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CN116230761B - Two-dimensional reconfigurable transistor, preparation method thereof and regulation and control method - Google Patents

Two-dimensional reconfigurable transistor, preparation method thereof and regulation and control method Download PDF

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CN116230761B
CN116230761B CN202310174874.8A CN202310174874A CN116230761B CN 116230761 B CN116230761 B CN 116230761B CN 202310174874 A CN202310174874 A CN 202310174874A CN 116230761 B CN116230761 B CN 116230761B
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dielectric layer
electrode
bottom gate
gate dielectric
gate electrode
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CN116230761A (en
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张跃
卫孝福
张铮
张先坤
于慧慧
高丽
洪孟羽
陈匡磊
尚金森
都娴
罗雨欣
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University of Science and Technology Beijing USTB
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D12/00Bipolar devices controlled by the field effect, e.g. insulated-gate bipolar transistors [IGBT]
    • H10D12/01Manufacture or treatment
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D64/00Electrodes of devices having potential barriers
    • H10D64/20Electrodes characterised by their shapes, relative sizes or dispositions 
    • H10D64/27Electrodes not carrying the current to be rectified, amplified, oscillated or switched, e.g. gates
    • H10D64/311Gate electrodes for field-effect devices
    • H10D64/411Gate electrodes for field-effect devices for FETs

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  • Junction Field-Effect Transistors (AREA)

Abstract

The invention provides a two-dimensional reconfigurable transistor and a preparation method and a regulation method thereof, wherein the transistor comprises an insulating substrate, a source electrode, a bottom gate dielectric layer, a two-dimensional semiconductor layer, a top gate dielectric layer, a drain electrode and a top gate electrode; the source electrode and the bottom gate electrode are positioned above the insulating substrate, the bottom gate dielectric layer covers the bottom gate electrode, the two-dimensional semiconductor layer is positioned above the bottom gate dielectric layer and is in contact with the source electrode, the top gate dielectric layer covers the two-dimensional semiconductor layer, the drain electrode is in contact with the two-dimensional semiconductor layer, and the top gate electrode is positioned above the top gate dielectric layer and is not in contact with the drain electrode. When the two-dimensional reconfigurable transistor regulated by the vertical double grid voltage is applied to a future integrated circuit, a large number of transistors can be saved under the same calculation force condition, the occupied area of the integrated circuit is reduced, the cost of the integrated circuit and the whole energy consumption are reduced, and the development requirements of applications such as artificial intelligence, the Internet of things and the like in the future are met.

Description

一种二维可重构晶体管及其制备方法、调控方法A two-dimensional reconfigurable transistor and its preparation method and control method

技术领域Technical Field

本发明涉及二维半导体材料技术领域,尤其涉及一种二维可重构晶体管及其制备方法、调控方法。The present invention relates to the technical field of two-dimensional semiconductor materials, and in particular to a two-dimensional reconfigurable transistor and a preparation method and a control method thereof.

背景技术Background technique

随着人工智能、大数据、边缘计算等新兴电子应用产业的蓬勃发展,对信息高效处理的需求愈发迫切,可以显著提高电子元件利用率的可重构技术提供了可能的解决方案。然而,由于传统硅基场效应晶体管一旦制备成功只能具备单一的电学特性(N型/P型),其场效应特性再也无法通过电学操作实现动态转换,需要耗费大量的晶体管资源构建复杂的电路结构,才能获得可重构的高效计算能力,增加了电路的整体占用面积与功耗。因此,亟需开发全新的可重构技术减少功能模块必要的晶体管数量并实现更高效的计算能力。With the vigorous development of emerging electronic application industries such as artificial intelligence, big data, and edge computing, the demand for efficient information processing has become more urgent. Reconfigurable technology that can significantly improve the utilization rate of electronic components provides a possible solution. However, since traditional silicon-based field-effect transistors can only have a single electrical characteristic (N-type/P-type) once successfully prepared, their field-effect characteristics can no longer be dynamically converted through electrical operations. A large amount of transistor resources are required to build a complex circuit structure in order to obtain reconfigurable and efficient computing capabilities, which increases the overall footprint and power consumption of the circuit. Therefore, it is urgent to develop new reconfigurable technologies to reduce the number of transistors required for functional modules and achieve more efficient computing capabilities.

二维半导体材料由于其带隙可调性、原子级厚度和无悬挂键的特征使得它成为后摩尔时代被寄予厚望的基础电子材料之一。与传统方案不同的是,二维材料具备独特的上下双表面沟道分层输运特性,即可以通过在单个晶体管的沟道上下两个表面同时施加栅极控制电压,实现“一个人干两个人的活”,减少功能电路冗余,提高晶体管的利用效率,实现更高的集成密度。此外,二维材料独特的双极性场效应特性和栅极电压可控的极性改变特性,使得单个二维晶体管在电压操作下实现多种开关特性,展现了其在可重构技术领域的应用潜力,采用这种可重构晶体管集成的功能电路可以进一步减少冗余的晶体管数量。然而,目前还没有通过垂直双栅极电压操作获得二维可重构晶体管的相关报道。Two-dimensional semiconductor materials have become one of the most anticipated basic electronic materials in the post-Moore era due to their adjustable band gap, atomic-level thickness and no dangling bonds. Unlike traditional solutions, two-dimensional materials have unique upper and lower dual-surface channel layered transport characteristics, that is, by applying gate control voltage on the upper and lower surfaces of the channel of a single transistor at the same time, "one person does the work of two people", reducing functional circuit redundancy, improving transistor utilization efficiency, and achieving higher integration density. In addition, the unique bipolar field effect characteristics of two-dimensional materials and the controllable polarity change characteristics of gate voltage enable a single two-dimensional transistor to achieve a variety of switching characteristics under voltage operation, demonstrating its application potential in the field of reconfigurable technology. The functional circuit integrated with this reconfigurable transistor can further reduce the number of redundant transistors. However, there is currently no report on obtaining a two-dimensional reconfigurable transistor through vertical dual gate voltage operation.

