CN115188665A - Semiconductor structure and forming method thereof - Google Patents
Semiconductor structure and forming method thereof Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及半导体制造技术领域,尤其涉及一种半导体结构及其形成方法。The present invention relates to the technical field of semiconductor manufacturing, and in particular, to a semiconductor structure and a method for forming the same.
背景技术Background technique
硅基光电集成将微电子技术和光子学技术进行融合,是微电子技术的集成和发展,是信息技术发展的重要前沿研究领域。其研究内容包括硅基高效光源、硅基高速光电探测器、硅基高速光调制器、低损耗光波导器件等。硅衬底上外延生长锗材料是硅基高速长波长光电探测器的首选材料。Silicon-based optoelectronic integration integrates microelectronics technology and photonics technology. It is the integration and development of microelectronics technology and an important frontier research field in the development of information technology. His research contents include silicon-based high-efficiency light sources, silicon-based high-speed photodetectors, silicon-based high-speed optical modulators, and low-loss optical waveguide devices. The epitaxial growth of germanium on silicon substrate is the preferred material for silicon-based high-speed long-wavelength photodetectors.
目前,在硅衬底上生长锗材料的主要工艺包括硅图形衬底上生长锗的工艺等。硅图形衬底上生长锗的方法包括:在硅衬底上制备氧化硅薄膜,然后光刻刻蚀氧化硅露出生长锗的窗口,锗将选择性地在窗口暴露出的硅的位置生长,并横向过生长而在氧化硅表面合并,形成完整的锗外延层。At present, the main processes for growing germanium materials on silicon substrates include processes for growing germanium on silicon patterned substrates. The method for growing germanium on a silicon pattern substrate comprises: preparing a silicon oxide film on the silicon substrate, then photolithographically etching the silicon oxide to expose a window for growing germanium, and germanium will selectively grow at the position of the silicon exposed by the window, and Lateral overgrowth merges on the silicon oxide surface to form a complete germanium epitaxial layer.
然而,现有硅图形衬底上生长锗的工艺有待进一步改善。However, the process of growing germanium on the existing silicon pattern substrate needs to be further improved.
发明内容SUMMARY OF THE INVENTION
本发明解决的技术问题是提供一种半导体结构及其形成方法,以提高形成的半导体结构的性能。The technical problem solved by the present invention is to provide a semiconductor structure and a method for forming the same, so as to improve the performance of the formed semiconductor structure.
为解决上述技术问题,本发明技术方案提供一种半导体结构,包括:衬底;位于所述衬底表面的介质层;位于所述介质层和所述衬底内的外延层,所述外延层包括第一区、与所述第一区相邻且位于所述第一区上的第二区,以及与所述第二区相邻且位于所述第二区上的第三区,所述第一区位于所述衬底内,所述第二区和所述第三区位于所述介质层内,所述第二区侧壁相对于所述第三区侧壁凸出,所述第二区侧壁齐平于或凸出于所述第一区侧壁。In order to solve the above technical problems, the technical solution of the present invention provides a semiconductor structure, comprising: a substrate; a dielectric layer located on the surface of the substrate; an epitaxial layer located in the dielectric layer and the substrate, the epitaxial layer comprising a first area, a second area adjacent to and on the first area, and a third area adjacent to and on the second area, the The first region is located in the substrate, the second region and the third region are located in the dielectric layer, the sidewall of the second region is protruded from the sidewall of the third region, the first region The sidewalls of the second region are flush with or protrude from the sidewalls of the first region.
可选的,所述外延层的材料包括锗。Optionally, the material of the epitaxial layer includes germanium.
可选的,所述介质层的材料包括氧化硅。Optionally, the material of the dielectric layer includes silicon oxide.
本发明技术方案还提供一种半导体结构的形成方法,包括:提供衬底;在所述衬底表面形成介质层;形成位于所述介质层内的第一开口、位于介质层内的第二开口、以及位于衬底内的初始第三开口,所述第二开口位于第一开口底部且与第一开口连通,所述第二开口侧壁相对于第一开口侧壁凹陷,所述第二开口侧壁相对于初始第三开口侧壁凹陷,且所述第二开口底部暴露出所述衬底部分顶部表面;对所述初始第三开口内壁和所述第二开口底部暴露出的衬底顶部表面进行刻蚀,在所述衬底内形成第三开口;在所述第三开口、所述第二开口和所述第一开口内形成外延层。The technical solution of the present invention also provides a method for forming a semiconductor structure, including: providing a substrate; forming a dielectric layer on the surface of the substrate; forming a first opening in the dielectric layer and a second opening in the dielectric layer , and an initial third opening located in the substrate, the second opening is located at the bottom of the first opening and communicates with the first opening, the sidewall of the second opening is recessed relative to the sidewall of the first opening, and the second opening The sidewall is recessed relative to the sidewall of the initial third opening, and the bottom of the second opening exposes the top surface of the substrate portion; the substrate top exposed to the inner wall of the initial third opening and the bottom of the second opening The surface is etched to form a third opening in the substrate; an epitaxial layer is formed in the third opening, the second opening and the first opening.
