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CN117185713A - Airport drainage ditch slope concrete and preparation method and construction method thereof - Google Patents

Airport drainage ditch slope concrete and preparation method and construction method thereof Download PDF

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Publication number
CN117185713A
CN117185713A CN202310918217.XA CN202310918217A CN117185713A CN 117185713 A CN117185713 A CN 117185713A CN 202310918217 A CN202310918217 A CN 202310918217A CN 117185713 A CN117185713 A CN 117185713A
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hydrophobic
parts
concrete
plant fiber
drainage ditch
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王鑫
孙良
王胜儒
张晔波
王冰
左平平
金敏
张志昌
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China Railway Airport Construction Co ltd
China Railway Beijing Engineering Group Co Ltd
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China Railway Airport Construction Co ltd
China Railway Beijing Engineering Group Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
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    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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Abstract

The application relates to airport drainage ditch slope concrete in the technical field of concrete preparation, which comprises the following components in parts by weight: 95-105 parts of cement, 30-35 parts of fly ash, 25-30 parts of slag, 450-458 parts of machine-made sand, 485-495 parts of broken stone, 1-2 parts of air-entraining water reducer, 7-9 parts of accelerator, 35-40 parts of hydrophobic auxiliary agent and 65-70 parts of water; the hydrophobic auxiliary agent comprises the following components in percentage by mass: (0.6-0.8) a hydrophobic mineral powder and a hydrophobically modified plant fiber; the treatment method of the hydrophobically modified plant fiber comprises the following steps: firstly, carrying out hydrophobic treatment on plant fibers to obtain hydrophobic plant fibers, wherein the hydrophobic contact angle of the hydrophobic plant fibers is 90-150 degrees; and then carrying out surface roughness modification treatment on the hydrophobic plant fiber to obtain the hydrophobic modified plant fiber. The application has the effect of improving the shape quality and the safety performance of the airport trapezoid open trench body.

Description

一种机场排水沟坡面混凝土及其制备方法、施工方法A kind of airport drainage ditch slope concrete and its preparation method and construction method

技术领域Technical field

本申请涉及混凝土制备技术的领域,尤其是涉及一种机场排水沟坡面混凝土及其制备方法、施工方法。The present application relates to the field of concrete preparation technology, and in particular to an airport drainage ditch slope concrete and its preparation method and construction method.

背景技术Background technique

机场的梯形明沟排水沟体需要用混凝土进行浇筑坡面,梯形明沟沟体具有坡面陡(坡比1:1)、厚度薄(20cm)等特点。传统混凝土通常是将水泥、粉煤灰、机制砂、碎石和水加入搅拌釜内搅拌形成混凝土。水泥、粉煤灰作为凝胶材料,水泥与水进行水化反应,使得混凝土能够凝结;粉煤灰可以改善混凝土,使混凝土易于泵送、浇筑成型,机制砂和碎石能够提升混凝土的抗压强度。The airport's trapezoidal open ditch drainage ditch body needs to be poured with concrete on the slope. The trapezoidal open ditch ditch body has the characteristics of steep slope (slope ratio 1:1) and thin thickness (20cm). Traditional concrete is usually made by adding cement, fly ash, machine-made sand, gravel and water into a mixing tank to form concrete. Cement and fly ash are used as gel materials. Cement reacts with water to allow concrete to solidify. Fly ash can improve concrete, making it easier to pump and pour. Machine-made sand and gravel can improve the compression resistance of concrete. strength.

由于对于一些地势平坦的位置浇筑时,需要混凝土具有较好的流动性以进行自流平,以形成较平整的混凝土层,因此传统混凝土所需的流动性通常较大。使用传统混凝土浇筑机场排水沟坡面时,由于梯形明沟沟体具有坡面陡、厚度薄等特点,混凝土因流动性较好而易受重力影响沿坡面进行流动,加上混凝土自身的凝结时间相对较长,导致最终成型的机场排水沟坡面的形态质量较差。Because when pouring in some flat locations, the concrete needs to have good fluidity for self-leveling to form a flatter concrete layer, so the fluidity required for traditional concrete is usually greater. When traditional concrete is used to pour airport drainage ditch slopes, due to the characteristics of the trapezoidal open ditch body with steep slope and thin thickness, the concrete has good fluidity and is easily affected by gravity to flow along the slope. In addition, the concrete itself takes a long time to set. The relatively long length results in poor morphological quality of the final airport drainage ditch slope.

并且由于梯形明沟沟体坡面的混凝土长期处于潮湿和水位变动的环境中,使得混凝土颗粒间的凝聚力降低,而导致混凝土的抗渗性变差,进而导致耐久性变差,从而对机场排水沟坡面的质量造成严重影响,使得机场梯形明沟排水沟体附近的机场地面的安全性能得不到保障。Moreover, because the concrete on the slope of the trapezoidal open ditch body has been exposed to moisture and water level changes for a long time, the cohesion between concrete particles is reduced, resulting in poor impermeability of concrete, which in turn leads to poor durability, thus affecting the airport drainage ditch. The quality of the slope has a serious impact, making it impossible to guarantee the safety performance of the airport ground near the airport's trapezoidal open ditch drainage ditch body.

发明内容Contents of the invention

为了提升机场梯形明沟沟体的形态质量和安全性能,本申请提供一种机场排水沟坡面混凝土及其制备方法、施工方法。In order to improve the morphological quality and safety performance of the airport trapezoidal open ditch body, this application provides an airport drainage ditch slope concrete and its preparation method and construction method.

本申请提供的一种机场排水沟坡面混凝土采用如下的技术方案:The airport drainage ditch slope concrete provided by this application adopts the following technical solution:

一种机场排水沟坡面混凝土,其包括如下重量份的组分:水泥95-105份、粉煤灰30-35份、矿渣25-30份、机制砂450-458份、碎石485-495份、引气减水剂1-2份、速凝剂7-9份、疏水助剂35-40份、水65-70份;An airport drainage ditch slope concrete includes the following components by weight: 95-105 parts of cement, 30-35 parts of fly ash, 25-30 parts of slag, 450-458 parts of machine-made sand, and 485-495 parts of gravel. parts, 1-2 parts of air-entraining water-reducing agent, 7-9 parts of quick-setting agent, 35-40 parts of hydrophobic additives, and 65-70 parts of water;

所述疏水助剂包括质量比为1:(0.6-0.8)的疏水矿物粉和疏水改性植物纤维;The hydrophobic auxiliary agent includes hydrophobic mineral powder and hydrophobic modified plant fiber with a mass ratio of 1: (0.6-0.8);

所述疏水改性植物纤维的处理方法:先对植物纤维进行疏水处理,得到疏水植物纤维,疏水植物纤维的疏水接触角度在90-150°之间;再对所述疏水植物纤维进行表面粗糙度改性处理,得到疏水改性植物纤维。The treatment method of the hydrophobic modified plant fiber: first perform hydrophobic treatment on the plant fiber to obtain hydrophobic plant fiber. The hydrophobic contact angle of the hydrophobic plant fiber is between 90-150°; and then conduct surface roughness treatment on the hydrophobic plant fiber. Modification treatment to obtain hydrophobic modified plant fiber.