发明内容Summary of the invention

为解决上述技术问题,本发明提出了一种二维可重构晶体管及其制备方法、调控方法,通过上下双栅极独立控制源极接触和漏极接触极性,获得P型场效应晶体管、N型场效应晶体管、正偏二极管、反偏二极管等多种开关特性。本发明提供的制备方法避免了化学掺杂,物理掺杂,缺陷调控等手段带来的材料极性不稳定的问题,提出一种简便可行,无损可逆的高面积效率可重构晶体管构筑新途径。In order to solve the above technical problems, the present invention proposes a two-dimensional reconfigurable transistor and a preparation method and a control method thereof, which independently controls the source contact and drain contact polarity through the upper and lower double gates to obtain a variety of switching characteristics such as P-type field effect transistors, N-type field effect transistors, forward-biased diodes, and reverse-biased diodes. The preparation method provided by the present invention avoids the problem of unstable material polarity caused by chemical doping, physical doping, defect control and other means, and proposes a simple, feasible, lossless and reversible new way to construct a high-area efficiency reconfigurable transistor.

为实现上述目的,本发明提供了一种二维可重构晶体管,包括:To achieve the above object, the present invention provides a two-dimensional reconfigurable transistor, comprising:

绝缘衬底、源极、底栅电极、底栅介电层、二维半导体层、顶栅介电层、漏极和顶栅电极;其中,所述源极和所述底栅电极位于所述绝缘衬底上方,所述底栅介电层覆盖所述底栅电极且不与所述源极接触,所述二维半导体层位于所述底栅介电层上方并与所述源极接触,所述顶栅介电层覆盖所述二维半导体层,所述漏极与所述二维半导体层接触,所述顶栅电极位于所述顶栅介电层上方且不与漏极接触。An insulating substrate, a source, a bottom gate electrode, a bottom gate dielectric layer, a two-dimensional semiconductor layer, a top gate dielectric layer, a drain and a top gate electrode; wherein the source and the bottom gate electrode are located above the insulating substrate, the bottom gate dielectric layer covers the bottom gate electrode and is not in contact with the source, the two-dimensional semiconductor layer is located above the bottom gate dielectric layer and is in contact with the source, the top gate dielectric layer covers the two-dimensional semiconductor layer, the drain is in contact with the two-dimensional semiconductor layer, and the top gate electrode is located above the top gate dielectric layer and is not in contact with the drain.

优选地,所述二维半导体层采用具有双极性场效应特性的二维层状材料,所述二维半导体层厚度为2-10nm。Preferably, the two-dimensional semiconductor layer is made of a two-dimensional layered material having bipolar field effect characteristics, and the thickness of the two-dimensional semiconductor layer is 2-10 nm.

优选地,所述绝缘衬底为带有氧化层的硅片、柔性绝缘PET或蓝宝石基底。Preferably, the insulating substrate is a silicon wafer with an oxide layer, a flexible insulating PET or a sapphire substrate.

优选地,所述源极、底栅电极、漏极和顶栅电极的材料包括金属电极材料、二维半金属材料,厚度为20-50nm,所述底栅介电层和所述顶栅介电层的材料采用二维层状氮化硼、氧化硅、氧化铝或氧化铪,厚度为20-40nm。Preferably, the materials of the source, bottom gate electrode, drain and top gate electrode include metal electrode materials, two-dimensional semi-metal materials, with a thickness of 20-50nm, and the materials of the bottom gate dielectric layer and the top gate dielectric layer are two-dimensional layered boron nitride, silicon oxide, aluminum oxide or hafnium oxide, with a thickness of 20-40nm.

为了实现上述目的,本发明还提供了二维可重构晶体管的制备方法,包括:In order to achieve the above object, the present invention also provides a method for preparing a two-dimensional reconfigurable transistor, comprising:

基于绝缘衬底沉积源极和底栅电极;Depositing source and bottom gate electrodes based on an insulating substrate;

在所述底栅电极上沉积底栅介电层,完成全部覆盖;Depositing a bottom gate dielectric layer on the bottom gate electrode to achieve full coverage;

将二维半导体层置于所述底栅介电层上方,并与所述源极直接接触;Placing a two-dimensional semiconductor layer above the bottom gate dielectric layer and in direct contact with the source electrode;

在所述二维半导体层上方沉积顶栅介电层进行局部覆盖;Depositing a top gate dielectric layer on the two-dimensional semiconductor layer for partial coverage;

在所述顶栅介电层上方沉积顶栅电极,在未覆盖所述顶栅介电层的二维半导体层上方沉积漏极,完成垂直双栅电极调控的二维可重构晶体管的制备。A top gate electrode is deposited on the top gate dielectric layer, and a drain electrode is deposited on the two-dimensional semiconductor layer not covering the top gate dielectric layer, thereby completing the preparation of a two-dimensional reconfigurable transistor controlled by vertical dual gate electrodes.

优选地,进行所述沉积的过程包括:Preferably, the process of performing the deposition comprises:

利用电子束曝光工艺或紫外曝光工艺进行图案化处理,再利用热蒸镀工艺完成沉积。The patterning process is performed using an electron beam exposure process or an ultraviolet exposure process, and then the deposition is completed using a thermal evaporation process.

