CN102933810B - ring reducer mixer - Google Patents
ring reducer mixer Download PDFInfo
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- CN102933810B CN102933810B CN201180027335.7A CN201180027335A CN102933810B CN 102933810 B CN102933810 B CN 102933810B CN 201180027335 A CN201180027335 A CN 201180027335A CN 102933810 B CN102933810 B CN 102933810B
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
- F01N3/206—Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
- F01N3/2066—Selective catalytic reduction [SCR]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/431—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
- B01F25/4315—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor the baffles being deformed flat pieces of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/431—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
- B01F25/4316—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor the baffles being flat pieces of material, e.g. intermeshing, fixed to the wall or fixed on a central rod
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/431—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
- B01F25/4318—Ring-shaped blades or strips
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/431—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
- B01F25/43197—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor characterised by the mounting of the baffles or obstructions
- B01F25/431971—Mounted on the wall
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2892—Exhaust flow directors or the like, e.g. upstream of catalytic device
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
- F01N2240/20—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a flow director or deflector
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
Description
技术领域technical field
本发明涉及发动机排气后处理系统,并且更具体地涉及采用用于NOx还原技术的还原剂的排气后处理系统。The present invention relates to engine exhaust aftertreatment systems, and more particularly to exhaust aftertreatment systems employing reductants for NOx reduction technology.
背景技术Background technique
在用于动力系统的排气处理或后处理系统中可包括选择性催化还原(SCR)系统,以除去或还原来自发动机排气的氮氧化物(NOx或NO)排放物。SCR系统使用被导入排气系统中的还原剂,例如尿素。Selective catalytic reduction (SCR) systems may be included in exhaust treatment or aftertreatment systems for powertrain systems to remove or reduce nitrogen oxide (NOx or NO) emissions from engine exhaust. SCR systems use a reducing agent, such as urea, that is introduced into the exhaust system.
美国专利US 7,581,387公开了一种包括用于使尿素与排气流混合的混合叶片的混合系统。US patent US 7,581,387 discloses a mixing system comprising mixing blades for mixing urea with the exhaust gas flow.
发明内容Contents of the invention
本发明提供了一种包括构造成将还原剂导入排气管道中的喷射器和配置在排气流中的环的发动机排气后处理系统。The present invention provides an engine exhaust aftertreatment system including an injector configured to introduce a reductant into an exhaust conduit and a ring disposed in the exhaust flow.
附图说明Description of drawings
图1是包括发动机和带有混合器的后处理系统的动力系统的概略图。FIG. 1 is a schematic diagram of a powertrain including an engine and an aftertreatment system with a mixer.
图2是混合器的正视图。Figure 2 is a front view of the mixer.
图3是混合器的另一个实施例的正视图。Figure 3 is a front view of another embodiment of a mixer.
图4是混合器的另一个实施例的正视图。Figure 4 is a front view of another embodiment of a mixer.
图5是混合器的另一个实施例的正视图。Figure 5 is a front view of another embodiment of a mixer.
图6是混合器的另一个实施例的正视图。Figure 6 is a front view of another embodiment of a mixer.
图7是加入了混合器的双支管后处理系统的概略图。Fig. 7 is a schematic diagram of a double-branch aftertreatment system incorporating a mixer.
具体实施方式detailed description
如图1所示,动力系统10包括发动机12和用于处理由发动机12产生的排气流16的后处理系统14。发动机12可包括其他未示出的特征结构,例如控制器、燃料系统、空气系统、冷却系统、周边设备、传动系构件、涡轮增压器、排气再循环系统等。As shown in FIG. 1 , a powertrain system 10 includes an engine 12 and an aftertreatment system 14 for treating an exhaust flow 16 produced by the engine 12 . Engine 12 may include other features not shown, such as controls, fuel system, air system, cooling system, peripherals, driveline components, turbochargers, exhaust gas recirculation systems, and the like.
发动机12可以是任何类型的发动机(内燃、气体、柴油、气态燃料、天然气、丙烷等),可以具有任何尺寸,带有任何数量的气缸,并且采用任何构造(“V”型、直列、径向等)。发动机12可以用于驱动任何机器或其他装置,包括公路卡车或车辆、野外卡车或机械、运土设备、发电机、航天应用、机车应用、海洋应用、泵、静止设备或其他发动机驱动的应用。Engine 12 may be any type of engine (internal combustion, gas, diesel, gaseous fuel, natural gas, propane, etc.), may be of any size, with any number of cylinders, and in any configuration ("V", inline, radial Wait). Engine 12 may be used to drive any machine or other device, including on-highway trucks or vehicles, off-road trucks or machinery, earth-moving equipment, generators, aerospace applications, locomotive applications, marine applications, pumps, stationary equipment, or other engine-driven applications.
后处理系统14包括排气管道18和选择性催化还原(SCR)系统20。SCR系统20包括SCR催化剂22、混合管道24、混合器26和还原剂供应系统28。The aftertreatment system 14 includes an exhaust conduit 18 and a selective catalytic reduction (SCR) system 20 . SCR system 20 includes SCR catalyst 22 , mixing conduit 24 , mixer 26 and reductant supply system 28 .
SCR催化剂22包括配置在基底上的催化剂材料。基底可由堇青石、碳化硅、其他陶瓷或金属组成。基底可包括多个贯通的通道并且可形成蜂窝结构。The SCR catalyst 22 includes a catalyst material disposed on a substrate. The substrate can be composed of cordierite, silicon carbide, other ceramics or metals. The substrate may include a plurality of channels therethrough and may form a honeycomb structure.
