CN102991073B - Polyolefin composite modified asphalt wet paving waterproof roll and production method thereof - Google Patents
Polyolefin composite modified asphalt wet paving waterproof roll and production method thereof Download PDFInfo
- Publication number
- CN102991073B CN102991073B CN201210546765.6A CN201210546765A CN102991073B CN 102991073 B CN102991073 B CN 102991073B CN 201210546765 A CN201210546765 A CN 201210546765A CN 102991073 B CN102991073 B CN 102991073B
- Authority
- CN
- China
- Prior art keywords
- waterproof roll
- thermoplastic elastomer
- polyolefin
- elastomer material
- concrete
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 51
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 31
- 239000010426 asphalt Substances 0.000 title claims abstract description 22
- 239000002131 composite material Substances 0.000 title claims abstract description 17
- 238000005096 rolling process Methods 0.000 title claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 77
- 239000010410 layer Substances 0.000 claims abstract description 64
- 239000004567 concrete Substances 0.000 claims abstract description 41
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 35
- 238000006243 chemical reaction Methods 0.000 claims abstract description 30
- 239000011241 protective layer Substances 0.000 claims abstract description 30
- 230000004888 barrier function Effects 0.000 claims abstract description 27
- 239000000126 substance Substances 0.000 claims abstract description 27
- 239000011229 interlayer Substances 0.000 claims abstract description 12
- 238000007906 compression Methods 0.000 claims abstract description 9
- 238000005520 cutting process Methods 0.000 claims abstract description 7
- -1 octyl ester Chemical class 0.000 claims description 33
- 239000003963 antioxidant agent Substances 0.000 claims description 18
- 230000003078 antioxidant effect Effects 0.000 claims description 18
- 239000004902 Softening Agent Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 15
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 11
- 239000003921 oil Substances 0.000 claims description 11
- 235000019198 oils Nutrition 0.000 claims description 11
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
- 239000007822 coupling agent Substances 0.000 claims description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 239000011787 zinc oxide Substances 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 238000004513 sizing Methods 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 5
- 239000012847 fine chemical Substances 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 230000001404 mediated effect Effects 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 235000012424 soybean oil Nutrition 0.000 claims description 5
- 239000003549 soybean oil Substances 0.000 claims description 5
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims 1
- 230000000630 rising effect Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 23
- 239000004568 cement Substances 0.000 abstract description 17
- 238000000034 method Methods 0.000 abstract description 17
- 230000002427 irreversible effect Effects 0.000 abstract description 10
- 239000008280 blood Substances 0.000 abstract description 7
- 210000004369 blood Anatomy 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 230000002045 lasting effect Effects 0.000 abstract description 4
- 239000011148 porous material Substances 0.000 abstract description 4
- 230000009257 reactivity Effects 0.000 abstract 1
- 238000005496 tempering Methods 0.000 abstract 1
- 238000010276 construction Methods 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 8
- 229920002397 thermoplastic olefin Polymers 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 7
- 238000010382 chemical cross-linking Methods 0.000 description 7
- 239000003292 glue Substances 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000011247 coating layer Substances 0.000 description 5
- 239000004745 nonwoven fabric Substances 0.000 description 5
- 238000004078 waterproofing Methods 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 238000001363 water suppression through gradient tailored excitation Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000011280 coal tar Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001343 alkyl silanes Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000005465 channeling Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229940086555 cyclomethicone Drugs 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000010406 interfacial reaction Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- VHUCVIFTAJKQRR-UHFFFAOYSA-N propan-1-amine trimethoxysilane Chemical compound CO[SiH](OC)OC.C(CC)N VHUCVIFTAJKQRR-UHFFFAOYSA-N 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011382 roller-compacted concrete Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 230000036555 skin type Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- CMXPERZAMAQXSF-UHFFFAOYSA-M sodium;1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate;1,8-dihydroxyanthracene-9,10-dione Chemical compound [Na+].O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=CC=C2O.CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC CMXPERZAMAQXSF-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000005737 synergistic response Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
- Laminated Bodies (AREA)
Abstract
A kind of polyolefin (TPO) composite modified asphalt wet paving waterproof roll and production method thereof; comprise can with concrete jointly rise chemical crosslink reaction and physics mortise and tenon work in coordination with cementation modified pitch tack coat, bond barrier film protective layer and polyolefin thermoplastic elastomer material layer; its interlayer structure is as follows: ground floor is polyolefin thermoplastic elastomer material layer, intermediate layer is modified pitch tack coat, cutting optimal is barrier film protective layer, and each interlayer is by thermo-compression bonding in production process.The water resistance of this waterproof roll is excellent, it is wriggled by the modified pitch with reactivity and penetrates into cement gel and concrete pore in cement, concrete setting process, and there is chemical crosslink reaction in the interface of contact, formed have cohesive force large, bond irreversible, bond the basal plane conversion zone of tempering toughness with gentleness, boning lasting, reach in conjunction with tight, firm, irreversible as closely linked as flesh and blood bond effect.
Description
Technical field
The present invention relates to a kind of architectural waterproof material, particularly a kind ofly can play the reaction bonded type polyolefin composite waterproof roll of chemical crosslink reaction with concrete.
