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CN110105526A - A kind of green plants organic environmental-protection foam and its production technology - Google Patents

A kind of green plants organic environmental-protection foam and its production technology Download PDF

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Publication number
CN110105526A
CN110105526A CN201910426901.XA CN201910426901A CN110105526A CN 110105526 A CN110105526 A CN 110105526A CN 201910426901 A CN201910426901 A CN 201910426901A CN 110105526 A CN110105526 A CN 110105526A
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Prior art keywords
weight
parts
green plants
organic environmental
protection foam
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Pending
Application number
CN201910426901.XA
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Chinese (zh)
Inventor
吴聚精
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Individual
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Priority to CN201910426901.XA priority Critical patent/CN110105526A/en
Publication of CN110105526A publication Critical patent/CN110105526A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/36Hydroxylated esters of higher fatty acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/6696Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/36 or hydroxylated esters of higher fatty acids of C08G18/38
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00Manufacture of cellular products

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

The present invention relates to a kind of green plants organic environmental-protection foams, raw material including following parts by weight is prepared: the polyethers of 55~65 parts by weight, the plant polyatomic alcohol of 35~45 parts by weight, the water of 0.2~0.4 parts by weight, the silicone oil of 1.2~1.4 parts by weight, the catalyst of 0.5~0.7 parts by weight, the stannous octoate of 0.03~0.05 parts by weight, the MDI of 6~8 parts by weight, the TDI of 6~8 parts by weight, the color of 2~3 parts by weight, common foam compares on the market, green plants organic environmental-protection foam substitutes traditional oil polyalcohol applied in foam production using plant polyatomic alcohol, make green plants organic environmental-protection foam that there is degradability, solve the degradation and recycling problem of petroleum polyurethane products, effectively degradation is reduced to environment dirt Dye has natural environmental-protective characteristic, and plant polyatomic alcohol is extracted by pure plant, nontoxic, can be effectively prevented because of bacterium, fungus-caused peculiar smell, will not damage human health.

