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CN1153680C - Method for transferring artistic pattern of sublimable dye onto curved surface of billiard ball - Google Patents

Method for transferring artistic pattern of sublimable dye onto curved surface of billiard ball Download PDF

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CN1153680C
CN1153680C CNB001317938A CN00131793A CN1153680C CN 1153680 C CN1153680 C CN 1153680C CN B001317938 A CNB001317938 A CN B001317938A CN 00131793 A CN00131793 A CN 00131793A CN 1153680 C CN1153680 C CN 1153680C
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stopper
color
lithographic printing
heart
pattern
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CN1349897A (en
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艾尔伯特・戴维斯
艾尔伯特·戴维斯
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Abstract

一种将可升华染料美术图案转印到台球外曲表面上的方法。首先模制具有至少一凹部的非白色聚酯台球,该凹部在其外曲表面上有第一预定结构。然后将具有第一预定结构的塞子插入到凹部内,并使塞子在凹部内热固,同时在辅助载板上形成由可升华染料形成的第一平版印刷美术图案,该图案的外部边缘与第一预定结构基本相同。环绕该外部边缘形成有向内延伸的诸切口。最后将带有可升华染料的第一平版印刷美术图案热压转印到塞子的外曲表面上。

A method for transferring a sublimable dye art pattern onto the outer curved surface of a billiard ball. First, a non-white polyester billiard ball having at least one recess is molded, and the recess has a first predetermined structure on its outer curved surface. Then, a plug having the first predetermined structure is inserted into the recess, and the plug is heat-set in the recess, while a first lithographic art pattern formed of a sublimable dye is formed on an auxiliary carrier, and the outer edge of the pattern is substantially the same as the first predetermined structure. Incisions extending inward are formed around the outer edge. Finally, the first lithographic art pattern with sublimable dye is heat-pressed and transferred onto the outer curved surface of the plug.

Description

将可升华染料美术图案转印到台球的外曲表面上的方法Method for transferring a sublimable dye art pattern onto the outer curved surface of a billiard ball

技术领域technical field

本发明涉及一种包括热致转印可升华染料图案的方法,尤其涉及将此类图案施加到台球曲面上的方法。The present invention relates to a method involving thermal transfer of a sublimable dye pattern, and more particularly to a method of applying such a pattern to the curved surface of a billiard ball.

背景技术Background technique

可通过升华转印印刷法来修饰多种表面。此类转印法包括第一步:采用具有当其被加热时会升华或蒸发成气体的特性的、所谓的“消散”染料在纸上进行全色平版印刷。第二步:在热量和通常在转印压制中的压力的作用下,将所印制的图案转印到能接受可升华油墨的基材上。通过采用腐蚀凹版(gravure)压制滚筒和标准平版印刷纸的平版印刷法可将油墨印到纸上,这样就能得到通过这些技术所获得的高质全色复制品。A variety of surfaces can be modified by sublimation transfer printing. Such transfer methods consist of a first step: full-color lithographic printing on paper using so-called "dissipating" dyes that have the property of sublimating or evaporating into a gas when heated. Second step: The printed pattern is transferred to a substrate receptive to sublimable inks under the action of heat and pressure usually in a transfer press. Inks can be applied to paper by lithography using a gravure press cylinder and standard lithographic paper, allowing for the high quality full-color reproductions obtained by these techniques.

以往发现,升华转印法尤其适用于将全色复制品印到聚酯纤维织物上。在此类织物上可获得卓越的色质和有效的转印,但倘若将它们印到诸如木料、微粒板(particle board)、塑料板、皮革、橡胶及其它有机物或天然物材料之类的非纺织物品上则通常得到较差的结果。而且,根本就无法在玻璃纤维、玻璃板、金属表面、大理石或其它无机材料上进行转印。本发明人在他自己的美国专利4,395,263号中提供了一种用于将可升华油墨转印到上述任意一种基材(无论是有机物或无机物)上的方法。Sublimation transfer printing has previously been found to be particularly suitable for printing full-color reproductions onto polyester fabrics. Excellent color quality and effective transfer can be obtained on such fabrics, but if they are printed on non-materials such as wood, particle board (particle board), plastic board, leather, rubber and other organic or natural materials On textile items generally poorer results are obtained. Also, transfer printing on fiberglass, glass sheets, metal surfaces, marble or other inorganic materials is simply not possible. The present inventors in their own US Patent No. 4,395,263 provide a method for transferring sublimable inks to any of the substrates described above, whether organic or inorganic.