优选地,基于原子沉积工艺对介电层进行所述全部覆盖或所述局部覆盖。Preferably, the entire covering or the partial covering of the dielectric layer is performed based on an atomic deposition process.

优选地,将所述二维半导体层置于所述底栅介电层上方时采用干法转移工艺。Preferably, a dry transfer process is used when placing the two-dimensional semiconductor layer above the bottom gate dielectric layer.

为了实现上述目的,本发明还提供了二维可重构晶体管的调控方法,包括:In order to achieve the above object, the present invention also provides a control method for a two-dimensional reconfigurable transistor, comprising:

二维可重构晶体管运行时,漏极为施加电压端提供偏压,源极接地,则栅电极的组合方式包括:底栅电极和顶栅电极均施加正电压、底栅电极和顶栅电极均施加负电压、底栅电极施加正电压和顶栅电极施加负电压、底栅电极施加负电压和顶栅电极施加正电压;When the two-dimensional reconfigurable transistor is in operation, the drain provides a bias voltage to the voltage application terminal, and the source is grounded, then the combination of gate electrodes includes: applying a positive voltage to both the bottom gate electrode and the top gate electrode, applying a negative voltage to both the bottom gate electrode and the top gate electrode, applying a positive voltage to the bottom gate electrode and a negative voltage to the top gate electrode, and applying a negative voltage to the bottom gate electrode and a positive voltage to the top gate electrode;

当所述漏极施加正电压时,电子从所述源极流向漏极、空穴从所述漏极流向所述源极;当源极施加负电压时,电子从所述漏极流向所述源极、空穴从所述源极流向所述漏极;When a positive voltage is applied to the drain, electrons flow from the source to the drain and holes flow from the drain to the source; when a negative voltage is applied to the source, electrons flow from the drain to the source and holes flow from the source to the drain;

若所述底栅电极施加正电压,所述漏极则为N型接触,阻碍空穴传输;若所述底栅电极施加负电压,所述漏极则表现为P型接触,阻碍电子传输;If a positive voltage is applied to the bottom gate electrode, the drain electrode becomes an N-type contact, which hinders hole transmission; if a negative voltage is applied to the bottom gate electrode, the drain electrode becomes a P-type contact, which hinders electron transmission;

若所述顶栅电极施加正电压,所述源极则表现为N型接触;若所述顶栅电极施加负电压,所述源极则表现为P型接触。If a positive voltage is applied to the top gate electrode, the source electrode behaves as an N-type contact; if a negative voltage is applied to the top gate electrode, the source electrode behaves as a P-type contact.

与现有技术相比,本发明具有如下优点和技术效果:Compared with the prior art, the present invention has the following advantages and technical effects:

本发明垂直双栅极电压调控的二维可重构晶体管应用于未来集成电路时,同等算力条件下,可以节省大量的晶体管,减少集成电路占用面积,降低集成电路成本和整体的能耗,满足未来人工智能、物联网等应用的发展需求;When the two-dimensional reconfigurable transistor with vertical dual-gate voltage control of the present invention is applied to future integrated circuits, under the same computing power conditions, a large number of transistors can be saved, the area occupied by the integrated circuit can be reduced, the cost of the integrated circuit and the overall energy consumption can be reduced, and the development needs of future artificial intelligence, the Internet of Things and other applications can be met;

本发明申请的垂直双栅极电压调控的二维可重构晶体管的调控方式为全新架构的数字电路提供了新的设计方案,实现‘一个人干多个人的活’,可以大幅减少晶体管资源的消耗,有利于未来电子产品的微型化;The control method of the vertical dual-gate voltage-controlled two-dimensional reconfigurable transistor applied in the present invention provides a new design scheme for digital circuits of a new architecture, realizing "one person doing the work of multiple people", which can greatly reduce the consumption of transistor resources and is conducive to the miniaturization of future electronic products;

本发明提供的制备方法与现有半导体技术兼容,具有普适性。The preparation method provided by the present invention is compatible with existing semiconductor technology and has universal applicability.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

构成本申请的一部分的附图用来提供对本申请的进一步理解,本申请的示意性实施例及其说明用于解释本申请,并不构成对本申请的不当限定。在附图中:The drawings constituting a part of the present application are used to provide a further understanding of the present application. The illustrative embodiments and descriptions of the present application are used to explain the present application and do not constitute an improper limitation on the present application. In the drawings:

图1为本发明实施例的垂直双栅极电压调控的二维可重构晶体管结构示意图;FIG1 is a schematic diagram of a two-dimensional reconfigurable transistor structure with vertical dual-gate voltage control according to an embodiment of the present invention;

图2为本发明实施例的底栅电极和顶栅电极均施加正电压时,在正负偏压条件下,源漏极金属与二硒化钨沟道材料接触的能带示意图;2 is a schematic diagram of energy bands of source and drain metals in contact with tungsten diselenide channel materials under positive and negative bias conditions when positive voltages are applied to both the bottom gate electrode and the top gate electrode of an embodiment of the present invention;

图3为本发明实施例的底栅电极和顶栅电极均施加负电压时,在正负偏压条件下,源漏极金属与二硒化钨沟道材料接触的能带示意图;3 is a schematic diagram of energy bands of source and drain metals in contact with tungsten diselenide channel materials under positive and negative bias conditions when negative voltages are applied to both the bottom gate electrode and the top gate electrode of an embodiment of the present invention;

图4为本发明实施例的底栅电极施加正电压和顶栅电极施加负电压时,在正负偏压条件下,源漏极金属与二硒化钨沟道材料接触的能带示意图;4 is a schematic diagram of energy bands of source and drain metals in contact with tungsten diselenide channel materials under positive and negative bias conditions when a positive voltage is applied to the bottom gate electrode and a negative voltage is applied to the top gate electrode according to an embodiment of the present invention;

