CN103833459A - Drug fertilizer composition for preventing and treating green turf diseases and application thereof - Google Patents
Drug fertilizer composition for preventing and treating green turf diseases and application thereof Download PDFInfo
- Publication number
- CN103833459A CN103833459A CN201210484528.1A CN201210484528A CN103833459A CN 103833459 A CN103833459 A CN 103833459A CN 201210484528 A CN201210484528 A CN 201210484528A CN 103833459 A CN103833459 A CN 103833459A
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- CN
- China
- Prior art keywords
- acid
- fertilizer composition
- sulfate
- kilogram
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 78
- 239000003814 drug Substances 0.000 title claims abstract description 62
- 239000000203 mixture Substances 0.000 title claims abstract description 58
- 201000010099 disease Diseases 0.000 title claims abstract description 28
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 title claims abstract description 28
- 229940079593 drug Drugs 0.000 title abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- 235000015097 nutrients Nutrition 0.000 claims abstract description 20
- 239000000126 substance Substances 0.000 claims abstract description 19
- 230000012010 growth Effects 0.000 claims abstract description 14
- 230000003050 macronutrient Effects 0.000 claims abstract description 5
- 235000021073 macronutrients Nutrition 0.000 claims abstract description 5
- -1 acetic acid diethylaminoethanol ester Chemical class 0.000 claims description 36
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 28
- 229910052700 potassium Inorganic materials 0.000 claims description 20
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 18
- 239000011591 potassium Substances 0.000 claims description 18
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 17
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 15
- 241000894006 Bacteria Species 0.000 claims description 14
- PRPINYUDVPFIRX-UHFFFAOYSA-N 1-naphthaleneacetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CC=CC2=C1 PRPINYUDVPFIRX-UHFFFAOYSA-N 0.000 claims description 13
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 10
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 10
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 10
- 239000004202 carbamide Substances 0.000 claims description 9
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 9
- 239000004021 humic acid Substances 0.000 claims description 9
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical group CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 claims description 8
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- 229920001661 Chitosan Polymers 0.000 claims description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 6
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims description 6
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 6
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 6
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 6
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 6
- RMOGWMIKYWRTKW-UONOGXRCSA-N (S,S)-paclobutrazol Chemical compound C([C@@H]([C@@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1 RMOGWMIKYWRTKW-UONOGXRCSA-N 0.000 claims description 5
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 5
- 206010011224 Cough Diseases 0.000 claims description 5
- 239000005760 Difenoconazole Substances 0.000 claims description 5
- 229930191978 Gibberellin Natural products 0.000 claims description 5
- 239000005985 Paclobutrazol Substances 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical group [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 claims description 5
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims description 5
- 239000011790 ferrous sulphate Substances 0.000 claims description 5
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 5
- 239000003448 gibberellin Substances 0.000 claims description 5
- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical class C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 claims description 5
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 claims description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 5
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 5
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 5
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
- 239000003375 plant hormone Substances 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 239000004323 potassium nitrate Substances 0.000 claims description 5
- 235000010333 potassium nitrate Nutrition 0.000 claims description 5
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 5
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 5
- 235000011151 potassium sulphates Nutrition 0.000 claims description 5
- YNWVFADWVLCOPU-MDWZMJQESA-N (1E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MDWZMJQESA-N 0.000 claims description 4
- DARPYRSDRJYGIF-PTNGSMBKSA-N (Z)-3-ethoxy-2-naphthalen-2-ylsulfonylprop-2-enenitrile Chemical compound C1=CC=CC2=CC(S(=O)(=O)C(\C#N)=C/OCC)=CC=C21 DARPYRSDRJYGIF-PTNGSMBKSA-N 0.000 claims description 4
- OICGFSUWXCJLCO-UHFFFAOYSA-N 1-ethylsulfonylsulfanylethane Chemical compound CCSS(=O)(=O)CC OICGFSUWXCJLCO-UHFFFAOYSA-N 0.000 claims description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 4
- PBNCAAFYQGMMRF-UHFFFAOYSA-N 4-(1h-indol-2-yl)butanoic acid;potassium Chemical compound [K].C1=CC=C2NC(CCCC(=O)O)=CC2=C1 PBNCAAFYQGMMRF-UHFFFAOYSA-N 0.000 claims description 4
- IXVMHGVQKLDRKH-VRESXRICSA-N Brassinolide Natural products O=C1OC[C@@H]2[C@@H]3[C@@](C)([C@H]([C@@H]([C@@H](O)[C@H](O)[C@H](C(C)C)C)C)CC3)CC[C@@H]2[C@]2(C)[C@@H]1C[C@H](O)[C@H](O)C2 IXVMHGVQKLDRKH-VRESXRICSA-N 0.000 claims description 4
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 4
- 239000005808 Metalaxyl-M Substances 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 4
- NWBJYWHLCVSVIJ-UHFFFAOYSA-N N-benzyladenine Chemical compound N=1C=NC=2NC=NC=2C=1NCC1=CC=CC=C1 NWBJYWHLCVSVIJ-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005820 Prochloraz Substances 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 4
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 4
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 4
- IXVMHGVQKLDRKH-KNBKMWSGSA-N brassinolide Chemical compound C1OC(=O)[C@H]2C[C@H](O)[C@H](O)C[C@]2(C)[C@H]2CC[C@]3(C)[C@@H]([C@H](C)[C@@H](O)[C@H](O)[C@@H](C)C(C)C)CC[C@H]3[C@@H]21 IXVMHGVQKLDRKH-KNBKMWSGSA-N 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 claims description 4
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 4
- 239000011565 manganese chloride Substances 0.000 claims description 4
