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CN103165694B - A kind of solar module and manufacture method thereof - Google Patents

A kind of solar module and manufacture method thereof Download PDF

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Publication number
CN103165694B
CN103165694B CN201110407403.4A CN201110407403A CN103165694B CN 103165694 B CN103165694 B CN 103165694B CN 201110407403 A CN201110407403 A CN 201110407403A CN 103165694 B CN103165694 B CN 103165694B
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China
Prior art keywords
substrate
conductive structure
battery cell
solar battery
adhesive film
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CN201110407403.4A
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Chinese (zh)
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CN103165694A (en
Inventor
骆志炯
朱慧珑
尹海洲
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Poly Day (suzhou) Technology Co Ltd
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Poly Day (suzhou) Technology Co Ltd
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Priority to CN201110407403.4A priority Critical patent/CN103165694B/en
Publication of CN103165694A publication Critical patent/CN103165694A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

A kind of solar module, this assembly includes packaging body, the first conductive structure, solaode, the second conductive structure and lower package body from top to bottom, described solaode includes multiple parallel strip solar battery cell, the front electrode of this solar battery cell includes multiple parallel pole, and the part covering described solar battery cell enters bright finish;Preferably, in the multiple parallel strip grooves during described solar battery cell is embedded in described upper packaging body and/or lower package body;Described first conductive structure includes at least first bus, and the front contact electrode of described first conductive structure and described solar battery cell;Described second conductive structure includes at least second bus, and described second conductive structure is staggered with described first conductive structure;On the surface of described upper packaging body, there is light adjustment structure.Correspondingly, present invention also offers the manufacture method of a kind of above-mentioned solar module.Solar module provided by the present invention has low cost, material saving, technique is simple, conversion efficiency is high advantage.

Description

A kind of solar module and manufacture method thereof
Technical field
The present invention relates to area of solar cell, particularly relate to a kind of solar module and Manufacture method.
Background technology
In recent years, due to the problem such as energy shortage and environmental pollution, solar energy become solution these One of scheme of problem, and developing rapidly along with solaode and semiconductor industry, solar energy Battery is widely used in every field.Since solaode comes out, how to reduce solar-electricity The cost in pond and how to improve the conversion efficiency of solaode and be always solar cell working people The target of member.
Improving the light absorbing ability of solaode is improve conversion efficiency of solar cell important One of approach, wherein, forms suede structure in solar cell surface, can efficiently reduce too Sunlight, in the reflection loss of silicon chip surface, is the raising light absorbing energy of solaode in prior art A kind of important method of power.But, form matte in solar cell surface, need at solar energy In the manufacture process of cell silicon chip, the method etched by corrosion is completed, and its processing technology is more Complicated.
And the height of solaode cost depends primarily on for manufacturing silicon chip of solar cell This height.At present, solaode is typically to be made up of the silicon chip of monoblock, or by multiple whole The silicon chip of block is in series, and wherein, the area of silicon chip is the biggest, and generating efficiency is the highest.But, Manufacturing the silicon chip not only complex process that area is bigger, cost is the highest.
Therefore, a kind of processing technology of proposition is needed badly simple, with low cost and can be effectively improved again and turn Change solar module and the manufacture method thereof of efficiency.
Summary of the invention
It is an object of the invention to provide a kind of solar module and manufacture method thereof, it makes work Skill is simple, with low cost and can be effectively improved the conversion efficiency of solaode.
According to an aspect of the present invention, it is provided that a kind of solar module, this assembly includes Packaging body, the first conductive structure, solaode, the second conductive structure and lower package body, its In: what described upper packaging body was positioned at solaode enters on bright finish, and described solaode has Front electrode and back electrode, what this front electrode and back electrode laid respectively at solaode enters bright finish and the back of the body On bright finish, described first conductive structure and the second conductive structure are electrical with described solaode respectively Connect, it is characterised in that:
Described solaode includes multiple parallel strip solar battery cell, this solar-electricity The front electrode of pool unit covers the part of described solar battery cell and enters bright finish;
Described first conductive structure includes at least first bus, and described first conductive structure Front contact electrode with described solar battery cell;
Described second conductive structure includes at least second bus, and described second conductive structure It is staggered with described first conductive structure;
On the surface of described upper packaging body and/or lower package body, there is light adjustment structure.
Preferably, during described solar battery cell is embedded in described upper packaging body and/or lower package body Strip groove in.
Another aspect of the present invention, also provides for the manufacture method of a kind of solar module, the method Including:
A) multiple strip solar battery cell is formed;
B) the plurality of strip solar battery cell is sealed supreme packaging body and lower package body it Between, it is used for embedding the plurality of strip solar battery cell, in the plurality of strip solar-electricity The entering between bright finish and upper packaging body and be respectively present between shady face and lower package body of pool unit The first conductive structure and second for being electrically connected with the plurality of strip solar battery cell are led Electricity structure;
C) on described, light adjustment structure on the surface of packaging body, is formed.
Compared with prior art, the invention have the advantages that
1) solaode is made up of the solar battery cell of multiple strips, and in prior art The full wafer silicon chip that usable floor area is bigger forms solaode and compares, and forms described solaode list Unit, its manufacturing process is simple, and cost is the most relatively low;
2) enter upper packaging body surface on bright finish and form light and adjust being positioned at solar battery cell Nodule structure, i.e. at upper packaging body surface formation suede structure to reach to fall into light effect, or upper Packaging body surface forms fresnel lens array to reach the effect of optically focused.Wherein, suede structure can By again collecting surface emitting light, to reduce the effect of surface reflection loss, the most also may be used To form sunken light at inside battery, it is reflected by internally reflective and light is trapped in inside solar energy battery, and luxuriant and rich with fragrance alunite You can converge more sunlight by lens effectively, and two kinds of structures all can improve solar energy significantly Utilization rate, thus significantly increase the conversion efficiency of battery.Additionally, in upper packaging body surface shape The technique becoming light adjustment structure is relatively simple, especially forms suede structure on upper packaging body surface Technique, compared to tradition for solar cell surface forms the technique of suede structure, the simplest Single, it is also easier to realize.
