CN110351904A - A kind of thermal imaging patterning electrothermal device and electric heating products - Google Patents
A kind of thermal imaging patterning electrothermal device and electric heating products Download PDFInfo
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Classifications
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/02—Details
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/34—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs
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- Surface Heating Bodies (AREA)
Abstract
本发明涉及一种热成像图案化电热器件,该电热器件包括发热层和保护层,所述发热层为热成像图案化发热层;和/或,所述保护层为热成像图案化保护层。本发明还涉及一种含有上述电热器件的电热产品。与现有技术相比,本发明的电热器件能产生热成像图案,且产品结构简单,适用于批量化生产,而且该电热器件能够在已有设备上生产,降低二次设备的资金投入;另外,本发明的电热器件的热成像效果能通过多种途径达成,具有非常大的设计空间。
The present invention relates to a thermal imaging patterned electrothermal device, the electrothermal device comprises a heating layer and a protective layer, the heating layer is a thermal imaging patterned heating layer; and/or, the protective layer is a thermal imaging patterned protective layer. The present invention also relates to an electric heating product containing the above electric heating device. Compared with the prior art, the electrothermal device of the present invention can produce thermal imaging patterns, and the product structure is simple, suitable for mass production, and the electrothermal device can be produced on existing equipment, reducing the capital investment of secondary equipment; in addition , the thermal imaging effect of the electrothermal device of the present invention can be achieved through various ways, and has a very large design space.
Description
技术领域technical field
本发明涉及电加热元件技术领域,具体涉及一种热成像图案化电热器件及电热产品。The invention relates to the technical field of electric heating elements, in particular to a thermal imaging patterned electric heating device and an electric heating product.
背景技术Background technique
传统的供暖方式包括燃烧燃料和用电热元件产热。前者虽然热能转化率高,但对环境污染较为严重。后者利用电热元件制成各种供暖设备,利用空气对流和热辐射的方式向一定的空间传递热量,设备方便安装,便于家庭使用。常用的电加热产品,如电热毯、电吹风、电热地暖、电热膜等已进入人们的日常生活。目前,绝大多数的电热产品仅仅注重其加热功能,并在电热产品外侧进行包装并印刷图案进行美化。但是,现有技术中并没有注意到,通过控制电热产品所产生的热辐射的量以及范围,可以使得电热产品在热成像领域形成独特的热成像图案。Traditional heating methods include burning fuel and generating heat with electric heating elements. Although the former has a high thermal energy conversion rate, it causes serious environmental pollution. The latter utilizes electric heating elements to be made into various heating equipment, utilizes the mode of air convection and heat radiation to transfer heat to certain space, and equipment is convenient for installation, is convenient to family use. Commonly used electric heating products, such as electric blankets, hair dryers, electric floor heating, and electric heating films, have entered people's daily lives. At present, the vast majority of electric heating products only focus on their heating function, and are packaged and printed on the outside of the electric heating product for beautification. However, it has not been noticed in the prior art that by controlling the amount and range of thermal radiation generated by the electrothermal product, the electrothermal product can form a unique thermal imaging pattern in the thermal imaging field.
发明内容Contents of the invention
本发明的目的就是为了克服上述现有技术存在的缺陷而提供一种结构简单的热成像图案化电热器件。The object of the present invention is to provide a thermal imaging patterned electrothermal device with a simple structure in order to overcome the above-mentioned defects in the prior art.
本申请之目的还在于提供一种含有上述电热器件的电热产品。The purpose of the present application is also to provide an electric heating product containing the above electric heating device.
为了实现本发明之目的,本申请提供以下技术方案。In order to realize the purpose of the present invention, the application provides the following technical solutions.
在第一方面中,本申请提供一种热成像图案化电热器件,该电热器件包括发热层和保护层,其特征在于,所述发热层为热成像图案化发热层;In the first aspect, the present application provides a thermal imaging patterned electrothermal device, the electrothermal device includes a heating layer and a protective layer, characterized in that the heating layer is a thermal imaging patterned heating layer;
和/或,所述保护层为热成像图案化保护层。And/or, the protective layer is a thermal imaging patterned protective layer.