Description

A kind of green plants organic environmental-protection foam and its production technology
Technical field
The present invention relates to foamed cotton fields, and in particular to a kind of green plants organic environmental-protection foam and its production technology.
Background technique
Foam is the material that plastic pellet foamed, such as polyphenyl foamed board, foam polyvinyl chloride insulation board, polyurethane foam Cotton etc. is used in civil construction, refrigeration industry, transportation, engineering, water survival gear, various instrument packaging, daily use Sundry goods Etc. industries, the defect of existing common foam be no degradability and be difficult to recycle, certain damage is had to environment, in addition common bubble Raw material used by cotton has mild toxicity, peculiar smell, to human body nocuousness.
Summary of the invention
The technical issues of for present in the common foam of the prior art not environmentally, the present invention provides a kind of green plantss to have Machine environment friendly foam cotton and its production technology, specific technical solution are as follows:
A kind of green plants organic environmental-protection foam, the raw material including following parts by weight are prepared: 55~65 parts by weight Polyethers, the plant polyatomic alcohol of 35~45 parts by weight, the water of 0.2~0.4 parts by weight, 1.2~1.4 parts by weight silicone oil, The catalyst of 0.5~0.7 parts by weight, the stannous octoate of 0.03~0.05 parts by weight, the MDI of 6~8 parts by weight, 6~8 The color of the TDI of parts by weight, 2~3 parts by weight.
As a preferred solution of the present invention, a kind of green plants organic environmental-protection foam includes the original of following parts by weight Material is prepared: the polyethers of 57~63 parts by weight, the plant polyatomic alcohol of 37~43 parts by weight, 0.25~0.35 parts by weight Water, the silicone oil of 1.25~1.35 parts by weight, the catalyst of 0.55~0.65 parts by weight, 0.035~0.045 parts by weight Stannous octoate, the MDI of 6.5~7.5 parts by weight, the TDI of 6.5~7.5 parts by weight, 2.5~3 parts by weight color.
As a preferred solution of the present invention, a kind of green plants organic environmental-protection foam includes the original of following parts by weight Material is prepared: the polyethers of 56~61 parts by weight, the plant polyatomic alcohol of 36~39 parts by weight, 0.22~0.37 parts by weight Water, the silicone oil of 1.28~1.32 parts by weight, the catalyst of 0.65~0.68 parts by weight, 0.04~0.05 parts by weight Stannous octoate, the MDI of 7~8 parts by weight, the TDI of 6~7 parts by weight, 2~3 parts by weight color.
As a preferred solution of the present invention, a kind of green plants organic environmental-protection foam includes the original of following parts by weight Material is prepared: the polyethers of 60 parts by weight, the plant polyatomic alcohol of 40 parts by weight, the water of 0.3 parts by weight, 1.32 parts by weight The several catalyst of silicone oil, 0.6 parts by weight, the stannous octoate of 0.042 parts by weight, the MDI of 7 parts by weight, 7 parts by weight TDI, 2.43 parts by weight color.
As a preferred solution of the present invention, the catalyst is amines catalyst.
A kind of green plants organic environmental-protection foam production technology, follows the steps below:
1. mixing, according to parts by weight the polyethers of 55~65 parts by weight, the plant polyatomic alcohol of 35~45 parts by weight, 0.2 The water of~0.4 parts by weight, the silicone oil of 1.2~1.4 parts by weight, the catalyst of 0.5~0.7 parts by weight, 0.03~0.05 The color addition of the stannous octoate of parts by weight, the MDI of 6~8 parts by weight, the TDI of 6~8 parts by weight, 2~3 parts by weight Mixture is sufficiently mixed into mixing machine;
2. curing, mixing machine discharging curing molds semi-finished product green plants organic environmental-protection foam in 88~92 seconds;
3. cooling down, semi-finished product green plants organic environmental-protection foam, which molds bulk green plants through cooling heat dissipation in 47~49 hours, to be had Machine environment friendly foam cotton;
4. cut, bulk green plants organic environmental-protection foam cut into the fritter green plants organic environmental-protection foam of suitable dimension at Product.
Compared with common foam on the market, the advantages of green plants organic environmental-protection foam of the present invention, is:
(1) green plants organic environmental-protection foam substitutes traditional oil polyalcohol using plant polyatomic alcohol and is applied in foam production, Make green plants organic environmental-protection foam that there is degradability, solves the degradation and recycling problem of petroleum polyurethane products, effectively Degradation reduces environmental pollution, has natural environmental-protective characteristic;
(2) plant polyatomic alcohol is extracted by pure plant, nontoxic, is effectively prevented because of bacterium, fungus-caused peculiar smell, Human health will not be damaged;
(3) the selection of green plants organic environmental-protection foam is reasonable, has higher conduction stability and resilience.
Specific embodiment
A specific embodiment of the invention is described further below:
Embodiment 1, a kind of green plants organic environmental-protection foam, the raw material including following parts by weight are prepared: 55~65 weights Measure the polyethers of number, the plant polyatomic alcohol of 35~45 parts by weight, the water of 0.2~0.4 parts by weight, 1.2~1.4 parts by weight Silicone oil, the catalyst of 0.5~0.7 parts by weight, the stannous octoate of 0.03~0.05 parts by weight, 6~8 parts by weight MDI, the TDI of 6~8 parts by weight, 2~3 parts by weight color.
Embodiment 2, a kind of green plants organic environmental-protection foam include that the raw material of following parts by weight is prepared: 57~63 The polyethers of parts by weight, the plant polyatomic alcohol of 37~43 parts by weight, the water of 0.25~0.35 parts by weight, 1.25~1.35 weights Measure the silicone oil of number, the catalyst of 0.55~0.65 parts by weight, the stannous octoate of 0.035~0.045 parts by weight, 6.5~ The MDI of 7.5 parts by weight, the TDI of 6.5~7.5 parts by weight, 2.5~3 parts by weight color.
Embodiment 3, a kind of green plants organic environmental-protection foam include that the raw material of following parts by weight is prepared: 56~61 The polyethers of parts by weight, the plant polyatomic alcohol of 36~39 parts by weight, the water of 0.22~0.37 parts by weight, 1.28~1.32 weights Measure the silicone oil of number, the catalyst of 0.65~0.68 parts by weight, the stannous octoate of 0.04~0.05 parts by weight, 7~8 weight The MDI of number, the TDI of 6~7 parts by weight, 2~3 parts by weight color.
Embodiment 4, a kind of green plants organic environmental-protection foam include that the raw material of following parts by weight is prepared: 60 weight The polyethers of number, the plant polyatomic alcohol of 40 parts by weight, the water of 0.3 parts by weight, the silicone oil of 1.32 parts by weight, 0.6 weight The catalyst of number, the stannous octoate of 0.042 parts by weight, the MDI of 7 parts by weight, the TDI of 7 parts by weight, 2.43 parts by weight Several colors.
Specifically, catalyst is amines catalyst, plant polyatomic alcohol is palm oil modified polyether polylol.MDI full name Diphenyl-methane-diisocyanate, the entitled methyl diphenylene diisocyanate of Chinese, molecular formula are C15H10N2O2;TDI full name Toluene-2,4-diisocyanate, Chinese name is toluene di-isocyanate(TDI).Polyethers both polyethers Polyalcohol is by initiator (compound containing active hydrogen group) and ethylene oxide (EO), propylene oxide (PO), epoxy butane (BO) etc. it is made in the presence of a catalyst through sudden reaction.
A kind of green plants organic environmental-protection foam production technology, follows the steps below:
1. mixing, according to parts by weight the polyethers of 55~65 parts by weight, the plant polyatomic alcohol of 35~45 parts by weight, 0.2 The water of~0.4 parts by weight, the silicone oil of 1.2~1.4 parts by weight, the catalyst of 0.5~0.7 parts by weight, 0.03~0.05 The color addition of the stannous octoate of parts by weight, the MDI of 6~8 parts by weight, the TDI of 6~8 parts by weight, 2~3 parts by weight Mixture is sufficiently mixed into mixing machine;
2. curing, mixing machine discharging curing molds semi-finished product green plants organic environmental-protection foam in 88~92 seconds;
3. cooling down, semi-finished product green plants organic environmental-protection foam, which molds bulk green plants through cooling heat dissipation in 47~49 hours, to be had Machine environment friendly foam cotton;
4. cut, bulk green plants organic environmental-protection foam cut into the fritter green plants organic environmental-protection foam of suitable dimension at Product.
In conclusion green plants organic environmental-protection foam of the present invention, which chooses plant polyatomic alcohol, substitutes traditional oil polyalcohol Applied in foam production, so being named as plant organic environmental-protection foam, the energy that manufacture plant polyatomic alcohol is consumed is less, dioxy Change carbon emission amount is also lower, and compared with the raw material that petroleum extracts, the consumption of plant polyatomic alcohol total energy can reduce by 30%, from raw material Economical environment-protective, and green plants organic environmental-protection foam has degradability, at the degradation and recycling for solving petroleum polyurethane products Reason problem, effectively degradation reduce environmental pollution, have natural environmental-protective characteristic, meet environment protection requirement, plant polyatomic alcohol by Pure plant extracts, nontoxic, cooperate the antibacterial material of foam itself together more can ground prevent from causing because of bacterium, fungi Peculiar smell, density be 80~200kg/m3, and color mainly matches yellowly, green, blue, black etc., it is beautiful and generous, gorgeous more It is color
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that this hair Bright specific implementation is only limited to these instructions, and for those of ordinary skill in the art to which the present invention belongs, is not being taken off Under the premise of from present inventive concept, a number of simple deductions or replacements can also be made, all shall be regarded as belonging to protection of the invention Range.

