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CN115403668A - Extraction process of bioactive collagen peptide of channel catfish swim bladder - Google Patents

Extraction process of bioactive collagen peptide of channel catfish swim bladder Download PDF

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Publication number
CN115403668A
CN115403668A CN202211186880.7A CN202211186880A CN115403668A CN 115403668 A CN115403668 A CN 115403668A CN 202211186880 A CN202211186880 A CN 202211186880A CN 115403668 A CN115403668 A CN 115403668A
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bladder
collagen
collagen peptide
extraction process
swimming
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CN202211186880.7A
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Inventor
蔡焰值
王红兵
蔡煜
王杰
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Hubei Xingxiang Biotechnology Co ltd
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Hubei Xingxiang Biotechnology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07KPEPTIDES
    • C07K14/00Peptides having more than 20 amino acids; Gastrins; Somatostatins; Melanotropins; Derivatives thereof
    • C07K14/435Peptides having more than 20 amino acids; Gastrins; Somatostatins; Melanotropins; Derivatives thereof from animals; from humans
    • C07K14/78Connective tissue peptides, e.g. collagen, elastin, laminin, fibronectin, vitronectin or cold insoluble globulin [CIG]
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P21/00Preparation of peptides or proteins
    • C12P21/06Preparation of peptides or proteins produced by the hydrolysis of a peptide bond, e.g. hydrolysate products

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Zoology (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Genetics & Genomics (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Toxicology (AREA)
  • Gastroenterology & Hepatology (AREA)
  • Biophysics (AREA)
  • Medicinal Chemistry (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Peptides Or Proteins (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

The invention discloses an extraction process of collagen peptide of bullhead catfish swim bladder, which mainly utilizes swim bladder after the bullhead product is processed, firstly removes non-collagen in the swim bladder, decolors, degreases and the like, and then carries out enzymatic hydrolysis, enzyme inactivation, isoelectric point adjustment, centrifugal concentration, low-temperature vacuum freeze drying and superfine grinding to obtain a finished product. The invention carries out high-valued deep processing and utilization on swimming bladders processed from the longsnout catfish products, extracts II type raw material products with biological activity and purity as high as more than 93.5 percent, and has obvious high-valued deep processing effect on the swimming bladders: the product is widely used in the industries of medicine, health food, cosmetics, food additives and the like; the extraction process has no heavy metal and drug residue exceeding standards, and reaches the national food sanitation safety standard, and the processing discharge wastewater conforms to the national class I to II discharge standards; the extraction process has simple equipment and low production cost.

