CN103524246A - Production process of suspending calcium dual-phase reaction organic fertilizer - Google Patents
Production process of suspending calcium dual-phase reaction organic fertilizer Download PDFInfo
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- CN103524246A CN103524246A CN201310507022.2A CN201310507022A CN103524246A CN 103524246 A CN103524246 A CN 103524246A CN 201310507022 A CN201310507022 A CN 201310507022A CN 103524246 A CN103524246 A CN 103524246A
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- organic fertilizer
- production technique
- calcium
- reaction organic
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- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 239000011575 calcium Substances 0.000 title claims abstract description 23
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 18
- 239000003895 organic fertilizer Substances 0.000 title claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 29
- 239000000843 powder Substances 0.000 claims abstract description 20
- 239000000725 suspension Substances 0.000 claims abstract description 14
- 241000208125 Nicotiana Species 0.000 claims abstract description 9
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract description 9
- 235000013555 soy sauce Nutrition 0.000 claims abstract description 9
- 239000010902 straw Substances 0.000 claims abstract description 9
- 229920001661 Chitosan Polymers 0.000 claims abstract description 7
- 229920002472 Starch Polymers 0.000 claims abstract description 7
- 235000019698 starch Nutrition 0.000 claims abstract description 7
- 239000008107 starch Substances 0.000 claims abstract description 7
- 239000002699 waste material Substances 0.000 claims abstract description 7
- 238000005507 spraying Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 18
- 230000002051 biphasic effect Effects 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- 238000004904 shortening Methods 0.000 claims description 4
- 102000002322 Egg Proteins Human genes 0.000 claims description 2
- 108010000912 Egg Proteins Proteins 0.000 claims description 2
- 241000237502 Ostreidae Species 0.000 claims description 2
- 241000209140 Triticum Species 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 210000003278 egg shell Anatomy 0.000 claims description 2
- 235000009973 maize Nutrition 0.000 claims description 2
- 235000020636 oyster Nutrition 0.000 claims description 2
- 235000019505 tobacco product Nutrition 0.000 claims description 2
- 239000010815 organic waste Substances 0.000 abstract description 7
- 239000011248 coating agent Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 4
- 235000010443 alginic acid Nutrition 0.000 abstract description 2
- 229920000615 alginic acid Polymers 0.000 abstract description 2
- 239000012528 membrane Substances 0.000 abstract description 2
- 208000035240 Disease Resistance Diseases 0.000 abstract 1
- 238000012271 agricultural production Methods 0.000 abstract 1
- 229960001126 alginic acid Drugs 0.000 abstract 1
- 239000000783 alginic acid Substances 0.000 abstract 1
- 150000004781 alginic acids Chemical class 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000003337 fertilizer Substances 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 206010006956 Calcium deficiency Diseases 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a production process of suspending calcium dual-phase reaction organic fertilizer. The biological organic fertilizer is prepared by granulating a mixture of tobacco waste, soy sauce residues, straw powder and a starch solution as a built-in material, spraying a calcium powder suspension layer, and using alginic acid and chitosan as a coating material. The organic fertilizer realizes full utilization of organic wastes from agricultural production as a raw material; the unique calcium powder suspension layer can participate in dual-phase reaction with the built-in material and the coating material, thus enhancing conversion of calcium powder and improving utilization rate of calcium; in addition, the membrane material, as an antibacterial material, can improve disease resistance of crops.
Description
Technical field
The invention belongs to chemical fertilizers production technical field, relate in particular to a kind of suspension calcium biphasic reaction membrane technique organic fertilizer production technique.
Background technology
China's fertilizer industry consumption is presenting the mineral resources such as coal, water, electricity and phosphorus, the potassium of trend ，Zhe Gei China of cumulative year after year and is bringing immense pressure.China natural resources data statistics demonstration, petroleum resources only can be used 50 years, and natural gas source only can be used 65 years, and coal only can be used 220 years, and phosphorus (richness) ore deposit only can be used 10 years.One side traditional fertilizer utilization ratio more developed country compares general ， China's nitrogenous fertilizer on the low side and potassium utilization rate is 30%, and phosphate fertilizer utilization efficiency is only 20% left and right.China's agricultural organic waste resource is considerable on the other hand, produces every year more than 700,000,000 ton of stalk, and except part is gone back field amount, quite a few has been incinerated.Nervous in power supply, common fertilizer utilization ratio is low, under the organic waste wasting of resources and the day by day concerned situation of environmental problem, utilize organic waste development of new fertilizer to become the grand strategy target of fertilizer industry technological revolution.