在美国专利4,395,263号的指导下尝试着将可升华染料的平版印刷美术图案热转印到台球曲面上的过程中,碰到了某些困难。In attempting to thermally transfer lithographic artwork of sublimable dyes to the curved surface of a billiard ball under the guidance of US Patent No. 4,395,263, certain difficulties were encountered.

在将心形或黑桃形(纸牌中的)平版印制的、其直径远大于1.905-2.540厘米(3/4-1英寸)的美术作品印制在标准球形台球的尝试中,平版印刷纸在热压转印操作中会起皱,并且在所转印的图案上会产生令人不满的锯齿状边。平版印刷机对此无能为力,而且也没有能解决该起皱问题的柔性的或弹性的纸材用。In an attempt to print lithographically printed artwork in the shape of hearts or spades (of playing cards), much larger than 1.905-2.540 cm (3/4-1 inch) in diameter, on standard billiard balls, lithographic paper Wrinkles during heat transfer operations and can produce unsatisfactory jagged edges on transferred graphics. Lithographic printing presses cannot do this, and there are no flexible or elastic paper stocks that can solve this wrinkling problem.

发明内容Contents of the invention

本发明的一个目的在于提供一种将可升华染料美术图案转印到物体的外曲表面上的新颖的方法。It is an object of the present invention to provide a novel method of transferring a sublimable dye fine art pattern onto a curved surface of an object.

本发明另一个目的在于提供一种将可升华染料美术图案转印到台球的外曲表面上的新颖的方法。Another object of the present invention is to provide a novel method of transferring sublimable dye art patterns onto the curved surface of a billiard ball.

本发明还有一个目的在于提供一种将可升华染料美术图案转印到台球的外曲表面上、且所转印的图案不会产生由于平版印刷纸在热压操作期间发生起皱所带来的令人不满的锯齿状边的新颖的方法。Yet another object of the present invention is to provide a method for transferring sublimable dye art patterns onto the outer curved surface of a billiard ball without the resulting pattern being wrinkled due to lithographic printing paper during the heat-pressing operation. A novel approach to unsatisfactory jagged edges.

本发明涉及一种将可升华染料美术图案转印到诸如台球、高尔夫球、网球、保龄球、电话、玩具之类物体的外曲表面上的方法。一较佳实施例是关于将可升华染料美术图案热转印到台球上。The present invention relates to a method of transferring a sublimable dye art pattern to the outer curved surface of an object such as billiard balls, golf balls, tennis balls, bowling balls, telephones, toys and the like. A preferred embodiment concerns the thermal transfer of sublimable dye art graphics onto billiard balls.

本发明是由于乔治·埃默里(George Emery)所发明的落袋台球游戏(PokerPool)的发展而开发的。该游戏须要诸台球上具有与一副纸牌中的四组牌相对应的图案。因此,必须向台球的外曲表面施加心形和黑桃形图案。The present invention was developed as a result of the development of the game of pocket billiards (PokerPool) invented by George Emery. The game requires the billiard balls to have patterns corresponding to the four sets of cards in a deck. Therefore, a pattern of hearts and spades must be applied to the outer curved surface of the billiard ball.

在克服曲面上进行热转印过程中的起皱现象的工作中发现,这个问题是可以克服的。这是通过用钢尺染色切割略大于所印制的图案的心形或黑桃形美术图案、并提供自外部边缘向内延伸大约0.15875-0.635厘米(1/16-1/4英寸)的切口,于是在热转印过程中,介于诸切口之间的部分只会发生重叠而不会起皱。由于萨布利斯泰蒂克(sublistatic)印刷法的升华特性,因而因红心或黑桃色彩完美的均匀混和,则从纸上的切口中觉察不到明显的痕迹,而且,也不会出现由于纸起皱而形成的锯齿状边。In work to overcome wrinkling during thermal transfer printing on curved surfaces it was found that this problem can be overcome. This is done by dye-cutting with a steel ruler a heart or spade art pattern slightly larger than the printed pattern, and providing a cut extending approximately 0.15875-0.635 cm (1/16-1/4 inch) inward from the outer edge , so in the thermal transfer process, the parts between the cuts will only overlap without wrinkling. Due to the sublime nature of the sublistatic printing process, there is no perceptible trace from the incision on the paper due to the perfectly even blending of the hearts or spades and, moreover, no traces due to A jagged edge caused by crumpling paper.