Description

Extraction process of bioactive collagen peptide of channel catfish swim bladder
Technical Field
The invention relates to the technical field of biological enzymolysis extraction, in particular to an extraction process of collagen peptide of bullhead ictalurus punctatus swim bladder.
Background
Collagen is a biological high molecular substance, has various biological functions and plays a role of a binding tissue in an animal connective tissue. Collagen is one of the most critical raw materials in the biotechnology industry, and is also the best medical, moisturizing, repairing, aging delaying, nutrition and other materials with huge demand. Is a main component for maintaining the shape and structure of skin, tissues and organs, and is also an important raw material for repairing each damaged tissue.
The primary way for obtaining natural collagen and collagen peptide in the past is from animal skin tissues of livestock and poultry, and the possibility of infection of mad cow disease and other related diseases exists, so that the use of the collagen and the collagen peptide product of the terrestrial mammals is limited. Nowadays, the method is gradually turning to collagen peptides such as fish skin, fish scale and the like, and the fish collagen is obviously superior to the collagen of terrestrial animals in some aspects, such as having the characteristics of low antigenicity, low allergy and the like, and can gradually replace the collagen of terrestrial animals.
More than 100 catfishes in the world belong to scale-free economic fishes, the catfishes have omnivorous meat preference, fast growth, wide application range and rich meat nutrition, swim bladders live in water body to balance up-and-down activities, and the swim bladders contain the most abundant collagen. In the world, catfishes without muscle bones are convenient to process into various aquatic products, swimming bladders are processed at the low end of the processing of the aquatic products, and at present, few processing enterprises adopt organic solvents such as acid, alkali and the like to extract collagen of the catfish swimming bladders of the catfishes, so that the environmental pollution is easily caused, the product quality and purity are low, the impurity content is high, secondary pollution of chemical substances and the like is caused, and side effects are generated on human bodies.
Disclosure of Invention
The invention aims to solve the defects in the prior art and provides an extraction process of collagen peptide of the fish maw of channel catfish.
In order to achieve the purpose, the invention adopts the following technical scheme:
an extraction process of collagen peptide of swim bladder of channel catfish comprises the following steps:
a. carrying out non-collagen protein, fat and pigment removal treatment on the swimming bladder of the channel catfish for 4 to 5 hours by using a mixed solution with the concentration of 0.02 to 0.03 percent of edible alkali (Na 2CO 3), 2.3 to 2.7 percent of salt (NaCl) and 0.07 to 0.09 percent of food-grade hydrogen peroxide under the condition of continuously stirring at the temperature of between 10 and 12 ℃;
b. rinsing the swimming bladder subjected to the triple dehydration treatment to be neutral or weakly acidic by using clear water, draining water on the surface of the treated swimming bladder, and grinding the swimming bladder into colloid by using a colloid mill;
c. adjusting the pH value of the minced bullhead ictalurus punctatus maw to 4-5, adding 200 ten thousand units/g of collagen complex enzyme according to the proportion of 1.5 per thousand of the weight of the bullhead ictalurus punctatus maw, and carrying out heat preservation and enzymatic hydrolysis at the low temperature of 18 ℃ for about 24 hours;
d. filtering the enzymolysis liquid with 3000D-5000D molecular sieve, inactivating the filtered collagen peptidase enzymolysis liquid by adjusting enzyme deactivation isoelectric point, adjusting pH value to 5.8, centrifuging by a centrifuge at 5000r/min for 20min to precipitate fish collagen peptide colloid;
e. and (3) carrying out vacuum freeze drying at the low temperature of-45 ℃ and airflow superfine grinding on the centrifuged colloidal collagen peptide to obtain a powdery collagen peptide finished product.
And c, the method for processing the water on the surface of the fish skin in the step b is to filter the water at a low temperature or dry the water by a vibrating screen.
And c, grinding the swimming bladders in the step b by using a mechanical meat grinder.
Compared with the prior art, the invention has the beneficial effects that:
1. the method takes the fish skin of the longsnout catfish after processing as the raw material to extract the collagen peptide, so that the swim bladder of the longsnout catfish is fully utilized to generate a high-valued product;
2. the method of enzyme hydrolysis is adopted to extract effective substances, the technical problem of secondary toxic and harmful medicine and heavy metal residue in the traditional chemical extraction process is solved, and the product is safe and has no toxic or side effect;
3. the wastewater discharged after the swimming bladder collagen is extracted by the enzymatic hydrolysis does not produce non-point source pollution to the ecological environment, and reaches the national level I to level II discharge standard;
4. the invention adopts alkali release and salt edible hydrogen peroxide solution to remove non-collagen, fat and decoloration, improves the purity of extracted collagen peptide, has low fat and no melanin, the purity of II type collagen peptide is up to more than 95 percent, and the relative molecular weight range is 1000-5000D (dalton);
5. the whole extraction process of the collagen peptide is carried out at low temperature to maintain the biological activity of the collagen peptide;
6. the collagen peptide raw material product obtained by the invention has wide application range and can be widely used in the industries of medicines, food additives, cosmetics, health-care foods and the like;
7. the extraction equipment required by the invention is simple, the operation is convenient, the raw material source range is wide, the labor is saved, and the production cost is low.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
Example 1
5 kg of swimming bladder raw material of channel catfish is taken, and a mixed solution with the concentration of 0.025 percent edible alkali (Na 2CO 3), 2.5 percent salt (NaCl) and 0.09 percent edible hydrogen peroxide is mixed with the raw material according to the weight ratio of 10:1, treating for 4-5 hours under the condition of continuously stirring at 10-12 ℃ to remove non-collagen, fat and pigment. Washing the swimming bladders for a plurality of times by clear water until the pH value of the swimming bladders is 5.0, washing the swimming bladders by pure sterile water, draining the swimming bladders, grinding the swimming bladders into colloid by a colloid mill, mixing the colloid with the water by a ratio of 1: adding purified sterile water according to a proportion of 8.5, adding 7.5 g of collagen complex enzyme with 200 ten thousand units/g according to a proportion of 1.5 per thousand of the weight of a raw material substrate, carrying out enzymatic hydrolysis at the low temperature of 18 ℃ for 24 hours, carrying out isoelectric point inactivation of enzyme inactivation adjustment on enzymatic hydrolysate, adjusting the optimal pH value of collagen to 5.8, centrifuging for 20 minutes by using a centrifuge at 5000r/min, carrying out low-vacuum freeze drying at the temperature of-40 ℃ on slurry-like collagen peptide, and crushing by using a superfine pulverizer to obtain a finished product, and finally obtaining 906 g of collagen peptide with bioactivity, wherein the extraction rate of the raw material of the bullacta punctatus maw is 18.12%. The molecular weight of the type II collagen peptide is 1000-5000 daltons.
Example 2
The embodiment of the invention takes 5 kg of swimming bladder raw material of channel catfish, and takes a mixed solution with the concentration of 0.025 percent edible alkali (Na 2CO 3), 2.5 percent salt (NaCl) and 0.09 percent edible hydrogen peroxide and the raw material according to the weight ratio of 10:1, treating for 4-5 hours under the condition of continuously stirring at 10-12 ℃ to remove non-collagen, fat and pigment. Washing the swimming bladder with clear water for a plurality of times until the pH value of the swimming bladder is 5.0, washing the swimming bladder with pure sterile water, draining the swimming bladder, grinding the swimming bladder into colloid by a colloid mill, mixing the colloid with the water 1: adding pure sterile water according to a proportion of 8.5, adding 5 g of collagen complex enzyme of 200 ten thousand units/g according to a proportion of 1.5 per thousand of the weight of a raw material substrate, carrying out enzymatic hydrolysis for 24 hours at a low temperature of 18 ℃, inactivating an isoelectric point of an enzymatic hydrolysate after adjusting enzyme inactivation, adjusting the optimal pH value of collagen to 5.8, centrifuging for 20 minutes by using a centrifuge at 5000r/min, carrying out low-vacuum freeze drying at-40 ℃ on slurry-shaped collagen peptide, and crushing by using a superfine pulverizer to obtain a finished product, and finally obtaining the extraction rate of the raw material of the bullacta ictalurus mazeri 16.19 percent and the extraction rate of the collagen peptide 809.5 g with biological activity. The molecular weight of the type II collagen peptide is 1000-5000 daltons.
Example 3
The embodiment of the invention takes 5 kg of swimming bladder raw material of channel catfish, and takes a mixed solution with the concentration of 0.025 percent edible alkali (Na 2CO 3), 2.5 percent salt (NaCl) and 0.09 percent edible hydrogen peroxide and the raw material according to the weight ratio of 10:1, treating for 4-5 hours under the condition of continuously stirring at 10-12 ℃ to remove non-collagen, fat and pigment. Washing the swimming bladders for a plurality of times by clear water until the pH value of the swimming bladders is 5.0, washing the swimming bladders by pure sterile water, draining the swimming bladders, grinding the swimming bladders into colloid by a colloid mill, mixing the colloid with the water by a ratio of 1: adding pure sterile water according to a proportion of 8.5, adding 6 g of collagen complex enzyme with 200 ten thousand units/g according to a proportion of 1.5 per thousand of the weight of a raw material substrate, carrying out enzymatic hydrolysis for 24 hours at a low temperature of 18 ℃, inactivating an isoelectric point of an enzymatic hydrolysate after adjusting enzyme inactivation, adjusting the optimal pH value of collagen to be 5.8, centrifuging for 20 minutes by using a centrifuge with 5000r/min, carrying out low-vacuum freeze drying at a temperature of-40 ℃ on slurry-like collagen peptide, and crushing by using a superfine pulverizer to obtain a finished product, wherein the extraction rate of the raw material of the bullacta ictalurus punctatus mazeri is 17.05 percent, and the raw material of the collagens punctatus with biological activity is 852.5 g. The molecular weight of the type II collagen peptide is 1000-5000 daltons.
Example 4
5 kg of swimming bladder raw material of channel catfish is taken, and a mixed solution with the concentration of 0.025 percent edible alkali (Na 2CO 3), 2.5 percent salt (NaCl) and 0.09 percent edible hydrogen peroxide is mixed with the raw material according to the weight ratio of 10:1, treating for 4-5 hours under the condition of continuously stirring at 10-12 ℃ to remove non-collagen, fat and pigment. Washing the swimming bladder with clear water for a plurality of times until the pH value of the swimming bladder is 5.0, washing the swimming bladder with pure sterile water, draining the swimming bladder, grinding the swimming bladder into colloid by a colloid mill, mixing the colloid with the water 1: adding pure sterile water according to a proportion of 8.5, adding 8.5 g of collagen complex enzyme with 200 ten thousand units/g according to a proportion of 1.5 per thousand of the weight of a raw material substrate, carrying out enzymatic hydrolysis at the low temperature of 18 ℃ for 24 hours, carrying out isoelectric point inactivation of enzyme inactivation adjustment on enzymatic hydrolysate, adjusting the optimal pH value of collagen to 5.8, centrifuging for 20 minutes by using a centrifuge at 5000r/min, carrying out low-vacuum freeze drying at the temperature of-40 ℃ on slurry-like collagen peptide, and crushing by using a superfine pulverizer to obtain a finished product, and finally obtaining 911 g of collagen peptide with bioactivity, wherein the extraction rate of the raw material of the bullacta punctatus maw is 18.22%. The molecular weight of the type II collagen peptide is 1000-5000 daltons.
In the above embodiments, the swimming bladder of the channel catfish is washed with water, then drained and ground into slurry, and the channel catfish swimming bladder with physical crushing function is crushed without limitation to specific equipment, such as a meat grinder, a tissue masher, a body grinder, etc.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (3)

