CN102800245B - Water-soluble trademark and preparing method thereof - Google Patents
Water-soluble trademark and preparing method thereof Download PDFInfo
- Publication number
- CN102800245B CN102800245B CN201210315879.XA CN201210315879A CN102800245B CN 102800245 B CN102800245 B CN 102800245B CN 201210315879 A CN201210315879 A CN 201210315879A CN 102800245 B CN102800245 B CN 102800245B
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- Prior art keywords
- water
- trademark
- soluble
- trade mark
- wet sensitive
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- 238000000034 method Methods 0.000 title description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 49
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 49
- 230000002427 irreversible effect Effects 0.000 claims abstract description 30
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 47
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 16
- 238000006136 alcoholysis reaction Methods 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 5
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 5
- 229960004889 salicylic acid Drugs 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 230000008034 disappearance Effects 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Images
Landscapes
- Coloring (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a water-soluble trademark, comprising a bottom lining surface and a trademark surface, wherein the bottom lining surface is a PVA (Polyvinyl Alcohol) film; the trademark surface is humidity-sensitive irreversible printing ink; and the trademark surface is printed on the bottom lining surface in a silk printing or flexographic printing manner. According to the water-soluble trademark disclosed by the invention, the clothes trademark position and the original trademark fabrication technology are not changed completely, so that a clothes trademark can conveniently disappear after being washed, therefore the improper friction between the trademark and human skin when the clothes are worn to the skin is prevented, the wearing comfortableness is realized, and the situation that a customer damages the clothes due to removing the trademark owing to psychological reactance can also be effectively prevented.
Description
Technical field
The invention belongs to garment accessories field, particularly relate to a kind of water-soluble trade mark and preparation method thereof.
Background technology
Textile is one of necessity of human lives, and the mankind have not just been the dependence to its physical characteristics to the concern of textile, but pay close attention to more and more its snugness of fit.At present, known clothes label method of sewing is all directly fixedly made the trade mark position at clothes by trade mark. and wherein, the trade mark of shirt, T-shirt class underwear is made at neck seat, and the trade mark of skirt and trousers is made in waist position; Trade mark is made up of man-made fiber braiding, and compared with common the possessed soft smooth of garment material, its rough surface is hard, in the time wearing next to the skin, human body skin is produced to improper friction, makes us very uncomfortable.In daily life, though clothes label is little, in the time that consumer wears clothes, tend to produce prodding and itching feeling at collare trade mark place, if remove trade mark, very easily damage again clothing.Form thus an awkward situation.
Summary of the invention
Based on this, the object of this invention is to provide a kind of water-soluble trade mark.
Concrete technical scheme is as follows:
A kind of water-soluble trade mark, comprises end liner face and mark face, and described end liner face is PVAC polyvinylalcohol film, and mark face is the irreversible ink of wet sensitive, and described mark face is printed on end liner face by the mode of silk-screen or flexo.
In some embodiment, the alcoholysis degree of described PVAC polyvinylalcohol film is that 87.0-98.0%(alcoholysis degree is the molar percentage of the Zhan Zong functional group of functional group of successful alcoholysis therein).
In some embodiment, the irreversible ink of described wet sensitive is prepared from by following raw material therein: the oligomeric degree polyvinyl alcohol resin of the liquid 70%-80% that viscosity is 800-1200mPas; Antioxidant 0.1%-0.3%; Aqueous color paste 2%-5%; Distilled water 9.73%-25%; Ethanol 2%-5%; Salicylic acid 0.01%-0.05%; Defoamer 0.01%-0.05%, the summation of above-mentioned raw materials is 100%.
Another object of the present invention is to provide the preparation method of above-mentioned water-soluble trade mark.
Concrete technical scheme is as follows:
The preparation method of above-mentioned water-soluble trade mark, comprises the steps:
(1) take in proportion the each raw material of the irreversible ink of wet sensitive, mix and obtain the irreversible ink of wet sensitive;
(2) adopt the mode of silk-screen or flexo to be printed on PVAC polyvinylalcohol film in irreversible wet sensitive ink, cut and obtain described water-soluble trade mark.
