CN102746706B - Preparation method and application of Korepine bark natural dye - Google Patents
Preparation method and application of Korepine bark natural dye Download PDFInfo
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- CN102746706B CN102746706B CN2012102680477A CN201210268047A CN102746706B CN 102746706 B CN102746706 B CN 102746706B CN 2012102680477 A CN2012102680477 A CN 2012102680477A CN 201210268047 A CN201210268047 A CN 201210268047A CN 102746706 B CN102746706 B CN 102746706B
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- korean pine
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- pine bark
- natural dyestuff
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- 238000002360 preparation method Methods 0.000 title abstract description 9
- 229930182559 Natural dye Natural products 0.000 title abstract 5
- 239000000978 natural dye Substances 0.000 title abstract 5
- 239000010985 leather Substances 0.000 claims abstract description 49
- 240000007263 Pinus koraiensis Species 0.000 claims abstract description 47
- 235000011615 Pinus koraiensis Nutrition 0.000 claims abstract description 47
- 238000000034 method Methods 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 7
- 238000001914 filtration Methods 0.000 claims abstract description 7
- 239000000975 dye Substances 0.000 claims description 55
- 241000896103 Pinus sibirica Species 0.000 claims description 6
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 238000010186 staining Methods 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 abstract description 9
- 208000031320 Teratogenesis Diseases 0.000 abstract description 2
- 230000000711 cancerogenic effect Effects 0.000 abstract description 2
- 206010002198 Anaphylactic reaction Diseases 0.000 abstract 1
- 230000036783 anaphylactic response Effects 0.000 abstract 1
- 208000003455 anaphylaxis Diseases 0.000 abstract 1
- 238000010411 cooking Methods 0.000 abstract 1
- 230000001795 light effect Effects 0.000 abstract 1
- 239000000284 extract Substances 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 206010052428 Wound Diseases 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
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- 241000238631 Hexapoda Species 0.000 description 1
- 235000001018 Hibiscus sabdariffa Nutrition 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 244000208060 Lawsonia inermis Species 0.000 description 1
- 235000008582 Pinus sylvestris Nutrition 0.000 description 1
- 235000005291 Rumex acetosa Nutrition 0.000 description 1
- 240000007001 Rumex acetosella Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 208000030961 allergic reaction Diseases 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001741 anti-phlogistic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
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- 239000003205 fragrance Substances 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000001839 pinus sylvestris Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
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- 235000003513 sheep sorrel Nutrition 0.000 description 1
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- 239000004753 textile Substances 0.000 description 1
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Landscapes
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Coloring (AREA)
Abstract
The invention relates to a preparation method and application of Korean pine bark natural dye. The method comprises the steps of: chopping Korean pine bark into small blocks, placing in an enamel pan, adding water, cooking with mild fire to obtain redbrown liquid, filtering the liquid to obtain the Korean pine bark natural dye. Research trial shows that the Korean pine bark natural dye obtained by the method has excellent dyeing performance on leather, different dark and light effects can be obtained by different dyeing times, the color fastness is excellent, the dyed leather is mellow is color, safe to wear, good in ecological environment compatibility and biodegradable, and does not cause carcinogenic action and teratogenesis or anaphylaxis; and furthermore, by utilizing Korean pine bark to prepare the natural dye, the price is low, natural resources are sufficiently utilized, and the market prospect is fully wide.
Description
Technical field
The present invention relates to the natural dyestuff field, particularly a kind of preparation method of Korean pine bark natural dyestuff, and to the dyeing purposes of leather.