在第一方面的一种具体实施方式中,所述热成像图案化发热层为热成像图案化电热层,且所述保护层为热成像图案化保护层或均匀保护层。In a specific implementation manner of the first aspect, the thermal imaging patterned heating layer is a thermal imaging patterned electric heating layer, and the protective layer is a thermal imaging patterned protective layer or a uniform protective layer.
在第一方面的一种具体实施方式中,所述发热层为均匀发热的发热层,且所述保护层为热成像图案化保护层。In a specific implementation manner of the first aspect, the heating layer is a heating layer that generates heat uniformly, and the protective layer is a thermal imaging patterned protective layer.
在第一方面的一种具体实施方式中,所述发热层通过涂布、印刷、电镀、金属刻蚀和蒸镀中的一种或多种方式的组合制备得到。In a specific implementation manner of the first aspect, the heat generating layer is prepared by combining one or more methods of coating, printing, electroplating, metal etching and vapor deposition.
在第一方面的一种具体实施方式中,所述保护层包括绝缘层、保温层和散热层中的一种或多种组合。In a specific implementation manner of the first aspect, the protective layer includes one or more combinations of an insulating layer, a thermal insulation layer and a heat dissipation layer.
在第一方面的一种具体实施方式中,所述热成像图案化保护层包括热成像图案化保温层和热成像图案化散热层中的至少一种,其中所述热成像图案化散热层中设有至少两个具有不同散热能力的散热区域;所述热成像图案化保温层中设有至少两个具有不同保温能力的保温区域。In a specific implementation manner of the first aspect, the thermal imaging patterned protective layer includes at least one of a thermal imaging patterned thermal insulation layer and a thermal imaging patterned heat dissipation layer, wherein in the thermal imaging patterned heat dissipation layer There are at least two heat dissipation regions with different heat dissipation capabilities; the thermal imaging patterned heat preservation layer is provided with at least two heat preservation regions with different heat preservation capabilities.
在第一方面的一种具体实施方式中,所述发热层的材质包括金属材料或无机非金属材料中的一种,所述无机非金属材料包括碳素材料、红外陶瓷和托玛琳材料中的一种或多种,优选的,所述发热层的材质为碳素材料。In a specific implementation manner of the first aspect, the material of the heating layer includes one of metallic materials or inorganic non-metallic materials, and the inorganic non-metallic materials include carbon materials, infrared ceramics, and tourmaline materials. One or more, preferably, the heat generating layer is made of carbon material.
在第一方面的一种具体实施方式中,所述金属材料包括由铜、铝、铁和镍中的一种或多种制得的粉料、浆料或电镀原料;In a specific implementation manner of the first aspect, the metal material includes powder, slurry or electroplating raw material made of one or more of copper, aluminum, iron and nickel;
和/或,所述碳素材料包括由石墨、导电炭黑、碳晶、纳米碳管、碳纤维、石墨烯和富勒烯中的一种或多种制得的粉料或浆料;And/or, the carbonaceous material includes powder or slurry made of one or more of graphite, conductive carbon black, carbon crystal, carbon nanotube, carbon fiber, graphene and fullerene;
所述红外陶瓷和所述托玛琳材料为粉料或浆料。The infrared ceramic and the tourmaline material are powder or slurry.
在第一方面的一种具体实施方式中,所述发热层的类型包含全覆盖型、条纹型和镂空型中的一种或多种的组合;且所述全覆盖型的发热层厚度不完全相同,条纹型的发热层和镂空型的发热层中不同部位的发热线条的厚度不全相同和/或宽度不全相同。In a specific implementation manner of the first aspect, the type of the heat generating layer includes a combination of one or more of full coverage type, stripe type and hollow type; and the thickness of the heat generation layer of the full coverage type is incomplete Similarly, the thickness and/or width of the heat-generating lines in different parts of the stripe-type heat-generating layer and the hollow-out-type heat-generating layer are not all the same.