1. An extraction process of collagen peptide of swim bladder of channel catfish is characterized by comprising the following steps according to an extraction process flow:
a. carrying out non-collagen protein, fat and pigment removal treatment on the swimming bladder of the channel catfish for 4 to 5 hours by using a mixed solution with the concentration of 0.02 to 0.03 percent of edible alkali (Na 2CO 3), 2.3 to 2.7 percent of salt (NaCl) and 0.07 to 0.09 percent of food-grade hydrogen peroxide under the condition of continuously stirring at the temperature of between 10 and 12 ℃;
b. rinsing the swimming bladder subjected to the triple dehydration treatment to be neutral or weakly acidic by using clear water, draining water on the surface of the treated swimming bladder, and grinding the swimming bladder into colloid by using a colloid mill;
c. adjusting the pH value of the ground swimming bladder of the Ictalurus punctatus to 4-5, adding 200 ten thousand units/g of collagen complex enzyme according to the weight of 1.5 per thousand of the swimming bladder of the Ictalurus punctatus, and carrying out constant temperature enzymatic hydrolysis at the low temperature of 18 ℃ for about 24 hours;
d. filtering the enzymolysis liquid with 3000D-5000D molecular sieve, inactivating the filtered collagen peptidase enzymolysis liquid by adjusting enzyme deactivation isoelectric point, adjusting pH value to 5.8, centrifuging by a centrifuge at 5000r/min for 20min to precipitate fish collagen peptide colloid;
e. and (3) carrying out vacuum freeze drying and superfine grinding on the centrifuged colloidal collagen peptide at the low temperature of-45 ℃ to obtain a powdery collagen peptide finished product.
2. The extraction process of collagen peptide of bullhead ictalurus punctatus swim bladder according to claim 1, wherein the swim bladder surface moisture treatment method in the step b is draining under a low temperature condition or drying with a vibrating screen.
3. The process for extracting collagen peptide from swim bladder of Ictalurus punctatus as claimed in claim 1, wherein the method for grinding swim bladder into colloid in step b is mechanical colloid mill.
CN202211186880.7A 2022-09-28 2022-09-28 Extraction process of bioactive collagen peptide of channel catfish swim bladder Pending CN115403668A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114231585A (en) * 2022-01-06 2022-03-25 广西金海盈高新技术有限公司 Preparation process of fish collagen peptide of channel catfish