- 229940099607 manganese chloride Drugs 0.000 claims description 4
- OXOKTPUZOHPXSA-UHFFFAOYSA-L manganese(2+);n-propyl-n-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide;dichloride Chemical compound Cl[Mn]Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl OXOKTPUZOHPXSA-UHFFFAOYSA-L 0.000 claims description 4
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 4
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 claims description 4
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000011785 micronutrient Substances 0.000 claims description 4
- 235000013369 micronutrients Nutrition 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000002773 nucleotide Substances 0.000 claims description 4
- 125000003729 nucleotide group Chemical group 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 claims description 4
- MKWYFZFMAMBPQK-UHFFFAOYSA-J sodium feredetate Chemical compound [Na+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O MKWYFZFMAMBPQK-UHFFFAOYSA-J 0.000 claims description 4
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 4
- 239000004328 sodium tetraborate Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000000080 wetting agent Substances 0.000 claims description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 4
- 229960001763 zinc sulfate Drugs 0.000 claims description 4
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 3
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 3
- 229920000881 Modified starch Polymers 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000005839 Tebuconazole Substances 0.000 claims description 3
- 235000001014 amino acid Nutrition 0.000 claims description 3
- 150000001413 amino acids Chemical class 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- JHECKPXUCKQCSH-UHFFFAOYSA-J calcium;disodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;hydrate Chemical compound O.[Na+].[Na+].[Ca+2].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O JHECKPXUCKQCSH-UHFFFAOYSA-J 0.000 claims description 3
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000002509 fulvic acid Substances 0.000 claims description 3
- 229940095100 fulvic acid Drugs 0.000 claims description 3
- JTEDVYBZBROSJT-UHFFFAOYSA-N indole-3-butyric acid Chemical compound C1=CC=C2C(CCCC(=O)O)=CNC2=C1 JTEDVYBZBROSJT-UHFFFAOYSA-N 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 235000011147 magnesium chloride Nutrition 0.000 claims description 3
- 235000019426 modified starch Nutrition 0.000 claims description 3
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 3
- 229930182490 saponin Natural products 0.000 claims description 3
- 150000007949 saponins Chemical class 0.000 claims description 3
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 3
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- AXKBOWBNOCUNJL-UHFFFAOYSA-M sodium;2-nitrophenolate Chemical compound [Na+].[O-]C1=CC=CC=C1[N+]([O-])=O AXKBOWBNOCUNJL-UHFFFAOYSA-M 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 claims description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004368 Modified starch Substances 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 2
- 239000011609 ammonium molybdate Substances 0.000 claims description 2
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 2
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 2
- 229940010552 ammonium molybdate Drugs 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical compound [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 2
- 239000011654 magnesium acetate Substances 0.000 claims description 2
- 235000011285 magnesium acetate Nutrition 0.000 claims description 2
- 229940069446 magnesium acetate Drugs 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 229960001708 magnesium carbonate Drugs 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 229960002337 magnesium chloride Drugs 0.000 claims description 2
- 229960003390 magnesium sulfate Drugs 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000011572 manganese Substances 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
- 239000011592 zinc chloride Substances 0.000 claims description 2
- 235000005074 zinc chloride Nutrition 0.000 claims description 2
- 241001122767 Theaceae Species 0.000 claims 1
- 230000000855 fungicidal effect Effects 0.000 abstract description 5
- 239000000417 fungicide Substances 0.000 abstract description 5
- 239000005648 plant growth regulator Substances 0.000 abstract description 5
- 230000002265 prevention Effects 0.000 abstract description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 230000001681 protective effect Effects 0.000 abstract description 4
- 230000000845 anti-microbial effect Effects 0.000 abstract 1
- 230000009977 dual effect Effects 0.000 abstract 1
- 230000008029 eradication Effects 0.000 abstract 1
- 230000001360 synchronised effect Effects 0.000 abstract 1
- 241000743339 Agrostis Species 0.000 description 18
- 241000196324 Embryophyta Species 0.000 description 15
- 235000007686 potassium Nutrition 0.000 description 15
- 230000000694 effects Effects 0.000 description 14
- 230000009193 crawling Effects 0.000 description 13
- 239000003905 agrochemical Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 244000025254 Cannabis sativa Species 0.000 description 8
- 239000002131 composite material Substances 0.000 description 8
- 235000013399 edible fruits Nutrition 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000002689 soil Substances 0.000 description 7
- 238000011161 development Methods 0.000 description 6
- 230000018109 developmental process Effects 0.000 description 6
- 238000012423 maintenance Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 230000003449 preventive effect Effects 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 239000004254 Ammonium phosphate Substances 0.000 description 3
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 3
- 235000019289 ammonium phosphates Nutrition 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 230000002363 herbicidal effect Effects 0.000 description 3
- 239000004009 herbicide Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 235000008935 nutritious Nutrition 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000004563 wettable powder Substances 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 230000000050 nutritive effect Effects 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- CHNQZRKUZPNOOH-UHFFFAOYSA-J zinc;manganese(2+);n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Zn+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S CHNQZRKUZPNOOH-UHFFFAOYSA-J 0.000 description 2