Accompanying drawing explanation
The detailed description that non-limiting example is made made with reference to the following drawings by reading, The other features, objects and advantages of the present invention will become more apparent upon:
Fig. 1 is the manufacture method stream of the solar module according to one embodiment of the present of invention Cheng Tu;
Fig. 2 to Figure 10, Figure 13 and Figure 16 are the multiple strip solar energy of the formation according to the present invention The cross-sectional schematic of battery unit each fabrication stage;
Figure 11 and Figure 12 is respectively schematic top plan view and the elevational schematic view of Figure 10;
Figure 14 and Figure 15 is respectively schematic top plan view and the elevational schematic view of Figure 13;
Figure 17 and Figure 18 is respectively schematic top plan view and the elevational schematic view of Figure 16;
Figure 19, Figure 21, Figure 23, Figure 26 and Figure 28 be according to the present invention to solar-electricity Pool unit is packaged the schematic top plan view in each stage;
Figure 20 is the cross-sectional schematic along hatching line AA ' of Figure 19;
Figure 22 is the cross-sectional schematic along hatching line AA ' of Figure 21;
Figure 24 and Figure 25 is respectively the section view along hatching line AA ' with along hatching line BB ' of Figure 23 and shows It is intended to;
Figure 27 is the cross-sectional schematic along hatching line BB ' of Figure 26;
Figure 29 is the cross-sectional schematic along hatching line AA ' of Figure 28;
Figure 30 is to cut open the edge after the solar module pressing cap rock shown in Figure 28 and bottom The cross-sectional schematic of line AA ';
Figure 31 and Figure 32 is respectively packaging body on described according to one embodiment of present invention Suede structure and cylinder or the cross-sectional schematic of fresnel lens array is formed on surface;
Figure 33 and Figure 34 is respectively packaging body on described according to another embodiment of the invention Surface on form suede structure and cylinder or the cross-sectional schematic of fresnel lens array;And
Figure 35 and Figure 36 is respectively packaging body on described according to still another embodiment of the invention Surface on form suede structure and cylinder or the cross-sectional schematic of fresnel lens array.
Detailed description of the invention
Embodiments of the invention are described below in detail, and the example of described embodiment is shown in the accompanying drawings Go out.The embodiment described below with reference to accompanying drawing is exemplary, is only used for explaining the present invention, And be not construed as limiting the claims.
Following disclosure provides many different embodiments or example for realizing the present invention's Different structure.In order to simplify disclosure of the invention, hereinafter parts and the setting to specific examples It is described.Certainly, they are the most merely illustrative, and are not intended to limit the present invention.This Outward, the present invention can in different examples repeat reference numerals and/or letter.This repeat be for Simplify and clearly purpose, itself do not indicate between discussed various embodiment and/or setting Relation.Additionally, the invention provides various specific technique and the example of material, but this Skilled person is it can be appreciated that the making of the property of can be applicable to of other techniques and/or other materials With.It should be noted that, parts illustrated in the accompanying drawings are not drawn necessarily to scale.The present invention saves Omit the description to known assemblies and treatment technology and process to avoid being unnecessarily limiting this Bright.
According to an aspect of the invention, it is provided a kind of solar module, refer to figure 31 and Figure 32.As shown in Figure 31 and Figure 32, this assembly include from top to bottom packaging body, First conductive structure, solaode, the second conductive structure and lower package body.
Wherein, described solaode is made up of multiple parallel strip solar battery cells, Each solar battery cell include at least one PN junction (with reference to shown in dotted line in Fig. 4), with And front electrode 107 (with reference to Figure 27) and back electrode 106, in the present embodiment, described PN junction position In entering the region of bright finish near solaode master, described front electrode 107 include an electrode or Multiple parallel poles, what the plurality of parallel pole was positioned at solar battery cell enters on bright finish, covers The part covering described solar battery cell enters bright finish, and sunlight is not by by described front electrode 107 surfaces covered enter inside solar battery cell;Described back electrode 106 is positioned at solar energy On the shady face of battery unit, in the present embodiment, described back electrode 106 covers solar-electricity Whole shady faces of pool unit, in other embodiments, described back electrode 106 can also only cover The part shady face of lid solar battery cell.Described solar battery cell is used for being formed The material of PN junction can be single crystalline Si, monocrystalline Ge, single crystalline Si Ge, polycrystalline Si, polycrystalline Ge, Polycrystal SiGe, amorphous Si, amorphous Ge, amorphous SiGe, III-V or II-VI group compound half One in conductor or its combination in any;Preferably, the long side of described solar battery cell Face includes the side wall that insulate, to ensure that the PN junction in solar battery cell will not be from side short circuit. The width (w in Fig. 3) of described solar battery cell is preferably smaller than 5mm;Described front electrode 107 and the material of back electrode 106 be preferably metal material, metal material conducts electricity very well,. Wherein, described metal material include Al, Cr, Cu, Ag, Au, Fe, Ni, Pb, Zn, One in Co, Ti, Mg, Sn or its combination in any.In other embodiments, before described The material of electrode 107 and back electrode 106 can also is that deposit transparent conductive oxide (Transparent Conductive Oxide, TCO), wherein, described TCO includes SnO2、 In2O3、ZnO、ITO、CdO、Cd2SnO4, one in FTO, AZO or its any group Close.When the material of described back electrode 106 is TCO material when, it may be necessary at the sun Shady face one layer of reflectance coating of coating of energy battery unit, it would be possible to the light outside cell body can be transmitted Line reflection is returned, thus strengthens the conversion efficiency of sunlight.
