CN116773762B - Heterogeneous catalytic wastewater treatment monitoring system and method - Google Patents
Heterogeneous catalytic wastewater treatment monitoring system and method Download PDFInfo
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Abstract
Description
技术领域Technical field
本发明涉及环保废水处理监测技术领域,更具体地说,本发明涉及一种多相催化废水处理监测系统及方法。The present invention relates to the technical field of environmentally friendly wastewater treatment and monitoring. More specifically, the invention relates to a heterogeneous catalytic wastewater treatment monitoring system and method.
背景技术Background technique
目前,随着工业农业生产及生活的发展,水环境中难降解有机污染物和新型污染物的种类含量日趋多样化,废水污染状况也越来越复杂,给环保废水处理领域带来新的技术问题和挑战;常规废水处理工艺过程统通常以去除水中悬浮及胶体污染物为主,对难降解有机污染物的去除能力十分有限;因此,多相催化氧化在多样化及复杂的废水处理过程中的应用前景越来越重要;多相催化不但可以去除水中悬浮及胶体污染物,还能够全面去除难降解有机污染物,而且不会引入其它有毒有害的化学药剂,催化剂可一次性填装,在废水处理过程中具有非常广泛的技术优势;但是现阶段,废水处理的多相催化过程监测及水质实时监测仍待提高;多相催化废水处理的催化过程监测的精准性仍待改进,具体问题包括:如何检测分离膜表面修饰多相催化纳米粒子原位生成过程、如何检测多相催化废水处理过程水质、如何分析多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间的关系、如何预测判定废水处理最终水质进行废水处理过程调节及水质智能判定实时监测等问题尚待解决;因此,有必要提出一种多相催化废水处理监测系统及方法,以至少部分地解决现有技术中存在的问题。At present, with the development of industrial, agricultural production and life, the types and contents of refractory organic pollutants and new pollutants in the water environment are becoming increasingly diversified, and the wastewater pollution situation is becoming more and more complex, bringing new technologies to the field of environmentally friendly wastewater treatment. Problems and challenges; Conventional wastewater treatment processes usually focus on removing suspended and colloidal pollutants in water, and their ability to remove refractory organic pollutants is very limited; therefore, heterogeneous catalytic oxidation plays an important role in diverse and complex wastewater treatment processes. Its application prospects are becoming more and more important; heterogeneous catalysis can not only remove suspended and colloidal pollutants in water, but also comprehensively remove refractory organic pollutants without introducing other toxic and harmful chemicals. The catalyst can be filled in one time. There are very extensive technical advantages in the wastewater treatment process; however, at this stage, the monitoring of the heterogeneous catalytic process of wastewater treatment and the real-time monitoring of water quality still need to be improved; the accuracy of the monitoring of the catalytic process of heterogeneous catalytic wastewater treatment still needs to be improved. Specific problems include : How to detect the in-situ generation process of separation membrane surface-modified heterogeneous catalytic nanoparticles, how to detect the water quality of heterogeneous catalytic wastewater treatment process, how to analyze the water quality data of heterogeneous catalytic wastewater treatment process and the in-situ generation process parameters of separation membrane heterogeneous catalytic nanoparticles The relationship between the two, how to predict and determine the final water quality of wastewater treatment, adjust the wastewater treatment process, and intelligently determine the real-time monitoring of water quality have yet to be solved; therefore, it is necessary to propose a heterogeneous catalytic wastewater treatment monitoring system and method to at least partially Solve the problems existing in the existing technology.
发明内容Contents of the invention
在发明内容部分中引入了一系列简化形式的概念,这将在具体实施方式部分中进一步详细说明;本发明的发明内容部分并不意味着要试图限定出所要求保护的技术方案的关键特征和必要技术特征,更不意味着试图确定所要求保护的技术方案的保护范围。The summary of the invention introduces a series of concepts in simplified form, which will be further described in detail in the detailed description of the invention; the summary of the invention is not meant to attempt to define the key features and essential features of the claimed technical solution. technical features, let alone an attempt to determine the scope of protection of the claimed technical solution.
为至少部分地解决上述问题,本发明提供了一种多相催化废水处理监测系统,包括:In order to at least partially solve the above problems, the present invention provides a heterogeneous catalytic wastewater treatment monitoring system, including:
纳米粒子多相催化检测分系统,用于检测分离膜表面修饰多相催化纳米粒子原位生成过程,获取分离膜多相催化纳米粒子原位生成过程参数;Nanoparticle heterogeneous catalytic detection subsystem is used to detect the in-situ generation process of separation membrane surface-modified heterogeneous catalytic nanoparticles and obtain the in-situ generation process parameters of separation membrane heterogeneous catalytic nanoparticles;
多相催化废水处理检测分系统,用于根据分离膜多相催化纳米粒子原位生成过程参数,实时检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据;The multiphase catalytic wastewater treatment detection subsystem is used to detect the water quality of the multiphase catalytic wastewater treatment process in real time based on the in-situ generation process parameters of the separation membrane multiphase catalytic nanoparticles, and obtain the water quality data of the multiphase catalytic wastewater treatment process;
检测数据分析分系统,用于分析多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间的关系,并利用废水处理水质与多相催化关系对神经网络进行训练,获取废水处理多相催化关系模型;The detection data analysis subsystem is used to analyze the relationship between the water quality data of the heterogeneous catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane heterogeneous catalytic nanoparticles, and use the relationship between wastewater treatment water quality and heterogeneous catalysis to train the neural network , obtain the heterogeneous catalytic relationship model for wastewater treatment;
智能判定实时监测分系统,用于根据废水处理多相催化关系模型,智能预测判定多相催化废水处理最终水质,调整多相催化废水处理过程,进行废水处理过程的水质智能判定实时监测。The intelligent judgment and real-time monitoring subsystem is used to intelligently predict and judge the final water quality of multiphase catalytic wastewater treatment based on the multiphase catalytic relationship model of wastewater treatment, adjust the multiphase catalytic wastewater treatment process, and perform intelligent judgment and real-time monitoring of water quality in the wastewater treatment process.
优选的,纳米粒子多相催化检测分系统包括:Preferably, the nanoparticle heterogeneous catalytic detection subsystem includes:
分离膜检测子系统,用于检测基础分离膜基础参数,获取分离膜基础检测参数;The separation membrane detection subsystem is used to detect the basic parameters of the basic separation membrane and obtain the basic detection parameters of the separation membrane;
修饰过程检测子系统,用于根据分离膜基础检测参数,对基础分离膜进行表面修饰,检测分离膜表面修饰参数;The modification process detection subsystem is used to perform surface modification on the basic separation membrane based on the basic detection parameters of the separation membrane and detect the surface modification parameters of the separation membrane;
纳米粒子原位生成检测子系统,用于根据分离膜表面修饰参数,进行多相催化纳米粒子原位生成,并检测分离膜表面修饰多相催化纳米粒子原位生成过程参数,获取分离膜多相催化纳米粒子原位生成过程参数。The in-situ generation and detection subsystem of nanoparticles is used to generate in-situ heterogeneous catalytic nanoparticles based on the surface modification parameters of the separation membrane, and detect the in-situ generation process parameters of the surface-modified heterogeneous catalytic nanoparticles of the separation membrane to obtain the multi-phase properties of the separation membrane. Process parameters for in situ generation of catalytic nanoparticles.
优选的,多相催化废水处理检测分系统包括:Preferably, the heterogeneous catalytic wastewater treatment detection subsystem includes:
分离膜多相催化采样子系统,用于在废水处理过程中,对分离膜多相催化纳米粒子进行实时少量采样,并根据采样量自动加入预设比例蒸馏水稀释混合,定量移液至待检测混悬容器,获取定量待检测混悬液样品;The separation membrane heterogeneous catalytic sampling subsystem is used to sample a small amount of the separation membrane heterogeneous catalytic nanoparticles in real time during the wastewater treatment process, and automatically adds a preset proportion of distilled water to dilute and mix according to the sampling amount, and quantitatively pipettes the liquid into the mixture to be detected. Suspension container to obtain a quantitative suspension sample to be tested;
混悬液样品分型子系统,用于根据废水经验模型,将定量待检测混悬液样品进行待检测分型,获取待检测混悬液样品分型;The suspension sample classification subsystem is used to classify the quantitative suspension samples to be tested based on the wastewater empirical model to obtain the suspension sample classification to be tested;
废水处理过程水质检测子系统,用于根据待检测混悬液样品分型,对定量待检测混悬液样品进行水质检测,检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据。The wastewater treatment process water quality detection subsystem is used to conduct water quality detection on quantitative suspension samples to be detected based on the classification of the suspension samples to be detected, detect the water quality of the multiphase catalytic wastewater treatment process, and obtain water quality data of the multiphase catalytic wastewater treatment process. .
