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CN102922621A - Production method for automobile roof made of fiber reinforced composite material - Google Patents

Production method for automobile roof made of fiber reinforced composite material Download PDF

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Publication number
CN102922621A
CN102922621A CN2012104846763A CN201210484676A CN102922621A CN 102922621 A CN102922621 A CN 102922621A CN 2012104846763 A CN2012104846763 A CN 2012104846763A CN 201210484676 A CN201210484676 A CN 201210484676A CN 102922621 A CN102922621 A CN 102922621A
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mold
resin
fiber
injection port
car roof
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CN102922621B (en
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祝颖丹
秦永利
孟令军
滑聪
蔡晶
于丽萍
范欣愉
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Ningbo Institute of Material Technology and Engineering of CAS
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Ningbo Institute of Material Technology and Engineering of CAS
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Abstract

本发明涉及纤维增强复合材料汽车顶盖的生产方法。具体地,本发明公开的汽车顶盖生产方法包括步骤:(1)采用本发明的第一模具制备汽车顶盖纤维预制件;以及(2)采用本发明的第二模具来制备汽车顶盖等步骤,实现了纤维增强复合材料汽车顶盖的连续、自动化的生产,该方法显著缩短了汽车顶盖的生产周期,大大提高了其生产效率,有利于环境保护和人体健康,具有十分广阔的应用前景。The invention relates to a method for producing a fiber-reinforced composite automobile roof cover. Specifically, the method for producing a car roof disclosed by the present invention includes the steps of: (1) using the first mold of the present invention to prepare a fiber preform for a car roof; and (2) using the second mold of the present invention to prepare a car roof, etc. The continuous and automatic production of fiber-reinforced composite car roofs has been realized. This method has significantly shortened the production cycle of car roofs, greatly improved its production efficiency, and is beneficial to environmental protection and human health. It has a very wide range of applications prospect.

Description

一种纤维增强复合材料汽车顶盖的生产方法A kind of production method of fiber-reinforced composite automobile roof cover

技术领域technical field

本发明属于汽车工业和复合材料领域,具体地,涉及一种纤维增强复合材料汽车顶盖连续自动化生产方法。The invention belongs to the fields of automobile industry and composite materials, and in particular relates to a continuous automatic production method for fiber-reinforced composite automobile top covers.

背景技术Background technique

由于全球变暖的温室效应和日益突出的能源危机,节能与环保成为世界各国汽车工业面临的最重要的命题。汽车轻量化技术是为新能源汽车和传统内燃机汽车节省能源消耗,降低环境污染的有效技术途径之一。纤维增强复合材料具有高比强度、高比模量、抗疲劳、耐腐蚀、可设计性强等一系列优异性能,近年来已成为汽车工业领域的轻量化主流技术趋势。Due to the greenhouse effect of global warming and the increasingly prominent energy crisis, energy conservation and environmental protection have become the most important propositions faced by the automobile industry in all countries in the world. Automobile lightweight technology is one of the effective technical ways to save energy consumption and reduce environmental pollution for new energy vehicles and traditional internal combustion engine vehicles. Fiber-reinforced composite materials have a series of excellent properties such as high specific strength, high specific modulus, fatigue resistance, corrosion resistance, and strong designability. In recent years, they have become the mainstream lightweight technology trend in the automotive industry.

当前,世界主要汽车制造商在未来汽车技术蓝图中,都大量地采用纤维复合材料,尤其是碳纤维复合材料,来实现轻量化和高比性能质的突破。福特公司研究表明,合理设计的复合材料可以将零部件减少80%,加工费用相对钢材降低60%,粘结费用相对焊接减少25%到40%,且复合材料结构表现出极好的韧性和抗冲撞性能。权威研究显示,若汽车整车重量降低10%,燃油效率可提高6%—8%;汽车整备质量每减少100公斤,百公里油耗可降低0.3—0.6升。从行驶性能和碰撞安全性方面来看,汽车轻量化后加速性提高,制动距离减小,碰撞时惯性减小,车辆控制灵敏性、稳定性、噪声振动方面也均有改善。At present, the world's major automobile manufacturers are using fiber composite materials, especially carbon fiber composite materials, in large quantities in the future automobile technology blueprint to achieve breakthroughs in lightweight and high specific performance. Ford's research shows that reasonably designed composite materials can reduce parts by 80%, processing costs are reduced by 60% compared to steel, bonding costs are reduced by 25% to 40% compared to welding, and composite structures exhibit excellent toughness and resistance. crash performance. According to authoritative research, if the weight of the vehicle is reduced by 10%, the fuel efficiency can be increased by 6%-8%; for every 100 kg of vehicle curb weight reduction, the fuel consumption per 100 kilometers can be reduced by 0.3-0.6 liters. From the perspective of driving performance and collision safety, after the car is lightweight, the acceleration is improved, the braking distance is reduced, the inertia of the collision is reduced, and the vehicle control sensitivity, stability, noise and vibration are also improved.

然而,目前纤维复合材料汽车制件在汽车上的规模化应用受到很大的限制,主要是其连续自动化的量产技术未突破,现有的制备技术如手糊、传统RTM成型、真空辅助注射成型方法等,成型周期长、人工劳动密集、生产效率低下、自动化程度低、产品质量不稳定,无法满足汽车工业对零部件的大批量需求。However, at present, the large-scale application of fiber composite automotive parts in automobiles is greatly restricted, mainly because its continuous and automated mass production technology has not broken through. Existing preparation technologies such as hand lay-up, traditional RTM molding, and vacuum-assisted injection Molding methods, etc., have a long molding cycle, labor-intensive, low production efficiency, low degree of automation, and unstable product quality, which cannot meet the large-volume demand for parts in the automotive industry.

综上所述,本领域迫切需要开发一种生产周期短、生产效率高的可连续、自动化生产纤维增强复合材料汽车制件的生产方法。To sum up, there is an urgent need in this field to develop a continuous and automatic production method for fiber-reinforced composite automotive parts with short production cycle and high production efficiency.

发明内容Contents of the invention

本发明的技术目的是针对上述现有技术中存在的不足,提供一种生产周期短、生产效率高的纤维增强复合材料汽车顶盖的连续自动化生产方法。The technical purpose of the present invention is to provide a continuous automatic production method of fiber-reinforced composite automobile roof cover with short production period and high production efficiency in view of the above-mentioned deficiencies in the prior art.

在本发明第一方面中,提供了一种纤维增强复合材料汽车顶盖的生产方法,其包括步骤:In a first aspect of the present invention, a method for producing a fiber-reinforced composite automobile roof is provided, which includes the steps of:

(1)汽车顶盖纤维预制件的制备(1) Preparation of automotive roof fiber prefabricated parts

定型纤维织物后,裁剪纤维织物;将裁剪后的纤维织物通过机械装置转入用于制备汽车顶盖纤维预制件的第一模具后,合模,加压;然后开模、脱模,取出汽车顶盖纤维预制件,待用;After the fiber fabric is shaped, the fiber fabric is cut; after the cut fiber fabric is transferred to the first mold for preparing the fiber prefabricated part of the car roof cover through a mechanical device, the mold is closed and pressurized; then the mold is opened, the mold is demoulded, and the car is taken out Top cover fiber preform, ready for use;

(2)汽车顶盖的制备(2) Preparation of car roof

(2.1)将步骤(1)制得的汽车顶盖纤维预制件通过机械装置转入用于制备汽车顶盖的第二模具后,合模;(2.1) after the automobile roof fiber prefabricated part that step (1) is made is transferred into the second mold that is used to prepare the automobile roof through a mechanical device, mold closing;

所述的第二模具包括:上模具、下模具、注胶口以及出胶口;The second mold includes: an upper mold, a lower mold, a glue injection port and a glue outlet;

其中,所述的下模具位于所述上模具的下方,且当所述的下模具与所述上模具闭合时,两者共同形成一模腔,所述模腔用于制造汽车顶盖;在所述模腔周边具有一闭合的树脂流道;Wherein, the lower mold is located below the upper mold, and when the lower mold and the upper mold are closed, the two jointly form a mold cavity, and the mold cavity is used to manufacture a car roof; The periphery of the mold cavity has a closed resin flow channel;