Claims (6)

1. a kind of green plants organic environmental-protection foam, which is characterized in that the raw material including following parts by weight is prepared: 55~ The polyethers of 65 parts by weight, the plant polyatomic alcohol of 35~45 parts by weight, the water of 0.2~0.4 parts by weight, 1.2~1.4 weight The silicone oil of number, the catalyst of 0.5~0.7 parts by weight, the stannous octoate of 0.03~0.05 parts by weight, 6~8 parts by weight MDI, the TDI of 6~8 parts by weight, 2~3 parts by weight color.
2. a kind of green plants organic environmental-protection foam according to claim 1, it is characterised in that: including following parts by weight Raw material be prepared: the polyethers of 57~63 parts by weight, the plant polyatomic alcohol of 37~43 parts by weight, 0.25~0.35 weight The water of number, the silicone oil of 1.25~1.35 parts by weight, the catalyst of 0.55~0.65 parts by weight, 0.035~0.045 weight The stannous octoate of number, the MDI of 6.5~7.5 parts by weight, the TDI of 6.5~7.5 parts by weight, 2.5~3 parts by weight color Cream.
3. a kind of green plants organic environmental-protection foam according to claim 1, it is characterised in that: including following parts by weight Raw material be prepared: the polyethers of 56~61 parts by weight, the plant polyatomic alcohol of 36~39 parts by weight, 0.22~0.37 weight The water of number, the silicone oil of 1.28~1.32 parts by weight, the catalyst of 0.65~0.68 parts by weight, 0.04~0.05 parts by weight The several MDI of stannous octoate, 7~8 parts by weight, the TDI of 6~7 parts by weight, 2~3 parts by weight color.
4. a kind of green plants organic environmental-protection foam according to claim 1, it is characterised in that: including following parts by weight Raw material be prepared: the polyethers of 60 parts by weight, the plant polyatomic alcohol of 40 parts by weight, the water of 0.3 parts by weight, 1.32 weights Measure the silicone oil of number, the catalyst of 0.6 parts by weight, the stannous octoate of 0.042 parts by weight, the MDI of 7 parts by weight, 7 weight The color of the TDI of number, 2.43 parts by weight.
5. a kind of green plants organic environmental-protection foam according to any one of claims 1 to 4, it is characterised in that: the catalysis Agent is amines catalyst.
6. a kind of green plants organic environmental-protection foam production technology, which is characterized in that follow the steps below:
1. mixing, according to parts by weight the polyethers of 55~65 parts by weight, the plant polyatomic alcohol of 35~45 parts by weight, 0.2 The water of~0.4 parts by weight, the silicone oil of 1.2~1.4 parts by weight, the catalyst of 0.5~0.7 parts by weight, 0.03~0.05 The color addition of the stannous octoate of parts by weight, the MDI of 6~8 parts by weight, the TDI of 6~8 parts by weight, 2~3 parts by weight Mixture is sufficiently mixed into mixing machine;
2. curing, mixing machine discharging curing molds semi-finished product green plants organic environmental-protection foam in 88~92 seconds;
3. cooling down, semi-finished product green plants organic environmental-protection foam, which molds bulk green plants through cooling heat dissipation in 47~49 hours, to be had Machine environment friendly foam cotton;
4. cut, bulk green plants organic environmental-protection foam cut into the fritter green plants organic environmental-protection foam of suitable dimension at Product.
CN201910426901.XA 2019-05-22 2019-05-22 A kind of green plants organic environmental-protection foam and its production technology Pending CN110105526A (en)