- SCFXRRMXMMHURF-UHFFFAOYSA-N 2-nitrophenol;sodium Chemical compound [Na].OC1=CC=CC=C1[N+]([O-])=O SCFXRRMXMMHURF-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- SPANOECCGNXGNR-UITAMQMPSA-N Diallat Chemical compound CC(C)N(C(C)C)C(=O)SC\C(Cl)=C\Cl SPANOECCGNXGNR-UITAMQMPSA-N 0.000 description 1
- 208000035240 Disease Resistance Diseases 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229940058573 b-d glucose Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000003381 deacetylation reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- LLLILZLFKGJCCV-UHFFFAOYSA-M n-methyl-n-[(1-methylpyridin-1-ium-4-yl)methylideneamino]aniline;methyl sulfate Chemical compound COS([O-])(=O)=O.C=1C=CC=CC=1N(C)\N=C\C1=CC=[N+](C)C=C1 LLLILZLFKGJCCV-UHFFFAOYSA-M 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 230000001863 plant nutrition Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 235000002137 reduced nutrient intake Nutrition 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to a drug fertilizer composition for preventing and treating green turf diseases. The drug fertilizer composition comprises the following components by mass percent: 0.05-5% of antimicrobial actives, 0.05-1.5% of plant growth regulator, 45-60% of macronutrient compound, 1-15% of trace nutrient element compound, 5-25% of active organic nutrient substance, and 0.5-15% of booster. By adopting the drug fertilizer composition, the plant growth regulator is reasonably compounded with a protective fungicide or a fungicide with treatment and eradication functions. An experiment proves that the drug fertilizer composition has an obvious synergic effect, and is further compounded and fused with the plant nutrient substance, so as to achieve dual effects of the drug and the fertilizer. The green turf diseases can be prevented and treated, sufficient balanced nutrient elements can be provided for maintaining the lawn, synchronous use of the drug and the fertilizer is achieved, and the drug fertilizer composition can be widely applied to growth of the golf green lawn and/or prevention and treatment of diseases.
Description
Technical field
The invention belongs to composite pesticide technology, relate to particularly a kind of control green turf disease medicine fertilizer composition and application thereof.
Background technology
Research China about medicine fertilizer starts from the eighties in 20th century.It is reported di_allate No. 2 control of weed in wheat field 6.2 ten thousand hm of Qinghai Province
2, wherein is mostly to carry out dispenser taking chemical fertilizer as carrier.The herbicide urea of Zhejiang and Ningxia development, adopts coating method that weedicide is wrapped in to urea granules appearance, on producing, topdresses and uses, though formed product, too single because of fertilizer and weedicide, not comprehensive nutrition, herbicide spectrum is narrower, and integrated application effect is undesirable, applies not yet.In addition the also composite fertilizer special of positive other crop of active development of people.As the coating medicine fertilizer of Chinese Academy of Sciences's Nanjing soil Research Institute is applicable to rice and wheat; The precious special medicated fertilizer of development Huanglong of fruit tree yellow twig research office of Central-South agricultural science and technology development research institute is suitable for citrus yellow shoot disease control etc.Domestic obtain the fertile registration of medicine have the Chlorpyrifos 94 medicament-fertilizer mixture of specially controlling subterranean pest-insect, a benzyl fourth medicament-fertilizer mixture of rice striking root herbicide double effects.Medicine fertilizer " integrated " is the useful measure that the low consumption of agricultural " three height " (being high yield, high quality, high benefit) is produced; combination of pesticide and fertilizer; saving of work and time; synergy mutually between fertilizer and medicine; agricultural chemicals evenly mixes together with fertilizer, can make the dispersity of agricultural chemicals improve, thereby can play a good provide protection to the root system of crop; fertilizer can promote again the absorption of agricultural chemicals simultaneously, to pesticide synergistic.
At present more for agricultural chemicals and the fertilizer research of the farm crop such as paddy rice, and for agricultural chemicals and the fertilizer few on lawn, and at present lawn application more and more extensive, for example campus, residential quarters etc.Especially be accompanied by the development of reform and opening-up and economic society, China's golf takes the lead in from coastal open areas such as Guangdong rising, golf course spreads all on both sides of the Changjiang River, according to Chinese Golf Association's incomplete statistics, at present there is nearly 500 of all kinds of golf club in China, match play number adds up to approximately 9500, because China's golf course construction starting is late, development rapidly, supporting lawn maintenance machinery, fertilizer, agricultural chemicals relatively lag behind, and mainly use imported product and agricultural field crop fertilizer, agricultural chemicals.
Golf green is the lawn that is positioned at a slice precision management around of golf course match play, is the most important and the most careful place of maintenance of golf course, and the quality of its quality has determined the grade of golf course.Requirement lawn, high quality fruit ridge is short, and branches and leaves density is large, and surface smoothing is even, and rebound resilience is good, but fruit ridge is sand matrix, and the soil organism and nutrient are extremely low, a little less than fertilizer-preserving ability; Fruit ridge grass is pruned frequent, the shallow table of lawn root system, and anti-adversity is low; Race and manual work, trample are frequent, cause the serious solid ventilation property of fruit ridge soil poor; Factor green turf in the majority adverse circumstance growth all the time, must frequently apply fertilizer and use sterilant, to maintain green turf growth.70% fertilizer and agricultural chemicals are lost in water body and air, cause environmental pollution and waste greatly.The fertile combination of medicine is with the feature of agricultural chemicals and fertilizer, and both improve security in conjunction with synergy mutually, reduce the application of inert ingredient, economize on resources, and simple to operate in production reality, saving of work and time, is the new direction of green lawn maintenance product.