优选的,检测数据分析分系统包括:Preferably, the detection data analysis subsystem includes:
过程水质参照标准子系统,用于通过历史废水处理数据统计废水处理过程水质参照标准,获取废水处理过程水质参照标准数据;The process water quality reference standard subsystem is used to calculate the water quality reference standard of the wastewater treatment process through historical wastewater treatment data and obtain the water quality reference standard data of the wastewater treatment process;
处理催化数据训练子系统,用于根据废水处理过程水质参照标准数据,分离膜多相催化纳米粒子原位生成过程参数数据作为输入,将多相催化废水处理过程水质数据作为输出,对废水处理多相催化关系数据通过神经网络进行数据训练,获取废水处理多相催化关系数据神经网络训练结果;The processing catalytic data training subsystem is used to use the reference standard data of water quality in the wastewater treatment process, the parameter data of the in-situ generation process of the separation membrane multi-phase catalytic nanoparticles as input, and the water quality data of the multi-phase catalytic wastewater treatment process as the output. The phase catalysis relationship data is trained through neural network to obtain the neural network training results of wastewater treatment multi-phase catalysis relationship data;
废水处理多相催化模型子系统,用于分析废水处理多相催化关系数据神经网络训练结果,直至废水处理多相催化关系数据神经网络训练结果稳定于废水处理过程水质参照标准数据的设定参照对比范围,获取废水处理多相催化关系模型。The wastewater treatment heterogeneous catalysis model subsystem is used to analyze the wastewater treatment heterogeneous catalysis relationship data neural network training results until the wastewater treatment heterogeneous catalysis relationship data neural network training results stabilize at the setting reference comparison of the wastewater treatment process water quality reference standard data. Scope, obtain the heterogeneous catalytic relationship model for wastewater treatment.
优选的,智能判定实时监测分系统包括:Preferably, the intelligent judgment real-time monitoring subsystem includes:
最终水质结果预测子系统,用于根据废水处理多相催化关系模型,预测废水处理最终水质结果,获取废水处理最终水质预测信息;The final water quality result prediction subsystem is used to predict the final water quality result of wastewater treatment based on the multiphase catalytic relationship model of wastewater treatment, and obtain the final water quality prediction information of wastewater treatment;
最终水质预测判定子系统,用于根据废水处理最终水质预测信息,判定废水处理最终水质预测是否符合废水处理最终水质标准,获取废水处理最终水质预测判定结果;The final water quality prediction and determination subsystem is used to determine whether the final water quality prediction of wastewater treatment meets the final water quality standard of wastewater treatment based on the final water quality prediction information of wastewater treatment, and obtain the final water quality prediction and determination result of wastewater treatment;
智能判定实时监测子系统,用于根据废水处理最终水质预测判定结果,调整多相催化废水处理过程,进行废水处理过程的水质智能判定实时监测。The intelligent determination real-time monitoring subsystem is used to adjust the multi-phase catalytic wastewater treatment process based on the final water quality prediction and determination results of wastewater treatment, and perform real-time monitoring of the intelligent determination of water quality in the wastewater treatment process.
本发明提供了一种多相催化废水处理监测方法,包括:The invention provides a heterogeneous catalytic wastewater treatment monitoring method, which includes:
S100,检测分离膜表面修饰多相催化纳米粒子原位生成过程,获取分离膜多相催化纳米粒子原位生成过程参数;S100, detect the in-situ generation process of the separation membrane surface-modified heterogeneous catalytic nanoparticles, and obtain the in-situ generation process parameters of the separation membrane multi-phase catalytic nanoparticles;
S200,根据分离膜多相催化纳米粒子原位生成过程参数,实时检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据;S200, based on the in-situ generation process parameters of multi-phase catalytic nanoparticles of the separation membrane, detects the water quality of the multi-phase catalytic wastewater treatment process in real time, and obtains the water quality data of the multi-phase catalytic waste water treatment process;
S300,分析多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间的关系,并利用废水处理水质与多相催化关系对神经网络进行训练,获取废水处理多相催化关系模型;S300, analyze the relationship between the water quality data of the heterogeneous catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane heterogeneous catalytic nanoparticles, and use the relationship between wastewater treatment water quality and heterogeneous catalysis to train the neural network to obtain the multiphase wastewater treatment Catalytic relationship model;
S400,根据废水处理多相催化关系模型,智能预测判定多相催化废水处理最终水质,调整多相催化废水处理过程,进行废水处理过程的水质智能判定实时监测。S400, based on the multiphase catalytic relationship model of wastewater treatment, intelligently predicts and determines the final water quality of multiphase catalytic wastewater treatment, adjusts the multiphase catalytic wastewater treatment process, and performs real-time monitoring of the intelligent determination of water quality in the wastewater treatment process.
优选的,S100包括:Preferably, S100 includes:
S101,检测基础分离膜基础参数,获取分离膜基础检测参数;S101, detect the basic parameters of the basic separation membrane and obtain the basic detection parameters of the separation membrane;
S102,根据分离膜基础检测参数,对基础分离膜进行表面修饰,检测分离膜表面修饰参数;S102, perform surface modification on the basic separation membrane according to the basic detection parameters of the separation membrane, and detect the surface modification parameters of the separation membrane;
S103,根据分离膜表面修饰参数,进行多相催化纳米粒子原位生成,并检测分离膜表面修饰多相催化纳米粒子原位生成过程参数,获取分离膜多相催化纳米粒子原位生成过程参数。S103, perform in-situ generation of heterogeneous catalytic nanoparticles based on the separation membrane surface modification parameters, and detect the in-situ generation process parameters of the separation membrane surface-modified heterogeneous catalytic nanoparticles to obtain the in-situ generation process parameters of the separation membrane multi-phase catalytic nanoparticles.
优选的,S200包括:Preferably, S200 includes:
S201,在废水处理过程中,对分离膜多相催化纳米粒子进行实时少量采样,并根据采样量自动加入预设比例蒸馏水稀释混合,定量移液至待检测混悬容器,获取定量待检测混悬液样品;S201, during the wastewater treatment process, a small amount of heterogeneous catalytic nanoparticles on the separation membrane are sampled in real time, and a preset proportion of distilled water is added to dilute and mix automatically according to the sampling amount, and the liquid is quantitatively transferred to the suspension container to be detected to obtain a quantitative suspension to be detected. liquid sample;
S202,根据废水经验模型,将定量待检测混悬液样品进行待检测分型,获取待检测混悬液样品分型;S202. According to the wastewater empirical model, classify the quantitative suspension sample to be detected to obtain the classification of the suspension sample to be detected;
S203,根据待检测混悬液样品分型,对定量待检测混悬液样品进行水质检测,检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据。S203. According to the classification of the suspension sample to be detected, perform water quality testing on the quantitative suspension sample to be detected, detect the water quality of the multi-phase catalytic wastewater treatment process, and obtain the water quality data of the multi-phase catalytic wastewater treatment process.
优选的,S300包括:Preferably, S300 includes:
S301,通过历史废水处理数据统计废水处理过程水质参照标准,获取废水处理过程水质参照标准数据;S301, calculate the water quality reference standard of the wastewater treatment process through historical wastewater treatment data, and obtain the water quality reference standard data of the wastewater treatment process;
S302,根据废水处理过程水质参照标准数据,分离膜多相催化纳米粒子原位生成过程参数数据作为输入,将多相催化废水处理过程水质数据作为输出,对废水处理多相催化关系数据通过神经网络进行数据训练,获取废水处理多相催化关系数据神经网络训练结果;S302, according to the water quality reference standard data of the wastewater treatment process, the parameter data of the in-situ generation process of the separation membrane multi-phase catalytic nanoparticles is used as input, the water quality data of the multi-phase catalytic waste water treatment process is used as the output, and the multi-phase catalytic relationship data of the waste water treatment is passed through the neural network Conduct data training to obtain the neural network training results of wastewater treatment heterogeneous catalysis relationship data;
S303,分析废水处理多相催化关系数据神经网络训练结果,直至废水处理多相催化关系数据神经网络训练结果稳定于废水处理过程水质参照标准数据的设定参照对比范围,获取废水处理多相催化关系模型。S303, analyze the neural network training results of the wastewater treatment multiphase catalytic relationship data until the wastewater treatment multiphase catalytic relationship data neural network training results stabilize within the set reference comparison range of the wastewater treatment process water quality reference standard data, and obtain the wastewater treatment multiphase catalytic relationship. Model.