可选的,在形成所述介质层前,在所述衬底部分表面形成牺牲层,所述介质层位于所述牺牲层侧壁和顶部表面。Optionally, before forming the dielectric layer, a sacrificial layer is formed on a surface of a part of the substrate, and the dielectric layer is located on the sidewalls and the top surface of the sacrificial layer.
可选的,所述第一开口、所述第二开口和所述初始第三开口的形成方法包括:在所述介质层部分表面形成掩膜层;以所述掩膜层为掩膜刻蚀所述介质层,直到暴露出部分所述牺牲层,形成所述第一开口;以所述掩膜层为掩膜刻蚀所述第一开口暴露出的所述牺牲层和所述衬底,在所述衬底内形成所述初始第三开口,在所述介质层内形成初始第二开口,所述初始第二开口侧壁暴露出所述牺牲层;形成所述初始第三开口后,去除剩余的所述牺牲层,形成所述第二开口。Optionally, the method for forming the first opening, the second opening and the initial third opening includes: forming a mask layer on a partial surface of the dielectric layer; etching using the mask layer as a mask the dielectric layer until part of the sacrificial layer is exposed to form the first opening; the sacrificial layer and the substrate exposed by the first opening are etched using the mask layer as a mask, The initial third opening is formed in the substrate, the initial second opening is formed in the dielectric layer, and the sidewall of the initial second opening exposes the sacrificial layer; after the initial third opening is formed, The remaining sacrificial layer is removed to form the second opening.
可选的,所述第一开口的形成工艺包括干法刻蚀工艺和湿法刻蚀工艺中的一者或两者的结合;所述初始第三开口和所述初始第二开口的形成工艺包括干法刻蚀工艺和湿法刻蚀工艺中的一者或两者的结合。Optionally, the formation process of the first opening includes one or a combination of a dry etching process and a wet etching process; the formation process of the initial third opening and the initial second opening It includes one or a combination of a dry etching process and a wet etching process.
可选的,去除剩余的所述牺牲层的工艺为各项同性的刻蚀工艺。Optionally, the process of removing the remaining sacrificial layer is an isotropic etching process.
可选的,所述牺牲层的材料与所述介质层的材料不同;所述牺牲层的材料与所述衬底的材料不同。Optionally, the material of the sacrificial layer is different from the material of the dielectric layer; the material of the sacrificial layer is different from the material of the substrate.
可选的,所述第一开口、所述第二开口和所述初始第三开口的形成方法包括:刻蚀所述介质层,直到暴露出部分所述牺牲层,在所述介质层内形成第一开口;形成所述第一开口后,去除所述牺牲层,形成所述第二开口;形成所述第二开口后,刻蚀所述第一开口底部暴露出的所述衬底,以形成所述初始第三开口。Optionally, the method for forming the first opening, the second opening and the initial third opening includes: etching the dielectric layer until part of the sacrificial layer is exposed, and forming in the dielectric layer a first opening; after the first opening is formed, the sacrificial layer is removed to form the second opening; after the second opening is formed, the substrate exposed at the bottom of the first opening is etched to The initial third opening is formed.
可选的,所述第一开口的形成工艺包括干法刻蚀工艺和湿法刻蚀工艺中的一者或两者的结合。Optionally, the formation process of the first opening includes one or a combination of a dry etching process and a wet etching process.
可选的,去除所述牺牲层的工艺为各项同性刻蚀工艺。Optionally, the process of removing the sacrificial layer is an isotropic etching process.
可选的,位于所述衬底和所述介质层之间还有保护层。Optionally, a protective layer is located between the substrate and the dielectric layer.
可选的,所述保护层的材料包括氧化硅;所述牺牲层的材料包括多晶硅。Optionally, the material of the protective layer includes silicon oxide; the material of the sacrificial layer includes polysilicon.
