CN102799076B - A kind of exposure method for non-planar substrates and exposure device - Google Patents
A kind of exposure method for non-planar substrates and exposure device Download PDFInfo
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Abstract
本发明公开了一种用于非平面基材的曝光方法,其包括:提供非平面基材;用感光抗蚀剂覆盖非平面基材中非平面的至少一部分;使用立体曝光方法对非平面基材中非平面的至少一部分的感光抗蚀剂进行曝光。本发明还公开了一种用于非平面基材的曝光装置。本发明的用于非平面基材的曝光方法及曝光装置通过在非平面基材的每一部分表面覆盖感光抗蚀剂,再使用立体曝光方法进行曝光,能够适应于大尺寸的非平面基材。
The invention discloses an exposure method for a non-planar substrate, which comprises: providing a non-planar substrate; covering at least a part of the non-planar substrate in the non-planar substrate with a photosensitive resist; exposing the photoresist to at least a portion of the non-planar material. The invention also discloses an exposure device for non-planar substrates. The exposure method and exposure device for non-planar substrates of the present invention can be adapted to large-size non-planar substrates by covering the surface of each part of the non-planar substrate with photosensitive resist and then using a stereoscopic exposure method for exposure.
Description
技术领域 technical field
本发明涉及图形曝光技术领域,特别是涉及一种用于非平面基材的曝光方法及曝光装置。The invention relates to the technical field of graphic exposure, in particular to an exposure method and an exposure device for non-planar substrates.
背景技术 Background technique
对于在非平面基板表面制作线路图形,现有技术一般采用激光表面改性技术以及电镀工艺来实现。激光表面改性技术由于其大幅度提高了基材表面的硬度、耐磨性等,并且能够控制成本,目前得到广泛应用。电镀工艺由于工艺成熟,目前应用也较为广泛。For making circuit patterns on the surface of non-planar substrates, the prior art generally adopts laser surface modification technology and electroplating technology to realize. Laser surface modification technology is currently widely used because it greatly improves the hardness and wear resistance of the substrate surface, and can control costs. Due to the mature technology, the electroplating process is widely used at present.
但是,由于激光表面改性技术存在激光束小,导致其处理面小,因此不适应于大尺寸的非平面基材;电镀工艺采用的电镀槽是根据需要电镀的非平面基材设计的,若非平面基材的尺寸过大,则电镀槽的尺寸必须相应增大,导致电镀过程中的控制精度降低。因此电镀工艺也不适应于大尺寸的非平面基材。However, due to the small laser beam in the laser surface modification technology, the treatment surface is small, so it is not suitable for large-sized non-planar substrates; the electroplating tank used in the electroplating process is designed according to the non-planar substrates that need to be electroplated. If the size of the planar substrate is too large, the size of the electroplating tank must be increased accordingly, resulting in a decrease in control accuracy during the electroplating process. Therefore, the electroplating process is not suitable for large-sized non-planar substrates.
发明内容 Contents of the invention
本发明主要解决的技术问题是提供一种用于非平面基材的曝光方法及曝光装置,能够适应于大尺寸的非平面基材。The technical problem mainly solved by the present invention is to provide an exposure method and an exposure device for non-planar substrates, which can be adapted to large-sized non-planar substrates.
为解决上述技术问题,本发明提供了一种用于非平面基材的曝光方法,其包括:提供非平面基材;用感光抗蚀剂覆盖非平面基材中非平面的至少一部分;使用立体曝光方法对非平面基材中非平面的至少一部分的感光抗蚀剂进行曝光。In order to solve the above technical problems, the present invention provides an exposure method for non-planar substrates, which includes: providing a non-planar substrate; covering at least a part of the non-planar substrate in the non-planar substrate with a photoresist; using a three-dimensional The exposure method exposes at least a portion of the photoresist that is non-planar in the non-planar substrate.
其中,使用立体曝光方法对非平面基材中非平面的至少一部分的感光抗蚀剂进行曝光的步骤具体为:在非平面基材中非平面的每一部分均相对设置一光源,使得多个光源相对非平面基材呈立体分布;在每一光源和非平面基材中非平面的每一部分之间设置图形转移工具;利用光源照射图形转移工具,从图形转移工具透射的光线使得感光抗蚀剂发生反应,从而使得图形转移工具上的图形转移至非平面基材。Wherein, the step of exposing at least a part of the non-planar photoresist in the non-planar substrate using a stereoscopic exposure method is specifically: a light source is arranged opposite to each part of the non-planar substrate in the non-planar substrate, so that the plurality of light sources The non-planar substrate is three-dimensionally distributed; a graphic transfer tool is set between each light source and each part of the non-planar substrate; the graphic transfer tool is irradiated by the light source, and the light transmitted from the graphic transfer tool makes the photosensitive resist A reaction occurs that transfers the graphic on the graphic transfer tool to the non-planar substrate.