所述的注胶口用于灌入树脂,其位于所述上模具的侧面或上表面或下模具的侧面,与所述树脂流道相互连通,且注胶口和树脂流道同时位于上模具或同时位于下模具;The injection port is used to pour resin, it is located on the side of the upper mold or the upper surface or the side of the lower mold, and communicates with the resin flow channel, and the injection port and the resin flow channel are located on the upper mold at the same time Or in the lower mold at the same time;

所述的出胶口用于排出树脂,其位于所述上模具上并贯穿所述上模具;The glue outlet is used to discharge resin, which is located on the upper mold and runs through the upper mold;

(2.2)从注胶口注入和/或吸入树脂,树脂通过注胶口进入树脂流道,然后通过树脂流道进入模腔,从而完成树脂的灌注;(2.2) Inject and/or inhale the resin from the injection port, the resin enters the resin flow channel through the injection port, and then enters the mold cavity through the resin flow channel, thereby completing the resin infusion;

(2.3)完成树脂的灌注后,固化树脂,然后开模、脱模,取出汽车顶盖制品;(2.3) After completing the pouring of the resin, solidify the resin, then open the mold, demould, and take out the car roof product;

(2.4)将步骤(2.3)制得的汽车顶盖制品进行后固化处理,再进行修边、打磨,得到纤维增强复合材料汽车顶盖。(2.4) Post-cure the car roof product prepared in step (2.3), and then perform trimming and grinding to obtain a fiber reinforced composite material car roof.

在另一优选例中,所述的树脂流道位于模腔周边且位于下模具的上表面。In another preferred example, the resin runner is located at the periphery of the mold cavity and on the upper surface of the lower mold.

在另一优选例中,所述的树脂流道位于模腔周边且位于上模具的下表面。In another preferred example, the resin runner is located on the periphery of the mold cavity and on the lower surface of the upper mold.

在另一优选例中,所述的定型纤维织物包括步骤:在纤维织物上喷撒定型剂或定型粉,从而定型纤维织物。In another preferred example, the setting of the fiber fabric includes the step of: spraying a setting agent or a setting powder on the fiber fabric, so as to set the shape of the fiber fabric.

在另一优选例中,所述的裁剪纤维织物包括步骤:按照所述第一模具的表面尺寸裁剪纤维织物。In another preferred example, the cutting of the fiber fabric includes the step of: cutting the fiber fabric according to the surface size of the first mould.

在另一优选例中,所述的出胶口位于远离注胶口且略偏离上模具中心的部位。In another preferred example, the glue outlet is located away from the glue injection port and slightly deviated from the center of the upper mold.

在另一优选例中,步骤(1)中,所述的第一模具包括:下模具和上模具;其中,所述的下模具位于所述的上模具的下方,且所述的下模具与该上模具闭合时两者共同形成一模腔,所述模腔用于制造汽车顶盖纤维预制件。In another preferred example, in step (1), the first mold includes: a lower mold and an upper mold; wherein, the lower mold is located below the upper mold, and the lower mold and the upper mold When the upper mold is closed, both of them jointly form a mold cavity, and the mold cavity is used for manufacturing the fiber prefabricated part of the automobile roof cover.

在另一优选例中,步骤(1)或步骤(2.3)所述的脱模,通过以下脱模装置实现:In another preference, the demoulding described in step (1) or step (2.3) is realized by the following demoulding device:

(a)带有一个或多个吸盘的装置;和/或(a) a device with one or more suction cups; and/or

(b)设置在下模具的一个或多个顶出杆。(b) One or more ejector pins provided on the lower mold.

在另一优选例中,所述的顶出杆带有气门嘴。In another preferred example, the ejector rod has a valve.

在另一优选例中,所述树脂流道的宽度为2-30mm(较佳地为5±2mm),且深为0.5-5mm(较佳地为2±1mm)。In another preferred example, the width of the resin channel is 2-30mm (preferably 5±2mm), and the depth is 0.5-5mm (preferably 2±1mm).

在另一优选例中,在步骤(1)中,将裁剪后的纤维织物通过机械装置转入所述的第一模具之前,加热所述的第一模具;和/或在步骤(2.1)中,将步骤(1)制得的汽车顶盖纤维预制件通过机械装置转入所述的第二模具之前,加热所述的第二模具。In another preference, in step (1), before the fiber fabric after cutting is transferred into described first mold by mechanical device, heat described first mold; And/or in step (2.1) , before the fiber preform of the automobile roof cover prepared in step (1) is transferred into the second mold through a mechanical device, the second mold is heated.

在另一优选例中,所述的纤维织物为增强纤维形成的织物。In another preferred example, the fiber fabric is a fabric formed of reinforcing fibers.

在另一优选例中,所述的纤维织物选自下组的一种或多种:平纹织物、斜纹织物、缎纹织物、单向织物、多轴向经编织物和三维织物;和/或In another preferred example, the fiber fabric is selected from one or more of the following group: plain weave, twill weave, satin weave, unidirectional fabric, multiaxial warp knitted fabric and three-dimensional fabric; and/or

所述的纤维织物选自下组的一种或多种:玻璃纤维织物、碳纤维织物、芳纶纤维织物、玄武岩纤维织物、陶瓷纤维织物、天然纤维织物,或其组合。The fiber fabric is selected from one or more of the following groups: glass fiber fabric, carbon fiber fabric, aramid fiber fabric, basalt fiber fabric, ceramic fiber fabric, natural fiber fabric, or combinations thereof.

在另一优选例中,在步骤(2.2)中,所述的从注胶口注入和/或吸入树脂包括步骤:采用0.1-0.6MPa注射压力从注胶口注入树脂;和/或从出胶口对模具抽真空后从注胶口吸注或吸入树脂。In another preferred example, in step (2.2), the injection and/or suction of resin from the injection port includes the steps of: using 0.1-0.6MPa injection pressure to inject resin from the injection port; After the mouth is vacuumed to the mold, the resin is injected or sucked from the injection port.

在另一优选例中,所述的树脂为快速固化树脂。In another preferred example, the resin is a fast-curing resin.

在另一优选例中,所述的快速固化树脂包含低粘度热固性树脂或可原位聚合的热塑性树脂(例如选自下组的树脂:不饱和树脂、环氧树脂、乙烯基酯树脂、聚氨酯树脂、阴离子开环聚合聚酰胺类树脂、或聚对苯二甲酸环丁二醇酯树脂。)In another preferred example, the fast-curing resin comprises a low-viscosity thermosetting resin or an in-situ polymerizable thermoplastic resin (for example, a resin selected from the group consisting of unsaturated resins, epoxy resins, vinyl ester resins, polyurethane resins , anionic ring-opening polymerized polyamide resin, or polycyclobutylene terephthalate resin.)

在另一优选例中,所述方法具有以下的一个或两个特征:In another preferred example, the method has one or both of the following features:

(i)所述的步骤(2.2)包括步骤:采用0.1-0.6MPa注射压力从注胶口注入已脱泡的快速固化树脂和/或对模具抽真空后从注胶口吸注或吸入已脱泡的快速固化树脂,待树脂从出胶口流出后,关闭注胶口和出胶口,从而完成树脂的灌注;和/或(i) The step (2.2) includes the steps of: using 0.1-0.6 MPa injection pressure to inject the degassed fast-curing resin from the injection port and/or sucking or sucking the degassed resin from the injection port after vacuuming the mold. The quick-curing resin of the foam, after the resin flows out from the glue outlet, close the glue injection port and the glue outlet, so as to complete the resin infusion; and/or

(ii)所述的步骤(2.3)包括步骤:完成树脂的灌注后,固化树脂1-30min(优选为5-20min或5-15min),得到固化的汽车顶盖制品,然后开模、脱模,取出汽车顶盖制品。(ii) The step (2.3) includes the steps of: after completing the pouring of the resin, curing the resin for 1-30min (preferably 5-20min or 5-15min) to obtain a cured car roof product, and then opening and demoulding , Take out the car roof products.