优选的,S400包括:Preferably, S400 includes:
S401,根据废水处理多相催化关系模型,预测废水处理最终水质结果,获取废水处理最终水质预测信息;S401, predict the final water quality results of wastewater treatment based on the multiphase catalytic relationship model of wastewater treatment, and obtain the final water quality prediction information of wastewater treatment;
S402,根据废水处理最终水质预测信息,判定废水处理最终水质预测是否符合废水处理最终水质标准,获取废水处理最终水质预测判定结果;S402, based on the final water quality prediction information of wastewater treatment, determine whether the final water quality prediction of wastewater treatment meets the final water quality standard of wastewater treatment, and obtain the final water quality prediction judgment result of wastewater treatment;
S403,根据废水处理最终水质预测判定结果,调整多相催化废水处理过程,进行废水处理过程的水质智能判定实时监测。S403: Adjust the multiphase catalytic wastewater treatment process according to the final water quality prediction and determination results of wastewater treatment, and perform real-time monitoring of the intelligent water quality determination of the wastewater treatment process.
相比现有技术,本发明至少包括以下有益效果:Compared with the prior art, the present invention at least includes the following beneficial effects:
本发明一种多相催化废水处理监测系统及方法,在废水处理过程中具有明显的技术优势;能够处理废水中多种类污染物,对难降解有机污染物的处理能力大幅提高,可以去除水中悬浮及胶体污染物,能够全面去除难降解有机污染物,对有毒有害的化学成分的检测能力有效提升,催化剂的利用效率显著提高;废水处理的多相催化参数监测的精准性明显改进,可以精确检测分离膜表面修饰多相催化纳米粒子原位生成过程,对于多相催化废水处理过程水质监测的实时性得以解决,多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间关系分析全面性显著提高,使废水处理过程实现创新性智能化数据处理,数据更清晰、准确、未来大规模通用性,可复制大规模应用。The present invention is a multi-phase catalytic wastewater treatment monitoring system and method, which has obvious technical advantages in the wastewater treatment process; it can treat multiple types of pollutants in wastewater, greatly improves the processing capacity of refractory organic pollutants, and can remove suspended matter in the water. and colloidal pollutants, which can comprehensively remove refractory organic pollutants, effectively improve the detection ability of toxic and harmful chemical components, and significantly improve the utilization efficiency of catalysts; the accuracy of monitoring heterogeneous catalytic parameters of wastewater treatment has been significantly improved, and accurate detection can be achieved The in-situ generation process of separation membrane surface-modified heterogeneous catalytic nanoparticles solves the problem of real-time water quality monitoring in the heterogeneous catalytic wastewater treatment process. The water quality data of the heterogeneous catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane heterogeneous catalytic nanoparticles The comprehensiveness of the analysis of the relationship between them has been significantly improved, enabling innovative intelligent data processing in the wastewater treatment process. The data is clearer, more accurate, has large-scale versatility in the future, and can be replicated for large-scale applications.
本发明所述的一种多相催化废水处理监测系统及方法,本发明的其它优点、目标和特征将部分通过下面的说明体现,部分还将通过对本发明的研究和实践而为本领域的技术人员所理解。A heterogeneous catalytic wastewater treatment monitoring system and method according to the present invention. Other advantages, objectives and characteristics of the present invention will be partly reflected by the following description, and partly will also be revealed by the research and practice of the present invention. understood by personnel.
附图说明Description of the drawings
附图用来提供对本发明的进一步理解,并且构成说明书的一部分,与本发明的实施例一起用于解释本发明,并不构成对本发明的限制。在附图中:The drawings are used to provide a further understanding of the present invention and constitute a part of the specification. They are used to explain the present invention together with the embodiments of the present invention and do not constitute a limitation of the present invention. In the attached picture:
图1为本发明实施例中一种多相催化废水处理监测系统框架示意图。Figure 1 is a schematic diagram of the framework of a multi-phase catalytic wastewater treatment monitoring system in an embodiment of the present invention.
图2为本发明实施例中一种多相催化废水处理监测方法步骤示意图。Figure 2 is a schematic diagram of the steps of a heterogeneous catalytic wastewater treatment monitoring method in an embodiment of the present invention.
图3为本发明实施例中一种多相催化废水处理监测方法步骤又一实施例示意图。Figure 3 is a schematic diagram of the steps of a heterogeneous catalytic wastewater treatment monitoring method in another embodiment of the present invention.
具体实施方式Detailed ways
下面结合附图以及实施例对本发明做进一步的详细说明,以令本领域技术人员参照说明书能够据以实施;如图1-图3所示,本发明提供了一种多相催化废水处理监测系统,包括:The present invention will be further described in detail below in conjunction with the accompanying drawings and examples, so that those skilled in the art can implement it with reference to the description; as shown in Figures 1-3, the present invention provides a heterogeneous catalytic wastewater treatment monitoring system ,include:
纳米粒子多相催化检测分系统,用于检测分离膜表面修饰多相催化纳米粒子原位生成过程,获取分离膜多相催化纳米粒子原位生成过程参数;Nanoparticle heterogeneous catalytic detection subsystem is used to detect the in-situ generation process of separation membrane surface-modified heterogeneous catalytic nanoparticles and obtain the in-situ generation process parameters of separation membrane heterogeneous catalytic nanoparticles;
多相催化废水处理检测分系统,用于根据分离膜多相催化纳米粒子原位生成过程参数,实时检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据;The multiphase catalytic wastewater treatment detection subsystem is used to detect the water quality of the multiphase catalytic wastewater treatment process in real time based on the in-situ generation process parameters of the separation membrane multiphase catalytic nanoparticles, and obtain the water quality data of the multiphase catalytic wastewater treatment process;
检测数据分析分系统,用于分析多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间的关系,并利用废水处理水质与多相催化关系对神经网络进行训练,获取废水处理多相催化关系模型;The detection data analysis subsystem is used to analyze the relationship between the water quality data of the heterogeneous catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane heterogeneous catalytic nanoparticles, and use the relationship between wastewater treatment water quality and heterogeneous catalysis to train the neural network , obtain the heterogeneous catalytic relationship model for wastewater treatment;
智能判定实时监测分系统,用于根据废水处理多相催化关系模型,智能预测判定多相催化废水处理最终水质,调整多相催化废水处理过程,进行废水处理过程的水质智能判定实时监测。The intelligent judgment and real-time monitoring subsystem is used to intelligently predict and judge the final water quality of multiphase catalytic wastewater treatment based on the multiphase catalytic relationship model of wastewater treatment, adjust the multiphase catalytic wastewater treatment process, and perform intelligent judgment and real-time monitoring of water quality in the wastewater treatment process.