Water-soluble is one of the most significant characteristic of the water-soluble trade mark of the present invention, and polyvinyl alcohol (PVA) is a kind of very unique high molecular weight water soluble polymer, and its water-soluble domination that is subject to a great extent alcoholysis degree can control that it is water-soluble by controlling alcoholysis degree.Can produce thus the water-solubility PVA shipping mark of different solution temperatures, for different occasions.The dissolubility of polyvinyl alcohol (PVA) has very big difference with the height of its alcoholysis degree.Alcoholysis degree is less than 66%, because the acetyl content of hydrophobic increases, and water-soluble decline.Temperature on the impact of polyvinyl alcohol (PVA) solubility property also because the height of alcoholysis degree is different.In the time that alcoholysis degree is 97%～98%, this impact becomes fairly obvious.
Environmental-protecting performance PVA trade mark is environmental friendliness shaped material, and first, the water-soluble of polyvinyl alcohol material gives this PVA shipping mark good recyclable recycling characteristic, and reclaim rebuilding course do not produce secondary pollution, consume energy low.Secondly, polyvinyl alcohol (PVA) is the macromolecular compound take C, H, O as chemical composition, has biodegradation character.Its mechanism of degradation is: first water-soluble, and form glue and infiltrate soil, can increase soil group clayization, gas penetration potential and water-retaining property, be particularly suitable for sandy soil transformation; Then bacterium-vacation unicellular (pseudomonas) that, the PVA in soil can be separated in soil belongs to bacterial strain and decomposes.The syntaxial system degradable PVA of at least two kinds of bacterium compositions: a kind of bacterium is the active bacterium of polyvinyl alcohol (PVA), another kind is the bacterium that produces the active bacterium desired substance of polyvinyl alcohol (PVA).First catalyzed polyethylene alcohol of the oxidation reaction enzyme of secondary alcohol, then hydrolytic enzyme cuts off oxidized polyvinyl alcohol (PVA) main chain, and further degraded, finally can be reduced to CO
2and H
2o.
Sanitation performance PVA trade mark is exactly plastics the safest, health, can be for having or not in the product of poison requirement.Much research shows, pure PVA is nontoxic, completely harmless with skin contact.
Water-solubility PVA trade mark of the present invention, can wash disappearance, need not be scraped neck again and perplex.And consider from the aspect to mankind close friend, the ink being printed on PVA film is selected the irreversible ink of wet sensitive, does not have ink to pollute on clothes after washing.
The water-soluble trade mark of the present invention does not make any changes to clothes label position and the former manufacture craft of trade mark, can easily clothes label be washed to disappearance, thereby exempt it, in the time wearing next to the skin, human body skin is produced to improper friction, make us comfortable and easy to wear, also can effectively avoid client to remove trade mark for resisting psychology, damage clothing.And stitch manufacture craft and do not limit with yarn sewing or bonding with glue, therefore manufacture craft of the present invention is simple.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of the water-soluble trade mark of the present invention.
Description of reference numerals:
1, end liner face PVA film; 2, mark face.
Embodiment
The raw material that the embodiment of the present invention is used is as follows:
PVAC polyvinylalcohol film is purchased from Jiangmen Powerleader profit water-soluble plastic company limited;
Viscosity is that the oligomeric degree polyvinyl alcohol resin of the liquid of 800-1200mPas is purchased from Guangzhou Qi Sheng Chemical Co., Ltd.;
Antioxidant is that Hinered phenols is purchased from Dongguan City Wei Boge Chemical Co., Ltd.;
Aqueous color paste is purchased from loose well pigment chemical industry institute of Japan;
Defoamer is polysiloxane-based purchased from Foshan Chu Ying Chemical Co., Ltd..
By specific embodiment, the present invention is further elaborated below.
A kind of water-soluble trade mark of the present embodiment, comprises end liner face and mark face, and described end liner face is PVAC polyvinylalcohol film, and mark face is the irreversible ink of wet sensitive, and described mark face is printed on end liner face by the mode of silk-screen or flexo.
The alcoholysis degree of described PVAC polyvinylalcohol film is 88%.