还原剂供应系统28可包括还原剂30、还原剂源32、泵34、阀36、还原剂管线38和喷射器40。还原剂30经由泵34从还原剂源32被抽吸并且经由阀36来控制向喷射器40的输送。也可通过泵34的运转来控制还原剂30的流动。The reductant supply system 28 may include a reductant 30 , a reductant source 32 , a pump 34 , a valve 36 , a reductant line 38 and an injector 40 . Reductant 30 is drawn from reductant source 32 via pump 34 and delivery to injector 40 is controlled via valve 36 . The flow of reductant 30 may also be controlled by operation of pump 34 .
混合管道24是还原剂30被导入的排气管道18的区段。混合管道24包括内壁25和外壁27。混合管道24还由内宽29限定。The mixing line 24 is the section of the exhaust line 18 into which the reducing agent 30 is introduced. The mixing duct 24 includes an inner wall 25 and an outer wall 27 . The mixing duct 24 is also defined by an inner width 29 .
还原剂供应系统28还可包括用于解冻冻结的还原剂30、防止还原剂30冻结或防止还原剂30过热的热管理系统。还原剂供应系统28的构件也可以是绝热的,以防止还原剂30过热。还原剂供应系统28还可包括用于导入压缩空气以协助在还原剂喷雾44中形成小液滴的空气辅助系统。空气辅助系统也可被用来在未使用时对还原剂管线38和其他还原剂供应系统28构件驱送还原剂30。Reductant supply system 28 may also include a thermal management system for thawing frozen reductant 30 , preventing reductant 30 from freezing, or preventing reductant 30 from overheating. Components of reductant supply system 28 may also be insulated to prevent overheating of reductant 30 . The reductant supply system 28 may also include an air assist system for introducing compressed air to assist in the formation of small droplets in the reductant spray 44 . An air assist system may also be used to drive reductant 30 to reductant line 38 and other reductant supply system 28 components when not in use.
还原剂30来自喷射器40的喷嘴或喷射器末端42,以形成还原剂喷雾44或者以其他方式导入排气流16或SCR催化剂22中。喷射器末端42的位置可以使得沿混合管道24和混合器26的中心线直接向下引导还原剂喷雾44。The reductant 30 comes from a nozzle or injector tip 42 of the injector 40 to form a reductant spray 44 or is otherwise introduced into the exhaust gas flow 16 or the SCR catalyst 22 . The position of injector tip 42 may be such that reductant spray 44 is directed directly down the centerline of mixing conduit 24 and mixer 26 .
后处理系统14也可包括柴油氧化催化剂(DOC)46、柴油颗粒过滤器(DPF)48和净化催化剂50。DOC 46和DPF 48可以如图所示位于同一个罐中或者是分开的。SCR催化剂22和净化催化剂50也可如图所示位于同一个罐中或者是分开的。The aftertreatment system 14 may also include a diesel oxidation catalyst (DOC) 46 , a diesel particulate filter (DPF) 48 , and a purification catalyst 50 . DOC 46 and DPF 48 may be in the same tank as shown or separate. The SCR catalyst 22 and the purification catalyst 50 can also be located in the same tank as shown or be separate.
后处理系统14构造成从排气流16除去、收集或转化不希望有的成分。DOC 46将一氧化碳(CO)和未燃烧的碳氢化合物(HC)转化成二氧化碳(CO2)。DPF 48收集颗粒物质或炭烟。SCR催化剂22构造成在存在还原剂30的情况下减少还原排气流16的NOx的量。Aftertreatment system 14 is configured to remove, collect, or convert undesired components from exhaust stream 16 . The DOC 46 converts carbon monoxide (CO) and unburned hydrocarbons (HC) into carbon dioxide (CO2). DPF 48 collects particulate matter or soot. The SCR catalyst 22 is configured to reduce the amount of NOx reducing the exhaust gas flow 16 in the presence of the reductant 30 .
还可包括热源52,以从DPF 48除去炭烟,热管理SCR催化剂22、DOC 46或净化催化剂50,以从SCR催化剂22除去硫,或者除去可能已形成的还原剂30的沉淀物。热源52可体现为燃烧器、用于在DOC 46上形成放热反应的碳氢化合物计量供给系统、电加热元件、微波装置或其他热源。热源52也可体现为使发动机12在产生升高的排气流16温度的状态下运转。热源52也可体现为排气中的背压阀或另一个制约装置,以使排气流16温度升高。A heat source 52 may also be included to remove soot from the DPF 48 , thermally manage the SCR catalyst 22 , DOC 46 , or purge catalyst 50 to remove sulfur from the SCR catalyst 22 or to remove deposits of the reductant 30 that may have formed. Heat source 52 may embody a burner, a hydrocarbon metering system for creating an exothermic reaction on DOC 46, an electric heating element, a microwave device, or other heat source. The heat source 52 may also be embodied as operating the engine 12 in a condition that produces an elevated temperature of the exhaust flow 16 . The heat source 52 may also embody a backpressure valve or another restriction in the exhaust to increase the temperature of the exhaust stream 16 .
在图示的实施例中,排气流16离开发动机12,绕开或经过热源52,经过DOC 46、DPF 48,然后经过SCR系统20,并且然后经由排气管道18经过净化催化剂50。In the illustrated embodiment, exhaust gas flow 16 exits engine 12 , bypasses or passes heat source 52 , passes DOC 46 , DPF 48 , then passes SCR system 20 , and then passes purification catalyst 50 via exhaust conduit 18 .
