CN103031563A - Lithium-containing ferrous metal cleaner - Google Patents
Lithium-containing ferrous metal cleaner Download PDFInfo
- Publication number
- CN103031563A CN103031563A CN201110293692XA CN201110293692A CN103031563A CN 103031563 A CN103031563 A CN 103031563A CN 201110293692X A CN201110293692X A CN 201110293692XA CN 201110293692 A CN201110293692 A CN 201110293692A CN 103031563 A CN103031563 A CN 103031563A
- Authority
- CN
- China
- Prior art keywords
- clean
- out system
- water
- cleaner
- ferrous metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 19
- 239000002184 metal Substances 0.000 title claims abstract description 19
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims abstract description 18
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 17
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 42
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 28
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 28
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 14
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 14
- 239000013530 defoamer Substances 0.000 claims abstract description 14
- 229920000570 polyether Polymers 0.000 claims abstract description 14
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 14
- 235000010288 sodium nitrite Nutrition 0.000 claims abstract description 14
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 14
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims abstract description 12
- 238000012545 processing Methods 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims abstract description 5
- 239000000428 dust Substances 0.000 claims abstract description 5
- 230000000694 effects Effects 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims abstract description 3
- 230000001681 protective effect Effects 0.000 claims abstract description 3
- 239000004902 Softening Agent Substances 0.000 claims description 26
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 13
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 13
- 235000019353 potassium silicate Nutrition 0.000 claims description 13
- 235000017550 sodium carbonate Nutrition 0.000 claims description 13
- 229940117013 triethanolamine oleate Drugs 0.000 claims description 11
- 238000012856 packing Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 5
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 235000019633 pungent taste Nutrition 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- -1 ferrous metals Chemical class 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 230000007794 irritation Effects 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The aim of the present invention is to manufacture a lithium-containing ferrous metal cleaner, which is characterized by composing a cleaner of an anionic surfactant of alkylbenzene sulfonic acid, a cleaner of an anionic surfactant of oleic acid triethanolamine salt, a cleaner of sodium carbonate, a cleaner of potassium hydroxide, a water softener of sodium silicate, a water softener of disodium edetate, a corrosion inhibitor of sodium nitrite, an defoamer of polyether, and pure water. The present invention is mainly suitable for washing ferrous metals prior to the processing, and is especially effective for cleaning oil traces and dust on ferrous metal surfaces. The appearance of the cleaner shows colorless or light yellow transparent liquid, the pH value is greater than 12, the cleaner has irritation for human skin, and protective gloves should be used during using the cleaner. The cleaner does not contain phosphorus, and does not produce overfertilization effects on aquatic environment.
Description
[technical field]
The invention reside in and make a kind of ferrous metal clean-out system that contains lithium, it is characterized in that being formed by clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium, clean-out system anion surfactant triethanol amine oleate, clean-out system yellow soda ash, clean-out system potassium hydroxide, water-softening agent water glass, water-softening agent disodium ethylene diamine tetraacetate, inhibiter Sodium Nitrite, defoamer polyethers, pure water.
[background technology]
Ferrous metal mainly refers to steel, the pig iron, iron alloy, cast iron etc.Pure iron and chromium are argenteous, and manganese is silver gray.Because steel surface covers the Z 250 of one deck black usually, and manganese and chromium are mainly used in the steel alloy of smelting black, so just can be called as ferrous metal.Because ferrous metal is before various complete processings, a large amount of dusts, oil stain and dirt can be adhered in its surface, so must clean.
[summary of the invention]
The object of the invention provides a kind of ferrous metal clean-out system that contains lithium, it is characterized in that being comprised of clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium, clean-out system anion surfactant triethanol amine oleate, clean-out system yellow soda ash, clean-out system potassium hydroxide, water-softening agent water glass, water-softening agent disodium ethylene diamine tetraacetate, inhibiter Sodium Nitrite, defoamer polyethers, pure water.
The present invention mainly is applicable to the cleaning before the ferrous metal processing, especially cleans very effective to the contained oil stain of ferrous metal surface, dust.
The present invention mainly is applicable to the cleaning before the ferrous metal processing, especially cleans very effective to the contained oil stain of ferrous metal surface, dust.
Outward appearance of the present invention is colourless or light yellow transparent liquid, and there is pungency pH value>12 to human body skin, need be with protective gloves during use.
The present invention is not phosphorous, can not produce the overfertilization effect to water surrounding.
The present invention it is characterized in that being comprised of clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium 1-3%, clean-out system anion surfactant triethanol amine oleate 1-3%, clean-out system yellow soda ash 6-8%, clean-out system potassium hydroxide 2-4%, water-softening agent water glass 1-3%, water-softening agent disodium ethylene diamine tetraacetate 1-3%, inhibiter Sodium Nitrite 0.5-1.5%, defoamer polyethers 0.5-1.5%, pure water 70-90%.