The irreversible ink of described wet sensitive is prepared from by following raw material: the oligomeric degree polyvinyl alcohol resin 80% of liquid that viscosity is 800-1200mPas; Antioxidant 0.2%; Aqueous color paste 5%; Distilled water 9.73%; Ethanol 5%; Salicylic acid 0.05%; Defoamer 0.02%.
The preparation method of above-mentioned water-soluble trade mark, comprises the steps:
(1) take in proportion the each raw material of the irreversible ink of wet sensitive, mix and obtain the irreversible ink of wet sensitive;
(2) adopt the mode of silk-screen or flexo to be printed on PVAC polyvinylalcohol film in irreversible wet sensitive ink, cut and obtain described water-soluble trade mark (as shown in Figure 1).
The water-soluble trade mark that the present embodiment prepares can dissolve completely in the time of 25 ℃ of water temperatures, can pollution clothes after the irreversible ink of wet sensitive is water-soluble.
A kind of water-soluble trade mark of the present embodiment, comprises end liner face and mark face, and described end liner face is PVAC polyvinylalcohol film, and mark face is the irreversible ink of wet sensitive, and described mark face is printed on end liner face by the mode of silk-screen or flexo.
The alcoholysis degree of described PVAC polyvinylalcohol film is 92.0%.
The irreversible ink of described wet sensitive is prepared from by following raw material: the oligomeric degree polyvinyl alcohol resin 70% of liquid that viscosity is 800-1200mPas; Antioxidant 0.3%; Aqueous color paste 3%; Distilled water 23.63%; Ethanol 3%; Salicylic acid 0.02%; Defoamer 0.05%.
The preparation method of above-mentioned water-soluble trade mark, comprises the steps:
(1) take in proportion the each raw material of the irreversible ink of wet sensitive, mix and obtain the irreversible ink of wet sensitive;
(2) adopt the mode of silk-screen or flexo to be printed on PVAC polyvinylalcohol film in irreversible wet sensitive ink, cut and obtain described water-soluble trade mark.
The water-soluble trade mark that the present embodiment prepares can dissolve completely in the time of 25 ℃ of water temperatures, can pollution clothes after the irreversible ink of wet sensitive is water-soluble.
Embodiment 3
A kind of water-soluble trade mark of the present embodiment, comprises end liner face and mark face, and described end liner face is PVAC polyvinylalcohol film, and mark face is the irreversible ink of wet sensitive, and described surface is printed on end liner face by the mode of silk-screen or flexo.
The alcoholysis degree of described PVAC polyvinylalcohol film is 98.0%.
The irreversible ink of described wet sensitive is prepared from by following raw material: the oligomeric degree polyvinyl alcohol resin 75% of liquid that viscosity is 800-1200mPas; Antioxidant 0.1%; Aqueous color paste 2%; Distilled water 20.83%; Ethanol 2%; Salicylic acid 0.05%; Defoamer 0.02%.
The preparation method of above-mentioned water-soluble trade mark, comprises the steps:
(1) take in proportion the each raw material of the irreversible ink of wet sensitive, mix and obtain the irreversible ink of wet sensitive;
(2) adopt the mode of silk-screen or flexo to be printed on PVAC polyvinylalcohol film in irreversible wet sensitive ink, cut and obtain described water-soluble trade mark.
The water-soluble trade mark that the present embodiment prepares can dissolve completely in the time of 25 ℃ of water temperatures, can pollution clothes after the irreversible ink of wet sensitive is water-soluble.
The above embodiment has only expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (3)
1. a water-soluble trade mark, is characterized in that, comprises end liner face and mark face, and described end liner face is PVAC polyvinylalcohol film, and mark face is the irreversible ink of wet sensitive, and described mark face is printed on end liner face by the mode of silk-screen or flexo; The irreversible ink of described wet sensitive is prepared from by following raw material: the oligomeric degree polyvinyl alcohol resin of the liquid 70%-80% that viscosity is 800-1200mPas; Antioxidant 0.1%-0.3%; Aqueous color paste 2%-5%; Distilled water 9.73%-25%; Ethanol 2%-5%; Salicylic acid 0.01%-0.05%; Defoamer 0.01%-0.05%, the summation of above-mentioned raw materials is 100%.
