CN103525273A - UV (ultraviolet) coating with water drop effect and preparation method thereof - Google Patents
UV (ultraviolet) coating with water drop effect and preparation method thereof Download PDFInfo
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- CN103525273A CN103525273A CN201310457282.3A CN201310457282A CN103525273A CN 103525273 A CN103525273 A CN 103525273A CN 201310457282 A CN201310457282 A CN 201310457282A CN 103525273 A CN103525273 A CN 103525273A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 19
- 238000000576 coating method Methods 0.000 title claims abstract description 19
- 230000000694 effects Effects 0.000 title claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- -1 benzyl dimethyl ketal Chemical compound 0.000 claims abstract description 5
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims abstract description 4
- 229920000728 polyester Polymers 0.000 claims abstract description 4
- 229920000570 polyether Polymers 0.000 claims abstract description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 244000028419 Styrax benzoin Species 0.000 claims description 9
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 9
- 235000008411 Sumatra benzointree Nutrition 0.000 claims description 9
- 229960002130 benzoin Drugs 0.000 claims description 9
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 9
- 235000019382 gum benzoic Nutrition 0.000 claims description 9
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 6
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 6
- 241001330002 Bambuseae Species 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 6
- 239000011425 bamboo Substances 0.000 claims description 6
- 239000003610 charcoal Substances 0.000 claims description 6
- 239000010977 jade Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 3
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 3
- 241000628997 Flos Species 0.000 claims description 3
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 3
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims description 3
- DLVOLKJQRNEXQR-UHFFFAOYSA-N butoxy ethyl hydrogen phosphate Chemical compound CCCCOOP(O)(=O)OCC DLVOLKJQRNEXQR-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 3
- 239000003973 paint Substances 0.000 abstract description 5
- 239000002253 acid Substances 0.000 abstract description 2
- 230000003666 anti-fingerprint Effects 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 abstract 1
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 abstract 1
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005507 spraying Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000003847 radiation curing Methods 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
A UV coating with a water drop effect comprises the components in parts by weight as follows: 45-50 parts of polyester acrylate, 20-24 parts of polyether acrylate, 16-18 parts of tripropylene glycol diacrylate, 4-6 parts of zinc stearate, 2-3 parts of hydroxyethyl acrylate, 2-3 parts of TBEP, 1-2 parts of nonyphenol, 1-2 parts of polyvinyl butyral, 5-8 parts of 1-hydroxy-cyclohexyl phenyl ketone, 1-2 parts of benzyl dimethyl ketal, 1-2 parts of an anti-aging agent MB and 4-5 parts of dispersing agents. The UV coating is high in curing speed, excellent in flexibility and adhesive force, low in contractibility, viscosity, acid value and odor and high in adhesive force to other paint surfaces, surface coating is facilitated, coated products are gorgeous in appearance and have an anti-fingerprint effect on surface, and the UV coating is suitable for surface coating of printed wrapped paper and plastics.
Description
Technical field
The invention belongs to paint field, relate in particular to UV coating of a kind of tool water droplet effect and preparation method thereof.
Background technology
Development along with market economy, there is great variety in paint field, wherein UV coating has the advantages such as curing speed is fast, energy-conservation, ambient cure, superior performance, environmental protection, on it, ray velocity is fast, rete luminance brightness is high, and dry rear face is firm heat-resisting, and refractive power is effective, make ground produce strong main body sense, be widely used in the fields such as chemical industry, machinery, electronics light industry, communication.Due to its environment-friendly advantage, UV solidifies and to have obtained the strong support of relevant environment rules and the close attention of industry member, and UV radiation curing material is in market requirement rapid growth, and UV Radiation-curing system is just with multiple technologies combination, to overcome some defect, meet actual application.Now in printing industry; the packing that can make UV obtains some special effects: high glossiness, good ink protection feature, the slipping that can add control and rub resistance, low smell or do not have smell, low extract maybe cannot detect extract, and the provide protection to ink.
Current UV solidify material is various, but still in various degree exist some problems, such as: Organic pollutants, xanthochromia, explosive look, not low temperature resistant, the series of problems such as cost is high, corrosion-resistant, all need to continue improvement for different purposes, reduce production costs, expand purposes.
Summary of the invention
The object of the present invention is to provide UV coating of a kind of tool water droplet effect and preparation method thereof, this coating has strong adhesion, impact-resistant feature.