Summary of the invention
In view of this, a kind of control green turf disease medicine fertilizer composition and application thereof are provided, to effectively solve green turf disease and regulate lawn growth, can prevent and treat fruit ridge grass Common Diseases, can provide grass growth required nutritive element and material for green turf again.
A kind of control green turf disease medicine fertilizer composition, it comprises the component of following mass percent:
Wherein, component A is RP-26019, derosal, prochloraz, prochloraz-manganese chloride complex, m-tetrachlorophthalodinitrile, ethylicin, the mould spirit of evil, metaxanin, Metalaxyl-M, coughs up at least one in bacterium cyanogen, tebuconazole, difenoconazole, phonetic bacterium fat, ether bacterium fat; B component is at least one in Plant hormones regulators,gibberellins, Nafusaku, naphthylacetic acid, naphthylacetic acid potassium, indolylacetic acid, indolebutyric acid, indolebutyric acid potassium, benzyladenine, brassinolide, acetic acid diethylaminoethanol ester, Whitfield's ointment, choline dichloride, mepiquat chloride, paclobutrazol, uniconazole, sodium nitrophenolate, triacontanol price quote.
And above-mentioned control green turf disease medicine fertilizer composition is for green lawn growth and/or disease control.
This medicine fertilizer composition is by rationally composite the sterilant of plant-growth regulator and protective fungicide or treatment and shoveling function; show by test; this medicine fertilizer composition has notable synergistic effect; further with the composite fusion of plant nutrient substance; reach the fertile economic benefits and social benefits of medicine; can prevent and treat green turf disease, again can be for maintenance lawn provide sufficient balanced nutritious element, realize medicine, fertilizer synchronously uses.
Embodiment
For making object of the present invention, technical scheme and technological merit clearer, below in conjunction with embodiment, content of the present invention is described further.Specific embodiment only, for explaining the present invention, is not intended to limit the present invention.All any amendments of making within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
The embodiment of the present invention provides a kind of control green turf disease medicine fertilizer composition, and it comprises the component of following mass percent:
Wherein, component A is RP-26019, derosal, prochloraz, prochloraz-manganese chloride complex, m-tetrachlorophthalodinitrile, ethylicin, the mould spirit of evil, metaxanin, Metalaxyl-M, coughs up at least one in bacterium cyanogen, tebuconazole, difenoconazole, phonetic bacterium fat, ether bacterium fat; B component is at least one in Plant hormones regulators,gibberellins, Nafusaku, naphthylacetic acid, naphthylacetic acid potassium, indolylacetic acid, indolebutyric acid, indolebutyric acid potassium, benzyladenine, brassinolide, acetic acid diethylaminoethanol ester, Whitfield's ointment, choline dichloride, mepiquat chloride, paclobutrazol, uniconazole, sodium nitrophenolate, triacontanol price quote.
Wherein, macronutrient compound is preferably at least one in urea, ammonium chloride, ammonium nitrate, ammonium sulfate, bicarbonate of ammonia, primary ammonium phosphate, Secondary ammonium phosphate, potassium primary phosphate, dipotassium hydrogen phosphate, Repone K, saltpetre, potassium sulfate, ammonium polyphosphate.More preferably, in above-mentioned medicine fertilizer composition macronutrient Compound Phase to medicine fertilizer composition total mass 100%, contain 0.5%～15% N element, 0.5%～10% P
2o
5, 0.5%～25% K
2one or more in O.
Meso-and micro-nutrients compound is preferably at least one in magnesium sulfate, magnesium chloride, magnesiumcarbonate, magnesium acetate, magnesium nitrate, nitrocalcite, EDTA calcium, borax, boric acid, four water eight Sodium Tetraboratees, zinc sulfate, zinc nitrate, zinc chloride, EDTA zinc, ferrous sulfate, ferrous ammonium sulphate, ironic citrate, NaFeEDTA, copper sulfate, cupric nitrate, EDTA copper, manganous sulfate, EDTA manganese, Sodium orthomolybdate, ammonium molybdate, EDTA molybdenum.More preferably, Meso-and micro-nutrients Compound Phase in above-mentioned medicine fertilizer composition to medicine fertilizer composition total mass 100%, preferably contain lower column element wherein at least one: one or more in 0.05%～5% MgO, 0.01%～0.5% B element, 0.1%～0.5% Zn element, 0.05%～0.5% Fe element, 0.05%～0.5% Cu element, 0.05%～0.5% Mn element, 0.05%～0.5% Mo element.
Active organic nutrient substance is preferably at least one in potassium humate, Sodium salts humic acids, yellow humic acid, biochemical fulvic acid potassium, aminoacids complex, Lalgine, chitosan, Nucleotide, tea saponin.The content of active organic nutrient substance is 5%～25%.
A more step ground, active organic nutrient substance is preferably at least one in potassium humate, yellow humic acid, chitosan.