另一个必须要克服的问题是在台球上提供适于通过升华的方式从平版印刷纸载体上转印染料的一适当表面。在台球的特殊情况中,可采用包括黑色在内的不同的颜色。为了在这些不同颜色的表面上印制红心、黑桃及多种颜色的美术图案,则必须要有具有白色背景的塞子。这是通过首先模制一具有至少一个凹部的球形聚酯台球所实现的,其中该台球在其外表面中形成有心形或黑桃形的预定结构。该台球由非白色材料制成。下一步则将由聚酯树脂材料所制成的塞子插入或制入到凹部内,并且该塞子应当具有相应的心形或黑桃形结构。作为更节省成本的该方法的一种变型及简化形式,由于黑桃的平版印刷美术图案的黑色背面在任何颜色的球体上均印成黑色而无需白色塞子的背景色,而美术图案中所有其它的颜色则均需白色塞子的背景色,因而可将所有的白色塞子均制成为心形结构。接着,塞子在凹部内热固,由此该台球具有大致球形外表面。该塞子可由一种不透明的白色材料制成。然后,在塞子的表面上涂上光亮的醇酸树脂和三聚氰胺甲醛树脂。Another problem that had to be overcome was that of providing a suitable surface on the billiard ball for the transfer of dyes by sublimation from the lithographic paper support. In the particular case of billiard balls, different colors can be used including black. In order to print hearts, spades, and multi-color art patterns on the surfaces of these different colors, it is necessary to have a stopper with a white background. This is accomplished by first molding a spherical polyester billiard ball having at least one recess, wherein the billiard ball has a predetermined configuration of hearts or spades formed in its outer surface. This billiard ball is made of non-white material. In the next step, a plug made of polyester resin material is inserted or molded into the recess, and the plug should have a corresponding heart-shaped or spade-shaped configuration. As a variation and simplification of this method which is more cost effective, since the black backside of the lithographic art pattern of spades is printed black on any color sphere without the need for a background color of white stoppers, all other in the art pattern The colors of all the white plugs need the background color of the white plug, so all the white plugs can be made into a heart-shaped structure. Next, the plug is thermoset within the recess, whereby the billiard ball has a generally spherical outer surface. The plug can be made of an opaque white material. Then, a glossy alkyd and melamine formaldehyde resin is applied to the surface of the stopper.

在个别操作中,红心和黑桃的平版印刷美术图案形成在辅助载板上。该平版印刷美术图案由可升华染料形成。心形或黑桃形平版印刷图案的外部边缘应当具有环绕该平版印刷美术图案周长的外部边缘的、向内延伸的诸切口。接着,将这些平版印刷美术图案施加到塞子的外表面上,于是,进行平版印刷美术图案的热压转印操作,从而将可升华染料印到了塞子的外曲表面上。In a separate operation, lithographic artwork of hearts and spades was formed on a secondary carrier. The lithographic fine art pattern is formed from sublimable dyes. The outer edge of the heart or spade lithographic design should have inwardly extending cutouts around the outer edge of the lithographic artwork perimeter. These lithographic artworks were then applied to the outer surface of the stopper, whereupon a heat press transfer operation of the lithographic artwork was performed, whereby the sublimable dye was printed on the outer curved surface of the stopper.

虽然这种劳动密集型方法产生了最佳的结果,但通过在彩色台球内制造或插设心形或黑桃形二氧化钛着色苯乙烯聚酯塞子来取代上述聚酯树脂的支承层可得到该方法的另一种变型及简化形式。然后,聚酯树脂塞子的表面上可涂上光亮的醇酸树脂和三聚氰胺甲醛树脂并热固,以便提供通过从平版印刷纸载体升华进行转印的染料层。While this labor-intensive method yields the best results, it is obtained by fabricating or inserting heart or spade titanium dioxide colored styrene polyester stoppers within colored billiard balls in place of the polyester resin support layer described above. Another variant and simplified form of . The surface of the polyester resin stopper may then be coated with glossy alkyd and melamine formaldehyde resins and thermoset to provide a dye layer which is transferred by sublimation from the lithographic paper support.

