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CN103580105B - Charging device - Google Patents

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CN103580105B
CN103580105B CN201310336576.0A CN201310336576A CN103580105B CN 103580105 B CN103580105 B CN 103580105B CN 201310336576 A CN201310336576 A CN 201310336576A CN 103580105 B CN103580105 B CN 103580105B
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charging
voltage
secondary battery
power supply
change rate
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CN103580105A (en
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饴井俊裕
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SMK Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

本发明提供在快速充电前不进行检测二次电池的电池容量的容量测定处理,即使是不同的电池容量的二次电池,也以与其电池容量相应的适当的充电电流(Ic)进行快速充电的充电装置。在电源部用直流电力对二次电池进行充电期间,能以使上述直流电力的充电电压为二次电池的端子电压,并且由计算单元计算出的电压上升变化率为预定的设定上升变化率的方式控制上述直流电力的充电电流。

The present invention provides a method of performing rapid charging at an appropriate charging current (Ic) corresponding to the battery capacity even for secondary batteries with different battery capacities without performing capacity measurement processing for detecting the battery capacity of the secondary battery before fast charging. charging device. While the power supply unit is charging the secondary battery with direct current power, the charging voltage of the above direct current power can be made to be the terminal voltage of the secondary battery, and the voltage rise change rate calculated by the calculation unit is a predetermined set rise change rate The way to control the charging current of the above-mentioned DC power.

Description

充电装置charging device

技术领域technical field

本发明涉及对二次电池进行充电的充电装置,尤其涉及在快速充电模式中,即使进行充电的二次电池的电池容量不同,也能够利用与其电池容量一致的最适的充电电流进行充电。The present invention relates to a charging device for charging a secondary battery, and particularly relates to charging with an optimum charging current matching the battery capacity of the secondary battery being charged even if the battery capacity of the secondary battery to be charged is different in a fast charging mode.

背景技术Background technique

以往,锂离子等二次电池通常利用图3所示的CCCV(定电流定电压:ConstandCurrent Constant Voltage)充电方式进行充电。在CCCV充电方式中,如该图(b)所示,在进行施加微小的充电电流Ic并确认二次电池的端子间的电压(称为端子电压)Vb的上升的预充电后,进行利用一定电流Ik1的充电电流Ic进行充电的快速充电,在端子电压Vb(t)到达在二次电池中规定的最大充电电压Ve或将要到达之前,进行以维持最大充电电压Ve附近的端子电压Vb(t)的方式逐渐减少充电电流Ic(t)的定电压充电。在此,最大充电电压Ve是在对二次电池进行充电时容许的最大的充电电压,当以超过最大的充电电压的电压充电时,成为过充电,存在二次电池劣化或达到破损的危险。该二次电池的最大充电电压Ve不论电池容量,根据其种类大致一定,在锂离子电池的场合为4.2V。Conventionally, secondary batteries such as lithium-ion batteries are usually charged using the CCCV (Constant Current Constant Voltage) charging method shown in FIG. 3 . In the CCCV charging method, as shown in (b) of the figure, after precharging by applying a small charging current Ic and confirming the rise of the voltage between the terminals of the secondary battery (referred to as terminal voltage) Vb, a constant voltage is used. The rapid charging for charging with the charging current Ic of the current Ik1 is performed to maintain the terminal voltage Vb(t) near the maximum charging voltage Ve before the terminal voltage Vb(t) reaches or is about to reach the maximum charging voltage Ve specified in the secondary battery. ) way to gradually reduce the charging current Ic (t) constant voltage charging. Here, the maximum charging voltage Ve is the maximum charging voltage allowed when charging the secondary battery. Charging at a voltage exceeding the maximum charging voltage causes overcharging and the secondary battery may deteriorate or be damaged. The maximum charging voltage Ve of the secondary battery is substantially constant depending on the type of the battery regardless of the battery capacity, and is 4.2 V in the case of a lithium ion battery.

另一方面,在快速充电中,以一定的充电电流Ik1上升的端子电压Vb(t)的上升率(斜率)根据将要充电的二次电池的电池容量而不同,与电池容量相比,如果充电电流Ik1小,则快速充电的充电时间延长,相反,若大,则超过二次电池的自然的化学变化速度进行充电,因此二次电池的耐用年数缩短。因此,使用使以名义容量值进行完全充电的二次电池为定电流放电,在以一小时为放电结束(SOC(State of Charge)为0%)时的放电电流值为1C(C为额定放电容量值),在每个由将要充电的二次电池的电池容量所规定的1C上设定图3(a)所示的一定电流Ik1,使1C左右的充电电流Ic为定电流输出的充电装置,在快速充电中进行所谓的1C充电。如果利用1C充电进行快速充电,则能够不超过二次电池的自然的化学变化速度地在最短时间内充电到完全充电。On the other hand, in quick charging, the rising rate (slope) of the terminal voltage Vb(t) rising at a constant charging current Ik1 differs depending on the battery capacity of the secondary battery to be charged. Compared with the battery capacity, if charging If the current Ik1 is small, the charging time for quick charging is prolonged. Conversely, if the current Ik1 is large, charging is performed beyond the natural chemical change rate of the secondary battery, and thus the service life of the secondary battery is shortened. Therefore, using a secondary battery that is fully charged with a nominal capacity value as a constant current discharge, the discharge current value at the end of discharge (SOC (State of Charge) is 0%) is 1C (C is the rated discharge) capacity value), a charging device that sets a constant current Ik1 shown in Figure 3(a) for each 1C specified by the battery capacity of the secondary battery to be charged, and makes the charging current Ic of about 1C a constant current output , so-called 1C charging in fast charging. If rapid charging is performed by 1C charging, it can be charged to full charge in the shortest time without exceeding the natural chemical change rate of the secondary battery.

但是,必须准备对每个将要充电的二次电池的电池容量设定Ik1的专用的充电装置,为了解决该问题,已知有将在快速充电中进行定电流控制的充电电流Ic从二次电池侧设定为与二次电池的电池容量一致的一定电流Ik2,将即使普通的充电装置也不同的电池容量的二次电池利用对每个其电池容量所设定的最适值的充电电流Ik2进行充电的充电方式。在该充电方式中,如图4所示,使用将比二次电池的最大充电电压Ve充分高的直流电压Vk作为充电电压Vc进行定电压输出的充电装置,利用收放二次电池的设备侧的定电流控制电路,以快速充电中的充电电流Ik2为与二次电池的电池容量一致的1C的方式进行定电流控制。因此,在快速充电中,进行对二次电池进行1C充电,在大致经过一小时后,当端子电压Vb(t)到达最大充电电压Ve时,使充电电流Ic(t)下降,并将端子电压Vb维持为最大充电电压Ve的定电压充电。However, it is necessary to prepare a dedicated charging device for setting Ik1 for each battery capacity of the secondary battery to be charged. In order to solve this problem, it is known that the charging current Ic for constant current control during fast charging is transferred from the secondary battery The side is set to a constant current Ik2 consistent with the battery capacity of the secondary battery, and the charging current Ik2 of the optimum value set for each battery capacity is used for secondary batteries with different battery capacities even in ordinary charging devices. charging method. In this charging method, as shown in FIG. 4, a charging device that outputs a DC voltage Vk that is sufficiently higher than the maximum charging voltage Ve of the secondary battery as a charging voltage Vc and outputs a constant voltage is used, and the equipment side that stores and stores the secondary battery is used. The constant current control circuit performs constant current control so that the charging current Ik2 during quick charging is 1C, which is consistent with the battery capacity of the secondary battery. Therefore, in quick charging, 1C charging is performed on the secondary battery, and when the terminal voltage Vb(t) reaches the maximum charging voltage Ve after about one hour, the charging current Ic(t) is decreased and the terminal voltage Vb is charged at a constant voltage maintained at the maximum charging voltage Ve.