可选的,所述保护层、所述牺牲层的形成方法包括:在所述衬底上形成栅氧材料层;在所述栅氧材料层上形成伪栅极材料层;在所述伪栅极材料层上形成图形化层;以所述图形化层为掩膜,刻蚀所述伪栅极材料层和所述栅氧材料层,形成所述牺牲层和所述保护层。Optionally, the method for forming the protective layer and the sacrificial layer includes: forming a gate oxide material layer on the substrate; forming a dummy gate material layer on the gate oxide material layer; forming a dummy gate material layer on the dummy gate A patterned layer is formed on the electrode material layer; using the patterned layer as a mask, the dummy gate material layer and the gate oxide material layer are etched to form the sacrificial layer and the protection layer.
可选的,形成所述牺牲层和所述保护层的同时,所述栅氧材料层还被刻蚀形成栅氧层,所述伪栅极材料层还被刻蚀形成伪栅极,用于在其他区域形成MOS器件。Optionally, while forming the sacrificial layer and the protective layer, the gate oxide material layer is also etched to form a gate oxide layer, and the dummy gate material layer is also etched to form a dummy gate for MOS devices are formed in other regions.
可选的,对所述初始第三开口内壁和所述第二开口底部暴露出的衬底顶部表面进行刻蚀的工艺包括干法刻蚀工艺和湿法刻蚀工艺中的一者或两者的结合。Optionally, the process of etching the inner wall of the initial third opening and the top surface of the substrate exposed at the bottom of the second opening includes one or both of a dry etching process and a wet etching process. combination.
可选的,对所述初始第三开口内壁和所述第二开口底部暴露出的衬底顶部表面进行刻蚀的工艺为干法刻蚀工艺,所述干法刻蚀工艺采用的刻蚀气体包括氯化氢。Optionally, the process of etching the inner wall of the initial third opening and the top surface of the substrate exposed at the bottom of the second opening is a dry etching process, and the dry etching process adopts an etching gas. Including hydrogen chloride.
与现有技术相比,本发明实施例的技术方案具有以下有益效果:Compared with the prior art, the technical solutions of the embodiments of the present invention have the following beneficial effects:
本发明技术方案提供的半导体结构的形成方法中,对所述初始第三开口内壁和所述第二开口底部暴露出的衬底顶部表面进行刻蚀,在所述衬底内形成第三开口。在所述刻蚀工艺中,由于所述第二开口使所述初始第三开口侧壁相邻的所述衬底的顶部表面也暴露在刻蚀液或刻蚀气体中,使所述初始第三开口侧壁暴露出的衬底被刻蚀的同时,也对所述第二开口底部暴露出的衬底顶部表面进行刻蚀,从而避免了仅对所述初始第三开口侧壁的衬底刻蚀而造成的“咬边”缺陷,进而提高所形成的器件的性能。In the method for forming a semiconductor structure provided by the technical solution of the present invention, the inner wall of the initial third opening and the top surface of the substrate exposed from the bottom of the second opening are etched, and a third opening is formed in the substrate. In the etching process, because the second opening exposes the top surface of the substrate adjacent to the sidewall of the initial third opening to an etching solution or an etching gas, the initial third opening is also exposed to the etching solution or gas. When the substrate exposed by the sidewalls of the three openings is etched, the top surface of the substrate exposed at the bottom of the second opening is also etched, so as to avoid only the substrate with the sidewalls of the initial third opening being etched The "undercut" defect caused by etching, thereby improving the performance of the formed device.
附图说明Description of drawings
图1至图3是一种半导体结构形成过程的剖面示意图;1 to 3 are schematic cross-sectional views of a semiconductor structure formation process;
图4至图9是本发明一实施例中的半导体结构的形成方法各步骤的结构示意图;4 to 9 are schematic structural diagrams of each step of a method for forming a semiconductor structure according to an embodiment of the present invention;
图10至图15是本发明另一实施例中的半导体结构的形成方法各步骤的结构示意图。10 to 15 are schematic structural diagrams of each step of a method for forming a semiconductor structure in another embodiment of the present invention.
具体实施方式Detailed ways
需要注意的是,本说明书中的“表面”、“上”,用于描述空间的相对位置关系,并不限定于是否直接接触。It should be noted that "surface" and "upper" in this specification are used to describe the relative positional relationship in space, and are not limited to whether they are in direct contact.
如背景技术所述,采用现有的硅图形衬底上生长锗工艺形成的半导体结构,性能亟需提升。现结合一种半导体结构的形成过程进行说明分析。As described in the background art, the performance of a semiconductor structure formed by using an existing process of growing germanium on a silicon pattern substrate needs to be improved. The description and analysis are now combined with the formation process of a semiconductor structure.
图1至图3是一种半导体结构形成过程的剖面示意图。1 to 3 are schematic cross-sectional views of a process of forming a semiconductor structure.