Background technology
At present, tunnel in communications and transportation, subway basement and for shed deckhead, civil air defense constructions and installations, dykes and dams culverts and water gates, the water proof anti-seepage construction work of all kinds of pond and storied building top surface etc. gets more and more, in order to material mainly coating and various sheet material or the coiled material of waterproof, along with the appearance of the macromolecular sheet material of asphalt water-proof coiled material or fabric layer, because it can factorial praluction, easy to use, the favor being more and more subject to people is applied in construction, particularly building top layer terrace, the construction of subway terrace and dykes and dams culverts and water gates end face, modified bituminous pitch coiled material is directly pasted concrete surface with the one side of adhesive, reach the object of waterproof.Open source literature also discloses the technology of some this respects, such as:
1. Chinese patent: be compounded with tyre water-proof coiled material and adhesive, application number: CN94110918.6, the applying date: 1994.04.04, publication number: CN1110301, publication date: 1995.10.18, applicant: Zhang Guoming, address: No. 18, balcony mountain villa, balcony road, zhuzhou, hunan province city, inventor: Zhang Guoming, summary: be compounded with tyre water-proof coiled material and adhesive is architectural waterproof material, described waterproof roll and adhesive all with thermoplastic rubber and haloflex, polychloroethylene blended after mixed resin, then add appropriate coal tar and inserts, auxiliary material are made.In the proportioning of described coiled material, mixed resin accounts for 25 ~ 35%, and coal tar accounts for 35 ~ 40%, and inserts accounts for 25 ~ 30%, and auxiliary material accounts for 5%, and in described viscose glue, mixed resin accounts for 10 ~ 15%, and coal tar accounts for 50 ~ 55%, and inserts accounts for 25 ~ 30%, and auxiliary material accounts for 5 ~ 10%.Polyvinyl chloride used is new and old not to be limit, and inserts used is talcum powder, red mud, charcoal acid calcium or flyash; Describedly be compounded with tyre water-proof coiled material, be carcass with fabrics such as glass, jute, non-woven fabrics, make through extruding compound technology.
2. Chinese patent: waterproof construction and manufacture method thereof, application number: CN200810112011.3, the applying date: 2008.05.20, publication number: CN101586381, publication date: 2009.11.25, applicant: Beijing Shinjuker Polymer Materials Co., Ltd.; Yu Jianping, address: room, No. 3 No. 3 building 1111, Xijing Road ,Badachu New & High Technology Industry Development Park District ,Shijingshan District ,Beijing City, inventor: Yu Jianping, summary: this invention is about a kind of waterproof construction and manufacture method thereof.The waterproof of this waterproof construction detail treatment on roofing, comprises waterproof roll layer, and waterproof coating layer, is arranged on detail treatment position, and overlaps bonding mutually with above-mentioned waterproof roll layer.Can comprise material in described waterproof coating layer is polyester or nylon nonwoven fabrics or woven fabric enhancement Layer.The material of this waterproof coating layer is exposed type polyurea waterproof coating material or its modified water-proof coating, exposed type polyurethane water-proof paint or its modified water-proof coating, exposed type polymethyl methacrylate class water-repellent paint and modified water-proof coating thereof or exposed type polystyrene-ethylene-butadiene-styrene or its modified water-proof coating.Waterproof construction of the present invention due to the cohesive force of waterproof coating layer large, tensile resistance is strong, and higher elasticity, when running into strong wind weather or other reasons and causing roofing detail treatment position distortions, waterproof coating layer can not be destroyed, and still has excellent waterproof effect.
2. Chinese patent: Multi-layer high-molecular water-proof rolled, application number: 00245890, the applying date: 2000.08.15, notification number: CN2442835, applicant: Zhang Shoubin, address: Qinhuangdao, Hebei province, summary: a kind of Multi-layer high-molecular water-proof rolled, its cross section is at least four layers of structure, from top to bottom be followed successively by: filament polypropylene fibre non-woven fabric upper surface protective layer, EVA resin modified polyethylene waterproof enhancement layer, polypropylene waterproof membrane lamella, filament polypropylene fibre non-woven fabric lower surface protective layer; The filament polypropylene fibre non-woven fabric material outer surface on its upper and lower surface has groove and the projection of stereo grid shaped rectangle and/or rhombus.
But, the present inventor finds, above patent and present seen waterproof roll are on the market mainly modified asphalt waterproof coiled material, macromolecular sheet material, its construction method is mainly with hot pressing construction or be coated with oil, macromolecule glue bonding at the bottom of oiliness pool cream, oiliness, there is highly energy-consuming, danger, environmental pollution is large, moisture substrate construction bonding is insecure; With the waterproof roll that polyvinyl alcohol latex cement adhesive and other polymer latex cement bond, they are moistening by cement slurry and form physical absorption and certain mortise and tenon effect between basal plane and be bonded on basal plane, as easy as rolling off a logly to affect by factors such as environment moisture and hot ageing, steam expansion, base layer motion, thus cohesive force is declined, produce the process of desorption and de-mortise and tenon, lose permanent seal waterproof effect.
Summary of the invention
The object of the invention is the deficiency in order to overcome background technology, avoid common overlaying, wet paving waterproof roll Problems existing, present inventors studied a kind of bonding technology, by the double action of chemical crosslink reaction and physics mortise and tenon, waterproof roll and basic unit are reached in conjunction with tight, firm, irreversible as closely linked as flesh and blood bond effect.
The patent of these parties concerned had once been applied for, application number: 200910114456.X title: carry out with concrete the waterproof roll open (bulletin) number that bonding worked in coordination with by chemical crosslinking and physics mortise and tenon: CN101694114A Main classification number: E04B1/66 (2006.01) I applies for (patent right) people: Guangxi Jiyusan Waterproof Decoration Co., Ltd. address: (design) people is invented in No. 267-1, WangZhou Road, Nanning City, Guangxi Zhuang Autonomous nationality District: Lu Guicai before the present inventor, Wu Shengjiang, Zhu Fangwu, Guo Wenxiong, summary: a kind of wet paving overlays waterproof roll, that modified pitch compound is carried out dip-coating on carcass, control thick sizing, overlay film, the techniques such as rolling are made, described modified pitch compound is modified pitch, plasticizer, antioxidant, functional aid and filler, matrix pitch is placed in retort by preparation method, add tackifier, random polyethylene and SBS, be mixed evenly, heat up, stir 1.5-2h, then temperature is dropped to about 180 DEG C, again by filler, plasticizer, antioxidant, function additive is added to retort, stir 0.5-1h, carry out fully mixed and modified, then colloid mill is transported to, material is ground repeatedly, again pitch good for modification is carried out dip-coating on carcass, control thick sizing, overlay film, rolling, just be prepared into excellent performance carry out chemical crosslinking with concrete and physics mortise and tenon is collaborative bonds.