Background technology
Natural dyestuff refers to flower from plant, really, extract leaf, bark, root, stem or animal secretions, mineral substance, nontoxic, in preparation process, can not cause environmental pollution, and have biodegradability and Environmental compatibility preferably.The part natural dyestuff, except dyeing, also have special fragrance and certain nutrition and medicine healthy sofa function.Approximately B.C. 1500 businessman of ancient Egypt just utilize natural extract and grape wine to improve the color and luster of candy, and Jia Si Important Arts for the People's Welfare that peaceful is shown were also mentioned specially ancient times and used as dyestuff from plant, extracting pigment the last years of a dynasty or reign in the Northern Song Dynasty.Ancient kazakh also utilizes the fur of animal to make dress ornament and uses in nomadism, the surface of leather adopts vegetable dye to dye, and the dress ornament of dyeing is attractive in appearance, and prevents that the willing of insect from eating.In modern society people Environmental awareness, constantly strengthen and advocate under the tide of green consumption, natural dyestuff is at high-grade leatherware, real silk dress ornament, health-care underclothes, home textile product, and adornment field has a wide range of applications.
Leaf of Siberian Stone Pine (Pinus sylvestris Loud.Mayr) also cry the Altay Korean pine, in China, originates in the northwestward, In The North of Xinjiang Altai Mountains, up to 35M, diameter of a cross-section of a tree trunk 1.3 meters above the ground 1.8M, bark beige or sorrel, material is better, can keep mountain region water and soil, be important germ plasm resource.Medicinal and the dyeing of Cortex Pini is historical can trace back to the approximately Hippcrates of B.C. 400 years ancient Greek, until Middle Ages, Cortex Pini is all regarded as the good medicine for the treatment of wound by the European.And in China, Cortex Pini, also as commonly using a kind of of herbal medicine, is usually used in the treatment of wound, has the bactericidal antiphlogistic effect.
At present, for the research of Cortex Pini, only on a small quantity be used to adopting resin and turps extraction aspect, about the preparation method of Cortex Pini natural dyestuff and in the research of leather coloring technique, have no report both at home and abroad.
Summary of the invention
The object of the invention is, a kind of Preparation method and use of Korean pine bark natural dyestuff is provided, the method is that the bark of Korean pine is cut into to fritter, put in enamel kiln and add water and boil with warm fire, obtain brown liquid, then liquid filtering can be obtained to the Cortex Pini natural dyestuff, test shows after deliberation: the Cortex Pini natural dyestuff obtained by the method for the invention has good dyeing behavior to leather, by the difference of dyeing number of times, can obtain the effect that the depth is different, and colour fastness is good.
The preparation method of a kind of Korean pine bark natural dyestuff of the present invention follows these steps to carry out:
A, selection self-sow, ripe, trunk is high 1-1.5 rice overhead, the leaf of Siberian Stone Pine of bark thickness showed 10-15 centimetre, remove after crust the fritter of cutting growth 5-6 centimetre, thick 1-2 centimetre, adopt decocting method that the Cortex Pini of cutting is put in enamel kiln, add water, with warm fire, boil 2-3 hour, obtain brown liquid;
B, by step a liquid filtering, can obtain 0.5-0.6 and rise concentrated Korean pine bark natural dyestuff.
The volume ratio of the described Korean pine bark of step a and water is 1-3:10-30.
The purposes of the Korean pine bark natural dyestuff that described method obtains, this Korean pine bark natural dyestuff is preparing the staining agent of leather.
The Preparation method and use of a kind of Korean pine bark natural dyestuff of the present invention, adopt decocting method from the Korean pine skin, extracting the red-brown natural dyestuff, extraction process is simple, and extracts active ingredients efficiency is apparently higher than other methods such as ethanol refluxing processes, and leaching process can not cause environmental pollution; Extract is good to the protein fibre dyefastness; After dyeing, the leather color and luster is soft, wears safety, does not have carcinogenic, teratogenesis or causes allergic reaction; Good, biodegradable with the ecotope consistency; And utilize the standby natural dyestuff low price of Korean pine leather, and taking full advantage of natural resource, market outlook are very wide.