在本发明第二方面中,提供了一种用于制备汽车顶盖的模具,所述的模具包括:上模具、下模具、注胶口以及出胶口;In the second aspect of the present invention, a mold for preparing an automobile roof is provided, the mold comprising: an upper mold, a lower mold, a glue injection port and a glue outlet;

其中,所述的下模具位于所述上模具的下方,且当所述的下模具与所述上模具闭合时,两者共同形成一模腔,所述模腔用于制造汽车顶盖;在所述模腔周边具有一闭合树脂流道;Wherein, the lower mold is located below the upper mold, and when the lower mold and the upper mold are closed, the two jointly form a mold cavity, and the mold cavity is used to manufacture a car roof; The periphery of the mold cavity has a closed resin flow channel;

所述的注胶口用于灌入树脂,其位于所述上模具的侧面或上表面或下模具的侧面,且与所述树脂流道相互连通,注胶口和树脂流道同时位于上模具或同时位于下模具;The injection port is used to pour resin, it is located on the side of the upper mold or the upper surface or the side of the lower mold, and communicates with the resin flow channel, and the injection port and the resin flow channel are located on the upper mold at the same time Or in the lower mold at the same time;

所述的出胶口用于排出树脂,其位于所述上模具上并贯穿所述上模具。The glue outlet is used to discharge resin, it is located on the upper mold and runs through the upper mold.

在另一优选例中,所述树脂流道的宽度为2-30mm(较佳地为5±2mm),深为0.5-5mm(较佳地为2±1mm)。In another preferred example, the width of the resin channel is 2-30mm (preferably 5±2mm), and the depth is 0.5-5mm (preferably 2±1mm).

在本发明第三方面中,提供了一种用于生产汽车顶盖的系统,所述系统包括:In a third aspect of the present invention there is provided a system for producing an automotive roof comprising:

用于制备汽车顶盖纤维预制件的第一模具;The first mold for the production of fiber preforms for automotive roof covers;

如本发明第二方面所述的用于制备汽车顶盖的第二模具;A second mold for preparing a car roof as described in the second aspect of the present invention;

用于转移材料的机械装置;以及Mechanical devices used to transfer materials; and

脱模装置,所述的脱模装置包括:(a)采用带有一个或多个吸盘的装置;和/或(b)在下模具设置一个或多个顶出杆。A demoulding device, said demoulding device comprising: (a) using a device with one or more suction cups; and/or (b) setting one or more ejector rods on the lower mold.

在另一优选例中,所述的材料为用于制备汽车顶盖的原材料(如纤维织物)或汽车顶盖纤维预制件。In another preferred example, the material is a raw material (such as a fiber fabric) for preparing an automobile roof or a fiber prefabricated part of an automobile roof.

在另一优选例中,所述的机械装置用于:将用于制备汽车顶盖的原材料(如纤维织物)转入所述的第一模具;和/或将汽车顶盖纤维预制件转入所述的第二模具。In another preferred example, the mechanical device is used to: transfer the raw material (such as fiber fabric) used to prepare the automobile roof into the first mold; and/or transfer the fiber preform of the automobile roof into the The second mould.

应理解,在本发明范围内中,本发明的上述各技术特征和在下文(如实施例)中具体描述的各技术特征之间都可以互相组合,从而构成新的或优选的技术方案。限于篇幅,在此不再一一累述。It should be understood that within the scope of the present invention, the above-mentioned technical features of the present invention and the technical features specifically described in the following (such as embodiments) can be combined with each other to form new or preferred technical solutions. Due to space limitations, we will not repeat them here.

附图说明Description of drawings

图1是制作纤维增强复合材料汽车顶盖纤维预制件的工艺结构示意图。Figure 1 is a schematic diagram of the process structure for making fiber-reinforced composite automotive roof fiber prefabricated parts.

图2是制作纤维增强复合材料汽车顶盖的工艺结构示意图。Figure 2 is a schematic diagram of the process structure for making a fiber-reinforced composite car roof.

图3是制作纤维增强复合材料汽车顶盖模具的树脂流道结构示意图。Figure 3 is a schematic diagram of the resin runner structure for making a fiber-reinforced composite car roof mold.

上述各图中,1为下模具、2为封孔剂、3为脱模剂、4为纤维预制体、5为密封胶条、6为上模具、7为注胶口、8为出胶口、9为密封槽、10为树脂流道。In the above figures, 1 is the lower mold, 2 is the sealing agent, 3 is the release agent, 4 is the fiber prefabricated body, 5 is the sealing strip, 6 is the upper mold, 7 is the injection port, and 8 is the glue outlet , 9 is a sealing groove, and 10 is a resin runner.

具体实施方式Detailed ways

本发明人经过长期而深入的研究,意外发现汽车顶盖纤维预制件的制备和汽车顶盖的制备采用各自独立的模具,并在采用具有特定树脂流道的模具制备汽车顶盖,实现了汽车顶盖的连续自动化生产方法,该方法显著缩短了汽车顶盖的制作周期,大大提高其生产效率,适合工业化生产。在此基础上发明人完成了本发明。After long-term and in-depth research, the inventor unexpectedly found that the preparation of the fiber prefabricated part of the automobile roof and the preparation of the automobile roof adopt independent molds, and the automobile roof is prepared by using a mold with a specific resin flow path, realizing the automobile The continuous automatic production method of the top cover significantly shortens the production cycle of the automobile top cover, greatly improves its production efficiency, and is suitable for industrialized production. The inventors have completed the present invention on this basis.

第二模具second mold

本发明所述的“第二模具”是指用于制备汽车顶盖的模具。The "second mold" mentioned in the present invention refers to a mold used to prepare an automobile roof.

现结合图2和图3对本发明的第二模具作进一步详细的描述,其包括:Now in conjunction with Fig. 2 and Fig. 3, the second mold of the present invention is described in further detail, which includes:

所述的第二模具包括:上模具、下模具、注胶口、树脂流道以及出胶口;The second mold includes: an upper mold, a lower mold, a glue injection port, a resin runner and a glue outlet;

其中,所述的下模具位于所述上模具的下方,当所述的下模具与所述上模具可密封闭合时,两者共同形成一模腔,所述模腔用于制造汽车顶盖;在所述模腔周边具有一闭合树脂流道;Wherein, the lower mold is located below the upper mold, and when the lower mold and the upper mold can be sealed and closed, the two together form a mold cavity, and the mold cavity is used to manufacture a car roof; There is a closed resin flow channel at the periphery of the mold cavity;

优选地,所述的树脂流道位于所述下模具的上表面或上模具的下表面并分布在所述模腔的四周。所述的树脂流道为闭合流道(如图3所示)。Preferably, the resin runners are located on the upper surface of the lower mold or the lower surface of the upper mold and are distributed around the cavity. The resin flow path is a closed flow path (as shown in FIG. 3 ).

另外,所述的树脂流道可以是长方形(如图3所示)、正方形等任意形状;所述树脂流道的拐角处为直角或圆弧等常规设置方式。树脂流道与注胶口连通之处的俯视形状可采用如图3所示的圆弧形状,应理解,该连通之处也可采用其它任何合适的形状(例如方形或尖角形等),以保证注胶口、树脂流道和该处模腔边缘可连通为佳。In addition, the resin flow path can be in any shape such as rectangle (as shown in FIG. 3 ), square, etc.; the corners of the resin flow path can be arranged in a normal way such as right angle or arc. The top view shape of the connection between the resin flow channel and the injection port can adopt the arc shape as shown in Figure 3. It should be understood that the connection can also adopt any other suitable shape (such as square or pointed shape, etc.), so as to It is better to ensure that the injection port, the resin flow channel and the edge of the mold cavity can be connected.

优选地,所述的树脂流道的宽度优选为2-30mm(较佳地为5±2mm),深为0.5-5mm(较佳地为2±1mm)。Preferably, the resin channel has a width of 2-30mm (preferably 5±2mm), and a depth of 0.5-5mm (preferably 2±1mm).

