CN117494395B - Fluid migration calculation method and system based on one-dimensional steady flow model - Google Patents
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Abstract
Description
技术领域Technical Field
本发明涉及流体运移计算技术领域,尤其涉及基于一维稳态流模型的流体运移计算方法及系统。The present invention relates to the field of fluid migration calculation technology, and in particular to a fluid migration calculation method and system based on a one-dimensional steady-state flow model.
背景技术Background technique
幔源流体组分(如He、CO2、N2)是了解地球表面和内部之间质量和能量演化的重要手段,在火山爆发、地震监测、查明潜在的地热资源方面具有重要作用。在新生代火山区,如洋中脊、俯冲带的火山弧和热点区,岩浆是幔源氦上升至地表释放的载体,然而,在缺乏近代火山活动的大陆地区,幔源氦的来源及释放机理仍不清楚。定量评价幔源流体的运移速率及通过地壳的时间尺度,对于理解构造发生时间和活动性至关重要,也为地震监测及探寻地热资源开发有利区提供理论指导。现阶段,定量评价幔源流体运移速率的方法为幔源氦气平均流速的计算,其应用于计算加利福尼亚州圣安德烈亚斯断层系统的流体上升速率或是被运用于秘鲁板片释放流体的运移速率,但是,现有方法未考虑地壳的孔隙度,将流体作为管道流处理,忽略地壳孔隙度会造成估算流速比实际流速低1-2个数量级,或是忽略了岩石密度和流体密度的差异性即忽略了地质参数,因此,现有方法不能真实地反映幔源流体的真实运移状况。Mantle-derived fluid components (such as He, CO 2 , N 2 ) are important means to understand the evolution of mass and energy between the Earth's surface and interior, and play an important role in volcanic eruptions, earthquake monitoring, and identifying potential geothermal resources. In Cenozoic volcanic areas, such as mid-ocean ridges, volcanic arcs in subduction zones, and hotspots, magma is the carrier of mantle-derived helium rising to the surface and released. However, in continental areas lacking modern volcanic activity, the source and release mechanism of mantle-derived helium remain unclear. Quantitative evaluation of the migration rate of mantle-derived fluids and the time scale of their passage through the crust is crucial to understanding the timing and activity of tectonic occurrence, and also provides theoretical guidance for earthquake monitoring and the exploration of favorable areas for geothermal resource development. At present, the method for quantitatively evaluating the migration rate of mantle-derived fluids is to calculate the average flow rate of mantle-derived helium, which is used to calculate the fluid ascent rate in the San Andreas fault system in California or is used to calculate the migration rate of fluid released from the Peruvian plate. However, the existing methods do not take into account the porosity of the crust and treat the fluid as a pipe flow. Ignoring the porosity of the crust will cause the estimated flow rate to be 1-2 orders of magnitude lower than the actual flow rate, or ignoring the difference between rock density and fluid density, that is, ignoring geological parameters. Therefore, the existing methods cannot truly reflect the actual migration conditions of mantle-derived fluids.
发明内容Summary of the invention
为了解决上述技术问题,本发明的目的是提供基于一维稳态流模型的流体运移计算方法及系统,通过考虑地壳岩石的渗透性和密度构建一维稳态流模型进行地热流体幔源氦的迁移速度的估算,能够真实地反映幔源流体的真实运移状况。In order to solve the above technical problems, the purpose of the present invention is to provide a fluid migration calculation method and system based on a one-dimensional steady-state flow model. By considering the permeability and density of crustal rocks to construct a one-dimensional steady-state flow model to estimate the migration velocity of mantle-derived helium in geothermal fluid, it can truly reflect the actual migration conditions of mantle-derived fluids.
本发明所采用的第一技术方案是:基于一维稳态流模型的流体运移计算方法,包括以下步骤:The first technical solution adopted by the present invention is: a fluid migration calculation method based on a one-dimensional steady-state flow model, comprising the following steps:
采集地热气体并进行空气污染校正处理,得到校正后的地热气体;Collecting geothermal gas and performing air pollution correction processing to obtain corrected geothermal gas;
考虑地壳岩石的渗透性和密度,构建一维稳态流模型;Considering the permeability and density of crustal rocks, a one-dimensional steady flow model is constructed;
根据所述一维稳态流模型对所述校正后的地热气体进行估算,得到所述校正后的地热气体的运移速率。The corrected geothermal gas is estimated according to the one-dimensional steady-state flow model to obtain the corrected geothermal gas migration rate.
进一步,所述采集地热气体并进行空气污染校正处理,得到校正后的地热气体这一步骤,其具体包括:Furthermore, the step of collecting geothermal gas and performing air pollution correction processing to obtain corrected geothermal gas specifically includes:
通过排水集气法对地热流体进行采集处理,得到地热气体;The geothermal fluid is collected and processed by the drainage gas collection method to obtain geothermal gas;
通过质谱仪对所述地热气体进行组分分析处理,得到气体的组分;Performing component analysis on the geothermal gas by means of a mass spectrometer to obtain the components of the gas;
通过惰性气体质谱仪对所述气体的组分进行测定处理,确定地热气体3He/4He的比值和地热气体4He/20Ne的比值;The components of the gas are measured and processed by an inert gas mass spectrometer to determine the ratio of 3 He/ 4 He of the geothermal gas and the ratio of 4 He/ 20 Ne of the geothermal gas;
基于所述地热气体4He/20Ne的比值对所述地热气体3He/4He的比值进行空气污染校正处理,得到校正后的地热气体3He/4He的比值。Based on the ratio of 4 He/ 20 Ne of the geothermal gas, the ratio of 3 He/ 4 He of the geothermal gas is subjected to air pollution correction processing to obtain the corrected ratio of 3 He/ 4 He of the geothermal gas.