Calcium is very important for maintaining plant cell membrane normal configuration and physiological function, it can prevent that the nutrients such as intracellular sugar, amino acid from exosmosing, strengthen the extraneous nutrient of plasma membrane and select the ability absorbing, the invasion and attack of Antifungi, bacterium effectively again, strengthen the resistance against diseases of plant.Calcium deficiency becomes the new problem of chemical fertilizer development with replenishing the calcium.
Based on above reason and need to the invention provides a kind of suspension calcium biphasic reaction organic fertilizer production technology, this technology is to utilize calcareous powder to spray to organic waste the technology that rear parcel sodium alginate/chitosan film is produced organic fertilizer.
Summary of the invention
The object of the present invention is to provide a kind of organic waste that utilizes to do built-in material, the calcareous powder of spray ultra micro, by Lalgine and chitosan aqueous solution, carry out the organic fertilizer production technique of coating processing, wherein the calcareous powder of ultra micro is suspended in the middle of built-in material and film, both can with organic waste in organic acid reaction generate calcium of organic acid, can react with the Lalgine in coating again and generate alginate calcium, biphasic reaction is changed calcareous powder, improves the utilization ratio of calcium.
The object of the present invention is achieved like this:
Built-in material: 20 parts-30 parts of tobacco wastes, 20 parts-30 parts of soy sauce residues, after 40 parts of-50 parts of mixing of straw powder, high-temperature pressure (more than 100 ℃) dry method shortening is 1 hour, and adding concentration is that 2 parts-5 parts of 2% starch solutions carry out granulation.
Mould material: 2 parts-5 parts of Lalgines, 1 part-2 parts of chitosans, 60 parts-80 parts, water.
60 parts of-80 parts of built-in materials, through spraying after 2 parts of-3 parts of calcareous powder, carry out disk overlay film with 3 parts of-5 parts of mould materials and are products obtained therefrom.
In described built-in material tobacco waste be the tankage of tobacco manufacturing enterprise or discarded tobacco product through being crushed to 40 order-60 order products obtained therefroms, wherein moisture is below 30%, organic 70%-80%.
The tankage that in described built-in material, soy sauce residues is soy sauce brewing manufacture are through being crushed to 40 order-60 order products obtained therefroms, and wherein moisture is below 30%, organic 60%-70%.
In described built-in material straw powder be one or more of maize straw, wheat stalk or other class agricultural stalks through being crushed to 40 order-60 order products obtained therefroms, wherein moisture is below 2%.
In described built-in material, 2% starch is proportionally to add starch in 70 ℃ of-80 ℃ of warm water, and stirring and dissolving, is stored in heat insulation tank stand-by.
One or both that described calcareous powder is oyster shells, eggshell are micronizing products obtained therefrom after cleaning, being dried.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described.
Embodiment 1: a kind of suspension calcium biphasic reaction organic fertilizer production technique, built-in material: 25 parts of tobacco wastes, 20 parts of soy sauce residues, high-temperature pressure after 40 parts of mixing of straw powder (more than 100 ℃) dry method shortening 1 hour, adding concentration is that 2 parts of 2% starch solutions carry out granulation.Coated fertilizer: 2 parts of Lalgines, 1 part of chitosan, 60 parts, water mixes.60 parts of built-in materials carry out disk overlay film with 3 parts of mould materials and are products obtained therefrom after spraying 2 parts of calcareous powder.
Embodiment 2: a kind of suspension calcium biphasic reaction organic fertilizer production technique, built-in material: 30 parts of tobacco wastes, 25 parts of soy sauce residues, high-temperature pressure after 45 parts of mixing of straw powder (more than 100 ℃) dry method shortening 1 hour, adding concentration is that 3 parts of 2% starch solutions carry out granulation.Coated fertilizer: 4 parts of Lalgines, 1.5 parts of chitosans, 70 parts, water mixes.75 parts of built-in materials carry out disk overlay film with 5 parts of mould materials and are products obtained therefrom after spraying 3 parts of calcareous powder.
