CN115565972B - A heat spreader with high efficiency in heat dissipation and a method for manufacturing the same - Google Patents
A heat spreader with high efficiency in heat dissipation and a method for manufacturing the same Download PDFInfo
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- CN115565972B CN115565972B CN202211198297.8A CN202211198297A CN115565972B CN 115565972 B CN115565972 B CN 115565972B CN 202211198297 A CN202211198297 A CN 202211198297A CN 115565972 B CN115565972 B CN 115565972B
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/42—Fillings or auxiliary members in containers or encapsulations selected or arranged to facilitate heating or cooling
- H01L23/427—Cooling by change of state, e.g. use of heat pipes
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/38—Electroplating: Baths therefor from solutions of copper
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D15/00—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
- F28D15/02—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
- F28D15/04—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure
- F28D15/046—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure characterised by the material or the construction of the capillary structure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/367—Cooling facilitated by shape of device
- H01L23/3672—Foil-like cooling fins or heat sinks
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
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- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
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- Sustainable Development (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Electroplating Methods And Accessories (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
Abstract
The invention provides a soaking plate with high-efficiency heat dissipation and a manufacturing method thereof, the soaking plate is divided into an upper plate, a gradient hydrophobic layer, a gradient hydrophilic layer and a lower plate, the gradient hydrophilic layer is constructed on the lower plate by adopting a sintering-electroplating technology, cold end liquid rapidly flows to a hot end through the action of Laplacian force, working media can be rapidly vaporized into steam after the soaking plate absorbs heat, the upper plate is provided with the gradient hydrophobic layer, liquid drops formed by the steam under the action of the Laplacian force of the gradient hydrophobic layer and the pressure difference of the cold end and the hot end can be rapidly transferred to the cold end, liquid films or liquid drops form a liquid pool on the cold end, the liquid drops rapidly fall under the double actions of hydrophobicity and gravity, the thermal resistance between a wall surface and the steam is reduced, and the gradient hydrophobic layer and the steam can fully exchange heat. The heat exchange device has the beneficial effects that based on a bionic principle, a gradient structure of the lower surface of the upper plate and the upper surface of the lower plate is established, the moving speed of a liquid phase towards a hot end and a vapor phase towards a cold end is accelerated, the heat exchange is enhanced, the heat exchange efficiency is improved, and a high-efficiency circulating heat exchange system is formed.
Description
Technical Field
The invention relates to the technical field of heat dissipation devices, in particular to a soaking plate capable of efficiently dissipating heat and a manufacturing method thereof.
Background
The vapor chamber is used as a main component for heat energy transfer, is widely applied to different fields of new energy automobiles, household appliances, industrial production and the like, optimizes the structural process of the vapor chamber, strengthens the heat energy transfer efficiency, reduces the loss of heat exchange equipment and is an important means for improving the overall performance of the system.
In recent years, with the development of high performance, integration and miniaturization of electronic components, the problem of heat dissipation of electronic chips has been increasingly prominent. At present, the conventional soaking plate structure cannot meet the heat dissipation requirement of electronic chips under the increasing high heat flux density. Heat transfer devices face increasing difficulties and challenges, especially in mobile terminals such as smartphones, tablet computers, etc., and thermal management designs are very difficult.
In the soaking plate, a layer of air film is formed on the boiling surface due to the large amount of aggregation of air bubbles, the heat transfer surface is deteriorated, the heat transfer process is increased, the heat transfer coefficient is reduced suddenly, a liquid film and liquid drops are formed on the condensing surface due to the condensation of steam on the condensing surface, the heat transfer paths of the steam and the wall surface are increased, and the heat transfer efficiency is reduced.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide a soaking plate with high heat dissipation efficiency and a manufacturing method thereof, which can improve the heat dissipation efficiency and meet the heat dissipation requirement of an electronic chip.
In order to solve the problems, the technical scheme adopted by the invention is as follows:
The utility model provides a high-efficient radiating soaking plate, including upper plate (1), gradient hydrophobic layer (2), gradient hydrophilic layer (3), hypoplastron (4), upper plate (1) and hypoplastron (4) both ends all have connecting portion (5), the clearance is left at the middle part of upper plate (1) and hypoplastron (4), connect fixedly and seal through the welding mode between connecting portion (5), gradient hydrophobic layer (2) are attached to the below of upper plate (1), gradient hydrophilic layer (3) are attached to the top of hypoplastron (4), gradient hydrophobic layer (2) are the nanometer ripple form structure of a plurality of sections different degree of depth on upper plate (1), gradient hydrophilic layer (3) are the region that the sintering of hypoplastron (4) upper surface has copper powder granule of different mesh numbers.