请参考图1,提供衬底100;在所述衬底100上形成氧化层101。Referring to FIG. 1 , a substrate 100 is provided; an
请参考图2,刻蚀所述氧化层101和所述衬底100,形成位于所述氧化层101和所述衬底100内的开口103;去除所述衬底100位于开口103底部表面的表面损伤层。Referring to FIG. 2, the
请参考图3,去除所述损伤层后,在所述开口103内形成锗材料层104。Referring to FIG. 3 , after removing the damaged layer, a
上述方法中,所述衬底100的材料为硅,锗材料层104在所述衬底100位于所述开口103底部的表面外延生长。为锗在硅表面的外延生长做准备,需要去除所述衬底100位于所述开口103底部表面的表面损伤层,通常采用HCl气相腐蚀抛光工艺,利于高温下HCl气体与硅反应的方式,将损伤层去除。在所述工艺过程中,由于所述开口103的侧壁暴露在刻蚀气体中,会对所述开口103位于所述衬底100内的侧壁造成横向刻蚀,形成位于所述开口103侧壁的“咬边”(undercut)缺陷A(如图3所示)。所述缺陷A会影响形成的锗光电探测器的性能,所述缺陷A的大小以及深度与器件的暗电流呈正相关关系。为了消除“咬边”(undercut)缺陷的影响。In the above method, the material of the substrate 100 is silicon, and the
在一种解决上述问题的实施例中,在HCl气相腐蚀抛光工艺中,引入二氯硅烷(DCS)前驱气体,去除损伤层的同时,在所述开口103表面沉积晶体硅,使硅在所述开口103暴露出的硅100衬底表面外延生长,从而对所述开口103暴露出的衬底100表面进行修复,减少“咬边”(undercut)缺陷A的尺寸。然而,引入所述前驱气体的方法不能完全消除“咬边”(undercut)缺陷A,且所述外延生长的工艺对温度的要求严格,温度过高会影响衬底100表面对晶体硅生长的选择性,温度太低会影响晶体硅的质量。In an embodiment to solve the above problem, in the HCl vapor phase etching and polishing process, dichlorosilane (DCS) precursor gas is introduced to remove the damaged layer, and at the same time, crystalline silicon is deposited on the surface of the
为了解决上述问题,本发明提供的一种半导体结构的形成方法中,对所述初始第三开口内壁和所述第二开口底部暴露出的衬底顶部表面进行刻蚀,在所述衬底内形成第三开口。在所述刻蚀工艺中,由于所述第二开口使所述初始第三开口侧壁相邻的所述衬底的顶部表面也暴露在刻蚀液或刻蚀气体中,使所述初始第三开口侧壁暴露出的衬底被刻蚀的同时,也对所述第二开口底部暴露出的衬底顶部表面进行刻蚀,从而避免了仅对所述初始第三开口侧壁的衬底刻蚀而造成的“咬边”缺陷,进而提高所形成的器件的性能。In order to solve the above problem, in a method for forming a semiconductor structure provided by the present invention, the inner wall of the initial third opening and the top surface of the substrate exposed from the bottom of the second opening are etched, and the inner wall of the initial third opening and the top surface of the substrate exposed from the bottom of the second opening are etched, A third opening is formed. In the etching process, because the second opening exposes the top surface of the substrate adjacent to the sidewall of the initial third opening to an etching solution or an etching gas, the initial third opening is also exposed to the etching solution or gas. When the substrate exposed by the sidewalls of the three openings is etched, the top surface of the substrate exposed at the bottom of the second opening is also etched, so as to avoid only the substrate with the sidewalls of the initial third opening being etched The "undercut" defect caused by etching, thereby improving the performance of the formed device.
为使本发明的上述目的、特征和有益效果能够更为明显易懂,下面结合附图对本发明的具体实施例做详细的说明。In order to make the above objects, features and beneficial effects of the present invention more clearly understood, specific embodiments of the present invention will be described in detail below with reference to the accompanying drawings.
图4至图7是本发明一实施例中的半导体结构的形成方法各步骤的结构示意图。4 to 7 are schematic structural diagrams of each step of a method for forming a semiconductor structure according to an embodiment of the present invention.