其中,用感光抗蚀剂覆盖非平面基材中非平面的至少一部分的步骤包括:将非平面基材浸入感光抗蚀剂中并取出,使得感光抗蚀剂覆盖非平面基材中非平面的至少一部分。Wherein, the step of covering at least a part of the non-planar part of the non-planar substrate with the photoresist comprises: immersing the non-planar substrate in the photoresist and taking it out, so that the photoresist covers the non-planar part of the non-planar substrate at least partly.
其中,感光抗蚀剂为树脂型光感材料。Wherein, the photosensitive resist is a resin type photosensitive material.
其中,非平面基材为超材料非平面基材。Wherein, the non-planar substrate is a metamaterial non-planar substrate.
为解决上述技术问题,本发明还提供了一种曝光装置,其包括:承载部,用于承载非平面基材,非平面基材中非平面的至少一部分覆盖有感光抗蚀剂;至少一光源,相对承载部设置;图形转移工具,设置于光源与非平面基材之间的光路之中;其中,至少一光源和图形转移工具使用立体曝光方法对非平面基材中非平面的至少一部分的感光抗蚀剂进行曝光。In order to solve the above-mentioned technical problems, the present invention also provides an exposure device, which includes: a carrying part for carrying a non-planar substrate, at least a part of the non-planar substrate in the non-planar substrate is covered with a photosensitive resist; at least one light source , arranged relative to the bearing part; the pattern transfer tool is arranged in the optical path between the light source and the non-planar substrate; wherein, at least one light source and the pattern transfer tool use a stereoscopic exposure method to at least a part of the non-planar substrate in the non-planar substrate The photoresist is exposed.
其中,装置包括:溶液槽,用于盛载感光抗蚀剂;操作机构,用于将非平面基材浸入感光抗蚀剂中并取出,使得非平面基材中非平面的至少一部分覆盖有感光抗蚀剂,再将非平面基材置入承载部。Wherein, the device includes: a solution tank, used to hold the photosensitive resist; an operating mechanism, used to immerse the non-planar substrate in the photosensitive resist and take it out, so that at least a part of the non-planar surface of the non-planar substrate is covered with photosensitive resist. resist, and then place the non-planar substrate into the carrier.
其中,光源为多个,多个光源相对承载部呈立体分布,以使非平面基材中非平面的每一部分均相对设置有一光源。Wherein, there are multiple light sources, and the multiple light sources are three-dimensionally distributed relative to the bearing part, so that each non-planar part of the non-planar base material is relatively provided with a light source.
其中,感光抗蚀剂为树脂型光感材料。Wherein, the photosensitive resist is a resin type photosensitive material.
其中,非平面基材为超材料非平面基材。Wherein, the non-planar substrate is a metamaterial non-planar substrate.
本发明的用于非平面基材的曝光方法及曝光装置通过在非平面基材中非平面的至少一部分覆盖感光抗蚀剂,再使用立体曝光方法对感光抗蚀剂进行曝光,光照范围足够大,光照强度及光照时间容易控制,适应于对大尺寸的非平面基材的曝光处理。The exposure method and exposure device for non-planar substrates of the present invention cover at least a part of the non-planar substrate with a photosensitive resist, and then use a stereoscopic exposure method to expose the photosensitive resist, and the illumination range is large enough , light intensity and light time are easy to control, and are suitable for exposure treatment of large-size non-planar substrates.
附图说明 Description of drawings
图1是本发明曝光方法一实施方式的流程图;Fig. 1 is a flowchart of an embodiment of the exposure method of the present invention;
图2是图1所示的曝光方法的具体流程图;Fig. 2 is the specific flowchart of the exposure method shown in Fig. 1;
图3是本发明曝光装置一实施方式的俯视示意图。FIG. 3 is a schematic top view of an embodiment of the exposure device of the present invention.