通过采用上述技术方案,矿渣中的玻璃相可以在混凝土中形成微观结构,增加混凝土的粘聚力和内聚力,从而能一定程度地降低混凝土流动性和凝结时间,提升机场排水沟坡面混凝土的凝结速率。机制砂和碎石能够提升混凝土的抗压强度。引气减水剂能在混凝土中引入大量的、微小的、封闭的气泡并对混凝土有塑化作用,能够提升混凝土的耐久性、抗渗性等性能。速凝剂掺入混凝土中能就加快混凝土的凝结硬化,进一步提升凝结速率。By adopting the above technical solution, the glass phase in the slag can form a microstructure in the concrete, increase the cohesion and cohesion of the concrete, thereby reducing the fluidity and setting time of the concrete to a certain extent, and improving the setting of the concrete on the slope of the airport drainage ditch. rate. Manufactured sand and gravel can increase the compressive strength of concrete. Air-entraining water-reducing agents can introduce a large number of tiny, closed bubbles into concrete and have a plasticizing effect on concrete, which can improve the durability, impermeability and other properties of concrete. The accelerating setting agent mixed into concrete can accelerate the setting and hardening of concrete and further increase the setting rate.

疏水矿物粉本身具有疏水性,将疏水矿物粉掺入混凝土中,能使得混凝土颗粒具有一定的疏水性,以增强明沟沟体混凝土混凝土的抗渗性。但由于疏水矿物粉表面具有物理润滑性,疏水矿物粉分散性较差,疏水矿物粉在粒径较小、以及掺量较多时易发生团聚,且会增加混凝土的流动性;且由于疏水矿物粉本身结构强度较低,疏水矿物粉的掺入会导致混凝土强度降低。而植物纤维本身具有很好的分散性,将植物纤维经过疏水改性处理以及表面粗糙度改性处理后,以降低植物纤维的亲水性,且得到的疏水改性植物纤维的表面粗糙度和反应活性也得到提高,以植物纤维与疏水矿物粉以及其他组分的耐水结合性能,使得疏水改性植物纤维和疏水矿物粉对混凝土的抗渗性能进行提升的同时,疏水改性植物纤维与疏水矿物粉进行结合后提升疏水矿物粉的分散性,使得疏水矿物粉不易团聚,提升混凝土的疏水稳定性;疏水改性植物纤维与疏水矿物粉进行结合后能够降低疏水矿物粉对混凝土流动性的影响;疏水改性植物纤维与疏水矿物粉进行结合后还能提升疏水矿物粉在混凝土中的力学性能,以减小疏水矿物粉的掺入对混凝土强度的不良影响。Hydrophobic mineral powder itself is hydrophobic. Mixing hydrophobic mineral powder into concrete can make the concrete particles have a certain degree of hydrophobicity to enhance the impermeability of open ditch concrete. However, due to the physical lubricity of the surface of hydrophobic mineral powder, the dispersion of hydrophobic mineral powder is poor. Hydrophobic mineral powder is prone to agglomeration when the particle size is small and the dosage is large, and it will increase the fluidity of concrete; and because hydrophobic mineral powder The structural strength itself is low, and the incorporation of hydrophobic mineral powder will lead to a reduction in the strength of concrete. The plant fiber itself has good dispersion. After the plant fiber is hydrophobically modified and surface roughness modified, the hydrophilicity of the plant fiber is reduced, and the surface roughness of the hydrophobically modified plant fiber obtained is The reactivity has also been improved. With the water-resistant binding properties of plant fibers and hydrophobic mineral powders and other components, the hydrophobic modified plant fibers and hydrophobic mineral powders improve the impermeability properties of concrete. At the same time, the hydrophobic modified plant fibers and hydrophobic The combination of mineral powders improves the dispersion of hydrophobic mineral powders, making them less likely to agglomerate and improving the hydrophobic stability of concrete. The combination of hydrophobic modified plant fibers and hydrophobic mineral powders can reduce the impact of hydrophobic mineral powders on the fluidity of concrete. ; The combination of hydrophobic modified plant fiber and hydrophobic mineral powder can also improve the mechanical properties of hydrophobic mineral powder in concrete to reduce the adverse effects of the addition of hydrophobic mineral powder on the strength of concrete.

通过降低混凝土的流动性、凝结时间,以及提升混凝土的抗渗性和耐用性的提升,能够提升机场排水沟坡面的形态质量和安全性能。By reducing the fluidity and setting time of concrete, as well as improving the impermeability and durability of concrete, the morphological quality and safety performance of airport drainage ditch slopes can be improved.

可选的,所述疏水处理的处理步骤如下:Optionally, the hydrophobic treatment steps are as follows:

对植物纤维依次进行碱洗、去离子水清洗,再采用酸液中和至中性,加入含亚硫酸钠,加热至60~70℃,并恒温30~40min;再加入邻苯二甲酸酐溶液,升温至100~110℃,接着加入过氧化物酶,反应60~80min;加入丙烯酸酯类单体,升温至140~160℃,120~140min后进行过滤、洗涤、干燥,得到疏水植物纤维。The plant fibers are washed with alkali and deionized water in sequence, and then neutralized with acid solution to neutrality. Add sodium sulfite, heat to 60-70°C, and keep the temperature constant for 30-40 minutes; then add phthalic anhydride solution and raise the temperature. to 100-110°C, then add peroxidase and react for 60-80 minutes; add acrylate monomer, raise the temperature to 140-160°C, filter, wash and dry after 120-140 minutes to obtain hydrophobic plant fibers.

