CN102964761A - Resin composition for sandblasting three-dimensional protective film - Google Patents
Resin composition for sandblasting three-dimensional protective film Download PDFInfo
- Publication number
- CN102964761A CN102964761A CN2011102574632A CN201110257463A CN102964761A CN 102964761 A CN102964761 A CN 102964761A CN 2011102574632 A CN2011102574632 A CN 2011102574632A CN 201110257463 A CN201110257463 A CN 201110257463A CN 102964761 A CN102964761 A CN 102964761A
- Authority
- CN
- China
- Prior art keywords
- thixotropic agent
- resin combination
- agent
- protective membrane
- propylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001681 protective effect Effects 0.000 title claims abstract description 16
- 238000005488 sandblasting Methods 0.000 title abstract 3
- 239000011342 resin composition Substances 0.000 title abstract 2
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 28
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 18
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims description 13
- 239000012528 membrane Substances 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- -1 polyoxypropylene methyl ether Polymers 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 235000004443 Ricinus communis Nutrition 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical class CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 3
- 238000000518 rheometry Methods 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 abstract 2
- 125000005250 alkyl acrylate group Chemical group 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000006061 abrasive grain Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses a resin composition for a sandblasting three-dimensional protective film. The composition includes the following components by mass: 100 parts of a propylene (co) polymer; 5-40 parts of a stripping agent; and 0-10 parts of a thixotropic agent. Specifically, the propylene (co) polymer takes thermoplastic alkyl acrylate as the main body, and the glass transition temperature Tg is 20-100DEG C. Even on a 3-dimensional curved surface or body, the composition can be prepared into a sandblasting shielding protective film simply and efficiently rate at any position. The composition can be made into the shielding protective film simply and efficiently.
Description
Technical field
The present invention relates to a kind of sandblast processing solid protective membrane resin combination.
Background technology
Sandblast processing refers to that small-particle (iron particle abrasive grains glass particle other) is clashed into many times, and cut, concavo-convex, reduction, damage etc. appear in the surface of object.According to by kind, the impact strength of the particle that bumped against, be knocked the material at position, the result is various for bump.It is used as various raw-material working method such as propylene, plastics, glass, stone material, timber, metal always.Sandblast processing is the extremely wide technology of range of application, such as grooving, carving literal, frosted processing, perforate, to the processing of timber etc.Carry out sandblast processing, at first form the shielding protection film, process by the hole jet particle.
Summary of the invention
In order to overcome defects, the invention provides a kind of sandblast processing solid protective membrane resin combination, said composition can be simply, high-level efficiency is made the shielding protection film.
The present invention for the technical scheme that solves its technical problem and adopt is: a kind of sandblast processing solid protective membrane resin combination comprises the component of following mass fraction:
Propylene (being total to) polymer: 100 parts;
Stripping agent: 5-40 part;
Thixotropic agent: 0-10 part;
Wherein, described propylene (being total to) polymer is take thermoplastically acrylic acid alkyl fat as main body, and its glass tansition temperature Tg is 20-100 ℃.
As a further improvement on the present invention, the polymeric molecular structural formula of described propylene (being total to) is:
Wherein, R
ABe hydrogen or methyl, RB is fatty group or the alicyclic group of hydrogen or carbon number 1-12.
As a further improvement on the present invention, the polymeric glass tansition temperature of described propylene (being total to) Tg (being tried to achieve by the FOX relational expression) satisfies following relationship:
1/Tg＝Wa/Tga+Wb/Tgb+……
Wherein, Wa, Wb represent respectively the quality percentage composition of the polymeric monomer a of propylene (being total to), b, the glass tansition temperature when Tga, Tgb distinguish described monomer a, b respectively as polymer.
As a further improvement on the present invention, described stripping agent is polyoxypropylene methyl ether.
As a further improvement on the present invention, the described stripping agent stripping intensity adjusting agent that is the shielding protection film.