另外,还已知在快速充电前执行检测进行预充电的二次电池的电池容量的容量测定处理,以根据检测出的电池容量设定的充电电流Ic在快速充电中执行定电流充电处理的充电装置(专利文献1)。二次电池的电池容量从对在容量测定处理中对从充电装置向二次电池使容量检测用的已知的充电电流Io流动的充电路进行开闭控制,隔着充电电流Io流出的一定时间△t的间隔检测的两个SOC1、SOC2(单位%)得到。In addition, it is also known to execute a capacity measurement process of detecting the battery capacity of a precharged secondary battery before quick charging, and to perform charging of a constant current charging process during quick charging with a charging current Ic set based on the detected battery capacity. device (Patent Document 1). The battery capacity of the secondary battery is a certain period of time from when the charging circuit that flows the known charging current Io for capacity detection from the charging device to the secondary battery in the capacity measurement process is switched on and off, and the charging current Io flows out The two SOC1 and SOC2 (unit %) detected at the interval of Δt are obtained.

即,二次电池的电池容量由That is, the battery capacity of the secondary battery is given by

电池容量=充电电流Io·一定时间△t·100/(SOC2-SOC1)Battery capacity = charging current Io · certain time △ t · 100 / (SOC2-SOC1)

计算。其中,作为电池残留量的SOC(State of Charge)使二次电池在完全充电时为100%,与二次电池的端子间的开放电压的变化量成比例地增减,因此SOC1与SOC2从以隔着充电时间△t的前后对充电路进行打开控制的二次电池的开放电压计算。calculate. Among them, the SOC (State of Charge), which is the remaining amount of the battery, makes the secondary battery 100% when fully charged, and increases and decreases in proportion to the change in the open voltage between the terminals of the secondary battery. Therefore, SOC1 and SOC2 change from Calculate the open voltage of the secondary battery that controls the opening of the charging circuit before and after the charging time Δt.

现有技术文献prior art literature

专利文献1:日本特开2008-61373号公报Patent Document 1: Japanese Patent Laid-Open No. 2008-61373

在上述现有的图3所示的CCCV充电方式中,需要对每个二次电池的电池容量准备专用的充电装置,在快速充电中,当与电池容量相比,流过过大的充电电流Ic时,成为二次电池劣化的原因,耐用年数变短。相反地,当与电池容量相比,以过小的充电电流Ic进行定电流充电时,到完全充电的充电时间延长,无法快速充电。In the above-mentioned conventional CCCV charging method shown in FIG. 3 , it is necessary to prepare a dedicated charging device for each battery capacity of the secondary battery. During rapid charging, when compared with the battery capacity, an excessive charging current flows. When Ic, it becomes a cause of deterioration of a secondary battery, and the service life becomes short. Conversely, when constant current charging is performed with a charging current Ic that is too small compared with the battery capacity, the charging time until full charging is prolonged, and rapid charging cannot be performed.

另一方面,在图4所示的与二次电池的电池容量一致,从进行充电的二次电池侧或收放二次电池的设备侧将快速充电中的充电电流Ic(t)控制为一定电流Ik2的充电方式中,即使在快速充电中,二次电池的端子电压Vb(t)上升,由于无法从二次电池或设备侧控制从充电装置输出的充电电压Vc,因此从充电装置以定电压输出比二次电池的最大充电电压Ve充分高的直流电压Vk。其结果,尤其在快速充电中的初期,作为充电电压Vc的直流电压Vk与二次电池的端子电压Vb(t)的电位差大,通过一定电流Ik2流过,电力损失变大,并且,损失能量转换为热能等,产生无意识的温度上升。On the other hand, in accordance with the battery capacity of the secondary battery shown in FIG. 4 , the charging current Ic(t) during quick charging is controlled to be constant from the side of the secondary battery that is charged or from the side of the device that houses the secondary battery. In the current Ik2 charging method, even during rapid charging, the terminal voltage Vb(t) of the secondary battery rises, and since the charging voltage Vc output from the charging device cannot be controlled from the secondary battery or the equipment side, the charging voltage from the charging device is constant. The voltage output is a DC voltage Vk sufficiently higher than the maximum charging voltage Ve of the secondary battery. As a result, especially in the initial stage of rapid charging, the potential difference between the DC voltage Vk as the charging voltage Vc and the terminal voltage Vb(t) of the secondary battery is large, and the constant current Ik2 flows, resulting in a large power loss, and the loss Energy is converted to heat, etc., producing an involuntary temperature rise.

另外,在专利文献1记载的充电装置中,需要在快速充电前进行检测二次电池的电池容量的容量测定处理,在容量测定处理中,存在多次对充电路进行开闭控制并测定二次电池的开放电压的麻烦,其控制也复杂。In addition, in the charging device described in Patent Document 1, it is necessary to perform capacity measurement processing for detecting the battery capacity of the secondary battery before rapid charging. The open voltage of the battery is troublesome, and its control is also complicated.

另外,在每次检测电池残留量(SOC)时,由于对充电路进行打开控制,二次电池的端子电压较大地下降,因此在容量测定处理中,实质上不进行充电,存在充电效率差之类的问题。In addition, since the charging circuit is controlled to be opened every time the remaining battery capacity (SOC) is detected, the terminal voltage of the secondary battery drops greatly, so charging is not substantially performed in the capacity measurement process, and there is a problem of poor charging efficiency. class questions.

发明内容Contents of the invention

本发明的目的在于提供在快速充电前不进行检测二次电池的电池容量的容量测定处理,即使是不同的电池容量的二次电池,也以与其电池容量相应的适当的充电电流Ic(t)进行快速充电的充电装置。The purpose of the present invention is to provide a capacity measurement process for detecting the battery capacity of a secondary battery before quick charging, and to provide an appropriate charging current Ic(t) corresponding to the battery capacity even for secondary batteries with different battery capacities. A charging device for fast charging.

另外,本发明的目的在于提供从快速充电中的充电装置输出的充电电压Vc与二次电池的端子电压Vb(t)一致,不产生电力损失地进行快速充电的充电装置。Another object of the present invention is to provide a charging device that performs fast charging without power loss by matching the charging voltage Vc output from the charging device during fast charging to the terminal voltage Vb(t) of the secondary battery.

为了实现上述目的,方案一的充电装置具备用直流电力对二次电池充电的电源部、控制上述电源部的充电动作直到上述二次电池的端子电压到达预定的结束电压的电源控制部,电源控制部具有检测上述二次电池的端子电压的电压检测部、对经过时间进行计时的计时单元、依次计算以微小单位经过时间中的端子电压增加量△V表示的电压上升变化率的计算单元,在电源部用直流电力对二次电池进行充电期间,能以使上述直流电力的充电电压为二次电池的端子电压,并且用计算单元计算出的电压上升变化率为预定的设定上升变化率的方式控制上述直流电力的充电电流。In order to achieve the above object, the charging device of Scheme 1 is provided with a power supply unit for charging the secondary battery with DC power, and a power supply control unit for controlling the charging operation of the above-mentioned power supply unit until the terminal voltage of the above-mentioned secondary battery reaches a predetermined end voltage. The unit has a voltage detection unit that detects the terminal voltage of the secondary battery, a timer unit that counts the elapsed time, and a calculation unit that sequentially calculates the voltage rise and change rate represented by the terminal voltage increase amount ΔV in a minute unit of elapsed time. During the period when the power supply unit charges the secondary battery with the direct current power, the charging voltage of the direct current power can be made to be the terminal voltage of the secondary battery, and the voltage rise and change rate calculated by the calculation unit is equal to or equal to the predetermined set rise and change rate. way to control the charging current of the above DC power.

电源控制部在电源部用直流电力对二次电池进行充电期间,在计时单元计测的微小单位经过时间前后,从电压检测部检测的二次电池的端子电压的电位差得到端子电压增加量△V,计算上述微小单位经过时间中的电压上升变化率。计算出的电压上升变化率表示二次电池的充电速度,与充电电流成比例,因此通过以电压上升变化率为设定上升变化率的方式对充电电流进行可变控制,不论二次电池的电池容量如何,都能够以适于二次电池的最适的充电速度充电。The power supply control unit obtains the terminal voltage increase amount △ from the potential difference of the terminal voltage of the secondary battery detected by the voltage detection unit before and after the micro-unit elapsed time measured by the timer unit while the power supply unit is charging the secondary battery with DC power. V, calculates the rate of change of voltage rise in the above minute unit elapsed time. The calculated voltage rise and change rate indicates the charging speed of the secondary battery and is proportional to the charging current. Therefore, by setting the rise and change rate according to the voltage rise and change rate, the charging current is variably controlled regardless of the battery of the secondary battery. Regardless of the capacity, it can be charged at an optimum charging speed suitable for the secondary battery.