图5为本发明实施例的底栅电极施加负电压和顶栅电极施加正电压时,在正负偏压条件下,源漏极金属与二硒化钨沟道材料接触的能带示意图;5 is a schematic diagram of energy bands of source and drain metals in contact with tungsten diselenide channel materials under positive and negative bias conditions when a negative voltage is applied to the bottom gate electrode and a positive voltage is applied to the top gate electrode according to an embodiment of the present invention;

图6为本发明实施例的底栅电极与顶栅电极施加的电压均为正、均为负、一正一负、一负一正四种组合下的伏安特性曲线;6 is a volt-ampere characteristic curve of the embodiment of the present invention under four combinations of voltages applied to the bottom gate electrode and the top gate electrode: both are positive, both are negative, one is positive and the other is negative, and one is negative and the other is positive;

其中,1、绝缘衬底,2、源极,3、二维半导体层,4、顶栅介电层,5、顶栅电极,6、漏极,7、底栅介电层,8、底栅电极。Among them, 1. insulating substrate, 2. source, 3. two-dimensional semiconductor layer, 4. top gate dielectric layer, 5. top gate electrode, 6. drain, 7. bottom gate dielectric layer, 8. bottom gate electrode.

具体实施方式Detailed ways

需要说明的是,在不冲突的情况下,本申请中的实施例及实施例中的特征可以相互组合。下面将参考附图并结合实施例来详细说明本申请。It should be noted that, in the absence of conflict, the embodiments and features in the embodiments of the present application can be combined with each other. The present application will be described in detail below with reference to the accompanying drawings and in combination with the embodiments.

需要说明的是,在附图的流程图示出的步骤可以在诸如一组计算机可执行指令的计算机系统中执行,并且,虽然在流程图中示出了逻辑顺序,但是在某些情况下,可以以不同于此处的顺序执行所示出或描述的步骤。It should be noted that the steps shown in the flowcharts of the accompanying drawings can be executed in a computer system such as a set of computer executable instructions, and that, although a logical order is shown in the flowcharts, in some cases, the steps shown or described can be executed in an order different from that shown here.

本发明二维可重构晶体管的结构示意图见图1,其中,1为绝缘衬底,2为源极,3为二维半导体层,4为顶栅介电层,5为顶栅电极,6为漏极,7为底栅介电层,8为底栅电极。The structural schematic diagram of the two-dimensional reconfigurable transistor of the present invention is shown in Figure 1, wherein 1 is an insulating substrate, 2 is a source, 3 is a two-dimensional semiconductor layer, 4 is a top gate dielectric layer, 5 is a top gate electrode, 6 is a drain, 7 is a bottom gate dielectric layer, and 8 is a bottom gate electrode.

源极2和底栅电极8位于绝缘衬底1上方,所述底栅介电层7仅完全覆盖底栅电极8,所述底栅介电层7为“L”形结构,其长边分别与所述二维半导体层3、底栅电极8接触,且长边短于二维半导体层3,其短边分别与源极2、底栅电极8接触;二维半导体层3位于所述底栅介电层7上方并与源极2形成接触,所述顶栅介电层4局部覆盖二维半导体层3且空留出漏极接触区域,所述漏极6与二维半导体层3形成接触,所述顶栅电极5位于顶栅介电层4上方且与漏极6不接触,顶栅介电层4为“L”形结构,其长边分别与顶栅电极5、二维半导体层3接触,短边分别与顶栅电极5、漏极6接触。值得注意的是,顶栅电极5不参与调控漏极接触区域、底栅电极8不参与调控源极极接触区域。The source 2 and the bottom gate electrode 8 are located above the insulating substrate 1, the bottom gate dielectric layer 7 only completely covers the bottom gate electrode 8, the bottom gate dielectric layer 7 is an "L"-shaped structure, the long sides of which are in contact with the two-dimensional semiconductor layer 3 and the bottom gate electrode 8 respectively, and the long sides are shorter than the two-dimensional semiconductor layer 3, and the short sides of which are in contact with the source 2 and the bottom gate electrode 8 respectively; the two-dimensional semiconductor layer 3 is located above the bottom gate dielectric layer 7 and is in contact with the source 2, the top gate dielectric layer 4 partially covers the two-dimensional semiconductor layer 3 and leaves a drain contact area, the drain 6 is in contact with the two-dimensional semiconductor layer 3, the top gate electrode 5 is located above the top gate dielectric layer 4 and is not in contact with the drain 6, the top gate dielectric layer 4 is an "L"-shaped structure, the long sides of which are in contact with the top gate electrode 5 and the two-dimensional semiconductor layer 3 respectively, and the short sides are in contact with the top gate electrode 5 and the drain 6 respectively. It is worth noting that the top gate electrode 5 does not participate in regulating the drain contact area, and the bottom gate electrode 8 does not participate in regulating the source contact area.

本实施例提供一种垂直双栅极电压调控的二硒化钨可重构晶体管,其具体制备步骤如下:This embodiment provides a vertical dual-gate voltage-controlled tungsten diselenide reconfigurable transistor, and the specific preparation steps are as follows:

(1)源极2和底栅电极8的预沉积:在绝缘衬底1上旋涂一层PMMA胶体并180℃烘干1min,利用电子束曝光技术进行图案化处理,并通过热蒸镀工艺沉积金属电极,电极材料为纯金,完成源极和底栅电极的预沉积,厚度为30nm;(1) Pre-deposition of source electrode 2 and bottom gate electrode 8: a layer of PMMA colloid is spin-coated on insulating substrate 1 and dried at 180°C for 1 min. Electron beam exposure technology is used for patterning, and metal electrodes are deposited by thermal evaporation process. The electrode material is pure gold. Pre-deposition of source electrode and bottom gate electrode is completed. The thickness is 30 nm.

