcer Toxicity 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The invention relates to foaming agent type shampoo which comprises (30 percent) 20 percent to 40 percent of lauryl alcohol polyoxyethylene ether sulpho succinate monoester disodium salt, (30 percent) 20 percent to 40 percent of lauroyl sodium sarcosinate, 0.1 to 0.5 percent of disodium EDTA, 1 to 5 percent of sodium lactate, (40 percent) 1 to 5 percent of polyquat-7, (30 percent) 2 to 5 percent of acrylate copolymer, 1 to 6 percent of PEG-12 dimethyl silicone, 0.1 to 1 percent of aromatic oil or essence, 0.01 to 0.3 percent of citric acid, and 0.04 to 1 percent of preservative agents, and the rest is deionized water. the foaming agent type shampoo is characterized in that foam is squeezed out through a mousse pump head, and the shampoo is not centralized at the top of the head but applied and diffused to other parts, so that the contact of chemical substances and the scalp can be reduced, the probability of furfur, calvities and balding can be reduced, and the effects of economy, environmental friendliness and no side effect can be achieved.
Description
Technical field
The present invention relates to a kind of shampoo, be specifically related to a kind of foaming agent shampoo.
Background technology
Along with improving constantly of people's living standard, almost every day, people used shampoo to clean hair.But current traditional shampoo Shortcomings part:
One, the shampoo of common market sale is used the surfactants such as laureth ammonium sulfate, sodium laureth sulfate, sodium lauryl sulfate, Zetesol AP as first type surface activating agent, these surfactant degreasing powers are strong, zest is large, while rinsing hair, be not easy to rinse well, residual Surfactant accumulates over a long period, surfactant in chemical composition directly contacts with people's scalp for a long time, than being easier to, stimulates the skin on the crown easily to cause following harm:
Skin allergy: allergy is the most common hazard symptoms of shampoo.A series of anaphylaxiss such as scalp is dry, scalp is sent out ancient term for country school, the generation dandruff, redness, raw skin ulcer, inflammation, this type of shampoo of life-time service, causes skin of head to become more and more fragile, more and more responsive, is easy to produce anaphylaxis.
Damage hair follicle, causes alopecia: the acute and chronic stimulation of shampoo can cause the inflammatory reaction of scalp and hair follicle, the of a specified duration place of withering that can cause hair follicle, and hair from the coarse to fine, finally comes off.
Two, tradition shampoo can contact with scalp for a long time, because this mode that is traditional shampoo foaming determines: traditional shampoo be take emulsion form form as main, compare thickness, during use, normally shampoo is extruded into topple over afterwards on hand and is placed in head and massages, shampoo can not foam at once, must handle after soft massage hair or scalp and could produce foam after a period of time, shampoo large area contact with head scalp and the higher time of local concentration longer, while rinsing hair, on scalp, residual shampoo is not easy to rinse well, thereby scalp irritation causes the inflammatory reaction of scalp and hair follicle, accumulate over a long period, the surfactant scalp contact gear ratio directly long-term and people that tradition shampoo moderate stimulation is strong is easier to stimulate the skin on the crown, therefore make to produce dandruff, the probability of alopecia and crown alopecia etc. hair quality problem increases greatly.
Three, improving constantly along with people's living standard; the raw material that shampoo is used whether safety and whether easily degraded be day by day subject to people and pay close attention to and pay attention to; unsafe and difficult degraded surfactant raw material is excreted in natural environment; easily cause environmental pollution; destroy ecological balance, be unfavorable for the protection of environment.
Summary of the invention
The object of this invention is to provide a kind of foaming agent shampoo, can directly extrude and enrich fine and smooth foam by mousse pump head, reduce the time that shampoo contacts with scalp, to reduce contacting of chemical substance and scalp, reach the probability, saving, environmental protection of effective minimizing dandruff, alopecia and crown alopecia, the effect having no side effect.
The present invention adopts following technical scheme to realize foregoing invention object:
A foaming agent shampoo, described foaming agent shampoo comprises following component: polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) 20 ~ 40%, sodium N-lauroyl sarcosinate (30%) 20 ~ 40%, disodiumedetate 0.1 ~ 0.5%, sodium lactate 1 ~ 5%, polyquaternary ammonium salt-7(40%) 1 ~ 5%, acrylate copolymer (30%) 2 ~ 5%, PEG-12 dimethyl siloxane 1 ~ 6%, aromatic oil or essence 0.1 ~ 1%, citric acid 0.01 ~ 0.3%, antiseptic 0.04 ~ 1%, deionized water surplus; Each constituent content is mass percent above, and each constituent mass percent sum is 100%.
