CN103039541B - Environmental-friendly automobile air conditioner and interior environment purification agent and preparation method thereof - Google Patents
Environmental-friendly automobile air conditioner and interior environment purification agent and preparation method thereof Download PDFInfo
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- CN103039541B CN103039541B CN201210583888.7A CN201210583888A CN103039541B CN 103039541 B CN103039541 B CN 103039541B CN 201210583888 A CN201210583888 A CN 201210583888A CN 103039541 B CN103039541 B CN 103039541B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 238000000746 purification Methods 0.000 title abstract description 9
- 235000001405 Artemisia annua Nutrition 0.000 claims abstract description 10
- 240000000011 Artemisia annua Species 0.000 claims abstract description 10
- 240000001851 Artemisia dracunculus Species 0.000 claims abstract description 10
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 10
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims abstract description 10
- 241000018646 Pinus brutia Species 0.000 claims abstract description 10
- 235000011613 Pinus brutia Nutrition 0.000 claims abstract description 10
- 238000004378 air conditioning Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000000706 filtrate Substances 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 10
- 235000003092 Artemisia dracunculus Nutrition 0.000 claims description 9
- 244000025254 Cannabis sativa Species 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 241000209205 Coix Species 0.000 claims description 8
- 235000007354 Coix lacryma jobi Nutrition 0.000 claims description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 239000003381 stabilizer Substances 0.000 claims description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
- 238000004064 recycling Methods 0.000 claims description 5
- 239000005711 Benzoic acid Substances 0.000 claims description 4
- 235000010233 benzoic acid Nutrition 0.000 claims description 4
- 229940074391 gallic acid Drugs 0.000 claims description 4
- 235000004515 gallic acid Nutrition 0.000 claims description 4
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 3
- 229930003268 Vitamin C Natural products 0.000 claims description 3
- 235000019154 vitamin C Nutrition 0.000 claims description 3
- 239000011718 vitamin C Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 abstract 1
- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 abstract 1
- 235000003097 Artemisia absinthium Nutrition 0.000 abstract 1
- 235000017731 Artemisia dracunculus ssp. dracunculus Nutrition 0.000 abstract 1
- 235000003261 Artemisia vulgaris Nutrition 0.000 abstract 1
- 244000077995 Coix lacryma jobi Species 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 abstract 1
- 241000208125 Nicotiana Species 0.000 abstract 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 abstract 1
- 239000001138 artemisia absinthium Substances 0.000 abstract 1
- 229960000846 camphor Drugs 0.000 abstract 1
- 229930008380 camphor Natural products 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 235000008216 herbs Nutrition 0.000 abstract 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000009423 ventilation Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 230000008033 biological extinction Effects 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an automobile air conditioner and interior environment purification agent and a preparation method thereof, and the purification agent is obtained by extracting after the reaction of plant materials consisting of tobacco stems, wormwood leaves, pine leaves, sweet wormwood herbs, coix seeds and camphor leaves. The automobile air conditioner care product provided by the invention is environment-friendly, low in price, good in cleaning effect and disinfection effect, and has no any side effects on human bodies and automobiles. The preparation method has the advantages of simple and convenient operation, low reaction temperature and pressure, low material and catalyst costs, and high productivity, and can be applied to the field of air conditioner cleaning in the automobile and relative fields.
Description
Technical field
The present invention relates to a kind of Environmental-friendautomobile automobile air conditioner and interior environment purification agent and preparation method thereof, particularly relate to the natural botanical extraction liquid of environment for use close friend and utilize biology enzyme as catalyzer to prepare high-efficiency environment friendly air conditioning for automobiles care product.
Background technology
Air conditioning for automobiles and the primary work of environment inside car maintenance remove sterilization in foreign material and car in the air circulation system for air conditioning for automobiles.Like that car is through travelling for a long time, can cause part leaf, dust or impurity to enter in air-conditioning and car, have peculiar smell when opening air-conditioning on the one hand; Spring and summer alternately on the other hand, the suitable temperature that automotive air-conditioning system evaporation tank place is dark, moist, easily grows germ and acarid, and becomes in their " breeding place ", and each corner in car can be spread out in a large number, thus preferably giving air-conditioning " ablution " during this period of time.The cleaning of air-conditioning filter net mainly adopts two kinds of ways, and one is take the screen pack of evaporation tank to take apart, and then cleans, if screen pack has too dirty or damages phenomenon, needs to change; Another kind is then use vehicle air conditioner cleaning agent.Similar this cleaning agent is all rising in recent years, uses more convenient.At present air conditioner cleaning agent is on the market the combination of the chemical substance of technical grade mostly, likely cause evaporation tank or miscellaneous part impaired, reduction of service life, its residue also can affect the health of driver and conductor simultaneously.