请参考图4,提供衬底200;在所述衬底200表面形成介质层201。Referring to FIG. 4 , a
所述衬底200的材料包括硅。The material of the
所述介质层201的材料包括氧化硅。The material of the
本实施例中,位于所述衬底200和所述介质层201之间还有保护层203。In this embodiment, a
所述保护层203的材料包括氧化硅。The material of the
本实施例中,在形成所述介质层201前,在所述衬底200部分表面形成牺牲层202,所述介质层201位于所述牺牲层202侧壁和顶部表面。In this embodiment, before forming the
所述牺牲层202的材料包括多晶硅。The material of the
所述牺牲层202用于为后续形成第二开口占据空间,故所述牺牲层202的材料可以为其他与所述介质层201不同的材料,并在形成所述第二开口的刻蚀工艺中,所述牺牲层202相对于所述介质层201具有较大的刻蚀选择比,减少所述刻蚀工艺对所述介质层201的刻蚀损伤。本实施例中,所述牺牲层202的材料为多晶硅。The
所述保护层203、所述牺牲层202的形成方法包括:在所述衬底200上形成栅氧材料层(图中未标出);在所述栅氧材料层上形成伪栅极材料层(图中未标出);在所述伪栅极材料层上形成图形化层(图中未标出);以所述图形化层为掩膜,刻蚀所述伪栅极材料层和所述栅氧材料层,形成所述牺牲层202和所述保护层203。The method for forming the
另一实施例中,形成所述牺牲层202和所述保护层203的同时,所述栅氧材料层还被刻蚀形成栅氧层(图中未标出),所述伪栅极材料层还被刻蚀形成伪栅极(图中未标出),用于在其他区域形成MOS器件。所述牺牲层202和所述伪栅极同时形成,所述保护层203和所述栅氧层同时形成,节约了工序,降低生产成本。In another embodiment, when the
后续,形成位于所述介质层内的第一开口、位于介质层内的第二开口、以及位于衬底内的初始第三开口,所述第二开口位于第一开口底部且与第一开口连通,所述第二开口侧壁相对于第一开口侧壁凹陷,所述第二开口侧壁相对于初始第三开口侧壁凹陷,且所述第二开口底部暴露出所述衬底部分顶部表面。Subsequently, a first opening in the dielectric layer, a second opening in the dielectric layer, and an initial third opening in the substrate are formed, and the second opening is located at the bottom of the first opening and communicated with the first opening , the sidewall of the second opening is recessed relative to the sidewall of the first opening, the sidewall of the second opening is recessed relative to the sidewall of the initial third opening, and the bottom of the second opening exposes the top surface of the substrate portion .
本实施例中,所述第一开口、所述第二开口和所述初始第三开口的形成方法,请参考图5至图7。其他实施例中,所述第一开口、所述第二开口和所述初始第三开口的形成方法包括:在所述介质层部分表面形成掩膜层;以所述掩膜层为掩膜刻蚀所述介质层,直到暴露出部分所述牺牲层,形成所述第一开口;以所述掩膜层为掩膜刻蚀所述第一开口暴露出的所述牺牲层和所述衬底,在所述衬底内形成所述初始第三开口,在所述介质层内形成初始第二开口,所述初始第二开口侧壁暴露出所述牺牲层;形成所述初始第三开口后,去除剩余的所述牺牲层,形成所述第二开口。In this embodiment, for the formation method of the first opening, the second opening and the initial third opening, please refer to FIG. 5 to FIG. 7 . In other embodiments, the method for forming the first opening, the second opening and the initial third opening includes: forming a mask layer on a partial surface of the dielectric layer; using the mask layer as a mask to etch etching the dielectric layer until part of the sacrificial layer is exposed to form the first opening; etching the sacrificial layer and the substrate exposed by the first opening using the mask layer as a mask , the initial third opening is formed in the substrate, the initial second opening is formed in the dielectric layer, and the sidewall of the initial second opening exposes the sacrificial layer; after the initial third opening is formed , removing the remaining sacrificial layer to form the second opening.