方案二的充电装置的特征在于,结束电压是二次电池所容许的最大充电电压,电源控制部在快速充电模式中控制上述电源部的充电动作,直到二次电池的端子电压到达比最大充电电压稍低的目标电压,将在快速充电模式下的上述设定上升变化率设定为下述场合的电压上升变化率附近:使名义容量值的二次电池为定电流放电,使以一小时成为放电结束的电流值为1C,以1C的充电电流进行充电。The charging device of Solution 2 is characterized in that the end voltage is the maximum charging voltage allowed by the secondary battery, and the power supply control unit controls the charging operation of the power supply unit in the fast charging mode until the terminal voltage of the secondary battery reaches a value higher than the maximum charging voltage. For a slightly lower target voltage, set the above-mentioned rising change rate in the fast charging mode to be close to the voltage rising change rate of the following occasion: discharge the secondary battery with the nominal capacity value at a constant current, and make it become The current value at the end of the discharge is 1C, and the charging is performed with a charging current of 1C.

直到二次电池的端子电压到达比最大充电电压稍低的目标电压,二次电池的端子电压以用大致1C的充电电流充电的场合的电压上升变化率上升。在快速充电模式中,二次电池不论其电池容量,都以与自然放电速度大致相等的充电速度充电。Until the terminal voltage of the secondary battery reaches the target voltage which is slightly lower than the maximum charging voltage, the terminal voltage of the secondary battery increases at a rate of change in voltage increase when charging with a charging current of approximately 1C. In the fast charging mode, the secondary battery is charged at a charging rate approximately equal to a natural discharge rate regardless of its battery capacity.

方案三的充电装置的特征在于,目标电压是与充电电流成比例的电压上升变化率开始下降的拐点电压。The charging device according to the third solution is characterized in that the target voltage is the inflection point voltage at which the rate of voltage increase and change proportional to the charging current starts to decrease.

当二次电池的端子电压超过拐点电压时,即使施加相同的充电电流,端子电压的上升率也急剧地下降,供给到二次电池的电能转换为热能的比例增加,导致充电效率恶化。因此,在到达充电效率将要恶化之前的拐点电压的时机,结束使端子电压以在用大致1C的充电电流进行充电的场合的电压上升变化率上升的快速充电模式。When the terminal voltage of the secondary battery exceeds the inflection point voltage, even if the same charging current is applied, the rate of increase of the terminal voltage drops sharply, and the rate of conversion of electric energy supplied to the secondary battery to heat increases, deteriorating charging efficiency. Therefore, the rapid charging mode in which the terminal voltage is increased at a rate of change in voltage increase when charging with a charging current of approximately 1C is terminated at the timing of reaching the inflection point voltage just before the charging efficiency deteriorates.

方案四的充电装置的特征在于,电源控制部在二次电池的端子电压到达上述目标电压后,以微调充电模式控制上述电源部的充电动作直到最大充电电压,将微调充电模式下的上述设定上升变化率设定为比快速充电模式下的上述设定上升变化率充分低的值。The charging device of Solution 4 is characterized in that, after the terminal voltage of the secondary battery reaches the above-mentioned target voltage, the power supply control part controls the charging operation of the above-mentioned power supply part to the maximum charging voltage in the fine-tuning charging mode, and the above-mentioned setting in the fine-tuning charging mode The rate of change of rise is set to a value sufficiently lower than the rate of change of rise set in the quick charge mode.

在二次电池的端子电压到达上述目标电压后,直到最大充电电压,二次电池的端子电压的电压上升变化率比快速充电模式快速下降,因此端子电压逐渐接近最大充电电压,不会为端子电压超过最大充电电压的过充电。After the terminal voltage of the secondary battery reaches the above-mentioned target voltage, until the maximum charging voltage, the voltage rise and change rate of the terminal voltage of the secondary battery decreases rapidly compared with the fast charging mode, so the terminal voltage gradually approaches the maximum charging voltage, and will not be the terminal voltage Overcharging exceeding the maximum charging voltage.

如果目标电压是拐点电压,则在到达拐点电压后,充电电流下降,因此在抑制发热的状态下,端子电压到达最大充电电压。If the target voltage is an inflection point voltage, the charging current decreases after reaching the inflection point voltage, so that the terminal voltage reaches the maximum charging voltage while heat generation is suppressed.

方案五的充电装置是方案一至四任一项所述的充电装置,其特征在于,电源部是通过串联地连接在至少比结束电压高的直流电压的直流输入电压间的开关元件的开闭,向二次电池的充电端子间输出上述直流电力的断路式降压转换器,电源控制部以由上述计算单元计算出的电压上升变化率与上述设定上升变化率一致的方式增减对上述开关元件进行开闭控制的脉冲宽度调制信号的接通能率,从而调整上述电压上升变化率。The charging device of claim 5 is the charging device described in any one of claims 1 to 4, characterized in that the power supply unit is connected in series by switching of a switching element between at least a DC input voltage of a DC voltage higher than the end voltage, In the open-circuit step-down converter that outputs the DC power between the charging terminals of the secondary battery, the power supply control unit increases or decreases the switching voltage of the switch so that the rate of voltage rise and change calculated by the calculation unit coincides with the set rate of rise and change. The on-off energy rate of the pulse width modulation signal for on-off control of the element is adjusted to adjust the above-mentioned voltage rise and change rate.

从断路式降压转换器输出的直流电力的大小依赖于对开关元件进行关闭控制的脉冲宽度调制信号的接通能率,因此根据接通能率的增减,对二次电池进行充电的直流电力增减。断路式降压转换器的输出电压是二次电池的端子电压,因此直流电力的增减表现为充电电流的增减,与充电电流成比例的电压上升变化率也增减。因此,通过调整脉冲宽度调制信号的接通能率,能够使由计算单元计算出的电压上升变化率与设定上升变化率一致。The magnitude of the DC power output from the off-type step-down converter depends on the on-duty rate of the pulse width modulation signal that controls the switching element to be turned off. Therefore, the DC power to charge the secondary battery increases or decreases according to the increase or decrease in the on-duty rate. reduce. The output voltage of the open circuit step-down converter is the terminal voltage of the secondary battery, so the increase and decrease of the DC power appear as the increase and decrease of the charging current, and the rate of change of the voltage rise proportional to the charging current also increases and decreases. Therefore, by adjusting the on-duty rate of the pulse width modulation signal, the voltage rise and change rate calculated by the calculation unit can be made to coincide with the set rise and change rate.

本发明的效果如下。The effects of the present invention are as follows.

根据方案一的发明,通过在快速充电前不进行检测二次电池的电池容量的容量测定处理,即使是不同的电池容量的二次电池,也任意地设定设定上升变化率,能够以与其电池容量相应的最适的充电速度对二次电池进行充电。因此不需要对每个将要充电的二次电池准备专用的充电装置,能够作为对多种二次电池进行充电的充电装置通用。According to the invention of claim 1, by not performing the capacity measurement process of detecting the battery capacity of the secondary battery before quick charging, even if it is a secondary battery with a different battery capacity, the rate of increase and change can be set arbitrarily, which can be compared with The secondary battery is charged at an optimum charging speed corresponding to the battery capacity. Therefore, it is not necessary to prepare a dedicated charging device for each secondary battery to be charged, and it can be used as a common charging device for charging multiple types of secondary batteries.

另外,由于在使充电电压与二次电池的端子电压一致的状态下对二次电池进行充电,因此由两者的电压差引起的电力损失小,能够不产生无谓的发热地进行充电。In addition, since the secondary battery is charged with the charging voltage equal to the terminal voltage of the secondary battery, the power loss due to the voltage difference between the two is small, and charging can be performed without unnecessary heat generation.