也可在SCR系统20上游、下游或其内部设置其他排气处理装置。在图示的实施例中,SCR系统20位于DPF 48下游并且DOC 46位于DPF 48上游。热源52位于DOC 46上游。净化催化剂50位于SCR系统20下游。在其他实施例中,这些装置可采用各种次序布置并且可组合在一起。在一个实施例中,SCR催化剂22可与DPF 48组合,其中催化剂材料沉淀在DPF 48上。Other exhaust gas treatment devices may also be provided upstream, downstream, or within the SCR system 20 . In the illustrated embodiment, SCR system 20 is located downstream of DPF 48 and DOC 46 is located upstream of DPF 48 . Heat source 52 is located upstream of DOC 46 . A cleanup catalyst 50 is located downstream of the SCR system 20 . In other embodiments, these means can be arranged in various orders and combined together. In one embodiment, the SCR catalyst 22 may be combined with the DPF 48 where the catalyst material is deposited on the DPF 48 .
虽然其他还原剂30是可能的,但尿素是最普遍的还原剂30的源。尿素还原剂30分解或水解成氨(NH3)并且然后被吸收或以其他方式存储在SCR催化剂22中。混合管道24可以很长,以协助还原剂30的混合或均匀分配到排气流16中并提供用于尿素还原剂30转化成NH3的停留时间。NH3通过NOx还原成氮气(N2)而在SCR催化剂22中被消耗。Urea is the most common source of reductant 30, although other reductants 30 are possible. The urea reductant 30 decomposes or hydrolyzes to ammonia (NH 3 ) and is then absorbed or otherwise stored in the SCR catalyst 22 . Mixing conduit 24 may be long to assist in mixing or uniform distribution of reductant 30 into exhaust stream 16 and to provide residence time for conversion of urea reductant 30 to NH3. NH3 is consumed in the SCR catalyst 22 by reduction of NOx to nitrogen (N2).
净化催化剂50可体现为氨氧化催化剂(AMOX)。净化催化剂50构造成捕获、存储、氧化、还原和/或转化可滑过或穿过SCR催化剂22的NH3。净化催化剂50也可构造成捕获、存储、氧化、还原和/或转化其他存在的成分。The purification catalyst 50 may be embodied as an ammonia oxidation catalyst (AMOX). The purge catalyst 50 is configured to capture, store, oxidize, reduce, and/or convert NH 3 that may slip over or pass through the SCR catalyst 22 . Purification catalyst 50 may also be configured to capture, store, oxidize, reduce, and/or convert other components present.
也可包括控制器和传感器系统,以控制发动机12、热源52、还原剂供应系统28和动力系统10或其应用中的其他构件。A controller and sensor system may also be included to control engine 12 , heat source 52 , reductant supply system 28 , and other components of power system 10 or its application.
混合器26包括环绕部件或环54。环54如图所示是平坦的,具有超环面形状和矩形截面,类似于垫圈。在其他实施例中,环54可具有各种其他截面,包括圆形。The mixer 26 includes a surrounding member or ring 54 . Ring 54 is shown flat, having a toroidal shape and a rectangular cross-section, similar to a washer. In other embodiments, ring 54 may have various other cross-sections, including circular.
环54包括正面表面(face surface)55、内表面56和外表面57。环54由在排气流16的流动方向上的厚度58、内径60、外径61和环宽度62限定。环宽度62是形成环54的部件的宽度并且是内径60与外径61之差的一半。环54的内径60限定中央开口64。Ring 54 includes a face surface 55 , an inner surface 56 and an outer surface 57 . The ring 54 is defined by a thickness 58 in the flow direction of the exhaust gas flow 16 , an inner diameter 60 , an outer diameter 61 , and a ring width 62 . Ring width 62 is the width of the components forming ring 54 and is half the difference between inner diameter 60 and outer diameter 61 . The inner diameter 60 of the ring 54 defines a central opening 64 .
由于环54可以是平坦的,所以环的表面可以贯穿厚度58是一致的并与正面表面55相同。横向平面65穿过混合器并切割混合管道24。横向平面65包括与它平行的平面群组。横向平面65可沿着正面表面55布置或者可延伸穿过混合器26的另一个部分。横向平面65可垂直于排气流16,如图所示。横向平面65也可垂直于混合管道24的内壁25。在其他实施例中,横向平面65可与排气流16和内壁26成各种角度配置。Since the ring 54 may be flat, the surface of the ring may be consistent through the thickness 58 and identical to the front surface 55 . A transverse plane 65 passes through the mixer and cuts the mixing duct 24 . Transverse plane 65 includes a group of planes parallel to it. The transverse plane 65 may be disposed along the frontal surface 55 or may extend through another portion of the mixer 26 . The transverse plane 65 may be perpendicular to the exhaust flow 16 as shown. The transverse plane 65 may also be perpendicular to the inner wall 25 of the mixing duct 24 . In other embodiments, transverse plane 65 may be arranged at various angles to exhaust flow 16 and inner wall 26 .