Particularly; above-mentioned potassium humate; for the aromatic hydroxy-carboxylic salt of the non-homogeneous of a kind of polymer, be alkalescence, contain carboxyl, phenolic hydroxyl group isoreactivity group; it is a kind of efficient organic potassic fertilizer; because humic acids is wherein a kind of biologically active agents, can improve Soil Available potassium content, reduce the loss of potassium and fix; increase absorption and the utilization ratio of crop to potassium, also there is improvement soil, promote plant growth, improve crop anti-adversity ability, improve crop quality, protect the functions such as agroecological environment.
Particularly, above-mentioned yellow humic acid, is the short carbon chain molecular structure material extracting in natural humic acid.It has high capacity amount and physiologically active, energy chelating constant and trace nutrient; Controlling plant diseases, strengthens waterlogging-resistant property; Slow release fertilizer, improves chemical fertilizer and agricultural chemicals utilization; Improve dietetic alimentation, promote plant germination and growth; Accelerate precipitation and decompose, improve Soil structure.
Particularly; above-mentioned chitosan, is the product of chitin N-deacetylation, and chemical name is Chitosan (1-4)-2-amino-B-D glucose; it is the natural short long agent of plant nutrition; can give plant insecticide, disease-resistant, play the effect of fertilizer; can decompose again plant and animal residues and micro-metals in soil; thereby be converted into the nutritive element of plant, strengthen via plant immunity, promote the health of plant.
Auxiliary is at least one in solvent, wetting agent, dispersion agent, emulsifying agent, disintegrating agent.By adding this auxiliary, can further be convenient to the formation of this medicine fertilizer composition, and improve its stability.
Solvent is preferably at least one in glycerol mono acetate bulk, turps, fatty acid methyl ester, N-ethyl pyrrolidone, N-Methyl pyrrolidone, dimethyl formamide, Virahol, isopropylcarbinol.Wetting agent is preferably at least one in alkyl-sulphate, alkylbenzene sulfonate, sulfonated alkyl naphathalene, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, sorbitan fatty acid ester.Dispersion agent is preferably at least one in sodium lignosulfonate, bay alcohol radical sodium sulfate, phosphoric acid salt, alkylphenol-polyethenoxy base phosphoric acid ester.Emulsifying agent is preferably at least one in calcium dodecylbenzene sulphonate, aliphatic acid polyethenoxy base ether, styroyl phenol polyethenoxy ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester.Disintegrating agent is preferably modified starch or sodium bicarbonate.
In above-mentioned medicine fertilizer composition formula; by rationally composite the sterilant of plant-growth regulator and protective fungicide or treatment and shoveling function; show by following test; this medicine fertilizer composition has notable synergistic effect; further, with the composite fusion of plant nutrient substance, reach the fertile economic benefits and social benefits of medicine, can prevent and treat green turf disease; again can be for maintenance lawn provide sufficient balanced nutritious element, realize medicine, fertilizer synchronously uses.
In addition, show by application in practice, this medicine fertilizer composition is to being obviously better than contrast in green turf plant height, panel length, leaf look, tiller number, disease resistance and appearance features (cover degree, frequency, color and luster, density) index.
Find in test, the medicine fertilizer composition of the embodiment of the present invention is to common fruit ridge grass crawl bent grass plant height, the long effect that has stronger retarding of growing of joint, through observation can effectively control plant height, internode is long, the speed of growth is eased up, promotion is tillered, and leaf look turns green, and blade, stipes are sturdy.While using first the 60th day, plant height, the long measurement result of joint are listed as follows:
The medicine fertilizer composition of table 1 different concns is on bent grass plant height and the long impact of joint of crawling
Each treatment capacity sprays processing to the bent grass of crawling after being watered 200 times of dilutions, and interval is reused for 15 days, and respectively processing consumption is the medicine fertilizer composition 20g/m of the embodiment of the present invention
2(A), 15g/m
2(B), 10g/m
2(C), with N-P
2o
5-K
2o is the water soluble fertilizer 15g/m of 24-10-16
2for contrast (CK), each processing can delay to crawl bent grass growth, reduces its speed of growth, shortens chap between envoy, has the metabolic balance effect that regulates earth's surface stolon and rhizome.Through the inspection of LSR method, between contrast and each processing, difference reaches conspicuous level.
By the medicine fertilizer composition re-treatment of the embodiment of the different concns bent grass of crawling, use first after the 60th day, the observed result of respectively processing overground part fresh weight and underground part (0～15cm) rhizome fresh weight is as shown in table 2.
The impact of the medicine fertilizer composition of table 2 different concns on the bent grass biomass of crawling
As can be seen from Table 2, bent grass its overground part fresh weight after the medicine fertilizer composition of the embodiment of the present invention is processed of crawling contrasts decline in various degree, and A processes overground part fresh weight and declines at most, checks each processing and contrast difference to reach conspicuous level through LSR method.The medicine fertilizer of the embodiment of the present invention is respectively processed the growth of bottom 0～15cm root system over the ground significant promoter action, can make well developed root system, main root sturdy, root system dense layer distributes high compared with control group, be conducive to improve the bent grass root/shoot ratio of crawling, can make like this its overground part unit vol absorb surface area larger, more easily absorb more nutrient
The impact of the embodiment of the present invention medicine fertilizer composition of table 3 different concns on the bent grass tiller number of crawling
As can be seen from Table 3, the medicine fertilizer composition of the embodiment of the present invention is respectively processed tiller number all than remarkable the increasing of contrast, reaches conspicuous level through LSR method inspection with contrasting.Visible, the medicine fertilizer of the embodiment of the present invention is tillered and is had obvious promoter action the bent grass of crawling, this is the medicine fertilizer composition due to the embodiment of the present invention, complement each other by the each composition in formula, by controlling and promoting to increase interaction, change the balance of each endogenous hormones in the bent grass of crawling, broken the apical dominance of the bent grass of crawling, thereby promoted the formation of tillering.In addition, plant height reduces with internode and shortens chap, has reduced nutrient consumption and photosynthesis and has strengthened, also for tiller formation provides enough basic substances.
