CN103086809A - Compound-mixed-type humic acid urea and preparation method thereof - Google Patents
Compound-mixed-type humic acid urea and preparation method thereof Download PDFInfo
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- CN103086809A CN103086809A CN2013100257251A CN201310025725A CN103086809A CN 103086809 A CN103086809 A CN 103086809A CN 2013100257251 A CN2013100257251 A CN 2013100257251A CN 201310025725 A CN201310025725 A CN 201310025725A CN 103086809 A CN103086809 A CN 103086809A
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- content
- nitrogen
- urea
- humic acid
- compound
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000004202 carbamide Substances 0.000 title claims abstract description 25
- 239000004021 humic acid Substances 0.000 title claims abstract description 25
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000003337 fertilizer Substances 0.000 claims abstract description 20
- 239000002245 particle Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007791 liquid phase Substances 0.000 claims abstract description 4
- 238000012216 screening Methods 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 49
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 25
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 239000002689 soil Substances 0.000 abstract description 4
- 229910010272 inorganic material Inorganic materials 0.000 abstract description 2
- 235000015097 nutrients Nutrition 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 abstract 3
- 230000004720 fertilization Effects 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 150000002484 inorganic compounds Chemical class 0.000 abstract 1
- 230000014075 nitrogen utilization Effects 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- 238000005469 granulation Methods 0.000 description 6
- 230000003179 granulation Effects 0.000 description 6
- 239000003895 organic fertilizer Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000618 nitrogen fertilizer Substances 0.000 description 4
- 244000005700 microbiome Species 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 238000007909 melt granulation Methods 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- -1 nitrogen-containing compound Chemical class 0.000 description 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium oxide Chemical compound [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000009479 steam granulation Methods 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
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- Fertilizers (AREA)
Abstract
The invention discloses a compound-mixed-type humic acid urea and a preparation method thereof, which solves the problems that in organic and inorganic compound fertilizer production, high-nitrogen content raw materials are hard to granulate and nitrogen nutrients cannot be slowly released. The compound-mixed-type humic acid urea is characterized by being prepared by using water and partial steam condensed water generated from the reaction of humic acid with urea as liquid phase; rolling into granules at the state that a balling agent is engaged; after the granules grow to certain particle sizes, throwing out under the action of a disc centrifugal force and driving into a drier through a belt; drying till the moisture is less than or equal to 2.5%; and subsequently screening into a granular fertilizer of 2-4.75mm. The following main technical indexes are achieved: N content is more than or equal to 34%, the organic content is more than or equal to 15%, the moisture is less than or equal to 3%, and the chlorine content is less than or equal to 3%, so that organic and inorganic compound-mixed fertilization production that the nitrogen content is more than 34% is realized, and the compound-mixed-type humic acid urea is particularly applicable to crop fertilization to soil which is short of nitrogen and needs more nitrogen, and has the functions of both improving the soil and increasing the nitrogen utilization rate.
Description
Technical field
The compound organic and inorganic fertilizer preparation field that the invention belongs to is specifically related to a kind of compound type humic acid urea and preparation method thereof.
Technical background
Along with development and the change of China's agriculture production, compound organic and inorganic fertilizer more and more is subject to the approval in market due to its function that has improvement soil concurrently and improve fertilizer efficiency.But commercially available organic-inorganic compound fertilizer inorganic nutrients (total nitrogen+Vanadium Pentoxide in FLAKES+potassium oxide) multimachine inorganic composite mixed fertilizer product is 25% left and right now, especially nitrogen content is on the low side, nitrogen content is mostly in 10% left and right, the high nitrogen-containing of the compound organic and inorganic fertilizer on market also super only 15%.Nitrogen content adds the major cause that does not get on: though the nitrogen fertilizer raw material is many, nitrogen content is all on the low side, and urea (N 〉=46%) is all selected by general producer.If the low raw material of nitrogen content is arranged during the compound granulation nitrogen content does not increase, balling-up is too poor again with the high raw material of nitrogen content, bad granulation.General enterprises is produced high nitrogen-containing compound organic and inorganic fertilizer main technique has urea to melt granulation and propylhomoserin granulation, any method no matter, if nitrogen content surpasses 15%, traditional production technology can not be produced qualified particle.And nitrogen is the major ingredient of farming object internal protein, and nitrogen has the macroelement that extremely important effect is also general farm crop requirement maximum on crop alimentary, for crop turn green, protein be formed with significance.Nitrogen glut or deficiency all can cause the remarkable underproduction of crop on producing, and applied nitrogen has obvious effect of increasing production.But in traditional mixed organic manure, nitrogen content is too low, especially for some because of nitrogen stress seriously needs emphasis to mend the crop applying amount of nitrogen fertilizer application can be very large, cost up.