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101607993A (en) * 2009-07-27 2009-12-23 湖北省水产科学研究所 A kind of extraction process of collagen of channel catfish skin
CN101613731A (en) * 2009-07-27 2009-12-30 湖北省水产科学研究所 A kind of leftovers of ictalurus punctatus is recycled technology
CN109022524A (en) * 2018-08-06 2018-12-18 湖南贝贝昇生物科技有限公司 A kind of extraction process of hornpout collagen peptide
CN114231585A (en) * 2022-01-06 2022-03-25 广西金海盈高新技术有限公司 Preparation process of fish collagen peptide of channel catfish
CN114344236A (en) * 2022-01-06 2022-04-15 广西金海盈高新技术有限公司 Preparation process of channel catfish egg extract

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101607993A (en) * 2009-07-27 2009-12-23 湖北省水产科学研究所 A kind of extraction process of collagen of channel catfish skin
CN101613731A (en) * 2009-07-27 2009-12-30 湖北省水产科学研究所 A kind of leftovers of ictalurus punctatus is recycled technology
CN109022524A (en) * 2018-08-06 2018-12-18 湖南贝贝昇生物科技有限公司 A kind of extraction process of hornpout collagen peptide
CN114231585A (en) * 2022-01-06 2022-03-25 广西金海盈高新技术有限公司 Preparation process of fish collagen peptide of channel catfish
CN114344236A (en) * 2022-01-06 2022-04-15 广西金海盈高新技术有限公司 Preparation process of channel catfish egg extract

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114231585A (en) * 2022-01-06 2022-03-25 广西金海盈高新技术有限公司 Preparation process of fish collagen peptide of channel catfish

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Application publication date: 20221129