Embodiment:
Embodiment 1:
A, selection self-sow, ripe, trunk is overhead high 1 meter, the leaf of Siberian Stone Pine that bark thickness showed is 10 centimeters, cut lower bark from trunk, removes after crust and cut the fritter of 5 centimeters, thick 1 centimeter of growing up, adopt decocting method that 1 kilogram of the Cortex Pini cut is put in enamel kiln, add 10 kilograms, water, boil 2-3 hour with warm fire, obtain brown liquid;
B, by step a liquid filtering, can obtain 0.5-0.6 and rise concentrated Korean pine skin natural dyestuff;
The Korean pine skin natural dyestuff obtained by the method is preparing the purposes of Colourate for leather, and concrete operations are:
Ripe good leather is smooth is placed on shady and cool smooth place, then Korean pine skin natural dyestuff is coated in uniformly on leather 3 times, 3-6 hour dries in the shade, leather ninety percent dry the time hang on plank the unnecessary Korean pine skin natural dyestuff with blunt knife extension peeling leather surface gently after, dye for the second time, Korean pine skin natural dyestuff is coated on leather 3 times uniformly, dried in the shade 3-6 hour, leather ninety percent hangs in the time of dry on plank with after the surperficial unnecessary Korean pine skin natural dyestuff of blunt knife extension peeling leather gently, dye for the third time again, Korean pine skin natural dyestuff is coated on leather 3 times uniformly, dried in the shade 3-6 hour, dyestuff ninety percent on leather hangs in the time of dry on plank with the blunt knife surperficial unnecessary Korean pine skin natural dyestuff of extension peeling leather gently, obtain henna leather, finally leather is rubbed and got final product fully according to a conventional method.
Embodiment 2:
A, selection self-sow, ripe, trunk is overhead high 1.2 meters, the leaf of Siberian Stone Pine that bark thickness showed is 12 centimeters, cut lower bark from trunk, removes after crust and cut the fritter of 6 centimeters, thick 2 centimeters of growing up, adopt decocting method that 2 kilograms of the Cortex Pinis cut are put in enamel kiln, add 20 kilograms, water, boiled 4 hours with warm fire, obtain brown liquid;
B, by step a liquid filtering, can obtain 1-1.1 and rise concentrated Korean pine skin natural dyestuff;
The Korean pine skin natural dyestuff obtained by the method is preparing the purposes of Colourate for leather, and concrete operations are:
Ripe good leather is smooth is placed on shady and cool smooth place, then Korean pine skin natural dyestuff is coated in uniformly on leather 2 times, 2-5 hour dries in the shade, leather ninety percent hangs in the time of dry on plank with after the surperficial unnecessary Korean pine skin natural dyestuff of blunt knife extension peeling leather gently, dye for the second time, Korean pine skin natural dyestuff is coated on leather 2 times uniformly, 2-5 hour dries in the shade, leather ninety percent hangs in the time of dry on plank with after the surperficial unnecessary Korean pine skin natural dyestuff of blunt knife extension peeling leather gently, dye for the third time again, Korean pine skin natural dyestuff is coated on leather 2 times uniformly, 2-5 hour dries in the shade, dyestuff ninety percent on leather hangs in the time of dry on plank with the blunt knife unnecessary Korean pine skin natural dyestuff that scrapes off leather surface gently, obtain the leather of light brown red, finally leather is rubbed and got final product fully according to a conventional method.
Embodiment 3
A, selection self-sow, ripe, trunk is overhead high 1.5 meters, the leaf of Siberian Stone Pine that bark thickness showed is 15 centimeters, cut lower bark from trunk, removes after crust the fritter of cutting growth 5-6 centimetre, thick 1-2 centimetre, adopt decocting method that 3 kilograms of the Cortex Pinis cut are put in enamel kiln, add 30 kilograms, water, boil 4-5 hour with warm fire, obtain brown liquid;
B, by step a liquid filtering, can obtain 1.5-1.6 and rise concentrated Korean pine skin natural dyestuff;
The Korean pine skin natural dyestuff obtained by the method is preparing the purposes of Colourate for leather, and concrete operations are:
Ripe good leather is smooth is placed on shady and cool smooth place, then Korean pine skin natural dyestuff is coated in uniformly on leather 1 time, 2-3 hour dries in the shade, leather ninety percent hangs in the time of dry on plank with after the surperficial unnecessary Korean pine skin natural dyestuff of blunt knife extension peeling leather gently, dye for the second time, Korean pine skin natural dyestuff is coated on leather 1 time uniformly, 2-3 hour dries in the shade, leather ninety percent hangs in the time of dry on plank with after the surperficial unnecessary Korean pine skin natural dyestuff of blunt knife extension peeling leather gently, dye for the third time, Korean pine skin natural dyestuff is coated on leather 1 time uniformly, 2-3 hour dries in the shade, dyestuff ninety percent on leather hangs in the time of dry on plank with the blunt knife unnecessary Korean pine skin natural dyestuff that scrapes off leather surface gently, obtain the leather of light brown red, finally leather is rubbed and got final product fully according to a conventional method.