The solar battery cell of the plurality of strip be sealed in abreast upper packaging body and under Between packaging body, wherein, what described upper packaging body was positioned at solar battery cell enters on bright finish, Described lower package body is positioned under the shady face of solar battery cell.Preferably, described upper envelope Dress body and/or lower package body have multiple parallel strip groove 301 (with reference to Figure 19 and Figure 20), It is fixed in solar battery cell is embedded in this groove 301, it is preferable that described The size (including the length and width of groove 301) of groove 301 and the chi of solar battery cell Very little unanimously, and the quantity of described groove 301 is consistent with the quantity of solar battery cell, i.e. Solar battery cell and groove 301 one_to_one corresponding.The advantage of groove is to limit easily The position of fixed each bar shaped solaode.But groove can also be need not, such as at one Multiple bar shaped solaode is arranged, by the two of every solaode in smooth lower package body End clamping position, clamps solaode by upper packaging body and lower package body, then heats Pressurization softens packaging body can also realize the encapsulation of solaode.Wherein, described upper packaging body Can be single layer structure with lower package body, i.e. described upper packaging body is upper packaging adhesive film 304, Lower package body is lower packaging adhesive film 300, described upper packaging adhesive film 304 and lower packaging adhesive film 300 Material be preferably ethane-acetic acid ethyenyl resin copolymer (EVA), in other embodiments, described The material of upper packaging adhesive film 304 and lower packaging adhesive film 300 can also include polyvinyl butyral resin (PVB), polyethylene terephthalate (PET), PC (Merlon), PMMA (gather Methyl methacrylate), high density polyethylene (HDPE) (HDPE), polrvinyl chloride (PVC), low-density Polyethylene (LDPE), polypropylene (PP), polystyrene (PS), TPU, silicone, ionomer One in polymer, light-cured resin or its combination in any.The material of described upper packaging adhesive film 304 Expect that the material with lower packaging adhesive film 300 can be identical, it is also possible to different.Preferably, such as Figure 33 Shown in Figure 34, described upper packaging body and lower package body are double-decker, except including upper envelope Outside dress glued membrane 304 and lower packaging adhesive film 300, also include being positioned on packaging adhesive film 304 Cap rock 307 and be positioned at the bottom 308 under lower packaging adhesive film 300, described cap rock 307 Can be on the basis of upper packaging adhesive film 304 and lower packaging adhesive film 300 with bottom 308, to too Sun can be reinforced by battery unit further, plays a protective role.Wherein, described cap rock 307 Glass or polymer and combinations thereof is included with the material of bottom 308;Wherein glass includes: low ferrum glass Glass, safety glass, plate glass, textured glass, uviol, SiO2AR coating One in glass or its combination in any;And polymer includes: ethylene-tetrafluoroethylene copolymer, Polyvinyl fluoride, THV200, PET, ethane-acetic acid ethyenyl resin copolymer (EVA), polyvinyl alcohol contract Butyraldehyde (PVB), polyethylene terephthalate (PET), PC (Merlon), PMMA (gather Methyl methacrylate), high density polyethylene (HDPE) (HDPE), polrvinyl chloride (PVC), low-density gather Ethylene (LDPE), polypropylene (PP), polystyrene (PS), TPU, silicone, ionomeric One in thing, light-cured resin or its combination in any.Described cap rock 307 and the material of bottom 308 Material can be identical, it is also possible to differs.In other embodiments, according to design needs, described Upper packaging body can also be single layer structure, and lower package body is double-decker, such as Figure 35 and Tu Shown in 36, this is no longer going to repeat them.
The first conductive structure is there is between packaging body and solar battery cell, in institute on described State and between lower package body and solar battery cell, there is the second conductive structure, described first conduction Structure and the second conductive structure are for being electrically connected with the plurality of solar battery cell. In the present embodiment, described first conductive structure includes at least first bus 303 (reference Figure 26), and front electrode 107 phase of described first conductive structure and described solar battery cell Contact, it is preferable that electrode before the quantity of described first bus 303 and solar battery cell In 107, the quantity of parallel pole is identical, and the width of every first bus 303 is flat with described The width of row electrode is consistent, i.e. described first bus 303 just can and parallel pole Coincide, reduction contact resistance can be contacted to greatest extent with parallel pole.Described second leads Electricity structure includes at least second bus 302, and described second conductive structure and described the One conductive structure is staggered, wherein, and the quantity of described second bus 302 and solar-electricity The material of pool unit back electrode 106 is correlated with, if the back electrode of described solar battery cell 106 is the metal material with satisfactory electrical conductivity, the quantity of the most described second bus 302 without Need too many, even have only to an effect that can play preferably electric connection, if described The electric conductivity of solar battery cell back electrode 106 material is the most weaker compared to metal material, Such as TCO material, then can increase by the second bus according to the character of back electrode 106 material The quantity of 302, thus reach preferable conductive effect.Described first bus 303 and second The material of bus 302 includes TCO or metal material;Wherein said TCO includes: SnO2, In2O3, ZnO, ITO, CdO, Cd2SnO4, FTO, AZO or a combination thereof;Described gold Belong to material include Al, Cr, Cu, Ag, Au, Fe, Ni, Pb, Zn, Co, Ti, Mg, One in Sn or its combination in any.Described first bus 303 and the second bus 302 Material can be identical, it is also possible to different.Described first bus 303 and the second bus 302 Mid portion be sealed between described upper packaging body and lower package body, its two ends extend to described Outside upper packaging body and lower package body, for drawing front electrode 107 He of solar battery cell Back electrode 106.
Having light adjustment structure on described on the surface of packaging body, this light adjustment structure exists Before sunlight is incident upon solar battery cell, sunlight is carried out certain process, at this Reason includes falling into optical processing or optically focused processes.In order to reach to fall into the effect of light, described light regulates Structure can be suede structure 305, as shown in figure 31;In order to reach the effect of optically focused, described Light adjustment structure can be cylinder or fresnel lens array, as shown in figure 32, wherein, Described cylinder or fresnel lens array are made up of multiple cylinders or Fresnel Lenses 306, this phenanthrene Nie Er lens 306 can be upper surface be the Fresnel Lenses of dentation, utilize Fresnel Lenses table Sunlight is converged by the shape in face, it is also possible to upper surface is planar Fresnel lens, utilizes Structure within Fresnel Lenses realizes the convergence of sunlight.Wherein upper surface is the Fei Nie of plane Your lens easily facilitate cleaning and safeguard.Size according to solar battery cell and upper encapsulation The performance parameter (such as refractive index) of body material, formulates the size of Fresnel Lenses 306, thus can So that being gathered by the sunlight (arrow 500) of cylinder or Fresnel Lenses 306 and upper packaging body Burnt on bar shaped solar battery cell.
Compared with traditional solar module, the solar module tool that the present invention provides Have the advantage that
The first, solaode is made up of the solar battery cell of multiple strips, with existing The full wafer silicon chip that in technology, usable floor area is bigger forms solaode and compares, and forms the described sun Energy battery unit, its manufacturing process is simple, saves material, and cost is the most relatively low;
The second, light is formed being positioned at the upper packaging body surface that solar battery cell enters on bright finish Line adjustment structure, i.e. at upper packaging body surface formation suede structure to reach to fall into light effect, or It is to form Fresnel Lenses on upper packaging body surface to reach the effect of optically focused.Wherein, matte knot Structure can reduce the effect of surface reflection loss by again collecting surface emitting light, with Time can also form sunken light at inside battery, be reflected by internally reflective and light be trapped in inside battery, and post Face or Fresnel Lenses can converge more sunlight effectively, and two kinds of structures all can be significantly Improve the utilization rate of solar energy, thus significantly increase the conversion efficiency of battery.Additionally, upper The technique that packaging body surface forms light adjustment structure is relatively simple, especially on upper packaging body surface The technique forming suede structure, forms suede structure compared to tradition in solar cell surface For technique, the most simply, it is also easier to realize.
Correspondingly, present invention also offers the manufacture method of a kind of solar module, such as figure Shown in 1.Below, Fig. 2 to Figure 36 will be combined to the manufacturer of solar module in Fig. 1 Method is specifically described.
Referring to figs. 2 to Figure 18, in step S101, form multiple strip solaode list Unit.