虽然将环54描述和示出为超环面和圆形的并具有“直径”,但环54也可以是矩形的、八边形的、三角形的或任何其他形状。环54的形状可与混合管道24的内周一致并且可相应与容纳它的混合管道24的形状的至少一部分匹配。环54也可具有不同于混合管道24的形状并且尺寸适于配合在混合管道24内(例如,环54可具有配合在圆形混合管道24内的正方形形状)。环宽度62可以是或不是恒定的。环54的外形也可不同于内部形状(例如,外形可以是圆形的,而内部形状和中央开口64可以是矩形的)。While ring 54 is described and shown as toroidal and circular and has a "diameter," ring 54 may also be rectangular, octagonal, triangular, or any other shape. The shape of the ring 54 may conform to the inner circumference of the mixing duct 24 and may correspondingly match at least a portion of the shape of the mixing duct 24 that houses it. Ring 54 may also have a different shape than mixing duct 24 and be sized to fit within mixing duct 24 (eg, ring 54 may have a square shape that fits within circular mixing duct 24 ). Ring width 62 may or may not be constant. The outer shape of the ring 54 may also differ from the inner shape (eg, the outer shape may be circular while the inner shape and central opening 64 may be rectangular).
混合器26也可包括将环54与混合管道24的内壁25分开的间隔件66。间隔件66也可用来安装环54。The mixer 26 may also include a spacer 66 separating the ring 54 from the inner wall 25 of the mixing conduit 24 . A spacer 66 may also be used to mount the ring 54 .
环54的外表面57与内壁25之间的分隔限定间隙68。间隙68可以是环形的或者具有不同形状。间隙68可具有间隙宽度70。间隙宽度70在环54周围可以是或不是恒定的。在一些实施例中,在环54的一些部位可以不存在间隙68。The separation between the outer surface 57 of the ring 54 and the inner wall 25 defines a gap 68 . The gap 68 may be annular or have a different shape. Gap 68 may have a gap width 70 . Gap width 70 may or may not be constant around ring 54 . In some embodiments, there may be no gap 68 at some locations of the ring 54 .
以下提供混合器26的一些尺寸情况。这些尺寸情况可取决于在不同的动力系统10之间会有所改变的大量变量。例如,适当的混合器26尺寸可取决于排气流16速度、混合管道24尺寸、发动机12负载循环、发动机12背压要求、还原剂喷雾44液滴尺寸、还原剂喷雾44速率。为了说明这些变量,在比率方面限定以下尺寸并提供范围。Some dimensions of mixer 26 are provided below. These dimensions may depend on a number of variables that may vary between different powertrains 10 . For example, appropriate mixer 26 size may depend on exhaust flow 16 velocity, mixing duct 24 size, engine 12 duty cycle, engine 12 backpressure requirements, reductant spray 44 droplet size, reductant spray 44 rate. To account for these variables, the following dimensions are defined and ranges are provided in terms of ratios.
间隙宽度70可以是大约1/8英寸。在其他实施例中,间隙宽度70可以介于1/16与1/4英寸之间。在另外的其他实施例中,间隙宽度70可以介于1/16与1/2英寸之间。Gap width 70 may be approximately 1/8 inch. In other embodiments, gap width 70 may be between 1/16 and 1/4 inch. In still other embodiments, gap width 70 may be between 1/16 and 1/2 inch.
间隙宽度70的尺寸也可以是内宽29的函数。在一个实施例中,间隙68沿着横向平面65的面积可以是混合管道沿着横向平面65的面积的大约1.3%。在其他实施例中,间隙68沿着横向平面65的面积可以介于混合管道沿着横向平面65的面积的0.5%与5%之间、0.1%与10%之间或0.7%与2%之间。The size of the gap width 70 can also be a function of the inner width 29 . In one embodiment, the area of the gap 68 along the transverse plane 65 may be approximately 1.3% of the area of the mixing duct along the transverse plane 65 . In other embodiments, the area of the gap 68 along the transverse plane 65 may be between 0.5% and 5%, between 0.1% and 10%, or between 0.7% and 2% of the area of the mixing duct along the transverse plane 65 .
环宽度62可以是大约2英寸。在其他实施例中,环宽度62可介于1与3英寸之间。在另外的其他实施例中,环宽度62可介于0.5与5英寸之间。Ring width 62 may be approximately 2 inches. In other embodiments, ring width 62 may be between 1 and 3 inches. In still other embodiments, ring width 62 may be between 0.5 and 5 inches.
环宽度62的尺寸也可以是内宽29的函数。在一个实施例中,环宽度62可以是内宽29的大约10%。在其他实施例中,环宽度62可以介于内宽29的5%与15%之间或2%与25%之间。The dimension of ring width 62 may also be a function of inner width 29 . In one embodiment, ring width 62 may be approximately 10% of inner width 29 . In other embodiments, ring width 62 may be between 5% and 15% or between 2% and 25% of inner width 29 .
间隙宽度70和环宽度62也可选择成根据内宽29实现中央开口64的给定尺寸。在一个实施例中,中央开口64沿着横向平面65的面积可以是混合管道24沿着横向平面65的面积的大约62%。在其他实施例中,中央开口64沿着横向平面65的面积可以介于混合管道24沿着横向平面65的面积的50%与70%之间、40%与80%之间、30%与80%之间或20%与90%之间。Gap width 70 and ring width 62 may also be selected to achieve a given size of central opening 64 based on inner width 29 . In one embodiment, the area of the central opening 64 along the transverse plane 65 may be approximately 62% of the area of the mixing duct 24 along the transverse plane 65 . In other embodiments, the area of the central opening 64 along the transverse plane 65 may be between 50% and 70%, between 40% and 80%, between 30% and 80% of the area of the mixing duct 24 along the transverse plane 65. % or between 20% and 90%.