通过采用上述技术方案,先采用亚硫酸钠对纤维表面的木质素进行磺甲基化反应,再与邻苯二甲酸酐在过氧化物酶的催化作用下活化反应,破坏表层木质素结构,产生酚氧自由基,即可实现下一步与丙烯酸酯类单体的接枝反应。在植物纤维的表面接枝引入丙烯酸酯类单体这类大分子长链,可明显增加植物纤维表面的疏水性。By adopting the above technical solution, sodium sulfite is first used to perform a sulfomethylation reaction on the lignin on the fiber surface, and then it is activated with phthalic anhydride under the catalysis of peroxidase to destroy the surface lignin structure and generate phenolic oxygen. Free radicals can be used to achieve the next step of grafting reaction with acrylate monomers. Grafting the long chains of macromolecules such as acrylate monomers on the surface of plant fibers can significantly increase the hydrophobicity of the surface of plant fibers.

可选的,所述表面粗糙度改性处理的处理步骤如下:Optionally, the surface roughness modification treatment steps are as follows:

将所述疏水植物纤维加入4-6wt%的NaOH溶液中,搅拌并升温至150-170℃,反应1-2h,降温后进行过滤得到沉淀产物,冷却后用去离子水清洗,干燥后得到前处理植物纤维;Add the hydrophobic plant fiber to 4-6wt% NaOH solution, stir and raise the temperature to 150-170°C, react for 1-2 hours, filter after cooling to obtain the precipitated product, wash with deionized water after cooling, and dry to obtain the former Processing of plant fibers;

配制ph为7.8的乙醇溶液的氨水和乙醇,加入所述前处理植物纤维,搅拌35-40min,再将前处理植物纤维添加量的1/5的正硅酸乙酯逐滴添加入反应釜B中,搅拌8-12min;再加入前处理植物纤维添加量的1/5的三甲氧基硅烷,在室温下搅拌24h,得到沉淀产物,用去离子水清洗,干燥后得到疏水改性植物纤维。Prepare an ethanol solution of ammonia and ethanol with a pH of 7.8, add the pre-treated plant fiber, stir for 35-40 minutes, and then add 1/5 of the pre-treated plant fiber addition amount of tetraethyl orthosilicate dropwise into reactor B. medium, stir for 8-12 minutes; then add 1/5 of the amount of trimethoxysilane added to the pre-treated plant fiber, stir at room temperature for 24 hours, and obtain the precipitated product, wash it with deionized water, and dry it to obtain hydrophobic modified plant fiber.

通过采用上述技术方案,通过上述步骤能够提高疏水植物纤维的表面粗糙度和活性反应位点,以有效地增强疏水植物纤维与疏水矿物粉和其他颗粒的机械互锁和界面结合力。By adopting the above technical solution, the surface roughness and active reaction sites of hydrophobic plant fibers can be improved through the above steps to effectively enhance the mechanical interlocking and interfacial bonding force between hydrophobic plant fibers and hydrophobic mineral powders and other particles.

可选的,所述疏水矿物粉选自石墨和滑石中的一种。Optionally, the hydrophobic mineral powder is selected from graphite and talc.

通过采用上述技术方案,石墨、滑石粉是天然的疏水性矿物,石墨、滑石粉不易被水润湿,因此石墨、滑石粉具有较好的疏水性,且造低相对较低,能够适用于实际应用。By adopting the above technical solution, graphite and talc powder are natural hydrophobic minerals. Graphite and talc powder are not easily wetted by water. Therefore, graphite and talc powder have good hydrophobicity and relatively low cost, and can be suitable for practical applications. application.

可选的,所述疏水矿物粉的粒径范围为6-10μm。Optionally, the particle size range of the hydrophobic mineral powder is 6-10 μm.

通过采用上述技术方案,在混凝土中掺入上述粒径范围的疏水矿物粉,疏水矿物粉在提高混凝土疏水性的同时,能够提高混凝土的堆积密度,以提升混凝土的密实度,以进一步提升混凝土的抗渗性和耐用性。By adopting the above technical solution, hydrophobic mineral powder with the above particle size range is mixed into concrete. The hydrophobic mineral powder can not only improve the hydrophobicity of concrete, but also increase the bulk density of concrete to improve the compactness of concrete and further improve the strength of concrete. Impermeability and durability.

可选的,所述机制砂的粒径0-4.75mm。Optionally, the particle size of the machine-made sand is 0-4.75mm.

通过采用上述技术方案,上述粒径范围的机制砂能够更好地提升混凝土的可塑性,并且能够更好地增加混凝土的强度和耐用性。By adopting the above technical solution, the machine-made sand in the above particle size range can better improve the plasticity of concrete, and can better increase the strength and durability of concrete.

可选的,碎石的粒径范围为4.75-31.5mm。Optional, the particle size range of gravel is 4.75-31.5mm.

通过采用上述技术方案,上述粒径范围的碎石能够较好地填充混凝土的空隙,增加混凝土的强度和稳定性,保持适当的流动性。By adopting the above technical solution, the gravel in the above particle size range can better fill the gaps in the concrete, increase the strength and stability of the concrete, and maintain appropriate fluidity.

可选的,所述水泥的硬度等级为42.5R。Optionally, the hardness grade of the cement is 42.5R.

通过采用上述技术方案,在混凝土中掺入42.5R的水泥能够满足排水沟坡面混凝土的承重要求。By adopting the above technical solution, adding 42.5R cement into the concrete can meet the load-bearing requirements of the concrete on the slope of the drainage ditch.

第二方面,本申请提供的一种混凝土的制备方法,采用如下的技术方案:In the second aspect, this application provides a concrete preparation method that adopts the following technical solution:

一种混凝土的制备方法,包括以下步骤:常温下,先加入碎石和机制砂,搅拌25-35s,再加入水泥、粉煤灰和矿粉,搅拌25-35s,接着加入水、减水剂和速凝剂,搅拌40-50s,最后加入疏水矿物粉和疏水改性植物纤维,搅拌25-35s。A method for preparing concrete, including the following steps: at normal temperature, first add gravel and machine-made sand, stir for 25-35 seconds, then add cement, fly ash and mineral powder, stir for 25-35 seconds, and then add water and water-reducing agent and accelerating setting agent, stir for 40-50s, finally add hydrophobic mineral powder and hydrophobic modified plant fiber, and stir for 25-35s.