Specifically, first, it is provided that substrate 100, as in figure 2 it is shown, described substrate 100 includes First surface 100-1 and the second surface 100-2 relative with first surface 100-1, wherein, institute State one that substrate 100 is Semiconductor substrate, for example, silicon, germanium and compound semiconductor or A combination thereof, includes but not limited to single crystalline Si, monocrystalline Ge, single crystalline Si Ge, described substrate 100 Can also is that polycrystalline Si, polycrystalline Ge, polycrystal SiGe, amorphous Si, amorphous Ge, amorphous SiGe, III-V or II-VI group compound semiconductor or a combination thereof or a combination thereof.In other embodiments, This substrate 100, such as deposit, epitaxial growth etc., described substrate can be generated in several ways 100 can have n-type doping configuration or p-type doping configuration.The thickness of described substrate 100 is excellent Choosing is less than 5mm.
Especially, on the first surface 100-1 and second surface 100-2 of described substrate 100 Form substrate layer 100a, and to the first surface 100-1 of described substrate 100 and second surface 100-2 is patterned.Then, with described substrate layer 100a as etching stop layer, to described lining The end 100, performs etching, and forms at least two the from the first surface 100-1 of described substrate 100 One groove 102-1, and form at least one from the second surface 100-2 of described substrate 100 Second groove 102-2, the most each described second groove 102-2 are positioned at described in adjacent two Between first groove 102-1, thus form at least two substrate 102 and at least one substrate 101 The vertical base plate array constituted, as shown in Figure 3.Owing to the thickness of described substrate 100 is less than 5mm, so utilizing the thickness of the substrate 102 that substrate 100 thickness formed (to use w in Fig. 3 Represent) again smaller than 5mm.Described substrate 102 has first surface 102b and second surface 102a, Here, the sidewall of the second groove 102-2 is called the first surface 102b of substrate, the first groove The sidewall of 102-1 is referred to as the second surface 102a of substrate 102.
Then, as shown in phantom in Figure 4, by the way of the diffusion of such as dopant ion, in institute State formation PN junction in substrate 102, i.e. when described substrate 102 has n-type doping configuration, From the first surface 102b or second surface 102a of described substrate 102, described substrate 102 is entered Row p-type alloy spreads;When described substrate 102 has p-type doping configuration, from described base The first surface 102b or second surface 102a of plate 102 carries out N-type to described substrate 102 and mixes Foreign material spread.In other embodiments, it is also possible to by the first surface at described substrate 102 102b or second surface 102a deposition has partly leading of different doping type from described substrate 102 Body layer and form PN junction.Wherein, PN tied the surface of close substrate 102 will be as the sun The master of energy battery enters bright finish, i.e. if carried out from the first surface 102b of described substrate 102 Doping, the master as solaode is entered light by the first surface 102b of the most described substrate 102 Face, if be doped from the second surface 102a of described substrate 102, the most described substrate 102 Second surface 102a the master as solaode is entered bright finish.In the present embodiment, with Illustrate as a example by the first surface 102b of described substrate 102 is doped.
Preferably, after being formed there is the substrate 102 of PN junction, by spraying, CVD, PVD, The processes such as ALD, evaporation, spin coating or a combination thereof, at least part of at vertical base plate array Flexible material layer 103 is formed on substrate 101 surface and/or at least partly substrate 102 surface, as Shown in Fig. 5.Wherein, described flexible material layer 103 includes metal, polymer, nano material In one or its combination in any.Described flexible material layer 103 has suitable flexibility, extension Property and adhesive force, it is possible to reduce substrate 102 is stretched substrate 101 in flattening process break follow-up The probability split.
Then, as shown in Figure 6, whole substrate junction is smoothly stretched from vertical base plate array two ends Structure, forms planar substrates array;As shown in Figure 7 and Figure 8, this planar substrates array is placed On conveyer belt 104, such as laser edge is utilized to be perpendicular to direction (Fig. 7 of planar substrates array The direction of middle arrow 10) cut described substrate 101 and flexible material layer 103, by base plate array It is divided into independent multiple substrates 102.
As shown in Figures 9 to 11, will be separated by modes such as sucker 105 or mechanical arms Multiple strip substrates 102 put in wafer holder 200, by methods such as selective etch, Optionally remove flexible material layer 103 or remove described substrate 101 and flexible material layer 103.When only removing flexible material layer 103, substrate 101 remains in solar-electricity The side of pool unit, as insulation side wall, is conducive to avoiding solaode list in subsequent technique The PN junction short circuit of unit.Wherein, described wafer holder 200 has multiple field, each hurdle One piece of substrate 102 can be placed in Wei, additionally, each field of described wafer holder 200 Bottom also has multiple parallel opening 201, as shown in figure 12.
After removing flexible material layer 103 or removing described substrate 101 and flexible material layer 103, Needs utilize the cleanout fluid such as such as deionized water to be carried out described substrate 102, to remove State the pollution impurity on substrate 102 surface.The end due to the described each field of wafer holder 200 Portion has multiple parallel opening 201, thereby may be ensured that during cleaning, with described The first surface 102b of the described substrate 102 that wafer holder 200 contacts can also be by very Clean well.After having cleaned, described substrate 102 is dried or anneals.
Then, electrode before the first surface 102b at the substrate 102 of the plurality of strip is formed 107 and form back electrode 106 at second surface 102a, thus form multiple solar-electricity Pool unit, refer to Figure 13 to Figure 18.As shown in FIG. 13 to 15, described wafer is used Clamper 200 is by described substrate 102 clamping sides;After being clamped by substrate 102, use evaporation Or the method for sputtering, by the opening 201 bottom wafer holder 200, at described substrate The region that the first surface 102b of 102 exposes forms front electrode 107, at the second of described substrate Surface 102a forms back electrode 106, to form solar battery cell, such as Figure 16 to Figure 18 Shown in, wherein, there is the first surface 102b of front electrode 107 using as solaode Enter bright finish, there is the second surface 102a of back electrode 106 using the backlight as solaode Face, is positioned at and includes multiple parallel electrode, the plurality of parallel electricity into the front electrode 107 on bright finish The shape of pole is consistent with the shape of wafer holder 200 bottom opening, works as solar battery cell Front electrode 107 opaque time, sunlight can be penetrated by the region between parallel pole Enter the inside of solar battery cell.Additionally, due to described substrate 102 is by wafer holder 200 Clamping, so the sidewall of substrate 102 will not form conducting film, thus avoids front electrode 107 With the short circuit of back electrode 106, if the substrate layer of retention substrate sidewall as insulation side wall; could To obtain more preferable insulation effect.The material of described front electrode 107 and back electrode 106 is preferably Metal material, metal material not only conducts electricity very well, and light tight, can be to may be saturating The light penetrating solar battery cell external reflects, and strengthens the conversion efficiency of sunlight. In other embodiments, the material of described front electrode 107 and back electrode 106 can also is that deposit Transparent conductive oxide (Transparent Conductive Oxide, TCO), wherein, described TCO includes SnO2、In2O3、ZnO、ITO、CdO、Cd2SnO4, in FTO, AZO One or its combination in any.When the material of described back electrode 106 is TCO when, can The shady face at solar battery cell can be needed to coat one layer of reflectance coating (not shown), it would be possible to The light that can transmit outside cell body reflects, thus strengthens the conversion efficiency of sunlight.