所述的注胶口用于灌入树脂,其位于所述上模具的侧面或上表面或下模具的侧面,且与所述树脂流道相互连通,注胶口和树脂流道同时位于上模具或同时位于下模具。The injection port is used to pour resin, it is located on the side of the upper mold or the upper surface or the side of the lower mold, and communicates with the resin flow channel, and the injection port and the resin flow channel are located on the upper mold at the same time Or both located under the mold.

所述的出胶口用于排出树脂,其位于所述上模具上并贯穿所述上模具,且与所述的模腔相互连通;优选地,所述的出胶口位于远离注胶口且略偏离上模具中心的部位。The glue outlet is used to discharge resin, it is located on the upper mold and runs through the upper mold, and communicates with the mold cavity; preferably, the glue outlet is located away from the glue injection port and Slightly deviated from the center of the upper mold.

当下模具与上模具闭合后,树脂从注胶口进入模具后分布于整个树脂流道,然后逐步充满整个模腔,待充满整个模腔后,树脂将从出胶口流出,从而完成整个注胶过程。树脂流道的设计在实现注胶均匀的同时,减少了注胶口的数量,因此,成型周期更短、效率更高、产品质量更稳定。After the lower mold and the upper mold are closed, the resin enters the mold from the injection port and distributes in the entire resin flow channel, and then gradually fills the entire mold cavity. After the entire cavity is filled, the resin will flow out from the glue outlet to complete the entire injection process. The design of the resin flow channel reduces the number of injection ports while achieving uniform injection. Therefore, the molding cycle is shorter, the efficiency is higher, and the product quality is more stable.

本文所用的“第二模具”中,上模具和下模具均采用硬质材料(如钢材、铝材、复合材料、木材等)。In the "second mold" used herein, both the upper mold and the lower mold are made of hard materials (such as steel, aluminum, composite materials, wood, etc.).

第一模具first mold

本发明所述的“第一模具”是指用于制备汽车顶盖纤维预制件的模具,基本上与本发明所述的第二模具基本相同,不同之处在于,所述的第一模具不设有注胶口、树脂流道以及出胶口。优选地可以采用如图1所示的模具,包括上模具和下模具;所述的上模具和下模具可以密封闭合。当所述的上模具与上模具密封闭合时,两者共同形成一模腔,所述模腔用于制造汽车顶盖纤维预制件。The "first mold" in the present invention refers to the mold used to prepare the fiber preform of the automobile roof cover, which is basically the same as the second mold in the present invention, the difference is that the first mold is not It is equipped with a glue injection port, a resin flow channel and a glue outlet. Preferably, a mold as shown in FIG. 1 can be used, including an upper mold and a lower mold; the upper mold and the lower mold can be sealed and closed. When the upper mold and the upper mold are hermetically closed, they together form a mold cavity, and the mold cavity is used to manufacture the fiber prefabricated part of the automobile roof cover.

本文所用的“第一模具”中,下模具可采用硬质材料(如钢材、铝材、复合材料、木材等)。而上模具可采用硬质材料(如钢材、铝材、复合材料、木材等),也可采用软质材料(如硅胶、真空袋薄膜等)。In the "first mold" used herein, the lower mold can be made of hard materials (such as steel, aluminum, composite materials, wood, etc.). The upper mold can be made of hard materials (such as steel, aluminum, composite materials, wood, etc.), or soft materials (such as silica gel, vacuum bag film, etc.).

生产方法production method

现结合图1、图2和图3对本发明的生产方法作进一步详细的描述,本发明的纤维增强复合材料汽车顶盖的连续自动化生产方法主要包括以下几个步骤:Now in conjunction with Fig. 1, Fig. 2 and Fig. 3, the production method of the present invention is described in further detail, the continuous automatic production method of the fiber-reinforced composite car roof cover of the present invention mainly includes the following steps:

(1)汽车顶盖纤维预制件4的制备:(1) Preparation of automobile roof fiber prefabricated part 4:

定型纤维织物后,裁剪纤维织物;将裁剪后的纤维织物通过机械装置(如机械手)转入本发明所述的第一模具中,合模,加压(例如加压至5-20MPa;较佳地至8-15MPa)一段时间(例如5-60秒;优选10-30秒),然后开模、脱模,取出汽车顶盖纤维预制件4,待用;After the fibrous fabric is shaped, cut the fibrous fabric; transfer the cut fibrous fabric to the first mold of the present invention through a mechanical device (such as a manipulator), close the mold, and pressurize (for example, pressurize to 5-20MPa; preferably ground to 8-15MPa) for a period of time (such as 5-60 seconds; preferably 10-30 seconds), then open the mold, demould, take out the fiber prefabricated part 4 of the car roof cover, and set it aside;

在另一优选例中,所述的定型纤维织物包括步骤:在纤维织物上喷撒定型剂或定型粉。本发明所用的定型剂或定型粉为本领域常用的定型剂或定型粉。例如所述的定型剂或定型粉包括:热固性型(如环氧树脂型定型剂/粉、双马树脂型定型剂/粉)和热塑性型(如聚异丁烯定型剂/粉、乙烯醚定型剂/粉)。In another preferred example, said sizing fiber fabric includes the step of: spraying sizing agent or sizing powder on the fiber fabric. The sizing agent or sizing powder used in the present invention is a sizing agent or sizing powder commonly used in the art. For example, said setting agent or setting powder include: thermosetting type (such as epoxy resin type setting agent/powder, double horse resin type setting agent/powder) and thermoplastic type (such as polyisobutylene setting agent/powder, vinyl ether setting agent/powder) pink).

在另一优选例中,所述的裁剪纤维织物包括步骤:按照第一模具的表面尺寸裁剪纤维织物,以使得剪裁的纤维织物适合用于制造汽车顶盖纤维预制件的模腔。In another preferred example, the cutting of the fiber fabric includes the step of: cutting the fiber fabric according to the surface size of the first mold, so that the cut fiber fabric is suitable for the mold cavity of the fiber preform for manufacturing the automobile roof cover.

在另一优选例中,当采用定型粉或定型剂来定型所述的纤维织物时,根据定型粉或定型剂的性质,可在将裁剪后的纤维织物通过机械装置转入第一模具之前,加热所述的第一模具(至与定型剂匹配的温度即可),尤其是当所述的定型粉或定型剂为中温定型粉或中温定型剂,如ES-T321等。当然若采用常温定型剂,所述的第一模具也可以不作加热处理。In another preferred example, when using a sizing powder or a sizing agent to set the fibrous fabric, according to the properties of the sizing powder or the sizing agent, before the cut fiber fabric is transferred to the first mold by a mechanical device, Heat the first mold (to a temperature that matches the setting agent), especially when the setting powder or setting agent is a medium-temperature setting powder or a medium-temperature setting agent, such as ES-T321. Of course, if a normal-temperature sizing agent is used, the first mold may not be subjected to heat treatment.

优选地,本发明所用的纤维织物为增强纤维形成的织物;较佳地,所述的纤维织物选自下组的一种或多种:平纹织物、斜纹织物、缎纹织物、单向织物、多轴向经编织物和三维织物;和/或所述的纤维织物为玻璃纤维织物、碳纤维织物、芳纶纤维织物、玄武岩纤维织物、陶瓷纤维织物、天然纤维织物,或其组合。Preferably, the fiber fabric used in the present invention is a fabric formed of reinforcing fibers; preferably, the fiber fabric is selected from one or more of the following group: plain weave, twill weave, satin weave, unidirectional fabric, Multiaxial warp knitted fabrics and three-dimensional fabrics; and/or the fiber fabrics are glass fiber fabrics, carbon fiber fabrics, aramid fiber fabrics, basalt fiber fabrics, ceramic fiber fabrics, natural fiber fabrics, or combinations thereof.

优选地,所述的步骤(1)之前还包括第一模具的准备步骤:打磨、擦拭干净所述的第一模具的表面,将密封胶条放入所述第一模具的密封槽内或放在所述第一模具的周边。Preferably, before the step (1), the preparation step of the first mold is also included: grinding and wiping the surface of the first mold, putting the sealing strip into the sealing groove of the first mold or putting at the periphery of the first mould.