Summary of the invention
Object of the present invention is for Problems existing in air conditioning for automobiles maintenance and nursing, provide a kind of Environmental-friendautomobile automobile air conditioner and interior environment purification agent, raw material is renewable resources, and the clarificant safety non-toxic of gained and the advantage such as cheap and easy to get, sterilization effect is excellent.
Another object of the present invention aims to provide reaction condition gentleness, the above-mentioned Environmental-friendautomobile automobile air conditioner of good yields and interior environment purification agent preparation method.
The object of the invention is to be realized by following manner:
Environmental-friendautomobile automobile air conditioner and interior environment purification agent, to comprise the raw material of 5 ~ 15 parts of offals of following weight portion, 2 ~ 10 parts of tarragon grass, 1 ~ 8 part of pine tree leaf, 0.5 ~ 5 part of sweet wormwood, 0.5 ~ 4 portion of seed of Job's tears and 1 ~ 7 part of camphortree leaf, and be solvent with water, under closed environment, 70 ~ 110 DEG C, under 30 ~ 120psi, reaction forms.
Preparation method of the present invention comprises the following steps:
Under air-proof condition, be solvent with water, add the raw material of following weight portion: 5 ~ 15 parts of offals, 2 ~ 10 parts of tarragon grass, 1 ~ 8 part of pine tree leaf, 0.5 ~ 5 part of sweet wormwood, 0.5 ~ 4 portion of seed of Job's tears and 1 ~ 7 part of camphortree leaf; Be warming up to 70 ~ 110 DEG C, react under pressure 30-120psi; After reacting completely, the filtrate that obtains of reacting liquid filtering is finished product.
Add in course of reaction of the present invention and have catalyzer vitamin C.The addition of catalyzer is preferably 0.05 ~ 0.3 part.
Reaction time of the present invention is preferably 3-10h.
After having reacted, be also added with one or more in stabilizing agent benzoic acid, gallic acid, pyrogallic acid.
Reacting liquid filtering obtains filter residue and can reuse, and continues reaction at least one times.
The addition of water of the present invention is advisable with 40-60 part.
Certainly, those skilled in the art also knows completely, less at the consumption of water, and the clarificant obtained to dilute rear use, still can not affect result of use.
Concrete processing step of the present invention is as follows:
1) in (100L) reactor, offal 5-15 kilogram is added, tarragon grass 2-10 kilogram, pine tree leaf 1-8 kilogram, sweet wormwood 0.5-5 kilogram, seed of Job's tears 0.5-4 kilogram, camphortree leaf 1-7 kilogram, 50-300 gram of catalyzer and 40-60 kilogram of deionized water, reactor is tightened, detects air-tightness, make it air tight.
2) open ventilation switch, passing into the pressure controlled in reactor is 30 ~ 120psi, shuts switch.
3) reactor is placed in electric jacket, uniform temperature 70 ~ 110 DEG C is set, and use sensor to carry out temperature control.
4) react after 6-12 hour, stop heating, reactor room temperature is cooled.
5) when reactor cools completely, and after pressure no longer changes, release unnecessary gas, by reacting liquid filtering, filter residue recycling once.Filtrate is through detecting, and add the stabilizing agent benzoic acid accounting for filtrate gross weight 0.1-1.2%, gallic acid, pyrogallic acid or their mixture are finished product.
The using method of Environmental-friendautomobile automobile air conditioner of the present invention and interior environment purification agent is: get the common heating devices heat of product utilization of the present invention and circulate, until clarificant all disappears inside steam input air conditioning for automobiles.
Advantageous effect of the present invention is as follows:
Offal has been selected especially in the present invention, tarragon grass, pine tree leaf, sweet wormwood, the seed of Job's tears, camphortree leaf is as raw material, having raw material is renewable resources, safety non-toxic and the advantage such as cheap and easy to get, use these materials to obtain useful chemical products for raw material realizes suitability for industrialized production, can environmental pollution be alleviated, there is again very high economic worth; Sterilization, air purification effect is excellent; To human body and car body without any side effect, can apply in the cleaning air conditioner field of automobile and association area.Simultaneously the present invention reaction requires low to temperature and pressure, can reduce reaction condition, avoids because temperature and pressure is too high causes danger, therefore the present invention is easy and simple to handle, and operation simplifies, and reduces costs, raise the efficiency, make product quality good simultaneously, can be applied in the industrial production.