Preferably, described foaming agent shampoo comprises following component: polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) 20 ~ 30%, sodium N-lauroyl sarcosinate (30%) 20 ~ 30%, disodiumedetate 0.1 ~ 0.3%, sodium lactate 2 ~ 4%, polyquaternary ammonium salt-7(40%) 1 ~ 3%, acrylate copolymer (30%) 2 ~ 4%, PEG-12 dimethyl siloxane 1 ~ 4%, aromatic oil or essence 0.1 ~ 0.6%, citric acid 0.01 ~ 0.2%, antiseptic 0.04 ~ 0.8%, deionized water surplus;
Each constituent content is mass percent above, and each constituent mass percent sum is 100%.
Preferably, described foaming agent shampoo comprises following component (each constituent content is mass percent): polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) 30%, sodium N-lauroyl sarcosinate (30%) 30%, disodiumedetate 0.3%, sodium lactate 4.0%, polyquaternary ammonium salt-7(40%) 3.0%, acrylate copolymer (30%) 4%, PEG-12 dimethyl siloxane 4%, aromatic oil or essence 0.6%, citric acid 0.2%, antiseptic 0.8%, deionized water to 100%.
Preferably, described foaming agent shampoo comprises following component (each constituent content is mass percent): polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) 25%, sodium N-lauroyl sarcosinate (30%) 25%, disodiumedetate 0.2%, sodium lactate 3%, polyquaternary ammonium salt-7(40%) 2%, acrylate copolymer (30%) 3%, PEG-12 dimethyl siloxane 3%, aromatic oil or essence 0.3%, citric acid 0.1%, antiseptic 0.4%, deionized water to 100%.
Preferably, described foaming agent shampoo comprises following component (each constituent content is mass percent): polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) 20%, sodium N-lauroyl sarcosinate (30%) 20%, disodiumedetate 0.1%, sodium lactate 2.0%, polyquaternary ammonium salt-7(40%) 1%, acrylate copolymer (30%) 2%, PEG-12 dimethyl siloxane 1%, aromatic oil or essence 0.1%, citric acid 0.01%, antiseptic 0.04%, deionized water to 100%
Beneficial effect of the present invention:
1. the present invention can directly use mousse pump head exruded foams, make shampoo bubble to smear again and diffuse to other positions without concentrating on the massage of crown part, reduce the time contacting of high concentration chemical substance and scalp, can reduce the probability of dandruff, alopecia and crown alopecia.
2. the present invention uses easily degraded surfactant of gentle safety, reaches green, energy-saving and environmental protection, realizes the good result of sustainable development with environment.
3. the present invention prepares conveniently, and result of use is good, effectively reduces the time of contact of chemical substance and scalp, can reduce the probability that various scalp problems occur, the effect that play protection scalp, hair healthy is grown.
The specific embodiment
The antiseptic using in the present invention is the general general antiseptic of shampoo, such as Kazon, DMDM Hydantoin, methyl hydroxybenzoate, sodium dehydroacetate, phenoxyethanol etc.
In the present invention, polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) refers to that the solid masses percentage composition of polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt is 30%.Polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt possesses the duplex surface chemical property of anion surfactant and non-ionic surface active agent simultaneously.There is the performances such as good washing, emulsifying, dispersion, moistening, solubilising, and strong, the easy rinsing of foaming power, pH value scope of application broadness, there is good antistatic behaviour, flexibility, very little to the zest of skin,, in surfactant, one of minimum kind of skin irritation is had to comfort, biodegradability is good, be a kind of novel amphoteric surfactant, be applicable to child and be applicable to the formulas such as shampoo, liquid detergent.
Sodium N-lauroyl sarcosinate (30%) refers to that the solid masses percentage composition of sodium N-lauroyl sarcosinate is 30%.Sodium N-lauroyl sarcosinate is a kind of novel amino analog anion surfactants; there is the performances such as good washing, emulsifying, dispersion, moistening, solubilising; superior foaminess; and foam is fine and smooth, lasting; low toxicity, low irritant biological degradability are good; environmentally safe, is particularly useful for the formulas such as shampoo for children, liquid detergent.