Application number: 201010513849.0 titles: one side glues wet paving waterproof roll and to wet the construction method open (bulletin) number of paving edge fit: CN102002983A Main classification number: E04B1/66 (2006.01) I applies for (patent right) people: Lu Gui just address: (design) people: Lu Guicai invents in WangZhou Road, Nanning City, Guangxi Zhuang Autonomous nationality District 267-1 Guangxi Jiyusan Waterproof Decoration Co., Ltd.; Wu Shengjiang; Zhu Fangwu; Guo Wenxiong, summary, one side glues wet paving waterproof roll and to wet the construction method of paving edge fit, one is stayed edge fit place in advance when producing one side and gluing wet paving waterproof roll, there are enhancing film, reaction viscose glue or self-adhesive and isolation protection film in edge fit place, when wet paving waterproof roll edge fit, the isolation protection film that edge fit place covers is torn, directly carry out wet paving edge fit; Two is do not staying the one side at edge fit place to glue wet paving waterproof roll edge fit place first dry wet paving waterproof roll or the tacky on two sides spreading width 60-100mm in advance, then carries out wet paving edge fit, and cross section is superimposed by viscose glue, forms large-area waterproof roll layer.The method is strictly pasted due to joint, and covers with concrete layer and react sticky sealant layer generation chemical crosslink reaction, reaches in conjunction with tight, firm, irreversible as closely linked as flesh and blood bond effect.Be applicable to being applied to the construction that roofing and underground waterproof engineering one side glue wet paving waterproof roll edge fit.
Application number: the 201110122795.X applying date: 2011.05.13 title: the preparation of SBS modified asphalt and waterproofing membrane production method open (bulletin) number: CN102220023A open (bulletin) day: 2011.10.19 Main classification number: C08L95/00 (2006.01) I applies for (patent right) people: Guangxi Jiyusan Waterproof Decoration Co., Ltd. address: No. 267-1, Wang Zhou road, Xingning District, Guangxi Zhuang Autonomous Region Nanning City invention (design) people: Lu Guicai, summary, a kind of SBS modified asphalt, by pitch, swelling star-shaped sbs, the composition that filler and auxiliary agent are made, the problem of star-shaped sbs as asphalt modifier difficult processing can be solved, production method is: the star-shaped sbs swelling with non-polar solven is joined pitch, in filler and auxiliary agent, by modification 50 ~ 150min under colloid mill or powerful high shear agitation device under the condition of 180 ~ 210 DEG C, then filler is added and auxiliary agent stirs, obtain uniform and stable modified pitch, this modified pitch can make the waterproof roll of excellent performance, also building roof can be made, basement, highway, sealing compound, tunnel or water conservancy projects waterproof glue-leakage-resistant, it has with pitch better compatible than existing SBS modified pitch, high and low temperature resistance is more excellent.
The present inventor's foregoing invention cover with concrete layer the waterproof roll reacting sticky sealant layer generation chemical crosslink reaction, start the new road in waterproof technique field, after being applied to the waterproofing works such as building top layer terrace, subway terrace and dykes and dams culverts and water gates end face, pond, achieve obvious effect, be described as waterproof high-end technology.And different products has different purposes, the present inventor is through constantly research, and being proposed again several new product, is below one of them:
Technical scheme of the present invention is achieved in that
Polyolefin composite modified asphalt wet paving waterproof roll; comprise can with concrete jointly rise chemical crosslink reaction and physics mortise and tenon work in coordination with cementation modified pitch tack coat, bond barrier film protective layer and polyolefin thermoplastic elastomer material layer; its interlayer structure is as follows: ground floor is polyolefin thermoplastic elastomer material layer, intermediate layer is modified pitch tack coat, cutting optimal is barrier film protective layer, and each interlayer is by thermo-compression bonding in production process.
Above-described polyolefin thermoplastic elastomer material layer thickness is 0.4 ~ 2.0mm, is set to one deck.
Above-described barrier film protective layer is polyethylene, polyvinyl chloride or polyester, and the thickness of barrier film protective layer is 0.02 ~ 0.05mm, is set to one deck.
Above-described polyolefin thermoplastic elastomer material layer, (TPO waterproof roll layer) is made again to be for base-material with Petropols and ethene, acetic acid, vinyl, add antioxidant, new type waterproof coiled material that age resistor, softening agent are made, inner reinforcing material can be done with polyester fiber grid cloth and make enhancement type water-proof coiled material, belong to synthetic polymeric waterproofing material class waterproof product.
In polyolefin thermoplastic elastomer material layer, be made up of the raw material of following portions by weight: copolymer 50-80 part, antioxidant 1.5-2.5 part, age resistor 1.0-2.0 part, softening agent 1-3 part, inserts 20-30; Its preparation method is: copolymer, antioxidant, age resistor, softening agent and inserts are mediated through 120 DEG C of-210 DEG C of banburyings and obtain.