进一步,所述校正处理这一步骤,其具体包括:Further, the correction process step specifically includes:
根据大气中的4He/20Ne比值与地热气体4He/20Ne的比值确定校正判定系数;The correction determination coefficient is determined based on the 4 He/ 20 Ne ratio in the atmosphere and the 4 He/ 20 Ne ratio in the geothermal gas;
构建校正判定系数阈值;Construct the threshold of the corrected determination coefficient;
选取所述校正判定系数大于所述校正判定系数阈值对应的地热气体为校正后的地热气体。进一步,所述校正处理的表达式具体如下所示:The geothermal gas corresponding to the correction determination coefficient being greater than the correction determination coefficient threshold is selected as the corrected geothermal gas. Further, the expression of the correction processing is specifically as follows:
Rc/Ra=[(Ryp/Ra)X-1]/(X-1)R c / Ra = [(R yp / Ra )X-1]/(X-1)
X=(4He/20Ne)yp/(4He/20Ne)air X=( 4 He/ 20 Ne) yp /( 4 He/ 20 Ne) air
上式中,Rc表示校正后的3He/4He比值,Ra表示大气中的3He/4He比值,(4He/20Ne)air表示大气中的4He/20Ne比值,(4He/20Ne)yp表示地热气体4He/20Ne的比值,Ryp表示地热气体3He/4He的比值,X表示校正判定系数。In the above formula, R c represents the corrected 3 He/ 4 He ratio, Ra represents the 3 He/ 4 He ratio in the atmosphere, ( 4 He/ 20 Ne) air represents the 4 He/ 20 Ne ratio in the atmosphere, ( 4 He/ 20 Ne) yp represents the geothermal gas 4 He/ 20 Ne ratio, R yp represents the geothermal gas 3 He/ 4 He ratio, and X represents the correction determination coefficient.
进一步,所述一维稳态流模型的表达式具体如下所示:Furthermore, the expression of the one-dimensional steady-state flow model is specifically as follows:
上式中,q表示幔源流体运移速率,t表示幔源流体运移时间,Hc表示地热流体穿过地壳厚度,P(4He)表示地壳岩石中4He的生成速率,ρs表示地壳岩石密度,表示孔隙度,[4He]i,mantle表示幔源流体中4He的初始浓度,ρf表示地壳流体密度,Rs表示地热气体样品的3He/4He比值,Rc表示地壳岩石中3He/4He比值,Ri,mantle表示幔源流体初始3He/4He比值。In the above formula, q represents the migration rate of mantle-derived fluid, t represents the migration time of mantle-derived fluid, Hc represents the thickness of the crust through which geothermal fluid passes, P( 4He ) represents the generation rate of 4He in crustal rocks, ρs represents the density of crustal rocks, represents porosity, [ 4 He] i,mantle represents the initial 4 He concentration in mantle-derived fluid, ρ f represents the density of crustal fluid, R s represents the 3 He/ 4 He ratio of geothermal gas sample, R c represents the 3 He/ 4 He ratio in crustal rock, and R i,mantle represents the initial 3 He/ 4 He ratio of mantle-derived fluid.
进一步,所述根据所述一维稳态流模型对所述校正后的地热气体进行估算,得到所述校正后的地热气体的运移速率这一步骤,其具体包括:Furthermore, the step of estimating the corrected geothermal gas according to the one-dimensional steady-state flow model to obtain the corrected geothermal gas migration rate specifically includes:
确定地壳岩石中3He的生成速率和4He的生成速率;Determine the generation rate of 3 He and the generation rate of 4 He in crustal rocks;
考虑地壳岩石的密度、地壳流体密度和地壳岩石的孔隙度,并结合地壳岩石中3He的生成速率和4He的生成速率,获取地壳岩石生成的3He和4He在地壳流体中的累积速率;Considering the density of crustal rocks, the density of crustal fluids and the porosity of crustal rocks, and combining the generation rate of 3 He and the generation rate of 4 He in crustal rocks, the accumulation rate of 3 He and 4 He generated from crustal rocks in crustal fluids is obtained;
确定地热水中的He浓度并结合所述校正后的3He/4He比值,获取地幔流体中4He的初始浓度;Determine the He concentration in the geothermal water and combine it with the corrected 3 He/ 4 He ratio to obtain the initial 4 He concentration in the mantle fluid;
根据所述地壳岩石生成的3He和4He在地壳流体中的累积速率以及所述地幔流体中4He的初始浓度,确定校正后的地热气体的运移时间;Determine the corrected migration time of geothermal gas according to the accumulation rate of 3 He and 4 He generated by the crustal rocks in the crustal fluid and the initial concentration of 4 He in the mantle fluid;
结合地壳岩石的厚度,确定校正后的地热气体的运移速率。Combined with the thickness of the crustal rocks, the corrected geothermal gas migration rate is determined.
进一步,所述获取地壳岩石生成的3He和4He在地壳流体中的累积速率的表达式具体如下所示:Furthermore, the expression for obtaining the accumulation rate of 3 He and 4 He generated by crustal rocks in crustal fluids is specifically as follows:
上式中,A(3,4He)表示地壳岩石生成的3He和4He在地壳流体中的累积速率,P(3,4He)表示地壳岩石中3He的生成速率和4He的生成速率,ρs表示地壳岩石的密度,ρf表示地壳流体密度,表示地壳岩石的孔隙度。In the above formula, A( 3,4 He) represents the accumulation rate of 3 He and 4 He generated by crustal rocks in crustal fluids, P( 3,4 He) represents the generation rate of 3 He and 4 He in crustal rocks, ρs represents the density of crustal rocks, ρf represents the density of crustal fluids, Represents the porosity of crustal rocks.