请参考图5,刻蚀所述介质层201,直到暴露出部分所述牺牲层202,在所述介质层201内形成第一开口205。Referring to FIG. 5 , the
本实施例中,所述第一开口205的形成方法还包括:在所述介质层201部分表面形成掩膜层204;以所述掩膜层204为掩膜刻蚀所述介质层201,直到暴露出部分所述牺牲层202,形成所述第一开口205。In this embodiment, the method for forming the
所述掩膜层204的材料为光刻胶。The material of the
请参考图6,形成所述第一开口205后,去除所述牺牲层202,形成所述第二开口206。Referring to FIG. 6 , after the
去除所述牺牲层202的工艺为各项同性刻蚀工艺。The process of removing the
去除所述牺牲层202的工艺包括干法刻蚀工艺和湿法刻蚀工艺中的一者或两者的结合。去除所述牺牲层202的工艺对所述牺牲层202相对所述介质层201具有较大的刻蚀选择比,利于去除所述牺牲层202的过程中,保护所述介质层201不受刻蚀损伤。The process of removing the
本实施例中,去除所述牺牲层202的工艺为湿法刻蚀工艺。所述湿法刻蚀工艺采用氢氧化钾溶液,由于氢氧化钾溶液对多晶硅材料和氧化硅材料具有较大的选择比,利于去除所述牺牲层202的过程中,使所述介质层201和所述保护层203不受刻蚀损伤,所述保护层203进一步保护所述衬底200不受刻蚀损伤。In this embodiment, the process of removing the
请参考图7,形成所述第二开口206后,刻蚀所述第一开口205底部暴露出的所述衬底200,以形成所述初始第三开口207。Referring to FIG. 7 , after the
请参考图8,对所述初始第三开口207(如图7所示)内壁和所述第二开口206底部暴露出的衬底200顶部表面进行刻蚀,在所述衬底200内形成第三开口208。Referring to FIG. 8 , the inner wall of the initial third opening 207 (as shown in FIG. 7 ) and the top surface of the
对所述初始第三开口207内壁和所述第二开口206底部暴露出的衬底200顶部表面进行刻蚀的工艺包括干法刻蚀工艺和湿法刻蚀工艺中的一者或两者的结合。The process of etching the inner wall of the initial
所述刻蚀工艺用于去除所述初始第三开口207内壁暴露出的所述衬底200的表面损伤层,为后续在第三开口内形成外延层做准备。同时,在所述刻蚀工艺中,由于所述第二开口206使所述初始第三开口207侧壁相邻的所述衬底200的顶部表面也暴露在刻蚀液或刻蚀气体中,使所述初始第三开口207侧壁暴露出的衬底被刻蚀的同时,也对所述第二开口206底部暴露出的衬底顶部表面进行刻蚀,从而避免了仅对所述初始第三开口207侧壁的衬底刻蚀而造成的“咬边”缺陷,进而提高所形成的器件的性能。本实施例中,对所述第二开口206底部暴露出的衬底顶部表面进行刻蚀的同时,还对所述保护层203进行刻蚀。The etching process is used to remove the surface damage layer of the
本实施例中,形成的第三开口208侧壁齐平于所述第二开口206侧壁。其他实施例中,所述第二开口206侧壁相对于所述第三开口208侧壁凹陷,所述第三开口208的形貌由刻蚀情况决定。In this embodiment, the sidewalls of the formed
本实施例中,对所述初始第三开口207内壁和所述第二开口206底部暴露出的衬底200顶部表面进行刻蚀的工艺为干法刻蚀工艺,所述干法刻蚀工艺采用的刻蚀气体包括氯化氢。In this embodiment, the process of etching the inner wall of the initial
后续,在所述第三开口208、所述第二开口206和所述第一开口205内形成外延层。Subsequently, an epitaxial layer is formed in the
本实施例中,形成所述外延层之前,还去除所述掩膜层204。In this embodiment, before forming the epitaxial layer, the
请参考图9,在所述第三开口208、所述第二开口206和所述第一开口205内形成外延层209。Referring to FIG. 9 , an
所述外延层209的材料包括锗。The material of the
所述第三开口208暴露出的所述衬底200用于作为籽晶,采用外延生长技术生成所述外延层209。The
所述外延层209包括位于所述第三开口208内的第一区(图中未显示)、位于所述第二开口206内的第二区(图中未显示)和位于所述第一开口205内的第三区(图中未显示)。所述外延层209的形貌由所述第一开口205、所述第二开口206和所述第三开口208形貌决定。The
相应的,本发明实施例还提供一种半导体结构,请继续参考图9,包括:衬底200;位于所述衬底200表面的介质层201;位于所述介质层201和所述衬底200内的外延层209,所述外延层209包括第一区(图中未标出)、与所述第一区相邻且位于所述第一区上的第二区(图中未标出),以及与所述第二区相邻且位于所述第二区上的第三区(图中未标出),所述第一区位于所述衬底200内,所述第二区和所述第三区位于所述介质层201内,所述第二区侧壁相对于所述第三区侧壁凸出,所述第二区侧壁齐平于或凸出于所述第一区侧壁。Correspondingly, an embodiment of the present invention further provides a semiconductor structure, please continue to refer to FIG. 9 , including: a
所述外延层209的材料包括锗。The material of the
所述介质层201的材料包括氧化硅。The material of the
本实施例中,位于所述衬底200和所述介质层201之间还有保护层203。In this embodiment, a
图10至图15是本发明另一实施例中的半导体结构的形成方法各步骤的结构示意图。10 to 15 are schematic structural diagrams of each step of a method for forming a semiconductor structure in another embodiment of the present invention.
