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CN114183874A - Purification device and air conditioner - Google Patents

Purification device and air conditioner Download PDF

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Publication number
CN114183874A
CN114183874A CN202111355979.0A CN202111355979A CN114183874A CN 114183874 A CN114183874 A CN 114183874A CN 202111355979 A CN202111355979 A CN 202111355979A CN 114183874 A CN114183874 A CN 114183874A
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Prior art keywords
light guide
light
purification
purification apparatus
photocatalytic material
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CN202111355979.0A
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Chinese (zh)
Inventor
刘永如
裴晨星
杨翠霞
章文贵
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Midea Group Co Ltd
GD Midea Air Conditioning Equipment Co Ltd
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Midea Group Co Ltd
GD Midea Air Conditioning Equipment Co Ltd
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Priority to CN202111355979.0A priority Critical patent/CN114183874A/en
Publication of CN114183874A publication Critical patent/CN114183874A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/10Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
    • F24F8/15Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by chemical means
    • F24F8/167Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by chemical means using catalytic reactions
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F1/00Room units for air-conditioning, e.g. separate or self-contained units or units receiving primary air from a central station
    • F24F1/0007Indoor units, e.g. fan coil units
    • F24F1/0071Indoor units, e.g. fan coil units with means for purifying supplied air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F1/00Room units for air-conditioning, e.g. separate or self-contained units or units receiving primary air from a central station
    • F24F1/02Self-contained room units for air-conditioning, i.e. with all apparatus for treatment installed in a common casing
    • F24F1/0328Self-contained room units for air-conditioning, i.e. with all apparatus for treatment installed in a common casing with means for purifying supplied air

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The embodiment of the application provides a purifier and air conditioner, purifier includes: a purification composition and a light guide assembly; the purification composition comprises a photocatalytic material and an adsorption material; the light guide assembly is used for guiding light generated by the light source to the photocatalytic material, so that the photocatalytic material can purify pollutants in the environment and pollutants adsorbed by the adsorption material. The purifier of this application embodiment has better result of use.

Description

Purification device and air conditioner
Technical Field
The application relates to the technical field of air conditioners, in particular to a purifying device and an air conditioner.
Background
At present, the air conditioner becomes an indispensable part of people's daily life, and more than 80% of people's lifetime spend indoors, and the elderly and infants spend indoors even more than 95%, so the air conditioner with the health functions of removing formaldehyde, removing PM2.5, resisting bacteria and the like is more and more the first choice of consumers.
However, the related art air conditioner purifying apparatus has a lot of inconvenience in use.
Disclosure of Invention
In view of this, it is desirable to provide a purification device and an air conditioner with better use effect.
To achieve the above object, an embodiment of the present application provides a purification apparatus, including:
a purification composition comprising a photocatalytic material and an adsorbent material;
the light guide assembly is used for guiding light generated by the light source to the photocatalytic material, so that the photocatalytic material can purify pollutants in the environment and pollutants adsorbed by the adsorption material.
In one embodiment, the light incident side of the light guide assembly is located within the irradiation range of the visible light source.
In one embodiment, the purification composition can be passed through by a gas stream.
In one embodiment, the light guide assembly comprises a fiber bundle, and the light emitting side of the fiber bundle faces the photocatalytic material.
In one embodiment, the light guide assembly further comprises a first light guide panel, wherein the first light guide panel is inserted into the light outlet side of the optical fiber bundle; and/or the presence of a gas in the gas,
the light guide assembly further comprises a second light guide panel, and the second light guide panel is inserted into the light inlet side of the optical fiber bundle.
In one embodiment, the second light guide panel is a light panel lamp.
In one embodiment, the light guide assembly is a module that transmits light by reflection or transmission.
In one embodiment, the photocatalytic material comprises ZnO, TiO2、CdS、ZnS、Bi2S3、g-C3N4、BiOX(X=Cl,Br,I)、BixWOyOne or more of; and/or the presence of a gas in the gas,
the photocatalytic material comprises ZnO and TiO2、CdS、ZnS、Bi2S3、g-C3N4、BiOX(X=Cl,Br,I)、BixWOyModified doped derivatives of at least one of (1).
In one embodiment, the adsorbent material comprises one or more of a porous carbon material, a molecular sieve, a modified molecular sieve, a silica gel, a modified silica gel, a metal organic framework.