Referring to figures 19 through Figure 29, in step s 102, by the plurality of strip solar-electricity Pool unit seals between supreme packaging body and lower package body, wherein, it is preferred that described upper encapsulation Body and/or lower package body have multiple parallel strip groove 301, are used for embedding the plurality of bar Shape solar battery cell, the plurality of strip solar battery cell enter bright finish with on seal Fill between body and be respectively present for being electrically connected with described many between shady face and lower package body First conductive structure of individual strip solar battery cell and the second conductive structure.
Specifically, after the solar battery cell forming multiple strips, need it is sealed Dress, this encapsulation step is as follows: first, as illustrated in figures 19 and 20, the lower packaging adhesive film of impressing 300, described lower packaging adhesive film 300 is formed multiple parallel strip groove 301, it is preferable that The size (including the length and width of groove 301) of described parallel strip groove 301 and solar energy Battery unit equivalently-sized, and the number of the quantity of described groove 301 and solar battery cell Amount is consistent, i.e. a groove 301 can be used for fixing a solar battery cell just. Wherein, the material of described lower packaging adhesive film 300 includes ethane-acetic acid ethyenyl resin copolymer (EVA), polyvinyl butyral resin (PVB), polyethylene terephthalate (PET), PC (gather Carbonic ester), PMMA (polymethyl methacrylate), high density polyethylene (HDPE) (HDPE), polychlorostyrene Ethylene (PVC), Low Density Polyethylene (LDPE), polypropylene (PP), polystyrene (PS), TPU, One in silicone, ionomer, light-cured resin or its combination in any.
Then, as shown in figure 21 and figure, described lower packaging adhesive film 300 upper surface with And the inner surface of groove 301 forms the second conductive structure, in subsequent step by multiple too Sun can be electrically connected with by back electrode 106 by battery unit.Wherein, described second conduction knot Structure includes one or more second bus 302, the quantity of described second bus 302 and The material of solar battery cell back electrode 106 is correlated with, if described solar battery cell Back electrode 106 is the metal material with satisfactory electrical conductivity, the most described second bus 302 Quantity, without too much, even has only to an effect that can play preferably electric connection, as The electric conductivity of the most described solar battery cell back electrode 106 material is the poorest compared to metal material Some, such as TCO material, then can increase by second according to the character of back electrode 106 material The quantity of bus 302, thus reach preferable conductive effect.By at described lower packaging plastic The upper surface of film 300 and the inner surface of groove 301 carry out printing and form described second bus 302, or by the way of evaporation, or directly described second bus 302 is fitted Upper surface and the inner surface of groove 301 at described lower packaging adhesive film 300.Described second leads The material of electricity bar 302 includes TCO or metal material;Wherein said TCO includes: SnO2, In2O3, ZnO, ITO, CdO, Cd2SnO4, FTO, AZO or a combination thereof;Described gold Belong to material include Al, Cr, Cu, Ag, Au, Fe, Ni, Pb, Zn, Co, Ti, Mg, One in Sn or its combination in any.
Then, as shown in Figure 23 to Figure 25, by embedding for the plurality of strip solar battery cell Enter in the plurality of parallel strip groove 301, i.e. one by one by each solar battery cell It is fixed in a groove 301.Wherein, by solar battery cell from wafer holder 200 After middle taking-up, need to carry out described solar battery cell the upset of 180 ° so that the sun Can battery unit back electrode 106 down, consequently, it is possible to will upset after solaode list Unit is embedded in groove 301, can make the back electrode 106 of solar battery cell and described the Two bus 302 contact.
As shown in Figure 26 and Figure 27, solar battery cell is embedded in lower packaging adhesive film 300 Groove 301 in after, formed on bright finish in entering of the plurality of strip solar battery cell First conductive structure, for carrying out multiple solar battery cells electrically by front electrode 107 Connect.Wherein, described first conductive structure includes at least first bus 303, and institute State the first bus 303 to contact, preferably with the front electrode 107 of described solar battery cell Ground, the quantity of described first bus 303 is parallel with electrode before solar battery cell 107 The quantity of electrode is identical, and the width of the width of every first bus 303 and described parallel pole Degree is consistent, i.e. described first bus 303 can coincide with parallel pole just, permissible Contact with parallel pole to greatest extent, to reduce contact resistance.Described first bus 303 Can also be formed by the way of such as printing, be deposited with and fitting.Described first bus 303 Material and the second bus 302 be similar to, including TCO or metal material;Wherein said TCO Including: SnO2, In2O3, ZnO, ITO, CdO, Cd2SnO4, FTO, AZO or its Combination;Described metal material include Al, Cr, Cu, Ag, Au, Fe, Ni, Pb, Zn, Co, One in Ti, Mg, Sn or its combination in any.Wherein, the material of described first bus 303 Expect that the material with described second bus 302 can be identical, it is also possible to different.Should be noted that It is to form the second bus 302 and when the first bus 303, will be staggered the Two bus 302 and the first bus 303, it is impossible to make it contact, in case occur short circuit and Damage solar battery cell.Additionally, described first bus 303 and the second bus 302 Two ends extend to outside lower package body, for after solar battery cell is sealed, draw The front electrode 107 of solar battery cell and back electrode 106.