根据方案二的发明,不论进行充电的二次电池的电池容量如何,都能够以不使二次电池劣化的最快速的充电速度进行充电。According to the invention of Claim 2, irrespective of the battery capacity of the secondary battery to be charged, it is possible to charge at the fastest charging speed that does not degrade the secondary battery.

根据方案三的发明,由于在到达拐点的时机结束电压上升变化率高的快速充电模式,因此能够防止充电效率下降。According to the invention of claim 3, since the fast charging mode with a high voltage rise and change rate is terminated at the timing when the inflection point is reached, it is possible to prevent a decrease in charging efficiency.

根据方案四的发明,不会由于过充电而使二次电池劣化。According to the invention of Claim 4, the secondary battery does not deteriorate due to overcharging.

另外,如果目标电压是拐点电压,则在超过了拐点电压的微调充电模式中,由于充电电压充分下降,因此能够抑制发热,不会使充电效率较大地下降地充电到最大充电电压。Also, if the target voltage is the knee point voltage, in the trim charging mode exceeding the knee point voltage, since the charging voltage is sufficiently lowered, heat generation can be suppressed, and the charging efficiency can be charged to the maximum charging voltage without greatly reducing the charging efficiency.

根据方案五的发明,能够只通过在使充电电压为端子电压的状态下,调整对开关元件进行开闭控制的脉冲宽度调制信号的接通能率,使电压上升变化率与设定上升变化率一致。According to the invention of Solution 5, it is possible to make the voltage rise and change rate coincide with the set rise and change rate only by adjusting the turn-on energy rate of the pulse width modulation signal that controls the switching element on and off while the charging voltage is in the state of the terminal voltage. .

附图说明Description of drawings

图1是对二次电池10进行充电的本发明的一个实施方式的充电装置1的电路图。FIG. 1 is a circuit diagram of a charging device 1 according to an embodiment of the present invention that charges a secondary battery 10 .

图2(a)是表示在利用充电装置1对二次电池10进行充电期间,从充电装置1输出的充电电压Vc与充电电流Ic的关系的图表,(b)是表示在利用充电装置1对二次电池10进行充电期间,端子电压波形Vb(t)与充电电流波形Ic(t)的图表。2( a ) is a graph showing the relationship between the charging voltage Vc output from the charging device 1 and the charging current Ic during charging the secondary battery 10 by the charging device 1 , and (b) is a graph showing the relationship between the charging device 1 and the charging current Ic. A graph of the terminal voltage waveform Vb(t) and the charging current waveform Ic(t) while the secondary battery 10 is being charged.

图3(a)是表示在利用现有的CCCV充电方式对二次电池进行充电期间,从充电装置输出的充电电压Vc与充电电流Ic的关系的图表,(b)是表示在利用现有的CCCV充电方式对二次电池进行充电期间,端子电压波形Vb(t)与充电电流波形Ic(t)的图表。Figure 3 (a) is a graph showing the relationship between the charging voltage Vc output from the charging device and the charging current Ic during the charging of the secondary battery using the existing CCCV charging method, and (b) shows the relationship between the charging current Ic and the charging current Ic using the existing CCCV charging method. Graphs of the terminal voltage waveform Vb(t) and the charging current waveform Ic(t) during the charging of the secondary battery by the CCCV charging method.

图4(a)是表示在利用现有的其他充电方式对二次电池进行充电期间,从充电装置输出的充电电压Vc与充电电流Ic的关系的图表,(b)是表示在利用现有的其他充电方式对二次电池进行充电期间,端子电压波形Vb(t)与充电电流波形Ic(t)的图表。Figure 4(a) is a graph showing the relationship between the charging voltage Vc output from the charging device and the charging current Ic during the charging of the secondary battery by other existing charging methods, and (b) is a graph showing the relationship between the charging current Ic and Graphs of the terminal voltage waveform Vb(t) and the charging current waveform Ic(t) during the charging of the secondary battery by other charging methods.

图中:1-充电装置,2-电源部,3-电源控制部,4-开关元件(开关元件),9-微处理器(计算单元),10-二次电池,12-端子电压检测电路,15-计时电路(计时单元)。In the figure: 1-charging device, 2-power supply unit, 3-power supply control unit, 4-switching element (switching element), 9-microprocessor (computing unit), 10-secondary battery, 12-terminal voltage detection circuit , 15 - timing circuit (timing unit).

具体实施方式detailed description

下面,根据图1与图2说明本发明的一个实施方式的充电装置1。如图1所示,充电装置1包括用直流电力对二次电池10进行充电的电源部2、控制电源部2的输出的电源控制部3。Next, a charging device 1 according to an embodiment of the present invention will be described with reference to FIGS. 1 and 2 . As shown in FIG. 1 , the charging device 1 includes a power supply unit 2 for charging a secondary battery 10 with direct current power, and a power supply control unit 3 for controlling the output of the power supply unit 2 .

电源部2由对被连接在一对输入2a、2b间的平滑电容器11平滑化的直流电源20的输入电压Vin进行降压,并且输出到一对输出2c、2d间的断路式降压转换器构成,具备连接在低压侧输入2b与低压侧输出2d间的开关元件4、连接在高压侧输入2a与高压侧输出2c间的感应器6、连接在一对输出2c、2d间的电容器7、连接在高压侧输入2a与低压侧输出2d间的逆流防止用开关元件。The power supply unit 2 steps down the input voltage Vin of the DC power supply 20 smoothed by the smoothing capacitor 11 connected between the pair of inputs 2a and 2b, and outputs it to an open-circuit step-down converter between the pair of outputs 2c and 2d. The structure includes a switching element 4 connected between the low-voltage side input 2b and the low-voltage side output 2d, an inductor 6 connected between the high-voltage side input 2a and the high-voltage side output 2c, a capacitor 7 connected between the pair of outputs 2c and 2d, A switching element for preventing backflow connected between the high-voltage side input 2a and the low-voltage side output 2d.

开关元件4是使漏极与信号源分别在低压侧输出2d与低压侧输入2b,将口连接在电源控制部3的后述的驱动电路17上的三端子式电场效果晶体管,利用从驱动电路17输出的正向开关控制信号对漏极-信号源间进行开闭控制。The switch element 4 is a three-terminal electric field effect transistor that makes the drain and the signal source output 2d and input 2b at the low voltage side respectively, and connects the port to the drive circuit 17 described later in the power supply control section 3. The forward switch control signal output by 17 controls the switch between the drain and the signal source.

逆流防止用开关元件也是使漏极在高压侧输入2a,使信号源在低压侧输出2d,将口连接在电源控制部3的驱动电路17上的三端子式电场效果晶体管,在利用从驱动电路17输出的回扫控制信号对开关元件4进行关闭控制期间,以阻止从高压侧输入2a向低压侧输入2b流动的电流的方式,对漏极-信号源之间进行断开控制,在对开关元件4进行打开控制期间,以使利用感应器6的回扫动作产生的从低压侧输出2d侧向高压侧输出2c的放电电流流动的方式对漏极-信号源之间进行导通控制。因此,可以代替该逆流防止用开关元件,使用以从低压侧输入2b向高压侧输入2a为顺方向的二极管。The switching element for backflow prevention is also a three-terminal electric field effect transistor with the drain input 2a on the high voltage side, the signal source output 2d on the low voltage side, and the port connected to the drive circuit 17 of the power control part 3. During the turn-off control of the switching element 4 by the flyback control signal output by 17, the disconnection control is performed between the drain and the signal source by preventing the current flowing from the high-voltage side input 2a to the low-voltage side input 2b. While the element 4 is being turned on, conduction between the drain and the signal source is controlled so that a discharge current from the low-side output 2d side to the high-side output 2c flows due to the flyback operation of the inductor 6 . Therefore, instead of the switching element for backflow prevention, a diode may be used in the forward direction from the low-voltage side input 2b to the high-voltage side input 2a.