环54可以由金属板构成,并且因此厚度58可以比较小,不过它可以是各种尺寸。在一个实施例中,该厚度可以小于1(一)英寸。在另一个实施例中,该厚度可以小于1/4英寸。厚度58也可小于环宽度62。Ring 54 may be constructed of sheet metal, and thus thickness 58 may be relatively small, although it may be of various sizes. In one embodiment, the thickness may be less than 1 (one) inch. In another embodiment, the thickness may be less than 1/4 inch. Thickness 58 may also be less than ring width 62 .
图2-6示出了具有如下所述的各种特征的混合器26的各种实施例。混合器26可包括文中描述的特征的任何组合。图2将环54作为实心表面示出。图2还示出间隔件66可由将环54与内壁25分离并安装或连接到内壁25的点焊72形成。2-6 illustrate various embodiments of mixer 26 having various features as described below. Mixer 26 may include any combination of the features described herein. Figure 2 shows the ring 54 as a solid surface. FIG. 2 also shows that spacer 66 may be formed by spot welds 72 that separate ring 54 from and fit or connect to inner wall 25 .
图3示出了环54可包括穿过正面表面55的一个或多个开口73。开口73可具有在环54上的各种位置并且可形成各种图案。图3还示出间隔件66可由从环54的外表面57延伸的接片(tab)74形成。接片74的远端然后可焊接、插入或以其他方式连接到混合管道24,以将环54与内壁25分离并安装或连接到内壁25,并且形成间隙68。FIG. 3 shows that ring 54 may include one or more openings 73 through front surface 55 . Openings 73 may have various locations on ring 54 and may form various patterns. FIG. 3 also shows that the spacers 66 may be formed from tabs 74 extending from the outer surface 57 of the ring 54 . The distal end of tab 74 may then be welded, inserted, or otherwise connected to mixing duct 24 to separate and mount or connect ring 54 to inner wall 25 and form gap 68 .
图4示出了混合器26可包括延伸到中央开口64中的中央结构76。这些中央结构76可从环54的内表面56或从另一个位置或本体延伸。中央结构76可体现为大的部件、小的金属丝或丝网。FIG. 4 shows that mixer 26 may include a central structure 76 extending into central opening 64 . These central structures 76 may extend from the inner surface 56 of the ring 54 or from another location or body. The central structure 76 can be embodied as a large part, a small wire or a wire mesh.
图5示出了可在混合器26上增加导流板78。导流板78包括导流板开口80和偏转器82。偏转器82与排气流16成小于90度的角度配置并由此引导排气流16以一定角度通过导流板开口80。导流板78可通过弯曲切口84或冲压扇形部(scallop)86而形成。图6示出偏转器82也可由间隔件66或中央结构76形成。FIG. 5 shows that a baffle 78 may be added to the mixer 26 . The baffle 78 includes a baffle opening 80 and a deflector 82 . The deflector 82 is disposed at an angle of less than 90 degrees to the exhaust flow 16 and thereby directs the exhaust flow 16 at an angle through the baffle opening 80 . The baffle 78 may be formed by bending a cutout 84 or stamping a scallop 86 . FIG. 6 shows that the deflector 82 can also be formed by the spacer 66 or the central structure 76 .
图1示出了混合器26在混合管道24中的位置。混合器26在距喷射器末端42的混合器距离88处配置在内壁25内。混合器距离88可以是这样的:当还原剂喷雾44到达环54时,喷雾44在其膨胀时的尺寸大致为中央开口64的尺寸。FIG. 1 shows the position of the mixer 26 in the mixing conduit 24 . The mixer 26 is arranged within the inner wall 25 at a mixer distance 88 from the injector tip 42 . The mixer distance 88 may be such that when the reductant spray 44 reaches the ring 54 , the size of the spray 44 as it expands is approximately the size of the central opening 64 .
图7示出了混合器26可用于双支管后处理系统90中。双支管后处理系统90包括接收排气流16和来自还原剂供应系统28的还原剂30的第一和第二SCR支管91和92。FIG. 7 shows that mixer 26 may be used in a dual-leg aftertreatment system 90 . Dual-leg aftertreatment system 90 includes first and second SCR legs 91 and 92 that receive exhaust gas flow 16 and reductant 30 from reductant supply system 28 .
来自混合管道24的排气流16在排气管道18的分隔区段93中被分割或分隔。分隔区段93可位于混合器26下游的分隔距离94处。分隔距离94可比混合器距离88长。在一个实施例中,分隔距离可以是内宽29的函数。分隔距离94可以是内宽29的大约1.2倍。在其他实施例中,分隔距离94可为内宽29的多于1.2倍、1与2倍之间或1与3倍之间。The exhaust flow 16 from the mixing duct 24 is divided or divided in a dividing section 93 of the exhaust duct 18 . Separation section 93 may be located at separation distance 94 downstream of mixer 26 . Separation distance 94 may be longer than mixer distance 88 . In one embodiment, the separation distance may be a function of the inner width 29 . Separation distance 94 may be approximately 1.2 times inner width 29 . In other embodiments, the separation distance 94 may be more than 1.2 times, between 1 and 2 times, or between 1 and 3 times the inner width 29 .
双支管后处理系统90也可包括将排气流16输送至还原剂供应系统28的第一和第二进入支管95和96。来自第一和第二进入支管95和96的排气流16在排气管道18的合并区段97中被分割或分隔。Dual-leg aftertreatment system 90 may also include first and second inlet legs 95 and 96 that deliver exhaust gas stream 16 to reductant supply system 28 . The exhaust flow 16 from the first and second inlet branches 95 and 96 is split or divided in a merged section 97 of the exhaust duct 18 .