Making method of the present invention is: be metered into pure water in reaction is filled with, stir, be metered into successively again clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium, clean-out system anion surfactant triethanol amine oleate, clean-out system yellow soda ash, clean-out system potassium hydroxide, water-softening agent water glass, water-softening agent disodium ethylene diamine tetraacetate, inhibiter Sodium Nitrite, defoamer polyethers.Stir after 30-40 minute, measure Specifications, the qualified rear filtration packing of packing into.
[embodiment]
Embodiment 1
Prescription: clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium 1%, clean-out system anion surfactant triethanol amine oleate 1%, clean-out system yellow soda ash 6%, clean-out system potassium hydroxide 2%, water-softening agent water glass 1%, water-softening agent disodium ethylene diamine tetraacetate 1%, inhibiter Sodium Nitrite 0.5%, defoamer polyethers 0.5%, pure water 87%.
Manufacture craft: in reaction is filled with, be metered into 87 kilograms of pure water, stir, be metered into successively again 1 kilogram of clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium, 1 kilogram of clean-out system anion surfactant triethanol amine oleate, 6 kilograms in clean-out system yellow soda ash, 2 kilograms in clean-out system potassium hydroxide, 1 kilogram of water-softening agent water glass, 1 kilogram of water-softening agent disodium ethylene diamine tetraacetate, 0.5 kilogram of inhibiter Sodium Nitrite, 0.5 kilogram of defoamer polyethers.Stir after 30-40 minute, measure Specifications, the qualified rear filtration packing of packing into.
Embodiment 2
Prescription: clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium 2%, clean-out system anion surfactant triethanol amine oleate 2%, clean-out system yellow soda ash 7%, clean-out system potassium hydroxide 3%, water-softening agent water glass 2%, water-softening agent disodium ethylene diamine tetraacetate 2%, inhibiter Sodium Nitrite 1%, defoamer polyethers 1%, pure water 80%.
Manufacture craft: in reaction is filled with, be metered into 80 kilograms of pure water, stir, be metered into successively again 2 kilograms of clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithiums, 2 kilograms of clean-out system anion surfactant triethanol amine oleates, 7 kilograms in clean-out system yellow soda ash, 3 kilograms in clean-out system potassium hydroxide, 2 kilograms of water-softening agent water glass, 2 kilograms of water-softening agent disodium ethylene diamine tetraacetate, 1 kilogram of inhibiter Sodium Nitrite, 1 kilogram of defoamer polyethers.Stir after 30-40 minute, measure Specifications, the qualified rear filtration packing of packing into.
Embodiment 3
Prescription: clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium 3%, clean-out system anion surfactant triethanol amine oleate 3%, clean-out system yellow soda ash 8%, clean-out system potassium hydroxide 4%, water-softening agent water glass 3%, water-softening agent disodium ethylene diamine tetraacetate 3%, inhibiter Sodium Nitrite 1.5%, defoamer polyethers 1.5%, pure water 73%.
Manufacture craft: in reaction is filled with, be metered into 73 kilograms of pure water, stir, be metered into successively again 3 kilograms of clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithiums, 3 kilograms of clean-out system anion surfactant triethanol amine oleates, 8 kilograms in clean-out system yellow soda ash, 4 kilograms in clean-out system potassium hydroxide, 3 kilograms of water-softening agent water glass, 3 kilograms of water-softening agent disodium ethylene diamine tetraacetate, 1.5 kilograms of inhibiter Sodium Nitrites, 1.5 kilograms of defoamer polyethers.Stir after 30-40 minute, measure Specifications, the qualified rear filtration packing of packing into.
Claims (7)
1. the invention reside in and make a kind of ferrous metal clean-out system that contains lithium, it is characterized in that being formed by clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium, clean-out system anion surfactant triethanol amine oleate, clean-out system yellow soda ash, clean-out system potassium hydroxide, water-softening agent water glass, water-softening agent disodium ethylene diamine tetraacetate, inhibiter Sodium Nitrite, defoamer polyethers, pure water.
2. described according to claim 1, the present invention mainly is applicable to the cleaning before the ferrous metal processing, especially cleans very effective to the contained oil stain of ferrous metal surface, dust.
3. described according to claim 1, prescription of the present invention is comprised of clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium 1-3%, clean-out system anion surfactant triethanol amine oleate 1-3%, clean-out system yellow soda ash 6-8%, clean-out system potassium hydroxide 2-4%, water-softening agent water glass 1-3%, water-softening agent disodium ethylene diamine tetraacetate 1-3%, inhibiter Sodium Nitrite 0.5-1.5%, defoamer polyethers 0.5-1.5%, pure water 70-90%.