Described copolymer comprises ethene and octene copolymer or polypropylene and ethylene propylene diene rubber copolymer;
Described antioxidant is the HS-362 that Beijing Big Dipper auxiliary agent Co., Ltd produces, NOR371(http: the //lfmjtszhuljccohx.shop.shangjia.cn/ of (No. 6, http://bjtgzj.china.b2b.cn/ South Sanhuan East Road, Fengtai District, Beijing City JiaYe Building) Ciba fine chemicals production) and Beijing Hua Teng engineered new materials Co., Ltd (http://www.hthitech.com/, Huatengkeji Building, No. 123, Avenue North, Zhongguancun, Haidian District, Beijing City) AOD, described age resistor is 2, 6-di-tert-butyl-4-methy phenol, described softening agent is epoxidized soybean oil and octyl ester of epoxy fatty acid, described inserts is zinc oxide, magnesia, a kind of or their mixture in dicalcium powder and talcum powder.
Above-describedly can jointly play chemical crosslink reaction and physics mortise and tenon with concrete and work in coordination with the composition of the modified pitch tack coat of cementation and parts by weight are: pitch 40-60 part, two wires oil 5-10 part, functional aid 0.5-5 part, filler 20-50 part.
Described pitch is the dregs of fat after petrochemical production process refining.
Described two wires oil is that petrochemical production process produces the slightly secondary nonstandard oil of next quality.
Described inserts is a kind of in zinc oxide, magnesia, dicalcium powder and talcum powder or their mixture.
Described functional aid has hydroxyl, the coupling agent of amino or carboxyl, particularly there is hydroxyl, the polysiloxane coupling agent of amino or carboxyl-reactive functional group, poly-naphthalene formaldehyde sulfonate salt or their mixture, polysiloxane coupling agent comprises: hydroxyl alkyl polysiloxanes, carboxyl polysiloxanes, the derivative of dimethyl siloxane or cyclomethicone, as poly-methylethoxy base silane, fatty acid amide alkyl silane, carboxyl polysiloxanes or 3-aminopropan trimethoxy silane or they two kinds, two or more mixtures, hydroxyl in them, amino or carboxyl can play the cooperative effect (ChemicalBondingandPhysicalCrosslinkingSynergism of chemical crosslinking-physics fourth of the twelve Earthly Branches camphor tree with cement or concrete, be called for short CPS) additive (background technology mention the present inventor application Chinese patent: Application Number (patent): CN2009lO114456.X, title: carry out the waterproof roll that chemical crosslinking and physics fourth of the twelve Earthly Branches camphor tree work in coordination with bonding with concrete, open (bulletin) number: CNlOl694114A.
Above-described polyolefin composite modified asphalt wets and spreads the production method of waterproof roll, first can jointly play chemical crosslink reaction and physics mortise and tenon with concrete to work in coordination with the modified pitch tack coat of cementation and polyolefin thermoplastic elastomer material layer is carried out, modified pitch compound is carried out on TPO sheet material apply, the condition thermo-compression bonding of 150-180 DEG C, control the techniques such as thick sizing, overlay film, rolling and make.
The present invention compared with prior art has following outstanding feature:
1. this polyolefin composite modified asphalt wet paving waterproof roll take polyolefin thermoplastic elastomer material as base material compression molding, there is excellent elasticity, oil resistivity and flexible resistance, particularly elasticity is the most outstanding, and it is nontoxic, safety and environmental protection, pollution-free, especially adapt to the construction being used for the waterproofing works such as building top layer terrace, subway terrace and dykes and dams culverts and water gates end face, pond.
2. good weatherability.Waterproof roll has ultraviolet aging resistance to polyolefin composite modified asphalt of the present invention wet paving, hot strength is high; large, the moist roofing of percentage elongation can be constructed, expose need not protective layer, easy construction, the Comprehensive Characteristics such as pollution-free, be very suitable for the watertight composition as exposing light energy-saving roofing.
2. cohesive force is large.The present invention be a kind of can play that chemical crosslink reaction and physics mortise and tenon synergistic response type modified pitch tack coat and rubber sheet lamination close with concrete overlay, wetly spread waterproof roll, the response type modified pitch tack coat of this coiled material can be wriggled and be penetrated in cement gel and concrete pore in the process of cement, concrete setting, concurrent biochemical cross-linking reaction formed have cohesive force larger, bond irreversible, bonding is tempered toughness with gentleness, bond more lasting interfacial reaction layer, reach in conjunction with tight, firm, irreversible as closely linked as flesh and blood bond effect.Its cohesive force is large, not only has physical absorption and mortise and tenon effect, and produces chemical bonding effect at the mortise and tenon position of going down to the grass-roots units, and two kinds of effects of mortise and tenon and chemical crosslinking is worked in coordination with and carries out, make bonding more firm.Even if coiled material top layer is destroyed, also can not be impaired and produce channeling water drainage with the interface of bonding basic unit.
3. bonding is irreversible.Because region of interest exists chemical bond, this bonding is irreversible, wants to take away or peel off watertight composition, is difficult to accomplish, except non-demolition coiled material, shovel rolls out the interface that material and basic unit bond.
4. bonding is tempered toughness with gentleness.Form flexible adhesion by physical absorption and mortise and tenon effect, to eliminate the stress because basic unit's change produces, and by the rigid bond that chemical bond produces, make boundary layer have enough adhesion strengths, be highly resistant to the destruction of extraneous stress.
5. bonding is lasting.Under the effect that physical absorption and mortise and tenon often expand with heat and contract with cold at solvent, steam or basal plane, produce the process of desorption and de-mortise and tenon, thus cohesive force is declined, lose the waterproof effect of permanent closure.Owing to there is chemical bonding effect at mortise and tenon position, do not affect by moisture and hot ageing, steam expansion, base layer motion, and produce adhesiving effect enduringly, make the waterproof life-span of coiled material identical with body layer.
Accompanying drawing explanation
Below in conjunction with accompanying drawing, enforcement structure of the present invention is described.
Fig. 1 is that polyolefin composite modified asphalt wets the schematic diagram of paving waterproof roll cross-section structure.