具体实施方式 detailed description
下面将结合本发明实施方式中的附图,对本发明实施方式中的技术方案进行清楚、完整地描述,显然,所描述的实施方式仅仅是本发明一部分实施方式,而不是全部的实施方式。基于本发明中的实施方式,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施方式,均属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of them. Based on the implementation manners in the present invention, all other implementation manners obtained by persons of ordinary skill in the art without making creative efforts belong to the scope of protection of the present invention.
请参阅图1,图1是本发明曝光方法一实施方式的流程图。曝光方法包括以下步骤:Please refer to FIG. 1 . FIG. 1 is a flow chart of an embodiment of the exposure method of the present invention. The exposure method includes the following steps:
步骤S10:提供非平面基材。Step S10: providing a non-planar substrate.
其中,非平面基材的表面不是平面,例如非平面基材呈半球形或锥体形。在本实施方式中,非平面基材是超材料非平面基材。超材料是指具有天然材料所不具备的超常物理性质的人工复合结构或复合材料。通过在材料的关键物理尺度上的结构有序设计,可以突破某些表观自然规律的限制,从而获得超出自然界固有的普通性质的超常材料功能。超材料的性质和功能主要来自于其内部的结构而非构成它们的材料。Wherein, the surface of the non-planar substrate is not planar, for example, the non-planar substrate is hemispherical or cone-shaped. In this embodiment, the non-planar substrate is a metamaterial non-planar substrate. Metamaterials refer to artificial composite structures or composite materials with extraordinary physical properties that natural materials do not have. Through the orderly design of the structure on the key physical scale of the material, the limitation of some apparent natural laws can be broken through, so as to obtain the supernormal material function beyond the ordinary nature inherent in nature. The properties and functions of metamaterials are mainly derived from their internal structure rather than the materials from which they are composed.
步骤S20:用感光抗蚀剂覆盖非平面基材中非平面的至少一部分。Step S20: Covering at least a part of the non-planar substrate in the non-planar substrate with a photoresist.
其中,步骤S20进一步包括将非平面基材浸入感光抗蚀剂中并取出,使得感光抗蚀剂覆盖非平面基材中非平面的至少一部分。当然,本领域技术人员可以容易的采用其它方式在非平面基材中非平面的至少一部分覆盖感光抗蚀剂,例如采用淋洒、喷洒等方式。Wherein, step S20 further includes immersing the non-planar substrate in the photoresist and taking it out, so that the photoresist covers at least a part of the non-planar part of the non-planar substrate. Of course, those skilled in the art can easily use other methods to cover at least a part of the non-planar substrate with the photoresist, such as showering, spraying and the like.
感光抗蚀剂是一种经光照后能够改变抗蚀能力的高分子化合物。并且是一种酸性腐蚀液(主要包括盐酸、次氯酸钠或三氯化铁等成分)。在本实施方式中,感光抗蚀剂为树脂型光感材料。非平面基材浸入感光抗蚀剂的时间可以根据实际需要设定。Photoresist is a polymer compound that can change the resist ability after being exposed to light. And it is an acidic corrosion solution (mainly including hydrochloric acid, sodium hypochlorite or ferric chloride and other components). In this embodiment, the photoresist is a resin-type photosensitive material. The time for immersing the non-planar substrate into the photosensitive resist can be set according to actual needs.
步骤S30:使用立体曝光方法对非平面基材中非平面的至少一部分的感光抗蚀剂进行曝光。Step S30: exposing at least a part of the non-planar photoresist in the non-planar substrate using a stereo exposure method.
其中,通过立体曝光方法,覆盖非平面基材中非平面的至少一部分的感光抗蚀剂裸露在光照下发生反应后,剩余的感光抗蚀剂便形成了预定图形。立体曝光方法相较现有技术只在非平面基材的单一表面涂布感光抗蚀剂进行曝光的基础上,在非平面基材的多表面均覆盖感光抗蚀剂进行立体曝光。Wherein, through the stereoscopic exposure method, after the photosensitive resist covering at least a part of the non-planar part of the non-planar substrate is exposed to light and reacts, the remaining photosensitive resist forms a predetermined pattern. Compared with the prior art, the three-dimensional exposure method only coats a single surface of a non-planar substrate with a photosensitive resist for exposure, and covers multiple surfaces of a non-planar substrate with a photosensitive resist for three-dimensional exposure.