Technical scheme of the present invention is as follows:
A kind of UV coating of tool water droplet effect, it is characterized in that being made by the raw material of following weight part: polyester acrylate 45-50, polyether acrylate 20-24, tri (propylene glycol) diacrylate 16-18, Zinc Stearate 4-6, Hydroxyethyl acrylate 2-3, butoxy ethyl phosphate 2-3, nonylphenol 1-2, polyvinyl butyral acetal 1-2,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5-8, benzoin dimethylether 1-2, antioxidant MB 1-2, dispersing auxiliary 4-5;
Described dispersing auxiliary is made by the raw material of following weight part: bamboo charcoal powder 4-5, jade powder 2-3, Flos Rosae Rugosae quintessence oil 1-2, xitix 1-2, pentaerythritol triacrylate 4-5, alcohol ester 12 3-4, Silane coupling agent KH550 1-2, ethyl acetate 14-18; Preparation method puts into 10-15% hydrochloric acid soln by bamboo charcoal powder, jade powder to steep 3-4 hour, takes out, with deionized water wash repeatedly, dry, be added in ethyl acetate, grind to obtain 20-40 μ m slurry, in slurry, add other remaining component, be heated to 50-55 ℃, stir 40-50 minute; Continue to be warming up to 70-75 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of the UV coating of described tool water droplet effect, it is characterized in that comprising the following steps: other composition except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, benzoin dimethylether is mixed, be warming up to 60-70 ℃, under 600-700 rev/min, stir 15-20 minute, cool to 40 ℃ and add again below 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, benzoin dimethylether, continue to stir 10-15 minute, obtain.
Beneficial effect of the present invention
Paint solidification speed of the present invention is fast, snappiness is good, sticking power is good, low-shrinkage, viscosity is low, acid value is low, smell is low, high to other lacquer painting sticking power, is convenient to external coating, product appearance after spraying is gorgeous, and there is the effect of anti-fingerprint on surface, be applicable to printed wrapper, frosting application.
Embodiment
A kind of UV coating of tool water droplet effect, by following weight part (kilogram) raw material make: polyester acrylate 48, polyether acrylate 24, tri (propylene glycol) diacrylate 17, Zinc Stearate 5, Hydroxyethyl acrylate 2, butoxy ethyl phosphate 2, nonylphenol 2, polyvinyl butyral acetal 1,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 6, benzoin dimethylether 2, antioxidant MB 2, dispersing auxiliary 4;
Described dispersing auxiliary by following weight part (kilogram) raw material make: bamboo charcoal powder 4, jade powder 2, Flos Rosae Rugosae quintessence oil 2, xitix 1.5, pentaerythritol triacrylate 4.6, alcohol ester 12, Silane coupling agent KH550 1.4, ethyl acetate 16; Preparation method puts into 14% hydrochloric acid soln by bamboo charcoal powder, jade powder to steep 3 hours, takes out, and uses deionized water wash 5 times, dry, be added in ethyl acetate, grind to obtain 25 μ m slurries, in slurry, add other remaining component, be heated to 53 ℃, stir 44 minutes; Continue to be warming up to 72 ℃, stirring reaction 2 hours, obtains.
The preparation method of the UV coating of described tool water droplet effect, comprise the following steps: other composition except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, benzoin dimethylether is mixed, be warming up to 60 ℃, under 600 revs/min, stir 18 minutes, cool to 25 ℃ and add again 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, benzoin dimethylether, continue to stir 13 minutes, obtain.
The UV coating of this tool water droplet effect can adopt the form of construction work of roller coating, showering, spraying to construct.The paint spraying making by above scheme sticking power on plank is all better than secondary, resistance to 75% ethanol is more than 24 hours, alkaline-resisting 24 hours above, acidproof more than 48 hours, the cold cycling that tolerates subzero 40 degree and 40 degree does not ftracture for 10 times, resistance to 15% salt solution is more than 70 hours, hardness can regulate between 3H at 2HB, and abrasion resistance index turns above 3000.
Claims (2)
1. the UV coating of a tool water droplet effect, it is characterized in that being made by the raw material of following weight part: polyester acrylate 45-50, polyether acrylate 20-24, tri (propylene glycol) diacrylate 16-18, Zinc Stearate 4-6, Hydroxyethyl acrylate 2-3, butoxy ethyl phosphate 2-3, nonylphenol 1-2, polyvinyl butyral acetal 1-2,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5-8, benzoin dimethylether 1-2, antioxidant MB 1-2, dispersing auxiliary 4-5;
Described dispersing auxiliary is made by the raw material of following weight part: bamboo charcoal powder 4-5, jade powder 2-3, Flos Rosae Rugosae quintessence oil 1-2, xitix 1-2, pentaerythritol triacrylate 4-5, alcohol ester 12 3-4, Silane coupling agent KH550 1-2, ethyl acetate 14-18; Preparation method puts into 10-15% hydrochloric acid soln by bamboo charcoal powder, jade powder to steep 3-4 hour, takes out, with deionized water wash repeatedly, dry, be added in ethyl acetate, grind to obtain 20-40 μ m slurry, in slurry, add other remaining component, be heated to 50-55 ℃, stir 40-50 minute; Continue to be warming up to 70-75 ℃, stirring reaction 1-2 hour, obtains.
