CN103817841B - Method for producing anti-static floor and anti-static wallboard using macromolecule chemical material - Google Patents
Method for producing anti-static floor and anti-static wallboard using macromolecule chemical material Download PDFInfo
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- CN103817841B CN103817841B CN201210464844.2A CN201210464844A CN103817841B CN 103817841 B CN103817841 B CN 103817841B CN 201210464844 A CN201210464844 A CN 201210464844A CN 103817841 B CN103817841 B CN 103817841B
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- antistatic floor
- floor according
- static
- epoxy resin
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- 239000000463 material Substances 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 229920002521 macromolecule Polymers 0.000 title description 4
- 239000000126 substance Substances 0.000 title description 4
- 239000003822 epoxy resin Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 17
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 17
- 239000003063 flame retardant Substances 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- 239000006260 foam Substances 0.000 claims abstract description 10
- 239000004970 Chain extender Substances 0.000 claims abstract description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 239000004088 foaming agent Substances 0.000 claims abstract description 8
- 239000012948 isocyanate Substances 0.000 claims abstract description 8
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 7
- 239000004020 conductor Substances 0.000 claims abstract description 6
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- 229920000642 polymer Polymers 0.000 claims abstract description 3
- 238000000748 compression moulding Methods 0.000 claims abstract 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 8
- 239000004411 aluminium Substances 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- -1 salt compound Chemical class 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 238000012856 packing Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical class CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 208000037656 Respiratory Sounds Diseases 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 230000001351 cycling effect Effects 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 150000008282 halocarbons Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- 150000004885 piperazines Chemical class 0.000 claims description 2
- 235000011056 potassium acetate Nutrition 0.000 claims description 2
- 229940066771 systemic antihistamines piperazine derivative Drugs 0.000 claims description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004246 zinc acetate Substances 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims 2
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 229910000410 antimony oxide Inorganic materials 0.000 claims 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims 1
- 229940074391 gallic acid Drugs 0.000 claims 1
- 235000004515 gallic acid Nutrition 0.000 claims 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims 1
- 239000004845 glycidylamine epoxy resin Substances 0.000 claims 1
- 125000001475 halogen functional group Chemical group 0.000 claims 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical group C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 4
- 238000011049 filling Methods 0.000 abstract description 2
- 239000002585 base Substances 0.000 description 16
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 description 2
- 101710130081 Aspergillopepsin-1 Proteins 0.000 description 2
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 description 2
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000001175 calcium sulphate Substances 0.000 description 2
- 235000011132 calcium sulphate Nutrition 0.000 description 2
- VONWDASPFIQPDY-UHFFFAOYSA-N dimethyl methylphosphonate Chemical compound COP(C)(=O)OC VONWDASPFIQPDY-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 230000005070 ripening Effects 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- IBOFVQJTBBUKMU-UHFFFAOYSA-N 4,4'-methylene-bis-(2-chloroaniline) Chemical compound C1=C(Cl)C(N)=CC=C1CC1=CC=C(N)C(Cl)=C1 IBOFVQJTBBUKMU-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- GNDMWRNTJIARLO-UHFFFAOYSA-N ClC(C)Cl.[F] Chemical class ClC(C)Cl.[F] GNDMWRNTJIARLO-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 241001112258 Moca Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 206010000269 abscess Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004844 aliphatic epoxy resin Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000011900 installation process Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Floor Finish (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a method for producing an anti-static floor and an anti-static wallboard with polymer compounds. The method comprises the following steps: mixing a component A and a component B according to a weight ratio of 1:(1 to 2), wherein the component A comprises polyhydric alcohol, a chain extender, a foam stabilizer, a foaming agent, a catalyst, a fire retardant, a filling material and a conducting material; the component B comprises isocyanate and epoxy resin, injecting the mixed components in a die, and performing compression molding to obtain the anti-static floor and the anti-static wallboard. The anti-static floor and the anti-static wallboard can save resources and energy, reduce consumption, preserve heat, guard against damp, retard flame, resist ageing, keep shape, and can be directly paved without a keel.
Description
Technical field
The present invention relates to a kind of method for producing antistatic floor and antistatic wallboard with macromolecule chemical material.
