CN110358643A - A kind of functional form quickly takes off iodine liquid detergent and preparation method thereof - Google Patents
A kind of functional form quickly takes off iodine liquid detergent and preparation method thereof Download PDFInfo
- Publication number
- CN110358643A CN110358643A CN201910569732.5A CN201910569732A CN110358643A CN 110358643 A CN110358643 A CN 110358643A CN 201910569732 A CN201910569732 A CN 201910569732A CN 110358643 A CN110358643 A CN 110358643A
- Authority
- CN
- China
- Prior art keywords
- liquid detergent
- iodine
- functional form
- agent
- iodine liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 45
- 229910052740 iodine Inorganic materials 0.000 title claims abstract description 42
- 239000011630 iodine Substances 0.000 title claims abstract description 42
- 239000003599 detergent Substances 0.000 title claims abstract description 40
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 241000894006 Bacteria Species 0.000 claims abstract description 10
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 230000002401 inhibitory effect Effects 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 239000000344 soap Substances 0.000 claims description 6
- 230000008719 thickening Effects 0.000 claims description 6
- 235000019864 coconut oil Nutrition 0.000 claims description 5
- 239000003240 coconut oil Substances 0.000 claims description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 claims description 4
- AGTHHOQYAQDNSL-FOWTUZBSSA-N 5-[(1e)-2,6-dimethylhepta-1,5-dienyl]-1-pentylimidazole Chemical compound CCCCCN1C=NC=C1\C=C(/C)CCC=C(C)C AGTHHOQYAQDNSL-FOWTUZBSSA-N 0.000 claims description 3
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical group CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 claims description 2
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 claims description 2
- 229960003415 propylparaben Drugs 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- XEUCQOBUZPQUMQ-UHFFFAOYSA-N Glycolone Chemical compound COC1=C(CC=C(C)C)C(=O)NC2=C1C=CC=C2OC XEUCQOBUZPQUMQ-UHFFFAOYSA-N 0.000 claims 1
- UWIULCYKVGIOPW-UHFFFAOYSA-N Glycolone Natural products CCOC1=C(CC=CC)C(=O)N(C)c2c(O)cccc12 UWIULCYKVGIOPW-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- WJEIYVAPNMUNIU-UHFFFAOYSA-N [Na].OC(O)=O Chemical group [Na].OC(O)=O WJEIYVAPNMUNIU-UHFFFAOYSA-N 0.000 claims 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical group OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 11
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 6
- 239000006260 foam Substances 0.000 abstract description 6
- 206010040880 Skin irritation Diseases 0.000 abstract description 3
- 231100000475 skin irritation Toxicity 0.000 abstract description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 2
- 238000005282 brightening Methods 0.000 abstract description 2
- 239000011574 phosphorus Substances 0.000 abstract description 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 2
- 230000036556 skin irritation Effects 0.000 abstract description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 239000000047 product Substances 0.000 description 19
- 230000000694 effects Effects 0.000 description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 13
- 239000000243 solution Substances 0.000 description 9
- -1 alkyl glycosides Chemical class 0.000 description 7
- 150000002191 fatty alcohols Chemical class 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 238000005202 decontamination Methods 0.000 description 5
- 230000003588 decontaminative effect Effects 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 235000017550 sodium carbonate Nutrition 0.000 description 5
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 5
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 231100000252 nontoxic Toxicity 0.000 description 4
- 230000003000 nontoxic effect Effects 0.000 description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 description 4
- 235000019345 sodium thiosulphate Nutrition 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229930182470 glycoside Natural products 0.000 description 3
- 239000008233 hard water Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229940098465 tincture Drugs 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 229960003511 macrogol Drugs 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- 240000001624 Espostoa lanata Species 0.000 description 1
- 235000009161 Espostoa lanata Nutrition 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 206010015946 Eye irritation Diseases 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 101150096185 PAAS gene Proteins 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000000043 antiallergic agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229940117927 ethylene oxide Drugs 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000000215 hyperchromic effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 230000001662 opsonic effect Effects 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 235000013555 soy sauce Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of functional forms quickly to take off iodine liquid detergent, it is made of following raw materials according, it is indicated with mass fraction are as follows: surfactant 15%-25%, auxiliary agent, builder 5%-15% take off idodine 1%-5%, take off iodine stabilizer 0.5%-1%, antiseptic and inhibiting bacteria function agent 0.2%-1%, thickener 1%-5%, essence 0.5%-1%, deionized water 50%-65%.Liquid detergent of the invention is raw materials used renewable, easily biological-degradable, no pollution to the environment；Product pH=8-9 has the characteristics that quickly to take off iodine, Low-foam and easily rinsing, strong detergency, antistatic, bactericidal, without phosphorus, unstressed configuration brightening agent, machine-wash, hand washing all may be used to no skin irritation.