在第二方面中,本申请提供一种电热产品,所述电热产品设有如上所述的热成像图案化电热器件。In a second aspect, the present application provides an electrothermal product, which is provided with the thermal imaging patterned electrothermal device as described above.
与现有技术相比,本发明的有益效果在于:Compared with prior art, the beneficial effect of the present invention is:
(1)本发明的电热器件能产生热成像图案,且产品结构简单,适用于批量化生产,成本低。(1) The electrothermal device of the present invention can generate thermal imaging patterns, has a simple product structure, is suitable for mass production, and has low cost.
(2)本发明的电热器件能够在已有设备上生产,降低二次设备的资金投入。(2) The electrothermal device of the present invention can be produced on existing equipment, reducing capital investment for secondary equipment.
(3)本发明电热器件的热成像效果能通过多种途径达成,具有非常大的设计空间。(3) The thermal imaging effect of the electrothermal device of the present invention can be achieved through various ways, and has a very large design space.
(4)对于曲线、圆形、异形、球面等原先难以均匀发热的发热器件,可通过本发明的方案,制得可均匀发热的器件。(4) For heating devices that are difficult to generate heat uniformly, such as curves, circles, special shapes, and spherical surfaces, devices that can generate heat uniformly can be produced through the solution of the present invention.
附图说明Description of drawings
图1为实施例1中热成像图案化发热层的表面结构示意图;1 is a schematic diagram of the surface structure of the thermographic patterned heating layer in Example 1;
图2为实施例1中电热器件的剖面结构示意图;Fig. 2 is the sectional structure schematic diagram of electrothermal device in embodiment 1;
图3为实施例1中电热器件的热成像测试结果示意图;3 is a schematic diagram of the thermal imaging test results of the electrothermal device in Example 1;
图4为实施例2中热成像图案化发热层的表面结构示意图;4 is a schematic diagram of the surface structure of the thermal imaging patterned heating layer in Example 2;
图5为实施例2中电热器件的热成像测试结果示意图;5 is a schematic diagram of the thermal imaging test results of the electrothermal device in Example 2;
图6为实施例3中热成像图案化发热层的表面结构示意图;6 is a schematic diagram of the surface structure of the thermal imaging patterned heating layer in Example 3;
图7为实施例3中电热器件的剖面结构示意图;Fig. 7 is a schematic cross-sectional structure diagram of the electrothermal device in embodiment 3;
图8为实施例3中电热器件的热成像测试结果示意图;8 is a schematic diagram of the thermal imaging test results of the electrothermal device in Example 3;
图9为实施例4中热成像图案化发热层的表面结构示意图;9 is a schematic diagram of the surface structure of the thermal imaging patterned heating layer in Example 4;
图10为实施例4中电热器件的热成像测试结果示意图;10 is a schematic diagram of the thermal imaging test results of the electrothermal device in Example 4;
图11为实施例5中热成像图案化发热层的表面结构示意图;11 is a schematic diagram of the surface structure of the thermal imaging patterned heating layer in Example 5;
图12为实施例5中电热器件的热成像测试结果示意图;12 is a schematic diagram of the thermal imaging test results of the electrothermal device in Example 5;
图13为实施例6及实施例8中热成像图案化保护层的表面结构示意图;13 is a schematic diagram of the surface structure of the thermal imaging patterned protective layer in Embodiment 6 and Embodiment 8;
图14为实施例6中电热器件的剖面结构示意图;Fig. 14 is a schematic cross-sectional structure diagram of the electrothermal device in embodiment 6;
图15为实施例6中电热器件的热成像测试结果示意图;15 is a schematic diagram of the thermal imaging test results of the electrothermal device in Example 6;
图16为实施例7及实施例8中热成像图案化保护层的表面结构示意图;16 is a schematic diagram of the surface structure of the thermal imaging patterned protective layer in Embodiment 7 and Embodiment 8;
图17为实施例7中电热器件的剖面结构示意图;Fig. 17 is a schematic cross-sectional structure diagram of the electrothermal device in Embodiment 7;
图18为实施例7中电热器件的热成像测试结果示意图;18 is a schematic diagram of the thermal imaging test results of the electrothermal device in Example 7;
图19为实施例8中热成像图案化发热层的表面结构示意图;19 is a schematic diagram of the surface structure of the thermal imaging patterned heating layer in Example 8;
图20为实施例8中电热器件的剖面结构示意图;Fig. 20 is a schematic cross-sectional structure diagram of the electrothermal device in Embodiment 8;
图21为实施例8中电热器件的热成像测试结果示意图。FIG. 21 is a schematic diagram of the thermal imaging test results of the electrothermal device in Example 8. FIG.