(2)底栅介电层7的沉积:在带有源极2和底栅电极8衬底上旋涂PMMA胶体并180℃烘干1min,利用电子束套刻技术进行图案化处理,并通过原子层沉积工艺生长底栅介电层7,实现底栅电极8的全部覆盖,且保证源极2暴露在外,介电层材料为氧化铪,底栅介电层7的厚度为25nm;(2) Deposition of bottom gate dielectric layer 7: spin-coat PMMA colloid on the substrate with source 2 and bottom gate electrode 8 and dry at 180° C. for 1 min, perform patterning using electron beam overlay technology, and grow bottom gate dielectric layer 7 using atomic layer deposition process to achieve full coverage of bottom gate electrode 8 and ensure that source 2 is exposed. The dielectric layer material is hafnium oxide, and the thickness of bottom gate dielectric layer 7 is 25 nm.

(3)利用机械剥离法制备少层二硒化钨纳米片:将3M蓝膜胶带粘在二硒化钨晶体上,缓慢撕下,这时胶带上残留较厚的多层二硒化钨样品,随后轻轻对折2-3次减薄二硒化钨样品的厚度,得到二硒化钼样品母带,然后将减薄后的二硒化钨母带轻轻按压在硅片上,缓慢揭开,使少层二硒化钨纳米片留在硅片上,多次重复上一步操作,即可获得不同厚度的氮化硼纳米片,本实施例选用的二硒化钨样品厚度为3nm;(3) Preparing a few-layer tungsten diselenide nanosheet by mechanical stripping: stick 3M blue film tape on the tungsten diselenide crystal and slowly tear it off. At this time, a thick multi-layer tungsten diselenide sample remains on the tape. Then, gently fold it in half 2-3 times to thin the thickness of the tungsten diselenide sample to obtain a molybdenum diselenide sample master tape. Then, gently press the thinned tungsten diselenide master tape on the silicon wafer and slowly peel it off to leave a few-layer tungsten diselenide nanosheet on the silicon wafer. Repeat the previous step many times to obtain boron nitride nanosheets of different thicknesses. The thickness of the tungsten diselenide sample selected in this embodiment is 3nm;

(4)二维半导体层3的组装:在带有少层二硒化钨样品的硅片上旋涂PPC胶体,100℃烘干1min形成厚度为500nm的PPC膜,借助3M胶带将带有二硒化钨样品的PPC薄膜从硅片上慢慢揭下来,并固定到带有PDMS的定制载物板上,最后,利用精确转移平台将PPC薄膜上的二硒化钨样品精准堆垛于底栅介电层7上表面并与源极2形成接触,完成二维半导体层3的组装;(4) Assembly of the two-dimensional semiconductor layer 3: Spin-coat PPC colloid on a silicon wafer with a few layers of tungsten diselenide sample, dry at 100°C for 1 min to form a PPC film with a thickness of 500 nm, slowly peel off the PPC film with the tungsten diselenide sample from the silicon wafer with the help of 3M tape, and fix it to a customized carrier plate with PDMS. Finally, use a precise transfer platform to accurately stack the tungsten diselenide sample on the PPC film on the upper surface of the bottom gate dielectric layer 7 and form contact with the source electrode 2, completing the assembly of the two-dimensional semiconductor layer 3;

(5)顶栅介电层4的沉积:采用与步骤(2)同样的原子层沉积工艺在二维半导体层3上表面生长顶栅介电层4并预留出漏极6与二维半导体层3的接触区域,完成局部覆盖,介电层材料为氧化铪,厚度为25nm;(5) Deposition of the top gate dielectric layer 4: The top gate dielectric layer 4 is grown on the upper surface of the two-dimensional semiconductor layer 3 by the same atomic layer deposition process as in step (2) and a contact area between the drain electrode 6 and the two-dimensional semiconductor layer 3 is reserved to complete partial coverage. The dielectric layer material is hafnium oxide and has a thickness of 25 nm.

(6)沉积顶栅电极5和漏极6:采用与步骤(1)同样的工艺在顶栅介电层上表面沉积底栅电极5,在二维半导体层3上方预留的漏极接触区域位置沉积漏极6,电极材料均为纯金,厚度为30nm,最终完成垂直双栅极电压控制的二硒化钨可重构晶体管的制备。(6) Deposition of top gate electrode 5 and drain electrode 6: The bottom gate electrode 5 is deposited on the upper surface of the top gate dielectric layer using the same process as step (1), and the drain electrode 6 is deposited at the reserved drain contact area above the two-dimensional semiconductor layer 3. The electrode materials are all pure gold with a thickness of 30 nm, and finally the preparation of a vertical dual-gate voltage-controlled tungsten diselenide reconfigurable transistor is completed.