上述技术方案的原理及效果为:本发明提供了一种多相催化废水处理监测系统,通过检测分离膜表面修饰多相催化纳米粒子原位生成过程,获取分离膜多相催化纳米粒子原位生成过程参数;将基础分离膜浸泡在第一设定浓度及第一氢离子浓度指数的缓冲溶液中,检测第一设定浓度及第一氢离子浓度指数参数;通过第一氧化剂组催化修饰第一预设时间,检测第一氧化剂组成分及第一预设时间;在基础分离膜表面形成聚合层,获取表面聚合层基础分离膜,检测表面聚合层厚度;将表面聚合层基础分离膜浸泡在第二设定浓度金属盐溶液中,检测第二设定浓度金属盐溶液浓度;利用第二还原剂修饰第二预设时间原位生成纳米粒子,检测第二还原剂浓度及第二预设时间;循环上述步骤进行分离膜表面修饰多相催化纳米粒子原位生成,检测分离膜表面修饰多相催化纳米粒子原位生成过程,获取分离膜多相催化纳米粒子原位生成过程参数;通过多相催化废水处理过程中实时检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据;以多相催化废水处理过程水质数据作为第一分析参数,以分离膜多相催化纳米粒子原位生成过程参数作为第二分析参数,分析多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间的关系,并利用废水处理水质与多相催化关系对神经网络进行训练,训练随着多相催化废水处理过程分阶段进行,每个阶段完成作为一个废水处理过程阶段的子模型,并形成废水处理过程水质和多相催化关系的系列模型,获取废水处理多相催化关系模型;根据废水处理多相催化关系模型,在多相催化废水处理过程中,预测多相催化废水处理下一个废水处理过程阶段水质,并依次预测多相催化废水处理每个废水处理过程阶段水质,智能预测判定多相催化废水处理最终水质,调整多相催化废水处理过程,进行废水处理过程的水质智能判定实时监测,多阶段智能预测实时循环精准监测;本发明在废水处理过程中具有明显的技术优势;能够处理废水中多种类污染物,对难降解有机污染物的处理能力大幅提高,可以去除水中悬浮及胶体污染物,能够全面去除难降解有机污染物,对有毒有害的化学成分的检测能力有效提升,催化剂的利用效率显著提高;废水处理的多相催化参数监测的精准性明显改进,可以精确检测分离膜表面修饰多相催化纳米粒子原位生成过程,对于多相催化废水处理过程水质监测的实时性得以解决,多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间关系分析全面性显著提高,使废水处理过程实现创新性智能化数据处理,数据更清晰、准确、未来大规模通用性,可复制大规模应用。The principle and effect of the above technical solution are: the present invention provides a heterogeneous catalytic wastewater treatment monitoring system, which detects the in-situ generation process of the separation membrane surface-modified heterogeneous catalytic nanoparticles, and obtains the in-situ generation of the separation membrane multi-phase catalytic nanoparticles. Process parameters; soak the basic separation membrane in the buffer solution with the first set concentration and the first hydrogen ion concentration index, detect the first set concentration and the first hydrogen ion concentration index parameters; catalytically modify the first set concentration through the first oxidant group Preset time, detect the first oxidant composition and the first preset time; form a polymerization layer on the surface of the basic separation membrane, obtain the surface polymerization layer basic separation membrane, detect the surface polymerization layer thickness; soak the surface polymerization layer basic separation membrane in the third In two set concentration metal salt solutions, detect the concentration of the second set concentration metal salt solution; use the second reducing agent to modify the second preset time to generate nanoparticles in situ, and detect the second reducing agent concentration and the second preset time; Cycle the above steps to perform in-situ generation of separation membrane surface-modified heterogeneous catalytic nanoparticles, detect the in-situ generation process of separation membrane surface-modified heterogeneous catalytic nanoparticles, and obtain the parameters of the in-situ generation process of separation membrane heterogeneous catalytic nanoparticles; through heterogeneous catalysis During the wastewater treatment process, the water quality of the heterogeneous catalytic wastewater treatment process is detected in real time to obtain the water quality data of the heterogeneous catalytic wastewater treatment process; the water quality data of the heterogeneous catalytic wastewater treatment process is used as the first analysis parameter, and the separation membrane is used to generate in-situ multiphase catalytic nanoparticles. The process parameters are used as the second analysis parameters to analyze the relationship between the water quality data of the heterogeneous catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane multiphase catalytic nanoparticles, and use the relationship between wastewater treatment water quality and heterogeneous catalysis to train the neural network , the training is carried out in stages as the heterogeneous catalytic wastewater treatment process is completed. Each stage is completed as a sub-model of a wastewater treatment process stage, and a series of models of the relationship between water quality and heterogeneous catalysis in the wastewater treatment process are formed to obtain the heterogeneous catalytic relationship in wastewater treatment. Model; According to the wastewater treatment heterogeneous catalytic relationship model, in the heterogeneous catalytic wastewater treatment process, the water quality of the next wastewater treatment process stage of the heterogeneous catalytic wastewater treatment is predicted, and the water quality of each wastewater treatment process stage of the heterogeneous catalytic wastewater treatment is predicted in turn, Intelligent prediction determines the final water quality of multi-phase catalytic wastewater treatment, adjusts the multi-phase catalytic wastewater treatment process, carries out real-time monitoring of the intelligent determination of water quality in the wastewater treatment process, and multi-stage intelligent prediction real-time cycle accurate monitoring; the present invention has obvious technology in the wastewater treatment process Advantages: It can handle many types of pollutants in wastewater, and its processing capacity for refractory organic pollutants has been greatly improved. It can remove suspended and colloidal pollutants in water, can comprehensively remove refractory organic pollutants, and has the ability to detect toxic and harmful chemical components. Effectively improved, the utilization efficiency of the catalyst has been significantly improved; the accuracy of heterogeneous catalytic parameter monitoring of wastewater treatment has been significantly improved, and the in-situ generation process of multiphase catalytic nanoparticles modified on the surface of the separation membrane can be accurately detected, which is useful for water quality monitoring in the heterogeneous catalytic wastewater treatment process. The real-time nature of the problem has been solved, and the comprehensive analysis of the relationship between the water quality data of the multiphase catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane multiphase catalytic nanoparticles has been significantly improved, enabling the wastewater treatment process to achieve innovative intelligent data processing, and the data is more accurate. Clear, accurate, future large-scale versatility, can be replicated for large-scale applications.
在一个实施例中,纳米粒子多相催化检测分系统包括:In one embodiment, the nanoparticle heterogeneous catalytic detection subsystem includes:
分离膜检测子系统,用于检测基础分离膜基础参数,获取分离膜基础检测参数;The separation membrane detection subsystem is used to detect the basic parameters of the basic separation membrane and obtain the basic detection parameters of the separation membrane;
修饰过程检测子系统,用于根据分离膜基础检测参数,对基础分离膜进行表面修饰,检测分离膜表面修饰参数;The modification process detection subsystem is used to perform surface modification on the basic separation membrane based on the basic detection parameters of the separation membrane and detect the surface modification parameters of the separation membrane;
纳米粒子原位生成检测子系统,用于根据分离膜表面修饰参数,进行多相催化纳米粒子原位生成,并检测分离膜表面修饰多相催化纳米粒子原位生成过程参数,获取分离膜多相催化纳米粒子原位生成过程参数。The in-situ generation and detection subsystem of nanoparticles is used to generate in-situ heterogeneous catalytic nanoparticles based on the surface modification parameters of the separation membrane, and detect the in-situ generation process parameters of the surface-modified heterogeneous catalytic nanoparticles of the separation membrane to obtain the multi-phase properties of the separation membrane. Process parameters for in situ generation of catalytic nanoparticles.
上述技术方案的原理及效果为:检测基础分离膜基础参数,获取分离膜基础检测参数;分离膜基础参数包括:透过性滲透速率参数和分离性表征参数;分离性表征参数包括:分离脱盐率表征参数、超滤截留率表征参数、气体分离系数表征参数;分离膜基础检测参数包括:透过性滲透速率检测参数和分离性检测参数;分离性检测参数包括:分离脱盐率检测参数、超滤截留率检测参数、气体分离系数检测参数;根据分离膜基础检测参数,对基础分离膜进行表面修饰,检测分离膜表面修饰参数;对基础分离膜进行表面修饰包括:在第一设定浓度及第一氢离子浓度指数的缓冲溶液中浸泡基础分离膜;通过第一氧化剂组催化修饰第一预设时间;在基础分离膜表面形成聚合层,获取表面聚合层基础分离膜;设定第一设定浓度及第一氢离子浓度指数,实时检测第一设定浓度及第一氢离子浓度指数参数;选择第一氧化剂组及第一预设时间,检测第一氧化剂组成分及第一预设时间;检测表面聚合层厚度,检测分离膜表面修饰参数;The principle and effect of the above technical solution are: detect the basic parameters of the basic separation membrane and obtain the basic detection parameters of the separation membrane; the basic parameters of the separation membrane include: permeability permeability rate parameters and separation characterization parameters; the separation characterization parameters include: separation rejection rate Characterization parameters, ultrafiltration rejection rate characterization parameters, gas separation coefficient characterization parameters; separation membrane basic detection parameters include: permeability permeability detection parameters and separation detection parameters; separation detection parameters include: separation rejection rate detection parameters, ultrafiltration Rejection rate detection parameters and gas separation coefficient detection parameters; according to the basic detection parameters of the separation membrane, surface modification is performed on the basic separation membrane, and the surface modification parameters of the separation membrane are detected; surface modification of the basic separation membrane includes: at the first set concentration and the second Soaking the basic separation membrane in a buffer solution with a hydrogen ion concentration index; catalytically modifying the first preset time through the first oxidant group; forming a polymerization layer on the surface of the basic separation membrane to obtain the surface polymerization layer of the basic separation membrane; setting the first setting Concentration and the first hydrogen ion concentration index, detect the first set concentration and the first hydrogen ion concentration index parameters in real time; select the first oxidant group and the first preset time, and detect the components of the first oxidant group and the first preset time; Detect the thickness of the surface polymerization layer and detect the surface modification parameters of the separation membrane;
根据分离膜表面修饰参数,进行多相催化纳米粒子原位生成,将表面聚合层基础分离膜浸泡在第二设定浓度金属盐溶液中;利用第二还原剂修饰第二预设时间原位生成纳米粒子;进行分离膜表面修饰多相催化纳米粒子原位生成;并检测分离膜表面修饰多相催化纳米粒子原位生成过程参数,获取分离膜多相催化纳米粒子原位生成过程参数;设置第二设定浓度金属盐溶液浓度,实时检测第二设定浓度金属盐溶液浓度;选择第二还原剂和第二预设时间,实时检测第二还原剂浓度及第二预设时间;废水处理的多相催化参数监测的精准性明显改进,可以精确检测分离膜表面修饰多相催化纳米粒子原位生成过程。According to the surface modification parameters of the separation membrane, perform in-situ generation of multi-phase catalytic nanoparticles, soak the basic separation membrane of the surface polymerization layer in a second set concentration metal salt solution; use a second reducing agent to modify the second preset time for in-situ generation Nanoparticles; perform in-situ generation of separation membrane surface-modified heterogeneous catalytic nanoparticles; and detect the in-situ generation process parameters of separation membrane surface-modified heterogeneous catalytic nanoparticles to obtain the in-situ generation process parameters of separation membrane multi-phase catalytic nanoparticles; set the Two set concentration metal salt solution concentrations, real-time detection of the second set concentration metal salt solution concentration; select the second reducing agent and the second preset time, real-time detection of the second reducing agent concentration and the second preset time; wastewater treatment The accuracy of heterogeneous catalytic parameter monitoring has been significantly improved, and the in-situ generation process of heterogeneous catalytic nanoparticles modified on the surface of the separation membrane can be accurately detected.