As a further improvement on the present invention, described thixotropic agent is at least one of fatty acid amide series thixotropic agent, hydrogenated castor oleylamide series thixotropic agent, hydrogenated castor oil series thixotropic agent, the sticking serial thixotropic agent of hydrogenated castor oil, higher fatty acid nitrogen inductor series thixotropic agent and long lock fatty acid ester polymer series thixotropic agent.
As a further improvement on the present invention, described thixotropic agent can freely be adjusted printability by rheology control.
Said composition the invention has the beneficial effects as follows: even also can be made in position arbitrarily the shielding protection film of sandblast processing usefulness simply efficiently on 3 dimension curved surfaces, solid.
Embodiment
The solid protective membrane resin combination is processed in a kind of sandblast, comprises the component of following mass fraction:
Propylene (being total to) polymer: 100 parts;
Stripping agent: 5-40 part;
Thixotropic agent: 0-10 part;
Wherein, described propylene (being total to) polymer is take thermoplastically acrylic acid alkyl fat as main body, and its glass tansition temperature Tg is 20-100 ℃.
The polymeric molecular structural formula of aforesaid propylene (being total to) is:
Wherein, R
ABe hydrogen or methyl, RB is fatty group or the alicyclic group of hydrogen or carbon number 1-12.
The polymeric glass tansition temperature of aforesaid propylene (being total to) Tg (being tried to achieve by the FOX relational expression) satisfies following relationship:
1/Tg＝Wa/Tga+Wb/Tgb+……
Wherein, Wa, Wb represent respectively the quality percentage composition of the polymeric monomer a of propylene (being total to), b, the glass tansition temperature when Tga, Tgb distinguish described monomer a, b respectively as polymer.
Above-mentioned stripping agent is polyoxypropylene methyl ether.
The stripping intensity adjusting agent that above-mentioned stripping agent is the shielding protection film.
Above-mentioned thixotropic agent is at least one of fatty acid amide series thixotropic agent, hydrogenated castor oleylamide series thixotropic agent, hydrogenated castor oil series thixotropic agent, the sticking serial thixotropic agent of hydrogenated castor oil, higher fatty acid nitrogen inductor series thixotropic agent and long lock fatty acid ester polymer series thixotropic agent.
Above-mentioned thixotropic agent can freely be adjusted printability by rheology control.
Claims (7)
1. the solid protective membrane resin combination is processed in a sandblast, it is characterized in that it comprises the component of following mass fraction:
Propylene (being total to) polymer: 100 parts;
Stripping agent: 5-40 part;
Thixotropic agent: 0-10 part;
Wherein, described propylene (being total to) polymer is take thermoplastically acrylic acid alkyl fat as main body, and its glass tansition temperature Tg is 20-100 ℃.
2. the solid protective membrane resin combination is processed in sandblast according to claim 1, and it is characterized in that: the polymeric molecular structural formula of described propylene (being total to) is:
Wherein, R
ABe hydrogen or methyl, RB is fatty group or the alicyclic group of hydrogen or carbon number 1-12.
3. the solid protective membrane resin combination is processed in sandblast according to claim 1, and it is characterized in that: the polymeric glass tansition temperature of described propylene (being total to) Tg satisfies following relationship:
1/Tg＝Wa/Tga+Wb/Tgb+……
Wherein, Wa, Wb represent respectively the quality percentage composition of the polymeric monomer a of propylene (being total to), b, the glass tansition temperature when Tga, Tgb distinguish described monomer a, b respectively as polymer.
4. the solid protective membrane resin combination is processed in sandblast according to claim 1, and it is characterized in that: described stripping agent is polyoxypropylene methyl ether.
5. sandblast processing solid protective membrane resin combination according to claim 1 is characterized in that: the stripping intensity adjusting agent that described stripping agent is the shielding protection film.