Background technology
Traditional antistatic floor can be divided into according to base material is different with surface lining：Base steel, aluminium base, composite base, wood shavings
Plate base (being also wooden base), calcium sulphate-based etc., veneer can be tripolycyanamide (HPL) and PVC.
Aluminium base, calcium sulphate-based price are higher, and the floor of aluminium base will not be got rusty, but domestic aluminium base floor precision is not high,
The price of import aluminium base is too high；
Base steel and composite base are moderate, but base steel floor section gets rusty easily, so section is required for mopping to do antirust treatment,
The section on composite base floor will also do dust-proof process.
The price of particieboard base is relatively low, but water absorption rate is too high, and fire protecting performance is poor, carries low, is not suitable for what is had high demands
Place uses.
Veneer easily aging peeling is done with tripolycyanamide (HPL), surface easily scratches, and corner easily comes off.
Veneer being done with PVC easily aging, easy cleaning not being allowed after completing, floor is easily aging, and fire protecting performance is also not all right.
The present invention just component A includes (polyhydric alcohol, chain extender, foam stabilizer, foaming agent, catalyst, fire retardant, filling material
Material and conductive material) include that with B component (isocyanates, epoxy resin) in mass ratio 1: 1-2 injects mould after mixing, then Jing adds
Antistatic floor made by work can not only overcome the shortcoming of any of the above antistatic floor, with insulation, it is moistureproof, fire-retardant, anti-ageing
Change, advantage that is indeformable, directly laying without the need for Os Draconis.Most prominent the characteristics of is that the antistatic of entire body is consistent with fire resistance, very
Extremely also possess antistatic and anti-flammability (separately patent application) in the supporting glue of installation process.Additionally, also specification style spirit
The features such as work is various, construction is simple and convenient.
The content of the invention
Component A is included into (polyhydric alcohol, chain extender, foam stabilizer, foaming agent, catalyst, fire retardant, packing material and conduction
Material) include that with B component (isocyanates, epoxy resin) in mass ratio 1: 1-2 injects mould after mixing, then it is processed make it is anti-
Electrostatic floor and antistatic wallboard, its main performance reach：
Electric conductivity：10 powers of 7 powers -10 of 9 power ohm body resistivities 10 of 6 powers -10 of sheet resistance 10
Ohm/cm
Anti-flammability：From fiery self-extinguishment
Wearability：0.1g/1000 turns
Water absorption：＜ 0.5%
Resistance to extremely cold very hot property：-25℃-150℃
10 priority cold cyclings of Jing occur without obvious crackle
Flexural strength：Meansigma methodss are not less than 27Mpa
Floor specification：(100～1200) × (100～1200) × (10～50) mm as needed
The polyalcohols are polyether polyol and PEPA or are polyethers, polyester polyols blend, in macromolecule
The toughness of material can mainly be increased in material.
The chain extender is that ethylene glycol, diethylene glycol, glycerol, diethanolamine, triethanolamine, MOCA etc. contain 2 or 2
The compound of individual above active hydrogen, the addition of chain extender seldom, but can improve the intensity of material in macromolecular material.
The foam stabilizer is organic silicon surfactant, adds a small amount of organic silicon surfactant and can be obviously improved height
The abscess of molecular material is thick, and the defect such as steep.
The foaming agent is water, 141B, dichloromethane, Pentamethylene., carbon dioxide etc..
The catalyst be N, N- dimethyl cyclohexyl amines, triethanolamine, double (dimethylaminoethyl) ethers, triethylene diamine,
One kind in zinc acetate, antimony glycol, potassium acetate, stannous octoate, titanate ester, imdazole derivatives and bridged piperazine derivatives or wherein
Several mixture,.
The fire retardant be halophosphoric acid esters, phosphoric acid ester, halogenated hydrocarbon and fire-retardant graphite, red phosphorus, aluminium hydroxide, three
Aoxidize the inorganic combustion inhibitors such as two antimony.
The packing material is age resistor, stabilizer, Calcium Carbonate, Pulvis Talci, glass fibre, glass microballoon, mill base etc..
The conductive material is copper powder, aluminium powder, argentum powder, electrically conductive graphite, conductive black, Conductive mica, quaternary ammonium salt chemical combination
Thing, metal salt compound etc..