进一步,所述获取地幔流体中4He的初始浓度的表达式具体如下所示:Furthermore, the expression for obtaining the initial concentration of 4 He in the mantle fluid is specifically as follows:
[4He]i,mantle=[4He]s×F(4He)[ 4 He] i,mantle =[ 4 He] s ×F( 4 He)
上式中,[4He]i,mantle表示地幔流体中4He的初始浓度,[4He]s表示地热水中的He浓度,F(4He)表示幔源4He所占比例。In the above formula, [ 4He ] i,mantle represents the initial concentration of 4He in the mantle fluid, [ 4He ] s represents the He concentration in geothermal water, and F( 4He ) represents the proportion of mantle-derived 4He .
进一步,所述确定校正后的地热气体的运移时间的表达式具体如下所示:Furthermore, the expression for determining the corrected migration time of geothermal gas is specifically as follows:
上式中,t表示校正后的地热气体的运移时间。In the above formula, t represents the corrected migration time of geothermal gas.
本发明所采用的第二技术方案是:基于一维稳态流模型的流体运移计算系统,包括:The second technical solution adopted by the present invention is: a fluid migration calculation system based on a one-dimensional steady-state flow model, comprising:
校正模块,用于采集地热气体并进行空气污染校正处理,得到校正后的地热气体;A correction module, used for collecting geothermal gas and performing air pollution correction processing to obtain corrected geothermal gas;
构建模块,用于考虑地壳岩石的渗透性和密度,构建一维稳态流模型;A building block for constructing a one-dimensional steady-state flow model taking into account the permeability and density of crustal rocks;
估算模块,用于根据所述一维稳态流模型对所述校正后的地热气体进行估算,得到所述校正后的地热气体的运移速率。An estimation module is used to estimate the corrected geothermal gas according to the one-dimensional steady-state flow model to obtain the migration rate of the corrected geothermal gas.
本发明方法及系统的有益效果是:本发明通过采集地热气体并进行校正处理,避免了采样和测试过程中可能引起的空气污染,进一步考虑地壳岩石的渗透性和密度,构建一维稳态流模型,更能揭示天然条件下的流体在岩石圈尺度的运移规律,通过构建一维稳态流模型估算了地热流体幔源氦的迁移速度和运移时间,提供了岩石圈结构的地球化学约束,并确定出热田的流体上升部位,能够真实地反映幔源流体的真实运移状况。The beneficial effects of the method and system of the present invention are as follows: the present invention avoids air pollution that may be caused during sampling and testing by collecting geothermal gas and performing correction processing, further considers the permeability and density of crustal rocks, and constructs a one-dimensional steady-state flow model, which can better reveal the migration law of fluids under natural conditions at the lithospheric scale. By constructing a one-dimensional steady-state flow model, the migration speed and migration time of mantle-derived helium in geothermal fluids are estimated, geochemical constraints on the lithospheric structure are provided, and the fluid rising position of the geothermal field is determined, which can truly reflect the actual migration status of the mantle-derived fluid.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是本发明实施例基于一维稳态流模型的流体运移计算方法的步骤流程图;FIG1 is a flow chart of the steps of a fluid migration calculation method based on a one-dimensional steady-state flow model according to an embodiment of the present invention;
图2是本发明实施例基于一维稳态流模型的流体运移计算系统的结构框图;2 is a structural block diagram of a fluid migration calculation system based on a one-dimensional steady-state flow model according to an embodiment of the present invention;
图3是本发明具体实施例通过排水集气法采集地热气体的装置示意图;FIG3 is a schematic diagram of a device for collecting geothermal gas by a drainage gas collection method according to a specific embodiment of the present invention;
图4是本发明具体实施例在孔隙度10%情况下通过本发明计算方法与现有计算方法计算流体运移速率的比较示意图;4 is a schematic diagram showing a comparison of the fluid migration rate calculated by the calculation method of the present invention and the existing calculation method under the condition of a porosity of 10% in a specific embodiment of the present invention;
图5是本发明具体实施例在孔隙度1%情况下通过本发明计算方法与现有计算方法计算流体运移速率的比较示意图。FIG5 is a schematic diagram showing a comparison of the fluid migration rate calculated by the calculation method of the present invention and the existing calculation method under the condition of 1% porosity in a specific embodiment of the present invention.
具体实施方式Detailed ways
下面结合附图和具体实施例对本发明做进一步的详细说明。对于以下实施例中的步骤编号,其仅为了便于阐述说明而设置,对步骤之间的顺序不做任何限定,实施例中的各步骤的执行顺序均可根据本领域技术人员的理解来进行适应性调整。The present invention is further described in detail below in conjunction with the accompanying drawings and specific embodiments. The step numbers in the following embodiments are only provided for the convenience of explanation and description, and the order between the steps is not limited in any way. The execution order of each step in the embodiment can be adaptively adjusted according to the understanding of those skilled in the art.