2. the preparation method of the UV coating of tool water droplet effect according to claim 1, it is characterized in that comprising the following steps: other composition except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, benzoin dimethylether is mixed, be warming up to 60-70 ℃, under 600-700 rev/min, stir 15-20 minute, cool to 40 ℃ and add again below 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, benzoin dimethylether, continue to stir 10-15 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310457282.3A CN103525273A (en) | 2013-09-30 | 2013-09-30 | UV (ultraviolet) coating with water drop effect and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310457282.3A CN103525273A (en) | 2013-09-30 | 2013-09-30 | UV (ultraviolet) coating with water drop effect and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103525273A true CN103525273A (en) | 2014-01-22 |
Family
ID=49927638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310457282.3A Pending CN103525273A (en) | 2013-09-30 | 2013-09-30 | UV (ultraviolet) coating with water drop effect and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103525273A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105015245A (en) * | 2014-04-24 | 2015-11-04 | 无锡市科虹标牌有限公司 | Manufacturing technology of colorful crystal toughened glass decoration panel having stereoscopic water drop effect |
| CN105199458A (en) * | 2015-10-09 | 2015-12-30 | 安徽枫慧金属股份有限公司 | High-performance primer for colored aluminum application |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044666A (en) * | 1989-02-01 | 1990-08-15 | 北京大学 | Photocurable composition and its production and use |
| CN1176985A (en) * | 1997-09-18 | 1998-03-25 | 庞德春 | Wood pencil special purpose ultra-violet cured color coating and prepn. method therefor |
| CN1294163A (en) * | 1999-10-28 | 2001-05-09 | 湖南亚大化工建材有限公司 | Ultraviolet ray solidified anticorrosion decorative paint for metal |
| CN1456621A (en) * | 2003-05-28 | 2003-11-19 | 无锡市富信涂料有限公司 | Ultraviolet curing coating and preparation method thereof |
| CN1632019A (en) * | 2004-11-22 | 2005-06-29 | 中国化工建设总公司常州涂料化工研究院 | Ultraviolet curable paint for transfer of coating |
| CN101153101A (en) * | 2006-09-25 | 2008-04-02 | 德古萨有限责任公司 | Radiation-curable formulation which forms flexible coatings with increased corrosion protection on metallic substrates |
| CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
| CN102977758A (en) * | 2012-12-24 | 2013-03-20 | 上海应用技术学院 | UV (ultraviolet) photocured water-based fluorine-containing polyurethane latex film and preparation method thereof |
-
2013
- 2013-09-30 CN CN201310457282.3A patent/CN103525273A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044666A (en) * | 1989-02-01 | 1990-08-15 | 北京大学 | Photocurable composition and its production and use |
| CN1176985A (en) * | 1997-09-18 | 1998-03-25 | 庞德春 | Wood pencil special purpose ultra-violet cured color coating and prepn. method therefor |
| CN1294163A (en) * | 1999-10-28 | 2001-05-09 | 湖南亚大化工建材有限公司 | Ultraviolet ray solidified anticorrosion decorative paint for metal |
| CN1456621A (en) * | 2003-05-28 | 2003-11-19 | 无锡市富信涂料有限公司 | Ultraviolet curing coating and preparation method thereof |
| CN1632019A (en) * | 2004-11-22 | 2005-06-29 | 中国化工建设总公司常州涂料化工研究院 | Ultraviolet curable paint for transfer of coating |
| CN101153101A (en) * | 2006-09-25 | 2008-04-02 | 德古萨有限责任公司 | Radiation-curable formulation which forms flexible coatings with increased corrosion protection on metallic substrates |
| CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
| CN102977758A (en) * | 2012-12-24 | 2013-03-20 | 上海应用技术学院 | UV (ultraviolet) photocured water-based fluorine-containing polyurethane latex film and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105015245A (en) * | 2014-04-24 | 2015-11-04 | 无锡市科虹标牌有限公司 | Manufacturing technology of colorful crystal toughened glass decoration panel having stereoscopic water drop effect |
| CN105199458A (en) * | 2015-10-09 | 2015-12-30 | 安徽枫慧金属股份有限公司 | High-performance primer for colored aluminum application |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20140122 |