In one embodiment, the porous carbon material comprises one or more of activated carbon, graphite, graphene, carbon aerogel, synthetic carbon.
In one embodiment, the photocatalytic material is mixed with the adsorbent material or layered.
In one embodiment, the photocatalytic material and the adsorbent material together form a solid structure.
In one embodiment, the purification device further comprises a composition carrier, the purification composition being disposed on the composition carrier.
In one embodiment, the composition support is a porous support or an air-permeable support through which the gas stream can pass, and the photocatalytic material is mixed with the adsorbent material and dispersed on the porous support or the air-permeable support.
In one embodiment, the material of the composition carrier is any one of an organic polymer material, a metal material, and an inorganic nonmetal; and/or the presence of a gas in the gas,
the purification device further comprises an auxiliary material for dispersing and/or immobilizing the purification composition on the composition carrier.
Another embodiment of the present application provides an air conditioner, including the above-mentioned purification device.
The embodiment of the application provides a purification device and an air conditioner, wherein a purification composition of the purification device is simultaneously provided with a photocatalytic material and an adsorption material, pollutants can be adsorbed and purified through the adsorption material at night without starting any light source for exciting the photocatalytic material, light generated by the light source can be guided to the photocatalytic material through a light guide assembly to excite the photocatalytic material to purify the pollutants in the environment and the pollutants adsorbed by the adsorption material in the daytime, namely, the photocatalytic material can decompose the pollutants in the environment and can decompose the pollutants adsorbed by the adsorption material at the same time so that the adsorption material cannot reach an adsorption saturation state (as can be understood, the adsorption material can adsorb and purify the pollutants in the daytime), therefore, through the mutual matching of the photocatalytic material and the adsorption material, the purification device can realize continuous purification in all weather, can avoid the influence of a UV mercury lamp or a UV-LED lamp which is turned on at night on the sleep quality of consumers, can also overcome the problem that an adsorption material needs to be replaced regularly, and further can enable the purification device of the embodiment of the application to have a better use effect.
Drawings
Fig. 1 is a schematic structural diagram of a purification apparatus according to an embodiment of the present invention, in which arrows indicate the direction of airflow.
Description of the reference numerals
A decontamination composition 10; a light guide member 20; an optical fiber bundle 21; a first light guide panel 22; a second light guide panel 23; a composition carrier 30.
Detailed Description
It should be noted that, in the present application, technical features in examples and embodiments may be combined with each other without conflict, and the detailed description in the specific embodiment should be understood as an explanation of the gist of the present application and should not be construed as an improper limitation to the present application.
Referring to fig. 1, the purification apparatus includes a purification composition 10 and a light guide member 20; the purification composition 10 includes a photocatalytic material and an adsorbent material; the light guide assembly 20 is used for guiding the light generated by the light source to the photocatalytic material, so that the photocatalytic material can purify the pollutants in the environment and the pollutants adsorbed by the adsorbing material.
Another embodiment of the present application further provides an air conditioner, which includes the purification device provided in any embodiment of the present application.
The pollutants described in the embodiments of the present application mainly refer to fine particulate matters (PM2.5), Volatile Organic Compounds (VOCs), semi-volatile organic compounds (semi-SVOCs), harmful microorganisms, allergic substances, odorous gases, and the like, which are commonly found in daily environments.
The photocatalytic material is a semiconductor catalyst material capable of generating photochemical reaction under the action of light, the photocatalytic material can generate photoproduction electrons and photoproduction holes under the excitation of light, a part of the photoproduction electrons and the photoproduction holes can be compounded on the bulk phase or the surface of the photocatalytic material and disappear in the migration process, energy is released in the form of heat or photons, the other part of the photoproduction electrons or the photoproduction holes can migrate to the surface of the photocatalytic material and respectively generate reduction and oxidation reactions with a reactant, if the generated photoproduction electrons have enough reduction capacity, oxygen adsorbed on the surface of the photocatalytic material can be converted into free radicals, and similarly, if the generated photoproduction holes have enough oxidation capacity, the generated photoproduction electrons can react with adsorbed water on the surface of the photocatalytic material to generate hydroxyl free radicals, and finally the active free radicals can further perform oxidation reaction with organic matter molecules adsorbed on the surface of the photocatalytic material, thereby achieving the purification of the pollutants.