幔源流体组分(如He、CO2、N2)是了解地球表面和内部之间质量和能量演化的重要手段,在火山爆发、地震监测、并查明潜在的地热资源方面具有重要作用。温泉和地热井释放大量热液流体(如He、CO2、N2)。幔源氦含更多原始气体,富集3He(3He/4He=8±1Ra,其中Ra为大气的3He/4He比值,为1.39×10-6);壳源氦则富集4He,由U(235,238U)、Th(232Th)通过α放射性衰变产生,3He/4He值较低(~0.02RA),因此基于壳源氦与幔源氦的3He/4He比值差异性可以有效识别地幔气体脱气的区域。在新生代火山区,如洋中脊、俯冲带的火山弧和热点区,岩浆是幔源氦上升至地表释放的载体。然而,在缺乏近代火山活动的大陆地区,幔源氦的来源及释放机理仍不清楚。已有的研究表明在缺乏近代火山区,引起幔源氦释放的潜在因素包括:地幔熔体侵入浅层地壳的伸展构造区、右旋剪切应变增加引起的岩石圈尺度的渗透率增强、岩石圈走滑断层或板块来源的流体活化大陆岩石圈地幔中的氦。定量评价这些过程,如幔源流体的运移速率及通过地壳的时间尺度,对于理解构造发生时间和活动性至关重要,也为地震监测及探寻地热资源开发有利区提供理论指导。温泉和地热井释放大量热液流体(如He、CO2、N2)。目前基于温泉和地热井采集到的气体,定量评价幔源氦气运移速率的方法主要有以下2种:Mantle-derived fluid components (such as He, CO 2 , and N 2 ) are important means of understanding the evolution of mass and energy between the Earth's surface and interior, and play an important role in volcanic eruptions, earthquake monitoring, and identifying potential geothermal resources. Hot springs and geothermal wells release a large amount of hydrothermal fluids (such as He, CO 2 , and N 2 ). Mantle-derived helium contains more original gas and is enriched in 3 He ( 3 He/ 4 He = 8±1Ra, where Ra is the 3 He/ 4 He ratio of the atmosphere, which is 1.39×10 -6 ); crust-derived helium is enriched in 4 He, which is produced by U ( 235,238 U) and Th ( 232 Th) through α radioactive decay, and has a lower 3 He/ 4 He value (~ 0.02RA ). Therefore, based on the difference in the 3 He/ 4 He ratio between crust-derived helium and mantle-derived helium, the area of mantle gas degassing can be effectively identified. In Cenozoic volcanic areas, such as mid-ocean ridges, volcanic arcs in subduction zones, and hotspots, magma is the carrier of mantle-derived helium rising to the surface and being released. However, in continental areas lacking modern volcanic activity, the source and release mechanism of mantle-derived helium remain unclear. Existing studies have shown that in areas lacking modern volcanism, potential factors causing mantle-derived helium release include: extensional tectonic zones where mantle melts intrude into the shallow crust, enhanced permeability at the lithospheric scale caused by increased right-lateral shear strain, and activation of helium in the continental lithospheric mantle by lithospheric strike-slip faults or plate-derived fluids. Quantitative evaluation of these processes, such as the migration rate of mantle-derived fluids and the time scale of their passage through the crust, is crucial to understanding the timing and activity of tectonic occurrence, and also provides theoretical guidance for seismic monitoring and the exploration of favorable areas for geothermal resource development. Hot springs and geothermal wells release large amounts of hydrothermal fluids (such as He, CO 2 , and N 2 ). Currently, there are two main methods for quantitatively evaluating the migration rate of mantle-derived helium based on gases collected from hot springs and geothermal wells:
方法1:平均流速可由以下公式计算Method 1: The average flow rate can be calculated by the following formula
该方法广泛应用于计算加利福尼亚州圣安德烈亚斯断层系统的流体上升速率。This method is widely used to calculate fluid rise rates in the San Andreas fault system in California.
方法2:Method 2:
该方法被运用于秘鲁板片释放流体的运移速率。The method was applied to the migration rates of fluids released from the Peruvian slab.
但是,方法1未考虑地壳的孔隙度,将流体做为管道流处理。而根据实际情况,下地壳孔隙度上限为1%,而中上地壳的孔隙度通常取10%,因此,忽略地壳孔隙度会造成估算流速比实际流速低1-2个数量级。而方法2则忽略了岩石密度和流体密度的差异性,通常地壳的平均密度为2.8g cm-3,流体密度取1.0g cm-3,可以看出,2种方法在不同程度上忽略了地质参数,不能真实地反映幔源流体的真实运移状况。However, method 1 does not consider the porosity of the crust and treats the fluid as a pipe flow. According to actual conditions, the upper limit of the porosity of the lower crust is 1%, while the porosity of the middle and upper crust is usually 10%. Therefore, ignoring the porosity of the crust will cause the estimated flow rate to be 1-2 orders of magnitude lower than the actual flow rate. Method 2 ignores the difference between rock density and fluid density. Usually, the average density of the crust is 2.8g cm -3 , and the fluid density is 1.0g cm -3 . It can be seen that the two methods ignore geological parameters to varying degrees and cannot truly reflect the actual migration of mantle-derived fluids.