Taking Common Diseases, if blight, brown spot are as the medicine fertilizer composition of the example explanation embodiment of the present invention prevention effect to green turf, wherein, table 4-1 and 4-2 show with 15g/m
2the result of the impact of 200 times of spray fruit ridges of medicine fertilizer composition dilution of the embodiment of the present invention on the bent grass Common Diseases of crawling.
The crawl preventive effect of bent grass grass blight of the medicine fertilizer composition Dui Guo ridge of the table 4-1 embodiment of the present invention
The crawl preventive effect of bent grass grass brown spot of the medicine fertilizer composition Dui Guo ridge of table 4-2, the embodiment of the present invention
From table 4-1, the medicine fertilizer composition Dui Guo ridge of the embodiment of the present invention bent grass grass blight prevention effect of crawling is obviously better than the effect of derosal, from table 4-2, crawl in the prevention effect of bent grass brown spot in the medicine fertilizer composition Dui Guo ridge of the embodiment of the present invention, after medicine, the 10th day disease index aspect fall is substantially suitable, and prevention effect also reaches higher level.
In practical application, the medicine fertilizer composition of the embodiment of the present invention, applicable to various Diseases of Turfgrass controls and growth regulating, for example, shows by spot testing, the medicine fertilizer composition of the embodiment of the present invention is being applied to green lawn growth and/or disease control, and effect is remarkable.
Component and the content thereof of medicine fertilizer composition of the present invention are described by concrete test examples below,
Embodiment 1
Component A: 0.5 kilogram of metaxanin, 0.25 kilogram of m-tetrachlorophthalodinitrile
B component: 0.25 kilogram of paclobutrazol, 0.2 kilogram of Plant hormones regulators,gibberellins
Macroelement compound: 20 kilograms, urea, 15 kilograms, Repone K, 8 kilograms of 15 kilograms of primary ammonium phosphates of ammonium chloride, 14 kilograms of potassium primary phosphates, 5 kilograms, ammonium sulfate
Middle trace compound: 0.8 kilogram, zinc sulfate, 0.5 kilogram of manganous sulfate, 0.5 kilogram of 0.1 kilogram of ferrous sulfate amine of copper sulfate, 8 kilograms, nitrocalcite
Active organic nutrient substance: 10 kilograms of potassium humates, 1 kilogram of tea saponin
Auxiliary: 0.4 kilogram of Virahol, 0.3 kilogram of sodium alkyl sulfate, 0.2 kilogram of fatty alcohol-polyoxyethylene ether (AEO-3).
Above-mentioned each component materials can be made into wettable powder through being pulverized and mixed.
Any one or several compositions of mixtures and this area any one or several mixtures in common knowledge in 0.3～1 kilogram of Sodium dodecylbenzene sulfonate of the replaceable one-tenth of sodium alkyl sulfate, sodium lignosulfonate, alkyl benzene calcium sulfonate, lauryl alcohol polyethylene glycol oxide base ether in above-described embodiment 1.
Embodiment 2
Component A: dislike mould clever 3 kilograms, 2 kilograms of RP-26019,0.25 kilogram of difenoconazole
B component: 0.25 kilogram, multiple nitrophenol sodium, 1 kilogram of choline dichloride, naphthylacetic acid 0.15
Macroelement compound: 35 kilograms, saltpetre, 5.5 kilograms of potassium sulfate, 10 kilograms of ammonium polyphosphates, 2.5 kilograms, ammonium nitrate
1.5 kilograms, middle trace compound EDTA zinc, 0.5 kilogram of manganous nitrate, 0.35 kilogram of cupric nitrate, 1 kilogram, ferrous sulfate, 5.5 kilograms, magnesium chloride
Active organic nutrient substance: 20 kilograms of aminoacids complexs, 1 kilogram of chitosan
Auxiliary: 7.5 kilograms of N-Methyl pyrrolidone, 3 kilograms of castor oil polyoxyethylene ethers.
Mould evil spirit, difenoconazole, RP-26019, naphthylacetic acid are dissolved in to N-Methyl pyrrolidone, after mixing with each component with castor oil polyoxyethylene ether emulsification, adopt spraying adsorption dry to make soluble powder.