Claims (7)
1. a suspension calcium biphasic reaction organic fertilizer production technique, it is characterized in that, its built-in material is 20 parts-30 parts of tobacco wastes, 20 parts-30 parts of soy sauce residues, after 40 parts of-50 parts of mixing of straw powder, high-temperature pressure (more than 100 ℃) dry method shortening is 1 hour, and adding concentration is that 2 parts-5 parts of 2% starch solutions carry out granulation.
2. a suspension calcium biphasic reaction organic fertilizer production technique, is characterized in that, its mould material is 2 parts-5 parts of Lalgines, 1 part-2 parts of chitosans, 60 parts-80 parts, water.
3. a suspension calcium biphasic reaction organic fertilizer production technique, is characterized in that, its production technique is as follows, and 60 parts of-80 parts of built-in materials carry out disk overlay film with 3 parts of-5 parts of mould materials and are products obtained therefrom after spraying 2 parts of-3 parts of calcareous powder.
4. a kind of suspension calcium biphasic reaction organic fertilizer production technique according to claim 1, is characterized in that tobacco waste in described built-in material is that the tankage of tobacco manufacturing enterprise or discarded tobacco product are through being crushed to 40 order-60 order products obtained therefroms.
5. a kind of suspension calcium biphasic reaction organic fertilizer production technique according to claim 1, is characterized in that tankage that in described built-in material, soy sauce residues is soy sauce brewing manufacture are through being crushed to 40 order-60 order products obtained therefroms.
6. a kind of suspension calcium biphasic reaction organic fertilizer production technique according to claim 1, is characterized in that straw powder in described built-in material is that one or more of maize straw, wheat stalk or other class agricultural stalks are through being crushed to 40 order-60 order products obtained therefroms.
7. a kind of suspension calcium biphasic reaction organic fertilizer production technique according to claim 3, is characterized in that one or both micronizing products obtained therefroms after cleaning, being dried that described calcareous powder is oyster shells, eggshell.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310507022.2A CN103524246B (en) | 2013-10-24 | 2013-10-24 | A kind of suspension calcium biphasic reaction organic fertilizer production technique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310507022.2A CN103524246B (en) | 2013-10-24 | 2013-10-24 | A kind of suspension calcium biphasic reaction organic fertilizer production technique |
Publications (2)
| Publication Number | Publication Date |
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| CN103524246A true CN103524246A (en) | 2014-01-22 |
| CN103524246B CN103524246B (en) | 2015-08-26 |
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| CN201310507022.2A Active CN103524246B (en) | 2013-10-24 | 2013-10-24 | A kind of suspension calcium biphasic reaction organic fertilizer production technique |
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| CN1237566A (en) * | 1999-06-16 | 1999-12-08 | 中国科学院水利部水土保持研究所 | Preparation method of biological calcium fertilizer |
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| CN103524246B (en) | 2015-08-26 |
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Effective date of registration: 20171122 Address after: 264000 Shandong Province, Yantai city Zhifu District Zhuji Road No. 20 East Patentee after: Zhongde fertilizer (Yantai) Co. Ltd. Address before: 264000 Shandong Province, Yantai city Zhifu District Zhuji Road No. 20 East Patentee before: YANTAI ZHONGDE GROUP CO., LTD. |
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Address after: 264002 Shandong Province, Yantai city Zhifu District Zhuji Road No. 20 East Patentee after: Zhongde fertilizer Limited by Share Ltd Address before: 264000 Shandong Province, Yantai city Zhifu District Zhuji Road No. 20 East Patentee before: Zhongde fertilizer (Yantai) Co. Ltd. |
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Address after: 264002 20 East Pearl Road West, Zhifu District, Yantai, Shandong Patentee after: Zhongde fertilizer (Yantai) Co. Ltd. Address before: 264002 20 East Pearl Road West, Zhifu District, Yantai, Shandong Patentee before: Zhongde fertilizer Limited by Share Ltd |
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