The light guide assembly 20 may enable the light generated by the light source to excite the photocatalytic material by guiding the light generated by the light source to the photocatalytic material.
The adsorbing material can adsorb the pollutants in the environment, but can not decompose the pollutants adsorbed by the adsorbing material, that is to say, the adsorbing material has saturation, and after the adsorbing material reaches adsorption saturation, the adsorbing material can not further adsorb the pollutants.
In the related art, there are air conditioners that perform purification by a photocatalytic method and air conditioners that perform purification by an adsorption method, but the air conditioners that perform purification by a photocatalytic method require a photocatalytic material to be excited by light to purify contaminants, and if the contaminants are to be purified at night, the UV (ultraviolet) mercury lamp or UV-LED lamp for exciting the photocatalytic material needs to be continuously turned on, which affects the sleep quality of consumers, in case that more than 70% of the air conditioners are used at night. And the air conditioner that adopts the adsorption mode to purify need to be changed the adsorption material after the adsorption material reaches the adsorption saturation, from this, also can influence consumer's use and experience.
The purifying composition 10 of the purifying device of the embodiment of the present application is provided with the photocatalytic material and the adsorbing material at the same time, so that the pollutants can be adsorbed and purified by the adsorbing material at night without turning on any light source for exciting the photocatalytic material, and the light generated by the light source can be guided to the photocatalytic material by the light guide assembly 20 during the day to excite the photocatalytic material to purify the pollutants in the environment and the pollutants adsorbed by the adsorbing material, that is, the pollutants in the environment can be decomposed by the photocatalytic material, and the pollutants adsorbed by the adsorbing material can also be decomposed at the same time, so that the adsorbing material can not reach the adsorption saturation state (it can be understood that the pollutants can also be adsorbed and purified by the adsorbing material during the day), therefore, through the mutual matching of the photocatalytic material and the adsorbing material, the continuous purification in all weather can be realized, the problem that the adsorption material needs to be replaced regularly can also be avoided that the sleep quality of consumers is influenced by the UV mercury lamp or the UV-LED lamp which is turned on at night, and the purification device provided by the embodiment of the application has a good use effect.
In addition, related technologies also include air conditioners that perform purification by means of filtration, high-voltage static electricity, catalysis (non-photocatalysis), and the like, where the filtration mainly uses a filter to remove pollutants such as PM2.5, harmful microorganisms, and the like in the environment, but the filter has a large resistance, needs to be replaced, and has substantially no effect on VOCs; the high-voltage static way is that the high-voltage electrostatic field is utilized to make dust particles in gas be concentrated on the dust collecting plate under the action of the electric field force after the dust particles are charged, so that the effect of air purification is achieved, the removal performance of the high-voltage static to PM2.5 and harmful microorganisms is good, however, ozone is generated in the using process, the removal performance to VOCs is poor, and the price is high; the catalytic mode is to utilize the abundant and complicated constitution and structure of metallic oxide, oxidizes organic pollutants into harmless molecules such as carbon dioxide and water, and the catalytic mode is better to the removal performance of reductive pollutants such as formaldehyde under the room temperature condition, but generally need to cooperate with high-voltage static to realize getting rid of pollutants such as VOCs to the catalytic mode can produce the accessory substance, leads to secondary pollution.
The purification composition 10 of the embodiment of the present application is mainly composed of a photocatalytic material and an adsorbing material, the photocatalytic material and the adsorbing material can rapidly remove VOCs, semi-SVOCs, odorous gases, harmful microorganisms, allergic substances, carbon dioxide and the like in the environment, the purification composition has the characteristics of high removal efficiency, low resistance, no need of replacement, low cost and the like, and therefore, compared with various purification modes in the related art, the purification device of the embodiment of the present application can bring excellent use experience to consumers.
The light incident side of the light guide assembly 20 in the embodiment of the present application may be located in the irradiation range of the visible light source, that is, the light guide assembly 20 may guide the visible light generated by the lamp and/or the natural light generated by the sun, etc. to the photocatalytic material.
Specifically, in the related art, ultraviolet rays generated by a UV mercury lamp or a UV-LED lamp are generally used to excite a photocatalytic material, but the ultraviolet rays have a certain destructive effect on a human body and the surrounding environment, and need to be protected, and even if the protection is done, the risk of leakage of the ultraviolet rays still exists.