本实施例中,所述第一开口、所述第二开口和所述初始第三开口的形成方法,请参考图10至图13。In this embodiment, for the formation methods of the first opening, the second opening and the initial third opening, please refer to FIG. 10 to FIG. 13 .
请参考图10,提供衬底300;在所述衬底300表面形成介质层301。Referring to FIG. 10 , a
所述衬底300的材料包括硅。The material of the
所述介质层301的材料包括氧化硅。The material of the
本实施例中,在形成所述介质层301前,在所述衬底300部分表面形成牺牲层302,所述介质层301位于所述牺牲层302侧壁和顶部表面。其他实施例中,在形成所述牺牲层302前,还在所述介质层301表面形成保护层。In this embodiment, before forming the
所述牺牲层302的材料与所述介质层301的材料不同;所述牺牲层302的材料与所述衬底300的材料不同。本实施例中,所述牺牲层302的材料为氮化硅。The material of the
所述牺牲层302用于为后续形成第二开口占据空间。在形成所述第二开口的过程中,可选择对所述牺牲层302和所述介质层301具有较大的选择比的刻蚀工艺,用于减少刻蚀过程对所述介质层301产生的损伤。在形成所述第二开口的过程中,可选择对所述牺牲层302和所述衬底300具有较大的选择比的刻蚀工艺,用于减少刻蚀过程对所述衬底300产生的损伤。The
所述牺牲层302的形成方法包括:在所述衬底200上形成牺牲材料层(图中未标出);在所述牺牲材料层上形成图形化层(图中未标出);以所述图形化层为掩膜,刻蚀所述牺牲材料层,形成所述牺牲层302。The method for forming the
请参考图11,在所述介质层301部分表面形成掩膜层303;以所述掩膜层303为掩膜刻蚀所述介质层301,直到暴露出部分所述牺牲层302,形成所述第一开口304。Referring to FIG. 11, a
所述掩膜层303的材料包括光刻胶。The material of the
所述第一开口304的形成工艺包括干法刻蚀工艺和湿法刻蚀工艺中的一者或两者的结合。本实施例中,所述第一开口304的形成工艺为干法刻蚀工艺,所述干法刻蚀工艺有利于形成较好形貌的开口。The formation process of the
请参考图12,以所述掩膜层303为掩膜刻蚀所述第一开口304暴露出的所述牺牲层302和所述衬底300,在所述衬底300内形成所述初始第三开口306,在所述介质层301内形成初始第二开口305,所述初始第二开口305侧壁暴露出所述牺牲层302。Referring to FIG. 12 , the
所述初始第三开口306和所述初始第二开口305的形成工艺包括干法刻蚀工艺和湿法刻蚀工艺中的一者或两者的结合。本实施例中,所述初始第三开口和所述初始第二开口305的形成工艺为干法刻蚀工艺,所述干法刻蚀工艺有利于形成较好形貌的开口,且所述初始第三开口306和所述初始第二开口305在同一工艺中形成,节省了工艺工序,有利于降低生产成本。The formation process of the initial
请参考图13,形成所述初始第三开口306后,去除剩余的所述牺牲层302,形成所述第二开口307。Referring to FIG. 13 , after the initial
去除剩余的所述牺牲层302的工艺为各项同性的刻蚀工艺。The process of removing the remaining
去除所述牺牲层302的工艺包括干法刻蚀工艺和湿法刻蚀工艺中的一者或两者的结合。去除所述牺牲层302的工艺对所述牺牲层302相对所述介质层301具有较大的刻蚀选择比,利于去除所述牺牲层302的过程中,保护所述介质层301不受刻蚀损伤。The process of removing the
本实施例中,去除所述牺牲层302的工艺为湿法刻蚀工艺。所述湿法刻蚀工艺采用磷酸溶液,由于磷酸溶液对氮化硅材料和氧化硅材料具有较大的选择比,利于去除所述牺牲层302的过程中,使所述介质层301不受刻蚀损伤;同时,由于磷酸溶液对氧化硅材料和硅材料具有较大的选择比,利于在去除所述牺牲层302的过程中,保护所述衬底300不受刻蚀损伤。In this embodiment, the process of removing the
请参考图14,对所述初始第三开口306(如图13所示)内壁和所述第二开口307(如图13所示)底部暴露出的衬底300顶部表面进行刻蚀,在所述衬底300内形成第三开口308。Referring to FIG. 14 , etching is performed on the inner wall of the initial third opening 306 (as shown in FIG. 13 ) and the top surface of the
对所述初始第三开口207内壁和所述第二开口206底部暴露出的衬底200顶部表面进行刻蚀的工艺包括干法刻蚀工艺和湿法刻蚀工艺中的一者或两者的结合。The process of etching the inner wall of the initial
所述刻蚀工艺用于去除所述初始第三开口207内壁暴露出的所述衬底200的表面损伤层,为后续在第三开口内形成外延层做准备。同时,在所述刻蚀工艺中,由于所述第二开口206使所述初始第三开口207侧壁相邻的所述衬底200的顶部表面也暴露在刻蚀液或刻蚀气体中,使所述初始第三开口207侧壁暴露出的衬底被刻蚀的同时,也对所述第二开口206底部暴露出的衬底顶部表面进行刻蚀,从而避免了仅对所述初始第三开口207侧壁的衬底刻蚀而造成的“咬边”缺陷,进而提高所形成的器件的性能。The etching process is used to remove the surface damage layer of the