在一个实施例中,多相催化废水处理检测分系统包括:In one embodiment, the heterogeneous catalytic wastewater treatment detection subsystem includes:
分离膜多相催化采样子系统,用于在废水处理过程中,对分离膜多相催化纳米粒子进行实时少量采样,并根据采样量自动加入预设比例蒸馏水稀释混合,定量移液至待检测混悬容器,获取定量待检测混悬液样品;The separation membrane heterogeneous catalytic sampling subsystem is used to sample a small amount of the separation membrane heterogeneous catalytic nanoparticles in real time during the wastewater treatment process, and automatically adds a preset proportion of distilled water to dilute and mix according to the sampling amount, and quantitatively pipettes the liquid into the mixture to be detected. Suspension container to obtain a quantitative suspension sample to be tested;
混悬液样品分型子系统,用于根据废水经验模型,将定量待检测混悬液样品进行待检测分型,获取待检测混悬液样品分型;The suspension sample classification subsystem is used to classify the quantitative suspension samples to be tested based on the wastewater empirical model to obtain the suspension sample classification to be tested;
废水处理过程水质检测子系统,用于根据待检测混悬液样品分型,对定量待检测混悬液样品进行水质检测,检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据。The wastewater treatment process water quality detection subsystem is used to conduct water quality detection on quantitative suspension samples to be detected based on the classification of the suspension samples to be detected, detect the water quality of the multiphase catalytic wastewater treatment process, and obtain water quality data of the multiphase catalytic wastewater treatment process. .
上述技术方案的原理及效果为:对多相催化废水处理过程进行采样、分型及过程水质检测;设定采样量,通过分离膜多相催化采样器,在废水处理过程中,根据采样量对分离膜多相催化纳米粒子进行实时采样,并通过蒸馏水自动定量添加,根据采样量自动加入预设比例蒸馏水稀释混合,通过自动移液器,定量移液至待检测混悬容器,获取定量待检测混悬液样品;通过历史废水实验数据,进行混悬液的经验预估分型,建立废水经验模型;根据废水经验模型,将定量待检测混悬液样品进行待检测分型,获取待检测混悬液样品分型;根据待检测混悬液样品分型,对定量待检测混悬液样品进行水质检测,检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据;对于多相催化废水处理过程水质监测的实时性得以解决。The principle and effect of the above technical solution are: sampling, typing and process water quality testing of the multiphase catalytic wastewater treatment process; setting the sampling volume, through the separation membrane multiphase catalytic sampler, during the wastewater treatment process, according to the sampling volume The separation membrane multi-phase catalytic nanoparticles are sampled in real time, and distilled water is automatically added quantitatively. According to the sampling volume, a preset ratio of distilled water is automatically added for dilution and mixing. Through an automatic pipette, the liquid is quantitatively transferred to the suspension container to be detected, and the quantitative quantity to be detected is obtained. Suspension samples; use historical wastewater experimental data to conduct empirical prediction and classification of suspensions, and establish a wastewater experience model; based on the wastewater experience model, classify quantitative suspension samples to be detected to obtain the mixture to be detected Classification of suspension samples; according to the classification of suspension samples to be tested, water quality testing is performed on quantitative suspension samples to be tested, the water quality of the multi-phase catalytic wastewater treatment process is detected, and the water quality data of the multi-phase catalytic wastewater treatment process is obtained; for multi-phase Real-time monitoring of water quality in the catalytic wastewater treatment process is solved.
在一个实施例中,检测数据分析分系统包括:In one embodiment, the detection data analysis subsystem includes:
过程水质参照标准子系统,用于通过历史废水处理数据统计废水处理过程水质参照标准,获取废水处理过程水质参照标准数据;The process water quality reference standard subsystem is used to calculate the water quality reference standard of the wastewater treatment process through historical wastewater treatment data and obtain the water quality reference standard data of the wastewater treatment process;
处理催化数据训练子系统,用于根据废水处理过程水质参照标准数据,分离膜多相催化纳米粒子原位生成过程参数数据作为输入,将多相催化废水处理过程水质数据作为输出,对废水处理多相催化关系数据通过神经网络进行数据训练,获取废水处理多相催化关系数据神经网络训练结果;The processing catalytic data training subsystem is used to use the reference standard data of water quality in the wastewater treatment process, the parameter data of the in-situ generation process of the separation membrane multi-phase catalytic nanoparticles as input, and the water quality data of the multi-phase catalytic wastewater treatment process as the output. The phase catalysis relationship data is trained through neural network to obtain the neural network training results of wastewater treatment multi-phase catalysis relationship data;
废水处理多相催化模型子系统,用于分析废水处理多相催化关系数据神经网络训练结果,直至废水处理多相催化关系数据神经网络训练结果稳定于废水处理过程水质参照标准数据的设定参照对比范围,获取废水处理多相催化关系模型。The wastewater treatment heterogeneous catalysis model subsystem is used to analyze the wastewater treatment heterogeneous catalysis relationship data neural network training results until the wastewater treatment heterogeneous catalysis relationship data neural network training results stabilize at the setting reference comparison of the wastewater treatment process water quality reference standard data. Scope, obtain the heterogeneous catalytic relationship model for wastewater treatment.
上述技术方案的原理及效果为:利用数据统计历史废水处理过程水质,选择废水处理过程水质最优数据及废水处理过程水质允许差异范围,统计废水处理过程水质参照标准,获取废水处理过程水质参照标准数据;根据废水处理过程水质参照标准数据,分离膜多相催化纳米粒子原位生成过程参数数据作为输入,将多相催化废水处理过程水质数据作为输出,对废水处理多相催化关系数据通过神经网络进行数据训练,获取废水处理多相催化关系数据神经网络训练结果;分析废水处理多相催化关系数据神经网络训练结果,直至废水处理多相催化关系数据神经网络训练结果稳定于废水处理过程水质参照标准数据的设定参照对比范围,获取废水处理多相催化关系模型;多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间关系分析全面性显著提高。The principle and effect of the above technical solution are: use data to count the water quality of the historical wastewater treatment process, select the optimal data of the water quality of the wastewater treatment process and the allowable difference range of the water quality of the wastewater treatment process, count the water quality reference standards of the wastewater treatment process, and obtain the water quality reference standards of the wastewater treatment process. Data; According to the water quality reference standard data of the wastewater treatment process, the parameter data of the in-situ generation process of the separation membrane multi-phase catalytic nanoparticles is used as input, the water quality data of the multi-phase catalytic waste water treatment process is used as the output, and the multi-phase catalytic relationship data of the waste water treatment is passed through the neural network Conduct data training to obtain the neural network training results of wastewater treatment multiphase catalytic relationship data; analyze the wastewater treatment multiphase catalytic relationship data neural network training results until the wastewater treatment multiphase catalytic relationship data neural network training results stabilize within the wastewater treatment process water quality reference standard The data is set with reference to the comparison range to obtain the heterogeneous catalytic relationship model for wastewater treatment; the comprehensive analysis of the relationship between the water quality data of the heterogeneous catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane multiphase catalytic nanoparticles is significantly improved.
在一个实施例中,智能判定实时监测分系统包括:In one embodiment, the intelligent decision real-time monitoring subsystem includes:
最终水质结果预测子系统,用于根据废水处理多相催化关系模型,预测废水处理最终水质结果,获取废水处理最终水质预测信息;The final water quality result prediction subsystem is used to predict the final water quality result of wastewater treatment based on the multiphase catalytic relationship model of wastewater treatment, and obtain the final water quality prediction information of wastewater treatment;
最终水质预测判定子系统,用于根据废水处理最终水质预测信息,判定废水处理最终水质预测是否符合废水处理最终水质标准,获取废水处理最终水质预测判定结果;The final water quality prediction and determination subsystem is used to determine whether the final water quality prediction of wastewater treatment meets the final water quality standard of wastewater treatment based on the final water quality prediction information of wastewater treatment, and obtain the final water quality prediction and determination result of wastewater treatment;
智能判定实时监测子系统,用于根据废水处理最终水质预测判定结果,调整多相催化废水处理过程,进行废水处理过程的水质智能判定实时监测。The intelligent determination real-time monitoring subsystem is used to adjust the multi-phase catalytic wastewater treatment process based on the final water quality prediction and determination results of wastewater treatment, and perform real-time monitoring of the intelligent determination of water quality in the wastewater treatment process.