下面,将对立体曝光方法进行详细说明。请一并参阅图2,图2是图1所示的曝光方法的具体流程图。在曝光方法中,步骤S30具体分为以下步骤:Next, the stereoscopic exposure method will be described in detail. Please refer to FIG. 2 together. FIG. 2 is a specific flowchart of the exposure method shown in FIG. 1 . In the exposure method, step S30 is specifically divided into the following steps:
步骤S31:在非平面基材中非平面的每一部分均相对设置一光源,使得多个光源相对非平面基材呈立体分布。Step S31 : setting a light source opposite to each non-planar part of the non-planar substrate, so that a plurality of light sources are distributed three-dimensionally relative to the non-planar substrate.
其中,由于非平面基材的非平面相对于平面而言呈三维立体分布,为了使非平面基材的非平面全部处于光源的照射范围内,在非平面基材中非平面的每一部分均相对设置一光源。为了节约光源数量,提高光照效率,可以在非平面基材中非平面的前后左右四个方向上各设置一个光源。Among them, since the non-plane of the non-planar substrate is three-dimensionally distributed relative to the plane, in order to make all the non-plane of the non-planar substrate within the irradiation range of the light source, each part of the non-plane in the non-planar substrate is relatively Set up a light source. In order to save the number of light sources and improve the lighting efficiency, one light source can be arranged in each of the four directions of the non-planar substrate, front, back, left, and right.
步骤S32:在每一光源和非平面基材中非平面的每一部分之间设置图形转移工具。Step S32: setting a graphic transfer tool between each light source and each non-planar portion of the non-planar substrate.
其中,图形转移工具可以是菲林、钢网等图形承载物,在本实施方式中,图形转移工具贴附于非平面基材中非平面的每一部分,以获得各不相同的图形。Wherein, the graphic transfer tool may be a graphic carrier such as a film or a steel mesh. In this embodiment, the graphic transfer tool is attached to each part of the non-planar substrate to obtain different graphics.
步骤S33:利用光源照射图形转移工具,从图形转移工具透射的光线使得感光抗蚀剂发生反应,从而使得图形转移工具上的图形转移至非平面基材。Step S33: irradiating the pattern transfer tool with a light source, and the light transmitted from the pattern transfer tool causes the photosensitive resist to react, so that the pattern on the pattern transfer tool is transferred to the non-planar substrate.
其中,各个光源均照射对应的图形转移工具,感光抗蚀剂受到光照的部分发生反应后,在图形转移工具的保护下没有受到光照的部分便形成预定图形。Wherein, each light source irradiates the corresponding pattern transfer tool, and after the part of the photosensitive resist exposed to light reacts, the part not exposed to light under the protection of the pattern transfer tool forms a predetermined pattern.
由于光源的光照范围大,因此能够照射大尺寸的非平面基材。而且光照强度和光照时间也较易控制,操作相对简单,而且成本较低。Due to the large illumination area of the light source, it is possible to illuminate large non-planar substrates. Moreover, the light intensity and light time are also easier to control, the operation is relatively simple, and the cost is low.
请参阅图3,图3是本发明曝光装置一实施方式的俯视示意图。为了清楚显示,图中同时示出了非平面基材111。曝光装置包括承载部110、至少一光源120以及图形转移工具(未标示)。Please refer to FIG. 3 . FIG. 3 is a schematic top view of an embodiment of the exposure device of the present invention. For clarity, the non-planar substrate 111 is also shown in the figure. The exposure device includes a bearing part 110 , at least one light source 120 and a pattern transfer tool (not shown).
承载部110用于承载非平面基材111。非平面基材111中非平面的至少一部分覆盖有感光抗蚀剂。具体地,曝光装置包括溶液槽130和操作机构140。溶液槽130用于盛载感光抗蚀剂。操作机构140可以是机械手臂等具有夹持功能的设备,操作机构140用于将非平面基材111浸入感光抗蚀剂中并取出,使得非平面基材111中非平面的至少一部分表面均覆盖有感光抗蚀剂,再将非平面基材111置入承载部110。The carrying part 110 is used for carrying the non-planar substrate 111 . At least a portion of the non-planar substrate 111 is covered with photoresist. Specifically, the exposure device includes a solution tank 130 and an operating mechanism 140 . The solution tank 130 is used to contain photoresist. The operating mechanism 140 can be a device with a clamping function such as a robot arm. The operating mechanism 140 is used to immerse the non-planar substrate 111 in the photosensitive resist and take it out, so that at least a part of the non-planar surface of the non-planar substrate 111 is covered. There is a photoresist, and then the non-planar substrate 111 is put into the carrying part 110 .
