CN102993955A - Non-arene anticorrosion process for metal structures - Google Patents
Non-arene anticorrosion process for metal structures Download PDFInfo
- Publication number
- CN102993955A CN102993955A CN201210548204XA CN201210548204A CN102993955A CN 102993955 A CN102993955 A CN 102993955A CN 201210548204X A CN201210548204X A CN 201210548204XA CN 201210548204 A CN201210548204 A CN 201210548204A CN 102993955 A CN102993955 A CN 102993955A
- Authority
- CN
- China
- Prior art keywords
- aromatic hydrocarbons
- metal construction
- anticorrosion
- anticorrosion process
- described metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 39
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 22
- 239000002184 metal Substances 0.000 title claims abstract description 22
- 238000000576 coating method Methods 0.000 claims abstract description 19
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 8
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 6
- 239000004642 Polyimide Substances 0.000 claims abstract description 6
- 239000004917 carbon fiber Substances 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 229920001721 polyimide Polymers 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000005507 spraying Methods 0.000 claims abstract description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- 238000010276 construction Methods 0.000 claims description 15
- 239000000758 substrate Substances 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 9
- 230000035800 maturation Effects 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 7
- 230000008021 deposition Effects 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 5
- TXTCTCUXLQYGLA-UHFFFAOYSA-L calcium;prop-2-enoate Chemical compound [Ca+2].[O-]C(=O)C=C.[O-]C(=O)C=C TXTCTCUXLQYGLA-UHFFFAOYSA-L 0.000 claims description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- MZSAMHOCTRNOIZ-UHFFFAOYSA-N 3-[4-(aminomethyl)-6-(trifluoromethyl)pyridin-2-yl]oxy-N-phenylaniline Chemical compound NCC1=CC(=NC(=C1)C(F)(F)F)OC=1C=C(NC2=CC=CC=C2)C=CC=1 MZSAMHOCTRNOIZ-UHFFFAOYSA-N 0.000 claims description 2
- 230000001680 brushing effect Effects 0.000 claims description 2
- 238000005137 deposition process Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 6
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- 238000002791 soaking Methods 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- -1 rare earth compounds Chemical class 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 5
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007739 conversion coating Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a non-arene anticorrosion process for metal structures. Through carrying out curing treatment on a mixture of components such as siloxane, solvents, silica particles, rare earth compounds, deionized water, catalysts, carbon fibers and polyimide and the like, filtering the mixture subjected to curing, and coating the obtained product on the surface of a base material through spray coating, brush coating or soaking, a coating is formed on the surface of the base material after the obtained product is deposited, thereby achieving an effect of anti-corrosion treatment on the surface.
Description
Technical field
The present invention relates to a kind of metal construction without the anticorrosion process of aromatic hydrocarbons, relate in particular to a kind of metal structure surface that is applicable to, have the coating method of the environmental protection coating material of excellent gloss and mechanical and physical performance and aromatic free solvent.
Background technology
In modern industry and daily life, corrosion of metal is seen everywhere, and the destruction of the forms such as crevice corrosion, stress corrosion and corrosion fatigue that especially occur in the storage vessel of a fuel oil dangerization product is caused great potential safety hazard for people's lives.
The metal protection method that adopts at present can roughly be divided three classes: a class is to carry out anodic oxidation treatment, namely form the anode oxide film of one deck tens micron thickness in the metallic surface, but because the anode oxidation process power consumption is large, and electrolyte solution is seriously polluted, be difficult to process, use its application to be restricted; Equations of The Second Kind is chemical conversion film, being about to metal parts is immersed in the solution of definite composition, rely at a certain temperature chemical reaction to form one deck chemical conversion film, now most widely used is the oxidation of chromic salt chemistry, but chromic salt is a kind of carcinogenic toxicant, and the world environments protective tissue has proposed restriction and used chromic salt and other to contain chromate compound; The 3rd class is organic coating, namely applies one deck organic coating in the metallic surface, with outward appearance and the physical and chemical performance that improves metal.People begin rare earth element is used in the aseptic technic of metallic surface in recent years.
The rare-earth conversion coatings film technique develops into today, and people have carried out a large amount of improvement to various film-forming process, and the performance of film also is improved.At present the rare-earth conversion coatings technology mainly is immersion treatment, and this technological operation is simple, be easy to safeguard; But its drawback is that the long period of soaking process treatment time is oversize, and formed rete is thinner and relatively poor with the sticking power of base material.Find through long-term exploratory development, add strong oxidizer in the soaking solution, such as H
2O
2, KMnO
4, (NH
4)
2S
2O
8Etc. strong oxide compound, rate of film build is improved greatly, the treatment time shortens dramatically, and the treatment soln temperature is not high yet simultaneously, can at room temperature use.But because the existence of strong oxidizer is so that the less stable for the treatment of process.