The component A includes polyhydric alcohol, chain extender, foam stabilizer, foaming agent, catalyst, fire retardant, packing material and conduction
The quality proportioning of material is 100: 2-10: 0.5-2: 5-20: 0.5-5: 7-20: 10-20: 5-30.
The isocyanates are toluene di-isocyanate(TDI) (Toluene Diisocyanate, abbreviation TDI)；Diphenyl methane
Diisocyanate (Methylenediphenyl Diisocyanate, abbreviation MDI), polymeric MDI and its modified and performed polymer.
The epoxy resin is glycidyl ether type epoxy resin, glycidyl ester epoxy resin, (+)-2,3-Epoxy-1-propanol amine
Epoxy resin, linear aliphatic epoxy resin and aromatic series based epoxy resin.
The B component includes isocyanates, the quality proportioning of epoxy resin is 20: 1-4.
The AB components are injected in grinding tool after mixing, after heating the operations such as ripening, machining, detection packaging,
Make the product that size is (100～1200) × (100～1200) × (10～50) mm.
Description of the drawings
Fig. 1 is a kind of method for producing antistatic floor and antistatic wallboard described in the specific embodiment of the present invention
Flow chart；
Specific embodiment
Polyether polyol 450L (the federal chemistry Industrial Co., Ltd of Zibo moral letter, hydroxyl value 450mgKOH/g)
PEPA 315B (Langfang development zone Si Kerui polyurethane company limited, phthalic anhydride polyester, hydroxyl value 315mgKOH/
g)
Pulvis Talci (1250 mesh)
Diethylene glycol
N, N- dimethyl cyclohexyl amine
Blowing agent H CFC-141B (Ju Hua groups, a fluorine dichloroethanes)
Phosphate ester flame retardants DMMP
Aluminium powder
44V20 (Bayer) (polymeric MDI, NCO content 30%-32%)
Foam stabilizer 8830 (Nanjing Dymatic Shichuang Chemical Co., Ltd.)
Pigment (medium chrome yellow)
Epoxy resin E-44 (Hebei Li Dong cold coatings company limited)
Example
In 1 ton of reactor, 500 kilograms of addition polyester 315B, 400 kilograms of polyethers 450L, 5 kilograms of diethylene glycol,
1 kilogram of N, N- dimethyl cyclohexyl amine, 8,830 1 kilograms, 10 kilograms of HCFC-141B, 8 kilograms of DMMP, 10 kilograms of Pulvis Talci, aluminum
20 kilograms of powder, 2 kilograms of medium chrome yellow, high-speed stirred 2 hours make component A.
In 1 ton of reactor, 910 kilograms of 44V20,70 kilograms of epoxy resin E-44 is added to be heated to 80 degree of insulations
B component is made in stirring 2 hours, discharging.
Two kinds of components are poured in mould by weight 1: 1.1 by casting machine, the demoulding after 40 degree of ripenings 6 hours, plus
Work, you can acquisition density is 300kg/m3Antistatic floor or antistatic wallboard.
The foregoing is only presently preferred embodiments of the present invention, not to limit the present invention, all spirit in the present invention and
Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Claims (12)
1. a kind of method for manufacturing antistatic floor, it is characterised in that methods described includes：Component A is included into polyhydric alcohol, chain extension
Agent, foam stabilizer, foaming agent, catalyst, fire retardant, packing material and conductive material and B component include isocyanates, epoxy resin
Inject mould after in mass ratio 1: 1-2 mixing, compression molding, then it is processed make antistatic floor and antistatic wallboard, its master
Want performance as follows：
Electric conductivity：10 power Europe of 7 powers -10 of 9 power ohm body resistivities 10 of 6 powers -10 of sheet resistance 10
Nurse centimetre；
Anti-flammability：From fiery self-extinguishment；
Wearability：0.1g/1000 turns；
Water absorption：＜ 0.5%, tests reference：《The measure of GB/T8810-2005 rigid foam water absorption rates》；
Resistance to extremely cold very hot property：-25℃-150℃；
10 priority cold cyclings of Jing occur without obvious crackle；
Flexural strength：Meansigma methodss are not less than 27Mpa；
Floor specification：(100～1200) × (100～1200) × (10～50) mm as needed.