本实施例提供的器件在运行时,漏极6连接电压源施加偏压,源极2始终接地;底栅电极8和顶栅电极5接两个独立的电压源施加栅极电压分别控制漏极和源极接触极性,包括以下具体调控方式:When the device provided in this embodiment is in operation, the drain 6 is connected to a voltage source to apply a bias voltage, and the source 2 is always grounded; the bottom gate electrode 8 and the top gate electrode 5 are connected to two independent voltage sources to apply gate voltages to control the contact polarities of the drain and source, respectively, including the following specific control methods:

(1)漏极施加正偏压时,电子从源极流向漏极、空穴从漏极流向源极,漏极金属的费米能级相对于源极金属向下移动;漏极施加负偏压时,电子从漏极流向源极、空穴从源极流向漏极,漏极金属的费米能级相对于源极金属向上移动;(1) When a positive bias is applied to the drain, electrons flow from the source to the drain and holes flow from the drain to the source, and the Fermi level of the drain metal moves downward relative to the source metal; when a negative bias is applied to the drain, electrons flow from the drain to the source and holes flow from the source to the drain, and the Fermi level of the drain metal moves upward relative to the source metal;

(2)图2为底栅电极和顶栅电极均施加正电压时,器件在正负偏压下源漏极金属与二硒化钨沟道材料接触的能带示意图;(2) FIG. 2 is a schematic diagram of the energy bands of the device in contact between the source and drain metals and the tungsten diselenide channel material under positive and negative bias when positive voltages are applied to both the bottom gate electrode and the top gate electrode;

当底栅电极与顶栅电极均施加正电压时,源极和漏极均表现为N型接触,即在正向静电场作用下,电子积累促使二硒化钨沟道材料的费米能级靠近导带,减小电子势垒,增加空穴势垒,利于电子的传输,阻碍空穴的传输;When positive voltage is applied to both the bottom gate electrode and the top gate electrode, the source and drain electrodes both show N-type contact, that is, under the action of the positive electrostatic field, the electron accumulation causes the Fermi level of the tungsten diselenide channel material to approach the conduction band, reducing the electron potential barrier and increasing the hole potential barrier, which is beneficial to the transmission of electrons and hinders the transmission of holes.

(3)图3为底栅电极和顶栅电极均施加负电压时,器件在正负偏压下源漏极金属与二硒化钨沟道材料接触的能带示意图;(3) FIG. 3 is a schematic diagram of the energy bands of the device in contact between the source and drain metals and the tungsten diselenide channel material under positive and negative bias when negative voltages are applied to both the bottom gate electrode and the top gate electrode;

当底栅电极与顶栅电极均施加负电压时,源极和漏极均表现为P型接触,即在负向静电场作用下,空穴积累促使二硒化钨沟道材料的费米能级靠近价带,减小空穴势垒,增加电子势垒,利于空穴的传输,阻碍电子的传输;When negative voltage is applied to both the bottom gate electrode and the top gate electrode, the source and drain electrodes both show P-type contact, that is, under the action of the negative electrostatic field, the accumulation of holes causes the Fermi level of the tungsten diselenide channel material to approach the valence band, reducing the hole barrier and increasing the electron barrier, which is beneficial to the transmission of holes and hinders the transmission of electrons.

(4)图4为底栅电极施加正电压和顶栅电极施加负电压时,器件在正负偏压下源漏极金属与二硒化钨沟道材料接触的能带示意图;(4) FIG. 4 is a schematic diagram of the energy bands of the device in contact with the source and drain metals and the tungsten diselenide channel material under positive and negative bias when a positive voltage is applied to the bottom gate electrode and a negative voltage is applied to the top gate electrode;

当底栅电极施加正电压时,漏极表现为N型接触,即在正向静电场作用下,电子积累促使二硒化钨沟道材料的费米能级靠近价带,减小电子势垒,增加空穴势垒,利于空穴的传输,阻碍电子的传输;顶栅电极施加负电压时,源极表现为P型接触,即在负向静电场作用下,空穴积累促使二硒化钨沟道材料的费米能级靠近价带,减小空穴势垒,增加电子势垒,利于空穴的传输,阻碍电子的传输;When a positive voltage is applied to the bottom gate electrode, the drain electrode exhibits an N-type contact, that is, under the action of a positive electrostatic field, the accumulation of electrons causes the Fermi energy level of the tungsten diselenide channel material to approach the valence band, reducing the electron potential barrier, increasing the hole potential barrier, facilitating the transmission of holes and hindering the transmission of electrons; when a negative voltage is applied to the top gate electrode, the source electrode exhibits a P-type contact, that is, under the action of a negative electrostatic field, the accumulation of holes causes the Fermi energy level of the tungsten diselenide channel material to approach the valence band, reducing the hole potential barrier, increasing the electron potential barrier, facilitating the transmission of holes and hindering the transmission of electrons;

(5)图5为底栅电极施加负电压和顶栅电极施加正电压时,器件在正负偏压下源漏极金属与二硒化钨沟道材料接触的能带示意图;(5) FIG. 5 is a schematic diagram of the energy bands of the device in contact between the source and drain metals and the tungsten diselenide channel material under positive and negative bias when a negative voltage is applied to the bottom gate electrode and a positive voltage is applied to the top gate electrode;

当底栅电极施加负电压时,漏极表现为P型接触,即在负向静电场作用下,空穴积累促使二硒化钨沟道材料的费米能级靠近价带,减小空穴势垒,增加电子势垒,利于空穴的传输,阻碍电子的传输;顶栅电极施加正电压时,源极表现为N型接触,即在正向静电场作用下,电子积累促使二硒化钨沟道材料的费米能级靠近价带,减小电子势垒,增加空穴势垒,利于空穴的传输,阻碍电子的传输。When a negative voltage is applied to the bottom gate electrode, the drain exhibits a P-type contact, that is, under the action of a negative electrostatic field, hole accumulation causes the Fermi level of the tungsten diselenide channel material to approach the valence band, reducing the hole potential barrier, increasing the electron potential barrier, facilitating the transmission of holes and hindering the transmission of electrons; when a positive voltage is applied to the top gate electrode, the source exhibits an N-type contact, that is, under the action of a positive electrostatic field, electron accumulation causes the Fermi level of the tungsten diselenide channel material to approach the valence band, reducing the electron potential barrier, increasing the hole potential barrier, facilitating the transmission of holes and hindering the transmission of electrons.