(2)汽车顶盖的制备:(2) Preparation of the car roof:

(2.1)将步骤(1)制得的汽车顶盖纤维预制件通过机械装置(如机械手)转入本发明所述的第二模具中,然后合模。(2.1) Transfer the fiber prefabricated part of the automobile roof cover prepared in step (1) into the second mold of the present invention through a mechanical device (such as a manipulator), and then close the molds.

(2.2)从注胶口注入和/或吸入树脂,树脂通过注胶口进入树脂流道,并通过树脂流道进入模腔,布满整个模腔后,树脂从出胶口流出,从而完成树脂的灌注。(2.2) Inject and/or inhale the resin from the injection port, the resin enters the resin flow channel through the injection port, and enters the mold cavity through the resin flow channel. After filling the entire cavity, the resin flows out from the plastic outlet to complete the resin perfusion.

优选地,所述的从注胶口注入和/或吸入树脂可包括如下的步骤:(i)采用0.1-0.6MPa注射压力从注胶口注入树脂;和/或(ii)对第二模具抽真空后从注胶口吸注或吸入树脂,待树脂从出胶口流出后,关闭注胶口和出胶口,从而完成树脂的灌注。Preferably, the injection and/or suction of the resin from the injection port may include the following steps: (i) injecting the resin from the injection port with an injection pressure of 0.1-0.6 MPa; and/or (ii) pumping the second mold Inject or inhale the resin from the injection port after vacuuming, and close the injection port and the output port after the resin flows out from the injection port to complete the resin infusion.

(2.3)完成树脂的灌注后,固化树脂,然后开模、脱模,取出汽车顶盖制品。(2.3) After the resin is poured, the resin is cured, and then the mold is opened and demoulded, and the car roof product is taken out.

优选地,树脂固化的时间为1-30min(优选为5-20min或5-15min)。Preferably, the curing time of the resin is 1-30 min (preferably 5-20 min or 5-15 min).

(2.4)将步骤(2.3)制得的汽车顶盖制品进行后固化处理,再进行修边、打磨,得到纤维增强复合材料汽车顶盖。(2.4) Post-cure the car roof product prepared in step (2.3), and then perform trimming and grinding to obtain a fiber reinforced composite material car roof.

本文所用的树脂优选为快速固化树脂,所述的快速固化树脂包含低粘度热固性树脂或可原位聚合的热塑性树脂(例如选自下组的树脂:不饱和树脂、环氧树脂、乙烯基酯树脂、聚氨酯树脂、阴离子开环聚合聚酰胺类树脂、或聚对苯二甲酸环丁二醇酯树脂)。The resins used herein are preferably fast-curing resins comprising low-viscosity thermosetting resins or in-situ polymerizable thermoplastic resins (for example, resins selected from the group consisting of unsaturated resins, epoxy resins, vinyl ester resins , polyurethane resin, anionic ring-opening polymerized polyamide resin, or polycyclobutylene terephthalate resin).

优选地,所述的步骤(2.1)之前还包括如下的第二模具的准备步骤:Preferably, before described step (2.1), also comprise the preparation step of following second mould:

打磨、擦拭干净本发明所述第二模具的表面后,在第二模具的表面依次涂覆封孔剂、脱模剂;After polishing and wiping the surface of the second mold of the present invention, apply a sealing agent and a release agent successively on the surface of the second mold;

然后将密封胶条放入所述第二模具的密封槽内或放在所述第二模具周边;Then put the sealing strip into the sealing groove of the second mold or place it on the periphery of the second mold;

接通所述的第二模具的注胶口处和出胶口处的管道;Connect the pipeline at the glue injection port and the glue outlet of the second mold;

加热所述的第二模具(例如加热至60-200℃;较佳地为80-180℃)。Heating the second mold (eg heating to 60-200° C.; preferably 80-180° C.).

本发明方法所用的封孔剂以及脱模剂为本领域常用的封孔剂以及脱模剂。例如,所述的封孔剂包括:甘油酯树脂、酚醛树脂、铝乙烯、环氧树脂、聚酰亚胺氨树脂等类型;所述的脱模剂包括:硅系列(主要包括:硅氧烷化合物、硅油、硅树脂甲基支链硅油、甲基硅油、乳化甲基硅油、含氢甲基硅油、硅脂、硅树脂、硅橡胶、硅橡胶甲苯溶液等)、蜡系列(主要包括:植物、动物、合成石蜡;微晶石蜡;聚乙烯蜡等)、氟系列(例如聚四氟乙烯、氟树脂粉末、氟树脂涂料等)、表面活性剂系列(例如金属皂、EO或PO衍生物等)等类型。The sealing agent and the release agent used in the method of the present invention are commonly used sealing agents and release agents in the art. For example, the sealing agent includes: glyceride resin, phenolic resin, aluminum vinyl, epoxy resin, polyimide ammonia resin and other types; the release agent includes: silicon series (mainly including: siloxane Compound, silicone oil, silicone resin methyl branched silicone oil, methyl silicone oil, emulsified methyl silicone oil, hydrogen-containing methyl silicone oil, silicone grease, silicone resin, silicone rubber, silicone rubber toluene solution, etc.), wax series (mainly including: plant , animal, synthetic paraffin; microcrystalline paraffin; polyethylene wax, etc.), fluorine series (such as polytetrafluoroethylene, fluororesin powder, fluororesin coating, etc.), surfactant series (such as metal soap, EO or PO derivatives, etc. ) and other types.

本发明所述的生产方法中,脱模步骤可采用多种脱模装置协助,以使所得的制品(即汽车顶盖纤维预制件或汽车顶盖)从模具上无损脱模,所述的脱模装置可采用(a)采用带有一个或多个吸盘的装置,将制得的制品吸出,从而使制品脱模;或(b)在下模具设置有一个或多个顶出杆,所述顶出杆可向上顶出,从而使得制品脱膜。在第二模具,所述的中心顶出杆优选带有气门嘴,开模后,往该带有气门嘴的顶杆处通入压缩空气,从而使得制品脱模。In the production method of the present invention, the demoulding step can be assisted by a variety of demoulding devices, so that the obtained product (i.e., the fiber prefabricated part of the car roof or the car roof) is demolded from the mold without damage. The molding device may adopt (a) a device with one or more suction cups to suck out the manufactured product, thereby demoulding the product; or (b) one or more ejector pins are provided on the lower mold, and the ejector The ejection rod can be ejected upwards, so that the product can be released from the film. In the second mold, the center ejector rod preferably has a valve. After the mold is opened, compressed air is fed into the ejector rod with the valve, so that the product is demolded.

本发明提供的一种纤维增强复合材料汽车顶盖连续自动化生产方法,其主要优点为:A continuous automatic production method for fiber-reinforced composite automobile roof provided by the present invention has the main advantages of:

采用本发明的汽车顶盖生产方法制得的汽车顶盖,既维持了顶盖的刚度、强度等性能,而且与金属汽车顶盖相比实现了减重40%以上,且力学性能优异。The automobile roof produced by the automobile roof production method of the present invention not only maintains the rigidity, strength and other properties of the roof, but also achieves a weight reduction of more than 40% compared with the metal automobile roof, and has excellent mechanical properties.

本发明的汽车顶盖生产方法,实现了汽车顶盖的连续自动化生产方法,且制作周期显著缩短,生产效率大大提高,适合工业化生产。The production method of the automobile top cover of the invention realizes the continuous automatic production method of the automobile top cover, and the production period is significantly shortened, the production efficiency is greatly improved, and it is suitable for industrialized production.

本发明的所述的第二模具通过一个注胶口,结合闭合的树脂流道,实现了单注胶口和单出胶口,且注胶均匀、充模效率高、模具容易清理。The second mold of the present invention realizes a single glue injection port and a single glue outlet through a glue injection port combined with a closed resin flow channel, and the glue injection is uniform, the mold filling efficiency is high, and the mold is easy to clean.