本实施例中,对所述初始第三开口207内壁和所述第二开口206底部暴露出的衬底200顶部表面进行刻蚀的工艺为干法刻蚀工艺,所述干法刻蚀工艺采用的刻蚀气体包括氯化氢。In this embodiment, the process of etching the inner wall of the initial
后续,在所述第三开口308、所述第二开口307和所述第一开口304内形成外延层。Subsequently, an epitaxial layer is formed in the
本实施例中,形成所述外延层之前,还去除所述掩膜层204。In this embodiment, before forming the epitaxial layer, the
请参考图15,在所述第三开口308、所述第二开口307和所述第一开口304内形成外延层309。Referring to FIG. 15 , an
所述外延层309的材料包括锗。所述第三开口308暴露出的所述衬底200用于作为籽晶,采用外延生长技术生成所述外延层309。The material of the
虽然本发明披露如上,但本发明并非限定于此。任何本领域技术人员,在不脱离本发明的精神和范围内,均可作各种更动与修改,因此本发明的保护范围应当以权利要求所限定的范围为准。Although the present invention is disclosed above, the present invention is not limited thereto. Any person skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention should be based on the scope defined by the claims.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030082861A1 (en) * | 2001-10-29 | 2003-05-01 | Nec Corporation | Method for fabricating a MOSFET |
| US20080014700A1 (en) * | 2006-07-12 | 2008-01-17 | Woong-Hee Sohn | Methods for fabricating improved gate dielectrics |
| CN102064129A (en) * | 2009-11-13 | 2011-05-18 | 英特赛尔美国股份有限公司 | Semiconductor process using mask openings of varying widths to form two or more device structures |
| US20140080296A1 (en) * | 2012-09-18 | 2014-03-20 | Samsung Electronics Co., Ltd. | Method of fabricating semiconductor device |
| CN105097701A (en) * | 2014-04-25 | 2015-11-25 | 中芯国际集成电路制造(上海)有限公司 | Static memory cell forming method |
| US20160284806A1 (en) * | 2015-03-23 | 2016-09-29 | Sangjine Park | Semiconductor Device and Method for Manufacturing the Same |
| CN109192747A (en) * | 2018-10-31 | 2019-01-11 | 德淮半导体有限公司 | The forming method of imaging sensor |
-
2021
- 2021-04-01 CN CN202110356312.6A patent/CN115188665A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030082861A1 (en) * | 2001-10-29 | 2003-05-01 | Nec Corporation | Method for fabricating a MOSFET |
| US20080014700A1 (en) * | 2006-07-12 | 2008-01-17 | Woong-Hee Sohn | Methods for fabricating improved gate dielectrics |
| CN102064129A (en) * | 2009-11-13 | 2011-05-18 | 英特赛尔美国股份有限公司 | Semiconductor process using mask openings of varying widths to form two or more device structures |
| US20140080296A1 (en) * | 2012-09-18 | 2014-03-20 | Samsung Electronics Co., Ltd. | Method of fabricating semiconductor device |
| CN105097701A (en) * | 2014-04-25 | 2015-11-25 | 中芯国际集成电路制造(上海)有限公司 | Static memory cell forming method |
| US20160284806A1 (en) * | 2015-03-23 | 2016-09-29 | Sangjine Park | Semiconductor Device and Method for Manufacturing the Same |
| CN109192747A (en) * | 2018-10-31 | 2019-01-11 | 德淮半导体有限公司 | The forming method of imaging sensor |
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