通过采用上述技术方案,通过上述步骤,能够各组分充分的混合以及进行相应的化学反应,使得形成的混凝土的工作性能、抗渗性和耐用性能够达标。By adopting the above technical solution and through the above steps, each component can be fully mixed and carry out corresponding chemical reactions, so that the working performance, impermeability and durability of the formed concrete can meet the standards.

第三方面,本申请提供的一种混凝土的施工方法,采用如下的技术方案:In the third aspect, this application provides a concrete construction method that adopts the following technical solution:

步骤1:原材料检测;Step 1: Raw material testing;

步骤2:将水泥、粉煤灰、矿渣、机制砂、碎石、引气减水剂、速凝剂、疏水助剂和水各组分的重量份进行计算得到初步配合比;Step 2: Calculate the weight parts of each component of cement, fly ash, slag, machine-made sand, gravel, air-entraining water-reducing agent, accelerating setting agent, hydrophobic additive and water to obtain the preliminary mix ratio;

步骤3:通过实配、检测,进行工作性的调整,对初步配合比进行修正得到基准配合比;Step 3: Adjust the workability through actual matching and testing, and correct the preliminary mix ratio to obtain the benchmark mix ratio;

步骤4:满足设计强度的前提下,确定水泥用量最少的方案,从而进一步调整得到试验室配合比,按试验室配合比换算的各组分的重量份数如下:水泥95-105份、粉煤灰30-35份、矿渣25-30份、机制砂450-458份、碎石485-495份、引气减水剂1-2份、速凝剂7-9份、疏水助剂35-40份、水65-70份,其中疏水助剂包括质量比为1:(0.6-0.8)的疏水矿物粉和疏水改性植物纤维;Step 4: Under the premise of meeting the design strength, determine the solution with the least amount of cement, so as to further adjust the laboratory mix ratio. The weight parts of each component converted according to the laboratory mix ratio are as follows: 95-105 parts of cement, pulverized coal 30-35 parts of ash, 25-30 parts of slag, 450-458 parts of machine-made sand, 485-495 parts of gravel, 1-2 parts of air-entraining water-reducing agent, 7-9 parts of quick-setting agent, 35-40 parts of hydrophobic additives parts and 65-70 parts of water, in which the hydrophobic additives include hydrophobic mineral powder and hydrophobic modified plant fiber with a mass ratio of 1: (0.6-0.8);

步骤5:根据原材料的含水率和天气状况进行调整得到施工配合比;Step 5: Adjust according to the moisture content of raw materials and weather conditions to obtain the construction mix ratio;

步骤6:按照施工配合比在拌合楼内加入指定重量分数的各组分进行拌和,得到混凝土。Step 6: Add the specified weight fraction of each component into the mixing plant according to the construction mix ratio and mix to obtain concrete.

通过采用上述技术方案,通过上述方法能够等到相对准确的试验室配合比,并根据实际情况调整后得到施工配合比,能够使得制得的混凝土更能够适应实际材料和环境,以达到更好的施工效果。By adopting the above technical solution, the above method can wait for a relatively accurate laboratory mix ratio, and adjust it according to the actual situation to obtain the construction mix ratio, which can make the concrete produced more adaptable to actual materials and environments to achieve better construction Effect.

可选的,速凝剂选自碱土金属碳酸盐、硅酸钾类速凝剂、铝酸盐类速凝剂和无碱液体速凝剂中的一种Optionally, the accelerating setting agent is selected from one of alkaline earth metal carbonates, potassium silicate accelerating setting agents, aluminate accelerating setting agents and alkali-free liquid accelerating setting agents.

综上所述,本申请包括以下至少一种有益技术效果:To sum up, this application includes at least one of the following beneficial technical effects:

1.粉煤灰、矿渣和速凝剂都能使得提升混凝土的凝结速率,并且降低混凝土的流动性,引气减水剂、疏水矿物粉和疏水改性植物纤维都能提升混凝土的抗渗性,疏水改性植物纤维与疏水矿物粉进行结合后提升疏水矿物粉的分散性、降低疏水矿物粉对混凝土流动性的影响、提升疏水疏水矿物粉在混凝土中的力学性能,以提升混凝土的抗渗性和耐用性;1. Fly ash, slag and accelerator can increase the setting rate of concrete and reduce the fluidity of concrete. Air-entraining water-reducing agent, hydrophobic mineral powder and hydrophobic modified plant fiber can all improve the impermeability of concrete. , the combination of hydrophobic modified plant fiber and hydrophobic mineral powder improves the dispersion of hydrophobic mineral powder, reduces the impact of hydrophobic mineral powder on the fluidity of concrete, and improves the mechanical properties of hydrophobic mineral powder in concrete to improve the anti-permeability of concrete. performance and durability;

2.6-10μm的疏水矿物粉,疏水矿物粉在提高混凝土疏水性的同时,能够提高混凝土的堆积密度,以提升混凝土的密实度,以进一步提升混凝土的抗渗性和耐用性;2.6-10μm hydrophobic mineral powder. Hydrophobic mineral powder can not only improve the hydrophobicity of concrete, but also increase the packing density of concrete to improve the compactness of concrete and further improve the impermeability and durability of concrete;

3.0-4.75mm的机制砂能够更好地提升混凝土的可塑性,并且能够更好地增加混凝土的强度和耐用性。3.0-4.75mm machine-made sand can better improve the plasticity of concrete, and can better increase the strength and durability of concrete.

具体实施方式Detailed ways

一、制备例:1. Preparation example:

疏水改性处理:将木粉、稻壳和秸秆等破碎得到的30kg植物纤维用氢氧化钠溶液进行1次碱洗,再去离子水清洗3次,再采用磷酸溶液中和至中性,加入反应釜内;向反应釜内加入含亚硫酸钠,加热至65℃,并恒温35min;再加入邻苯二甲酸酐溶液,升温至105℃,接着加入过氧化物酶,反应70min;加入丙烯酸酯类单体,升温至150℃,130min后进行过滤、洗涤、干燥,得到疏水植物纤维。Hydrophobic modification treatment: 30kg of plant fibers obtained by crushing wood powder, rice husk and straw were washed once with sodium hydroxide solution, washed three times with deionized water, neutralized with phosphoric acid solution until neutral, and added In the reaction kettle; add sodium sulfite into the reaction kettle, heat to 65°C, and keep the temperature constant for 35 minutes; then add phthalic anhydride solution, heat to 105°C, then add peroxidase, react for 70 minutes; add acrylate monomers body, raise the temperature to 150°C, filter, wash and dry after 130 minutes to obtain hydrophobic plant fiber.