上述技术方案的原理及效果为:根据废水处理多相催化关系模型利用模型预测废水处理最终水质结果,获取废水处理最终水质预测信息;预设置废水处理最终水质标准,对比判定废水处理最终水质预测是否符合废水处理最终水质标准,获取废水处理最终水质预测判定结果;废水处理最终水质标准通过模型参数预设置;根据获取废水处理最终水质预测判定结果,当废水处理最终水质预测判定结果为废水处理最终水质预测不符合废水处理最终水质标准时,反推并前置调整多相催化废水处理过程,修正废水处理最终水质预测信息,直至废水处理最终水质预测符合废水处理最终水质标准,进行废水处理过程的水质智能判定实时监测;使废水处理过程实现创新性智能化数据处理,数据更清晰、准确、未来大规模通用性。The principle and effect of the above technical solution are: use the model to predict the final water quality results of wastewater treatment based on the multiphase catalytic relationship model of wastewater treatment, and obtain the final water quality prediction information of wastewater treatment; preset the final water quality standard of wastewater treatment, and compare and determine whether the final water quality prediction of wastewater treatment is Comply with the final water quality standard of wastewater treatment, and obtain the final water quality prediction and determination result of wastewater treatment; the final water quality standard of wastewater treatment is preset through the model parameters; according to the final water quality prediction and determination result of wastewater treatment, when the final water quality prediction and determination result of wastewater treatment is the final water quality of wastewater treatment When the prediction does not meet the final water quality standards for wastewater treatment, the multi-phase catalytic wastewater treatment process is reversed and adjusted in advance, and the final water quality prediction information of wastewater treatment is corrected until the final water quality prediction of wastewater treatment meets the final water quality standards for wastewater treatment, and water quality intelligence of the wastewater treatment process is carried out. Determine real-time monitoring; enable innovative intelligent data processing in the wastewater treatment process, making the data clearer, more accurate, and more versatile in the future.
本发明提供了一种多相催化废水处理监测方法,包括:The invention provides a heterogeneous catalytic wastewater treatment monitoring method, which includes:
S100,检测分离膜表面修饰多相催化纳米粒子原位生成过程,获取分离膜多相催化纳米粒子原位生成过程参数;S100, detect the in-situ generation process of the separation membrane surface-modified heterogeneous catalytic nanoparticles, and obtain the in-situ generation process parameters of the separation membrane multi-phase catalytic nanoparticles;
S200,根据分离膜多相催化纳米粒子原位生成过程参数,实时检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据;S200, based on the in-situ generation process parameters of multi-phase catalytic nanoparticles of the separation membrane, detects the water quality of the multi-phase catalytic wastewater treatment process in real time, and obtains the water quality data of the multi-phase catalytic waste water treatment process;
S300,分析多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间的关系,并利用废水处理水质与多相催化关系对神经网络进行训练,获取废水处理多相催化关系模型;S300, analyze the relationship between the water quality data of the heterogeneous catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane heterogeneous catalytic nanoparticles, and use the relationship between wastewater treatment water quality and heterogeneous catalysis to train the neural network to obtain the multiphase wastewater treatment Catalytic relationship model;
S400,根据废水处理多相催化关系模型,智能预测判定多相催化废水处理最终水质,调整多相催化废水处理过程,进行废水处理过程的水质智能判定实时监测。S400, based on the multiphase catalytic relationship model of wastewater treatment, intelligently predicts and determines the final water quality of multiphase catalytic wastewater treatment, adjusts the multiphase catalytic wastewater treatment process, and performs real-time monitoring of the intelligent determination of water quality in the wastewater treatment process.
上述技术方案的原理及效果为:本发明提供了一种多相催化废水处理监测方法,通过检测分离膜表面修饰多相催化纳米粒子原位生成过程,获取分离膜多相催化纳米粒子原位生成过程参数;将基础分离膜浸泡在第一设定浓度及第一氢离子浓度指数的缓冲溶液中,检测第一设定浓度及第一氢离子浓度指数参数;通过第一氧化剂组催化修饰第一预设时间,检测第一氧化剂组成分及第一预设时间;在基础分离膜表面形成聚合层,获取表面聚合层基础分离膜,检测表面聚合层厚度;将表面聚合层基础分离膜浸泡在第二设定浓度金属盐溶液中,检测第二设定浓度金属盐溶液浓度;利用第二还原剂修饰第二预设时间原位生成纳米粒子,检测第二还原剂浓度及第二预设时间;循环上述步骤进行分离膜表面修饰多相催化纳米粒子原位生成,检测分离膜表面修饰多相催化纳米粒子原位生成过程,获取分离膜多相催化纳米粒子原位生成过程参数;通过多相催化废水处理过程中实时检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据;以多相催化废水处理过程水质数据作为第一分析参数,以分离膜多相催化纳米粒子原位生成过程参数作为第二分析参数,分析多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间的关系,并利用废水处理水质与多相催化关系对神经网络进行训练,训练随着多相催化废水处理过程分阶段进行,每个阶段完成作为一个废水处理过程阶段的子模型,并形成废水处理过程水质和多相催化关系的系列模型,获取废水处理多相催化关系模型;根据废水处理多相催化关系模型,在多相催化废水处理过程中,预测多相催化废水处理下一个废水处理过程阶段水质,并依次预测多相催化废水处理每个废水处理过程阶段水质,智能预测判定多相催化废水处理最终水质,调整多相催化废水处理过程,进行废水处理过程的水质智能判定实时监测,多阶段智能预测实时循环精准监测;本发明在废水处理过程中具有明显的技术优势;能够处理废水中多种类污染物,对难降解有机污染物的处理能力大幅提高,可以去除水中悬浮及胶体污染物,能够全面去除难降解有机污染物,对有毒有害的化学成分的检测能力有效提升,催化剂的利用效率显著提高;废水处理的多相催化参数监测的精准性明显改进,可以精确检测分离膜表面修饰多相催化纳米粒子原位生成过程,对于多相催化废水处理过程水质监测的实时性得以解决,多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间关系分析全面性显著提高,使废水处理过程实现创新性智能化数据处理,数据更清晰、准确、未来大规模通用性,可复制大规模应用。The principle and effect of the above technical solution are: the present invention provides a heterogeneous catalytic wastewater treatment monitoring method, which detects the in-situ generation process of the separation membrane surface-modified heterogeneous catalytic nanoparticles, and obtains the in-situ generation of the separation membrane multi-phase catalytic nanoparticles. Process parameters; soak the basic separation membrane in the buffer solution with the first set concentration and the first hydrogen ion concentration index, detect the first set concentration and the first hydrogen ion concentration index parameters; catalytically modify the first set concentration through the first oxidant group Preset time, detect the first oxidant composition and the first preset time; form a polymerization layer on the surface of the basic separation membrane, obtain the surface polymerization layer basic separation membrane, detect the surface polymerization layer thickness; soak the surface polymerization layer basic separation membrane in the third In two set concentration metal salt solutions, detect the concentration of the second set concentration metal salt solution; use the second reducing agent to modify the second preset time to generate nanoparticles in situ, and detect the second reducing agent concentration and the second preset time; Cycle the above steps to perform in-situ generation of separation membrane surface-modified heterogeneous catalytic nanoparticles, detect the in-situ generation process of separation membrane surface-modified heterogeneous catalytic nanoparticles, and obtain the parameters of the in-situ generation process of separation membrane heterogeneous catalytic nanoparticles; through heterogeneous catalysis During the wastewater treatment process, the water quality of the heterogeneous catalytic wastewater treatment process is detected in real time to obtain the water quality data of the heterogeneous catalytic wastewater treatment process; the water quality data of the heterogeneous catalytic wastewater treatment process is used as the first analysis parameter, and the separation membrane is used to generate in-situ multiphase catalytic nanoparticles. The process parameters are used as the second analysis parameters to analyze the relationship between the water quality data of the heterogeneous catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane multiphase catalytic nanoparticles, and use the relationship between wastewater treatment water quality and heterogeneous catalysis to train the neural network , the training is carried out in stages as the heterogeneous catalytic wastewater treatment process is completed. Each stage is completed as a sub-model of a wastewater treatment process stage, and a series of models of the relationship between water quality and heterogeneous catalysis in the wastewater treatment process are formed to obtain the heterogeneous catalytic relationship in wastewater treatment. Model; According to the wastewater treatment heterogeneous catalytic relationship model, in the heterogeneous catalytic wastewater treatment process, the water quality of the next wastewater treatment process stage of the heterogeneous catalytic wastewater treatment is predicted, and the water quality of each wastewater treatment process stage of the heterogeneous catalytic wastewater treatment is predicted in turn, Intelligent prediction determines the final water quality of multi-phase catalytic wastewater treatment, adjusts the multi-phase catalytic wastewater treatment process, performs real-time monitoring of the intelligent determination of water quality in the wastewater treatment process, and multi-stage intelligent prediction real-time cycle accurate monitoring; the present invention has obvious technology in the wastewater treatment process Advantages: It can handle many types of pollutants in wastewater, and its processing capacity for refractory organic pollutants is greatly improved. It can remove suspended and colloidal pollutants in water, it can comprehensively remove refractory organic pollutants, and it has the ability to detect toxic and harmful chemical components. Effectively improved, the utilization efficiency of the catalyst has been significantly improved; the accuracy of heterogeneous catalytic parameter monitoring of wastewater treatment has been significantly improved, and the in-situ generation process of multiphase catalytic nanoparticles modified on the surface of the separation membrane can be accurately detected, which is useful for water quality monitoring in the heterogeneous catalytic wastewater treatment process. The real-time nature of the problem has been solved, and the comprehensive analysis of the relationship between the water quality data of the multiphase catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane multiphase catalytic nanoparticles has been significantly improved, enabling innovative intelligent data processing in the wastewater treatment process, and the data is more accurate. Clear, accurate, future large-scale versatility, can be replicated for large-scale applications.