Polyquaternary ammonium salt-7(40%) the solid masses percentage composition that refers to polyquaternary ammonium salt-7 is 40%.In shampoo of the present invention, be mainly used as conditioner, can greatly improve modifiability and the conditioning property of hair, after hair washing, can make glossy, the submissive easy comb of hair, make hair there is good wet reason, dry combing and anti-entanglement.
Acrylate copolymer (30%) refers to that solid masses percentage composition is 30% lightly crosslinked acrylate copolymer.Main as thickening stabilizing agent in shampoo of the present invention.
Below in conjunction with embodiment, the present invention is further explained and is illustrated, following examples do not constitute any limitation the present invention.
Embodiment 1
(1) by formula 1, take each raw material:
Table 1 shampoo formula 1
| Component title | Mass percent |
| Polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) | 30% |
| Sodium N-lauroyl sarcosinate (30%) | 30% |
| Disodiumedetate | 0.3% |
| Sodium lactate | 4% |
| Polyquaternary ammonium salt-7(40%) | 3.0% |
| Acrylate copolymer (30%) | 4% |
| PEG-12 dimethyl siloxane | 4% |
| Essence | 0.6% |
| Citric acid | 0.2% |
| Antiseptic | 0.8% |
| Deionized water | To 100% |
(2) first deionized water is divided into two parts, portion accounts for 90% of addition, and portion accounts for addition 10%, the container splendid attire of having sterilized with two cleanings respectively.
(3) 90% deionized water that first portion is accounted for to addition adds the cleaning a mixing bowl of having sterilized, and opens and stirs, and mixing speed is 20 ~ 30 revs/min, adds successively except the raw material of acrylate copolymer (30%), stirs dissolving extremely completely in 20 ~ 30 minutes.
(4) first acrylate copolymer (30%) is added portion to account for addition 10% deionized water for stirring and disperse 5 ~ 8 minutes to being uniformly dispersed, add a mixing bowl, stir 15 ~ 20 minutes to dissolving completely.With 300 mesh filter screens, filter discharging.
Embodiment 2
(1) by formula 2, take each raw material:
Table 2 shampoo formula 2
| Component title | Mass percent |
| Polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) | 30% |
| Sodium N-lauroyl sarcosinate (30%) | 20% |
| Disodiumedetate | 0.25% |
| Sodium lactate | 3.5% |
| Polyquaternary ammonium salt-7(40%) | 2.5% |
| Acrylate copolymer (30%) | 3.5% |
| PEG-12 dimethyl siloxane | 2.5% |
| Quintessence oil | 0.4% |
| Citric acid | 0.15% |
| Antiseptic | 0.6% |
| Deionized water | To 100% |
(2) first deionized water is divided into two parts, portion accounts for 90% of addition, and portion accounts for addition 10%, the container splendid attire of having sterilized with two cleanings respectively.
(3) 90% deionized water that first portion is accounted for to addition adds the cleaning a mixing bowl of having sterilized, and opens and stirs, and mixing speed is 20 ~ 30 revs/min, adds successively except the raw material of acrylate copolymer (30%), stirs dissolving extremely completely in 20 ~ 30 minutes.
(4) first acrylate copolymer (30%) is added portion to account for addition 10% deionized water for stirring and disperse 5 ~ 8 minutes to being uniformly dispersed, add a mixing bowl, stir 15 ~ 20 minutes to dissolving completely.With 300 mesh filter screens, filter discharging.
Embodiment 3
(1) by formula 3, take each raw material:
Table 3 shampoo formula 3
| Component title | Mass percent |
| Polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) | 20% |
| Sodium N-lauroyl sarcosinate (30%) | 30% |
| Disodiumedetate | 0.15% |
| Sodium lactate | 2.5% |
| Polyquaternary ammonium salt-7(40%) | 1.5% |
| Acrylate copolymer (30%) | 2.5% |
| PEG-12 dimethyl siloxane | 2% |
| Herba Rosmarini Officinalis essence | 0.2% |
| Citric acid | 0.05% |
| Antiseptic | 0.3% |
| Deionized water | To 100% |
(2) first deionized water is divided into two parts, portion accounts for 90% of addition, and portion accounts for addition 10%, the container splendid attire of having sterilized with two cleanings respectively.