Description of reference numerals:
1. polyolefin thermoplastic elastomer material layer, 2 response type modified pitch tack coats, 3. barrier film protective layer.
Detailed description of the invention
Find out from accompanying drawing; polyolefin composite modified asphalt wet paving waterproof roll is by modified pitch tack coat (2), bonding barrier film protective layer (3) and polyolefin thermoplastic elastomer material layer (1); its interlayer structure is as follows: ground floor is polyolefin thermoplastic elastomer material layer (1), intermediate layer is modified pitch tack coat (2), cutting optimal is barrier film protective layer (3), and each interlayer is by thermo-compression bonding in production process.
Adhesive theory:
This reaction bonded type is rubber water-proofing coiled owing to adding modifier in modified asphalt layer, CPS is called for short) by the synergy (ChemicalBondingandPhysicalCrosslinkingSynergism) of chemical crosslinking and physics mortise and tenon, coiled material is wriggled in cement, concrete setting process and penetrates into cement gel and concrete pore, form netted mortise and tenon, and with cement related compounds generation chemical reaction, form chemical crosslinking effect, play CPS effect, coiled material and concrete is made to reach the bond effect that as closely linked as flesh and blood, it is with the process of concrete binding, not only there is the creep crack resistance of self-adhesive coiled material, self-healing, wet caking property, the performance of anti-channeling water-based, more highlight its unique advantage in concrete interface bonding, it forms " IPN grid type " interfacial structure between waterproof roll and concrete, thus reach combination closely, firmly, irreversible as closely linked as flesh and blood bond effect, thoroughly solve modified bituminous pitch coiled material and basal plane cohesive force is large not, cohesive force is not lasting, problem easily affected by environment, achieve coiled material and basal plane formed bond irreversible, the Waterproof structural course of not impaired integral type, " skin-type " waterproof idea is made to obtain perfect realization.
Detailed description of the invention
Be described below in conjunction with embodiment.
Embodiment 1
Produce a kind of polyolefin composite modified asphalt wet paving waterproof roll, comprise and can jointly play with concrete the modified pitch tack coat (2) that cementation worked in coordination with by chemical crosslink reaction and physics mortise and tenon, bonding barrier film protective layer (3), with polyolefin thermoplastic elastomer material layer (1), its interlayer structure is as follows: ground floor is polyolefin thermoplastic elastomer material layer (1), intermediate layer is modified pitch tack coat (2), cutting optimal is barrier film protective layer (3), production method first can jointly play chemical crosslink reaction and physics mortise and tenon with concrete to work in coordination with the modified pitch tack coat of cementation and polyolefin thermoplastic elastomer material layer is carried out, modified pitch compound is applied on TPO sheet material, the condition thermo-compression bonding of 150-180 DEG C, control thick sizing, overlay film, the techniques such as rolling are made.
Wherein the raw material of the parts by weight of polyolefin thermoplastic elastomer material layer (1) is made: ethene and octene copolymer 50 parts, 1.5 parts, antioxidant, 1.0 parts, age resistor, softening agent 1 part, inserts 20; Its preparation method is: ethene and octene copolymer, antioxidant, age resistor, softening agent and inserts mediated through 120 DEG C of-210 DEG C of banburyings and obtain; Polyolefin thermoplastic elastomer material layer (1) thickness is 0.4 ~ 2.0mm;
Described antioxidant is HS-362, the NOR371 of Ciba fine chemicals's production and the AOD of Beijing Hua Teng engineered new materials Co., Ltd that Beijing Big Dipper auxiliary agent Co., Ltd produces; Described age resistor is 2,6-di-tert-butyl-4-methy phenol; Described softening agent is epoxidized soybean oil and octyl ester of epoxy fatty acid; Described inserts is dicalcium powder and talcous mixture.
Described barrier film protective layer is polyethylene, polyvinyl chloride or polyester, and the thickness of barrier film protective layer is 0.02 ~ 0.05mm, is set to one deck.
Described can chemical crosslink reaction and physics mortise and tenon work in coordination with the composition of the modified pitch tack coat of cementation and parts by weight are: two wires oil 5 parts, poly-20 parts, naphthalene formaldehyde sulfonate salt 0.5 part, filler dicalcium powder or the zinc oxide of functional aid amino that pitch 40 parts, petrochemical production process are produced jointly with concrete.
Embodiment 2
Produce a kind of polyolefin composite modified asphalt wet paving waterproof roll, comprise and can jointly play with concrete the modified pitch tack coat (2) that cementation worked in coordination with by chemical crosslink reaction and physics mortise and tenon, bonding barrier film protective layer (3), with polyolefin thermoplastic elastomer material layer (1), its interlayer structure is as follows: ground floor is polyolefin thermoplastic elastomer material layer (1), intermediate layer is modified pitch tack coat (2), cutting optimal is barrier film protective layer (3), production method first can jointly play chemical crosslink reaction and physics mortise and tenon with concrete to work in coordination with the modified pitch tack coat of cementation and polyolefin thermoplastic elastomer material layer is carried out, modified pitch compound is applied on TPO sheet material, the condition thermo-compression bonding of 150-180 DEG C, control thick sizing, overlay film, the techniques such as rolling are made.
Wherein the raw material of the parts by weight of polyolefin thermoplastic elastomer material layer (1) is made: polypropylene and ethylene propylene diene rubber copolymer 80 parts, 2.5 parts, antioxidant, 2.0 parts, age resistor, softening agent 3 parts, inserts 30; Its preparation method is: polypropylene and ethylene propylene diene rubber copolymer, antioxidant, age resistor, softening agent and inserts mediated through 120 DEG C of-210 DEG C of banburyings and obtain; Polyolefin thermoplastic elastomer material layer (1) thickness is 0.4 ~ 2.0mm;
Described antioxidant is HS-362, the NOR371 of Ciba fine chemicals's production and the AOD of Beijing Hua Teng engineered new materials Co., Ltd that Beijing Big Dipper auxiliary agent Co., Ltd produces; Described age resistor is 2,6-di-tert-butyl-4-methy phenol; Described softening agent is epoxidized soybean oil and octyl ester of epoxy fatty acid; Described inserts is zinc oxide or talcum powder.