Preferably, the nano corrugated structure of the gradient hydrophobic layer (2) is manufactured by a femtosecond laser method, and a plurality of sections of the nano corrugated structure are divided into four sections of a 50 mu J area (201), a 80 mu J area (202), a 120 mu J area (203) and a 155 mu J area (204) according to the pulse energy, and the four sections are connected in sequence from small to large.
Preferably, the gradient hydrophilic layer (3) is manufactured by adopting a sintering-electroplating method, and a 50-mesh area (301), a 100-mesh area (302), a 150-mesh area (303), a 200-mesh area (304) and a 250-mesh area (305) are sequentially arranged above the lower plate (4) and are sequentially connected from small to large.
Preferably, the upper plate (1) and the lower plate (4) are preferably copper plates.
The method for manufacturing the soaking plate with high heat dissipation according to claim 1-4, comprising the following steps:
S1, manufacturing a nano corrugated structure of a gradient hydrophobic layer (2) by adopting a femtosecond laser method, fixing a scanning interval to be 50 mu m, enabling a lens focal length to be 200mm, scanning the lower part of an upper plate (1) according to a scanning speed of 0.5mm/S, and sequentially selecting pulse energy of the femtosecond laser to be 50 mu J, 80 mu J, 120 mu J and 155 mu J on the upper plate (1), wherein the nano corrugated structure with different depths is formed under the repeated action of different pulses under the condition that the pulse power of the femtosecond pulse laser exceeds an ablation threshold value;
S2, after femtosecond laser processing, placing the mixture into a fluorosilane ethanol solution with the concentration of 1%, standing and soaking for 3 to 5 hours, then taking out the mixture and placing the mixture into a blast drying oven with the temperature of 120 ℃, and standing and cooling the mixture after baking for 4 hours to obtain an upper plate (1) with a gradient hydrophobic layer (2);
S3, equally dividing the upper part of the lower plate (4) into five equal parts of areas, namely a 50-mesh area (301), a 100-mesh area (302), a 150-mesh area (303), a 200-mesh area (304) and a 250-mesh area (305), coating adhesive in the areas, and correspondingly bonding 50-mesh copper powder particles, 100-mesh copper powder particles, 150-mesh copper powder particles, 200-mesh copper powder particles and 250-mesh copper powder particles in the five areas of the 50-mesh area (301), the 100-mesh area (302), the 150-mesh area (303), the 200-mesh area (304) and the 250-mesh area (305);
s4, placing the lower plate (4) processed in the step S3 into a tube furnace, firstly raising the temperature in the furnace to 600 ℃ at the speed of 5 ℃ per minute, keeping for 10 minutes to remove the adhesive, then heating to 850 ℃ at the same speed, and preserving the heat for 2 hours;
S5, placing the lower plate (4) sintered in the step S4 into an electroplating device for electroplating treatment, wherein a copper sheet is used as an anode in an electroplating bath of the electroplating device, the sintered lower plate (4) is used as a cathode, and electrolytic copper simple substances are attached to the sintered lower plate (4) to form a gradient hydrophilic layer (3) with a micro-nano particle structure on the surface;
S6, the upper plate (1) and the lower plate (4) manufactured through the step S2 and the step S4 are aligned and welded together through the connecting parts of the upper plate and the lower plate, the gradient hydrophobic layer (2) on the lower surface of the upper plate (1) and the gradient hydrophilic layer (3) on the upper surface of the lower plate (4) are opposite, and a gap is reserved between the gradient hydrophobic layer (2) and the gradient hydrophilic layer (3).
Preferably, nitrogen is continuously introduced to isolate oxygen during the entire sintering process of step S4.
Preferably, in step S5, the plating solution of the plating apparatus is preferably a mixed solution of 0.8mol/L CuSO 4、1.5mol/L H2SO4 and 0.2mol/L HCl.