表面粗糙度改性处理:在反应釜A中配置5%浓度的NaOH溶液,将30kg的疏水植物纤维加入反应釜中,搅拌并升温至160℃,反应1h,降温后进行过滤得到沉淀产物,冷却后用去离子水清洗,干燥后得到前处理植物纤维;Surface roughness modification treatment: Prepare a 5% concentration NaOH solution in reactor A, add 30kg of hydrophobic plant fiber into the reactor, stir and raise the temperature to 160°C, react for 1 hour, cool down and then filter to obtain the precipitated product, cool Afterwards, it is washed with deionized water and dried to obtain pre-treated plant fiber;

在反应釜B中加入一定比例的氨水和乙醇,搅拌均匀,再将25kg的前处理植物纤维加入反应釜B中,搅拌40min,再将5kg的正硅酸乙酯逐滴添加入反应釜B中,搅拌10min;再加入5kg的三甲氧基硅烷,在室温下搅拌24h,得到沉淀产物,用去离子水清洗,干燥后得到疏水改性植物纤维。Add a certain proportion of ammonia and ethanol to reactor B, stir evenly, then add 25kg of pre-treated plant fiber to reactor B, stir for 40 minutes, and then add 5kg of ethyl orthosilicate dropwise into reactor B. , stir for 10 minutes; then add 5 kg of trimethoxysilane, stir at room temperature for 24 hours, and obtain a precipitated product, which is washed with deionized water and dried to obtain hydrophobic modified plant fiber.

二、实施例2. Embodiments

实施例1:Example 1:

混凝土制备:常温下,先加入485kg碎石和450kg机制砂,搅拌30s,再加入95kg水泥、30kg粉煤灰和25kg矿渣,搅拌30s,接着加入65kg水、1kg引气减水剂和7kg速凝剂,搅拌40s,最后加入35kg疏水助剂,搅拌30s,得到混凝土。Concrete preparation: At normal temperature, first add 485kg gravel and 450kg machine-made sand, stir for 30s, then add 95kg cement, 30kg fly ash and 25kg slag, stir for 30s, then add 65kg water, 1kg air-entraining water-reducing agent and 7kg quick-setting agent, stir for 40s, finally add 35kg of hydrophobic additive, stir for 30s, and obtain concrete.

其中疏水助剂包括质量比为1:0.7的滑石粉和疏水改性植物纤维(即20.6kg滑石粉和14.4kg疏水改性植物纤维),滑石粉的粒径为8μm,碎石的平均粒径为2.75mm,机制砂的平均粒径为15.5mm,引气减水剂为聚羧酸系引气减水剂,速凝剂为硅酸钾类速凝剂。The hydrophobic additives include talc powder and hydrophobic modified plant fiber with a mass ratio of 1:0.7 (i.e. 20.6kg talc powder and 14.4kg hydrophobic modified plant fiber). The particle size of the talc powder is 8 μm, and the average particle size of the crushed stone is 8 μm. The average particle size of machine-made sand is 15.5mm. The air-entraining water-reducing agent is polycarboxylic acid-based air-entraining water-reducing agent, and the accelerating setting agent is potassium silicate accelerating setting agent.

实施例2-3:Example 2-3:

一种机场排水沟坡面混凝土,与实施例1的不同之处如表1所示。A kind of airport drainage ditch slope concrete, the differences from Example 1 are shown in Table 1.

表1:Table 1:

实施例4:Example 4:

一种机场排水沟坡面混凝土,与实施例2的不同之处在于:疏水助剂为38kg,即滑石粉为22.35kg和疏水改性植物纤维为15.65kg。The difference between an airport drainage ditch slope concrete and Example 2 is that the hydrophobic additive is 38kg, that is, the talcum powder is 22.35kg and the hydrophobic modified plant fiber is 15.65kg.

实施例5:Example 5:

一种机场排水沟坡面混凝土,与实施例2的不同之处在于:疏水助剂为40kg,即滑石粉为23.5kg和疏水改性植物纤维为16.5kg。A kind of airport drainage ditch slope concrete is different from Example 2 in that: the hydrophobic additive is 40kg, that is, the talcum powder is 23.5kg and the hydrophobic modified plant fiber is 16.5kg.

实施例6:Example 6:

一种机场排水沟坡面混凝土,与实施例2的不同之处在于:滑石粉和疏水改性植物纤维的质量比为1:0.6,即滑石粉为23.75kg和疏水改性植物纤维为14.25kg。An airport drainage ditch slope concrete differs from Example 2 in that the mass ratio of talc powder and hydrophobic modified plant fiber is 1:0.6, that is, the talc powder is 23.75kg and the hydrophobic modified plant fiber is 14.25kg .

实施例7:Example 7:

一种机场排水沟坡面混凝土,与实施例2的不同之处在于:滑石粉和疏水改性植物纤维的质量比为1:0.8,即滑石粉为21.1kg和疏水改性植物纤维为16.9kg。An airport drainage ditch slope concrete differs from Example 2 in that the mass ratio of talc powder and hydrophobic modified plant fiber is 1:0.8, that is, the talc powder is 21.1kg and the hydrophobic modified plant fiber is 16.9kg .

实施例8:Example 8:

一种机场排水沟坡面混凝土,与实施例2的不同之处在于:矿渣的含量为25kg。An airport drainage ditch slope concrete differs from Example 2 in that the slag content is 25kg.

实施例9:Example 9:

一种机场排水沟坡面混凝土,与实施例2的不同之处在于:矿渣的含量为30kg。An airport drainage ditch slope concrete differs from Example 2 in that the slag content is 30kg.

三、对比例3. Comparative ratio

对比例1:Comparative example 1:

一种机场排水沟坡面混凝土,与实施例2的不同之处在于:其中疏水助剂等量替换为水泥。An airport drainage ditch slope concrete is different from Example 2 in that equal amounts of hydrophobic additives are replaced by cement.

对比例2:Comparative example 2:

一种机场排水沟坡面混凝土,与实施例2的不同之处在于:滑石粉和疏水改性植物纤维的质量比为1:0.4。An airport drainage ditch slope concrete differs from Example 2 in that the mass ratio of talcum powder and hydrophobic modified plant fiber is 1:0.4.