Summary of the invention
Purpose of the present invention overcomes above deficiency exactly, a kind of difficult problem that can break through high nitrogen-containing raw material granulation difficulty is provided, contain compound organic and inorganic fertilizer greater than 35mm with produced nitrogen than simple process, not only improve utilization rate of nitrogen fertilizer, thoroughly solved a kind of compound type humic acid urea of nitrogen stress soil application compound organic and inorganic fertilizer high expensive problem and preparation method thereof.
Technical scheme of the present invention is to realize like this, described a kind of compound type humic acid urea and preparation method thereof, it is characterized in that the water and the part vapour condensation water that utilize humic acids and urea reaction to generate are liquid phase, roll into particle under the state that becomes globule to participate in, particle grows to throw away by belt under the effect of disk centrifugal force after certain particle diameter and enters dryer, dries the granular fertilizer that obtains 2～4.75mm to the rear screening of moisture content≤2.5%.This granular fertilizer had both kept the high nitrogen-containing of urea, also kept and had strengthened the restraining effect of humic acids to urea.The preparation method of described a kind of compound type humic acids melanuria element, it is characterized in that adopting the weight part of raw material to be: urea content is 75%, humic acids content is 20%, the inhibitor acid content is 2%, becoming the globule acid content is 3%, the preparation method of described a kind of compound type humic acids melanuria element is characterized in that the key technical indexes reaches: N content 〉=34%, organic content 〉=15%, moisture content≤3%; Cl content≤3%.
The beneficial effect of a kind of compound type humic acid urea of the present invention and preparation method thereof is:
One, having nitrogen content is 35%, be much higher than of the same trade the highest 15% production level, and adopt disk steam granulation process to replace the propylhomoserin method granulation commonly used of composite fertilizer's industry and urine to melt granulation, operate simpler, production cost is lower, farthest reduce the generation of objectionable impurities biuret, guaranteed fertilizer safety.
Two, a kind of compound type humic acid urea and preparation method thereof also can be used for the nitrogen manure of microorganism organic composite fertilizer, in the situation that volume is less, can improve the nitrogen content of microorganism organic composite fertilizer, overcome again simultaneously the defective of the bad granulation of high density nitrogenous fertilizer, made the production efficiency of microorganism organic composite fertilizer improve the advantage more than 50%.
Embodiment;
the present invention is described in further detail below in conjunction with embodiment, a kind of compound type humic acid urea and preparation method thereof, be to adopt weight part to be: urea content is 75%, humic acids content is 20%, the inhibitor acid content is 2%, becoming the globule acid content is 3% to be raw material, the water and the part vapour condensation water that utilize humic acids and urea reaction to generate are liquid phase, roll into particle under the state that becomes globule to participate in, particle grows to throw away by belt under the effect of disk centrifugal force after certain particle diameter and enters dryer, dry the granular fertilizer that obtains 2～4.75mm to the rear screening of moisture content≤2.5%.Its key technical indexes is reached: N content 〉=34%, organic content 〉=15%, moisture content≤3%; The compound type humic acids melanuria element of cl content≤3%.
Claims (3)
1. compound type humic acid urea and preparation method thereof, it is characterized in that the water and the part vapour condensation water that utilize humic acids and urea reaction to generate are liquid phase, roll into particle under the state that becomes globule to participate in, particle grows to throw away by belt under the effect of disk centrifugal force after certain particle diameter and enters dryer, dries the granular fertilizer that obtains 2～4.75mm to the rear screening of moisture content≤2.5%.
2. a kind of compound type humic acid urea as claimed in claim 1 and preparation method thereof, it is characterized in that adopting the weight part of raw material to be: urea content is 75%, and humic acids content is 20%, and the inhibitor acid content is 2%, becoming the globule acid content is 3%.