(3) 90% deionized water that first portion is accounted for to addition adds the cleaning a mixing bowl of having sterilized, and opens and stirs, and mixing speed is 20 ~ 30 revs/min, adds successively except the raw material of acrylate copolymer (30%), stirs dissolving extremely completely in 20 ~ 30 minutes.
(4) first acrylate copolymer (30%) is added portion to account for addition 10% deionized water for stirring and disperse 5 ~ 8 minutes to being uniformly dispersed, add a mixing bowl, stir 15 ~ 20 minutes to dissolving completely.With 300 mesh filter screens, filter discharging.
Embodiment 4
(1) by formula 4, take each raw material:
Table 4 shampoo formula 4
| Component title | Mass percent |
| Polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) | 25% |
| Sodium N-lauroyl sarcosinate (30%) | 25% |
| Disodiumedetate | 0.2% |
| Sodium lactate | 3.0% |
| Polyquaternary ammonium salt-7(40%) | 2.0% |
| Acrylate copolymer (30%) | 3% |
| PEG-12 dimethyl siloxane | 3% |
| Essence | 0.3% |
| Citric acid | 0.1% |
| Antiseptic | 0.4% |
| Deionized water | To 100% |
(2) first deionized water is divided into two parts, portion accounts for 90% of addition, and portion accounts for addition 10%, the container splendid attire of having sterilized with two cleanings respectively.
(3) 90% deionized water that first portion is accounted for to addition adds the cleaning a mixing bowl of having sterilized, and opens and stirs, and mixing speed is 20 ~ 30 revs/min, adds successively except the raw material of acrylate copolymer (30%), stirs dissolving extremely completely in 20 ~ 30 minutes.
(4) first acrylate copolymer (30%) is added portion to account for addition 10% deionized water for stirring and disperse 5 ~ 8 minutes to being uniformly dispersed, add a mixing bowl, stir 15 ~ 20 minutes to dissolving completely.With 300 mesh filter screens, filter discharging.
Embodiment 5
(1) by formula 5, take each raw material:
Table 5 shampoo formula 5
| Component title | Mass percent |
| Polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) | 20% |
| Sodium N-lauroyl sarcosinate (30%) | 20% |
| Disodiumedetate | 0.1% |
| Sodium lactate | 2% |
| Polyquaternary ammonium salt-7(40%) | 1% |
| Acrylate copolymer (30%) | 2% |
| PEG-12 dimethyl siloxane | 1% |
| Aromatic oil or essence | 0.1% |
| Citric acid | 0.01% |
| Antiseptic | 0.04% |
| Deionized water | To 100% |
(2) first deionized water is divided into two parts, portion accounts for 90% of addition, and portion accounts for addition 10%, the container splendid attire of having sterilized with two cleanings respectively.
(3) 90% deionized water that first portion is accounted for to addition adds the cleaning a mixing bowl of having sterilized, and opens and stirs, and mixing speed is 20 ~ 30 revs/min, adds successively except the raw material of acrylate copolymer (30%), stirs dissolving extremely completely in 20 ~ 30 minutes.
(4) first acrylate copolymer (30%) is added portion to account for addition 10% deionized water for stirring and disperse 5 ~ 8 minutes to being uniformly dispersed, add a mixing bowl, stir 15 ~ 20 minutes to dissolving completely.With 300 mesh filter screens, filter discharging.
The sanitary index of the shampoo product of embodiment 1 ~ 5 all meets the requirement in table 6:
Table 6 sanitary index
The sanitary index of the shampoo product of embodiment 1 ~ 5 all meets the requirement in table 7:
Table 7 sense organ, physical and chemical index
Embodiment 1 ~ 5 is carried out to effect test and appraisal test by sensory evaluation method.
Sensory evaluation method is: by embodiment 1 ~ 5, issue respectively 100 testers and contrast use.When tester uses shampoo sample, by above-mentioned method hair washing, every kind of shampoo used two weeks.Tester according to oneself feel mark, standards of grading adopt ten point system, 1 minute the poorest, 10 minutes are best, the higher effect of mark is better, last evaluation result is averaged.Various shampoo result of use evaluation results are listed in table 8.