在附图中,1为PET膜,2为镂空区域,3为热成像图案化电热层,4为普通部分,5为发热图案部分,6为第三绝缘层,7为散热涂层,8为散热层,9为第一绝缘层,10为发热层,11为第二绝缘层,12为普通保温层,13为普通保温板,14为保温膜,15为保温层,16为普通散热层。In the attached drawings, 1 is the PET film, 2 is the hollow area, 3 is the thermal imaging patterned electric heating layer, 4 is the common part, 5 is the heating pattern part, 6 is the third insulating layer, 7 is the heat dissipation coating, 8 is Heat dissipation layer, 9 is the first insulation layer, 10 is the heating layer, 11 is the second insulation layer, 12 is the common insulation layer, 13 is the common insulation board, 14 is the insulation film, 15 is the insulation layer, and 16 is the common heat dissipation layer.
具体实施方式Detailed ways
除非另作定义,在本说明书和权利要求书中使用的技术术语或者科学术语应当为本发明所属技术领域内具有一般技能的人士所理解的通常意义。本文中列举的所有的从最低值到最高值之间的数值,是指当最低值和最高值之间相差两个单位以上时,最低值与最高值之间以一个单位为增量得到的所有数值。Unless otherwise defined, the technical terms or scientific terms used in the specification and claims shall have the ordinary meanings understood by those skilled in the technical field to which the present invention belongs. All the numerical values from the lowest value to the highest value listed in this article refer to all values obtained in increments of one unit between the lowest value and the highest value when the difference between the lowest value and the highest value is more than two units. value.
以下将结合附图描述本发明的具体实施方式,需要指出的是,在这些实施方式的具体描述过程中,为了进行简明扼要的描述,本说明书不可能对实际的实施方式的所有特征均作详尽的描述。在不偏离本发明的精神和范围的情况下,本领域技术人员可以对本发明的实施方式进行修改和替换,所得实施方式也在本发明的保护范围之内。Specific embodiments of the present invention will be described below in conjunction with the accompanying drawings. It should be pointed out that in the process of specific description of these embodiments, in order to describe briefly and concisely, it is impossible for this specification to describe all the features of the actual embodiments in detail. description of. Without departing from the spirit and scope of the present invention, those skilled in the art can modify and replace the embodiments of the present invention, and the obtained embodiments are also within the protection scope of the present invention.
传统的电热器件通过包装及印刷图案进行美化,但无法实现热成像。本申请之目的在于提供一种热成像图案化电热器件,该电热器件包括发热层和保护层,所述发热层为热成像图案化发热层;和/或,所述保护层为热成像图案化保护层。其中,保护层位于发热层的两侧或单侧,保护层的主要功能是对发热层进行保护或使得发热层产生的热量具有热成像图案化功能。优选为位于发热层的两侧。Traditional electric heating devices are beautified by packaging and printing patterns, but thermal imaging cannot be achieved. The purpose of this application is to provide a thermal imaging patterned electrothermal device, the electrothermal device includes a heating layer and a protective layer, the heating layer is a thermal imaging patterned heating layer; and/or, the protective layer is a thermal imaging patterned The protective layer. Wherein, the protective layer is located on both sides or one side of the heating layer, and the main function of the protective layer is to protect the heating layer or to enable the heat generated by the heating layer to have a thermal imaging patterning function. It is preferably located on both sides of the heat generating layer.
在一种具体实施方式中,所述热成像图案化发热层为通电自行发热形成热成像图案的发热层,即热成像图案化电热层,且所述保护层为均匀保护层。In a specific embodiment, the thermal imaging patterned heating layer is a heating layer that generates a thermal imaging pattern by itself when energized, that is, a thermal imaging patterned heating layer, and the protective layer is a uniform protective layer.