Embodiment
Embodiment 1
1) in 100L reactor, add offal 10 kilograms, tarragon grass 4 kilograms, pine tree leaf 2 kilograms, sweet wormwood 1 kilogram, the seed of Job's tears 1 kilogram, camphortree leaf 2 kilograms, 50 grams of catalyzer and 50L deionized water, tighten reactor, detects air-tightness, make it air tight.
2) open ventilation switch, pass into the air of 60psi, shut switch.
3) reactor is placed in electric jacket, set temperature 90 degree, and uses sensor to carry out temperature control.
4) react after 8 hours, stop heating, reactor room temperature is cooled.
5) when reactor cools completely, and after pressure no longer changes, release unnecessary gas, by reacting liquid filtering, filter residue recycling once.Filtrate is through detecting, and interpolation accounts for filtrate gross weight 0.1-1.2% stabilizing agent and is finished product.
6) (volume is 10m the clarificant of the present embodiment gained to be placed on test appointment scene
3) carry out field trial, measure the extinction rate (following examples same) of this clarificant to on-the-spot natural bacteria according to the field testing procedure that " disinfection technology standard " specifies.
Embodiment 2
1) in 100L reactor, add offal 11 kilograms, tarragon grass 5 kilograms, pine tree leaf 1 kilogram, sweet wormwood 2 kilograms, the seed of Job's tears 0.5 kilogram, camphortree leaf 4 kilograms, 100 grams of catalyzer and 50L deionized water, tighten reactor, detects air-tightness, make it air tight.
2) open ventilation switch, pass into the air of 90psi, shut switch.
3) reactor is placed in electric jacket, set temperature 100 degree, and uses sensor to carry out temperature control.
4) react after 6 hours, stop heating, reactor room temperature is cooled.
5) when reactor cools completely, and after pressure no longer changes, release unnecessary gas, by reacting liquid filtering, filter residue recycling once.Filtrate is through detecting, and interpolation accounts for filtrate gross weight 0.1-1.2% stabilizing agent and is finished product.
6) extinction rate 96% of natural bacteria.
Embodiment 3
1) in 100L reactor, add offal 6 kilograms, tarragon grass 10 kilograms, pine tree leaf 3 kilograms, sweet wormwood 1 kilogram, camphortree leaf 3 kilograms, 80 grams of catalyzer and 50L deionized water, tighten reactor, detects air-tightness, make it air tight.
2) open ventilation switch, pass into the air of 60psi, shut switch.
3) reactor is placed in electric jacket, set temperature 80 degree, and uses sensor to carry out temperature control.
4) react after 9 hours, stop heating, reactor room temperature is cooled.
5) when reactor cools completely, and after pressure no longer changes, release unnecessary gas, by reacting liquid filtering, filter residue recycling once.Filtrate, through detecting, is added the stabilizing agent accounting for filtrate gross weight 0.1-1.2% and is finished product.
6) extinction rate 98% of natural bacteria.
Claims (5)
1. the clarificant for air conditioning for automobiles and environment inside car of an environment-friendly type, it is characterized in that, by 5 ~ 15 parts of offals of following weight portion, 2 ~ 10 parts of tarragon grass, 1 ~ 8 part of pine tree leaf, 0.5 ~ 5 part of sweet wormwood, 0.5 ~ 4 portion of seed of Job's tears and 1 ~ 7 part of camphortree leaf at interior raw material, and be solvent with water, under closed environment, 70 ~ 110 DEG C, under 30 ~ 120psi, reaction forms; Catalyzer vitamin C is added in course of reaction; The addition of catalyzer is 0.05 ~ 0.3 part; After having reacted, add one or more in stabilizing agent benzoic acid, gallic acid, pyrogallic acid.
2. clarificant according to claim 1, is characterized in that, the addition of water is 40-60 part.