Shampoo is applied according to the following steps:
1. the foaming agent shampoo above-mentioned preparation being completed, packs band into and presses in mousse pump head bottle, tightens mousse pump head, standby.
2. specifically comprise following step:
(A) water is by hair moistening.
(B) after wet sending out, press mousse pump head and extrude appropriate foam, the foam that makes to have one's hair wash is dispersed on hair, after soft massage, then rinses well with clear water.
(C) on described hair, use the foaming agent shampoo of the embodiment 1 ~ 5 of effective dose, foaming agent shampoo is the use amount on hair at every turn, is calculated by weight to 3.0 ~ 20g, is preferably 3.0 ~ 12g, more preferably 3.0 ~ 8.0g.
These steps can be as required repeatedly, to reach the clean and anti-dandruff effect of looking for.
Table 8 shampoo result of use is evaluated
Hair washing method of the present invention has outstanding result of use as can be seen from Table 8; as can be seen from Table 8 trier to the use of this kind of bubble shampoo after the Comfort Evaluation of scalp higher; without uncomfortable and irritating reaction; that is to say that shampoo of the present invention has good mildness; can effectively protect the skin on the crown, reduce the probability of dandruff, alopecia and crown alopecia.
The announcement of book and instruction according to the above description, those skilled in the art in the invention can also change and revise above-mentioned embodiment.Therefore, the present invention is not limited to the specific embodiment disclosed and described above, to modifications and changes more of the present invention, also should fall in the protection domain of claim of the present invention.In addition,, although used some specific terms in this description, these terms just for convenience of description, do not form any restriction to the present invention.
Claims (5)
1. a foaming agent shampoo, is characterized in that, described foaming agent shampoo comprises following component:
The polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt 20～40% of 30% solid content
The sodium N-lauroyl sarcosinate 20～40% of 30% solid content
Disodiumedetate 0.1～0.5%
Sodium lactate 1～5%
The polyquaternary ammonium salt of 40% solid content-7 1～5%
The acrylate copolymer 2～5% of 30% solid content
PEG-12 dimethyl siloxane 1～6%
Aromatic oil or essence 0.1～1%
Citric acid 0.01～0.3%
Antiseptic 0.04～1%
Deionized water surplus;
Each constituent content is mass percent above, and each constituent mass percent sum is 100%.
2. a kind of foaming agent shampoo according to claim 1, is characterized in that, described foaming agent shampoo comprises following component:
The polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt 20～30% of 30% solid content
The sodium N-lauroyl sarcosinate 20～30% of 30% solid content
Disodiumedetate 0.1～0.3%
Sodium lactate 2～4%
The polyquaternary ammonium salt of 40% solid content-7 1～3%
The acrylate copolymer 2～4% of 30% solid content
PEG-12 dimethyl siloxane 1～4%
Aromatic oil or essence 0.1～0.6%
Citric acid 0.01～0.2%
Antiseptic 0.04～0.8%
Deionized water surplus;
Each constituent content is mass percent above, and each constituent mass percent sum is 100%.
3. a kind of foaming agent shampoo according to claim 1, is characterized in that, described foaming agent shampoo comprises following component (each constituent content is mass percent):
The polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt 30% of 30% solid content
The sodium N-lauroyl sarcosinate 30% of 30% solid content
Disodiumedetate 0.3%
Sodium lactate 4.0%
The polyquaternary ammonium salt of 40% solid content-7 3.0%
The acrylate copolymer 4% of 30% solid content
PEG-12 dimethyl siloxane 4%
Aromatic oil or essence 0.6%
Citric acid 0.2%
Antiseptic 0.8%
Deionized water to 100%.
4. a kind of foaming agent shampoo according to claim 1, is characterized in that, described foaming agent shampoo comprises following component (each constituent content is mass percent):
The polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt 25% of 30% solid content
The sodium N-lauroyl sarcosinate 25% of 30% solid content
Disodiumedetate 0.2%
Sodium lactate 3%
The polyquaternary ammonium salt of 40% solid content-7 2%
The acrylate copolymer 3% of 30% solid content
PEG-12 dimethyl siloxane 3%
Aromatic oil or essence 0.3%
Citric acid 0.1%
Antiseptic 0.4%
Deionized water to 100%.