第一和第二进入支管95和96被示出为包括DPF 48和DOC 46,但可以不包括上述任何一者,或者可以包括其他构件。在一个实施例中,第一和第二进入支管95和96不包括DPF 48。第一和第二进入支管95和96也可被示出为相对于第一和第二SCR支管91和92成直角配置,但可以成各种其他角度配置或可以线性地配置。双支管后处理系统90也可被容纳在带有分隔排气流的内壁的盒结构中。The first and second inlet legs 95 and 96 are shown to include the DPF 48 and the DOC 46 , but may include neither, or may include other components. In one embodiment, first and second inlet legs 95 and 96 do not include DPF 48 . The first and second inlet legs 95 and 96 may also be shown arranged at right angles relative to the first and second SCR legs 91 and 92 , but may be arranged at various other angles or may be arranged linearly. The dual-leg aftertreatment system 90 may also be housed in a box structure with inner walls separating the exhaust flow.
混合器26构件可由钢或任何其他各种材料构成。混合器26也可涂覆有协助还原剂30转化或水解成NH3的材料。The mixer 26 components may be constructed of steel or any other variety of materials. Mixer 26 may also be coated with a material that assists in the conversion or hydrolysis of reductant 30 to NH3.
工业实用性Industrial Applicability
混合器26有助于将还原剂30均匀地分配或混合到排气流16中,促进还原剂30转化成NH3,并且防止沉淀物的形成。混合器26还应该便宜、小并且形成最低背压。然而,这些特征常常互相冲突。例如,较大和复杂的结构可在将还原剂30均匀地分配到排气流16中和促进还原剂30转化成NH3方面有效但不便宜,占据过多的空间,并且常常形成大量背压。The mixer 26 helps to evenly distribute or mix the reductant 30 into the exhaust gas stream 16 , facilitates the conversion of the reductant 30 to NH 3 , and prevents the formation of deposits. The mixer 26 should also be cheap, small and create minimal back pressure. However, these features often conflict with each other. For example, large and complex structures can be effective at distributing reductant 30 evenly into exhaust gas stream 16 and promoting conversion of reductant 30 to NH 3 , but are not cheap, take up excessive space, and often create substantial back pressure.
将还原剂30均匀地分配到排气流16中通过将NH3均匀地引导到SCR催化剂的所有通道而提高了SCR系统20的效率并因此能发生大量转化。将还原剂30均匀地分配到排气流16中也可减少实现较大的效率所需的还原剂30的量。将还原剂30均匀地分配到排气流16中还可防止将过多NH3引导到可导致NH3滑过的一部分SCR催化剂区域。Evenly distributing the reductant 30 into the exhaust gas flow 16 increases the efficiency of the SCR system 20 by directing the NH3 evenly to all channels of the SCR catalyst and thus enables a large amount of conversion to occur. Evenly distributing the reductant 30 into the exhaust flow 16 may also reduce the amount of reductant 30 needed to achieve greater efficiency. Evenly distributing the reductant 30 into the exhaust flow 16 also prevents too much NH 3 from being directed to a portion of the SCR catalyst area that could cause NH 3 to slip through.
当还原剂30未迅速分解成NH3时可能形成沉淀物,并且聚集还原剂30的厚层。这些层可随着越来越多的还原剂30被喷射或收集而积累,这可具有阻止分解成NH3的冷却作用。结果,还原剂30升华成晶体或者以其他方式转变成固体组分而形成沉淀物。沉淀物组分可包含缩二脲(NH2CONHCONH2)或三聚氰酸((NHCO)3)或另一种组分,取决于温度和其他条件。这些沉淀物可形成在还原剂喷雾44撞击、沉淀或停滞的区域内或表面上。Precipitates may form when the reducing agent 30 is not rapidly decomposed into NH 3 , and a thick layer of the reducing agent 30 accumulates. These layers can build up as more and more reductant 30 is injected or collected, which can have a cooling effect that prevents decomposition into NH3. As a result, the reducing agent 30 sublimates into crystals or otherwise converts into solid components to form a precipitate. The precipitate component may contain biuret (NH2CONHCONH2) or cyanuric acid ((NHCO)3) or another component, depending on temperature and other conditions. These deposits may form in or on surfaces where the reductant spray 44 impinges, settles, or stagnates.
这些沉淀物可对动力系统10的运转有不利影响。沉淀物可阻塞排气流16流动,导致较高的背压并降低发动机12和后处理系统14性能和效率。沉淀物也可中断还原剂30流动和混合到排气流16中,由此减少分解成NH3并降低NOx还原效率。沉淀物的形成还消耗了还原剂30,使喷射的控制更难并且潜在地降低了NOx还原效率。沉淀物还可能腐蚀和降解SCR系统20的构件。These deposits may adversely affect the operation of power system 10 . The deposits can block the flow of the exhaust stream 16 , causing higher back pressure and reducing engine 12 and aftertreatment system 14 performance and efficiency. The deposits may also interrupt the flow and mixing of the reductant 30 into the exhaust stream 16, thereby reducing decomposition to NH3 and reducing NOx reduction efficiency. The formation of deposits also consumes the reductant 30 , making control of injection more difficult and potentially reducing NOx reduction efficiency. The deposits may also corrode and degrade the components of the SCR system 20 .
限制背压增加也很重要。高背压会危害发动机12性能。高背压还可引起沉淀物形成和排气泄漏。It is also important to limit the increase in back pressure. High back pressure can compromise engine 12 performance. High back pressure can also cause deposit formation and exhaust leaks.