6. the solid protective membrane resin combination is processed in sandblast according to claim 1, it is characterized in that: described thixotropic agent is at least one of fatty acid amide series thixotropic agent, hydrogenated castor oleylamide series thixotropic agent, hydrogenated castor oil series thixotropic agent, the sticking serial thixotropic agent of hydrogenated castor oil, the serial thixotropic agent of higher fatty acid nitrogen inductor and long lock fatty acid ester polymer series thixotropic agent.
7. the solid protective membrane resin combination is processed in sandblast according to claim 1, and it is characterized in that: described thixotropic agent can freely be adjusted printability by rheology control.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102574632A CN102964761A (en) | 2011-09-02 | 2011-09-02 | Resin composition for sandblasting three-dimensional protective film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102574632A CN102964761A (en) | 2011-09-02 | 2011-09-02 | Resin composition for sandblasting three-dimensional protective film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102964761A true CN102964761A (en) | 2013-03-13 |
Family
ID=47795212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102574632A Pending CN102964761A (en) | 2011-09-02 | 2011-09-02 | Resin composition for sandblasting three-dimensional protective film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102964761A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104945808A (en) * | 2015-07-16 | 2015-09-30 | 田菱精密制版（深圳）有限公司 | Cover oil resin combination used for hydrographics transfer printing |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1140843A (en) * | 1995-05-01 | 1997-01-22 | 松下电子工业株式会社 | Photosensitive resin composition for sandblast resist |
| US5676983A (en) * | 1992-06-16 | 1997-10-14 | Kernforschungszentrum Karlsruhe Gmbh | Tool for making a microstructured plastic mold |
| CN1353140A (en) * | 2000-11-07 | 2002-06-12 | 东京応化工业株式会社 | Photosensitive composition used in sand milling and photosensitive membrane using said composition |
| JP2002287349A (en) * | 2001-03-26 | 2002-10-03 | Mitsubishi Rayon Co Ltd | Sandblast-resistant photosensitive resin composition capable of visible exposure, dry film using the same, and method for cutting an object using the same |
| CN1678957A (en) * | 2002-09-03 | 2005-10-05 | 可隆株式会社 | Photopolymerizable resin composition for sandblasting protective layer |
| CN1690853A (en) * | 2004-04-26 | 2005-11-02 | 东京応化工业株式会社 | Photosensitive resin composition and photosensitive dry film containing the same |
| CN1800980A (en) * | 2006-01-11 | 2006-07-12 | 彩虹集团电子股份有限公司 | Sandblast resistant durable emulsion type photosensitive resin |
-
2011
- 2011-09-02 CN CN2011102574632A patent/CN102964761A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5676983A (en) * | 1992-06-16 | 1997-10-14 | Kernforschungszentrum Karlsruhe Gmbh | Tool for making a microstructured plastic mold |
| CN1140843A (en) * | 1995-05-01 | 1997-01-22 | 松下电子工业株式会社 | Photosensitive resin composition for sandblast resist |
| CN1353140A (en) * | 2000-11-07 | 2002-06-12 | 东京応化工业株式会社 | Photosensitive composition used in sand milling and photosensitive membrane using said composition |
| JP2002287349A (en) * | 2001-03-26 | 2002-10-03 | Mitsubishi Rayon Co Ltd | Sandblast-resistant photosensitive resin composition capable of visible exposure, dry film using the same, and method for cutting an object using the same |
| CN1678957A (en) * | 2002-09-03 | 2005-10-05 | 可隆株式会社 | Photopolymerizable resin composition for sandblasting protective layer |
| CN1690853A (en) * | 2004-04-26 | 2005-11-02 | 东京応化工业株式会社 | Photosensitive resin composition and photosensitive dry film containing the same |
| CN1800980A (en) * | 2006-01-11 | 2006-07-12 | 彩虹集团电子股份有限公司 | Sandblast resistant durable emulsion type photosensitive resin |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104945808A (en) * | 2015-07-16 | 2015-09-30 | 田菱精密制版（深圳）有限公司 | Cover oil resin combination used for hydrographics transfer printing |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130313 |