The light guide assembly 20 of the embodiment of the present application guides the visible light generated by the lamp and/or the natural light generated by the sun to the photocatalytic material, that is, the photocatalytic material can be excited only by using the common lamp and/or the sun as the light source, so that the ultraviolet light generated by the UV mercury lamp or the UV-LED lamp can be prevented from damaging the human body and the environment, and especially when only the sun is used as the light source, the consumption of electric energy can be reduced, so as to achieve green environmental protection.
It will be appreciated that in some embodiments, a UV mercury lamp or UV-LED lamp may also be used as the light source for exciting the photocatalytic material.
The purification composition 10 can be configured to allow a gas stream to pass therethrough, whereby contaminants in the gas stream can be brought into sufficient contact with the purification composition 10 when the gas stream containing the contaminants passes through the purification composition 10, and thus the purification effect can be improved.
The light guide member 20 shown in fig. 1 is disposed on the air intake side of the purification composition 10, and it is understood that the light guide member 20 is not limited to being disposed on the air intake side of the purification composition 10 as long as the light guide member 20 can guide the light generated from the light source to the photocatalytic material.
In some embodiments, the gas stream may not pass through the purification composition 10.
The light guide element 20 may have various structures, for example, in an embodiment, referring to fig. 1, the light guide element 20 includes an optical fiber bundle 21, and the light emitting side of the optical fiber bundle 21 faces the photocatalytic material.
Specifically, the optical fiber bundle 21 is composed of a plurality of light guide filaments, and the optical fiber bundle 21 has a good light guide performance and can guide more light to the photocatalytic material.
Further, in an embodiment, referring to fig. 1, the light guide assembly 20 further includes a first light guide panel 22 and a second light guide panel 23, the first light guide panel 22 is inserted into the light exit side of the optical fiber bundle 21, and the second light guide panel 23 is inserted into the light entrance side of the optical fiber bundle 21. The first light guide panel 22 can collect the light generated by the light source and guide the light to the optical fiber bundle 21, and the second light guide panel 23 can guide the light conducted by the optical fiber bundle 21 to the photocatalytic material, so that the light can be more uniformly irradiated on the photocatalytic material, that is, the light guide effect of the light guide assembly 20 can be improved by arranging the first light guide panel 22 and the second light guide panel 23.
In some embodiments, the first light guide panel 22 may be disposed only on the light exit side of the optical fiber bundle 21, or the second light guide panel 23 may be disposed only on the light entrance side of the optical fiber bundle 21, or the first light guide panel 22 and the second light guide panel 23 may not be disposed.
In addition, second light guide panel 23 and first light guide panel 22 can be the light guide panel who has the same structure, and second light guide panel 23 also can be the light panel lamp, that is to say, can set up a plurality of lamp pearls on the second light guide panel 23, and fiber bundle 21 leads the lamp pearl with light to shine the photocatalysis material through the lamp pearl of lighting, from this, can further improve the leaded light effect.
In some embodiments, the light guide assembly 20 may also be a module that transmits light by reflection or transmission, that is, the light guide assembly 20 may also direct light to the photocatalytic material by transmission or reflection.
The photocatalytic material described in the embodiments of the present application may be various, and for example, the photocatalytic material may include ZnO, TiO, and the like2、CdS、ZnS、Bi2S3、g-C3N4、BiOX(X=Cl,Br,I)、BixWOyMay also comprise one or more of ZnO and TiO2、CdS、ZnS、Bi2S3、g-C3N4、BiOX(X=Cl,Br,I)、BixWOyModified doped derivatives of at least one of (1).
Wherein the modified doped derivative is ZnO or TiO as exemplified above2、CdS、ZnS、Bi2S3、g-C3N4、BiOX(X=Cl,Br,I)、BixWOyThe modified doped derivatives corresponding to the materials can be independently used as the photocatalytic material, or a plurality of modified doped derivatives can be mixed together to jointly form the photocatalytic material, or one or more of the modified doped derivatives and ZnO and TiO can be used together with the photocatalytic material2、CdS、ZnS、Bi2S3、g-C3N4、BiOX(X=Cl,Br,I)、BixWOyOne or more of which are mixed together to collectively form the photocatalytic material.