Description
Technical field
The present invention relates to a kind of liquid detergent and preparation method thereof more particularly to a kind of functional form quickly take off iodine liquid detergent and
Preparation method.
Background technique
With the development of the social economy, people's living standard steps up, consumption idea is also quietly changing, and worships
Still Product Green, it is safe and efficient should be consumer first choice, and health washing be wherein important one of aspect.Liquid is washed
Wash agent (especially concentration efficient liquid detergent) by be future development emphasis；Low-foam and easily rinsing, energy-saving and water-saving type, safety
The articles for washing formula and the functionalization of product of environmental protection, customizations, sectionalization by be future development direction.
Currently, liquid detergent in the market is compounded using anion, nonionic and amphoteric surfactant, it is main
Wanting function is decontamination, antibacterial etc., and in some Code in Hazardous Special Locations such as hospital, the tincture of iodine (Iodophor) is that most common disinfection is used
Product are difficult to clean on clothing once adhering to, and there is the liquid detergent of de- iodine function to be also rarely reported in the market.The present invention removes
Except the effect of having both common liquid detergent, there is quickly de- iodine efficiency, and to soy sauce, coloured stains and the grease stain such as marinate
There is preferable cleaning effect, is used especially suitable for hospital, community medicine station, the residential care places such as keep a public place clean, also can be used as house
The standing liquid detergent in front yard is used for the washing of various fabrics.
Summary of the invention
The laundry used in fields such as keep a public place clean the purpose of the present invention is to provide a kind of hospital, community medicine station, residential care
Liquid and preparation method thereof solves that the technical problems such as iodine (iodine stain) cannot be taken off in existing liquid detergent.Original used in liquid detergent of the invention
Expect renewable, easily biological-degradable, no pollution to the environment；Product pH=8-9 has quickly de- iodine, low to no skin irritation
The features such as steeping easily rinsing, strong detergency, antistatic, bactericidal, without phosphorus, unstressed configuration brightening agent, machine washing are hand-washed and all may be used.
To achieve the above object, the technical solution adopted by the present invention are as follows:
A kind of functional form quickly takes off iodine liquid detergent, is made of following raw materials according, is indicated with mass fraction are as follows:
As a preferred technical solution of the present invention, wherein the surfactant is alkyl glycosides (APG), fat
One of alcohol polyethenoxy ether sodium sulfate (AES), fatty alcohol polyoxyethylene ether (AEO-9), two or more mixtures.
Alkyl glycosides (APG): alkyl glycosides is that origin is derived from the glucose of corn and potato starch and from coconut oil
Fatty alcohol synthesis nonionic surfactant.Its main feature is that surface tension it is low, without cloud point, HLB value is adjustable, wetting power, goes
Dirty power is strong, the fine and smooth stabilization of foaming abundancy, dissolubility are good；It can significantly improve the mildness of formula system, it is nontoxic, harmless, to skin
It is non-stimulated, 100% biodegrade；Can be with any type surfactant compound, synergistic effect is obvious；With stronger wide spectrum
Antibacterial activity, product thickening effect is significant, is easy to dilute, without gelatin phenomenon, easy to use；And it is resistance to highly basic, resistance to strong acid, resistance to
Hard water, salt-resistance are strong, and degreasing result is good.And have flexibility, antistatic property and shrink resistance concurrently, it is suitable for cold washing, raw material
It is renewable, be easy to get, belong to natural, green product.
Sodium sulfate of polyethenoxy ether of fatty alcohol (AES): AES is by nonionic fatty alcohols polyoxyethylene ether (AE) through sulfuric acid
Change, modified product made from alkali neutralization, belongs to the anionic surfactant of typical function admirable.It has excellent go
Dirty, emulsification, wetting, solubilising and foam performance, dissolubility, good from thickening property, hard water resistance property effect, compatibility is wide, biodegrade
Degree is high, nontoxic, low to skin and eye irritation.