在一个实施例中,S100包括:In one embodiment, S100 includes:
S101,检测基础分离膜基础参数,获取分离膜基础检测参数;S101, detect the basic parameters of the basic separation membrane and obtain the basic detection parameters of the separation membrane;
S102,根据分离膜基础检测参数,对基础分离膜进行表面修饰,检测分离膜表面修饰参数;S102, perform surface modification on the basic separation membrane according to the basic detection parameters of the separation membrane, and detect the surface modification parameters of the separation membrane;
S103,根据分离膜表面修饰参数,进行多相催化纳米粒子原位生成,并检测分离膜表面修饰多相催化纳米粒子原位生成过程参数,获取分离膜多相催化纳米粒子原位生成过程参数。S103, perform in-situ generation of heterogeneous catalytic nanoparticles based on the separation membrane surface modification parameters, and detect the in-situ generation process parameters of the separation membrane surface-modified heterogeneous catalytic nanoparticles to obtain the in-situ generation process parameters of the separation membrane multi-phase catalytic nanoparticles.
上述技术方案的原理及效果为:检测基础分离膜基础参数,获取分离膜基础检测参数;分离膜基础参数包括:透过性滲透速率参数和分离性表征参数;分离性表征参数包括:分离脱盐率表征参数、超滤截留率表征参数、气体分离系数表征参数;分离膜基础检测参数包括:透过性滲透速率检测参数和分离性检测参数;分离性检测参数包括:分离脱盐率检测参数、超滤截留率检测参数、气体分离系数检测参数;根据分离膜基础检测参数,对基础分离膜进行表面修饰,检测分离膜表面修饰参数;对基础分离膜进行表面修饰包括:在第一设定浓度及第一氢离子浓度指数的缓冲溶液中浸泡基础分离膜;通过第一氧化剂组催化修饰第一预设时间;在基础分离膜表面形成聚合层,获取表面聚合层基础分离膜;设定第一设定浓度及第一氢离子浓度指数,实时检测第一设定浓度及第一氢离子浓度指数参数;选择第一氧化剂组及第一预设时间,检测第一氧化剂组成分及第一预设时间;检测表面聚合层厚度,检测分离膜表面修饰参数;The principle and effect of the above technical solution are: detect the basic parameters of the basic separation membrane and obtain the basic detection parameters of the separation membrane; the basic parameters of the separation membrane include: permeability permeability rate parameters and separation characterization parameters; the separation characterization parameters include: separation rejection rate Characterization parameters, ultrafiltration rejection rate characterization parameters, gas separation coefficient characterization parameters; separation membrane basic detection parameters include: permeability permeability detection parameters and separation detection parameters; separation detection parameters include: separation rejection rate detection parameters, ultrafiltration Rejection rate detection parameters and gas separation coefficient detection parameters; according to the basic detection parameters of the separation membrane, surface modification is performed on the basic separation membrane, and the surface modification parameters of the separation membrane are detected; surface modification of the basic separation membrane includes: at the first set concentration and the second Soaking the basic separation membrane in a buffer solution with a hydrogen ion concentration index; catalytically modifying the first preset time through the first oxidant group; forming a polymerization layer on the surface of the basic separation membrane to obtain the surface polymerization layer of the basic separation membrane; setting the first setting Concentration and the first hydrogen ion concentration index, detect the first set concentration and the first hydrogen ion concentration index parameters in real time; select the first oxidant group and the first preset time, and detect the components of the first oxidant group and the first preset time; Detect the thickness of the surface polymerization layer and detect the surface modification parameters of the separation membrane;
根据分离膜表面修饰参数,进行多相催化纳米粒子原位生成,将表面聚合层基础分离膜浸泡在第二设定浓度金属盐溶液中;利用第二还原剂修饰第二预设时间原位生成纳米粒子;进行分离膜表面修饰多相催化纳米粒子原位生成;并检测分离膜表面修饰多相催化纳米粒子原位生成过程参数,获取分离膜多相催化纳米粒子原位生成过程参数;设置第二设定浓度金属盐溶液浓度,实时检测第二设定浓度金属盐溶液浓度;选择第二还原剂和第二预设时间,实时检测第二还原剂浓度及第二预设时间;废水处理的多相催化参数监测的精准性明显改进,可以精确检测分离膜表面修饰多相催化纳米粒子原位生成过程。According to the surface modification parameters of the separation membrane, perform in-situ generation of multi-phase catalytic nanoparticles, soak the basic separation membrane of the surface polymerization layer in a second set concentration metal salt solution; use a second reducing agent to modify the second preset time for in-situ generation Nanoparticles; perform in-situ generation of separation membrane surface-modified heterogeneous catalytic nanoparticles; and detect the in-situ generation process parameters of separation membrane surface-modified heterogeneous catalytic nanoparticles to obtain the in-situ generation process parameters of separation membrane multi-phase catalytic nanoparticles; set the Two set concentration metal salt solution concentrations, real-time detection of the second set concentration metal salt solution concentration; select the second reducing agent and the second preset time, real-time detection of the second reducing agent concentration and the second preset time; wastewater treatment The accuracy of heterogeneous catalytic parameter monitoring has been significantly improved, and the in-situ generation process of heterogeneous catalytic nanoparticles modified on the surface of the separation membrane can be accurately detected.
在一个实施例中,S200包括:In one embodiment, S200 includes:
S201,在废水处理过程中,对分离膜多相催化纳米粒子进行实时少量采样,并根据采样量自动加入预设比例蒸馏水稀释混合,定量移液至待检测混悬容器,获取定量待检测混悬液样品;S201, during the wastewater treatment process, a small amount of heterogeneous catalytic nanoparticles on the separation membrane are sampled in real time, and a preset proportion of distilled water is added to dilute and mix automatically according to the sampling amount, and the liquid is quantitatively transferred to the suspension container to be detected to obtain a quantitative suspension to be detected. liquid sample;
S202,根据废水经验模型,将定量待检测混悬液样品进行待检测分型,获取待检测混悬液样品分型;S202. According to the wastewater empirical model, classify the quantitative suspension sample to be detected to obtain the classification of the suspension sample to be detected;
S203,根据待检测混悬液样品分型,对定量待检测混悬液样品进行水质检测,检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据。S203. According to the classification of the suspension sample to be detected, perform water quality testing on the quantitative suspension sample to be detected, detect the water quality of the multi-phase catalytic wastewater treatment process, and obtain the water quality data of the multi-phase catalytic wastewater treatment process.