2. water-soluble trade mark according to claim 1, is characterized in that, the alcoholysis degree of described PVAC polyvinylalcohol film is 87.0-98.0%.
3. the preparation method of water-soluble trade mark described in claim 1-2 any one, is characterized in that, comprises the steps:
(1) take in proportion the each raw material of the irreversible ink of wet sensitive, mix and obtain the irreversible ink of wet sensitive;
(2) adopt the mode of silk-screen or flexo to be printed on PVAC polyvinylalcohol film in irreversible wet sensitive ink, cut and obtain described water-soluble trade mark.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210315879.XA CN102800245B (en) | 2012-08-30 | 2012-08-30 | Water-soluble trademark and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210315879.XA CN102800245B (en) | 2012-08-30 | 2012-08-30 | Water-soluble trademark and preparing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102800245A CN102800245A (en) | 2012-11-28 |
| CN102800245B true CN102800245B (en) | 2014-07-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210315879.XA Active CN102800245B (en) | 2012-08-30 | 2012-08-30 | Water-soluble trademark and preparing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108877483B (en) * | 2018-07-09 | 2021-04-20 | 庄亚新 | Environment-friendly label for textile products, preparation method and clothes |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5534966A (en) * | 1978-09-05 | 1980-03-11 | Toppan Printing Co Ltd | Method of printing on fruits |
| DE3037640A1 (en) * | 1980-10-04 | 1982-05-19 | Joachim 7440 Nürtingen Dudzik | USE OF A POLYVINYL ALCOHOL FILM FOR PRODUCING ADHESIVE MATERIAL LIKE LABEL MATERIAL |
| CN1053626A (en) * | 1990-01-25 | 1991-08-07 | 北京工业大学特种颜料厂 | Water soluble tri-idiochromatic fluorescent printing ink and preparation method thereof |
| GB9119118D0 (en) * | 1991-09-07 | 1991-10-23 | Ultramark Adhesive Products Lt | Labels |
| JPH08211829A (en) * | 1995-02-07 | 1996-08-20 | Toyo Coating Kk | Water-soluble tacky adhesive label |
| US5666785A (en) * | 1995-03-28 | 1997-09-16 | Chris-Craft Industrial Products, Inc. | Method and apparatus for in-line printing on a water soluble film |
| DE60033016T2 (en) * | 1999-12-28 | 2007-08-30 | Kanazawa, Hitoshi | METHOD FOR MODIFYING A POLYMERIC MATERIAL AND USE THEREOF |
| GB2369083A (en) * | 2000-11-17 | 2002-05-22 | Procter & Gamble | Process for preparing pouches |
| US7022656B2 (en) * | 2003-03-19 | 2006-04-04 | Monosol, Llc. | Water-soluble copolymer film packet |
| EP1689821B1 (en) * | 2003-11-14 | 2008-12-24 | 3M Innovative Properties Company | Water contact indicator |
| IL171091A (en) * | 2005-09-26 | 2011-01-31 | Samuel Icht | Water-soluble detergent film with a print and method of production |
| RU2509042C2 (en) * | 2009-05-19 | 2014-03-10 | Дзе Проктер Энд Гэмбл Компани | Method of printing on water-soluble film |
| CN102558952A (en) * | 2012-01-06 | 2012-07-11 | 浙江大学 | Irreversible thermally induced decoloring printing ink and preparation method thereof |
| CN102831818B (en) * | 2012-09-07 | 2014-07-09 | 广东溢达纺织有限公司 | Shipping mark capable of removing information by washing and preparation method of shipping mark |
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- 2012-08-30 CN CN201210315879.XA patent/CN102800245B/en active Active
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| CN102800245A (en) | 2012-11-28 |
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Effective date of registration: 20230310 Address after: No. 38, Mingli Road, Hecheng Street, Gaoming District, Foshan City, Guangdong Province, 528500 (residence application) Patentee after: Guangdong Kangpai Huanchuang Technology Co.,Ltd. Address before: 528500 Guangdong city of Foshan province river export processing zone Patentee before: Guangdong Esquel Textile Co.,Ltd. |