The adsorbing material according to the embodiment of the present disclosure may also be various, and for example, the adsorbing material may include one or more of porous carbon materials, molecular sieves, modified molecular sieves, silica gels, modified silica gels, and Metal-Organic Frameworks (MOFs).
The modified molecular sieve and the modified silica gel are respectively formed by modifying the molecular sieve and the silica gel, and the modification mode includes but is not limited to the change of pore diameter, particle size, silica-alumina ratio of the silica gel, surface activity and the like.
The porous carbon material can be one or more of activated carbon, graphite, graphene, carbon aerogel and artificially synthesized carbon materials, and has a good effect of adsorbing VOCs, SVOCs, PM2.5 and harmful microorganisms.
The MOFs are organic-inorganic hybrid materials with intramolecular pores formed by self-assembly of organic ligands and metal ions or clusters through coordination bonds, and have good adsorption performance on low-concentration odor molecules due to the existence of the metal ions.
The photocatalytic material can be mixed with the adsorption material, that is, the photocatalytic material and the adsorption material can be mixed to form a whole, for example, the powdered photocatalytic material and the powdered adsorption material are doped together to form the purification composition 10, and the mixing of the photocatalytic material and the adsorption material can facilitate the decomposition of pollutants adsorbed by the adsorption material by the photocatalytic material, so as to improve the purification effect of the photocatalytic material on the adsorption material.
In some embodiments, the photocatalytic material may also be layered with the adsorbent material, i.e., the photocatalytic material forms a layer of photocatalytic material, the adsorbent material forms a layer of adsorbent material, and the layer of photocatalytic material and the layer of adsorbent material are stacked together to form the purification composition 10.
In one embodiment, referring to fig. 1, the purification apparatus further includes a composition carrier 30, and the purification composition 10 is disposed on the composition carrier 30, that is, the composition carrier 30 can be used to carry the purification composition 10 regardless of whether the photocatalytic material and the adsorbent material are disposed in a mixed manner or in a layered manner.
The material of the composition carrier 30 is not limited, and the material of the composition carrier 30 may be, for example, an organic polymer material, a metal material, an inorganic nonmetal material, or the like.
The composition carrier 30 is not limited in structural form as long as it can carry the purification composition 10, and illustratively, the composition carrier 30 may be a porous carrier through which a gas flow can pass, and the photocatalytic material is mixed with and dispersed on the adsorbent material.
The porous carrier is a carrier having a certain porosity and a certain surface area, for example, the porous carrier may be an aluminum honeycomb, the photocatalytic material may be dispersed on the porous carrier after being mixed with the adsorption material, and when the airflow containing the pollutants passes through the porous carrier, the pollutants can be sufficiently contacted with the purification composition 10 dispersed on the porous carrier, thereby sufficiently decomposing the pollutants, and further improving the purification effect.
In some embodiments, the composition support 30 may also be a gas permeable support through which the gas stream may pass, with the photocatalytic material being mixed with and dispersed on the adsorbent material.
Further, in order to enable the photocatalytic material and the adsorbing material to be better dispersed and/or fixed on the composition carrier 30, in some scenarios, auxiliary materials such as an adhesive, a dispersing agent, a stabilizing agent, and the like may be further added as needed.
In some embodiments, the purification device may not have a composition carrier 30 disposed thereon, for example, the photocatalytic material and the adsorbent material may together form a solid structure whether they are disposed in a mixed or layered arrangement.
In addition, the solid structure may be provided with gas flow passages so that a gas flow containing contaminants may pass through the solid structure.
In a specific embodiment, the light guide assembly 20 is composed of a first light guide panel 22, a second light guide panel 23 and an optical fiber bundle 21, wherein the first light guide panel 22 and the second light guide panel 23 are made of polymethyl methacrylate (PMMA), the optical fiber bundle 21 can be composed of 300 light guide filaments with a diameter of 0.5mm to 1mm, and the adsorbing material is 80-325 mesh and has a large surface areaAt 1200m2Per g of activated carbon and having a pore size of
Figure BDA0003357205450000092
The catalytic material is g-C3N4And Bi2WO6The auxiliary material is a non-polar adhesive. The adsorbing material, the catalyzing material and the auxiliary material are uniformly mixed and then fixed on the composition carrier 30, wherein the composition carrier 30 can be a hexagonal aluminum honeycomb with the side length of 1.3mm, and the thickness is determined according to the air loss.