通过改变苯乙烯聚酯树脂塞子中的二氧化钛白色混合物可提供该方法的又一种变型及简化形式。这是通过将每100份树脂中的色素量减至8±6份,以足以使其半透明,这样就可去除最顶层的光亮的醇酸树脂和三聚氰胺甲醛树脂来实现的。虽然该简化的方法无法产生出如顶部透明层和极白的底层的较佳叠层组合所产生出的照相印刷的色彩亮度和浓度,但由该简化的方法所得到的色调是可令人接受的,并且该简化有利于经济效益。Yet another variation and simplification of the method can be provided by varying the titanium dioxide white mixture in the styrene polyester resin stopper. This was achieved by reducing the amount of pigment to 8 ± 6 parts per 100 parts resin, enough to make it translucent, so that the topmost glossy alkyd and melamine formaldehyde resins could be removed. While this simplified approach does not produce the brightness and depth of color in photographic prints as produced by the optimal laminate combination of a top clear layer and a very white base layer, the hues obtained by this simplified approach are acceptable , and this simplification is beneficial to economic benefits.

还有一个必须要克服的问题是将红心印迹或黑桃印迹精确地印制到各种颜色球中的白色塞子上。倘若红心印迹的形状和大小与白心状塞子完全一致,且可进行绝对完美的印制,则是毫无问题的。但即使在除红色之外的任何颜色球上沿任意方向稍有遗漏的情况发生,该球上就会露出一些白色区域和某些暗色边界(例如,在兰色球上,红色加兰色会产生紫色边界,而在绿色球上,红色加绿色则会产生黑色边界,等等)Still another problem that had to be overcome was the precise imprinting of hearts or spades onto the white plugs in the various colored balls. As long as the red heart is exactly the same shape and size as the white heart stopper and can be printed with absolute perfection, there is no problem. But even if a slight omission occurs in any direction on any color ball other than red, some white areas and some dark borders will be exposed on the ball (for example, on a blue ball, red and blue will be produces a purple border, while on a green ball, red plus green produces a black border, etc.)

使红心印迹小于白色塞子可消除不良的颜色边界问题,但却会在红心印迹周围留下令人不快的白色边界。通过环绕尺寸不足的红心印迹提供一定颜色的萨布利斯泰蒂克油墨边界、以使其与其上要印制的球体的颜色相匹配,可解决这一问题。该边界的宽度应当足以将匹配的颜色印到白色塞子区域中去,并将匹配的颜色套印到球的紧挨着白色塞子区域外部的区域中去。作为更节省成本的该方法的一种变型及简化形式,对于各种美术图案,该边界可为用于所有颜色的球的黑色(取代了与它要印制的球体的颜色相匹配的颜色)。于是,黑色的边界会将黑色印到白色塞子上,并同时将黑色印到所有颜色的球上的、对有色区域它所要套印的地方。Making the heart blot smaller than the white plug eliminates the undesirable color border problem, but leaves an unpleasant white border around the heart blot. This problem can be solved by providing a border of Sabri Stetic ink of a color around the undersized heart blot to match the color of the sphere to be printed on it. The border should be wide enough to print the matching color into the white plug area and to overprint the matching color into the area of the ball immediately outside the white plug area. As a variation and simplification of this method which is more cost effective, for various art patterns, the border could be black for all color balls (instead of a color matching the color of the ball it is printing on) . The black border then prints black onto the white plug, and simultaneously prints black onto all colored balls where it overprints the colored areas.

对于尺寸过大的黑桃美术图案可采用相同的基本方法,只是由于尺寸过大的黑色萨布利斯泰蒂克油墨美术图案将黑色印到任何颜色的球上以及白色塞子上,因而球体内不必具有黑桃形白色塞子插入件。在这种情况下,不存在遗漏问题,并且尺寸过大的黑桃美术图案将黑桃形印到插入的白心形塞子上,其中包括足够的黑色边界以遮盖任何遗漏的地方。The same basic approach can be used for the oversized spades art pattern except that since the oversized black Sabri Stetic ink art pattern prints black onto the ball of any color as well as the white stopper, the inside of the ball It is not necessary to have a spade-shaped white plug insert. In this case, there is no problem of omission, and the oversized spade art print of the spade onto the inserted white heart plug includes enough black borders to cover any omissions.