4. described according to claim 1, making method of the present invention is: be metered into pure water in reaction is filled with, stir, be metered into successively again clean-out system anion surfactant alkyl benzene sulphonate (ABS) lithium, clean-out system anion surfactant triethanol amine oleate, clean-out system yellow soda ash, clean-out system potassium hydroxide, water-softening agent water glass, water-softening agent disodium ethylene diamine tetraacetate, inhibiter Sodium Nitrite, defoamer polyethers.Stir after 30-40 minute, measure Specifications, the qualified rear filtration packing of packing into.
5. described according to claim 1, the present invention mainly is applicable to the cleaning before the ferrous metal processing, especially cleans very effective to the contained oil stain of ferrous metal surface, dust.
6. described according to claim 1, outward appearance of the present invention is colourless or light yellow transparent liquid, and there is pungency pH value>12 to human body skin, need be with protective gloves during use.
7. described according to claim 1, the present invention is not phosphorous, can not produce the overfertilization effect to water surrounding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110293692XA CN103031563A (en) | 2011-10-08 | 2011-10-08 | Lithium-containing ferrous metal cleaner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110293692XA CN103031563A (en) | 2011-10-08 | 2011-10-08 | Lithium-containing ferrous metal cleaner |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103031563A true CN103031563A (en) | 2013-04-10 |
Family
ID=48018948
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110293692XA Pending CN103031563A (en) | 2011-10-08 | 2011-10-08 | Lithium-containing ferrous metal cleaner |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103031563A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103469231A (en) * | 2013-09-11 | 2013-12-25 | 太仓市微贯机电有限公司 | Metal surface cleaning agent |
| CN103469228A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Environmentally-friendly water-based metal cleaner |
| CN103469238A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Non-phosphorus metal cleaner |
| CN103469239A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Metal cleaner |
| CN103469230A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Water-based metal brightener |
| CN103469237A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Metal oil contamination cleaner |
| CN103484882A (en) * | 2013-09-25 | 2014-01-01 | 太仓市微贯机电有限公司 | Environment-friendly metal cleaning agent |
Citations (5)
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|---|---|---|---|---|
| US20070021316A1 (en) * | 2005-07-22 | 2007-01-25 | Dilley Colin M | Cleaner composition, article and method |
| CN1919993A (en) * | 2005-08-23 | 2007-02-28 | 穆世民 | High effective environmental protection multifunctional deoiling decontaminant |
| CN100588743C (en) * | 2007-04-09 | 2010-02-10 | 比亚迪股份有限公司 | A kind of acidic solution and treatment method for treating the surface of magnesium alloy |
| CN102002714A (en) * | 2009-09-01 | 2011-04-06 | 中国石油化工股份有限公司 | Wet leveling liquid composition and use thereof |
| WO2011112674A2 (en) * | 2010-03-09 | 2011-09-15 | Air Products And Chemicals, Inc. | Biodegradable amphoteric surfactants based on c6 to c11 linear or predominately linear alcohols |
-
2011
- 2011-10-08 CN CN201110293692XA patent/CN103031563A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070021316A1 (en) * | 2005-07-22 | 2007-01-25 | Dilley Colin M | Cleaner composition, article and method |
| CN1919993A (en) * | 2005-08-23 | 2007-02-28 | 穆世民 | High effective environmental protection multifunctional deoiling decontaminant |
| CN100588743C (en) * | 2007-04-09 | 2010-02-10 | 比亚迪股份有限公司 | A kind of acidic solution and treatment method for treating the surface of magnesium alloy |
| CN102002714A (en) * | 2009-09-01 | 2011-04-06 | 中国石油化工股份有限公司 | Wet leveling liquid composition and use thereof |
| WO2011112674A2 (en) * | 2010-03-09 | 2011-09-15 | Air Products And Chemicals, Inc. | Biodegradable amphoteric surfactants based on c6 to c11 linear or predominately linear alcohols |
Non-Patent Citations (3)
| Title |
|---|
| 孙春霖: "新型缓蚀剂重烷基苯磺酸锂的制备和应用", 《江苏化工》, no. 2, 31 December 1992 (1992-12-31) * |
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| 谢全彪: "《日用化工》", 31 August 1992, article "缓蚀剂防蚀" * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103469231A (en) * | 2013-09-11 | 2013-12-25 | 太仓市微贯机电有限公司 | Metal surface cleaning agent |
| CN103469228A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Environmentally-friendly water-based metal cleaner |
| CN103469238A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Non-phosphorus metal cleaner |
| CN103469239A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Metal cleaner |
| CN103469230A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Water-based metal brightener |
| CN103469237A (en) * | 2013-09-25 | 2013-12-25 | 太仓市微贯机电有限公司 | Metal oil contamination cleaner |
| CN103484882A (en) * | 2013-09-25 | 2014-01-01 | 太仓市微贯机电有限公司 | Environment-friendly metal cleaning agent |
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Application publication date: 20130410 |