Fatty alcohol polyoxyethylene ether (AEO-9): nonionic surfactant has good emulsification, decontamination, washing, resists
The performances such as electrostatic are that natural fatty alcohol and ethyleneoxide addition are made.Biological degradability is good, environmentally protective, can with it is other kinds
Anion, nonionic, cationic surfactant are used in compounding, and synergistic effect is significant.
As a preferred technical solution of the present invention, the auxiliary agent is two in 6501, OP-10, PEG-400, EDTA
Kind or a variety of compounds.
6501: also known as Ninol, the entitled cocoanut fatty acid diethanolamide (CDEA) of chemistry, non-ionic surface active
Agent.Feature is: without cloud point, soluble easily in water, good with other surfaces active ingredient, having good foaming, foam stabilizing, infiltration
The functions such as decontamination, hard water resistance.
OP-10: alkyl phenol polyoxyethylene ether, emulsifier, nonionic surfactant.With excellent level dyeing, emulsification,
Inhibition, wetting, diffusion, the characteristics such as antistatic property.
PEG-400: polyethylene glycol PEG400, solubilizer is soaked, there is extensive compatibility with various solvents, stability is high
Non-volatile, moderate notoxic has soft effect to fabric.
EDTA: disodium ethylene diamine tetraacetate, chelating agent, Ca in complex water2+、Mg2+Ion improves washing effect.
As a preferred technical solution of the present invention, the builder is cocounut oil soap base (self-control).
Cocounut oil soap base: belonging to metal carboxylate anionic surfactant, is made using natural coconut oil with saponification, molten
Stablize in deionized water, transparent, pH value 6.5-8.Cocounut oil soap base has the characteristics that good defoaming, foam stabilizing, decontamination.Washing
When not only can be reduced rinsing times, save water resource；And can avoid gathering again for dirt, significantly increase the washing effect of product
Fruit.Cocounut oil soap base of the present invention the preparation method is as follows: coconut oil is added in 75 DEG C of reaction kettle, then add alkali and second
The mixed solution of alcohol, reflux under at the uniform velocity stirring, are saponified 35min, and cooling discharge can obtain cocounut oil soap base.Alkali used can be with
The NaOH solution for being 25% for mass fraction.Coconut oil, alkali, ethyl alcohol addition mass ratio are as follows: 50: 36: 14.
As a preferred technical solution of the present invention, the de- idodine is sodium thiosulfate (Na2S2O3)。
Sodium thiosulfate: transparent crystal also known as Sodium Thiosulfate, dodium thiosulfate, hypo.Reducing agent, disinfectant, antiallergy
Agent.
As a preferred technical solution of the present invention, the de- iodine stabilizer is sodium carbonate (Na2CO3)。
Sodium carbonate: also known as soda, soda ash, washing soda, white powder are soluble easily in water.Since sodium thiosulfate is acid molten
It is easily decomposed in liquid, uses proper amount of sodium carbonate as protective agent.
As a preferred technical solution of the present invention, the antiseptic and inhibiting bacteria function agent is Kathon CG KK-88, P-hydroxybenzoic acid
One of methyl esters (methylparaben), propylparaben (propylben), two or more mixtures.
Kathon CG (Kathon) KK-88: chemical name: isothiazolinone, preservative.Toxicity is low, antibacterial action range is wide, effect
Fruit is strong；It can be dissolved in water, easy to use, 80 DEG C or less can be directly added into, and be used cooperatively better effect with parabens.Energy
It mixes with various surfactants and emulsifier compatibility, can be used in 3~9.5 range of pH value, be day generally acknowledged in the world
Change product broad-spectrum sterilization preservative.
P-hydroxybenzoic acid first (third) ester: parabens preservative, chemical property is stablized, within the scope of wider pH value
It is antibacterial, anti-microbial effect is good, nontoxic, safety is good, be widely used in the anti-corrosion of food, cosmetics, medicine, feed.Methyl esters
With propyl ester compatible use, solubility not only can be improved, and cooperate with anti-corrosion effect that can significantly increase.
As a preferred technical solution of the present invention, the thickener is the double stearates of Macrogol 6000
(DM638), one or both of Sodium Polyacrylate compound.