Finally, as shown in Figure 28 and Figure 29, packaging adhesive film 304 and described lower encapsulation in pressing Glued membrane 300 seals, wherein, and the material of described upper packaging adhesive film 304 and described lower encapsulation The material of glued membrane 300 can be identical, it is also possible to different.The material of described upper packaging adhesive film 304 Including ethane-acetic acid ethyenyl resin copolymer (EVA), polyvinyl butyral resin (PVB), gather benzene Naphthalate (PET), Merlon (PC), polymethyl methacrylate (PMMA), High density polyethylene (HDPE) (HDPE), polrvinyl chloride (PVC), Low Density Polyethylene (LDPE), poly-third In alkene (PP), polystyrene (PS), TPU, silicone, ionomer, light-cured resin One or its combination in any.Now, described upper packaging adhesive film 304 is packaging body, and under Packaging adhesive film 300 is lower package body.Preferably, as shown in figure 30, encapsulate on described Pressing cap rock 307 and bottom 308 on glued membrane 304 and under lower packaging adhesive film 300, Described cap rock 307 and bottom 308 can be at upper packaging adhesive film 304 and lower packaging adhesive films 300 On the basis of, solar battery cell is reinforced further, plays a protective role.This In the case of, described cap rock 307 and upper packaging adhesive film 304 together constitute packaging body, institute State lower package body and bottom 308 together constitutes lower package body.Described cap rock 307 and bottom 308 Material include glass or polymer and combinations thereof;Wherein glass includes: low iron glass, tempering glass Glass, plate glass, textured glass, uviol, SiO2In AR coated glass one Plant or its combination in any;And polymer includes: ethylene-tetrafluoroethylene copolymer, polyvinyl fluoride, THV200, PET, ethane-acetic acid ethyenyl resin copolymer (EVA), polyvinyl butyral resin (PVB), Polyethylene terephthalate (PET), Merlon (PC), polymethyl methacrylate (PMMA), high density polyethylene (HDPE) (HDPE), polrvinyl chloride (PVC), Low Density Polyethylene (LDPE), polypropylene (PP), polystyrene (PS), TPU, silicone, ionomer, One in light-cured resin or its combination in any.The material of described cap rock 307 and bottom 308 can With identical, it is also possible to differ.In other embodiments, according to design needs, it is also possible to only Pressing bottom 308 under lower packaging adhesive film 300, plays solar battery cell further The effect supported.
Above-mentioned encapsulation step is carried out from the bottom to top, i.e. according to lower package body, the second conduction Bar, solar battery cell, the first bus, the order of upper packaging body are packaged, at it In his embodiment, it is possible to be packaged in a reverse order, i.e. be initially formed and there is multiple putting down The upper packaging body of row groove 301, and in the inner surface shape of the surface of upper packaging body and groove 301 Become the first bus 303, then by solar battery cell from wafer holder 200 directly Move in the groove 301 of packaging body, and make the front electrode 107 and of solar battery cell One bus 303 contacts, and is subsequently formed the second bus 302, finally, by lower package body Align with upper packaging body, carry out pressing, complete the encapsulation of solar battery cell.
With reference to Figure 31 to Figure 36, in step s 103, on described on the surface of packaging body Form light adjustment structure.
Specifically, below above packaging body be to illustrate as a example by single layer structure, as shown in figure 31, Be positioned at that solar battery cell enters on bright finish described on packaging adhesive film 304 surface on shape Become suede structure 305.Wherein, suede structure 305 is formed on the surface of upper packaging adhesive film 304 Including two kinds of methods: a kind of method be on upper packaging adhesive film 304 by the way of such as boning Fixing matte mould, another kind of method is making herbs into wool on upper packaging adhesive film 304, for example, it is possible to Matte is formed, it is also possible to necessarily with packaging adhesive film 304 on acid solution or other solution corrosions Temperature, packaging adhesive film 304 in hot padding under pressure, it is also possible to use plasma process Method forms suede structure.
As shown in figure 32, it is also possible on described, on the surface of packaging adhesive film 304, cylinder is set Or fresnel lens array, this fresnel lens array is made up of multiple Fresnel Lenses 306, Wherein, described Fresnel Lenses 306 can be upper surface be the Fresnel Lenses of dentation, utilize Sunlight is converged by the shape on Fresnel Lenses surface, it is also possible to be upper surface be that plane is luxuriant and rich with fragrance Nie Er lens, utilize the structure within Fresnel Lenses to realize the convergence of sunlight.Wherein go up table Face is that the Fresnel Lenses of plane easily facilitates cleaning.The quantity of Fresnel Lenses 306 and chi Very little can join according to the performance of the size of solar battery cell and upper packaging adhesive film 304 material Number (such as refractive index) is formulated, so that by cylinder or Fresnel Lenses 306 and upper The sunlight (arrow 500) of packaging adhesive film 304 focuses on each bar shaped solar battery cell.
When upper packaging body is double-decker, i.e. upper packaging body includes packaging adhesive film 304 He The when of cap rock 307, form matte knot 305 on the surface of described cap rock 307 (such as Figure 33 institute Show) or fresnel lens array (as shown in figure 34).In other embodiments, when upper packaging body For upper packaging adhesive film 304, and the when that lower package body being lower packaging adhesive film 300 and bottom 308, On described, the surface of packaging adhesive film 304 forms matte knot 305 (as shown in figure 35) or Fresnels Lens arra (as shown in figure 36), is not repeating one by one at this.
In other embodiments, it is also possible to be initially formed suede structure or post on upper packaging body surface After face or fresnel lens array, then packaging body and lower package body in pressing, to solar-electricity Pool unit is packaged.
After the above step is finished, in described solar module, described solaode Unit efficiently utilizes the thickness of substrate, on the premise of not increasing whole substrate dimension, obtains Obtain the surface area of more machinable substrates, improve the utilization rate of substrate, compared to prior art Used in the bigger full wafer silicon chip of area for, the cost of described solar battery cell is more Low;Additionally, form light being positioned at the upper packaging body surface that solar battery cell enters on bright finish Line adjustment structure, i.e. at upper packaging body surface formation suede structure to reach to fall into light effect, or It is to form cylinder or Fresnel Lenses on upper packaging body surface to reach the effect of optically focused.Wherein, Suede structure can reduce the work of surface reflection loss by again collecting surface emitting light With, sunken light can also be formed at inside battery simultaneously, be reflected by internally reflective and light is trapped in inside battery, And Fresnel Lenses can converge more sunlight effectively, two kinds of structures all can carry significantly The utilization rate of high solar, thus significantly increase the conversion efficiency of battery.Additionally, in upper envelope The technique that dress surface forms light adjustment structure is relatively simple, especially in upper packaging body surface shape The technique becoming suede structure, forms the work of suede structure compared to tradition in solar cell surface For skill, the most simply, it is also easier to realize.
Although being described in detail about example embodiment and advantage thereof, it should be understood that without departing from In the case of the spiritual and defined in the appended claims protection domain of the present invention, can be to these Embodiment carries out various change, substitutions and modifications.For other examples, the common skill of this area Art personnel it should be readily appreciated that while keeping in scope, processing step time Sequence can change.
Additionally, the range of application of the present invention is not limited to the specific embodiment described in description Technique, mechanism, manufacture, material composition, means, method and step.From disclosure of the invention Content, will readily appreciate that as those of ordinary skill in the art, for having existed at present or Technique, mechanism, manufacture, material composition, means, method or the step will developed after person Suddenly, wherein they perform the function that is substantially the same of corresponding embodiment with present invention description or obtain They can be applied by the result that must be substantially the same according to the present invention.Therefore, the present invention Claims are intended to these technique, mechanism, manufacture, material composition, means, method Or step is included in its protection domain.