高压侧输出2c与低压侧输出2d分别通过高压侧充电线8a与低压侧充电线8b直接连接在二次电池10的一对端子10a、10b上。由此,电源部(断路式降压转换器)2的一对输出2c、2d间的输出电压与利用电源部2进行充电的二次电池10的一对端子10a、10b间的端子电压Vb一致。The high-voltage side output 2c and the low-voltage side output 2d are directly connected to a pair of terminals 10a, 10b of the secondary battery 10 through a high-voltage side charging line 8a and a low-voltage side charging line 8b, respectively. Thus, the output voltage between the pair of outputs 2c and 2d of the power supply unit (open-circuit step-down converter) 2 matches the terminal voltage Vb between the pair of terminals 10a and 10b of the secondary battery 10 charged by the power supply unit 2 . .

用电源部2的直流电力进行充电的二次电池10是最大充电电压为4.2V,名义电压为3.7V的锂离子电池,锂离子电池耐不住超过最大充电电压的过电压,因此在此将使充电停止的结束电压作为最大充电电压4.2V,电压控制部3进行在一对输出2c、2d间的输出电压、即端子电压Vb到达4.2V的时机停止充电的充电控制。如上所述,在电压部2上使用使输入电压Vin降压的断路式降压转换器,因此直流电源20的输入电压Vin为至少比端子电压Vb的最大值4.2V高的电压。The secondary battery 10 charged by the DC power of the power supply unit 2 is a lithium-ion battery with a maximum charging voltage of 4.2V and a nominal voltage of 3.7V. Lithium-ion batteries cannot withstand overvoltages exceeding the maximum charging voltage. The end voltage of the charging stop is set as the maximum charging voltage 4.2V, and the voltage control unit 3 performs charging control to stop charging when the output voltage between the pair of outputs 2c and 2d, that is, the terminal voltage Vb reaches 4.2V. As described above, since the open-circuit step-down converter for stepping down the input voltage Vin is used in the voltage unit 2 , the input voltage Vin of the DC power supply 20 is at least higher than the maximum value of 4.2V of the terminal voltage Vb.

如图1所示,电源控制部3具备微处理器9、以数msec的周期检测输出2c、2d间的端子电压Vb并向微处理器9输出的端子电压检测电路12、除了微处理器9的执行程序外、存储在每个进行充电的二次电池10中所规定的结束电压或后述的目标电压、设定上升变化率等的ROM13、根据介于低压侧充电线8b之间的分电阻18的电压下降总是监视在低压侧充电线8b中流动的充电电流Ic并向微处理器9输出的充电电流检测电路14、将计时信息向微处理器9输出的计时电路15、检测直流电源20的输入电压Vin并向微处理器9输出的输入电压检测电路16及控制开关元件4和逆流防止用开关元件的动作的驱动电路17。微处理器9还连接在配置在二次电池10的附近的温度传感器19上,从温度传感器19输入二次电池10的温度信息。As shown in FIG. 1 , the power supply control unit 3 includes a microprocessor 9, a terminal voltage detection circuit 12 that detects the terminal voltage Vb between the output 2c and 2d at a cycle of several msec, and outputs it to the microprocessor 9. In addition to the microprocessor 9 Outside the execution program of the secondary battery 10 to be charged, the ROM 13 that stores the end voltage or the target voltage described later, setting the rate of change, etc. specified in each secondary battery 10 to be charged is based on the distribution between the low-voltage side charging lines 8b. The voltage drop of the resistor 18 always monitors the charging current Ic flowing in the low-voltage side charging line 8b and outputs the charging current detection circuit 14 to the microprocessor 9, the timing circuit 15 that outputs the timing information to the microprocessor 9, and detects the DC voltage. The input voltage Vin of the power supply 20 is output to the microprocessor 9 by the input voltage detection circuit 16 and the drive circuit 17 which controls the operation of the switching element 4 and the switching element for backflow prevention. The microprocessor 9 is also connected to a temperature sensor 19 disposed near the secondary battery 10 , and temperature information of the secondary battery 10 is input from the temperature sensor 19 .

在后述的高速充电模式中,由驱动电路17对开关元件4(FET的口)进行开闭控制的正向开关控制信号是以1μsec的周期使H电平与L电平反复的矩形波信号,在矩形波信号是H电平时,低压侧输出2d与低压侧输入2b导通。另外,由驱动电路17对逆流防止用开关元件5(FET的口)进行开闭控制的回扫控制信号是使上述正向开关控制信号的极性反转,并同步地输出到正向开关控制信号的信号,在对开关元件4进行关闭控制的期间,将L电平的矩形波信号向逆流防止用开关元件5输出,对高压侧输入2a与低压侧输出2d间进行遮断。因此,在对开关元件4进行关闭控制的接通期间中,直流电源20的输入电压Vin与端子电压Vb的电压差施加在感应器6上,对感应器6进行充电,将电能转换为磁能。In the high-speed charging mode described later, the forward switching control signal for switching the switching element 4 (the port of the FET) by the drive circuit 17 is a rectangular wave signal that repeats the H level and the L level in a period of 1 μsec. , when the rectangular wave signal is at the H level, the low-voltage side output 2d is connected to the low-voltage side input 2b. In addition, the flyback control signal for opening and closing the backflow prevention switching element 5 (FET port) by the drive circuit 17 inverts the polarity of the above-mentioned forward switching control signal and outputs it to the forward switching control signal synchronously. The signal of the signal outputs an L-level rectangular wave signal to the backflow prevention switching element 5 while the switching element 4 is being turned off, and blocks the high-voltage side input 2a and the low-voltage side output 2d. Therefore, during the ON period when the switching element 4 is turned off, the voltage difference between the input voltage Vin of the DC power supply 20 and the terminal voltage Vb is applied to the inductor 6 to charge the inductor 6 and convert electric energy into magnetic energy.

另一方面,在向开关元件4输出L电平的矩形波信号,对开关元件4进行打开控制的断开期间,向逆流防止用开关元件5输出H电平的矩形波信号,使高压侧输入2a与低压侧输出2d间导通,因此在接通期间蓄积在感应器6中的磁能成为电能即充电电流Ic,对并联地连接在感应器6的两端的二次电池10与电容器7进行充电。On the other hand, during the off-period during which an L-level rectangular wave signal is output to the switching element 4 to open the switching element 4, an H-level rectangular wave signal is output to the backflow prevention switching element 5, so that the high-voltage side input 2a conducts with the low-voltage side output 2d, so the magnetic energy accumulated in the inductor 6 during the ON period becomes electric energy, that is, the charging current Ic, which charges the secondary battery 10 and the capacitor 7 connected in parallel to both ends of the inductor 6 .

其中,在作为接通期间与断开期间的和的一周期(1μsec)中,在电源部2的输出2c、2d上产生的电能与一周期中的接通期间的比、即接通能率成比例。在输出2c、2d上产生的电能作为直流电力对二次电池10进行充电,但输出2c、2d连接在二次电池10的一对端子10a、10b上,因此输出2c、2d间的输出电压与端子10a、10b间的端子电压Vb相等,与接通能率成比例地增减的直流电力表示为对二次电池10进行充电的充电电流Ic的增减。Here, in one cycle (1 μsec) which is the sum of the ON period and the OFF period, the electric energy generated at the outputs 2c and 2d of the power supply unit 2 is proportional to the ratio of the ON period in one cycle, that is, the ON energy rate. Proportion. The electric energy generated on the outputs 2c, 2d charges the secondary battery 10 as DC power, but the outputs 2c, 2d are connected to the pair of terminals 10a, 10b of the secondary battery 10, so the output voltage between the outputs 2c, 2d is the same as The terminal voltage Vb between the terminals 10 a and 10 b is equal, and the DC power that increases or decreases in proportion to the conduction rate is expressed as an increase or decrease in the charging current Ic for charging the secondary battery 10 .