四、性能检测试验4. Performance testing test

1)凝结时间测试:根据GB/T1346-2011《水泥标准稠度用水量、凝结时间、安定性检验方法》对实施例1-9、对比例1-2制备的混凝土的初凝、终凝所需时间进行测试;1) Setting time test: According to GB/T1346-2011 "Cement standard consistency water consumption, setting time, stability test method", the initial setting and final setting requirements of the concrete prepared in Examples 1-9 and Comparative Examples 1-2 time for testing;

2)流动性测试:根据GB/T50080中的坍落度试验方法对实施例1-9、对比例1-2制备的混凝土在同等养护条件形成的混凝土试件进行测试;2) Fluidity test: According to the slump test method in GB/T50080, test the concrete specimens formed under the same curing conditions of the concrete prepared in Examples 1-9 and Comparative Examples 1-2;

3)力学性能测试:根据GB/T50081-2002《普通混凝土力学性能试验方法标准》对实施例1-9、对比例1-2制备的混凝土在同等养护条件形成的混凝土试件进行28d抗压强度测试;3) Mechanical property test: According to GB/T50081-2002 "Standard for Test Methods of Mechanical Properties of Ordinary Concrete", the 28-day compressive strength of the concrete specimens formed under the same curing conditions of the concrete prepared in Examples 1-9 and Comparative Examples 1-2 was tested. test;

4)抗渗耐用性能测试:根据GB/T50082-2009《普通混凝土长期性能和耐久性能试验方法标准》中的渗水高度法对实施例1-9、对比例1-2制备的混凝土在同等养护条件形成的混凝土试件进行测试。4) Anti-penetration and durability test: According to the water penetration height method in GB/T50082-2009 "Standard for Test Methods of Long-term Performance and Durability of Ordinary Concrete", the concrete prepared in Examples 1-9 and Comparative Examples 1-2 were tested under the same curing conditions. The resulting concrete specimens were tested.

以上性能测试结果如表2所示:The above performance test results are shown in Table 2:

表2:Table 2:

五、结果分析与总结5. Result Analysis and Summary

结合实施例1-9和对比例1-2并结合表2可以看出,实施例1-3中,实施例2的初凝和终凝所需时间均明显少于实施例1,但与实施例3相近;实施例2的坍落度明显小于实施例1,但与实施例3相近;实施例2的抗压强度均高于实施例1和实施例3;实施例2的渗水高度明显低于实施例1,但与实施例3相近。由上可知,实施例2所需的凝结时间明显少于实施例1、但与实施例3相近,实施例2的流动性明显小于实施例1、但与实施例3相近,实施例2的抗压强度均高于实施例1和实施例3,实施例2的抗渗性明显优于实施例1,但与实施例3相近。Combining Examples 1-9 and Comparative Examples 1-2 and Table 2, it can be seen that in Examples 1-3, the time required for the initial setting and final setting of Example 2 is significantly shorter than that of Example 1, but compared with the implementation Similar to Example 3; the slump of Example 2 is significantly smaller than that of Example 1, but similar to Example 3; the compressive strength of Example 2 is higher than that of Example 1 and Example 3; the water seepage height of Example 2 is significantly lower In Example 1, but similar to Example 3. It can be seen from the above that the coagulation time required by Example 2 is significantly less than that of Example 1, but similar to Example 3. The fluidity of Example 2 is significantly less than that of Example 1, but similar to Example 3. The resistance of Example 2 is The compressive strength is higher than that of Example 1 and Example 3. The impermeability of Example 2 is obviously better than that of Example 1, but similar to Example 3.

由此可得,实施例2的各个原料及其重量份相对实施例1和实施例3,在能够节约原料添加量的情况下,能够更好地减小混凝土流动性和减少凝结时间,并且能够更好地提升混凝土的抗渗性和耐用性,能够更显著地提升机场排水沟坡面的形态质量和安全性能。It can be seen from this that the various raw materials and their weight parts in Example 2 can better reduce the fluidity and setting time of concrete while saving the amount of raw materials added compared to Example 1 and Example 3, and can Better improving the impermeability and durability of concrete can significantly improve the morphological quality and safety performance of airport drainage ditch slopes.

另外的,实施例4中的疏水助剂含量相对实施例2较少,实施例5中疏水助剂含量相对实施例2较多。从表2可以看出,实施例2和实施例4-5初凝和终凝所需时间、坍落度、抗压强度相差不大,因此疏水助剂含量的变化对混凝土凝结时间、流动性以及抗压强度的影响不大。但可从表2看出,实施例4的渗水高度明显大于实施例2,实施例2与实施例5的渗水高度相近,由上可知,实施例4的抗渗性低于实施例2,实施例5的抗渗性与实施例2相近。In addition, the content of the hydrophobic auxiliary agent in Example 4 is less than that in Example 2, and the content of the hydrophobic auxiliary agent in Example 5 is greater than that in Example 2. It can be seen from Table 2 that the time required for initial setting and final setting, slump, and compressive strength are not much different between Example 2 and Example 4-5. Therefore, changes in the content of hydrophobic additives have an impact on the setting time and fluidity of concrete. and little impact on compressive strength. However, it can be seen from Table 2 that the water seepage height of Example 4 is significantly greater than that of Example 2. The water seepage heights of Example 2 and Example 5 are similar. From the above, it can be seen that the impermeability of Example 4 is lower than that of Example 2. The impermeability of Example 5 is similar to that of Example 2.

并且结合对比例1,对比例1的疏水助剂被等量替换为水泥,从表2可看出,对比例1的渗水高度远高于实施例2,同时高于实施例4-5,即对比例2的抗渗性低于实施例2和实施例4-5。And combined with Comparative Example 1, the hydrophobic additive of Comparative Example 1 was replaced by cement in equal amounts. As can be seen from Table 2, the water seepage height of Comparative Example 1 is much higher than that of Example 2, and at the same time higher than that of Examples 4-5, that is The impermeability of Comparative Example 2 is lower than that of Example 2 and Examples 4-5.

由上可得,疏水助剂能够显著提升混凝土的抗渗性,且实施例2中疏水助剂的含量相比于实施例4-5,能够在节约原料添加量的情况下,对混凝土的抗渗性进行更显著的提升。It can be seen from the above that hydrophobic additives can significantly improve the impermeability of concrete, and the content of hydrophobic additives in Example 2 is compared with Examples 4-5, which can improve the resistance of concrete while saving the amount of raw materials added. Permeability is significantly improved.