附图说明Description of drawings

图1是一种台球的前视立体图,其中在其外曲表面中形成有凹部;Figure 1 is a front perspective view of a billiard ball with recesses formed in its outer curved surface;

图2是该台球的前视立体图,其中在其凹部中插设有塞子;Figure 2 is a front perspective view of the billiard ball with a plug inserted in its recess;

图3A是可升华染料的心形平版印刷美术图案的前视图;Figure 3A is a front view of a heart-shaped lithographic fine art pattern of sublimable dye;

图3B是该可升华染料的心形平版印刷美术图案的侧视图;Figure 3B is a side view of a heart-shaped lithographic artwork of the sublimable dye;

图4是可升华染料的黑桃形平版印刷美术图案的前视图;以及Figure 4 is a front view of a spade lithographic fine art pattern of sublimable dye; and

图5是前视立体图,其中已将平版印刷的美术图案转印到塞子上。Figure 5 is a front perspective view in which a lithographic artwork has been transferred to the stopper.

具体实施方式Detailed ways

下面将参照图1-5来描述将可升华染料美术图案转印到诸如台球之类的一物体的外曲表面上的方法。台球10由非白色的聚酯树脂材料模制而成。它可呈黄色、绿色、红色等。该台球10形成有心形凹部12。该凹部的深度为0.0508-0.2032厘米(0.02-0.08英寸)。图2示出了一白色的塞子14已插入到该台球凹部内的情形。A method of transferring a sublimable dye art pattern onto the curved surface of an object such as a billiard ball will now be described with reference to FIGS. 1-5. Billiard ball 10 is molded from a non-white polyester resin material. It can be yellow, green, red, etc. The billiard ball 10 is formed with a heart-shaped recess 12 . The depth of the recess is 0.0508-0.2032 cm (0.02-0.08 inches). Figure 2 shows a white plug 14 inserted into the recess of the billiard ball.

图3A是第一心形平版印刷美术图案的前视图。它具有一中心部分18和环绕其外部边缘的周长延伸的一黑边20。若干切口22自平版印刷美术图案环绕其整个周长的外部边缘向内延伸。这些切口的长度为L1,该L1为0.15875-0.635厘米(1/16-1/4英寸)。图3B是该平版印刷美术图案16的侧视图,其中该美术图案16安装在一载板26上。Figure 3A is a front view of a first heart-shaped lithographic artwork. It has a central portion 18 and a black border 20 extending around the perimeter of its outer edge. A number of cutouts 22 extend inwardly from the outer edge of the lithographic artwork around its entire perimeter. The length of these incisions is L1, which is 0.15875-0.635 cm (1/16-1/4 inch). FIG. 3B is a side view of the lithographic artwork 16 mounted on a carrier 26 .

图4中示出了一种黑桃形平版印刷美术图案30。它呈黑色,并具有环绕其整个周长向内延伸的切口32。它也安装在一载板上。A lithographic graphic art pattern 30 in the shape of spades is shown in FIG. 4 . It is black in color and has a cutout 32 extending inwardly around its entire circumference. It is also mounted on a carrier board.

图5中示出了台球成品10,其中所转印的红心形图案40覆盖了白色塞子14。The finished billiard ball 10 is shown in FIG. 5 with the transferred red heart pattern 40 covering the white plug 14 .