因此,在本实施方式中,使作为矩形波信号的正向开关控制信号为以从微处理器9输出的规定的控制数据进行调制的PWM(脉冲宽度调制)信号,根据二次电池10的充电状况,利用从微处理器9向驱动电路17输出的控制数据,使正向开关控制信号的接通能率变化,从而对充电电流Ic进行增减控制。Therefore, in this embodiment, the forward switching control signal which is a rectangular wave signal is a PWM (Pulse Width Modulation) signal modulated with predetermined control data output from the microprocessor 9. In other words, by using the control data output from the microprocessor 9 to the drive circuit 17, the turn-on rate of the forward switch control signal is changed, thereby controlling the increase and decrease of the charging current Ic.

下面,分为图2(b)所示的预充电、快速充电、微调充电的各模式以微处理器9的动作为中心说明将作为锂离子电池的二次电池10充电到结束电压Ve的充电装置1的充电过程。Next, the charging of the secondary battery 10 as a lithium ion battery to the end voltage Ve will be described centering on the operation of the microprocessor 9 in each mode of pre-charging, quick charging, and fine-tuning charging shown in FIG. 2( b ). The charging process of device 1.

(预充电模式A)(precharge mode A)

在预充电模式中,在对二次电池10进行充电前,判断是否在二次电池10或充电电路中存在异常,在确认异常的场合,不转移到快速充电模式,中止充电。In the pre-charge mode, before charging the secondary battery 10, it is determined whether there is an abnormality in the secondary battery 10 or the charging circuit, and if an abnormality is confirmed, the charging is stopped without shifting to the rapid charging mode.

微处理器9在开始预充电模式的t0时,存储端子电压检测电路12、充电电流检测电路14、输入电压检测电路16、温度传感器19分别检测的端子电压Vb、充电电流Ic、输入电压Vin、二次电池10的温度Tb,同时,向驱动电路17输出控制数据,使电源部2进行动作,其中,输出数据输出正向开关控制信号与回扫控制信号。其中,输出到驱动电路17的控制数据利用脉冲宽度调制使正向开关控制信号的接通期间为短时间,因此,如图2A所示,在预充电模式中,利用微小的充电电流Ic(t)对二次电池10进行充电。When the microprocessor 9 starts the t0 of the precharge mode, the terminal voltage Vb, the charging current Ic, and the input voltage Vin detected by the terminal voltage detection circuit 12, the charging current detection circuit 14, the input voltage detection circuit 16, and the temperature sensor 19 are stored respectively. , the temperature Tb of the secondary battery 10, and at the same time, output control data to the drive circuit 17 to make the power supply unit 2 operate, wherein the output data output a forward switch control signal and a flyback control signal. Wherein, the control data output to the drive circuit 17 utilizes pulse width modulation to make the ON period of the forward switch control signal short, so, as shown in FIG. ) to charge the secondary battery 10 .

之后,微处理器9将由计时电路15计时的规定时间后的t1时的端子电压Vb、充电电流I、输入电压Vin、二次电池10的温度Tb分别从端子电压检测电路12、充电电流检测电路14、输入电压检测电路16、温度传感器19输入,在与t0时的值比较,任一个检测值存在异常值的场合,例如端子电压Vb(t)不上升的、充电电流Ic(t)不处于以控制数据预测的值的范围的、输入电压Vin是结束电压以下的、二次电池的温度Tb异常地上升等的场合,中止充电。充电中止使从微处理器9输出的正向开关控制信号总是为L电平,对开关元件4进行打开控制。After that, the microprocessor 9 detects the terminal voltage Vb, the charging current I, the input voltage Vin, and the temperature Tb of the secondary battery 10 at t1 after the predetermined time counted by the timer circuit 15 from the terminal voltage detection circuit 12 and the charging current detection circuit 12, respectively. The circuit 14, the input voltage detection circuit 16, and the temperature sensor 19 input, and when compared with the value at t 0 , any one of the detected values has an abnormal value, for example, if the terminal voltage Vb(t) does not rise, the charging current Ic(t) If the value is not within the range predicted by the control data, if the input voltage Vin is below the end voltage, if the temperature Tb of the secondary battery rises abnormally, etc., the charging is stopped. When the charge is suspended, the forward switching control signal output from the microprocessor 9 is always at L level, and the switching element 4 is controlled to be turned on.

(快速充电模式B→B′→C)(Quick charging mode B→B′→C)

在t1时的检测值不存在异常的场合,转移到快速充电模式。在快速充电模式中,以与二次电池10的额定放电速度大致相等的充电速度对二次电池10进行充电,直到端子电压Vb(t)到达比最大充电电压Ve稍低的目标电压Ve′的t2时。其中,所谓与二次电池10的额定放电速度大致相等的充电速度是下述速度:端子电压Vb(t)与使完全充电的名义容量值的二次电池10为定电流放电,使成为以一小时放电结束的电流值为1C,以1C的充电电流对二次电池10充电的场合(将之称为1C充电)的电压上升变化率(每单位时间的端子电压Vb(t)间的电压差)大致相等。另外,在本实施方式中,将结束快速充电模式的目标电压Ve′作为与充电电流Ic(t)成比例的电压上升变化率开始下降的拐点电压,为比最大充电电压Ve的4.2V稍低的4.0V。If there is no abnormality in the detection value at t1 , the mode shifts to the quick charging mode. In the fast charging mode, the secondary battery 10 is charged at a charging rate substantially equal to the rated discharge rate of the secondary battery 10 until the terminal voltage Vb(t) reaches the target voltage Ve' which is slightly lower than the maximum charging voltage Ve. t 2 hours. Here, the so-called charging rate approximately equal to the rated discharge rate of the secondary battery 10 is a rate at which the terminal voltage Vb(t) and the nominal capacity value of the fully charged secondary battery 10 are discharged at a constant current, so that the secondary battery 10 is discharged at a constant current. The current value at the end of hourly discharge is 1C, and the voltage rise rate (the voltage difference between the terminal voltage Vb(t) per unit time) when the secondary battery 10 is charged with a charging current of 1C (referred to as 1C charging) ) are approximately equal. In addition, in the present embodiment, the target voltage Ve' at which the fast charging mode is terminated is set as the inflection point voltage at which the rate of change of voltage increase proportional to the charging current Ic(t) starts to decrease, and is slightly lower than the maximum charging voltage Ve of 4.2V. 4.0V.

在ROM13中,作为锂离子电池即二次电池10的充电信息,存储根据进行,1C充电的场合的电压上升变化率(在每个二次电池10的电池种类上不同)设定将要充电的二次电池10的第一设定上升变化率(其中,设定为锂离子电池的场合的变化率)、设定为比第一设定上升变化率充分低的值的第二设定上升变化率、目标电压Ve′(4.0V)、作为结束电压的最大充电电压Ve(4.2V)。In the ROM 13, as the charging information of the secondary battery 10, which is a lithium ion battery, the secondary battery to be charged is stored according to the voltage rise and change rate (different for each battery type of the secondary battery 10) when 1C charging is performed. The first set rate of change of the secondary battery 10 (here, the rate of change in the case of a lithium-ion battery), and the second set rate of change set to a value sufficiently lower than the first set rate of change , a target voltage Ve′ (4.0V), and a maximum charging voltage Ve (4.2V) as an end voltage.

微处理器9在开始快速充电模式t1时后,将使正向开关控制信号的接通能率为规定值的控制数据输出到驱动电路17,从驱动电路17输出正向开关控制信号与使极性反转的回扫控制信号,使电源部2进行动作。之后,在数msec的微小时间△t的左右(B,B′)由端子电压检测电路12检测的端子电压Vb(t)间的电压差得到端子电压增加量△V,计算作为每个微小时间△t的端子电压增加量△V的电压上升变化率。After the microprocessor 9 starts the fast charging mode t1 , the control data that makes the turn-on energy of the forward switch control signal a predetermined value is output to the drive circuit 17, and the forward switch control signal and the polarity are output from the drive circuit 17. The flyback control signal with reversed nature makes the power supply unit 2 operate. After that, the terminal voltage increase ΔV is obtained from the voltage difference between the terminal voltage Vb(t) detected by the terminal voltage detection circuit 12 at about (B, B') of the minute time Δt of several msec, and is calculated as each minute time The terminal voltage increment of Δt is the voltage rise change rate of ΔV.