环54可形成有限的背压,同时仍实现较高的还原剂30混合到排气流16中的程度。中央开口64的大尺寸限制了制约并且还形成排气流16的翻滚(tumbling),这种翻滚对于使还原剂30混合到排气流16中有效。许多其他混合器设计实现了通过旋流混合或形成高紊流水平。这些混合器具有复杂和庞大的结构,并且因此往往很昂贵并产生背压。相反,已发现通过环54实现的翻滚对于混合有效,同时生产起来也便宜,并且不会产生其他混合器那么大的量的背压。环54的平坦形状通过切割便宜的简单板材而有利于其制造。更复杂的混合器需要昂贵的更复杂的切割、弯曲和焊接。The ring 54 may create limited back pressure while still achieving a higher degree of mixing of the reductant 30 into the exhaust flow 16 . The large size of the central opening 64 limits confinement and also creates tumbling of the exhaust flow 16 that is effective for mixing the reductant 30 into the exhaust flow 16 . Many other mixer designs achieve mixing by swirling or creating high turbulence levels. These mixers are of complex and bulky construction and thus tend to be expensive and generate back pressure. In contrast, tumbling via the ring 54 has been found to be effective for mixing while being cheap to produce and not creating as much back pressure as other mixers. The flat shape of the ring 54 facilitates its manufacture by cutting cheap simple sheet material. More complex mixers require expensive and more complex cutting, bending and welding.
可采用间隙68以允许排气流16流过,同时仍实现上述翻滚效果。这种流过防止否则将形成沉淀物的还原剂30的停滞聚集。这种流过还有助于减少背压。如果间隙68过大,则上述翻滚效果可能受到阻碍,因为大量流动将仅在环54周围进行而不是经中央开口64翻滚。如果间隙68过小,则所述流过可能不足以防止沉淀物或实现背压的显著减少。Gap 68 may be employed to allow exhaust flow 16 to flow through while still achieving the tumbling effect described above. This flow-through prevents stagnant accumulation of reductant 30 that would otherwise form a precipitate. This flow also helps reduce back pressure. If the gap 68 is too large, the tumbling effect described above may be hindered because the bulk flow will only be done around the ring 54 rather than tumbling through the central opening 64 . If the gap 68 is too small, the flow through may not be sufficient to prevent deposits or achieve a significant reduction in back pressure.
间隙68可沿着沿环54的外表面57的周边定位,因为这是还原剂将聚集的部位。在一些实施例中,间隙68可仅位于环54的底部,还原剂30否则会聚集在这里。The gap 68 may be located along the perimeter along the outer surface 57 of the ring 54 since this is where the reductant will collect. In some embodiments, gap 68 may be located only at the bottom of ring 54 where reductant 30 would otherwise collect.
混合器26与喷射器末端42的混合器距离88可影响沉淀物的形成和混合效力。如果混合器距离88过短,则还原剂喷雾44将集中在小的空间中,因为喷雾44还没有膨胀。相应地,还原剂喷雾44可仅通过中央开口64的精确中央部。由于喷雾44将集中在小的空间中并且仅通过中央开口的中心,所以上述翻滚效果可能不会起作用,并且还原剂30混合到排气流16中可能不会达到期望的程度。如果混合器距离88过长,则还原剂喷雾44将已膨胀到较大的体积并且可在转化为NH3前撞击在环54或内壁25上。这种撞击可能导致如上所述形成沉淀物。The mixer distance 88 of the mixer 26 from the injector tip 42 can affect sediment formation and mixing effectiveness. If the mixer distance 88 is too short, the reductant spray 44 will be concentrated in a small space because the spray 44 has not yet expanded. Accordingly, reductant spray 44 may only pass through the exact central portion of central opening 64 . Since the spray 44 will be concentrated in a small space and only pass through the center of the central opening, the tumbling effect described above may not work and the mixing of the reductant 30 into the exhaust flow 16 may not be to the desired extent. If the mixer distance 88 is too long, the reductant spray 44 will have expanded to a larger volume and may impinge on the ring 54 or inner wall 25 before being converted to NH3. This impact may lead to the formation of precipitates as described above.
可采用开口73来帮助减少背压并且还可减轻重量。也可使用开口73来形成还原剂30聚集的流过和排出区域,由此防止沉淀物。Opening 73 may be employed to help reduce back pressure and also reduce weight. The openings 73 can also be used to form flow-through and drain areas where the reducing agent 30 collects, thereby preventing deposits.
中央结构76可帮助使还原剂喷雾44碎化和雾化,由此有助于转化为NH3。中央结构76还可将可帮助转化为NH3的紊流导入排气流16中。中央结构76可以不形成沉淀物,因为它们位于具有高流速和高温度的区域内。中央结构76还可增加混合器26的刚性和结构强度。Central structure 76 may help fragment and atomize reductant spray 44, thereby facilitating conversion to NH3. The central structure 76 may also introduce turbulence into the exhaust flow 16 that may aid conversion to NH 3 . Central structures 76 may not form deposits because they are located in areas with high flow rates and high temperatures. Central structure 76 may also increase the rigidity and structural strength of mixer 26 .
可采用导流板78以除翻滚外还将旋流导入排气流16中以用于另外的混合。在一些实施例中,导流板78可产生反向旋转旋流。与开口73一样,导流板78还可帮助减少背压并且还可减轻重量。也可使用导流板78来形成还原剂30聚集的流过和排出区域,由此防止沉淀物。Baffles 78 may be employed to introduce swirl into the exhaust flow 16 for additional mixing in addition to tumbling. In some embodiments, the baffles 78 can create counter-rotating swirls. Like the opening 73, the baffle 78 can also help reduce back pressure and can also save weight. Baffles 78 may also be used to create flow-through and drain areas where reducing agent 30 collects, thereby preventing deposits.