Preferably, the electroplating device adopts an electroplating time of 40min and a current density of 0.4mA/mm 2.
The invention has the beneficial effects that:
1. According to the invention, based on a bionic structure, a gradient hydrophobic layer is established on the upper plate, after liquid drops and a liquid film are condensed on the wall surface, the gradient surface generates Laplacian force on the liquid drops, so that the liquid drops are spontaneously and directionally transported, the liquid drops are pushed to the cold end rapidly, the heat transfer path between the wall surface and steam is reduced, and the heat exchange efficiency is improved;
2. the hydrophobic structure of the upper plate can enable the wall liquid drops to drop rapidly, quicken the replenishment rate of the bottom liquid pool in the vapor chamber, improve the deterioration of heat exchange and improve the boiling heat transfer coefficient;
3. the gradient hydrophilic layer is manufactured by adopting the sintering-electroplating coupling method, and the wettability of different roughness is utilized to enable the liquid pool to spontaneously move to the hot end at the bottom, so that the migration speed of liquid on the lower plate is improved;
4. The surface of the lower plate in a micron scale formed by sintering increases the contact area of the surface and liquid, improves the heat exchange efficiency, provides more capillary force for a nano particle layer formed by electroplating, can form more vaporization cores, and further improves the boiling heat exchange coefficient.
Drawings
FIG. 1 is a schematic cross-sectional view of the structure of the present invention;
FIG. 2 is a schematic diagram of gradient hydrophobic layer gas migration;
fig. 3 is a schematic of gradient hydrophilic layer liquid migration.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without any inventive effort, are intended to be within the scope of the invention.
As shown in figures 1-3, the soaking plate with high-efficiency heat dissipation comprises an upper plate 1, a gradient hydrophobic layer 2, a gradient hydrophilic layer 3 and a lower plate 4, wherein the upper plate 1 and the lower plate 4 are preferably copper plates, connecting parts 5 are arranged at two ends of the upper plate 1 and the lower plate 4, gaps are reserved at the middle parts of the upper plate 1 and the lower plate 4, the connecting parts 5 are fixedly sealed through a welding mode, the sealing between the upper plate 1 and the lower plate 4 can be realized through a pressing mode, the gradient hydrophobic layer 2 is attached below the upper plate 1, the gradient hydrophilic layer 3 is attached above the lower plate 4, gaps are reserved between the gradient hydrophilic layer 2 and the gradient hydrophilic layer 3, working media are reserved in the gaps, the gradient hydrophobic layer 2 is a nano corrugated structure with a plurality of sections of different depths on the upper plate 1, and the gradient hydrophilic layer 3 is a region with copper powder particles with different meshes sintered on the lower plate 4.
The nano corrugated structure of the gradient hydrophobic layer 2 is manufactured by a femtosecond laser method, and a plurality of sections of nano corrugated structures are divided into four sections of a 50 mu J area 201, a 80 mu J area 202, a 120 mu J area 203 and a 155 mu J area 204 according to the size of pulse energy, and the four sections are connected in sequence from small to large.
The gradient hydrophilic layer 3 is manufactured by adopting a sintering-electroplating method, and a 50 mesh area 301, a 100 mesh area 302, a 150 mesh area 303, a 200 mesh area 304 and a 250 mesh area 305 are sequentially connected above the lower plate 4 from small to large.
The working medium can generate water vapor after being heated, the water vapor can form liquid drops on the gradient hydrophobic layer 2, and the liquid drops can spontaneously move to a 155 mu J area which is close to a cold end due to the gradient nano corrugated structure on the gradient hydrophobic layer 2, so that the liquid drops can quickly drop on the lower plate 4 at the cold end.
On the upper surface of the lower plate (4), the hydrophilic areas with different gradients, namely a 50 mesh area 301, a 100 mesh area 302, a 150 mesh area 303, a 200 mesh area 304 and a 250 mesh area 305, are utilized to lead the liquid to spontaneously move from a cold end (the 250 mesh area 305 is close to the cold end) to a hot end (the 50 mesh area 301 is close to the hot end), so that the migration speed of the liquid on the lower plate (4) is improved.