上述技术方案的原理及效果为:对多相催化废水处理过程进行采样、分型及过程水质检测;设定采样量,通过分离膜多相催化采样器,在废水处理过程中,根据采样量对分离膜多相催化纳米粒子进行实时采样,并通过蒸馏水自动定量添加,根据采样量自动加入预设比例蒸馏水稀释混合,通过自动移液器,定量移液至待检测混悬容器,获取定量待检测混悬液样品;通过历史废水实验数据,进行混悬液的经验预估分型,建立废水经验模型;根据废水经验模型,将定量待检测混悬液样品进行待检测分型,获取待检测混悬液样品分型;根据待检测混悬液样品分型,对定量待检测混悬液样品进行水质检测,检测多相催化废水处理过程水质,获取多相催化废水处理过程水质数据;对于多相催化废水处理过程水质监测的实时性得以解决。The principle and effect of the above technical solution are: sampling, typing and process water quality testing of the multiphase catalytic wastewater treatment process; setting the sampling volume, through the separation membrane multiphase catalytic sampler, during the wastewater treatment process, according to the sampling volume The separation membrane multi-phase catalytic nanoparticles are sampled in real time, and distilled water is automatically added quantitatively. According to the sampling volume, a preset ratio of distilled water is automatically added for dilution and mixing. Through an automatic pipette, the liquid is quantitatively transferred to the suspension container to be detected, and the quantitative quantity to be detected is obtained. Suspension samples; use historical wastewater experimental data to conduct empirical prediction and classification of suspensions, and establish a wastewater experience model; based on the wastewater experience model, classify quantitative suspension samples to be detected to obtain the mixture to be detected Classification of suspension samples; according to the classification of suspension samples to be tested, water quality testing is performed on quantitative suspension samples to be tested, the water quality of the multi-phase catalytic wastewater treatment process is detected, and the water quality data of the multi-phase catalytic wastewater treatment process is obtained; for multi-phase Real-time monitoring of water quality in the catalytic wastewater treatment process is solved.
在一个实施例中,S300包括:In one embodiment, S300 includes:
S301,通过历史废水处理数据统计废水处理过程水质参照标准,获取废水处理过程水质参照标准数据;S301, calculate the water quality reference standard of the wastewater treatment process through historical wastewater treatment data, and obtain the water quality reference standard data of the wastewater treatment process;
S302,根据废水处理过程水质参照标准数据,分离膜多相催化纳米粒子原位生成过程参数数据作为输入,将多相催化废水处理过程水质数据作为输出,对废水处理多相催化关系数据通过神经网络进行数据训练,获取废水处理多相催化关系数据神经网络训练结果;S302, according to the water quality reference standard data of the wastewater treatment process, the parameter data of the in-situ generation process of the separation membrane multi-phase catalytic nanoparticles is used as input, the water quality data of the multi-phase catalytic waste water treatment process is used as the output, and the multi-phase catalytic relationship data of the waste water treatment is passed through the neural network Conduct data training to obtain the neural network training results of wastewater treatment heterogeneous catalysis relationship data;
S303,分析废水处理多相催化关系数据神经网络训练结果,直至废水处理多相催化关系数据神经网络训练结果稳定于废水处理过程水质参照标准数据的设定参照对比范围,获取废水处理多相催化关系模型。S303, analyze the neural network training results of the wastewater treatment multiphase catalytic relationship data until the wastewater treatment multiphase catalytic relationship data neural network training results stabilize within the set reference comparison range of the wastewater treatment process water quality reference standard data, and obtain the wastewater treatment multiphase catalytic relationship. Model.
上述技术方案的原理及效果为:利用数据统计历史废水处理过程水质,选择废水处理过程水质最优数据及废水处理过程水质允许差异范围,统计废水处理过程水质参照标准,获取废水处理过程水质参照标准数据;根据废水处理过程水质参照标准数据,分离膜多相催化纳米粒子原位生成过程参数数据作为输入,将多相催化废水处理过程水质数据作为输出,对废水处理多相催化关系数据通过神经网络进行数据训练,获取废水处理多相催化关系数据神经网络训练结果;分析废水处理多相催化关系数据神经网络训练结果,直至废水处理多相催化关系数据神经网络训练结果稳定于废水处理过程水质参照标准数据的设定参照对比范围,获取废水处理多相催化关系模型;多相催化废水处理过程水质数据和分离膜多相催化纳米粒子原位生成过程参数之间关系分析全面性显著提高。The principle and effect of the above technical solution are: use data to count the water quality of the historical wastewater treatment process, select the optimal data of the water quality of the wastewater treatment process and the allowable difference range of the water quality of the wastewater treatment process, count the water quality reference standards of the wastewater treatment process, and obtain the water quality reference standards of the wastewater treatment process. Data; According to the water quality reference standard data of the wastewater treatment process, the parameter data of the in-situ generation process of the separation membrane multi-phase catalytic nanoparticles is used as input, the water quality data of the multi-phase catalytic waste water treatment process is used as the output, and the multi-phase catalytic relationship data of the waste water treatment is passed through the neural network Conduct data training to obtain the neural network training results of wastewater treatment multiphase catalytic relationship data; analyze the wastewater treatment multiphase catalytic relationship data neural network training results until the wastewater treatment multiphase catalytic relationship data neural network training results stabilize within the wastewater treatment process water quality reference standard The data is set with reference to the comparison range to obtain the heterogeneous catalytic relationship model for wastewater treatment; the comprehensive analysis of the relationship between the water quality data of the heterogeneous catalytic wastewater treatment process and the in-situ generation process parameters of the separation membrane multiphase catalytic nanoparticles is significantly improved.
在一个实施例中,S400包括:In one embodiment, S400 includes:
S401,根据废水处理多相催化关系模型,预测废水处理最终水质结果,获取废水处理最终水质预测信息;S401, predict the final water quality results of wastewater treatment based on the multiphase catalytic relationship model of wastewater treatment, and obtain the final water quality prediction information of wastewater treatment;
S402,根据废水处理最终水质预测信息,判定废水处理最终水质预测是否符合废水处理最终水质标准,获取废水处理最终水质预测判定结果;S402, based on the final water quality prediction information of wastewater treatment, determine whether the final water quality prediction of wastewater treatment meets the final water quality standard of wastewater treatment, and obtain the final water quality prediction judgment result of wastewater treatment;
S403,根据废水处理最终水质预测判定结果,调整多相催化废水处理过程,进行废水处理过程的水质智能判定实时监测。S403: Adjust the multiphase catalytic wastewater treatment process according to the final water quality prediction and determination results of wastewater treatment, and perform real-time monitoring of the intelligent water quality determination of the wastewater treatment process.
上述技术方案的原理及效果为:根据废水处理多相催化关系模型利用模型预测废水处理最终水质结果,获取废水处理最终水质预测信息;预设置废水处理最终水质标准,对比判定废水处理最终水质预测是否符合废水处理最终水质标准,获取废水处理最终水质预测判定结果;废水处理最终水质标准通过模型参数预设置;根据获取废水处理最终水质预测判定结果,当废水处理最终水质预测判定结果为废水处理最终水质预测不符合废水处理最终水质标准时,反推并前置调整多相催化废水处理过程,修正废水处理最终水质预测信息,直至废水处理最终水质预测符合废水处理最终水质标准,进行废水处理过程的水质智能判定实时监测;使废水处理过程实现创新性智能化数据处理,数据更清晰、准确、未来大规模通用性。The principle and effect of the above technical solution are: use the model to predict the final water quality results of wastewater treatment based on the multiphase catalytic relationship model of wastewater treatment, and obtain the final water quality prediction information of wastewater treatment; preset the final water quality standard of wastewater treatment, and compare and determine whether the final water quality prediction of wastewater treatment is Comply with the final water quality standard of wastewater treatment, and obtain the final water quality prediction and determination result of wastewater treatment; the final water quality standard of wastewater treatment is preset through the model parameters; according to the final water quality prediction and determination result of wastewater treatment, when the final water quality prediction and determination result of wastewater treatment is the final water quality of wastewater treatment When the prediction does not meet the final water quality standards for wastewater treatment, the multi-phase catalytic wastewater treatment process is reversed and adjusted in advance, and the final water quality prediction information of wastewater treatment is corrected until the final water quality prediction of wastewater treatment meets the final water quality standards for wastewater treatment, and water quality intelligence of the wastewater treatment process is carried out. Determine real-time monitoring; enable innovative intelligent data processing in the wastewater treatment process, making the data clearer, more accurate, and more versatile in the future.
尽管本发明的实施方案已公开如上,但其并不仅仅限于说明书和实施方式中所列运用,它完全可以被适用于各种适合本发明的领域,对于熟悉本领域的人员而言,可容易地实现另外的修改,因此在不背离权利要求及等同范围所限定的一般概念下,本发明并不限于特定的细节与这里示出与描述的图例。Although the embodiments of the present invention have been disclosed above, they are not limited to the applications listed in the description and embodiments. They can be applied to various fields suitable for the present invention. For those familiar with the art, they can easily Additional modifications may be made, and the invention is therefore not limited to the specific details and illustrations shown and described herein without departing from the general concept defined by the claims and equivalent scope.
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