3. a kind of compound type humic acid urea as claimed in claim 1 and preparation method thereof, is characterized in that the key technical indexes reaches: N content 〉=34%, organic content 〉=15%, moisture content≤3%; Cl content≤3%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2013100257251A CN103086809A (en) | 2013-01-10 | 2013-01-10 | Compound-mixed-type humic acid urea and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2013100257251A CN103086809A (en) | 2013-01-10 | 2013-01-10 | Compound-mixed-type humic acid urea and preparation method thereof |
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| CN103086809A true CN103086809A (en) | 2013-05-08 |
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| CN2013100257251A Pending CN103086809A (en) | 2013-01-10 | 2013-01-10 | Compound-mixed-type humic acid urea and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104402597A (en) * | 2014-11-07 | 2015-03-11 | 成都新柯力化工科技有限公司 | Stable phosphor-oxygen amide fertilizer and preparation method thereof |
| CN107721742A (en) * | 2017-11-09 | 2018-02-23 | 山西师范大学 | Humic acid exempts from heating and is granulated working system |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU9199882A (en) * | 1981-12-31 | 1983-07-07 | Scientific & Applied Processes Pty. Ltd. | Humus-based fertiliser compositions |
| CN1580005A (en) * | 2003-08-08 | 2005-02-16 | 张明 | Humic acid urea |
| CN1887819A (en) * | 2006-07-13 | 2007-01-03 | 杭州艾可泰投资有限公司 | Prepn of humic urea |
| WO2009078691A1 (en) * | 2007-12-19 | 2009-06-25 | Mezclas Y Fertilizantes, S.A. De C.V. | Liquid fertiliser composition |
| CN101817703A (en) * | 2010-03-13 | 2010-09-01 | 李金伟 | Compound fertilizer |
| CN102503628A (en) * | 2011-10-24 | 2012-06-20 | 山东农大肥业科技有限公司 | Preparation method of humic acid/urea long-acting nitrogen fertilizer |
| CN102731192A (en) * | 2012-07-13 | 2012-10-17 | 山西师范大学 | Humic acid compound fertilizer production process |
-
2013
- 2013-01-10 CN CN2013100257251A patent/CN103086809A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU9199882A (en) * | 1981-12-31 | 1983-07-07 | Scientific & Applied Processes Pty. Ltd. | Humus-based fertiliser compositions |
| CN1580005A (en) * | 2003-08-08 | 2005-02-16 | 张明 | Humic acid urea |
| CN1887819A (en) * | 2006-07-13 | 2007-01-03 | 杭州艾可泰投资有限公司 | Prepn of humic urea |
| WO2009078691A1 (en) * | 2007-12-19 | 2009-06-25 | Mezclas Y Fertilizantes, S.A. De C.V. | Liquid fertiliser composition |
| CN101817703A (en) * | 2010-03-13 | 2010-09-01 | 李金伟 | Compound fertilizer |
| CN102503628A (en) * | 2011-10-24 | 2012-06-20 | 山东农大肥业科技有限公司 | Preparation method of humic acid/urea long-acting nitrogen fertilizer |
| CN102731192A (en) * | 2012-07-13 | 2012-10-17 | 山西师范大学 | Humic acid compound fertilizer production process |
Non-Patent Citations (1)
| Title |
|---|
| 成绍鑫: "《腐植酸类物质概论》", 31 December 2007, 化学工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104402597A (en) * | 2014-11-07 | 2015-03-11 | 成都新柯力化工科技有限公司 | Stable phosphor-oxygen amide fertilizer and preparation method thereof |
| CN104402597B (en) * | 2014-11-07 | 2017-02-15 | 成都新柯力化工科技有限公司 | Stable phosphor-oxygen amide fertilizer and preparation method thereof |
| CN107721742A (en) * | 2017-11-09 | 2018-02-23 | 山西师范大学 | Humic acid exempts from heating and is granulated working system |
| CN107721742B (en) * | 2017-11-09 | 2021-01-01 | 山西师范大学 | Heat-free granulation production method of humic acid |
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Application publication date: 20130508 |