在一种具体实施方式中,所述热成像图案化发热层为热成像图案化电热层,且所述保护层为热成像图案化保护层,同时使用热成像图案电热层和热成像图案化保护层会得到更好的热成像效果。In a specific embodiment, the thermal imaging patterned heating layer is a thermal imaging patterned electric heating layer, and the protective layer is a thermal imaging patterned protective layer, and the thermal imaging patterned electric heating layer and the thermal imaging patterned protective layer are used layer for better thermal imaging.
在一种具体实施方式中,热成像图案化发热层包含全覆盖型、条纹型和镂空型中的一种或多种组合。其中,全覆盖型的热成像图案化发热层的厚度不完全相同;条纹型或镂空型的热成像图案化发热层中不同部位的发热线条的厚度不全相同和/或宽度不全相同。由于三种不同类型的热成像图案化发热层在热成像图案的设计上会有不同的效果,使用单一的类型在设计上相对简单,但对于复杂的需求,也可使用多种类型图像的结合。In a specific embodiment, the thermal imaging patterned heat generating layer includes one or more combinations of full coverage type, stripe type and hollow type. Among them, the thickness of the full-coverage thermal imaging patterned heating layer is not completely the same; the thickness and/or width of the heating lines in different parts of the striped or hollowed-out thermal imaging patterned heating layer are not all the same. Since three different types of thermal imaging patterned heating layers have different effects on the design of thermal imaging patterns, using a single type is relatively simple in design, but for complex needs, a combination of multiple types of images can also be used .
在一种具体实施方式中,所述自行发热形成热成像图案的发热层通过涂布、印刷、电镀、金属刻蚀和蒸镀中的一种或多种方式的组合制备得到。得到的发热层为涂层或镀层,两者属于面状发热,且加工工艺简单,可使用现有设备实现效果设计,降低二次设备的资金投入。In a specific embodiment, the heat-generating layer that generates thermal imaging patterns by self-heating is prepared by a combination of one or more methods of coating, printing, electroplating, metal etching and vapor deposition. The obtained heating layer is a coating or a plating layer, both of which are planar heating, and the processing technology is simple, and the existing equipment can be used to realize the effect design, and the capital investment of the secondary equipment can be reduced.
在一种具体实施方式中,所述自行发热形成热成像图案的加工工艺优选为涂布或印刷,这两种方式的生产成本更低,效果更好。In a specific embodiment, the process of forming thermal imaging patterns by self-heating is preferably coating or printing, both of which have lower production costs and better effects.
在一种具体实施方式中,所述均匀保护层包括均匀绝缘层、均匀保温层和均匀散热层中的一种或多种组合。散热层的主要功能是将发热层产生的热量散发出去;绝缘层的主要功能为隔绝发热层所通的电流;保温层的主要功能是防止发热层产生的热量散发出去。In a specific embodiment, the uniform protective layer includes one or more combinations of a uniform insulating layer, a uniform thermal insulation layer and a uniform heat dissipation layer. The main function of the heat dissipation layer is to dissipate the heat generated by the heating layer; the main function of the insulating layer is to isolate the current passing through the heating layer; the main function of the heat preservation layer is to prevent the heat generated by the heating layer from dissipating.
在一种具体实施方式中,所述均匀散热层为市场上可购得的一般的散热层材料,具体为散热涂层、散热膜、散热片和散热板中的一种或多种。其特点为所在区域具有近似相同的散热能力,具体为具有相同的比表面积或具有相同的热辐射系数,使其综合散热能力相同。In a specific embodiment, the uniform heat dissipation layer is a general heat dissipation layer material available in the market, specifically one or more of heat dissipation coating, heat dissipation film, heat dissipation fin and heat dissipation plate. Its characteristic is that the area has approximately the same heat dissipation capacity, specifically the same specific surface area or the same thermal radiation coefficient, so that the overall heat dissipation capacity is the same.