基于此,参照图1,本发明提供了基于一维稳态流模型的流体运移计算方法,该方法包括以下步骤:Based on this, referring to FIG. 1 , the present invention provides a fluid migration calculation method based on a one-dimensional steady-state flow model, the method comprising the following steps:
S1、采集地热气体并进行空气污染校正处理,得到校正后的地热气体;S1. Collect geothermal gas and perform air pollution correction processing to obtain corrected geothermal gas;
S11、通过排水集气法对地热流体进行采集处理,得到地热气体;S11, collecting and processing geothermal fluid by drainage and gas collection method to obtain geothermal gas;
具体地,从温泉或地热井中采集地热气体(如He,CO2,N2)。气体采集采用排水集气法,将连接硅胶管的漏斗倒置浸没于温泉泉口,最初将盐水玻璃瓶(50mL)装满地热水,浸没在地热水中。当地热水和气体将硅胶管和漏斗冲洗30min后,将硅管伸入玻璃瓶中,采用集气排水法进行气体收集,如图3所示,至瓶中留有少量地热水(密封),用橡胶塞密封玻璃瓶,整个过程中玻璃瓶口始终浸没在地热水面以下;之后取出玻璃瓶进一步用铝盖密封,装入盛满相应地热水的500ml的聚乙烯瓶中,确保无气泡残留,用封口胶进行密封,以避免运输过程中的大气污染。Specifically, geothermal gas (such as He, CO 2 , N 2 ) is collected from hot springs or geothermal wells. The gas is collected by the drainage gas collection method. The funnel connected to the silicone tube is inverted and immersed in the hot spring mouth. Initially, the salt water glass bottle (50 mL) is filled with geothermal water and immersed in the geothermal water. After the local hot water and gas rinse the silicone tube and the funnel for 30 minutes, the silicon tube is inserted into the glass bottle, and the gas is collected by the gas collection and drainage method, as shown in Figure 3, until a small amount of geothermal water remains in the bottle (sealed), and the glass bottle is sealed with a rubber stopper. During the whole process, the mouth of the glass bottle is always immersed below the surface of the geothermal water; then the glass bottle is taken out and further sealed with an aluminum cap, and placed in a 500 ml polyethylene bottle filled with the corresponding geothermal water to ensure that there is no bubble residue, and sealed with sealing glue to avoid atmospheric pollution during transportation.
S12、通过质谱仪对所述地热气体进行组分分析处理,得到气体的组分;S12, performing component analysis on the geothermal gas by means of a mass spectrometer to obtain components of the gas;
S13、通过惰性气体质谱仪对所述气体的组分进行测定处理,确定地热气体3He/4He的比值和地热气体4He/20Ne的比值;S13, measuring and processing the components of the gas by an inert gas mass spectrometer to determine the ratio of 3 He/ 4 He of the geothermal gas and the ratio of 4 He/ 20 Ne of the geothermal gas;
具体地,气体组分和同位素分析是在中国科学院地质与地球物理研究所兰州油气中心的稳定同位素组成分析实验室和稀有气体同位素分析实验室完成,气体组分使用MAT271质谱仪进行测定,检测限为0.0001%,相对标准误差<5%;3He/4He和4He/20Ne比值是由Noblesse惰性气体质谱仪(Nu Instruments,UK)测定的。Specifically, gas composition and isotope analysis were performed in the Stable Isotope Composition Analysis Laboratory and the Rare Gas Isotope Analysis Laboratory of Lanzhou Oil and Gas Center, Institute of Geology and Geophysics, Chinese Academy of Sciences. The gas composition was determined using a MAT271 mass spectrometer with a detection limit of 0.0001% and a relative standard error of <5%. The 3 He/ 4 He and 4 He/ 20 Ne ratios were determined by a Noblesse inert gas mass spectrometer (Nu Instruments, UK).
S14、基于所述地热气体4He/20Ne的比值对所述地热气体3He/4He的比值进行校正处理,得到校正后的地热气体。S14. Correcting the ratio of 3 He/ 4 He of the geothermal gas based on the ratio of 4 He/ 20 Ne of the geothermal gas to obtain corrected geothermal gas.
S141、根据大气中的4He/20Ne比值与地热气体4He/20Ne的比值确定校正判定系数;S141. Determine the correction determination coefficient based on the 4 He/ 20 Ne ratio in the atmosphere and the 4 He/ 20 Ne ratio in the geothermal gas;
S142、构建校正判定系数阈值;S142, constructing a correction determination coefficient threshold;
S143、选取所述校正判定系数大于所述校正判定系数阈值对应的地热气体为校正后的地热气体。S143, selecting the geothermal gas corresponding to the correction determination coefficient being greater than the correction determination coefficient threshold as the corrected geothermal gas.
具体地,为了消除在采样和测试过程中可能引起的空气污染,假定样品中的Ne全部来自于大气,基于样品中的4He/20Ne比值对样品中的3He/4He比值进行校正,具体如下所示:Specifically, in order to eliminate possible air pollution during sampling and testing, it is assumed that all Ne in the sample comes from the atmosphere, and the 3 He/ 4 He ratio in the sample is corrected based on the 4 He/ 20 Ne ratio in the sample, as shown below:
Rc/Ra=[(Ryp/Ra)X-1]/(X-1)R c / Ra = [(R yp / Ra )X-1]/(X-1)
X=(4He/20Ne)yp/(4He/20Ne)air X=( 4 He/ 20 Ne) yp /( 4 He/ 20 Ne) air
上式中,Rc表示校正后的3He/4He比值,Ra表示大气中的3He/4He比值,(4He/20Ne)air表示大气中的4He/20Ne比值,(4He/20Ne)yp表示地热气体4He/20Ne的比值,Ryp表示地热气体3He/4He的比值,X表示校正判定系数;In the above formula, R c represents the corrected 3 He/ 4 He ratio, Ra represents the 3 He/ 4 He ratio in the atmosphere, ( 4 He/ 20 Ne) air represents the 4 He/ 20 Ne ratio in the atmosphere, ( 4 He/ 20 Ne) yp represents the geothermal gas 4 He/ 20 Ne ratio, R yp represents the geothermal gas 3 He/ 4 He ratio, and X represents the correction determination coefficient;
当样品的X值大于10,表明氦同位素组成受大气氦的影响较小,X值小于10,表明样品污染严重,数据不能使用。When the X value of the sample is greater than 10, it indicates that the helium isotope composition is less affected by atmospheric helium. When the X value is less than 10, it indicates that the sample is seriously contaminated and the data cannot be used.
S2、考虑地壳岩石的渗透性和密度,构建一维稳态流模型;S2. Considering the permeability and density of crustal rocks, a one-dimensional steady-state flow model is constructed;
具体地,一维稳态流模型的表达式具体如下所示:Specifically, the expression of the one-dimensional steady flow model is as follows:
上式中,q表示幔源流体运移速率,t表示幔源流体运移时间,Hc表示地热流体穿过地壳厚度,P(4He)表示地壳岩石中4He的生成速率,ρs表示地壳岩石密度,表示孔隙度,[4He]i,mantle表示幔源流体中4He的初始浓度,ρf表示地壳流体密度,Rs表示地热气体样品的3He/4He比值,Rc表示地壳岩石中3He/4He比值,Ri,mantle表示幔源流体初始3He/4He比值。In the above formula, q represents the migration rate of mantle-derived fluid, t represents the migration time of mantle-derived fluid, Hc represents the thickness of the crust through which geothermal fluid passes, P( 4He ) represents the generation rate of 4He in crustal rocks, ρs represents the density of crustal rocks, represents porosity, [ 4 He] i,mantle represents the initial 4 He concentration in mantle-derived fluid, ρ f represents the density of crustal fluid, R s represents the 3 He/ 4 He ratio of geothermal gas sample, R c represents the 3 He/ 4 He ratio in crustal rock, and R i,mantle represents the initial 3 He/ 4 He ratio of mantle-derived fluid.
S3、根据所述一维稳态流模型对所述校正后的地热气体进行估算,得到所述校正后的地热气体的运移速率。S3. Estimate the corrected geothermal gas according to the one-dimensional steady-state flow model to obtain the migration rate of the corrected geothermal gas.
S31、确定地壳岩石中3He的生成速率和4He的生成速率;S31. Determine the generation rate of 3 He and the generation rate of 4 He in crustal rocks;
具体地,根据地壳岩石中Li、U和Th的浓度(以ppm为单位)来计算地壳中岩石的3He的生成速率(P(3He))和4He的生成速率(P(4He)(以cm3 STP g-1rock year-1为单位),其表达式为:Specifically, the generation rate of 3 He (P( 3 He)) and the generation rate of 4 He (P( 4 He)) in the crust (cm 3 STP g -1 rock year -1 ) are calculated based on the concentrations of Li, U and Th in the crustal rocks (in ppm). The expressions are:
P(3He)=(2.64×10-4[U]+6.40×10-5[Th])×[Li]×10-23×22414P( 3He )=(2.64× 10-4 [U]+6.40× 10-5 [Th])×[Li]× 10-23 ×22414
P(4He)=1.19634×10-13[U]+2.89665×10-14[Th]P( 4 He)=1.19634×10 -13 [U]+2.89665×10 -14 [Th]
上式中,P(3He)表示地壳中岩石的3He的生成速率,P(4He)表示地壳中岩石的4He的生成速率,Li、U和Th表示地壳岩石中Li、U和Th的浓度。In the above formula, P( 3 He) represents the generation rate of 3 He in rocks in the earth's crust, P( 4 He) represents the generation rate of 4 He in rocks in the earth's crust, and Li, U and Th represent the concentrations of Li, U and Th in crustal rocks.
S32、考虑地壳岩石的密度、地壳流体密度和地壳岩石的孔隙度,并结合地壳岩石中3He的生成速率和4He的生成速率,获取地壳岩石生成的3He和4He在地壳流体中的累积速率;S32. Considering the density of crustal rocks, the density of crustal fluids and the porosity of crustal rocks, and combining the generation rate of 3 He and the generation rate of 4 He in crustal rocks, the accumulation rate of 3 He and 4 He generated from crustal rocks in crustal fluids is obtained;
具体地,根据地壳密度(ρs),流体密度(ρf),为孔隙度,地壳中岩石的3He和4He生成速率(cm3 STP g-1rock year-1),计算地壳产生的3He和4He在流体中的累积速率(cm3 STPg-1H2O year-1),其表达式为:Specifically, according to the crust density (ρ s ), fluid density (ρ f ), is the porosity, the generation rate of 3 He and 4 He in the crust (cm 3 STP g -1 rock year -1 ), the accumulation rate of 3 He and 4 He in the crust (cm 3 STPg -1 H 2 O year -1 ) is calculated, and the expression is:
上式中,A(3,4He)表示地壳岩石生成的3He和4He在地壳流体中的累积速率,P(3,4He)表示地壳岩石中3He的生成速率和4He的生成速率,ρs表示地壳岩石的密度,ρf表示地壳流体密度,表示地壳岩石的孔隙度。In the above formula, A( 3,4 He) represents the accumulation rate of 3 He and 4 He generated by crustal rocks in crustal fluids, P( 3,4 He) represents the generation rate of 3 He and 4 He in crustal rocks, ρs represents the density of crustal rocks, ρf represents the density of crustal fluids, Represents the porosity of crustal rocks.
S33、确定地热水中的He浓度并结合所述校正后的3He/4He比值,获取幔源流体中4He的初始浓度;S33, determining the He concentration in the geothermal water and combining the corrected 3 He/ 4 He ratio to obtain the initial 4 He concentration in the mantle-derived fluid;
具体地,根据地热水中测量的He浓度和采样流体空气校正后的3He/4He比来计算幔源流体中4He的初始浓度([4He]i,mantle,cm3 g-1H2O),其表达式为:Specifically, the initial 4 He concentration in the mantle-derived fluid ([ 4 He] i,mantle , cm 3 g -1 H 2 O) is calculated based on the measured He concentration in the geothermal water and the 3 He/ 4 He ratio of the sampled fluid after air correction, and its expression is:
[4He]i,mdntle=[4He]s×F(4He)[ 4 He] i,mdntle =[ 4 He] s ×F( 4 He)
上式中,[4He]i,mantle表示幔源流体中4He的初始浓度,[4He]s表示地热水中的He浓度,F(4He)表示幔源4He所占比例,Rs表示地热气体样品的3He/4He比值,Rc表示地壳岩石中3He/4He比值,Rm表示地幔中3He/4He比值。In the above formula, [ 4He ] i,mantle represents the initial concentration of 4He in mantle-derived fluid, [ 4He ] s represents the He concentration in geothermal water, F( 4He ) represents the proportion of mantle-derived 4He , Rs represents the 3He / 4He ratio of geothermal gas samples, Rc represents the 3He / 4He ratio in crustal rocks, and Rm represents the 3He / 4He ratio in the mantle.
S34、根据所述地壳岩石生成的3He和4He在地壳流体中的累积速率以及所述幔源流体中4He的初始浓度,确定校正后的地热气体的运移时间;S34, determining the corrected migration time of geothermal gas according to the accumulation rate of 3 He and 4 He generated by the crustal rocks in the crustal fluid and the initial concentration of 4 He in the mantle-derived fluid;
具体地,初始的幔源流体在由地幔上升至地表的过程中会被地壳中放射性成因的4He和中子反应产生的3He进一步稀释,因此到达地表的幔源流体的3He/4He比值与运移时间有关,可由以下方程表示:Specifically, the initial mantle-derived fluid will be further diluted by the 3 He produced by the reaction of 4 He of radioactive origin and neutrons in the crust during its ascent from the mantle to the surface. Therefore, the 3 He/ 4 He ratio of the mantle-derived fluid reaching the surface is related to the migration time and can be expressed by the following equation:
Rs=(Ri,mantle×[4He]i,mantle+A(3He)×t)/([4He]i,mantle+A(4He)×t) Rs = (R i,mantle × [ 4 He] i,mantle + A( 3 He) × t) / ([ 4 He] i,mantle + A( 4 He) × t)
上式中,Rs表示样品空气污染校正后的3He/4He值,t表示流体运移时间,Ri,mantle和[4He]i,mantle分别表示幔源流体初始3He/4He比值(8±1Ra)和4He浓度(cm3 g-1H2O),A(3He)和A(4He)表示地壳产生的3He和4He在流体中的累积速率;In the above formula, Rs represents the 3 He/ 4 He value of the sample after air contamination correction, t represents the fluid migration time, R i,mantle and [ 4 He] i,mantle represent the initial 3 He/ 4 He ratio (8±1Ra) and 4 He concentration (cm 3 g -1 H 2 O) of the mantle-derived fluid, respectively, A( 3 He) and A( 4 He) represent the accumulation rates of 3 He and 4 He produced in the crust in the fluid;
可以得出幔源流体的运移时间为:It can be concluded that the migration time of mantle-derived fluid is:
上式中,t表示校正后的地热气体的运移时间。In the above formula, t represents the corrected migration time of geothermal gas.
S35、结合地壳厚度,确定校正后的地热气体的运移速率。S35. Determine the corrected migration rate of geothermal gas based on the thickness of the earth's crust.
参照图4和图5,根据现有的方法1和方法2,三种方法对比可以看出,较本发明和方法2,方法1未考虑地壳的孔隙度,将流体做为管道流处理。而根据实际情况,下地壳孔隙度上限为1%,而中上地壳的孔隙度通常取10%,因此,忽略地壳孔隙度会造成估算流速比实际流速低1-2个数量级。而方法2较本研究和方法1则忽略了岩石密度和流体密度的差异性,通常地壳的平均密度为2.8g cm-3,立体密度取1.0g cm-3,因此本发明基于一维稳态流模型计算岩石圈尺度流体运移速率及时间的公式充分考虑地壳的渗透性、岩石及流体的密度的差异性,可以更真实地反映天然条件下幔源流体的平均上升速度。Referring to Figures 4 and 5, according to the existing methods 1 and 2, it can be seen from the comparison of the three methods that, compared with the present invention and method 2, method 1 does not consider the porosity of the crust and treats the fluid as a pipeline flow. According to actual conditions, the upper limit of the porosity of the lower crust is 1%, while the porosity of the middle and upper crust is usually 10%. Therefore, ignoring the porosity of the crust will cause the estimated flow rate to be 1-2 orders of magnitude lower than the actual flow rate. Compared with this study and method 1, method 2 ignores the differences in rock density and fluid density. Generally, the average density of the crust is 2.8g cm -3 , and the three-dimensional density is 1.0g cm -3 . Therefore, the formula for calculating the migration rate and time of the lithospheric scale fluid based on the one-dimensional steady-state flow model of the present invention fully considers the permeability of the crust, the differences in the density of rocks and fluids, and can more truly reflect the average rising speed of mantle-derived fluids under natural conditions.
进一步,以青藏高原为检测地区进行本发明的实验;Furthermore, the experiment of the present invention was carried out using the Qinghai-Tibet Plateau as the testing area;
野外采集青藏高原亚东谷露地堑系的羊八井和嘎日穷的地热流体,分析氦气含量和3He/4He比值(Rm),并进行空气污染校正(Rc),如表1和表2所示,孔隙度取下地壳的上限1%,根据地壳中U含量为1.3ppm,Th含量为5.6ppm,Th/U为4.3,地壳4He的平均产率P(4He)为3.17×10-13cm3 STP g-1rock year-1,地壳密度(ρs)为2.8g cm-3,流体密度(ρf)为1g cm-3;地壳厚度(Hc)根据地球物理资料获取,羊八井为75.2km,嘎日穷为74.3km,根据获取地幔源流体中4He的初始浓度的计算公式获取幔源4He初始含量[4He]i,mantle;将上述参数代入确定校正后的地热气体的运移时间的计算公式以及一维稳态流模型的计算公式即可获得地热流体羊八井的平均运移时间为20.2ka,上升运移速率3720mm/年,嘎日穷的平均运移时间为37.8ka和上升运移速率1960mm/年,可以看出羊八井较嘎日穷具有更好地流体上升通道,地热资源开采条件更为有利。同时也说明,基于青藏高原3He/4He比值揭示的深部动力学演化状态,是介于青藏高原岩石学(>8Ma)和地球物理探测方法所揭示的岩石圈结构状态之间。Geothermal fluids from Yangbajing and Gariqiong in the Yadong Valley graben system of the Qinghai-Tibet Plateau were collected in the field. The helium content and 3 He/ 4 He ratio (R m ) were analyzed and corrected for air pollution (R c ). As shown in Tables 1 and 2, the porosity Taking the upper limit of 1% of the crust, based on the U content of 1.3ppm, Th content of 5.6ppm, Th/U of 4.3, the average yield of 4 He in the crust P( 4 He) is 3.17×10 -13 cm 3 STP g -1 rock year -1 , the crust density (ρ s ) is 2.8g cm -3 , and the fluid density (ρ f ) is 1g cm -3 ; the crust thickness (H c ) is obtained according to geophysical data, which is 75.2km in Yangbajing and 74.3km in Gariqiong. The initial content of mantle-derived 4 He is obtained according to the calculation formula for the initial concentration of 4 He in mantle-derived fluid [ 4 He] i,mantle ; Substituting the above parameters into the calculation formula for determining the corrected geothermal gas migration time and the calculation formula of the one-dimensional steady-state flow model, we can obtain that the average migration time of geothermal fluid in Yangbajing is 20.2ka, the upward migration rate is 3720mm/year, and the average migration time of Gariqiong is 37.8ka and the upward migration rate is 1960mm/year. It can be seen that Yangbajing has a better fluid upward channel than Gariqiong, and the conditions for geothermal resource exploitation are more favorable. It also shows that the deep dynamic evolution state revealed by the 3 He/ 4 He ratio of the Qinghai-Tibet Plateau is between the lithosphere structure state revealed by the Qinghai-Tibet Plateau petrology (>8Ma) and geophysical detection methods.
表1青藏高原羊八井和嘎日穷地热气体3He/4He值校正Table 1 Correction of 3 He/ 4 He values of geothermal gases in Yangbajing and Gariqiong in the Qinghai-Tibet Plateau
表2青藏高原羊八井和嘎日穷地热流体上升速率及运移时间计算Table 2 Calculation of geothermal fluid rise rate and migration time in Yangbajing and Gariqiong in the Qinghai-Tibet Plateau
参照图2,基于一维稳态流模型的流体运移计算系统,包括:2, a fluid migration calculation system based on a one-dimensional steady-state flow model includes:
校正模块,用于采集地热气体并进行空气污染校正处理,得到校正后的地热气体;A correction module, used for collecting geothermal gas and performing air pollution correction processing to obtain corrected geothermal gas;
构建模块,用于考虑地壳岩石的渗透性和密度,构建一维稳态流模型;A building block for constructing a one-dimensional steady-state flow model taking into account the permeability and density of crustal rocks;
估算模块,用于根据所述一维稳态流模型对所述校正后的地热气体进行估算,得到所述校正后的地热气体的运移速率。An estimation module is used to estimate the corrected geothermal gas according to the one-dimensional steady-state flow model to obtain the migration rate of the corrected geothermal gas.
上述方法实施例中的内容均适用于本系统实施例中,本系统实施例所具体实现的功能与上述方法实施例相同,并且达到的有益效果与上述方法实施例所达到的有益效果也相同。The contents of the above method embodiments are all applicable to the present system embodiments. The functions specifically implemented by the present system embodiments are the same as those of the above method embodiments, and the beneficial effects achieved are also the same as those achieved by the above method embodiments.
以上是对本发明的较佳实施进行了具体说明,但本发明创造并不限于所述实施例,熟悉本领域的技术人员在不违背本发明精神的前提下还可做作出种种的等同变形或替换,这些等同的变形或替换均包含在本申请权利要求所限定的范围内。The above is a specific description of the preferred implementation of the present invention, but the invention is not limited to the embodiments. Those skilled in the art may make various equivalent modifications or substitutions without violating the spirit of the present invention. These equivalent modifications or substitutions are all included in the scope defined by the claims of this application.
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