下面结合具体实施,进一步阐述本发明。应理解,这些实施例仅用于说明本发明而不用于限制本发明的范围。下列实施例中未注明具体条件的实验方法,通常按照常规条件,或按照制造厂商所建议的条件。除非另外说明,否则百分比和份数按重量计算。除非特别说明,本发明所用原料均市售可得。The present invention will be further described below in conjunction with specific implementation. It should be understood that these examples are only used to illustrate the present invention and are not intended to limit the scope of the present invention. For the experimental methods without specific conditions indicated in the following examples, the conventional conditions or the conditions suggested by the manufacturer are usually followed. Percentages and parts are by weight unless otherwise indicated. Unless otherwise specified, the raw materials used in the present invention are all commercially available.

实施例1碳纤维增强复合材料汽车顶盖的生产方法The production method of embodiment 1 carbon fiber reinforced composite automobile roof cover

步骤1:第一模具的清理及准备Step 1: Cleaning and preparation of the first mold

提供一图1所示的用于制备汽车顶盖纤维预制件的第一模具;Provide the first mold for preparing the fiber prefabricated part of the automobile roof cover as shown in Fig. 1;

将第一模具的下模具1和上模具6的表面用1000目砂纸打磨光滑,然后用酒精或丙酮将表面擦拭干净,将密封胶条5放入下模具1周边的密封槽内。The surface of the lower mold 1 and the upper mold 6 of the first mold is polished smooth with 1000 mesh sandpaper, then the surface is wiped clean with alcohol or acetone, and the sealing strip 5 is put into the sealing groove around the lower mold 1.

步骤2:汽车顶盖纤维预制件的制备Step 2: Preparation of fiber preforms for automotive roof

在东丽T700-12K碳纤维斜纹布待裁剪处喷涂少量定型剂(商品名:AIRTAC 2,购自Airtech公司),再采用裁床按照第一模具的表面尺寸裁剪4块碳纤维布,将4块碳纤维布通过机械手自动层叠后转入经步骤1处理的第一模具中,然后合模、在9MPa下加压10秒,开模、脱模后,取出汽车顶盖纤维预制件,待用;Spray a small amount of sizing agent (trade name: AIRTAC 2, purchased from Airtech Company) on the Toray T700-12K carbon fiber twill fabric to be cut, and then use the cutting machine to cut 4 pieces of carbon fiber cloth according to the surface size of the first mold, and put 4 pieces of carbon fiber cloth Transfer to the first mold processed by step 1 after being automatically stacked by a manipulator, then close the mold, pressurize at 9MPa for 10 seconds, open the mold and demould, take out the fiber prefabricated part of the car roof, and set it aside;

步骤3:第二模具的清理及准备Step 3: Cleaning and preparation of the second mold

提供图2所示的用于制备汽车顶盖的第二模具;Provide the second mold that is used to prepare the car top cover shown in Figure 2;

将第二模具的下模具1和上模具6表面用1000目砂纸打磨光滑,用酒精或丙酮擦拭干净;The surface of the lower mold 1 and the upper mold 6 of the second mold is polished smooth with 1000 mesh sandpaper, and wiped clean with alcohol or acetone;

待酒精或丙酮挥发完全后,在下模具1和上模具6表面均匀涂覆涂封孔剂2(商品名:

Figure BDA00002459511400101
15Sealer,购自CHEM-TREND公司);待封孔剂固化后然后在下模具1和上模具6表面均匀涂覆脱模剂3(商品名:
Figure BDA00002459511400102
购自CHEM-TREND公司),待脱膜剂干后再重复该操作2次;After the alcohol or acetone volatilize completely, evenly coat the sealing agent 2 (trade name:
Figure BDA00002459511400101
15Sealer, purchased from CHEM-TREND company); after the sealing agent is cured, evenly coat the release agent 3 on the surface of the lower mold 1 and the upper mold 6 (trade name:
Figure BDA00002459511400102
purchased from CHEM-TREND company), and repeat the operation 2 times after the release agent is dry;

将密封胶条5放入下模具和上模具的密封槽内,将第二模具的注胶口7和出胶口8接好管道,待用,然后将第二模具加热至85度;Put the sealing strip 5 into the sealing groove of the lower mold and the upper mold, connect the glue injection port 7 and the glue outlet 8 of the second mold to the pipeline, and set aside, then heat the second mold to 85 degrees;

步骤4:汽车顶盖的制备Step 4: Preparation of the car roof

将步骤2制得的汽车顶盖纤维预制件通过机械手转入经步骤3处理的第二模具)中;闭合所述的第二模具的上模具6和下模具1;采用0.2MPa注射压力从位于下模具侧面的注胶口7注入已脱泡的快速固化环氧树脂(商品名:EpoTech 167A:商品名:EpoTech 175B=100:21,质量比),树脂从出胶口8流出后关闭注胶口和出胶口;The automobile roof fiber prefabricated part that step 2 makes is transferred in the second mold that is processed through step 3) by manipulator; Close the upper mold 6 and the lower mold 1 of the second mold; Adopt 0.2MPa injection pressure from the Fill the injection port 7 on the side of the lower mold with degassed fast-curing epoxy resin (trade name: EpoTech 167A: trade name: EpoTech 175B=100:21, mass ratio), and close the injection after the resin flows out from the exit port 8 mouth and glue outlet;

步骤5:脱模Step 5: Unmold

树脂固化10min后开模,用带有多个吸盘的装置吸附制品的表面,使制品从模具上无损脱模,取出制品;After the resin is cured for 10 minutes, the mold is opened, and the surface of the product is absorbed by a device with multiple suction cups, so that the product is released from the mold without damage, and the product is taken out;

步骤6:汽车顶盖后处理Step 6: Car Roof Post-Processing

将步骤5所得的制品转入烘箱,在150度下进行后固化处理1小时,再进行修边、打磨,得到碳纤维增强复合材料汽车顶盖。Put the product obtained in step 5 into an oven, perform post-curing treatment at 150 degrees for 1 hour, and then trim and polish to obtain a carbon fiber reinforced composite car roof.

实施例2碳纤维增强复合材料汽车顶盖的生产方法The production method of embodiment 2 carbon fiber reinforced composite automobile roof cover

制备方法类似实施例1,不同的是采用如下条件:The preparation method is similar to Example 1, except that the following conditions are adopted:

步骤3中,将第二模具加热至150度;In step 3, the second mold is heated to 150 degrees;

步骤4中,将步骤2制得的汽车顶盖纤维预制件通过机械手转入将步骤3处理的第二模具中;闭合所述第二模具的上模具6和下模具1,从出胶口8对模具抽真空至不高于2.4kPa,然后通过真空从注胶口7吸入已脱泡的阴离子开环聚合聚酰胺6树脂(己内酰胺:己内酰胺溴化镁:六亚甲基-1,6-二甲酰己内酰胺=97:1.0:2.0,摩尔比),树脂从出胶口8流出后关闭注胶口和出胶口。In step 4, the fiber prefabricated part of the roof cover made in step 2 is transferred to the second mold processed in step 3 by manipulator; The mold is evacuated to no higher than 2.4kPa, and then the defoamed anionic ring-opening polymerized polyamide 6 resin (caprolactam: caprolactam magnesium bromide: hexamethylene-1,6-di formyl caprolactam=97:1.0:2.0, molar ratio), and the resin flows out from the glue outlet 8 and closes the glue injection port and the glue outlet.

步骤6中,将制品在150度下进行后固化处理1小时。In step 6, post-cure the product at 150 degrees for 1 hour.

实施例3碳纤维增强复合材料汽车顶盖的生产方法Embodiment 3 The production method of carbon fiber reinforced composite automobile roof cover

制备方法类似实施例1,不同的是采用如下条件:The preparation method is similar to Example 1, except that the following conditions are adopted:

在第二模具的下模具1中心处设置一带气门嘴的顶出杆;An ejector rod with a valve is arranged at the center of the lower mold 1 of the second mold;

步骤5中,树脂固化10min后开模,从下模具1中心处的顶出杆通入0.3MPa的压缩空气,使制品从模具上无损脱模,取出制品。In step 5, after the resin is solidified for 10 minutes, the mold is opened, and 0.3 MPa compressed air is introduced from the ejector rod at the center of the lower mold 1 to release the product from the mold without damage, and take out the product.