The problem that exists in order to solve the rare-earth conversion coatings treatment process, the present invention proposes a kind of improved metal construction without the anticorrosion process of aromatic hydrocarbons.This method anticorrosion with low cost, remarkable in economical benefits can be carried out normal temperature and be spread, and coating processes is simple, and solution is environment friendly and pollution-free.
Summary of the invention
The objective of the invention is for the deficiencies in the prior art part, provide a kind of environment protection metal structure without the anticorrosion process of aromatic hydrocarbons, in order to solve the protection against corrosion difficult problem of the surfaces externally and internally applications such as steel, aluminium, especially aluminium alloy, and coating aromatic free solvent, do not contain strong oxidizer, without poisonous pigment, be fit to various constructional methods, application is not subject to seasonal restrictions, and construction technology is simple and convenient, and technical costs is cheap, good environmental protection.The present invention is achieved by the following technical solutions:
(1) prepare following component (mass parts):
A 3-(triethoxy is silica-based) propyl group CALCIUM ACRYLATE 11-20;
B ethanol 61-80;
C SiO
2Particle 6-10;
The oxide compound 1-5 of d cerium;
E deionized water 26-50;
F acetic acid 4-6;
G carbon fiber 8-10;
H polyimide 4-6;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Embodiment
The present invention relates to metal construction without the anticorrosion process of aromatic hydrocarbons, after the various components of protective system are mixed, carry out maturation process, again the mixture after the slaking is filtered, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Described SiO
2The particle diameter of particle is the 50-100 nanometer.
Described maturation process is to leave standstill at normal temperatures 50-60 hour.
Described base material is steel or aluminium, preferred aluminium alloy.
Heat in the deposition process after spraying, brushing or dipping, Heating temperature is to heat 1 minute to 1 hour under 50 ℃ to the 150 ℃ temperature.
The thickness of described coating is 1 micron to 10 microns, preferred 1 micron to 5 microns.The preferred method that adopts spraying or brush forms coating at substrate surface.
Metal construction disclosed by the invention without the anticorrosion process operation of aromatic hydrocarbons simply, easily and fast, reliably, and raw material is cheap, this method can be simply in conjunction with enter the existing pre-treatment that comprises coating and after in the conventional production line of other postprocessing working procedures of substrate material, substantially need not to carry out other adjustment on the equipment, is the Eco-power production technique of a kind of height.
The below elaborates with embodiment to the present invention, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
(1) prepare following component (mass parts):
A 3-(triethoxy is silica-based) propyl group CALCIUM ACRYLATE 11;
B ethanol 61;
C SiO
2Particle 6;
The oxide compound 1 of d cerium;
E deionized water 26;
F acetic acid 4;
G carbon fiber 8;
H polyimide 4;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Embodiment 2
(1) prepare following component (mass parts):
A 3-(triethoxy is silica-based) propyl group CALCIUM ACRYLATE 20;
B ethanol 80;
C SiO
2Particle 10;
The oxide compound 3 of d cerium;
E deionized water 50;
F acetic acid 5;
G carbon fiber 10;
H polyimide 5;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Embodiment 3
(1) prepare following component (mass parts):
A 3-(triethoxy is silica-based) propyl group CALCIUM ACRYLATE 15;
B ethanol 70;
C SiO
2Particle 8;
The oxide compound 5 of d cerium;
E deionized water 38;
F acetic acid 6;
G carbon fiber 9;
H polyimide 6;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Claims (9)
1. metal construction comprises without the anticorrosion process of aromatic hydrocarbons:
(1) prepare following component (mass parts):
A 3-(triethoxy is silica-based) propyl group CALCIUM ACRYLATE 11-20;
B ethanol 61-80;
C SiO
2Particle 6-10;
The oxide compound 1-5 of d cerium;
E deionized water 26-50;
F acetic acid 4-6;
G carbon fiber 8-10;
H polyimide 4-6;
(2) with carrying out maturation process after the said components mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
2. described metal construction is characterized in that without the anticorrosion process of aromatic hydrocarbons according to claim 1, described SiO
2The particle diameter of particle is the 50-100 nanometer.
3. described metal construction is characterized in that without the anticorrosion process of aromatic hydrocarbons according to claim 1, and described maturation process is to leave standstill at normal temperatures 50-60 hour.