Claims (20)

1. but one kind is transferred to the lip-deep method of billiard ball outcurve with the sublimation dye artistic pattern, comprises the following steps:
(a) molded spherical polyester billiard ball with at least one recess, described recess has first predetermined structure in the curved surface outside it, and described billiard ball are made by non-white material;
(b) will be inserted in described at least one recess by the made stopper of white styrene mylar thermosetting material, described stopper has described first predetermined structure;
(c) on the outer surface of described stopper, coat bright alkyd resins and melamine resin then;
(d) follow described stopper and coating and carry out thermosetting in described recess, described thus billiard ball have spherical outer surface;
(e) on auxiliary support plate, form the first lithographic printing artistic pattern, but the described first lithographic printing artistic pattern formed by sublimation dye, the external margin of the described first lithographic printing artistic pattern is consistent with the shape of described first predetermined structure;
(f) external margin around the described first lithographic printing artistic pattern girth forms some otch that extend internally; And
(g) but described first lithographic printing artistic pattern and described sublimation dye hot pressing are transferred on the described outer curved surface of described stopper.
2. the method for claim 1 is characterized in that, described first predetermined structure is heart-shaped.
3. method as claimed in claim 2 is characterized in that, described lithographic printing artistic pattern is a red heart.
4. method as claimed in claim 3, it is characterized in that, the undersized of the described first lithographic printing artistic pattern is in described heart-shaped stopper, and Saab Li Sitaidike printing ink border is arranged around the red heart pattern of described undersize, the color of the spheroid that the color on this border and described lithographic printing artistic pattern will be printed is complementary, the width on described border is enough to color with described coupling and prints in the described stopper region and go, and the color cover of described coupling is printed to the described spheroid that is close to described stopper region outside gets on.
5. the method for claim 1 is characterized in that, described first predetermined structure is the spade shape in the playing cards.
6. the method for claim 1 is characterized in that, described mylar stopper contains the Chinese white that described stopper is white in color.
7. the method for claim 1 is characterized in that, described otch extends 0.15875-0.635 centimetre distance from external margin.
8. the method for claim 1 is characterized in that, described concave depth is 0.0508-0.2032 centimetre.
9. the method for claim 1 is characterized in that, described white styrene mylar thermosetting material contains titanium dioxide white pigment.
10. method as claimed in claim 9 is characterized in that, described first predetermined structure is heart-shaped.
11. method as claimed in claim 10 is characterized in that, described lithographic printing artistic pattern is a red heart.
12. method as claimed in claim 11, it is characterized in that, the undersized of the described first lithographic printing artistic pattern is in described heart-shaped stopper, and Saab Li Sitaidike printing ink border is arranged around the red heart pattern of described undersize, the color of the spheroid that the color on this border and described lithographic printing artistic pattern will be printed is complementary, the width on described border is enough to color with described coupling and prints in the described stopper region and go, and the color cover of described coupling is printed to the described spheroid that is close to described stopper region outside gets on.
13. method as claimed in claim 9 is characterized in that, described first predetermined structure is the spade shape in the playing cards.
14. the method for claim 1 is characterized in that, the titanium dioxide white pigment in the described white styrene mylar thermosetting material is adjusted and reduced to per 100 parts of resins 8 ± 6 parts of pigments, so that it is enough to is translucent.
15. method as claimed in claim 14 is characterized in that, described first predetermined structure is heart-shaped.
16. method as claimed in claim 15 is characterized in that, described lithographic printing artistic pattern is a red heart.
17. method as claimed in claim 16, it is characterized in that, the undersized of the described first lithographic printing artistic pattern is in described heart-shaped stopper, and Saab Li Sitaidike printing ink border is arranged around the red heart pattern of described undersize, the color of the spheroid that the color on this border and described lithographic printing artistic pattern will be printed is complementary, the width on described border is enough to color with described coupling and prints in the described stopper region and go, and the color cover of described coupling is printed to the described spheroid that is close to described stopper region outside gets on.
18. method as claimed in claim 14, it is characterized in that, the undersized of the described first lithographic printing artistic pattern is in described heart-shaped stopper, and have its width and be enough to printing black on any part of the described white stopper that exposes, and on any coloured moiety that is close to described white stopper region outside the Saab Li Sitaidike black border of printing black.
19. method as claimed in claim 14 is characterized in that, described first predetermined structure is the spade shape in the playing cards.
20. method as claimed in claim 14 is characterized in that, described first predetermined structure is the red heart shape in the playing cards.
CNB001317938A 2000-10-19 2000-10-19 Method for transferring artistic pattern of sublimable dye onto curved surface of billiard ball Expired - Fee Related CN1153680C (en)

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Application Number Priority Date Filing Date Title
CNB001317938A CN1153680C (en) 2000-10-19 2000-10-19 Method for transferring artistic pattern of sublimable dye onto curved surface of billiard ball

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