The method for manufacturing the soaking plate with high heat dissipation according to claim 1-4, comprising the following steps:
S1, manufacturing a nano corrugated structure of a gradient hydrophobic layer 2 by adopting a femtosecond laser method, fixing a scanning interval to be 50 mu m, enabling a lens focal length to be 200mm, scanning the lower part of an upper plate 1 according to a scanning speed of 0.5mm/S, sequentially selecting pulse energy of the femtosecond laser to be 50 mu J, 80 mu J, 120 mu J and 155 mu J on the upper plate 1, and forming the nano corrugated structure with different depths under the repeated action of different pulses under the condition that the pulse power of the femtosecond pulse laser exceeds an ablation threshold value;
S2, after femtosecond laser processing, placing the mixture into a fluorosilane ethanol solution with the concentration of 1%, standing and soaking for 3 to 5 hours, then taking out the mixture and placing the mixture into a blast drying oven with the temperature of 120 ℃, and standing and cooling the mixture after baking for 4 hours to obtain an upper plate 1 with a gradient hydrophobic layer 2;
S3, firstly, uniformly dividing the upper part of the lower plate 4 into five equal parts of areas, namely a 50-mesh area 301, a 100-mesh area 302, a 150-mesh area 303, a 200-mesh area 304 and a 250-mesh area 305, coating adhesive in the areas, and correspondingly bonding 50-mesh copper powder particles, 100-mesh copper powder particles, 150-mesh copper powder particles, 200-mesh copper powder particles and 250-mesh copper powder particles in the five areas of the 50-mesh area 301, the 100-mesh area 302, the 150-mesh area 303, the 200-mesh area 304 and the 250-mesh area 305;
S4, placing the lower plate 4 processed in the step S3 into a tube furnace, firstly raising the temperature in the furnace to 600 ℃ at a speed of 5 ℃ per minute, keeping for 10 minutes to remove the adhesive, then heating to 850 ℃ at the same speed, preserving heat for 2 hours, and continuously introducing nitrogen to isolate oxygen in the whole sintering process;
S5, placing the sintered lower plate 4 in the step S4 into an electroplating device for electroplating treatment, wherein the electroplating liquid of the electroplating device is preferably a mixed liquid composed of 0.8mol/L CuSO 4、1.5mol/L H2SO4 and 0.2mol/L HCl, the electroplating time is 40min, the current density is 0.4mA/mm 2, in an electroplating bath of the electroplating device, a copper sheet is used as an anode, the sintered lower plate 4 is used as a cathode, and electrolytic copper simple substances are attached to the sintered lower plate 4 to form a gradient hydrophilic layer 3 with a nano-particle structure on the surface;
S6, the upper plate 1 and the lower plate 4 manufactured through the step S2 and the step S4 are aligned and welded together through the connecting parts of the upper plate 1 and the lower plate, the gradient hydrophobic layer 2 on the lower surface of the upper plate 1 and the gradient hydrophilic layer 3 on the upper surface of the lower plate 4 are opposite, and a gap is reserved between the gradient hydrophobic layer 2 and the gradient hydrophilic layer 3.
The working principle is that heat generated by the operation of a processor is conducted to the evaporation end of a soaking plate, an internal working medium absorbs the heat and generates gasification to become steam, at the moment, the upper plate 1 forms a gradient nanoscale corrugated hydrophobic structure after being processed by femtosecond laser, liquid drops of the upper plate 1 quickly reach a cold end and quickly fall due to the Laplacian force formed by internal air pressure and a wall surface, the liquid drops formed by the upper plate 1 can fall onto a gradient hydrophilic layer 3 of the lower plate 2, which is constructed by a sintering electroplating technology, and liquid at the cold end can quickly flow to a hot end under the capillary action of the inner wall of a cavity, and evaporation and heat absorption are performed again.
Claims (5)
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| CN202211198297.8A CN115565972B (en) | 2022-09-29 | 2022-09-29 | A heat spreader with high efficiency in heat dissipation and a method for manufacturing the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103687455A (en) * | 2013-12-31 | 2014-03-26 | 上海交通大学 | A vacuum chamber vapor chamber |
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| CN103398613B (en) * | 2013-07-22 | 2016-01-20 | 施金城 | Vapor chamber and manufacturing method thereof |
| CN114025562B (en) * | 2021-10-27 | 2024-04-26 | 中国科学院工程热物理研究所 | Soaking plate with gradient liquid suction core structure and preparation method thereof |
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