5. a kind of foaming agent shampoo according to claim 1, is characterized in that, described foaming agent shampoo comprises following component (each constituent content is mass percent):
The polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt 20% of 30% solid content
The sodium N-lauroyl sarcosinate 20% of 30% solid content
Disodiumedetate 0.1%
Sodium lactate 2.0%
The polyquaternary ammonium salt of 40% solid content-7 1%
The acrylate copolymer 2% of 30% solid content
PEG-12 dimethyl siloxane 1%
Aromatic oil or essence 0.1%
Citric acid 0.01%
Antiseptic 0.04%
Deionized water to 100%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210195508.2A CN102697670B (en) | 2012-06-13 | 2012-06-13 | Foaming agent type shampoo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210195508.2A CN102697670B (en) | 2012-06-13 | 2012-06-13 | Foaming agent type shampoo |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102697670A CN102697670A (en) | 2012-10-03 |
| CN102697670B true CN102697670B (en) | 2014-07-30 |
Family
ID=46890924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210195508.2A Active CN102697670B (en) | 2012-06-13 | 2012-06-13 | Foaming agent type shampoo |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102697670B (en) |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9949914B2 (en) | 2015-04-23 | 2018-04-24 | The Procter & Gamble Company | Low viscosity hair care composition |
| US9949901B2 (en) | 2015-04-23 | 2018-04-24 | The Procter & Gamble Company | Low viscosity hair care composition |
| US10311575B2 (en) | 2016-03-23 | 2019-06-04 | The Procter And Gamble Company | Imaging method for determining stray fibers |
| US10426713B2 (en) | 2017-10-10 | 2019-10-01 | The Procter And Gamble Company | Method of treating hair or skin with a personal care composition in a foam form |
| US10441519B2 (en) | 2016-10-21 | 2019-10-15 | The Procter And Gamble Company | Low viscosity hair care composition comprising a branched anionic/linear anionic surfactant mixture |
| US10653590B2 (en) | 2016-10-21 | 2020-05-19 | The Procter And Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits comprising an anionic/zwitterionic surfactant mixture |
| US10799434B2 (en) | 2016-10-21 | 2020-10-13 | The Procter & Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits |
| US10842720B2 (en) | 2016-10-21 | 2020-11-24 | The Procter And Gamble Company | Dosage of foam comprising an anionic/zwitterionic surfactant mixture |
| US10888505B2 (en) | 2016-10-21 | 2021-01-12 | The Procter And Gamble Company | Dosage of foam for delivering consumer desired dosage volume, surfactant amount, and scalp health agent amount in an optimal formulation space |
| US10912732B2 (en) | 2017-12-20 | 2021-02-09 | The Procter And Gamble Company | Clear shampoo composition containing silicone polymers |
| US11116704B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition |
| US11116705B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition containing sulfate-free surfactants |
| US11116703B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition containing sulfate-free surfactants |
| US11129783B2 (en) | 2016-10-21 | 2021-09-28 | The Procter And Gamble Plaza | Stable compact shampoo products with low viscosity and viscosity reducing agent |
| US11141370B2 (en) | 2017-06-06 | 2021-10-12 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer mixture and providing improved in-use wet feel |
| US11154467B2 (en) | 2016-10-21 | 2021-10-26 | The Procter And Gamble Plaza | Concentrated shampoo dosage of foam designating hair conditioning benefits |
| US11224567B2 (en) | 2017-06-06 | 2022-01-18 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer/silicone mixture providing improved in-use wet feel |
| US11291616B2 (en) | 2015-04-23 | 2022-04-05 | The Procter And Gamble Company | Delivery of surfactant soluble anti-dandruff agent |
| US11318073B2 (en) | 2018-06-29 | 2022-05-03 | The Procter And Gamble Company | Low surfactant aerosol antidandruff composition |
| US11446217B2 (en) | 2016-03-03 | 2022-09-20 | The Procter & Gamble Company | Aerosol antidandruff composition |
| US11679073B2 (en) | 2017-06-06 | 2023-06-20 | The Procter & Gamble Company | Hair compositions providing improved in-use wet feel |