Claims (1)
1. a Korean pine bark natural dyestuff, in the purposes of the staining agent for preparing leather, is characterized in that following these steps to carrying out:
A, selection self-sow, ripe, trunk is height 1-1.5 rice overhead, the Korean pine of bark thickness showed 10-15 centimetre, from trunk, cut lower bark, cut growth 5-6 centimetre, the fritter of thick 1-2 centimetre after removing crust, adopt decocting method that the Cortex Pini of cutting is put in enamel kiln, add water, boil 2-3 hour with warm fire, obtain brown liquid, wherein Korean pine is leaf of Siberian Stone Pine, and the volume ratio of Korean pine bark and water is 1-3:10-30;
B, by step a liquid filtering, can obtain 0.5-0.6 and rise concentrated Korean pine skin natural dyestuff.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102680477A CN102746706B (en) | 2012-07-31 | 2012-07-31 | Preparation method and application of Korepine bark natural dye |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102680477A CN102746706B (en) | 2012-07-31 | 2012-07-31 | Preparation method and application of Korepine bark natural dye |
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| Publication Number | Publication Date |
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| CN102746706A CN102746706A (en) | 2012-10-24 |
| CN102746706B true CN102746706B (en) | 2013-11-27 |
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| CN2012102680477A Expired - Fee Related CN102746706B (en) | 2012-07-31 | 2012-07-31 | Preparation method and application of Korepine bark natural dye |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044956B (en) * | 2012-12-14 | 2014-03-12 | 北京林业大学 | Method for extracting natural haematochrome from larch bark |
| CN103334318B (en) * | 2013-07-24 | 2014-10-22 | 刘代玉 | Plant dyeing method |
| CN107523092A (en) * | 2017-09-05 | 2017-12-29 | 夏战利 | A kind of preparation method of Korean pine bark natural dye |
| CN112252056A (en) * | 2020-10-22 | 2021-01-22 | 安顺市西秀区星月苗族蜡染工艺品有限公司 | Wax printing color fixing method for vegetable natural dye |
| CN112251045A (en) * | 2020-11-16 | 2021-01-22 | 海南省林业项目管理办公室 | A kind of cabbage cone bark dye and preparation method and use thereof |
| CN117106990A (en) * | 2023-09-05 | 2023-11-24 | 浙江富邦汽车内饰科技有限公司 | Method for processing leather based on plant-based chemicals |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB126742A (en) * | 1917-08-01 | 1919-05-22 | Robert Harbottle | New Vegetable Dyes. |
| CN1176919C (en) * | 2003-03-07 | 2004-11-24 | 桂林莱茵生物制品有限公司 | Separation and extraction process of oligomer proanthocyanidin from pine bark |
| CN1303165C (en) * | 2004-01-12 | 2007-03-07 | 四川大学 | Extraction and separation of proto flower haematochrome and preparation method of its derivatives |
| DE102006000645A1 (en) * | 2006-01-03 | 2007-07-12 | Degussa Gmbh | Universal pigment preparations |
| CN101759727B (en) * | 2009-09-30 | 2013-03-27 | 钱娟 | Nano-scale pine bark extract and preparation method thereof |
| CN102321383B (en) * | 2011-06-15 | 2013-12-04 | 华南农业大学 | Preparation method for vegetable tannin dye liquor and application thereof in dyeing aspect of real silk fabric |
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