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Application Number Priority Date Filing Date Title
CN201910426901.XA CN110105526A (en) 2019-05-22 2019-05-22 A kind of green plants organic environmental-protection foam and its production technology

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CN110105526A true CN110105526A (en) 2019-08-09

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115232460A (en) * 2022-08-29 2022-10-25 启明星精密科技(惠州)有限公司 Method for manufacturing environment-friendly foam

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101717572A (en) * 2009-12-31 2010-06-02 南通恒康海绵制品有限公司 Biodegradable slow-recovery sponge
CN101974144A (en) * 2010-10-28 2011-02-16 江苏钟山化工有限公司 Method for preparing plant oil-based polyol for flexible polyurethane foam
CN102227295A (en) * 2008-10-30 2011-10-26 江森自控科技公司 Palm oil-based polyurethane foam products and method of production
CN103275296A (en) * 2013-04-16 2013-09-04 无锡吉兴木桥高分子材料科技有限公司 Polyurethane foam for wet-method preparation and preparation method thereof
US20140024733A1 (en) * 2012-07-20 2014-01-23 Bayer Materialscience Llc Process for the in situ production of polyether polyols based on renewable materials and their use in the production of flexible polyurethane foams
WO2015143562A1 (en) * 2014-03-27 2015-10-01 Trent University Metathesized triacylglycerol green polyols from palm oil for use in polyurethane applications and their related physical properties
CN109369901A (en) * 2018-09-29 2019-02-22 南京工业大学 Vegetable oil polyurethane flexible foam polyol and preparation method and application thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102227295A (en) * 2008-10-30 2011-10-26 江森自控科技公司 Palm oil-based polyurethane foam products and method of production
CN101717572A (en) * 2009-12-31 2010-06-02 南通恒康海绵制品有限公司 Biodegradable slow-recovery sponge
CN101974144A (en) * 2010-10-28 2011-02-16 江苏钟山化工有限公司 Method for preparing plant oil-based polyol for flexible polyurethane foam
US20140024733A1 (en) * 2012-07-20 2014-01-23 Bayer Materialscience Llc Process for the in situ production of polyether polyols based on renewable materials and their use in the production of flexible polyurethane foams
CN103275296A (en) * 2013-04-16 2013-09-04 无锡吉兴木桥高分子材料科技有限公司 Polyurethane foam for wet-method preparation and preparation method thereof
WO2015143562A1 (en) * 2014-03-27 2015-10-01 Trent University Metathesized triacylglycerol green polyols from palm oil for use in polyurethane applications and their related physical properties
CN109369901A (en) * 2018-09-29 2019-02-22 南京工业大学 Vegetable oil polyurethane flexible foam polyol and preparation method and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115232460A (en) * 2022-08-29 2022-10-25 启明星精密科技(惠州)有限公司 Method for manufacturing environment-friendly foam

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Application publication date: 20190809