| US11771635B2 (en) | 2021-05-14 | 2023-10-03 | The Procter & Gamble Company | Shampoo composition |
| US11819474B2 (en) | 2020-12-04 | 2023-11-21 | The Procter & Gamble Company | Hair care compositions comprising malodor reduction materials |
| US12226505B2 (en) | 2018-10-25 | 2025-02-18 | The Procter & Gamble Company | Compositions having enhanced deposition of surfactant-soluble anti-dandruff agents |
| US12427099B2 (en) | 2020-11-23 | 2025-09-30 | The Procter & Gamble Company | Personal care composition |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103705416B (en) * | 2013-12-19 | 2015-11-04 | 郑维雄 | A kind of shaving cream |
| CN107281074A (en) * | 2016-04-08 | 2017-10-24 | 广州植翠元生物科技有限公司 | A kind of pair of branch type shampoo pattern |
| WO2018075847A1 (en) | 2016-10-21 | 2018-04-26 | The Procter & Gamble Company | Concentrated shampoo dosage of foam designating hair volume benefits |
| US11980679B2 (en) | 2019-12-06 | 2024-05-14 | The Procter & Gamble Company | Sulfate free composition with enhanced deposition of scalp active |
| JP7481470B2 (en) | 2020-02-27 | 2024-05-10 | ザ プロクター アンド ギャンブル カンパニー | Sulfur-containing anti-dandruff compositions with enhanced efficacy and aesthetics |
| US11986543B2 (en) | 2021-06-01 | 2024-05-21 | The Procter & Gamble Company | Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1169674A (en) * | 1994-08-24 | 1998-01-07 | 普罗克特和甘保尔公司 | Mild shower gel composition comprising fatty alcohol which imparts improved lathering and thickening properties |
-
2012
- 2012-06-13 CN CN201210195508.2A patent/CN102697670B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1169674A (en) * | 1994-08-24 | 1998-01-07 | 普罗克特和甘保尔公司 | Mild shower gel composition comprising fatty alcohol which imparts improved lathering and thickening properties |
Non-Patent Citations (1)
| Title |
|---|
| 毛培坤.磺基琥珀酸酯香波Ⅰ.《实用发用化妆品配方集》.化学工业出版社,2006,第40页. * |
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9949914B2 (en) | 2015-04-23 | 2018-04-24 | The Procter & Gamble Company | Low viscosity hair care composition |
| US9949901B2 (en) | 2015-04-23 | 2018-04-24 | The Procter & Gamble Company | Low viscosity hair care composition |
| US11291616B2 (en) | 2015-04-23 | 2022-04-05 | The Procter And Gamble Company | Delivery of surfactant soluble anti-dandruff agent |
| US11446217B2 (en) | 2016-03-03 | 2022-09-20 | The Procter & Gamble Company | Aerosol antidandruff composition |
| US10311575B2 (en) | 2016-03-23 | 2019-06-04 | The Procter And Gamble Company | Imaging method for determining stray fibers |
| US10842720B2 (en) | 2016-10-21 | 2020-11-24 | The Procter And Gamble Company | Dosage of foam comprising an anionic/zwitterionic surfactant mixture |
| US11154467B2 (en) | 2016-10-21 | 2021-10-26 | The Procter And Gamble Plaza | Concentrated shampoo dosage of foam designating hair conditioning benefits |
| US10653590B2 (en) | 2016-10-21 | 2020-05-19 | The Procter And Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits comprising an anionic/zwitterionic surfactant mixture |
| US10888505B2 (en) | 2016-10-21 | 2021-01-12 | The Procter And Gamble Company | Dosage of foam for delivering consumer desired dosage volume, surfactant amount, and scalp health agent amount in an optimal formulation space |
| US10441519B2 (en) | 2016-10-21 | 2019-10-15 | The Procter And Gamble Company | Low viscosity hair care composition comprising a branched anionic/linear anionic surfactant mixture |
| US10799434B2 (en) | 2016-10-21 | 2020-10-13 | The Procter & Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits |
| US11129783B2 (en) | 2016-10-21 | 2021-09-28 | The Procter And Gamble Plaza | Stable compact shampoo products with low viscosity and viscosity reducing agent |
| US11202740B2 (en) | 2016-10-21 | 2021-12-21 | The Procter And Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits |
| US11679073B2 (en) | 2017-06-06 | 2023-06-20 | The Procter & Gamble Company | Hair compositions providing improved in-use wet feel |
| US11224567B2 (en) | 2017-06-06 | 2022-01-18 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer/silicone mixture providing improved in-use wet feel |
| US11141370B2 (en) | 2017-06-06 | 2021-10-12 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer mixture and providing improved in-use wet feel |