Described barrier film protective layer is polyethylene, polyvinyl chloride or polyester, and the thickness of barrier film protective layer is 0.02 ~ 0.05mm, is set to one deck.
Described can chemical crosslink reaction and physics mortise and tenon work in coordination with the composition of the modified pitch tack coat of cementation and parts by weight are: two wires oil 10 parts, functional aid carboxyl polysiloxane coupling agent 5 parts, filler magnesia, dicalcium powder or talcum powder 50 parts that pitch 60 parts, petrochemical production process are produced jointly with concrete.
Embodiment 3
Produce a kind of polyolefin composite modified asphalt wet paving waterproof roll, comprise and can jointly play with concrete the modified pitch tack coat (2) that cementation worked in coordination with by chemical crosslink reaction and physics mortise and tenon, bonding barrier film protective layer (3), with polyolefin thermoplastic elastomer material layer (1), its interlayer structure is as follows: ground floor is polyolefin thermoplastic elastomer material layer (1), intermediate layer is modified pitch tack coat (2), cutting optimal is barrier film protective layer (3), production method first can jointly play chemical crosslink reaction and physics mortise and tenon with concrete to work in coordination with the modified pitch tack coat of cementation and polyolefin thermoplastic elastomer material layer is carried out, modified pitch compound is applied on TPO sheet material, the condition thermo-compression bonding of 150-180 DEG C, control thick sizing, overlay film, the techniques such as rolling are made.
Wherein the raw material of the parts by weight of polyolefin thermoplastic elastomer material layer (1) is made: ethene and octene copolymer 60 parts, 1.5 parts, antioxidant, 1.0 parts, age resistor, softening agent 2 parts, inserts 20; Its preparation method is: ethene and octene copolymer, antioxidant, age resistor, softening agent and inserts mediated through 120 DEG C of-210 DEG C of banburyings and obtain; Polyolefin thermoplastic elastomer material layer (1) thickness is 0.4 ~ 2.0mm;
Described antioxidant is HS-362, the NOR371 of Ciba fine chemicals's production and the AOD of Beijing Hua Teng engineered new materials Co., Ltd that Beijing Big Dipper auxiliary agent Co., Ltd produces; Described age resistor is 2,6-di-tert-butyl-4-methy phenol; Described softening agent is epoxidized soybean oil and octyl ester of epoxy fatty acid; Described inserts is zinc oxide and magnesia.
Described barrier film protective layer is polyethylene, polyvinyl chloride or polyester, and the thickness of barrier film protective layer is 0.02 ~ 0.05mm, is set to one deck.
Described can chemical crosslink reaction and physics mortise and tenon work in coordination with the composition of the modified pitch tack coat of cementation and parts by weight are: two wires oil 8 parts, functional aid carboxyl polysiloxane coupling agent 3 parts, filler zinc oxide, dicalcium powder or talcum powder 30 parts that pitch 50 parts, petrochemical production process are produced jointly with concrete;
The technical performance of product of the present invention:
Product of the present invention on inspection its peel strength is national standard more than 2 times, and other performances meet the regulation of GB27789-2011 " TPO (TPO) waterproof roll ".
Major technique Testing index of the present invention (see with following table 1):
Table 1
tPO waterproof roll physical and mechanical property
Application Example:
As shown in Figure 1, tunnel, Nanning, in December, 2012, adopt this reaction bonded type thermoplastic polyolefin water-proof coiled material, its interlayer structure is as follows: polyolefin thermoplastic elastomer material layer 1; Modified pitch tack coat 2; Barrier film protective layer 3.Its work progress is as follows: needing the garage end face additionally arranged pours one deck cement concrete into, when cement concrete is not dry, tear barrier film protective layer 3, by directly auxiliary on cement concrete for the modified pitch adhesive layer 2 exposed, modified pitch is wriggled in cement, concrete setting process and penetrates into cement gel and concrete pore, form netted mortise and tenon; And with cement related compounds generation chemical reaction, form chemical crosslinking effect, play CPS effect, make coiled material and concrete reach the bond effect that as closely linked as flesh and blood.Through the test of instrumentation, do not find that there is seepage and seminess.
Claims (4)
1. a polyolefin composite modified asphalt wets and spreads the production method of waterproof roll, it is characterized in that: by jointly rising with concrete, the modified pitch tack coat (2) of cementation worked in coordination with by chemical crosslink reaction and physics mortise and tenon, bond barrier film protective layer (3) and polyolefin thermoplastic elastomer material layer (1) are formed, its interlayer structure is as follows: ground floor is polyolefin thermoplastic elastomer material layer (1), intermediate layer is modified pitch tack coat (2), cutting optimal is bonding barrier film protective layer (3), and each interlayer is by thermo-compression bonding in production process;
Described polyolefin thermoplastic elastomer material layer (1) is made up of the raw material of following portions by weight: copolymer 50-80 part, antioxidant 1.5-2.5 part, age resistor 1.0-2.0 part, softening agent 1-3 part, inserts 20-30 part; Its preparation method is: copolymer, antioxidant, age resistor, softening agent and inserts are mediated through 120 DEG C of-210 DEG C of banburyings and obtain;
Described copolymer comprises the copolymer of ethene and octene;
In polyolefin thermoplastic elastomer material layer (1), described antioxidant is HS-362, the NOR371 of Ciba fine chemicals's production and the AOD of Beijing Hua Teng engineered new materials Co., Ltd that Beijing Big Dipper auxiliary agent Co., Ltd produces; Described age resistor is 2,6-di-tert-butyl-4-methy phenol; Described softening agent is epoxidized soybean oil and octyl ester of epoxy fatty acid; Described inserts is a kind of in zinc oxide, magnesia, dicalcium powder and talcum powder or their mixture;
Described can jointly play chemical crosslink reaction and physics mortise and tenon with concrete and work in coordination with the composition of the modified pitch tack coat (2) of cementation and parts by weight are: pitch 40-60 part, two wires oil 5-10 part, functional aid 0.5-5 part, filler 20-50 part;
Described functional aid is the coupling agent with hydroxyl, amino or carboxyl, described in there is hydroxyl, amino or carboxyl coupling agent be polysiloxane coupling agent, poly-naphthalene formaldehyde sulfonate salt or their mixture; Production stage is as follows: first can jointly play chemical crosslink reaction and physics mortise and tenon with concrete and work in coordination with the modified pitch tack coat (2) of cementation and polyolefin thermoplastic elastomer material layer (1) is carried out, the condition thermo-compression bonding of 150-180 DEG C, control thick sizing, overlay film, rolling make.