混合器26也可适合于双支管后处理系统90。双支管后处理系统90常常与较大型的发动机系统联用。双支管后处理系统90可允许使用较小的后处理基底。由于这些基底常常是复杂的陶瓷体,所以它们可采用较小的尺寸更经济地生产。较小的尺寸还可改善包装选择并且改善跨基底面的流动分布。Mixer 26 may also be suitable for dual-leg aftertreatment system 90 . The dual branch aftertreatment system 90 is often used in conjunction with larger engine systems. The dual-leg aftertreatment system 90 may allow the use of smaller aftertreatment substrates. Since these substrates are often complex ceramic bodies, they can be produced more economically in smaller sizes. The smaller size also improves packaging options and improves flow distribution across the substrate.
由于混合器26导入有限的背压,所以它可均匀地结合来自第一和第二进入支管95和96的排气流16。通过混合器26形成的翻滚还可帮助将排气流16流动分隔到第一和第二离开支管91和92中。极大地依赖于旋流和紊流的混合器可形成朝第一和第二离开支管91和92中的任一者的偏流。Since the mixer 26 introduces limited back pressure, it can uniformly combine the exhaust stream 16 from the first and second inlet branches 95 and 96 . The tumbling created by the mixer 26 may also assist in the flow separation of the exhaust stream 16 into the first and second exit legs 91 and 92 . The mixer, which relies heavily on swirl and turbulence, can create a bias flow towards either of the first and second exit branches 91 and 92 .
分隔距离94可影响排气流16流动均匀分隔到第一和第二离开支管91和92中并防止形成沉淀物。Separation distance 94 may effect the flow uniform separation of exhaust gas stream 16 into first and second exit legs 91 and 92 and prevent the formation of deposits.
分隔距离94可影响排气流16流动均匀分隔到第一和第二离开支管91和92中。如果分隔距离94过短,则还原剂30可能没有时间转化成NH3并且来自混合器26的翻滚作用可能大。在分隔区段93前不良转化成NH3可能随着还原剂撞击在壁上而产生沉淀物。大的翻滚可能导致偏向第一和第二离开支管91和92中的一者。如果分隔距离过长,则可能引起双支管后处理系统90的包装困难并且可能导致损失激活SCR催化剂22和防止形成沉淀物所需的热量。The separation distance 94 may affect the flow uniformity of the exhaust stream 16 into the first and second exit legs 91 and 92 . If the separation distance 94 is too short, the reductant 30 may not have time to convert to NH3 and the tumbling effect from the mixer 26 may be large. Poor conversion to NH3 prior to separation section 93 may produce precipitates as the reducing agent impinges on the walls. A large roll may cause a bias towards one of the first and second exit branches 91 and 92 . If the separation distance is too long, it may cause packaging difficulties for the dual-leg aftertreatment system 90 and may result in a loss of heat needed to activate the SCR catalyst 22 and prevent deposit formation.
虽然上文将混合器26描述为协助将还原剂导入排气流,但也可设想,混合器26可用来协助将任何各种物质导入任何各种流动中。尽管如文中所述的本发明的实施例可以合并而不脱离以下权利要求的范围,但对于本领域技术人员而言将显而易见的是,可以作出各种改型和变型。根据说明书和对本发明的实践,其他实施例对本领域技术人员来说将显而易见。应该认为说明书和示例仅为示范性的,本发明的真实范围由以下权利要求和它们的等同方案指明。While mixer 26 is described above as assisting in introducing reductant into the exhaust stream, it is also contemplated that mixer 26 may be used to assist in introducing any of a variety of substances into any of a variety of flows. Although embodiments of the invention as described herein may be combined without departing from the scope of the following claims, it will be apparent to those skilled in the art that various modifications and changes can be made. Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the invention. It is intended that the specification and examples be considered exemplary only, with the true scope of the invention being indicated by the following claims and their equivalents.
Claims (8)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/754,144 US20110239631A1 (en) | 2010-04-05 | 2010-04-05 | Ring Reductant Mixer |
| US12/754,144 | 2010-04-05 | ||
| PCT/US2011/030865 WO2011126930A2 (en) | 2010-04-05 | 2011-04-01 | Ring reductant mixer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102933810A CN102933810A (en) | 2013-02-13 |
| CN102933810B true CN102933810B (en) | 2016-09-28 |
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|---|---|---|---|
| CN201180027335.7A Expired - Fee Related CN102933810B (en) | 2010-04-05 | 2011-04-01 | ring reducer mixer |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20110239631A1 (en) |
| CN (1) | CN102933810B (en) |
| DE (1) | DE112011101199T5 (en) |
| GB (1) | GB2491777A (en) |
| WO (1) | WO2011126930A2 (en) |
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Also Published As
| Publication number | Publication date |
|---|---|
| DE112011101199T5 (en) | 2013-01-24 |
| GB2491777A (en) | 2012-12-12 |
| GB201217708D0 (en) | 2012-11-14 |
| WO2011126930A2 (en) | 2011-10-13 |
| WO2011126930A3 (en) | 2012-04-05 |
| US20110239631A1 (en) | 2011-10-06 |
| CN102933810A (en) | 2013-02-13 |
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