Embodiment 3
Component A: 2 kilograms of RP-26019,0.5 kilogram of derosal, 0.3 kilogram of prochloraz-manganese chloride complex
B component: 0.8 kilogram of mepiquat chloride, 0.2 kilogram of Plant hormones regulators,gibberellins, 0.1 kilogram, indolebutyric acid potassium
Macroelement compound: 10 kilograms, urea, 5 kilograms, saltpetre, 10 kilograms of potassium sulfate, 10 kilograms of Secondary ammonium phosphates, 25 kilograms, Repone K, 8.2 kilograms, ammonium sulfate
Middle trace compound: 0.5 kilogram, EDTA zinc, 0.3 kilogram of manganous sulfate, 0.1 kilogram, copper sulfate, 0.5 kilogram of NaFeEDTA, 5 kilograms of magnesium nitrates
Active organic nutrient substance: 13 kilograms of biochemical fulvic acid potassiums, 1 kilogram of Lalgine
Auxiliary: 5 kilograms of dimethyl formamides, 2.5 kilograms of calcium dodecylbenzene sulphonates
RP-26019, derosal are dissolved in to dimethyl formamide, calcium dodecylbenzene sulphonate emulsification, after all mixing of materials, make after drying solvable pulvis.
Embodiment 4
Component A: 3 kilograms of tebuconazoles, 0.5 kilogram of Metalaxyl-M
B component: Nafusaku 0.25,0.001 kilogram of brassinolide, 0.01 kilogram of uniconazole
Macroelement compound: 25 kilograms, urea, 5 kilograms, Repone K, 10 kilograms of potassium sulfate, 7 kilograms of dipotassium hydrogen phosphates, 14.089 kilograms, ammonium nitrate
Middle trace compound: 0.5 kilogram, EDTA zinc, 0.3 kilogram, EDTA manganese, 0.1 kilogram, copper sulfate, 0.5 kilogram of ironic citrate, 5 kilograms, magnesium sulfate, 0.25 kilogram of four water eight Sodium Tetraborate
Active organic nutrient substance: 25 kilograms of yellow humic acids, 0.5 kilogram, Nucleotide
Auxiliary: 2.5 kilograms of sodium lignosulfonates, 0.5 kilogram of aliphatic acid polyethenoxy base ester
After being mixed, above-mentioned each component materials makes wettable powder
Embodiment 5
Component A: 0.5 kilogram of prochloraz, 0.1 kilogram, phonetic bacterium fat
B component: 0.05 kilogram of indolylacetic acid, 1 kilogram of acetic acid diethylaminoethanol ester, 0.15 kilogram of paclobutrazol, 0.75 kilogram of Whitfield's ointment
Macroelement compound: 25 kilograms, urea, 15 kilograms, Repone K, 10 kilograms of Secondary ammonium phosphates, 20 kilograms, ammonium sulfate
Middle trace compound: 0.8 kilogram of zinc nitrate, 0.5 kilogram, EDTA manganese, 0.09 kilogram of EDTA copper, 1 kilogram, ferrous sulfate, 5 kilograms of EDTA calcium, 6.8 kilograms, magnesium sulfate, 0.25 kilogram of boric acid, 0.01 kilogram of Sodium orthomolybdate
Active organic nutrient substance: 10 kilograms of Sodium salts humic acidss, 0.5 kilogram, Nucleotide
Auxiliary: 1 kilogram of sodium alkyl sulfate, 1.5 kilograms of calcium dodecylbenzene sulphonates
After being mixed, above-mentioned each component materials makes wettable powder
Embodiment 6
Component A: cough up 0.75 kilogram, bacterium cyanogen, 2.5 kilograms of ethylicins,, 0.5 kilogram, ether bacterium fat
B component: 0.25 kilogram of benzyladenine, 0.05 kilogram, naphthylacetic acid potassium, 1 kilogram of choline dichloride
Macroelement compound: 15 kilograms, saltpetre, 5.5 kilograms, Repone K, 10 kilograms of ammonium polyphosphates, 38.85 kilograms, urea
Middle trace compound: 0.75 kilogram, zinc sulfate, 0.25 kilogram, EDTA manganese, 0.1 kilogram, copper sulfate, 0.5 kilogram of NaFeEDTA, 7.5 kilograms, magnesium sulfate, 0.5 kilogram of borax
Active organic nutrient substance: 10 kilograms of potassium humates, 0.5 kilogram of Lalgine
Auxiliary: 2 kilograms of glycerol mono acetate bulks, 1 kilogram of alkane calcium dodecylbenzene sulphonate, 2.5 kilograms of modified starches
After coughing up bacterium cyanogen, ethylicin, ether bacterium fat and mixing with glycerol mono acetate bulk, alkane calcium dodecylbenzene sulphonate, then be mixed and made into water dispersible granules with other each component materials.