DM638: chemical name: the double stearates of Macrogol 6000 are a kind of macromolecule nonionic surfactants, increase
Thick dose, emulsifier.Feature: additive amount is few, can dramatically increase the viscosity of product, assigns the good rheological characteristic of product, improves foam
Feel has preferable opsonic action；There is good compatibility with various surfactants, in extensive pH value range
It is applicable in.
Sodium Polyacrylate: (ASAP), Chinese nickname: PAAS is a kind of while having hydrophilic and hydrophobic grouping macromolecule
Polymer, thickener, food additives have good thickening, stable and peptizaiton.
Above-mentioned functional form quickly take off iodine liquid detergent the preparation method comprises the following steps:
Step 1: measured deionized water is added in reaction kettle, temperature of reaction kettle sets 70-80 DEG C of heating；
Step 2: weighing raw material: surfactant, auxiliary agent, builder, antiseptic and inhibiting bacteria function agent, thickener, de- idodine, de- iodine
Stabilizer, essence；
Step 3: sequentially adding surfactant, auxiliary agent into reaction kettle when temperature of reaction kettle is to set temperature, helping and wash
Agent, at the uniform velocity stirring are sufficiently uniformly dissolved material；
Step 4: reaction kettle is cooled to 60 DEG C, de- idodine, de- iodine stabilizer, antiseptic and inhibiting bacteria function agent is added, stirs, is added
Thickener thickening, insulated and stirred 20min；
Step 5: reaction kettle is cooled to 50 DEG C hereinafter, essence (it is hyperchromic edible pigment can be added when needing) is added；
Step 6: product is stood, is cooling, defoaming, then dispense.
Various raw materials used in the present invention be it is well known it is commercially available, easily purchase raw material, application method and function are mature skill
Art.
Compared with prior art, the invention has the benefit that
1, liquid detergent of the invention is in addition to the low bubble, decontamination washing, restraining and sterilizing bacteria, antistatic etc. with commercial laundry liquid
Outside effect, have the function of quickly to take off iodine.
2, liquid detergent of the invention is not phosphorous, is free of fluorescent whitening agent, easily rinsing, noresidue, and concentration is efficient；Original used
Material safety easily purchase, inexpensive nontoxic, easily biological-degradable, it is environmentally protective.
3, the fabricating technology of liquid detergent of the present invention is simple and easy to control, and production process is pollution-free, non-volatile, it can be achieved that useless
The zero-emission of object.
4, the preparation process of liquid detergent of the present invention is of less demanding to production equipment, reliable in quality, safety, easy temperature control,
It is easy to operate, can effectively reduce production cost.
5, liquid detergent of the present invention be not only applicable to hospital, the places such as community medicine station, residential care are kept a public place clean, food and drink, also supply
Different estate consumer uses, and audient's range is wide, has certain application value.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail.
Embodiment 1
The quick de- iodine liquid detergent of the present embodiment, component and mass fraction (%) are as follows:
Embodiment 2
The quick de- iodine liquid detergent of the present embodiment, component and mass fraction (%) are as follows:
Embodiment 3
The quick de- iodine liquid detergent of the present embodiment, component and mass fraction (%) are as follows:
Embodiment 4
The quick de- iodine liquid detergent of the present embodiment, component and mass fraction (%) are as follows:
Embodiment 5
The quick de- iodine liquid detergent of the present embodiment, component and mass fraction (%) are as follows:
Embodiment 6
The quick de- iodine liquid detergent of the present embodiment, component and mass fraction (%) are as follows:
The liquid detergent preparation process of above-described embodiment is as follows:
(1) balance deionized water measured is added in reaction kettle, temperature of reaction kettle sets 70-80 DEG C, heating；
(2) when arriving set temperature, surfactant is sequentially added, at the uniform velocity stirring 15min to material all dissolves；
(3) sequentially adding auxiliary agent, builder and at the uniform velocity stirring 20min keeps material dissolution uniform；
(4) it is cooled to 60 DEG C under stirring, de- idodine, de- iodine stabilizer, antiseptic and inhibiting bacteria function agent, thickener insulated and stirred is added
20min；
(5) 50 DEG C or less addition essence are cooled to, are stood, defoaming, cooling, discharging, packing.