3. a preparation method for the clarificant for air conditioning for automobiles and environment inside car of environment-friendly type, is characterized in that, comprise the following steps:
Under air-proof condition, be solvent with water, add the raw material of following weight portion: 5 ~ 15 parts of offals, 2 ~ 10 parts of tarragon grass, 1 ~ 8 part of pine tree leaf, 0.5 ~ 5 part of sweet wormwood, 0.5 ~ 4 portion of seed of Job's tears and 1 ~ 7 part of camphortree leaf;
Be warming up to 70 ~ 110 DEG C, react under pressure 30-120psi; After reacting completely, reacting liquid filtering obtains filtrate is finished product; Catalyzer vitamin C is added in course of reaction; The addition of catalyzer is 0.05 ~ 0.3 part; After having reacted, add one or more in stabilizing agent benzoic acid, gallic acid, pyrogallic acid.
4. preparation method according to claim 3, is characterized in that, reacting liquid filtering obtains filter residue recycling, continues reaction.
5. the preparation method according to claim 3 or 4, is characterized in that, the time of reaction is 3-10h.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210583888.7A CN103039541B (en) | 2012-12-28 | 2012-12-28 | Environmental-friendly automobile air conditioner and interior environment purification agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210583888.7A CN103039541B (en) | 2012-12-28 | 2012-12-28 | Environmental-friendly automobile air conditioner and interior environment purification agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103039541A CN103039541A (en) | 2013-04-17 |
| CN103039541B true CN103039541B (en) | 2015-07-08 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210583888.7A Expired - Fee Related CN103039541B (en) | 2012-12-28 | 2012-12-28 | Environmental-friendly automobile air conditioner and interior environment purification agent and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106753829A (en) * | 2016-11-22 | 2017-05-31 | 闫博文 | A kind of preparation method of antibacterial corrosion-free type air conditioner cleaning agent |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1162490A (en) * | 1997-03-01 | 1997-10-22 | 杨正春 | Air freshener |
| CN1390462A (en) * | 2002-07-03 | 2003-01-15 | 舒朝然 | Biologic insecticidal bactericide without environmental pollution |
| US20030017178A1 (en) * | 2001-06-29 | 2003-01-23 | Mullen Patricia A. | Fragrance-containing insect repellant compositions |
| CN1633856A (en) * | 2004-12-11 | 2005-07-06 | 刘起麟 | Preparation and uses of specific medicine for killing influenza virus and bacteria through crystal volatilization |
| CN1685840A (en) * | 2005-04-23 | 2005-10-26 | 刘起麟 | Preparation of central air conditioning legionary bacteria controller and application method |
| CN1739358A (en) * | 2005-09-09 | 2006-03-01 | 张东旭 | Mosquito killing disinfectant |
| CN101069519A (en) * | 2007-05-10 | 2007-11-14 | 雷景华 | Bacteria inhibiting composition for air conditioner |
| CN101480498A (en) * | 2008-01-11 | 2009-07-15 | 翁乐灵 | Air refreshing agent |
| CN101601865A (en) * | 2009-07-09 | 2009-12-16 | 蒋勇 | A kind of sterilization incense for dispelling mosquito and fly |
-
2012
- 2012-12-28 CN CN201210583888.7A patent/CN103039541B/en not_active Expired - Fee Related
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1162490A (en) * | 1997-03-01 | 1997-10-22 | 杨正春 | Air freshener |
| US20030017178A1 (en) * | 2001-06-29 | 2003-01-23 | Mullen Patricia A. | Fragrance-containing insect repellant compositions |
| CN1390462A (en) * | 2002-07-03 | 2003-01-15 | 舒朝然 | Biologic insecticidal bactericide without environmental pollution |
| CN1633856A (en) * | 2004-12-11 | 2005-07-06 | 刘起麟 | Preparation and uses of specific medicine for killing influenza virus and bacteria through crystal volatilization |
| CN1685840A (en) * | 2005-04-23 | 2005-10-26 | 刘起麟 | Preparation of central air conditioning legionary bacteria controller and application method |
| CN1739358A (en) * | 2005-09-09 | 2006-03-01 | 张东旭 | Mosquito killing disinfectant |
| CN101069519A (en) * | 2007-05-10 | 2007-11-14 | 雷景华 | Bacteria inhibiting composition for air conditioner |
| CN101480498A (en) * | 2008-01-11 | 2009-07-15 | 翁乐灵 | Air refreshing agent |
| CN101601865A (en) * | 2009-07-09 | 2009-12-16 | 蒋勇 | A kind of sterilization incense for dispelling mosquito and fly |
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| CN103039541A (en) | 2013-04-17 |
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