4. described metal construction is characterized in that without the anticorrosion process of aromatic hydrocarbons according to claim 1, and described base material is steel or aluminium.
5. described metal construction is characterized in that without the anticorrosion process of aromatic hydrocarbons described base material is aluminium alloy according to claim 1.
6. described metal construction is characterized in that without the anticorrosion process of aromatic hydrocarbons according to claim 1, heats in described deposition process, and Heating temperature is 50 ℃ to 150 ℃, 1 minute to 1 hour heat-up time.
7. described metal construction is characterized in that without the anticorrosion process of aromatic hydrocarbons according to claim 1, and described coat-thickness is 1 micron to 10 microns.
8. described metal construction is characterized in that without the anticorrosion process of aromatic hydrocarbons according to claim 7, and described coat-thickness is 1 micron to 5 microns.
9. described metal construction is characterized in that without the anticorrosion process of aromatic hydrocarbons according to claim 1, adopts the method for spraying or brushing to form coating at substrate surface in the described step (2).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210548204XA CN102993955A (en) | 2012-12-17 | 2012-12-17 | Non-arene anticorrosion process for metal structures |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210548204XA CN102993955A (en) | 2012-12-17 | 2012-12-17 | Non-arene anticorrosion process for metal structures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102993955A true CN102993955A (en) | 2013-03-27 |
Family
ID=47923083
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210548204XA Pending CN102993955A (en) | 2012-12-17 | 2012-12-17 | Non-arene anticorrosion process for metal structures |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102993955A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078735A (en) * | 1992-05-11 | 1993-11-24 | 中国科学院上海有机化学研究所 | Fluoroplastic Coatings, Manufacture and Application |
| CN102174289A (en) * | 2011-02-25 | 2011-09-07 | 上海交通大学 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
| CN102762750A (en) * | 2010-02-19 | 2012-10-31 | 塔塔钢铁荷兰科技有限责任公司 | Strip, sheet or blank suitable for thermoforming and method for its production |
-
2012
- 2012-12-17 CN CN201210548204XA patent/CN102993955A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078735A (en) * | 1992-05-11 | 1993-11-24 | 中国科学院上海有机化学研究所 | Fluoroplastic Coatings, Manufacture and Application |
| CN102762750A (en) * | 2010-02-19 | 2012-10-31 | 塔塔钢铁荷兰科技有限责任公司 | Strip, sheet or blank suitable for thermoforming and method for its production |
| CN102174289A (en) * | 2011-02-25 | 2011-09-07 | 上海交通大学 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102993960A (en) | Rare-earth anticorrosion process for metal surfaces | |
| CN102942868A (en) | Non-aromatic corrosion prevention method for metal structure | |
| CN102936459A (en) | Coating process of environmentally friendly paint on metal surface | |
| CN102942855A (en) | Corrosion prevention technology for metal structure | |
| CN103031055A (en) | Non-aromatic corrosion resistance technique for metal surface | |
| CN102964997A (en) | Anticorrosion method of metal structure | |
| CN102942844A (en) | Non-aromatic corrosion prevention technology for metal structure | |
| CN102964991A (en) | Aromatic-hydrocarbon-free anti-corrosion flow of metal surface | |
| CN102977778A (en) | Coating technology for anticorrosive paint without aromatic hydrocarbon | |
| CN102993962A (en) | Metal surface aromatic hydrocarbon-free corrosion prevention process | |
| CN102942852A (en) | Corrosion prevention scheme of metal surface | |
| CN102965001A (en) | Anti-corrosion flow of metal surface | |
| CN102993801A (en) | Anti-corrosive paint coating method | |
| CN103045087A (en) | Coating process of anticorrosive coatings | |
| CN102942846A (en) | Coating scheme of anti-corrosion paint | |
| CN102942857A (en) | Non-aromatic corrosion prevention technology for metal structure | |
| CN102993955A (en) | Non-arene anticorrosion process for metal structures | |
| CN102993953A (en) | Non-arene anticorrosion process for metal surfaces | |
| CN102964989A (en) | Anticorrosion method of metal structure | |
| CN102993951A (en) | Rare-earth anticorrosion method for metal surfaces | |
| CN102993947A (en) | Rare earth anticorrosive paint coating process | |
| CN102977781A (en) | Aromatic hydrocarbon-free anti-corrosion technology of metal structure | |
| CN102977779A (en) | Method for coating anticorrosive paint without aromatic hydrocarbon | |
| CN102977775A (en) | Corrosion prevention technology for metal structure | |
| CN102993949A (en) | Rare earth anticorrosive paint coating technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130327 |
|
| RJ01 | Rejection of invention patent application after publication |