Effect simultaneous test
Carry out below the effect of more each embodiment by the bent grass grass application test of crawling at Golf green; Test was carried out in the rotten mildew high-incidence season in 2-5 month, each embodiment 15g/m
2dilute 1000 times of spray lawns, interval is once used three times for 15 days continuously; Use first latter 30 days and within 60 days, investigate the preventive effect of rotten mildew and measure " root/shoot ratio " and determine careless growing way and healthy and strong degree, and with N-P
2o
5-K
2o is water soluble fertilizer (NPK) 15g/m of 24-10-16
2the agent of+conventional sterilization is contrast; Result is as following table 5 and 6:
Table 5
| Embodiment | The 30th day preventive effect (%) to rotten mildew | The 30th day root/shoot ratio |
| 1 | 45 | 0.42 |
| 2 | 48 | 0.48 |
| 3 | 38 | 0.43 |
| 4 | 42 | 0.38 |
| 5 | 58 | 0.51 |
| 6 | 35 | 0.36 |
| NPK+ dislikes mould spirit | 32 | 0.34 |
| NPK+ zinc manganese ethylenebisdithiocarbamate | 28 | 0.32 |
Table 6
| Embodiment | The 60th day preventive effect (%) to rotten mildew | The 60th day root/shoot ratio |
| 1 | 52 | 0.52 |
| 2 | 56 | 0.61 |
| 3 | 45 | 0.48 |
| 4 | 43 | 0.42 |
| 5 | 75 | 0.56 |
| 6 | 48 | 0.50 |
| NPK+ dislikes mould spirit | 45 | 0.38 |
| NPK+ zinc manganese ethylenebisdithiocarbamate | 42 | 0.34 |
From above-mentioned each test; this medicine fertilizer composition passes through rationally composite the sterilant of plant-growth regulator and protective fungicide or treatment and shoveling function; there is notable synergistic effect; disease effect to lawn is remarkable; further, with the composite fusion of plant nutrient substance, reach the fertile economic benefits and social benefits of medicine, can prevent and treat green turf disease; again can be for maintenance lawn provide sufficient balanced nutritious element, realize medicine, fertilizer synchronously uses.
These are only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.
Claims (9)
1. a control green turf disease medicine fertilizer composition, it comprises the component of following mass percent:
Wherein, component A is RP-26019, derosal, prochloraz, prochloraz-manganese chloride complex, m-tetrachlorophthalodinitrile, ethylicin, the mould spirit of evil, metaxanin, Metalaxyl-M, coughs up at least one in bacterium cyanogen, tebuconazole, difenoconazole, phonetic bacterium fat, ether bacterium fat; B component is at least one in Plant hormones regulators,gibberellins, Nafusaku, naphthylacetic acid, naphthylacetic acid potassium, indolylacetic acid, indolebutyric acid, indolebutyric acid potassium, benzyladenine, brassinolide, acetic acid diethylaminoethanol ester, Whitfield's ointment, choline dichloride, mepiquat chloride, paclobutrazol, uniconazole, sodium nitrophenolate, triacontanol price quote.
2. composition according to claim 1, it is characterized in that, described macronutrient compound is at least one in urea, ammonium chloride, ammonium nitrate, ammonium sulfate, bicarbonate of ammonia, primary ammonium phosphate, Secondary ammonium phosphate, potassium primary phosphate, dipotassium hydrogen phosphate, Repone K, saltpetre, potassium sulfate, ammonium polyphosphate.
3. composition according to claim 1, it is characterized in that, described Meso-and micro-nutrients compound is at least one in magnesium sulfate, magnesium chloride, magnesiumcarbonate, magnesium acetate, magnesium nitrate, nitrocalcite, EDTA calcium, borax, boric acid, four water eight Sodium Tetraboratees, zinc sulfate, zinc nitrate, zinc chloride, EDTA zinc, ferrous sulfate, ferrous ammonium sulphate, ironic citrate, NaFeEDTA, copper sulfate, cupric nitrate, EDTA copper, manganous sulfate, EDTA manganese, Sodium orthomolybdate, ammonium molybdate, EDTA molybdenum.
4. composition according to claim 1, it is characterized in that, described active organic nutrient substance is at least one in potassium humate, Sodium salts humic acids, yellow humic acid, biochemical fulvic acid potassium, aminoacids complex, Lalgine, chitosan, Nucleotide, tea saponin.
5. composition according to claim 1, is characterized in that, described macronutrient Compound Phase to medicine fertilizer composition total mass 100%, contain 0.5%～15% N element, 0.5%～10% P
2o
5, 0.5%～25% K
2one or more in O.
6. composition according to claim 1, it is characterized in that, described Meso-and micro-nutrients Compound Phase to medicine fertilizer composition total mass 100%, contain one or more in 0.05%～5% MgO, 0.01%～0.5% B element, 0.1%～0.5% Zn element, 0.05%～0.5% Fe element, 0.05%～0.5% Cu element, 0.05%～0.5% Mn element, 0.05%～0.5% Mo element.
7. composition according to claim 1, is characterized in that, described auxiliary is at least one in solvent, wetting agent, dispersion agent, emulsifying agent, disintegrating agent.
8. composition according to claim 7, it is characterized in that, described solvent is glycerol mono acetate bulk, turps, fatty acid methyl ester, N-ethyl pyrrolidone, N-Methyl pyrrolidone, dimethyl formamide, Virahol, at least one in isopropylcarbinol, described wetting agent is alkyl-sulphate, alkylbenzene sulfonate, sulfonated alkyl naphathalene, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, at least one in sorbitan fatty acid ester, described dispersion agent is sodium lignosulfonate, bay alcohol radical sodium sulfate, phosphoric acid salt, at least one in alkylphenol-polyethenoxy base phosphoric acid ester, described emulsifying agent is calcium dodecylbenzene sulphonate, aliphatic acid polyethenoxy base ether, styroyl phenol polyethenoxy ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, at least one in aliphatic acid polyethenoxy base ester, described disintegrating agent is modified starch or sodium bicarbonate.
9. be used for green lawn growth and/or disease control according to the arbitrary described control green turf disease medicine fertilizer composition of claim 1～8.
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