在一种具体实施方式中,所述均匀保温层为市场上可购得的一般的保温层材料,具体为保温涂层、保温膜、保温片和保温板中的一种或多种。其特点为所在区域具有近似相同的导热能力,具体为具有相同厚度或具有相同的导热系数,使其综合导热能力相同。In a specific embodiment, the uniform thermal insulation layer is a general thermal insulation layer material available in the market, specifically one or more of thermal insulation coating, thermal insulation film, thermal insulation sheet and thermal insulation board. Its characteristic is that the area has approximately the same thermal conductivity, specifically the same thickness or the same thermal conductivity, so that the overall thermal conductivity is the same.
在一种具体实施方式中,所述发热层为均匀发热的发热层,且所述保护层为热成像图案化保护层。In a specific embodiment, the heat generating layer is a heat generating layer that generates heat uniformly, and the protective layer is a thermal imaging patterned protective layer.
在一种具体实施方式中,所述热成像图案化保护层包括热成像图案化保温层和热成像图案化散热层中的至少一种。In a specific embodiment, the thermal imaging patterned protective layer includes at least one of a thermal imaging patterned thermal insulation layer and a thermal imaging patterned heat dissipation layer.
在一种具体实施方式中,所述热成像图案化散热层中设有至少两个具有不同散热能力的散热区域。具体来说,不同散热能力的散热区域为具有不同比表面积和具有不同热辐射系数材料中的至少一种所构成的综合散热能力不同的区域。In a specific embodiment, at least two heat dissipation regions with different heat dissipation capabilities are provided in the thermal imaging patterned heat dissipation layer. Specifically, the heat dissipation regions with different heat dissipation capabilities are regions with different comprehensive heat dissipation capabilities formed by at least one of materials with different specific surface areas and different thermal emissivity coefficients.
在一种具体实施方式中,所述热成像图案化保温层中设有至少两个具有不同保温能力的保温区域。具体来说,不同保温能力的保温区域为具有不同厚度和具有不同导热系数材料中的至少一种所构成的综合导热能力不同的区域。In a specific embodiment, at least two heat-retaining regions with different heat-retaining capabilities are provided in the thermal imaging patterned heat-retaining layer. Specifically, the thermal insulation regions with different thermal insulation capabilities are regions with different comprehensive thermal conductivity formed by at least one of materials with different thicknesses and different thermal conductivity.
在一种具体实施方式中,所述保护层还包括绝缘层。In a specific implementation manner, the protective layer further includes an insulating layer.
在一种具体实施方式中,上述散热层、绝缘层和保温层为不同层和/或同一层中的一种或多种组合。因为有些具有特殊材料或特殊构造的材料本身可同时具备散热和绝缘的效果或者保温和绝缘的效果。因此,所述的散热层、绝缘层和保温层可以是各自独立的构成,也可以是多层合一的构成。考虑到加工的便利性,优选为多层合一的构成。In a specific embodiment, the heat dissipation layer, the insulating layer and the thermal insulation layer are one or more combinations of different layers and/or the same layer. Because some materials with special materials or special structures can have the effect of heat dissipation and insulation or the effect of heat preservation and insulation at the same time. Therefore, the heat dissipation layer, insulating layer and thermal insulation layer may be formed independently, or may be composed of multiple layers in one. Considering the convenience of processing, it is preferably a multi-layer structure.
在一种具体实施方式中,所述发热层的材质包括金属材料或无机非金属材料中的一种,所述无机非金属材料包括碳素材料、红外陶瓷和托玛琳材料中的一种或多种,优选的,所述发热层的材质为碳素材料。In a specific embodiment, the material of the heat generating layer includes one of metal materials or inorganic non-metal materials, and the inorganic non-metal materials include one of carbon materials, infrared ceramics and tourmaline materials or Multiple, preferably, the material of the heat generating layer is carbon material.
在一种具体实施方式中,所述金属材料包括由铜、铝、铁和镍中的一种或多种制得的粉料、浆料或电镀原料。In a specific embodiment, the metal material includes powder, slurry or electroplating raw material made of one or more of copper, aluminum, iron and nickel.