另外的,实施例6-7的疏水助剂中疏水矿物粉和疏水改性植物纤维的质量比均与实施例2不同。由表2可以看出,实施例6的坍落度明显高于实施例2,实施例7的坍落度与实施例2相近;实施例6的抗压强度远低于实施例2,实施例7的抗压强度略低于实施例2;实施例2的渗水高度均低于实施例6-7,由上可知,实施例2的流动性明显小于实施例6、但与实施例7相近,实施例2的抗压强度均高于实施例6-7,实施例2的抗渗性均优于实施6-7。In addition, the mass ratios of hydrophobic mineral powder and hydrophobic modified plant fiber in the hydrophobic additives of Examples 6-7 are different from those of Example 2. As can be seen from Table 2, the slump of Example 6 is significantly higher than that of Example 2, and the slump of Example 7 is similar to that of Example 2; the compressive strength of Example 6 is much lower than that of Example 2. The compressive strength of Example 7 is slightly lower than that of Example 2; the water penetration height of Example 2 is lower than that of Examples 6-7. From the above, it can be seen that the fluidity of Example 2 is significantly smaller than that of Example 6, but similar to Example 7. The compressive strength of Example 2 is higher than that of Examples 6-7, and the impermeability of Example 2 is better than that of Examples 6-7.

由此可得,实施例2的疏水助剂中疏水矿物粉和疏水改性植物纤维的质量比相比于实施例6-7,能够更显著地减小混凝土流动性,并且能够更显著地提升混凝土的抗渗性和耐用性,以能够更好地提升机场排水沟坡面的形态质量和安全性能。It can be concluded that compared with Examples 6-7, the mass ratio of hydrophobic mineral powder and hydrophobic modified plant fiber in the hydrophobic additive of Example 2 can more significantly reduce the fluidity of concrete, and can more significantly improve the fluidity of concrete. The impermeability and durability of concrete can better improve the morphological quality and safety performance of the airport drainage ditch slope.

并且结合对比例1,对比例1的疏水助剂中疏水矿物粉和疏水改性植物纤维的质量比为1:0.4,对比例1中的疏水改性植物纤维的占比均低于实施例2、实施例6-7。从表2可以看出,对比例2的抗压强度远低于实施例2、实施例6-7,且渗水高度高于实施例2。由上可得,当疏水助剂中疏水矿物粉质量占比较高、疏水改性植物纤维质量占比较低时,会对混凝土的抗压强度造成较大的负面影响,同时也会降低混凝土的抗渗性。And combined with Comparative Example 1, the mass ratio of hydrophobic mineral powder and hydrophobic modified plant fiber in the hydrophobic additive of Comparative Example 1 is 1:0.4, and the proportion of hydrophobic modified plant fiber in Comparative Example 1 is lower than that of Example 2 , Examples 6-7. As can be seen from Table 2, the compressive strength of Comparative Example 2 is much lower than that of Example 2 and Examples 6-7, and the water seepage height is higher than that of Example 2. It can be seen from the above that when the mass proportion of hydrophobic mineral powder in the hydrophobic additive is high and the mass proportion of hydrophobic modified plant fiber is low, it will have a greater negative impact on the compressive strength of concrete and will also reduce the compressive strength of concrete. Permeability.

另外的,实施例8的矿渣含量低于实施例2,实施例9的矿渣含量高于实施例2。从表2可以看出,实施例8的初凝和终凝所需时间均远高于实施例2,实施例9的的初凝和终凝所需时间与实施例2相近;实施例8的坍落度明显高于实施例2,实施例9的坍落度与实施例2相近。由上可知,实施例2所需的凝结时间明显少于实施例8、但与实施例9相近;实施例2的流动性明显小于实施例8、但与实施例9相近。In addition, the slag content of Example 8 is lower than that of Example 2, and the slag content of Example 9 is higher than that of Example 2. It can be seen from Table 2 that the time required for the initial setting and final setting of Example 8 is much longer than that of Example 2, and the time required for the initial setting and final setting of Example 9 is similar to that of Example 2; The slump is significantly higher than that of Example 2, and the slump of Example 9 is similar to that of Example 2. It can be seen from the above that the coagulation time required by Example 2 is significantly shorter than that of Example 8, but similar to that of Example 9; the fluidity of Example 2 is significantly shorter than that of Example 8, but similar to that of Example 9.

由此可得,实施例2的矿渣含量相比于实施例8-9,能够在节约原料添加量的情况下,更显著地减小混凝土流动性和减少凝结时间,以能够更好地提升机场排水沟坡面的形态质量,并且提高施工效率。It can be seen that compared with Examples 8-9, the slag content of Example 2 can more significantly reduce the fluidity of concrete and reduce the setting time while saving the amount of raw materials added, so as to better improve the airport. Improve the morphological quality of the drainage ditch slope and improve construction efficiency.

以上均为本申请的较佳实施例,并非依此限制本申请的保护范围,故:凡依本申请的结构、形状、原理所做的等效变化,均应涵盖于本申请的保护范围之内。The above are all preferred embodiments of the present application, and do not limit the scope of protection of the present application. Therefore, any equivalent changes made based on the structure, shape, and principle of the present application shall be covered by the protection scope of the present application. Inside.

Claims (10)