2. a kind of method for manufacturing antistatic floor according to claim 1, it is characterised in that the chain extender is second two
Alcohol, diethylene glycol, glycerol, diethanolamine, triethanolamine, 4,2 or 2 are contained in 4 '-diaminourea -3,3 '-dichloro diphenyl methane
One or more mixing in the compound of individual above active hydrogen.
3. a kind of method for manufacturing antistatic floor according to claim 1, it is characterised in that the foam stabilizer is organic
Silicon surface active agent.
4. a kind of method for manufacturing antistatic floor according to claim 1, it is characterised in that the foaming agent be water,
One or more mixing of HCFC-141B, dichloromethane, Pentamethylene., carbon dioxide.
5. a kind of method for manufacturing antistatic floor according to claim 1, it is characterised in that the catalyst is hexamethylene
Amine, triethanolamine, double (dimethylaminoethyl) ethers, the dilute diamidogen of three second, zinc acetate, antimony glycol, potassium acetate, stannous octoate, titanium
One kind or wherein several mixture in esters of gallic acid, imdazole derivatives and bridged piperazine derivatives.
6. a kind of method for manufacturing antistatic floor according to claim 1, it is characterised in that the fire retardant is halo
One or more of phosphoric acid ester, phosphoric acid ester, halogenated hydrocarbon and fire-retardant graphite, red phosphorus, aluminium hydroxide, antimony oxide are mixed
Close.
7. a kind of method for manufacturing antistatic floor according to claim 1, it is characterised in that the packing material is anti-
One or more mixing of old agent, stabilizer, Calcium Carbonate, Pulvis Talci, glass fibre, glass microballoon, mill base.
8. a kind of method for manufacturing antistatic floor according to claim 1, it is characterised in that the conductive material is copper
Powder, aluminium powder, argentum powder, electrically conductive graphite, conductive black, Conductive mica, quaternary ammonium compound, one kind of metal salt compound or
Several mixing.
9. a kind of method for manufacturing antistatic floor according to claim 1, it is characterised in that the component A includes polynary
The quality proportioning of alcohol, chain extender, foam stabilizer, foaming agent, catalyst, fire retardant, packing material and conductive material is 100: 2-10:
0.5-2∶5-20∶0.5-5∶7-20∶10-20∶5-30。
10. a kind of method for manufacturing antistatic floor according to claim 1, it is characterised in that the isocyanates are first
Phenylene diisocyanate (Toluene Diisocyanate, abbreviation TDI)；Methyl diphenylene diisocyanate
(Methylenediphenyl Diisocyanate, abbreviation MDI), polymeric MDI, and its it is modified a kind of or several with performed polymer
Plant mixing.
11. a kind of methods for manufacturing antistatic floor according to claim 1, it is characterised in that the epoxy resin is contracting
Water glycerol ether type epoxy resins, glycidyl ester epoxy resin, glycidyl amine epoxy resin, linear aliphatic class epoxy
One or several mixing of resin and aromatic series based epoxy resin.
12. a kind of method for manufacturing antistatic floor according to claim 1, it is characterised in that the B component includes different
Cyanate, the quality proportioning of epoxy resin are 20: 1-4.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210464844.2A CN103817841B (en) | 2012-11-19 | 2012-11-19 | Method for producing anti-static floor and anti-static wallboard using macromolecule chemical material |
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| CN201210464844.2A CN103817841B (en) | 2012-11-19 | 2012-11-19 | Method for producing anti-static floor and anti-static wallboard using macromolecule chemical material |
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| CN103817841B true CN103817841B (en) | 2017-04-26 |
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| CN107060190B (en) * | 2017-06-14 | 2019-03-26 | 合肥易美特建材有限公司 | A kind of Wood plastic wall board |
| CN107501974A (en) * | 2017-09-02 | 2017-12-22 | 安徽金睐格环保科技有限公司 | A kind of heat-resisting packaging boxboard of environmental-protection flame-retardant |
| CN109514867A (en) * | 2018-11-29 | 2019-03-26 | 南通理工学院 | Three-dimensional model data conversion device with 3D control unit |
| CN114933687B (en) * | 2022-06-30 | 2023-10-27 | 华南理工大学 | A high-strength controllable foaming material and its preparation method and application |
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| KR100902033B1 (en) * | 2007-09-28 | 2009-06-15 | 도레이새한 주식회사 | Manufacturing method of antistatic polyester film |
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