Claims (32)

1. a solar module, this assembly includes packaging body, the first conductive structure, solar energy Battery, the second conductive structure and lower package body, wherein:
What described upper packaging body was positioned at solaode enters on bright finish, and described solaode has front electricity Pole (107) and back electrode (106), this front electrode (107) and back electrode (106) lay respectively at entering of solaode On bright finish and shady face, described first conductive structure and the second conductive structure respectively with described solaode It is electrically connected with, it is characterised in that:
Described solaode includes multiple parallel strip solar battery cell, this solaode list The front electrode (107) of unit covers the part of described solar battery cell and enters bright finish;
Described first conductive structure includes at least first bus (303), and described first conductive structure Contact with the front electrode (107) of described solar battery cell;
Described second conductive structure includes at least second bus (302), and described second conductive structure Contact with the back electrode of described solaode, and described second conductive structure is tied with described first conduction Structure is staggered;
The mid portion of described first bus (303) and the second bus (302) is sealed on described Between packaging body and lower package body, its two ends extend to outside described upper packaging body and lower package body;
On the surface of described upper packaging body and/or lower package body, there is light adjustment structure.
Solar module the most according to claim 1, described upper packaging body and/or lower package body In there is strip groove (301), described solar battery cell is embedded in described upper packaging body and/or lower encapsulation In strip groove (301) in body.
Solar module the most according to claim 1, wherein, described light adjustment structure is Suede structure (305).
Solar module the most according to claim 1, wherein, described light adjustment structure is Cylindrical lens or fresnel lens array.
5. according to the solar module described in claim 1 or 3, wherein:
Described upper packaging body includes packaging adhesive film (304), or includes packaging adhesive film (304) and be positioned on this Cap rock (307) on packaging adhesive film (304);And/or
Described lower package body includes lower packaging adhesive film (300), or includes lower packaging adhesive film (300) and be positioned under this Bottom (308) under packaging adhesive film (300).
Solar module the most according to claim 5, wherein:
The material of described upper packaging adhesive film (304) and lower packaging adhesive film (300) includes that ethane-acetic acid ethyenyl fat is altogether Polymers (EVA), polyvinyl butyral resin (PVB), polyethylene terephthalate (PET), Merlon (PC), polymethyl methacrylate (PMMA), high density polyethylene (HDPE) (HDPE), polrvinyl chloride (PVC), Low Density Polyethylene (LDPE), polypropylene (PP), polystyrene (PS), TPU, silicone, ionomer are poly- One in compound, light-cured resin or its combination in any.
Solar module the most according to claim 5, wherein:
The material of described cap rock (307) and/or bottom (308) includes glass or polymer and combinations thereof;
Wherein glass includes: low iron glass, safety glass, plate glass, textured glass, saturating ultraviolet Line glass, SiO2One in AR coated glass or its combination in any;And
Polymer includes: polyvinyl fluoride, ethane-acetic acid ethyenyl resin copolymer (EVA), polyvinyl alcohol contracting fourth Aldehyde (PVB), polyethylene terephthalate (PET), Merlon (PC), poly-methyl methacrylate Ester (PMMA), high density polyethylene (HDPE) (HDPE), polrvinyl chloride (PVC), Low Density Polyethylene (LDPE), In polypropylene (PP), polystyrene (PS), TPU, silicone, ionomer, light-cured resin one Plant or its combination in any.
8. according to the solar module described in claim 1 or 3, wherein:
The material of described solar battery cell include single crystalline Si, monocrystalline Ge, single crystalline Si Ge, polycrystalline Si, Polycrystalline Ge, polycrystal SiGe, amorphous Si, amorphous Ge, amorphous SiGe, III-V or II-VI group compound Quasiconductor or a combination thereof.
9. according to the solar module described in claim 1 or 3, wherein, described front electrode (107) And/or the material of back electrode (106) includes TCO or metal material;
Wherein said TCO includes: SnO2、In2O3、ZnO、ITO、CdO、Cd2SnO4、FTO、 AZO or a combination thereof;
Described metal material include Al, Cr, Cu, Ag, Au, Fe, Ni, Pb, Zn, Co, Ti, One in Mg, Sn or its combination in any.
10. according to the solar module described in claim 1 or 3, wherein:
The material of described first conductive structure and described second conductive structure includes TCO or metal material;
Wherein said TCO includes: SnO2、In2O3、ZnO、ITO、CdO、Cd2SnO4、FTO、 AZO or a combination thereof;
Described metal material include Al, Cr, Cu, Ag, Au, Fe, Ni, Pb, Zn, Co, Ti, One in Mg, Sn or its combination in any.
11. according to the solar module described in claim 1 or 3, wherein, and described solaode The width of unit is less than 5mm.
12. solar modules according to claim 1, wherein, long at described solaode The side on limit includes the side wall that insulate.
The manufacture method of 13. 1 kinds of solar modules, the method includes:
A) multiple strip solar battery cell is formed;
B) the plurality of strip solar battery cell is sealed between supreme packaging body and lower package body, use In embedding the plurality of strip solar battery cell, in entering of the plurality of strip solar battery cell It is respectively present for being electrically connected with between bright finish and upper packaging body and between shady face and lower package body State the first conductive structure and second conductive structure of multiple strip solar battery cell;Wherein, described The mid portion of one conductive structure and the second conductive structure is sealed between described upper packaging body and lower package body, Its two ends extend to outside described upper packaging body and lower package body;
C) on described, light adjustment structure on the surface of packaging body, is formed.
14. manufacture methods according to claim 13, wherein said upper packaging body and/or lower package body In there is strip groove (301), described solar battery cell is embedded in described upper packaging body and/or lower encapsulation In strip groove (301) in body.
15. manufacture methods according to claim 13, wherein, described step c) including:
Imprint or corrode surface formation suede structure (305) of described upper packaging body.
16. manufacture methods according to claim 13, wherein, described step c) including:
Cylindrical lens or fresnel lens array are set on the surface of packaging body on described.
17. according to the manufacture method according to any one of claim 13 to 16, wherein, and described step A) including:
Substrate (100) is provided, this substrate (100) is divided into the substrate (102) of multiple strip, wherein, described Substrate (102) has first surface (102b) and the second surface (102a) relative with this first surface (102b), And there is PN junction in the region near described first surface (102b);
Electrode (107), Yi Ji before the first surface (102b) of the substrate (102) of the plurality of strip is formed Second surface (102a) forms back electrode (106).