接着,将计算出的电压上升变化率与从ROM13读取出的第一设定上升变化率比较,将以计算出的电压上升变化率与第一设定上升变化率一致的方式使正向开关控制信号的接通能率变化的控制数据输出到驱动电路17。即,在计算出的电压上升变化率是第一设定上升变化率以下的场合,将使正向开关控制信号的接通能率增加的控制数据输出到驱动电路17,使充电电流Ic(t)增加,相反,在计算出的电压上升变化率是第一设定上升变化率以上的场合,将使正向开关控制信号的接通能率减少的控制数据向驱动电路17输出,减少充电电流Ic(t)。端子电压Vb(t)的电压上升变化率根据充电电流Ic(t)而增减,因此通过在快速充电模式中以例如数msec的周期反复进行以上的处理,不论其电池容量的大小如何,都能够以与额定放电速度大致相等的充电速度对二次电池10进行充电。另外,就微小时间△t的长度、即反复进行上述处理的周期而言,在本实施方式中设定为数msec,但未必是这种长度,即使是数秒~数十秒左右的长度也能够实施本发明。Next, the calculated voltage rise and change rate is compared with the first set rise and change rate read from the ROM 13, and the forward switching is performed so that the calculated voltage rise and change rate coincide with the first set rise and change rate. Control data for changing the on-duty rate of the control signal is output to the drive circuit 17 . That is, when the calculated voltage rise change rate is equal to or less than the first set rise change rate, the control data for increasing the turn-on rate of the forward switch control signal is output to the drive circuit 17, so that the charging current Ic(t) On the contrary, when the calculated voltage rise change rate is above the first set rise change rate, the control data for reducing the turn-on energy rate of the forward switch control signal is output to the drive circuit 17 to reduce the charging current Ic( t). The voltage rise rate of the terminal voltage Vb(t) increases and decreases according to the charging current Ic(t). Therefore, by repeating the above-mentioned processing in a cycle of, for example, several msec in the fast charging mode, regardless of the size of the battery capacity, the The secondary battery 10 can be charged at a charge rate approximately equal to the rated discharge rate. In addition, the length of the minute time Δt, that is, the period in which the above-mentioned processing is repeated, is set to several msec in this embodiment, but it is not necessarily such a length, and it can be implemented even with a length of several seconds to several tens of seconds. this invention.

该快速充电模式中的充电电流Ic(t)优选在由进行充电的二次电池10的种类与其电容容量决定的充电电流值1C的附近变动,但不是如现有的充电装置那样利用规定的充电电流值1C对已知的二次电池10进行定电流控制,因此即使二次电池10的内部电阻的历年变化或充电线的阻值的变化之类的充电条件变化,充电电流Ic也自动变化地设定,能够根据其自身的充电条件维持最适的充电速度。The charging current Ic(t) in this fast charging mode preferably fluctuates around the charging current value 1C determined by the type of the secondary battery 10 to be charged and its capacitance capacity, but it does not use a predetermined charging method like a conventional charging device. The current value 1C performs constant current control on the known secondary battery 10, so even if the charging conditions such as the change in the internal resistance of the secondary battery 10 over the years or the change in the resistance value of the charging line change, the charging current Ic also automatically changes. setting, it can maintain the optimum charging speed according to its own charging conditions.

另外,微处理器9在以数msec的周期中反复进行上述处理的过程中,将端子电压检测电路12检测的端子电压Vb(t)与从ROM13读取出的目标电压Ve′(4.0)比较,在到达目标电压Ve′(4.0V)时,从快速充电模式转移到微调充电模式。In addition, the microprocessor 9 compares the terminal voltage Vb(t) detected by the terminal voltage detection circuit 12 with the target voltage Ve′ (4.0) read from the ROM 13 while repeating the above processing in a cycle of several msec. , when the target voltage Ve′ (4.0V) is reached, transfer from the fast charging mode to the fine-tuning charging mode.

(微调充电模式D)(fine-tuning charging mode D)

在微调充电模式中,由于端子电压Vb(t)超过二次电池10的充电效率急剧地下降的拐点电压,因此使二次电池10的充电电流Ic(t)下降,降低充电速度,能够防止过剩的充电电流Ic(t)转换为热能而导致充电效率恶化,并且防止端子电压Vb成为超过最大充电电压的过充电,导致二次电池10劣化或破损。In the fine-tuning charging mode, since the terminal voltage Vb(t) exceeds the inflection point voltage at which the charging efficiency of the secondary battery 10 drops sharply, the charging current Ic(t) of the secondary battery 10 is decreased to reduce the charging speed and prevent excess charging. The charging current Ic(t) is converted into thermal energy to degrade the charging efficiency, and prevents the terminal voltage Vb from being overcharged to exceed the maximum charging voltage, resulting in deterioration or damage to the secondary battery 10 .

微处理器9紧接着快速充电模式,检测数msec的微小时间△t前后的端子电压Vb(t),计算每微小时间△t时间的端子电压增加量△V即电压上升变化率,向驱动电路17输出以计算出的电压上升变化率与从ROM13读取出的第二设定上升变化率一致的方式使正向开关控制信号的接通能率变化的控制数据。The microprocessor 9 follows the fast charging mode, detects the terminal voltage Vb(t) before and after the tiny time Δt of a few msec, calculates the terminal voltage increment ΔV per tiny time Δt, that is, the voltage rise rate, and sends it to the driving circuit 17 outputs control data for changing the turn-on rate of the forward switch control signal so that the calculated voltage rise change rate matches the second set rise change rate read from the ROM 13 .

第二设定上升变化率与第一设定上升变化率相比充分低,为接近0的值,因此如图2(b)所示,使电压上升变化率与第二设定上升变化率一致的充电电流Ic从快速充电模式的充电电流Ic(t)急剧地下降,端子电压Vb(t)以极缓慢的倾斜上升。The second set rate of increase and change is sufficiently lower than the first set rate of change of increase and is a value close to 0. Therefore, as shown in FIG. The charging current Ic of the fast charging mode drops sharply from the charging current Ic(t) of the fast charging mode, and the terminal voltage Vb(t) rises with an extremely slow slope.

微处理器9在以数msec的周期反复进行上述处理的过程中,将端子电压检测电路12检测的端子电压Vb(t)与从ROM13读取出的结束电压即最大充电电压Ve(4.2V)相比,在到达结束电压(4,2V)的t3时,使从未处理器9输出的正向开关控制信号总是为L电平,对开关元件4进行打开控制,停止充电。While the microprocessor 9 repeats the above processing in a cycle of several msec, the terminal voltage Vb(t) detected by the terminal voltage detection circuit 12 and the maximum charging voltage Ve (4.2 V) which is the end voltage read from the ROM 13 are compared. In contrast, when t3 of the end voltage (4,2V) is reached, the forward switching control signal output from the slave processor 9 is always at L level, and the switching element 4 is turned on to stop charging.

在以上的二次充电10的充电工序中,在端子电压Vb(t)到达结束电压(4.2v)的t3时后,微处理器9将使电压上升变化率为0的控制数据输出到控制电路17,使微小的充电电流Ic(t)流动,端子电压Vb维持结束电压(4.2V)。In the charging process of the secondary charging 10 described above, after the terminal voltage Vb(t) reaches t3 when the end voltage (4.2v), the microprocessor 9 outputs the control data to make the voltage rise and change rate 0 to the control The circuit 17 flows a small charging current Ic(t) to maintain the terminal voltage Vb at the end voltage (4.2V).

另外,即使是快速充电模式或微调充电模式,都在温度传感器19检测的二次电池10的温度异常地上升、或输入电压Vin小于结束电压(4.2V)的场合对开关元件4进行打开控制,停止充电。In addition, even in the quick charging mode or the trimming charging mode, when the temperature of the secondary battery 10 detected by the temperature sensor 19 rises abnormally, or when the input voltage Vin is lower than the end voltage (4.2V), the switching element 4 is controlled to be turned on. Stop charging.