According to GB 18801 experimental method, the thickness of the material is 30m3The cleaning effect test is carried out in the test chamber, and the size of the test component is 500 multiplied by 300 multiplied by 30 mm.
The test results were as follows:
1. VOCs removal performance
Species of VOCs Time Rate of sterilization
Formaldehyde (I) 30min >99%
Toluene 60min >97%
2. Antibacterial property
Figure BDA0003357205450000091
Figure BDA0003357205450000101
The various embodiments/implementations provided herein may be combined with each other without contradiction.
The above description is only a preferred embodiment of the present application and is not intended to limit the present application, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, improvement and the like made within the spirit and principle of the present application are included in the protection scope of the present application.

Claims (16)

1. A purification apparatus, comprising:
a purification composition comprising a photocatalytic material and an adsorbent material;
the light guide assembly is used for guiding light generated by the light source to the photocatalytic material, so that the photocatalytic material can purify pollutants in the environment and pollutants adsorbed by the adsorption material.
2. The purification apparatus as claimed in claim 1, wherein the light incident side of the light guide member is located within the range of the visible light source.
3. The purification apparatus of claim 1 or 2, wherein the purification composition is permeable to a gas stream.
4. The purification apparatus of claim 1 or 2, wherein the light guide assembly comprises a fiber bundle, and the light exit side of the fiber bundle faces the photocatalytic material.
5. The purification apparatus of claim 4, wherein the light guide assembly further comprises a first light guide panel, the first light guide panel being plugged into the light exit side of the fiber bundle; and/or the presence of a gas in the gas,
the light guide assembly further comprises a second light guide panel, and the second light guide panel is inserted into the light inlet side of the optical fiber bundle.
6. The purification apparatus of claim 5, wherein the second light guide panel is a light panel lamp.
7. The purification apparatus of claim 1 or 2, wherein the light guide assembly is a module that achieves light transmission by reflection or transmission.
8. Purification device according to claim 1 or 2, wherein the photocatalytic material comprises ZnO, TiO2、CdS、ZnS、Bi2S3、g-C3N4、BiOX(X=Cl,Br,I)、BixWOyOne or more of; and/or the presence of a gas in the gas,
the photocatalytic material comprises ZnO and TiO2、CdS、ZnS、Bi2S3、g-C3N4、BiOX(X=Cl,Br,I)、BixWOyModified doped derivatives of at least one of (1).
9. The purification apparatus of claim 1 or 2, wherein the adsorbent material comprises one or more of a porous carbon material, a molecular sieve, a modified molecular sieve, a silica gel, a modified silica gel, a metal organic framework.
10. The purification apparatus of claim 9, wherein the porous carbon material comprises one or more of activated carbon, graphite, graphene, carbon aerogel, synthetic carbon.
11. The purification apparatus of claim 1 or 2, wherein the photocatalytic material is mixed with or layered with the adsorbent material.
12. The purification apparatus of claim 11, wherein the photocatalytic material and the adsorbent material together form a solid structure.
13. The purification apparatus of claim 1 or 2, further comprising a composition carrier on which the purification composition is disposed.
14. The purification apparatus of claim 13, wherein the composition carrier is a porous carrier or an air-permeable carrier through which the gas stream can pass, and the photocatalytic material is mixed with the adsorbent material and dispersed on the porous carrier or the air-permeable carrier.
15. The purification apparatus according to claim 13, wherein the composition carrier is made of any one of an organic polymer material, a metal material, and an inorganic nonmetal; and/or the presence of a gas in the gas,
the purification device further comprises an auxiliary material for dispersing and/or immobilizing the purification composition on the composition carrier.
16. An air conditioner characterized by comprising the purification apparatus of any one of claims 1 to 15.
CN202111355979.0A 2021-11-16 2021-11-16 Purification device and air conditioner Pending CN114183874A (en)

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CN116178740A (en) * 2023-02-21 2023-05-30 Tcl空调器(中山)有限公司 Air conditioner, zn-MOFs material and preparation method and application thereof
CN118879138A (en) * 2024-08-06 2024-11-01 盘锦天泉海实业有限公司 Aerogel interior wall paint with purification function

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