在一种具体实施方式中,所述碳素材料包括由石墨、导电炭黑、碳晶、纳米碳管、碳纤维、石墨烯和富勒烯中的一种或多种制得的粉料或浆料。由于热成像主要由红外辐射产生,因此结合导电能力和红外辐射能力,碳素材料是发热层材质的优选方案。In a specific embodiment, the carbonaceous material includes powder or slurry made from one or more of graphite, conductive carbon black, carbon crystal, carbon nanotube, carbon fiber, graphene and fullerene material. Since thermal imaging is mainly generated by infrared radiation, carbon materials are the preferred material for the heating layer in combination with electrical conductivity and infrared radiation capabilities.
在一种具体实施方式中,所述红外陶瓷和所述托玛琳材料为粉料或浆料。In a specific embodiment, the infrared ceramic and the tourmaline material are powder or slurry.
在一种具体实施方式中,本发明的电热器件,可以是市场上可见的任意形式,优选为电热涂层、电热布、电热纸、电热膜、电热板和电热块中的一种或多种的组合。考虑到使用的便利性,优选为电热布、电热纸、电热膜和电热板中的一种或多种的组合。In a specific embodiment, the electric heating device of the present invention can be in any form available on the market, preferably one or more of electric heating coating, electric heating cloth, electric heating paper, electric heating film, electric heating plate and electric heating block The combination. Considering the convenience of use, it is preferably a combination of one or more of electric heating cloth, electric heating paper, electric heating film and electric heating plate.
在一种具体实施方式中,所述上述热成像图案化电热器件可应用在电热产品上,且该类电热产品可应用在生活用品、艺术品、健康理疗、工程建筑、军事训练等方面。In a specific embodiment, the above-mentioned thermal imaging patterned electrothermal device can be applied to electrothermal products, and such electrothermal products can be applied to daily necessities, artworks, health physiotherapy, engineering construction, military training, etc.
实施例Example
下面将结合附图对本发明的实施例作详细说明,本实施例在以本发明技术方案为前提下进行实施,给出了详细的实施方式和具体的操作过程,但本发明的保护范围不限于下述的实施例。The embodiments of the present invention will be described in detail below in conjunction with the accompanying drawings. This embodiment is implemented on the premise of the technical solution of the present invention, and detailed implementation methods and specific operating procedures are provided, but the protection scope of the present invention is not limited to Examples described below.
实施例1Example 1
一种热成像图案化电热器件,以PET膜作为保护层,碳晶作为发热层材质,具体制备步骤如下:A thermal imaging patterned electric heating device, with PET film as the protective layer and carbon crystal as the material of the heating layer, the specific preparation steps are as follows:
(1)以PET膜1为基材,使用贴纸将PET膜1上需镂空的区域覆盖住,镂空的区域分别为一个正方形、一个圆形和一个三角形;(1) Using the PET film 1 as the base material, use stickers to cover the area to be hollowed out on the PET film 1. The hollowed out area is a square, a circle and a triangle;
(2)采用涂布的方式在上述覆盖有贴纸的PET膜1上将碳晶导电油墨涂布于基材表面;(2) The carbon crystal conductive ink is coated on the surface of the substrate on the above-mentioned PET film 1 covered with stickers by means of coating;
(3)待碳晶导电油墨干燥后,取下贴纸,即在PET膜1的表面形成了具有镂空区域2的热成像图案化电热层3,如图1所示,其剖视图如图2所示。(3) After the carbon crystal conductive ink is dried, the sticker is removed, and a thermal imaging patterned electric heating layer 3 with a hollow area 2 is formed on the surface of the PET film 1, as shown in Figure 1, and its cross-sectional view is shown in Figure 2 .
在该实施例中,PET膜购于仪化东丽聚酯薄膜有限公司,厚度为150um。碳晶导电油墨购于深圳市联昌达实业有限公司,热成像图案化电热层的厚度为10um。In this example, the PET film was purchased from Yihua Toray Polyester Film Co., Ltd., with a thickness of 150 um. Carbon crystal conductive ink was purchased from Shenzhen Lianchangda Industrial Co., Ltd., and the thickness of the thermal imaging patterned electric heating layer was 10um.