| US11116705B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition containing sulfate-free surfactants |
| US11129775B2 (en) | 2017-10-10 | 2021-09-28 | The Procter And Gamble Company | Method of treating hair or skin with a personal care composition in a foam form |
| US11116703B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition containing sulfate-free surfactants |
| US11116704B2 (en) | 2017-10-10 | 2021-09-14 | The Procter And Gamble Company | Compact shampoo composition |
| US10426713B2 (en) | 2017-10-10 | 2019-10-01 | The Procter And Gamble Company | Method of treating hair or skin with a personal care composition in a foam form |
| US11607373B2 (en) | 2017-10-10 | 2023-03-21 | The Procter & Gamble Company | Sulfate free clear personal cleansing composition comprising low inorganic salt |
| US10912732B2 (en) | 2017-12-20 | 2021-02-09 | The Procter And Gamble Company | Clear shampoo composition containing silicone polymers |
| US11318073B2 (en) | 2018-06-29 | 2022-05-03 | The Procter And Gamble Company | Low surfactant aerosol antidandruff composition |
| US12226505B2 (en) | 2018-10-25 | 2025-02-18 | The Procter & Gamble Company | Compositions having enhanced deposition of surfactant-soluble anti-dandruff agents |
| US12427099B2 (en) | 2020-11-23 | 2025-09-30 | The Procter & Gamble Company | Personal care composition |
| US11819474B2 (en) | 2020-12-04 | 2023-11-21 | The Procter & Gamble Company | Hair care compositions comprising malodor reduction materials |
| US11771635B2 (en) | 2021-05-14 | 2023-10-03 | The Procter & Gamble Company | Shampoo composition |
| US12409125B2 (en) | 2021-05-14 | 2025-09-09 | The Procter & Gamble Company | Shampoo compositions containing a sulfate-free surfactant system and sclerotium gum thickener |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102697670A (en) | 2012-10-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102697670B (en) | Foaming agent type shampoo | |
| CN102697668B (en) | Hair washing method of foaming agent type shampoo | |
| CN106038330B (en) | A kind of mildy wash and preparation method thereof | |
| CN102716044B (en) | Low-stimulation hair-cleaning compound | |
| CN103520053B (en) | Hair and body bathing powder | |
| CN103251523A (en) | Oil-control shampoo composite | |
| CN106137906A (en) | A kind of plant essence Face-protecting mask essence | |
| CN107998028A (en) | A kind of shower cream and preparation method thereof | |
| CN111265439A (en) | Oil-control, dandruff-removing and itching-relieving shampoo and preparation method thereof | |
| CN107595735A (en) | A kind of amino acid cleansing breast containing folium artemisiae argyi and preparation method thereof | |
| CN107982135A (en) | A kind of shampoo and preparation method thereof | |
| CN109568187B (en) | Multi-effect nursing bath foam for pet dogs and preparation method thereof | |
| CN105616292B (en) | Tea Saponin shampoo containing Chinese medical extract and preparation method thereof | |
| CN108815054B (en) | Bath lotion and preparation method thereof | |
| CN114344225A (en) | Silicon-free hair cleansing cream with oil control effect and preparation method thereof | |
| CN115414272B (en) | Female bubble shampoo without irritation in eyes and preparation method thereof | |
| CN104434698A (en) | Anti-static and anti-radiation shampoo paste and preparation method thereof | |
| CN113081889A (en) | Three-stage washing and protecting integrated composition | |
| CN109966166A (en) | Healthy and safe effective amino acid cleansing product of one kind and preparation method thereof | |
| CN103976940B (en) | A kind of gentle facial cleansing foam that can be used for wound skin | |
| CN115192476B (en) | Non-irritating shampoo bath lotion and preparation method thereof | |
| CN115887256A (en) | Application of batyl alcohol in hair washing and caring products and hair washing and caring products containing batyl alcohol | |
| CN114366693A (en) | Shampoo shower gel for infants and children | |
| CN107411993A (en) | A kind of shower cream and preparation method thereof | |
| CN108553384B (en) | Hair-care shampoo |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |