CN110028729A - Armoured cable aluminium-plastic tape - Google Patents
Armoured cable aluminium-plastic tape Download PDFInfo
- Publication number
- CN110028729A CN110028729A CN201910319854.9A CN201910319854A CN110028729A CN 110028729 A CN110028729 A CN 110028729A CN 201910319854 A CN201910319854 A CN 201910319854A CN 110028729 A CN110028729 A CN 110028729A
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- China
- Prior art keywords
- plastic film
- parts
- aluminium
- aluminium foil
- plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229920003023 plastic Polymers 0.000 title claims abstract description 22
- 239000004033 plastic Substances 0.000 title claims abstract description 22
- 239000002985 plastic film Substances 0.000 claims abstract description 33
- 229920006255 plastic film Polymers 0.000 claims abstract description 33
- 239000005030 aluminium foil Substances 0.000 claims abstract description 25
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 10
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 8
- -1 propionic acid octadecanol ester Chemical class 0.000 claims abstract description 8
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims abstract description 5
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 5
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims abstract description 4
- ZQWICJYATMSSSD-UHFFFAOYSA-M chembl2028584 Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=C(O)C=C(S([O-])(=O)=O)C2=C1 ZQWICJYATMSSSD-UHFFFAOYSA-M 0.000 claims abstract description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims abstract description 4
- 239000007822 coupling agent Substances 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 4
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 229960002415 trichloroethylene Drugs 0.000 claims description 4
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 claims description 4
- FVWQVDPNRUAXBQ-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)O.C(C)(C)(C)C=1C(=C(C=C(C1)C(C)(C)C)CCC(=O)O)O Chemical compound C(CCCCCCCCCCCCCCCCC)O.C(C)(C)(C)C=1C(=C(C=C(C1)C(C)(C)C)CCC(=O)O)O FVWQVDPNRUAXBQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 21
- 239000003344 environmental pollutant Substances 0.000 abstract description 4
- 231100000719 pollutant Toxicity 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 5
- 235000010215 titanium dioxide Nutrition 0.000 description 5
- 238000004891 communication Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000007719 peel strength test Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/21—Anti-static
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2427/16—Homopolymers or copolymers of vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of armoured cable aluminium-plastic tapes, including aluminium foil and plastic film, the plastic film is covered on aluminium foil, one or both sides in lower surface, the plastic film includes the material of following parts by weight: 65 ~ 80 parts of ethylene acrylic acid co polymer, 5 ~ 15 parts of Kynoar, 3 ~ 12 parts of low density polyethylene (LDPE), 1 ~ 3 part of titanium dioxide, 1 ~ 3 part of calcium carbonate powder, 0.5 ~ 2.5 part of nano silica, 0.1 ~ 0.5 part of styrene-ethylene-butadiene-styrene copolymer grafted maleic anhydride, 0.3 ~ 1 part of dibutyl hydroxy toluene, β-(3, 5- di-tert-butyl-hydroxy phenyl) 0.3 ~ 1 part of propionic acid octadecanol ester, 0.1 ~ 0.5 part of acid chrome blue, oleic diethanola mide borate ester BODEA0.2 ~ 1 part, coupling 0.3 ~ 1 part of agent.The aluminium-plastic tape can be obtained by heat posted method technique, and there is good product quality, and even if plastic film, which still is able to realize under hot paste method technique, to be merged with the hot sticky of aluminium foil with good Hot Tack strength in the case where aluminium foil surface has a small amount of pollutant.
Description
Technical field
The present invention relates to a kind of polyethylene film more particularly to a kind of armoured cable aluminium-plastic tapes.
Background technique
Aluminium-plastic tape is mainly used for communications optical cable, communication cable outer jacket, is bonded together composition synthesis with protective cover material
Sheath acts the moisture-proof layer for protecting cable core to corrode from moisture, while having armouring effect to cable core, resists extraneous effect
Power lay etc. in various applications for communications optical cable, communication cable and provides mechanical protection, guarantees the stability, reliably of application
Property.It is plastic-aluminum combined to generally use plastic film gluing composite metal belt and curtain coating composite metal belt production technology acquisition, production
Process was not only complicated but also cumbersome.And the hot paste method production of use is just much simplified and is convenient for control, the high reliablity of product quality,
However requirement of the hot paste method to raw material (aluminium foil and compound plastic film) is high, the quality of the two is to influence composite band product matter
An important factor for amount.
Summary of the invention
It is an object of that present invention to provide a kind of armoured cable aluminium-plastic tape, the plastics of the armoured cable aluminium-plastic tape are thin
Film can be very good to be bonded with aluminium foil by heat posted method technique completely, while guarantee the product quality of aluminium-plastic tape, and
Even if still being able to realize the heat bonding with aluminium foil under hot paste method technique in the case where aluminium foil surface has a small amount of pollutant
And there is good Hot Tack strength.
In order to achieve the above objectives, the technical solution adopted by the present invention is that: a kind of armoured cable aluminium-plastic tape, including aluminium foil
And plastic film, the plastic film are covered on the one or both sides in aluminium foil upper and lower surfaces, the plastic film includes following
The material of parts by weight:
65 ~ 80 parts of ethylene acrylic acid co polymer,
5 ~ 15 parts of Kynoar,
3 ~ 12 parts of low density polyethylene (LDPE),
1 ~ 3 part of titanium dioxide,
1 ~ 3 part of calcium carbonate powder,
0.5 ~ 2.5 part of nano silica,
0.1 ~ 0.5 part of styrene-ethylene-butadiene-styrene copolymer grafted maleic anhydride,
0.3 ~ 1 part of dibutyl hydroxy toluene,
0.3 ~ 1 part of ester of β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol,
0.1 ~ 0.5 part of acid chrome blue,
0.2 ~ 1 part of oleic diethanola mide borate ester BODEA,
0.3 ~ 1 part of coupling agent.
Further improved technical solution is as follows in above-mentioned technical proposal:
1. in above scheme, the coupling agent be one of methyl-silicone oil, butyl titanate or trichloro ethylene base silane or
Two kinds.
2. in above scheme, the average grain diameter of the titanium dioxide and calcium carbonate powder is 0.5 ~ 50 micron.
Due to the application of the above technical scheme, compared with the prior art, the invention has the following advantages:
Armoured cable aluminium-plastic tape of the present invention, using 65 ~ 80 parts of ethylene acrylic acid co polymers as base in the formula of plastic film
Material is added 5 ~ 15 parts of Kynoar blendings, so that the plastic film has good thermal bonding and flexibility, and is added to
3 ~ 12 parts of low density polyethylene (LDPE), the Hot Tack strength of plastic film is further enhanced, so that plastic film passes through heat posted method technique
It can be very good to be bonded with aluminium foil, guarantee the product quality of aluminium-plastic tape, can also reduce between plastic film and aluminium foil
Thermal-adhering temperature;In addition, being also added into 0.5 ~ 2.5 part of nano silica and oleic diethanola mide borate ester in its formula
BODEA0.2 ~ 1 part, the two are cooperateed with Kynoar, so that plastic film has good antistatic and antifouling property, it can
Guarantee the clean type of plastic film itself, and there is good antifouling property, even if it is few to have plastic film in aluminium foil surface
In the case where measuring pollutant, it still is able to the realization under hot paste method technique and merges with the hot sticky of aluminium foil with good hot sticky strong
Degree.
Specific embodiment
The present invention will be further described below with reference to examples:
Embodiment 1 ~ 4: a kind of armoured cable aluminium-plastic tape, including aluminium foil and plastic film, the plastic film are covered on aluminium
One or both sides in foil upper and lower surfaces, it is characterised in that: the plastic film includes the material of following parts by weight:
Table 1
The coupling agent is one or both of methyl-silicone oil, butyl titanate or trichloro ethylene base silane, the titanium white
The average grain diameter of powder and calcium carbonate powder is 0.5 ~ 50 micron.
The plastic film of the armoured cable aluminium-plastic tape is made by following steps:
S1. 65 ~ 80 parts of ethylene acrylic acid co polymer, 1 ~ 3 part of titanium dioxide, 1 ~ 3 part of calcium carbonate powder, dibutyl hydroxy toluene are weighed
0.3 ~ 1 part, 0.3 ~ 1 part of β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester, 0.1 ~ 0.5 part of acid chrome blue, idol
Join in 0.3 ~ 1 part of investment high-speed mixer of agent, put into double screw extruder extruding pelletization after mixing, obtains material A;
S2. 0.5 ~ 2.5 part of nano silica, styrene-ethylene-butadiene-styrene copolymer grafted maleic anhydride are weighed
0.1 ~ 0.5 part, in the investment magnetic stirrer of oleic diethanola mide borate ester BODEA0.2 ~ 1 part, be stirred 20min, obtain
Material B;
S3. by 3 ~ 12 parts of 5 ~ 15 parts of material A, material B and Kynoar, low density polyethylene (LDPE) investment mixers, at mixing
It discharges after reason 15min, obtains mixing masterbatch;
S4. mixing masterbatch is fed into inflation film manufacturing machine, is squeezed out blown film to get the plastic film of the armoured cable aluminium-plastic tape.
Comparative example 1 ~ 3: a kind of aluminium-plastic tape, including aluminium foil and plastic film, the plastic film is covered on aluminium foil,
One or both sides in lower surface, it is characterised in that: the plastic film includes the material of following parts by weight:
Table 2
The coupling agent is one or both of methyl-silicone oil, butyl titanate or trichloro ethylene base silane, the titanium white
The average grain diameter of powder and calcium carbonate powder is 0.5 ~ 50 micron.
Preparation method is common method.
The film performance detection data of the aluminium-plastic tape of each embodiment and comparative example preparation is as follows:
Table 3
Wherein, peel strength test method are as follows: batten is made in the thermal-adhering product of film obtained and aluminium foil, along test length
Film and aluminium foil are peeled off about 30mm by direction in advance, batten are placed in measurer for pulling force, by the glass rate of 100mm/min
It is removed, the peel strength between film and aluminium foil is as unit of N/Cm.
As shown in table 3, the plastic film prepared in various embodiments of the present invention either mechanical stretching performance or heat seal is strong
Degree is significantly better than that the plastic film of comparative example, meanwhile, the peel strength of the plastic film prepared in various embodiments of the present invention
Better than the plastic film of comparative example, plastic film produced by the present invention can be can be very good completely by heat posted method technique and aluminium
Foil fitting, while guaranteeing the product quality of aluminium-plastic tape, and even if in the case where aluminium foil surface has a small amount of pollutant, still
It can so realize under hot paste method technique and merge with the hot sticky of aluminium foil with good Hot Tack strength.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention.It is all according to the present invention
Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.
Claims (3)
1. a kind of armoured cable aluminium-plastic tape, including aluminium foil and plastic film, the plastic film is covered on the upper and lower table of aluminium foil
One or both sides in face, it is characterised in that: the plastic film includes the material of following parts by weight:
65 ~ 80 parts of ethylene acrylic acid co polymer,
5 ~ 15 parts of Kynoar,
3 ~ 12 parts of low density polyethylene (LDPE),
1 ~ 3 part of titanium dioxide,
1 ~ 3 part of calcium carbonate powder,
0.5 ~ 2.5 part of nano silica,
0.1 ~ 0.5 part of styrene-ethylene-butadiene-styrene copolymer grafted maleic anhydride,
0.3 ~ 1 part of dibutyl hydroxy toluene,
0.3 ~ 1 part of ester of β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol,
0.1 ~ 0.5 part of acid chrome blue,
0.2 ~ 1 part of oleic diethanola mide borate ester BODEA,
0.3 ~ 1 part of coupling agent.
2. armoured cable aluminium-plastic tape according to claim 1, it is characterised in that: the coupling agent be methyl-silicone oil,
One or both of butyl titanate or trichloro ethylene base silane.
3. armoured cable aluminium-plastic tape according to claim 1, it is characterised in that: the titanium dioxide and calcium carbonate powder
Average grain diameter be 0.5 ~ 50 micron.
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| CN201910319854.9A CN110028729A (en) | 2019-04-19 | 2019-04-19 | Armoured cable aluminium-plastic tape |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910319854.9A CN110028729A (en) | 2019-04-19 | 2019-04-19 | Armoured cable aluminium-plastic tape |
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Application publication date: 20190719 |