(6)图6为器件在底栅电极与顶栅电极施加的电压均为正、均为负、一正一负、一负一正四种组合下的输出特性曲线,展现出四种不同的开关特性;(6) FIG. 6 shows output characteristic curves of the device under four combinations of voltages applied to the bottom gate electrode and the top gate electrode: both are positive, both are negative, one is positive and the other is negative, and one is negative and the other is positive, showing four different switching characteristics;

依据图2-图5的分析,底栅电极和顶栅电极均施加正电压时,器件在正负偏压下均以电子为多数载流子导通,表现为N型晶体管开关特性;底栅电极和顶栅电极均施加负电压时,正负偏压下均以空穴为多数载流子导通,表现为P型晶体管开关特性;底栅电极施加正电压、顶栅电极施加负电压时,器件正向不导通,负向以空穴为多数载流子导通,表现为反偏二极管开关特性;底栅电极施加负电压、顶栅电极施加正电压时,器件正向以电子为多数载流子导通,负向不导通,表现为正偏二极管开关特性。According to the analysis of Figures 2 to 5, when positive voltages are applied to both the bottom gate electrode and the top gate electrode, the device conducts with electrons as the majority carriers under both positive and negative biases, exhibiting the switching characteristics of an N-type transistor; when negative voltages are applied to both the bottom gate electrode and the top gate electrode, the device conducts with holes as the majority carriers under both positive and negative biases, exhibiting the switching characteristics of a P-type transistor; when a positive voltage is applied to the bottom gate electrode and a negative voltage is applied to the top gate electrode, the device does not conduct in the forward direction, and conducts in the negative direction with holes as the majority carriers, exhibiting the switching characteristics of a reverse-biased diode; when a negative voltage is applied to the bottom gate electrode and a positive voltage is applied to the top gate electrode, the device conducts in the forward direction with electrons as the majority carriers, and does not conduct in the negative direction, exhibiting the switching characteristics of a forward-biased diode.

以上,仅为本申请较佳的具体实施方式,但本申请的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本申请揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本申请的保护范围之内。因此,本申请的保护范围应该以权利要求的保护范围为准。The above are only preferred specific implementations of the present application, but the protection scope of the present application is not limited thereto. Any changes or substitutions that can be easily thought of by any technician familiar with the technical field within the technical scope disclosed in the present application should be included in the protection scope of the present application. Therefore, the protection scope of the present application should be based on the protection scope of the claims.

Claims (9)