1. The airport drainage ditch slope concrete is characterized by comprising the following components in parts by weight: 95-105 parts of cement, 30-35 parts of fly ash, 25-30 parts of slag, 450-458 parts of machine-made sand, 485-495 parts of broken stone, 1-2 parts of air-entraining water reducer, 7-9 parts of accelerator, 35-40 parts of hydrophobic auxiliary agent and 65-70 parts of water;
the hydrophobic auxiliary agent comprises the following components in percentage by mass: (0.6-0.8) a hydrophobic mineral powder and a hydrophobically modified plant fiber;
the treatment method of the hydrophobically modified plant fiber comprises the following steps: firstly, carrying out hydrophobic treatment on plant fibers to obtain hydrophobic plant fibers, wherein the hydrophobic contact angle of the hydrophobic plant fibers is 90-150 degrees; and then carrying out surface roughness modification treatment on the hydrophobic plant fiber to obtain the hydrophobic modified plant fiber.
2. An airport drainage ditch slope concrete of claim 1, wherein: the hydrophobic treatment comprises the following treatment steps:
sequentially performing alkali washing and deionized water washing on the plant fibers, neutralizing to be neutral by adopting acid liquor, adding sodium sulfite, heating to 60-70 ℃, and keeping the temperature for 30-40 min; then adding phthalic anhydride solution, heating to 100-110 ℃, adding peroxidase, and reacting for 60-80 min; and adding an acrylic monomer, heating to 140-160 ℃, filtering, washing and drying after 120-140 min to obtain the hydrophobic plant fiber.
3. An airport drainage ditch slope concrete according to claim 2, wherein: the surface roughness modification treatment comprises the following treatment steps:
adding the hydrophobic plant fiber into 4-6wt% NaOH solution, stirring and heating to 150-170 ℃, reacting for 1-2h, cooling, filtering to obtain a precipitate, cooling, washing with deionized water, and drying to obtain pretreated plant fiber;
preparing ammonia water and ethanol of which the ph is 7.8, adding the pretreated plant fibers, stirring for 35-40min, dropwise adding 1/5 of ethyl orthosilicate with the addition amount of the pretreated plant fibers into a reaction kettle B, and stirring for 8-12min; adding 1/5 of trimethoxy silane for pretreatment of plant fiber, stirring at room temperature for 24h to obtain a precipitate, washing with deionized water, and drying to obtain the hydrophobically modified plant fiber.
4. An airport drainage ditch slope concrete of claim 1, wherein: the hydrophobic mineral powder is selected from one of graphite, silica fume and talc.
5. An airport drainage ditch slope concrete of claim 1, wherein: the particle size of the hydrophobic mineral powder is in the range of 6-10 mu m.
6. An airport drainage ditch slope concrete of claim 1, wherein: the grain diameter of the machine-made sand is 0-4.75mm.
7. An airport drainage ditch slope concrete of claim 1, wherein: the particle size of the crushed stone is 4.75-31.5mm.
8. An airport drainage ditch slope concrete of claim 1, wherein: the hardness grade of the cement is 42.5R.
9. A method of preparing a concrete according to any one of claims 1 to 8, comprising the steps of:
at normal temperature, firstly adding broken stone and machine-made sand, stirring for 25-35s, then adding cement, fly ash and mineral powder, stirring for 25-35s, then adding water, water reducing agent and accelerator, stirring for 40-50s, finally adding hydrophobic mineral powder and hydrophobic modified plant fiber, and stirring for 25-35s.
10. The construction method of the airport drainage ditch slope concrete is characterized by comprising the following steps of:
step 1: detecting raw materials;
step 2: the method comprises the steps of calculating the weight parts of cement, fly ash, slag, machine-made sand, broken stone, air-entraining water reducer, accelerator, hydrophobic auxiliary agent and water to obtain a preliminary mixing ratio;
step 3: through real matching and detection, workability is adjusted, and the preliminary matching proportion is corrected to obtain a reference matching proportion;
step 4: on the premise of meeting the design strength, determining the scheme with the least cement consumption, thereby further adjusting and obtaining the mixing ratio of the laboratory, and the weight parts of the components converted according to the mixing ratio of the laboratory are as follows: 95-105 parts of cement, 30-35 parts of fly ash, 25-30 parts of slag, 450-458 parts of machine-made sand, 485-495 parts of broken stone, 1-2 parts of air-entraining water reducer, 7-9 parts of accelerator, 35-40 parts of hydrophobic auxiliary agent and 65-70 parts of water, wherein the hydrophobic auxiliary agent comprises the following components in percentage by mass: (0.6-0.8) a hydrophobic mineral powder and a hydrophobically modified plant fiber;
step 5: adjusting according to the water content of the raw materials and weather conditions to obtain a construction mixing ratio;
step 6: and adding the components with the specified weight fractions into the mixing building according to the construction mixing proportion for mixing to obtain the concrete.
CN202310918217.XA 2023-07-25 2023-07-25 Airport drainage ditch slope concrete and preparation method and construction method thereof Pending CN117185713A (en)

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US20020059886A1 (en) * 2000-10-04 2002-05-23 Merkley Donald J. Fiber cement composite materials using sized cellulose fibers
FR3006311A1 (en) * 2013-06-04 2014-12-05 Italcementi Spa CEMENT MATRIX FOR GROUT, LIGHT CONCRETE MORTAR, CEMENTITIOUS COMPOSITIONS INCLUDING SUCH A MATRIX, AND USES THEREOF FOR STRUCTURAL LIGHT MIXTURES
CN108610652A (en) * 2018-04-26 2018-10-02 成都新柯力化工科技有限公司 A kind of wood-plastic composite panel and preparation method of the plant fiber containing hydrophobically modified
CN109897592A (en) * 2019-03-27 2019-06-18 北京林业大学 A kind of plant fiber modified soy-bean protein adhesive of biomimetic modification and preparation method thereof
CN114085052A (en) * 2021-12-22 2022-02-25 中建商品混凝土有限公司 Super-hydrophobic concrete based on high-stone-powder-content machine-made sand and preparation method thereof
CN114656217A (en) * 2022-04-08 2022-06-24 北京建工集团有限责任公司 Impervious high-durability mass concrete and preparation method thereof
CN114804778A (en) * 2022-05-23 2022-07-29 中交二公局萌兴工程有限公司 Super-retarding concrete for bridge construction and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020059886A1 (en) * 2000-10-04 2002-05-23 Merkley Donald J. Fiber cement composite materials using sized cellulose fibers
FR3006311A1 (en) * 2013-06-04 2014-12-05 Italcementi Spa CEMENT MATRIX FOR GROUT, LIGHT CONCRETE MORTAR, CEMENTITIOUS COMPOSITIONS INCLUDING SUCH A MATRIX, AND USES THEREOF FOR STRUCTURAL LIGHT MIXTURES
CN108610652A (en) * 2018-04-26 2018-10-02 成都新柯力化工科技有限公司 A kind of wood-plastic composite panel and preparation method of the plant fiber containing hydrophobically modified
CN109897592A (en) * 2019-03-27 2019-06-18 北京林业大学 A kind of plant fiber modified soy-bean protein adhesive of biomimetic modification and preparation method thereof
CN114085052A (en) * 2021-12-22 2022-02-25 中建商品混凝土有限公司 Super-hydrophobic concrete based on high-stone-powder-content machine-made sand and preparation method thereof
CN114656217A (en) * 2022-04-08 2022-06-24 北京建工集团有限责任公司 Impervious high-durability mass concrete and preparation method thereof
CN114804778A (en) * 2022-05-23 2022-07-29 中交二公局萌兴工程有限公司 Super-retarding concrete for bridge construction and preparation method thereof

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