综上所述,In summary,

1.与金属汽车顶盖相比,本发明的生产方法采用了轻量化、性能优异的纤维增强复合材料作为汽车顶盖的制作原料,制得的顶盖在维持刚度、强度等性能的同时,还实现了顶盖减重40%以上,而且力学性能优异。1. Compared with the metal car roof, the production method of the present invention adopts lightweight, high-performance fiber-reinforced composite material as the raw material for making the car roof, and the prepared roof maintains properties such as rigidity and strength. It also achieves a weight reduction of more than 40% on the top cover, and has excellent mechanical properties.

2.现有技术中,通常采用同一模具先后制备汽车顶盖纤维预制件和汽车顶盖,这样的方法生产周期长、效率低。而本发明的生产方法,在制备汽车顶盖纤维预制件和汽车顶盖时,分别采用了本发明的第一模具和第二模具,实现了汽车顶盖的连续自动化生产方法,显著缩短了汽车顶盖的制作周期,大大提高其生产效率,适合工业化生产。2. In the prior art, the same mold is usually used to successively prepare the fiber prefabricated part of the automobile roof and the automobile roof. Such a method has a long production cycle and low efficiency. And the production method of the present invention adopts the first mold and the second mold of the present invention respectively when preparing the automobile roof fiber prefabricated part and the automobile roof, and realizes the continuous automatic production method of the automobile roof, which significantly shortens the production time of the automobile roof. The production cycle of the top cover greatly improves its production efficiency and is suitable for industrial production.

3.现有的用于制备汽车顶盖的模具通常具有多个用于注入树脂的注胶口和出胶口,而多注胶口和多出胶口通常具有注胶不均匀、增加工序、且模具清洗费时等缺陷。而本发明的生产方法采用的第二模具通过一个注胶口,结合闭合的树脂流道,实现了单注胶口和单出胶口,且具备注胶均匀、充模效率高、模具容易清理等优点。3. Existing molds for preparing automotive roofs usually have multiple injection ports and outlets for injecting resin, and multiple injection ports and multiple outlets usually have uneven injection, increased processes, And mold cleaning is time-consuming and other defects. However, the second mold adopted in the production method of the present invention realizes a single injection port and a single glue outlet through a glue injection port and a closed resin flow channel, and has uniform glue injection, high mold filling efficiency, and easy cleaning of the mold. Etc.

在本发明提及的所有文献都在本申请中引用作为参考,就如同每一篇文献被单独引用作为参考那样。此外应理解,在阅读了本发明的上述讲授内容之后,本领域技术人员可以对本发明作各种改动或修改,这些等价形式同样落于本申请所附权利要求书所限定的范围。All documents mentioned in this application are incorporated by reference in this application as if each were individually incorporated by reference. In addition, it should be understood that after reading the above teaching content of the present invention, those skilled in the art can make various changes or modifications to the present invention, and these equivalent forms also fall within the scope defined by the appended claims of the present application.

Claims (10)