1. A two-dimensional reconfigurable transistor, comprising:
An insulating substrate (1), a source electrode (2), a bottom gate electrode (8), a bottom gate dielectric layer (7), a two-dimensional semiconductor layer (3), a top gate dielectric layer (4), a drain electrode (6) and a top gate electrode (5); the source electrode (2) and the bottom gate electrode (8) are located above the insulating substrate (1), the bottom gate dielectric layer (7) only completely covers the bottom gate electrode (8), the bottom gate dielectric layer (7) is of an L-shaped structure, the long sides of the bottom gate dielectric layer (7) are respectively contacted with the two-dimensional semiconductor layer (3) and the bottom gate electrode (8), the long sides of the bottom gate dielectric layer (7) are shorter than the two-dimensional semiconductor layer (3), the short sides of the bottom gate dielectric layer (7) are respectively contacted with the source electrode (2) and the bottom gate electrode (8), the two-dimensional semiconductor layer (3) is located above the bottom gate dielectric layer (7) and is contacted with the source electrode (2), the top gate dielectric layer (4) covers the two-dimensional semiconductor layer (3), the drain electrode (6) is contacted with the two-dimensional semiconductor layer (3), and the top gate electrode (5) is located above the top gate dielectric layer (4) and is not contacted with the drain electrode (6); the top gate dielectric layer (4) is of an L-shaped structure, the long side of the top gate dielectric layer (4) is respectively contacted with the top gate electrode (5) and the two-dimensional semiconductor layer (3), the short side of the top gate dielectric layer (4) is respectively contacted with the top gate electrode (5) and the drain electrode (6), the top gate electrode (5) does not participate in regulating and controlling a drain electrode contact area, and the bottom gate electrode (8) does not participate in regulating and controlling a source electrode contact area.
2. The two-dimensional reconfigurable transistor according to claim 1, characterized in that the two-dimensional semiconductor layer (3) is a two-dimensional layered material having bipolar field effect characteristics, the two-dimensional semiconductor layer (3) having a thickness of 2-10nm.
3. The two-dimensional reconfigurable transistor according to claim 1, characterized in that the insulating substrate (1) is a silicon wafer with an oxide layer, a flexible insulating PET or a sapphire substrate.
4. The two-dimensional reconfigurable transistor according to claim 1, wherein the materials of the source electrode (2), the bottom gate electrode (8), the drain electrode (6) and the top gate electrode (5) comprise a metal electrode material, a two-dimensional semi-metal material, and have a thickness of 20-50nm, and the materials of the bottom gate dielectric layer (7) and the top gate dielectric layer (4) adopt two-dimensional layered boron nitride, silicon oxide, aluminum oxide or hafnium oxide, and have a thickness of 20-40nm.
5. A method of fabricating a two-dimensional reconfigurable transistor, comprising:
Depositing a source electrode (2) and a bottom gate electrode (8) on the basis of an insulating substrate (1);
Depositing a bottom gate dielectric layer (7) on the bottom gate electrode (8) to complete the whole coverage;
-placing a two-dimensional semiconductor layer (3) over the bottom gate dielectric layer (7) and in direct contact with the source electrode (2);
Depositing a top gate dielectric layer (4) over the two-dimensional semiconductor layer (3) for partial coverage;
a top gate electrode (5) is deposited above the top gate dielectric layer (4), and a drain electrode (6) is deposited above the two-dimensional semiconductor layer (3) which is not covered by the top gate dielectric layer (4), so that the preparation of the two-dimensional reconfigurable transistor regulated and controlled by the vertical double gate electrode is completed;
The source electrode (2) and the bottom gate electrode (8) are positioned above the insulating substrate (1), the bottom gate dielectric layer (7) only completely covers the bottom gate electrode (8), the bottom gate dielectric layer (7) is of an L-shaped structure, the long sides of the bottom gate dielectric layer (7) are respectively contacted with the two-dimensional semiconductor layer (3) and the bottom gate electrode (8), the long sides of the bottom gate dielectric layer are shorter than the two-dimensional semiconductor layer (3), and the short sides of the bottom gate dielectric layer (7) are respectively contacted with the source electrode (2) and the bottom gate electrode (8); the two-dimensional semiconductor layer (3) is located above the bottom gate dielectric layer (7) and is in contact with the source electrode (2), the top gate dielectric layer (4) partially covers the two-dimensional semiconductor layer (3) and leaves a drain electrode contact area, the drain electrode (6) is in contact with the two-dimensional semiconductor layer (3), the top gate electrode (5) is located above the top gate dielectric layer (4) and is not in contact with the drain electrode (6), the top gate dielectric layer (4) is of an L-shaped structure, long sides of the top gate dielectric layer (4) are respectively in contact with the top gate electrode (5) and the two-dimensional semiconductor layer (3), short sides of the top gate dielectric layer are respectively in contact with the top gate electrode (5) and the drain electrode (6), the top gate electrode (5) does not participate in regulating the drain electrode contact area, and the bottom gate electrode (8) does not participate in regulating the source electrode contact area.
6. The method of claim 5, wherein performing the deposition comprises:
Patterning treatment is carried out by using an electron beam exposure process or an ultraviolet exposure process, and then deposition is completed by using a thermal evaporation process.
7. The method of manufacturing a two-dimensional reconfigurable transistor according to claim 5, wherein the total or partial coverage of the dielectric layer is performed based on an atomic deposition process.
8. The method of manufacturing a two-dimensional reconfigurable transistor according to claim 5, characterized in that a dry transfer process is used when the two-dimensional semiconductor layer (3) is placed over the bottom gate dielectric layer (7).
9. A method for controlling a two-dimensional reconfigurable transistor, applicable to the two-dimensional reconfigurable transistor according to any one of claims 1 to 4, comprising:
when the two-dimensional reconfigurable transistor operates, the drain electrode (6) provides bias voltage for the voltage application end, the source electrode (2) is grounded, and the combination mode of the gate electrode comprises the following steps: the bottom gate electrode (8) and the top gate electrode (5) apply positive voltages, the bottom gate electrode (8) and the top gate electrode (5) apply negative voltages, the bottom gate electrode (8) applies positive voltages and the top gate electrode (5) applies negative voltages, the bottom gate electrode (8) applies negative voltages and the top gate electrode (5) applies positive voltages;
when a positive voltage is applied to the drain electrode (6), electrons flow from the source electrode (2) to the drain electrode (6), and holes flow from the drain electrode (6) to the source electrode (2); when the drain electrode (6) applies a negative voltage, electrons flow from the drain electrode (6) to the source electrode (2), and holes flow from the source electrode (2) to the drain electrode (6);
if positive voltage is applied to the bottom gate electrode (8), the drain electrode (6) is in N-type contact, so that hole transmission is blocked; if the bottom gate electrode (8) is applied with a negative voltage, the drain electrode (6) is in P-type contact, and electron transmission is blocked;
if the top gate electrode (5) is applied with a positive voltage, the source electrode (2) is in N-type contact; if the top gate electrode (5) applies a negative voltage, the source (2) will appear as a P-type contact;
The source electrode (2) and the bottom gate electrode (8) are positioned above the insulating substrate (1), the bottom gate dielectric layer (7) only completely covers the bottom gate electrode (8), the bottom gate dielectric layer (7) is of an L-shaped structure, the long sides of the bottom gate dielectric layer (7) are respectively contacted with the two-dimensional semiconductor layer (3) and the bottom gate electrode (8), the long sides of the bottom gate dielectric layer are shorter than the two-dimensional semiconductor layer (3), and the short sides of the bottom gate dielectric layer (7) are respectively contacted with the source electrode (2) and the bottom gate electrode (8); the two-dimensional semiconductor layer (3) is located above the bottom gate dielectric layer (7) and is in contact with the source electrode (2), the top gate dielectric layer (4) partially covers the two-dimensional semiconductor layer (3) and leaves a drain electrode contact area, the drain electrode (6) is in contact with the two-dimensional semiconductor layer (3), the top gate electrode (5) is located above the top gate dielectric layer (4) and is not in contact with the drain electrode (6), the top gate dielectric layer (4) is of an L-shaped structure, long sides of the top gate dielectric layer (4) are respectively in contact with the top gate electrode (5) and the two-dimensional semiconductor layer (3), short sides of the top gate dielectric layer are respectively in contact with the top gate electrode (5) and the drain electrode (6), the top gate electrode (5) does not participate in regulating the drain electrode contact area, and the bottom gate electrode (8) does not participate in regulating the source electrode contact area.
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