Main material production quotient used in the present invention is respectively as follows:
List of the present invention just takes off iodine effect and commercial product comparison is as follows:
Compared with table 1 selects commercially available certain brand 1#, 2#, 3#, 4# liquid detergent to take off iodine effect with product of the present invention
Test method: de- iodine Contrast on effect is carried out with this product and commercially available certain brand liquid detergent 1#, 2#, 3#, 4# respectively.It is logical
It crosses table 1 and learns that comparing result is as follows:
1, it cotton (or other fabrics) is white, smears a small amount of tincture of iodine on the work clothes such as blue, pink, is coated with respectively few
This product and other commercial laundry liquid are measured, this product takes off iodine immediately, wipes no iodine mark, without stain shadow with cotton balls, clean as before；Other product
Board liquid detergent, residual and stain shadow are obvious.
2, several 100ml small beakers are taken, a small amount of Iodophor (tincture of iodine) is separately added into, then are separately added into this product and the city of equivalent
1#, 2#, 3#, 4# liquid detergent are sold, a small amount of water is added to dilute, oscillation, this product Iodophor color is taken off rapidly, other are then without significant change.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (9)
1. a kind of functional form quickly takes off iodine liquid detergent, which is characterized in that be made of following raw materials according, indicated with mass fraction are as follows:
Surfactant 15%-25%
Auxiliary agent, builder 5%-15%
De- idodine 1%-5%
De- iodine stabilizer 0.5%-1%
Antiseptic and inhibiting bacteria function agent 0.2%-1%
Thickener 1%-5%
Essence 0.5%-1%
Deionized water 50%-65%.
2. functional form according to claim 1 quickly take off iodine liquid detergent, which is characterized in that the surfactant be APG,
One of AES, AEO-9, two or more mixtures.
3. functional form according to claim 1 quickly takes off iodine liquid detergent, which is characterized in that the auxiliary agent is 6501, OP-
10, two or more compounds in PEG-400, EDTA.
4. functional form according to claim 1 quickly takes off iodine liquid detergent, which is characterized in that the builder is coconut oil soap
Base.
5. functional form according to claim 1 quickly takes off iodine liquid detergent, which is characterized in that the de- idodine is thiosulfuric acid
Sodium.
6. functional form according to claim 1 quickly takes off iodine liquid detergent, which is characterized in that the de- iodine stabilizer is carbonic acid
Sodium.
7. functional form according to claim 1 quickly takes off iodine liquid detergent, which is characterized in that the antiseptic and inhibiting bacteria function agent is Kathon CG
One of KK-88, methyl p-hydroxybenzoate, propylparaben, two or more mixtures.
8. functional form according to claim 1 quickly takes off iodine liquid detergent, which is characterized in that the thickener is polyethylene glycol
One or both of 6000 pairs of stearates (DM638), Sodium Polyacrylates compound.
9. described in any item functional forms quickly take off the preparation method of iodine liquid detergent according to claim 1 ~ 8, which is characterized in that packet
Include following steps:
Step 1: measured deionized water is added in reaction kettle, temperature of reaction kettle sets 70-80 DEG C of heating；
Step 2: weighing raw material: surfactant, auxiliary agent, builder, antiseptic and inhibiting bacteria function agent, thickener, de- idodine, de- iodine are stablized
Agent, essence；
Step 3: surfactant, auxiliary agent, builder are sequentially added into reaction kettle when temperature of reaction kettle is to set temperature, it is even
Speed stirring is sufficiently uniformly dissolved material；
Step 4: reaction kettle is cooled to 60 DEG C, de- idodine, de- iodine stabilizer, antiseptic and inhibiting bacteria function agent is added, thickening is added in stirring
Agent thickening, insulated and stirred 20min；
Step 5: reaction kettle is cooled to 50 DEG C hereinafter, essence is added；
Step 6: product is stood, is cooling, defoaming, then dispense.
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| CN117247812A (en) * | 2023-09-16 | 2023-12-19 | 河南莱帕克化工设备制造有限公司 | Liquid detergent preparation process |
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| CN1225021A (en) * | 1997-04-03 | 1999-08-04 | 奥福泰克斯株式会社 | One-pack preparation for disinfection, neutralization and cleaning of contact lenses and method of disinfection, neutralization and cleaning |
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