本发明未限定于以上的实施方式,能进行多种变形,例如,在快速充电模式中使电压上升变化率一致的第一设定上升变化率未必设定为在以1C的充电电流充电的场合的电压上升变化率,能够与2C充电或1/2C充电等任意的充电速度一致地设定。The present invention is not limited to the above embodiments, and can be modified in various ways. For example, the first setting rate of change for making the rate of rise and change of voltage consistent in the fast charging mode is not necessarily set to charge with a charging current of 1C. The rate of change in voltage rise can be set in accordance with any charging speed such as 2C charging or 1/2C charging.

另外,使电压上升变化率一致的设定上升变化率未必在快速充电模式中相同,可以在设定为不同的变化率的多个设定上升变化率的任一个与充电状况的变化一致地使电压上升变化率一致。例如,伴随温度传感器19检测的二次电池10的温度上升,改变为将使电压上升变化率一致的设定上升变化率设定为更低的值的设定上升变化率。In addition, the set rise change rate for matching the voltage rise change rate is not necessarily the same in the fast charging mode, and any one of a plurality of set rise change rates set to different change rates may be made to match the change of the charging state. The rate of change of voltage rise is consistent. For example, as the temperature of the secondary battery 10 detected by the temperature sensor 19 rises, the set rise change rate is changed to a set rise change rate that makes the voltage rise change rate equal to a lower value.

另外,在微小单位经过时间的左右检测的端子电压可以根据连续地检测的多个端子电压的相关,进行除去异常值或平均值化等的计算处理而特定。In addition, the terminal voltage detected around the elapsed time of the minute unit can be specified by performing calculation processing such as removing abnormal values or averaging based on the correlation of a plurality of continuously detected terminal voltages.

另外,电源部2只要能在使输出电压与端子电压连动的状态下可变控制对二次电池进行充电的输出电流(充电电流),则不限于断路式降压转换器,能够使用任意的直流电源。In addition, the power supply unit 2 is not limited to an open-circuit step-down converter, and any type of converter can be used as long as the output current (charging current) for charging the secondary battery can be variably controlled in a state in which the output voltage is linked to the terminal voltage. DC power supply.

另外,二次电池也只要是充电速度根据充电电流变化的特性的二次电池,则不限于锂离子电池,也可以是镍镉电池等其他二次电池。In addition, the secondary battery is not limited to a lithium-ion battery as long as it has a characteristic that the charging speed changes according to the charging current, and may be other secondary batteries such as nickel-cadmium batteries.

产业上的可利用性如下。Industrial applicability is as follows.

本发明适于将反转板弹簧作为可动接点板使用的充电装置。The present invention is suitable for a charging device using a reverse plate spring as a movable contact plate.

Claims (6)

1.一种充电装置,具备:用直流电力对二次电池进行充电的电源部、以及1. A charging device comprising: a power supply unit for charging a secondary battery with DC power; and 控制上述电源部的充电动作直到上述二次电池的端子电压到达预定的结束电压的电源控制部,a power supply control unit that controls the charging operation of the power supply unit until the terminal voltage of the secondary battery reaches a predetermined end voltage, 该充电装置的特征在于,The charging device is characterized in that, 电源控制部具有:The power control section has: 检测上述二次电池的端子电压的电压检测部;a voltage detection unit that detects a terminal voltage of the secondary battery; 对经过时间进行计时的计时单元;A timing unit for counting elapsed time; 依次计算以微小单位经过时间内的端子电压增加量△V表示的电压上升变化率的计算单元,A calculation unit that sequentially calculates the voltage rise and change rate expressed by the terminal voltage increase △V within a small unit elapsed time, 在电源部用直流电力对二次电池进行充电的期间,将上述直流电力的充电电压控制为二次电池的端子电压,并且对上述直流电力的充电电流进行可变控制,使得由上述计算单元算出的电压上升变化率为互相不同的多个预定的设定上升变化率。While the power supply unit is charging the secondary battery with DC power, the charging voltage of the above-mentioned DC power is controlled to the terminal voltage of the secondary battery, and the charging current of the above-mentioned DC power is variably controlled so that the calculation unit calculates The voltage rise and change rates are a plurality of predetermined set rise and change rates different from each other. 2.根据权利要求1所述的充电装置,其特征在于,2. The charging device according to claim 1, characterized in that, 结束电压是二次电池所容许的最大充电电压,The end voltage is the maximum charging voltage allowed by the secondary battery, 电源控制部以快速充电模式控制上述电源部的充电动作,直到二次电池的端子电压到达比最大充电电压稍低的目标电压,The power supply control unit controls the charging operation of the power supply unit in the fast charging mode until the terminal voltage of the secondary battery reaches a target voltage slightly lower than the maximum charging voltage, 将快速充电模式下的上述设定上升变化率设定成与以1C的充电电流进行了充电时的电压上升变化率相接近,其中,该1C为以恒定电流对以名义容量值进行了完全充电的二次电池进行放电,并且使放电在1小时结束的电流值。Set the above-mentioned rising change rate in the fast charging mode to be close to the voltage rising change rate when charging with a charging current of 1C, wherein the 1C is fully charged with a nominal capacity value at a constant current The secondary battery is discharged, and the current value that makes the discharge end in 1 hour. 3.根据权利要求2所述的充电装置,其特征在于,3. The charging device according to claim 2, characterized in that, 目标电压是与充电电流成比例的电压上升变化率开始下降的拐点电压。The target voltage is the inflection point voltage at which the rate of change of voltage increase proportional to the charging current starts to decrease. 4.根据权利要求2所述的充电装置,其特征在于,4. The charging device according to claim 2, characterized in that, 电源控制部在二次电池的端子电压到达上述目标电压后,以微调充电模式控制上述电源部的充电动作直到所述二次电池的端子电压到达最大充电电压,After the terminal voltage of the secondary battery reaches the target voltage, the power control unit controls the charging operation of the power supply unit in a fine-tuning charging mode until the terminal voltage of the secondary battery reaches the maximum charging voltage, 将微调充电模式下的上述设定上升变化率设定为比快速充电模式下的上述设定上升变化率充分低的值。The set increase change rate in the fine charge mode is set to a value sufficiently lower than the set increase change rate in the quick charge mode. 5.根据权利要求3所述的充电装置,其特征在于,5. The charging device according to claim 3, characterized in that, 电源控制部在二次电池的端子电压到达上述目标电压后,以微调充电模式控制上述电源部的充电动作直到所述二次电池的端子电压到达最大充电电压,After the terminal voltage of the secondary battery reaches the target voltage, the power control unit controls the charging operation of the power supply unit in a fine-tuning charging mode until the terminal voltage of the secondary battery reaches the maximum charging voltage, 将微调充电模式下的上述设定上升变化率设定为比快速充电模式下的上述设定上升变化率充分低的值。The set increase change rate in the fine charge mode is set to a value sufficiently lower than the set increase change rate in the quick charge mode. 6.根据权利要求1~5任一项所述的充电装置,其特征在于,6. The charging device according to any one of claims 1 to 5, characterized in that: 电源部是通过开关元件的开闭向二次电池的充电端子间输出上述直流电力的断路式降压转换器,该开关元件串联地连接在至少比结束电压高的直流电压的直流输入间,电源控制部以由上述计算单元计算出的电压上升变化率与上述设定上升变化率一致的方式增减脉冲宽度调制信号的接通能率,从而调整上述电压上升变化率,其中,该脉冲宽度调制信号对上述开关元件进行开闭控制。The power supply unit is an open-circuit step-down converter that outputs the above-mentioned DC power between the charging terminals of the secondary battery by opening and closing a switching element connected in series between a DC input of at least a DC voltage higher than the end voltage, and the power supply The control unit adjusts the above-mentioned voltage rise and change rate by increasing or decreasing the turn-on rate of the pulse width modulation signal in such a manner that the voltage rise and change rate calculated by the calculation unit coincides with the above-mentioned set rise and change rate, wherein the pulse width modulation signal Opening and closing control is performed on the above-mentioned switching element.
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