2. polyolefin composite modified asphalt according to claim 1 wets and spreads the production method of waterproof roll, it is characterized in that: described polyolefin thermoplastic elastomer material layer (1) thickness is 0.4 ~ 2.0mm, is set to one deck.
3. polyolefin composite modified asphalt according to claim 1 wets and spreads the production method of waterproof roll; it is characterized in that: described bonding barrier film protective layer (3) is polyethylene, polyvinyl chloride or polyester; the thickness of bonding barrier film protective layer (3) is 0.02 ~ 0.05mm, is set to one deck.
4. polyolefin composite modified asphalt according to claim 1 wets and spreads the production method of waterproof roll, it is characterized in that: in modified pitch tack coat (2), and described two wires oil is that petrochemical production process produces the slightly secondary nonstandard oil of next quality; Described filler is a kind of in zinc oxide, magnesia, dicalcium powder and talcum powder or their mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210546765.6A CN102991073B (en) | 2012-12-17 | 2012-12-17 | Polyolefin composite modified asphalt wet paving waterproof roll and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210546765.6A CN102991073B (en) | 2012-12-17 | 2012-12-17 | Polyolefin composite modified asphalt wet paving waterproof roll and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102991073A CN102991073A (en) | 2013-03-27 |
| CN102991073B true CN102991073B (en) | 2016-01-13 |
Family
ID=47920415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210546765.6A Active CN102991073B (en) | 2012-12-17 | 2012-12-17 | Polyolefin composite modified asphalt wet paving waterproof roll and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102991073B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104742432A (en) * | 2014-08-19 | 2015-07-01 | 吴华林 | Anti-corrosion self-adhered polymer modified asphalt waterproofing roll |
| CN105602477B (en) * | 2016-01-05 | 2017-09-05 | 四川杨氏达防水材料有限公司 | Cement adhesive for polymer waterproof membrane, composite waterproof membrane and preparation method thereof |
| CN106968409A (en) * | 2017-05-23 | 2017-07-21 | 中铁十六局集团置业投资有限公司 | A kind of external wall waterproof construction and preparation method thereof |
| CN117400525A (en) * | 2017-10-26 | 2024-01-16 | 中建材苏州防水研究院有限公司 | Process for forming modified asphalt waterproof coiled material with polyolefin material as matrix |
| CN108081706A (en) * | 2017-12-29 | 2018-05-29 | 苏州启跃新材料科技有限公司 | A kind of antibacterial waterproof roll and preparation method thereof |
| CN110293726B (en) * | 2018-07-28 | 2021-06-01 | 潍坊市晨鸣新型防水材料有限公司 | Thermoplastic polyolefin waterproof coiled material and preparation method thereof |
| CN110408340B (en) * | 2019-07-31 | 2022-01-11 | 广西禹杰防水防腐材料有限公司 | Reaction bonding wet-laid high-polymer waterproof roll and preparation method thereof |
| CN110437754B (en) * | 2019-08-15 | 2022-02-08 | 禹杰科技有限公司 | Reaction double-adhesion type high-polymer waterproof coiled material and production method thereof |
| CN112428601A (en) * | 2020-10-30 | 2021-03-02 | 安徽大禹防水科技发展有限公司 | Method for manufacturing bridge deck waterproof material |
| CN114182577A (en) * | 2021-12-30 | 2022-03-15 | 中国铁道科学研究院集团有限公司铁道建筑研究所 | Device and method for remedying railway ballast track bed mud pumping disease caused by slurry turning |
| CN115505154B (en) * | 2022-09-29 | 2023-07-25 | 深圳市卓宝科技股份有限公司 | A kind of functional film and preparation method and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101694114A (en) * | 2009-10-09 | 2010-04-14 | 广西金雨伞防水装饰有限公司 | Waterproof roll capable of carrying out chemical bonding and physical crosslinking synergism with concrete |
| WO2010088021A1 (en) * | 2009-01-30 | 2010-08-05 | W. R. Grace & Co.-Conn. | Waterproofing membrane |
| CN102121277A (en) * | 2010-12-30 | 2011-07-13 | 唐山德生防水材料有限公司 | Anticorrosive TPO modified asphalt composite waterproof coiled material and preparation method thereof |
| CN202064532U (en) * | 2011-05-12 | 2011-12-07 | 北京宇阳泽丽防水材料有限责任公司 | Novel TPO (thermoplastic polyolefin) waterproof coiled material |
| CN202965330U (en) * | 2012-12-17 | 2013-06-05 | 广西金雨伞防水装饰有限公司 | Wet waterproof coiled material of polyolefin composite modified asphalt |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100992952B1 (en) * | 2009-02-25 | 2010-11-09 | 네오방수기업 주식회사 | Composite waterproof structure using low melting point modified asphalt coating waterproofing agent and double-sided silica sheet adhesion and construction method |
-
2012
- 2012-12-17 CN CN201210546765.6A patent/CN102991073B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010088021A1 (en) * | 2009-01-30 | 2010-08-05 | W. R. Grace & Co.-Conn. | Waterproofing membrane |
| CN101694114A (en) * | 2009-10-09 | 2010-04-14 | 广西金雨伞防水装饰有限公司 | Waterproof roll capable of carrying out chemical bonding and physical crosslinking synergism with concrete |
| CN102121277A (en) * | 2010-12-30 | 2011-07-13 | 唐山德生防水材料有限公司 | Anticorrosive TPO modified asphalt composite waterproof coiled material and preparation method thereof |