至少一光源120相对承载部110设置。在本实施方式中,光源120为多个,例如4个,多个光源120相对承载部110呈立体分布,以使非平面基材111中非平面的每一部分均相对设置有一光源120,即多个光源120相对非平面基材111也呈立体分布。At least one light source 120 is disposed opposite to the bearing part 110 . In this embodiment, there are multiple light sources 120, for example four, and the multiple light sources 120 are three-dimensionally distributed relative to the bearing part 110, so that each non-planar part of the non-planar substrate 111 is relatively provided with a light source 120, that is, multiple The light sources 120 are also three-dimensionally distributed relative to the non-planar substrate 111 .
图形转移工具设置于光源120与非平面基材111之间的光路之中,具体地,图形转移工具设置于每一光源120和非平面基材111中非平面的每一部分之间。在感光抗蚀剂覆盖非平面基材111的每一部分后,图形转移工具可以贴附于感光抗蚀剂上,例如图形转移工具为湿菲林,也可以与光源120和非平面基材111均间隔设置,例如图形转移工具为钢网。The pattern transfer tool is disposed in the optical path between the light source 120 and the non-planar substrate 111 , specifically, the pattern transfer tool is disposed between each light source 120 and each non-planar part of the non-planar substrate 111 . After the photoresist covers each part of the non-planar substrate 111, the pattern transfer tool can be attached on the photoresist, for example, the pattern transfer tool is a wet film, and can also be spaced evenly from the light source 120 and the non-planar substrate 111 Settings such as graphics transfer tool to stencil.
至少一光源120和图形转移工具使用立体曝光方法对非平面基材111中非平面的至少一部分的感光抗蚀剂进行曝光,即多个光源120同时进行照射,透过图形转移工具的光线使感光抗蚀剂发生反应,未受到光照的感光抗蚀剂形成预定图形。图形转移工具便完成了图形转移。At least one light source 120 and the pattern transfer tool use a stereo exposure method to expose at least a part of the non-planar photosensitive resist in the non-planar substrate 111, that is, multiple light sources 120 illuminate simultaneously, and the light passing through the pattern transfer tool makes the photosensitive resist The resist reacts, and the photosensitive resist that has not been exposed to light forms a predetermined pattern. The graphics transfer tool completes the graphics transfer.
在更多实施方式中,光源120为一个且相对承载部110设置,承载部110能够进行旋转,在非平面基材111中非平面的每一部分贴附设置图形转移工具,各部分的图形转移工具具有相同或不同的图形。光源120进行照射时,承载部110带动非平面基材111以及图形转移工具旋转,使得非平面基材111中非平面的每一部分的图形转移工具均能受到照射,图形转移工具上的图形便转移至非平面基材111。In more embodiments, there is one light source 120 and it is set relative to the bearing part 110, the bearing part 110 can be rotated, and a graphic transfer tool is attached to each part of the non-planar substrate 111, and the graphic transfer tools of each part with the same or different graphics. When the light source 120 irradiates, the carrying part 110 drives the non-planar substrate 111 and the pattern transfer tool to rotate, so that the pattern transfer tool of each part of the non-planar part of the non-planar substrate 111 can be irradiated, and the pattern on the pattern transfer tool is transferred. to non-planar substrates 111.
通过上述方式,本发明的用于非平面基材的曝光方法及曝光装置通过在非平面基材中非平面的至少一部分覆盖感光抗蚀剂,再使用立体曝光方法对感光抗蚀剂进行曝光,光照范围足够大,光照强度及光照时间容易控制,能够适应于大尺寸的非平面基材,且简化操作,降低成本。Through the above method, the exposure method and exposure device for non-planar substrates of the present invention cover the photosensitive resist on at least a part of the non-planar substrate in the non-planar substrate, and then use the stereoscopic exposure method to expose the photosensitive resist, The illumination range is large enough, the illumination intensity and illumination time are easy to control, it can be adapted to large-size non-planar substrates, and the operation is simplified and the cost is reduced.
以上所述仅为本发明的实施方式,并非因此限制本发明的专利范围,凡是利用本发明说明书及附图内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。The above is only the embodiment of the present invention, and does not limit the patent scope of the present invention. Any equivalent structure or equivalent process conversion made by using the description of the present invention and the contents of the accompanying drawings, or directly or indirectly used in other related technologies fields, all of which are equally included in the scope of patent protection of the present invention.
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