1.一种纤维增强复合材料汽车顶盖的生产方法,其特征在于,1. A production method for a fiber-reinforced composite car roof, characterized in that, 包括步骤:Include steps: (1)汽车顶盖纤维预制件的制备(1) Preparation of automotive roof fiber prefabricated parts 定型纤维织物后,裁剪纤维织物;将裁剪后的纤维织物通过机械装置转入用于制备汽车顶盖纤维预制件的第一模具后,合模,加压;然后开模、脱模,取出汽车顶盖纤维预制件,待用;After the fiber fabric is shaped, the fiber fabric is cut; after the cut fiber fabric is transferred to the first mold for preparing the fiber prefabricated part of the car roof cover through a mechanical device, the mold is closed and pressurized; then the mold is opened, the mold is demoulded, and the car is taken out Top cover fiber preform, ready for use; (2)汽车顶盖的制备(2) Preparation of car roof (2.1)将步骤(1)制得的汽车顶盖纤维预制件通过机械装置转入用于制备汽车顶盖的第二模具后,合模;(2.1) after the automobile roof fiber prefabricated part that step (1) is made is transferred into the second mold that is used to prepare the automobile roof through a mechanical device, mold closing; 所述的第二模具包括:上模具、下模具、注胶口以及出胶口;The second mold includes: an upper mold, a lower mold, a glue injection port and a glue outlet; 其中,所述的下模具位于所述上模具的下方,且当所述的下模具与所述上模具闭合时,两者共同形成一模腔,所述模腔用于制造汽车顶盖;在所述模腔周边具有一闭合的树脂流道;Wherein, the lower mold is located below the upper mold, and when the lower mold and the upper mold are closed, the two jointly form a mold cavity, and the mold cavity is used to manufacture a car roof; The periphery of the mold cavity has a closed resin flow channel; 所述的注胶口用于灌入树脂,其位于所述上模具的侧面或上表面或下模具的侧面,与所述树脂流道相互连通,且注胶口和树脂流道同时位于上模具或同时位于下模具;The injection port is used to pour resin, it is located on the side of the upper mold or the upper surface or the side of the lower mold, and communicates with the resin flow channel, and the injection port and the resin flow channel are located on the upper mold at the same time Or in the lower mold at the same time; 所述的出胶口用于排出树脂,其位于所述上模具上并贯穿所述上模具;The glue outlet is used to discharge resin, which is located on the upper mold and runs through the upper mold; (2.2)从注胶口注入和/或吸入树脂,树脂通过注胶口进入树脂流道,然后通过树脂流道进入模腔,从而完成树脂的灌注;(2.2) Inject and/or inhale the resin from the injection port, the resin enters the resin flow channel through the injection port, and then enters the mold cavity through the resin flow channel, thereby completing the resin infusion; (2.3)完成树脂的灌注后,固化树脂,然后开模、脱模,取出汽车顶盖制品;(2.3) After completing the pouring of the resin, solidify the resin, then open the mold, demould, and take out the car roof product; (2.4)将步骤(2.3)制得的汽车顶盖制品进行后固化处理,再进行修边、打磨,得到纤维增强复合材料汽车顶盖。(2.4) Post-cure the car roof product prepared in step (2.3), and then perform trimming and grinding to obtain a fiber reinforced composite material car roof. 2.如权利要求1所述的纤维增强复合材料汽车顶盖的生产方法,其特征在于,步骤(1)或步骤(2.3)所述的脱模,通过以下脱模装置实现:2. the production method of fiber reinforced composite car roof as claimed in claim 1, is characterized in that, the described demoulding of step (1) or step (2.3), realizes by following demoulding device: (a)带有一个或多个吸盘的装置;和/或(a) a device with one or more suction cups; and/or (b)设置在下模具的一个或多个顶出杆。(b) One or more ejector pins provided on the lower mold. 3.如权利要求1所述的纤维增强复合材料汽车顶盖的生产方法,其特征在于,所述树脂流道的宽度为2-30mm,且深为0.5-5mm。3. The method for producing a fiber-reinforced composite car roof as claimed in claim 1, wherein the resin runner has a width of 2-30mm and a depth of 0.5-5mm. 4.如权利要求1所述的纤维增强复合材料汽车顶盖的生产方法,其特征在于,4. the production method of fiber-reinforced composite automobile roof cover as claimed in claim 1, is characterized in that, 在步骤(1)中,将裁剪后的纤维织物通过机械装置转入所述的第一模具之前,加热所述的第一模具;和/或In step (1), before the cut fiber fabric is transferred into the first mold by mechanical means, the first mold is heated; and/or 在步骤(2.1)中,将步骤(1)制得的汽车顶盖纤维预制件通过机械装置转入所述的第二模具之前,加热所述的第二模具。In the step (2.1), the second mold is heated before the fiber preform of the roof cover of the automobile prepared in the step (1) is transferred into the second mold by a mechanical device. 5.如权利要求1所述的纤维增强复合材料汽车顶盖的生产方法,其特征在于,所述的纤维织物为增强纤维形成的织物。5. The method for producing a fiber-reinforced composite car roof as claimed in claim 1, wherein said fiber fabric is a fabric formed of reinforcing fibers. 6.如权利要求1所述的纤维增强复合材料汽车顶盖的生产方法,其特征在于,在步骤(2.2)中,所述的从注胶口注入和/或吸入树脂包括步骤:采用0.1-0.6MPa注射压力从注胶口注入树脂;和/或从出胶口对模具抽真空后从注胶口吸注或吸入树脂。6. The production method of fiber-reinforced composite car roof as claimed in claim 1, characterized in that, in step (2.2), said injection and/or inhalation of resin from the injection port comprises the steps of: using 0.1- 0.6MPa injection pressure injects resin from the injection port; and/or sucks or inhales resin from the injection port after vacuuming the mold from the injection port. 7.如权利要求1所述的纤维增强复合材料汽车顶盖的生产方法,其特征在于,所述的树脂为快速固化树脂。7. The method for producing a fiber-reinforced composite car roof as claimed in claim 1, wherein said resin is a fast-curing resin. 8.如权利要求1所述的纤维增强复合材料汽车顶盖的生产方法,其特征在于,具有以下的一个或两个特征:8. The production method of fiber-reinforced composite car roof as claimed in claim 1, characterized in that, has one or both of the following characteristics: (i)所述的步骤(2.2)包括步骤:采用0.1-0.6MPa注射压力从注胶口注入已脱泡的快速固化树脂和/或对模具抽真空后从注胶口吸注或吸入已脱泡的快速固化树脂,待树脂从出胶口流出后,关闭注胶口和出胶口,从而完成树脂的灌注;和/或(i) The step (2.2) includes the steps of: using 0.1-0.6 MPa injection pressure to inject the degassed fast-curing resin from the injection port and/or sucking or sucking the degassed resin from the injection port after vacuuming the mold. The quick-curing resin of the foam, after the resin flows out from the glue outlet, close the glue injection port and the glue outlet, so as to complete the resin infusion; and/or (ii)所述的步骤(2.3)包括步骤:完成树脂的灌注后,固化树脂1-30min,得到固化的汽车顶盖制品,然后开模、脱模,取出汽车顶盖制品。(ii) The step (2.3) includes the steps of: curing the resin for 1-30 minutes to obtain a cured car roof product after the filling of the resin is completed, and then opening and demolding the car roof product. 9.一种用于制备汽车顶盖的模具,其特征在于,所述的模具包括:上模具、下模具、注胶口以及出胶口;9. A mold for preparing a car roof, characterized in that, the mold comprises: an upper mold, a lower mold, a glue injection port and a glue outlet; 其中,所述的下模具位于所述上模具的下方,且当所述的下模具与所述上模具闭合时,两者共同形成一模腔,所述模腔用于制造汽车顶盖;在所述模腔周边具有一闭合树脂流道;Wherein, the lower mold is located below the upper mold, and when the lower mold and the upper mold are closed, the two jointly form a mold cavity, and the mold cavity is used to manufacture a car roof; The periphery of the mold cavity has a closed resin flow channel; 所述的注胶口用于灌入树脂,其位于所述上模具的侧面或上表面或下模具的侧面,且与所述树脂流道相互连通,注胶口和树脂流道同时位于上模具或同时位于下模具;The injection port is used to pour resin, it is located on the side of the upper mold or the upper surface or the side of the lower mold, and communicates with the resin flow channel, and the injection port and the resin flow channel are located on the upper mold at the same time Or in the lower mold at the same time; 所述的出胶口用于排出树脂,其位于所述上模具上并贯穿所述上模具。The glue outlet is used to discharge resin, it is located on the upper mold and runs through the upper mold. 10.一种用于生产汽车顶盖的系统,其特征在于,包括:10. A system for producing a car roof, characterized in that it comprises: 用于制备汽车顶盖纤维预制件的第一模具;The first mold for the production of fiber preforms for automotive roof covers; 如权利要求9所述的用于制备汽车顶盖的第二模具;The second mold for preparing a car roof as claimed in claim 9; 用于转移材料的机械装置;以及Mechanical devices used to transfer materials; and 脱模装置,所述的脱模装置包括:(a)采用带有一个或多个吸盘的装置;和/或(b)在下模具设置一个或多个顶出杆。A demoulding device, said demoulding device comprising: (a) using a device with one or more suction cups; and/or (b) setting one or more ejector rods on the lower mold.
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CN106938549A (en) * 2017-05-05 2017-07-11 湖南大学 A kind of adjustable RTM mold of sheet thickness self adaptation and plate preparation method
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CN107891614A (en) * 2017-11-24 2018-04-10 山东双科技股份有限公司 The preparation method of passage reinforcing plate in a kind of composite material automobile
CN108973173A (en) * 2018-06-22 2018-12-11 当阳市益红金属制品有限公司 Improve the device and technique of fibre reinforced composites precision
CN109153805A (en) * 2016-03-30 2019-01-04 韦巴斯托股份公司 Produce the method for the deck component of motor vehicles and the deck component with molding portion
CN110524756A (en) * 2019-08-07 2019-12-03 中国商用飞机有限责任公司北京民用飞机技术研究中心 Treadmill test part molding die, treadmill test part production method and treadmill test part

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CN103496172A (en) * 2013-09-13 2014-01-08 常熟市乐德维织造有限公司 Novel fabric enhanced composite material with high tensile property
CN104552980A (en) * 2013-10-26 2015-04-29 宁波华翔汽车零部件研发有限公司 High-pressure resin transfer molding (RTM) process suitable for rapid molding of carbon fiber automobile parts
CN103552610B (en) * 2013-11-19 2018-08-17 中国科学院宁波材料技术与工程研究所 A kind of automotive openings component and preparation method thereof
CN103552610A (en) * 2013-11-19 2014-02-05 中国科学院宁波材料技术与工程研究所 Automobile opening part and manufacturing method thereof
CN104626609A (en) * 2014-12-05 2015-05-20 东莞市海旭新材料技术有限公司 Preparation method of a carbon fiber automobile grille inspection tool
CN104827684A (en) * 2015-04-20 2015-08-12 奇瑞汽车股份有限公司 Motor vehicle pedal manufacturing method and motor vehicle pedal
CN104875399A (en) * 2015-05-21 2015-09-02 江苏大学 Preparing equipment for carbon fiber reinforcement bars for test purposes
CN104943202A (en) * 2015-07-03 2015-09-30 浙江大学 Carbon fiber composite material axial flow fan impeller molding and curing device
CN104943202B (en) * 2015-07-03 2017-06-23 浙江大学 Carbon fibre composite axial flow fan vane wheel forming and hardening device
CN109153805A (en) * 2016-03-30 2019-01-04 韦巴斯托股份公司 Produce the method for the deck component of motor vehicles and the deck component with molding portion
CN105729831A (en) * 2016-04-28 2016-07-06 常州市新创复合材料有限公司 Production equipment and production process of carbon fiber product
CN106335151A (en) * 2016-11-07 2017-01-18 东莞华南设计创新院 Automobile accessory die
CN106335151B (en) * 2016-11-07 2018-10-30 东莞华南设计创新院 Auto-parts mould
CN106938549A (en) * 2017-05-05 2017-07-11 湖南大学 A kind of adjustable RTM mold of sheet thickness self adaptation and plate preparation method
CN107718594A (en) * 2017-08-17 2018-02-23 芜湖博康新材料技术有限公司 A kind of production technology of automobile top cover assembly
CN107891614A (en) * 2017-11-24 2018-04-10 山东双科技股份有限公司 The preparation method of passage reinforcing plate in a kind of composite material automobile
CN108973173A (en) * 2018-06-22 2018-12-11 当阳市益红金属制品有限公司 Improve the device and technique of fibre reinforced composites precision
CN110524756A (en) * 2019-08-07 2019-12-03 中国商用飞机有限责任公司北京民用飞机技术研究中心 Treadmill test part molding die, treadmill test part production method and treadmill test part

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