| CN202064532U (en) * | 2011-05-12 | 2011-12-07 | 北京宇阳泽丽防水材料有限责任公司 | Novel TPO (thermoplastic polyolefin) waterproof coiled material |
| CN202965330U (en) * | 2012-12-17 | 2013-06-05 | 广西金雨伞防水装饰有限公司 | Wet waterproof coiled material of polyolefin composite modified asphalt |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102991073A (en) | 2013-03-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102991073B (en) | Polyolefin composite modified asphalt wet paving waterproof roll and production method thereof | |
| CN102975465A (en) | Antiflaming waste rubber powder modified asphalt wet-paving waterproof coiled material and production method thereof | |
| CN102002983B (en) | Wet lay-up and edge-jointing construction method of single-sided adhesive wet lay-up waterproof coiled material | |
| CN102003190B (en) | Construction method for pre-laying tunnel waterproof coiled material | |
| CN107175870A (en) | Strengthen the modified asphalt waterproof coiled material and its production method of overlap edge | |
| CN202220385U (en) | Double-sided adhesive modified asphalt waterproof coiled material | |
| CN201826402U (en) | Reinforced composite waterproof roll with grid cloth | |
| CN105584135B (en) | Wet-laying waterproof roll is overlay with cross-linking reaction layer | |
| CN203004428U (en) | Laminated film composite waterproof coiled material | |
| CN203004430U (en) | TPO thermoplastic elastomer composite waterproof coiled material | |
| CN201598737U (en) | Three-in-one reaction high polymer composite waterproof coiled material | |
| CN204605052U (en) | Wet paving waterproof roll is overlay with cross-linking reaction layer | |
| CN202965330U (en) | Wet waterproof coiled material of polyolefin composite modified asphalt | |
| CN201665923U (en) | Two-in-one reaction type macromolecule composite waterproof coiled material | |
| CN201665960U (en) | Reactive type modified asphalt waterproof rolling material with aluminum foil surface | |
| CN203004429U (en) | Polymer film composite waterproof coiled material with both sides bonded | |
| CN201826234U (en) | Compound waterproof coiled material of crossly laminated powerful film | |
| CN105273231A (en) | Amino silane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof | |
| CN202440850U (en) | One-side reinforcing modified asphalt waterproof coiled material | |
| CN202731116U (en) | Modified bituminous waterproof sheet material | |
| CN201598736U (en) | Reactive high polymer composite waterproof sheet with knotted ropes | |
| CN203004460U (en) | Laminated film composite waterproof coiled material with both sides bonded | |
| CN201605677U (en) | Reactive type modified asphalt waterproof roll material | |
| CN105273234A (en) | Mercaptoalkoxy silane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof | |
| CN205705605U (en) | There is the enhancing modified asphalt water-proof coiled material of overlap edge |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Polyolefin composite modified asphalt wet-laid waterproof roll and production method thereof Effective date of registration: 20171206 Granted publication date: 20160113 Pledgee: Guangxi Beibu Bay bank Limited by Share Ltd Nanhu branch of Nanning City Pledgor: Lu Guicai|Guangxi Golden Umbrella Waterproofing Co.,Ltd. Registration number: 2017450000014 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 530001 Sunshine Green City, No. 18 Donggouling Landscape Road, Xingning District, Nanning City, Guangxi Zhuang Autonomous Region Patentee after: Xiniupi Waterproof Technology Co., Ltd. Address before: 530001 Sunshine Green City, No. 18 Donggouling Landscape Road, Xingning District, Nanning City, Guangxi Zhuang Autonomous Region Patentee before: Guangxi Golden Umbrella Waterproofing Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| PM01 | Change of the registration of the contract for pledge of patent right |
Change date: 20190409 Registration number: 2017450000014 Pledgor after: Xiniupi Waterproof Decoration Co., Ltd. Pledgor after: Lu Guicai Pledgor before: Guangxi Golden Umbrella Waterproof Decoration Co., Ltd. Pledgor before: Lu Guicai |
|
| PM01 | Change of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20190415 Granted publication date: 20160113 Pledgee: Guangxi Beibu Bay bank Limited by Share Ltd Nanhu branch of Nanning City Pledgor: West Cattle Leather Waterproof Decoration Co., Ltd.|Lu Guicai Registration number: 2017450000014 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| CP02 | Change in the address of a patent holder |
Address after: 530216 scientific research building, Xiniu science and Technology Park, No. 68, team 4, naluopo, Sitang community, Santang Town, Xingning District, Nanning City, Guangxi Zhuang Autonomous Region Patentee after: Xiniupi Waterproof Technology Co.,Ltd. Address before: 530001 Sunshine Green City, No. 18 Donggouling Landscape Road, Xingning District, Nanning City, Guangxi Zhuang Autonomous Region Patentee before: Xiniupi Waterproof Technology Co.,Ltd. |
|
| CP02 | Change in the address of a patent holder |