18. manufacture methods according to claim 17, wherein, are divided into multiple by this substrate (100) The step of strip substrate (102) including:
There is provided substrate (100), described substrate (100) include first surface (100-1) and with first surface (100-1) Relative second surface (100-2), forms base on described first surface (100-1) and second surface (100-2) Lamella (100a), to the base on the first surface (100-1) of described substrate (100) and second surface (100-2) Lamella (100a) is patterned exposing the first surface (100-1) of the described substrate of part (100) and the second table Face (100-2);
The first surface (100-1) of the described substrate (100) that etching exposes and second surface (100-2) are formed extremely Few two the first grooves (102-1) and at least one the second groove (102-2), the most each described second ditch Groove (102-2) is positioned between described first groove of adjacent two (102-1), thus forms at least two substrate (102) and the vertical base plate array that constitutes of at least one substrate (101), wherein, described substrate (102) has One surface (102b) and the second surface (102a) relative with this first surface (102b);
The first surface (102b) of described substrate (102) is doped, described substrate (102) is formed PN Knot;
On at least part of substrate (101) surface of vertical base plate array and/or at least part of substrate (102) surface Upper formation flexible material layer (103);
Stretch described vertical base plate array and form planar substrates array;
Utilize substrate described in cut (101) and flexible material layer (103), base plate array is divided into independence Multiple substrates (102).
19. manufacture methods according to claim 18, wherein, are being divided into independence by base plate array Multiple substrates (102) step after also include removing described flexible material layer (103) or removing described soft Property material layer (103) and the step of described substrate (101).
20. manufacture methods according to claim 17, wherein, at the substrate (102) of the plurality of strip First surface (102b) formed before electrode (107) and second surface (102a) formed back electrode (106) Step include:
Being kept flat by described substrate (102) has in the wafer holder (200) of opening to bottom, wherein, described The first surface (102b) of substrate (102) and the bottom connection of wafer holder (200) touch, and open described in passing through Mouth expose portion first surface (102b);
Described wafer holder (200) is used described substrate both sides (102) to be clamped;
By ion implanting, the method that sprays, be deposited with or sputter, at the first table of described substrate (102) The region that face (102b) exposes forms front electrode (107), and the second surface (102a) in described substrate (102) is formed Back electrode (106).
21. manufacture methods according to claim 20, wherein, described wafer holder (200) bottom Opening be multiple parallel strip openings (201).
22. manufacture methods according to claim 17, wherein, are being divided into many by this substrate (100) After the step of the substrate (102) of individual strip, also include:
E) substrate (102) to the plurality of strip is carried out, is dried or annealing.
23. manufacture methods according to claim 17, wherein:
The material of described substrate (100) includes single crystalline Si, monocrystalline Ge, single crystalline Si Ge, polycrystalline Si, polycrystalline Ge, polycrystal SiGe, amorphous Si, amorphous Ge, amorphous SiGe, III-V or II-VI group compound are partly led Body or a combination thereof.
24. manufacture methods according to claim 17, wherein, the thickness of described substrate (100) is less than 5mm。
25. manufacture methods according to claim 18, wherein:
Described flexible material layer (103) includes the one in metal, polymer, nano material or its any group Close.
26. manufacture methods according to claim 20, wherein:
The material of described front electrode (107) and/or back electrode (106) includes TCO or metal material;
Wherein said TCO includes: SnO2、In2O3、ZnO、ITO、CdO、Cd2SnO4、FTO、 AZO or a combination thereof;
Described metal material include Al, Cr, Cu, Ag, Au, Fe, Ni, Pb, Zn, Co, Ti, One in Mg, Sn or its combination in any.
27. manufacture methods according to claim 13, wherein, described step b) including:
The lower packaging adhesive film (300) of impressing, at the strip groove that the upper formation of described lower packaging adhesive film (300) is multiple (301), and form second at the upper surface of described lower packaging adhesive film (300) and the inner surface of groove (301) to lead Electricity structure;
The plurality of strip solar battery cell is embedded in the plurality of strip groove, wherein, institute The back electrode (106) stating multiple strip solar battery cell contacts with described second conductive structure;
The first conductive structure is formed on bright finish in entering of the plurality of strip solar battery cell, wherein, Described first conductive structure contacts with the front electrode (107) of the plurality of strip solar battery cell;
In pressing, packaging adhesive film (304) seals with described lower packaging adhesive film (300);
On described on packaging adhesive film (304) and under lower packaging adhesive film (300) pressing cap rock (307) and Bottom (308).
28. manufacture methods according to claim 27, wherein:
Described first conductive structure is first bus (303) or many first parallel bus (303);And
Described second conductive structure is second bus (302) or many second parallel bus (302)。
29. according to the manufacture method described in claim 27 or 28, wherein:
The method forming described first conductive structure and the second conductive structure includes printing, is deposited with or fits.
30. according to the manufacture method described in claim 27 or 28, wherein:
The material of described upper packaging adhesive film (304) and/or lower packaging adhesive film (300) includes ethane-acetic acid ethyenyl fat Copolymer (EVA), polyvinyl butyral resin (PVB), polyethylene terephthalate (PET), poly-carbonic acid Ester (PC), polymethyl methacrylate (PMMA), high density polyethylene (HDPE) (HDPE), polrvinyl chloride (PVC), Low Density Polyethylene (LDPE), polypropylene (PP), polystyrene (PS), TPU, silicone, from One in sub-cross linked polymer, light-cured resin or its combination in any.
31. according to the manufacture method described in claim 27 or 28, wherein:
The material of described cap rock (307) and/or bottom (308) includes glass or polymer and combinations thereof;
Wherein glass includes: low iron glass, safety glass, plate glass, textured glass, saturating ultraviolet Line glass, SiO2One in AR coated glass or its combination in any;And
Polymer includes: polyvinyl fluoride, ethane-acetic acid ethyenyl resin copolymer (EVA), polyvinyl alcohol contracting fourth Aldehyde (PVB), polyethylene terephthalate (PET), Merlon (PC), poly-methyl methacrylate Ester (PMMA), high density polyethylene (HDPE) (HDPE), polrvinyl chloride (PVC), Low Density Polyethylene (LDPE), In polypropylene (PP), polystyrene (PS), TPU, silicone, ionomer, light-cured resin One or its combination in any.
32. according to the manufacture method described in claim 27 or 28, wherein:
The material of described first conductive structure and/or described second conductive structure includes TCO or metal material;
Wherein said TCO includes: SnO2、In2O3、ZnO、ITO、CdO、Cd2SnO4、FTO、 AZO or a combination thereof;
Described metal material include Al, Cr, Cu, Ag, Au, Fe, Ni, Pb, Zn, Co, Ti, One in Mg, Sn or its combination in any.
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