将上述制备的得到的电热器件通电后进行热成像测试,其结果如图3所示。从中我们可以发现,本实施例的电热器件具有热成像图案化功能。The thermal imaging test was performed after the electrothermal device prepared above was energized, and the results are shown in FIG. 3 . From this we can find that the electrothermal device of this embodiment has a thermal imaging patterning function.
实施例2Example 2
一种热成像图案化电热器件,以PET膜作为保护层,石墨烯作为发热层材质,具体制备步骤如下:A thermal imaging patterned electrothermal device, with PET film as the protective layer and graphene as the material of the heating layer, the specific preparation steps are as follows:
使用PET膜作为基材,使用石墨烯导电油墨,采用凹版印刷的方式印刷满版图案,其中,凹版纹路为方孔,深度50微米,普通部分4密度为50目,发热图案部分5密度为100目。制得发热图案部分5比普通部分4印刷更薄的热成像图案化电热层,如图4所示,其剖视图与实施例1类似。Use PET film as the substrate, use graphene conductive ink, and use gravure printing to print full-page patterns, wherein the gravure lines are square holes, the depth is 50 microns, the density of the ordinary part 4 is 50 mesh, and the density of the heating pattern part 5 is 100 head. A thermographic patterned electric heating layer printed on the heating pattern part 5 thinner than the normal part 4 was obtained, as shown in FIG. 4 , whose cross-sectional view is similar to that of Example 1.
在该实施例中,PET膜购于仪化东丽聚酯薄膜有限公司,,其厚度为150um。石墨烯导电油墨购于深圳市联昌达实业有限公司,热成像图案化电热层的厚度为5um。In this embodiment, the PET film is purchased from Yihua Toray Polyester Film Co., Ltd., and its thickness is 150 um. The graphene conductive ink was purchased from Shenzhen Lianchangda Industrial Co., Ltd., and the thickness of the thermal imaging patterned electric heating layer was 5um.
将上述制备的得到的电热器件通电后进行热成像测试,其结果如图5所示。从中我们可以发现,本实施例的电热器件具有热成像图案化功能。The thermal imaging test was performed after the electrothermal device prepared above was energized, and the results are shown in FIG. 5 . From this we can find that the electrothermal device of this embodiment has a thermal imaging patterning function.
实施例3Example 3
一种热成像图案化电热器件,以PET膜作为保护层,导电炭黑和碳纳米管复合材料作为发热层材质,具体制备步骤如下:A thermal imaging patterned electric heating device, using PET film as a protective layer, conductive carbon black and carbon nanotube composite material as a heating layer material, the specific preparation steps are as follows:
使用PET膜1作为基材,使用导电炭黑和碳纳米管复合导电油墨,采用凹版印刷的方式印刷条纹状图案,其中,凹版纹路为方孔,深度50微米,普通部分4密度为50目,发热图案部分5密度为80目,制得发热图案部分5比普通部分4印刷更薄的热成像图案化电热层3,如图6所示。然后在热成像图案化电热层3的表面覆盖一层PET膜1作为保护膜,形成夹心结构,如图7所示。Use PET film 1 as the base material, use conductive carbon black and carbon nanotube composite conductive ink, and print striped patterns by gravure printing, wherein the gravure lines are square holes with a depth of 50 microns, and the density of the common part 4 is 50 mesh. The density of the heating pattern part 5 is 80 meshes, and the thermal imaging patterned electric heating layer 3 printed on the heating pattern part 5 is thinner than the ordinary part 4, as shown in FIG. 6 . Then, a layer of PET film 1 is covered on the surface of the thermal imaging patterned electrothermal layer 3 as a protective film to form a sandwich structure, as shown in FIG. 7 .
在该实施例中,PET膜购于仪化东丽聚酯薄膜有限公司,其厚度为150um。导电炭黑购于卡博特公司,碳纳米管购于镇江天奈公司,导电炭黑和碳纳米管的质量比为1:1,热成像图案化电热层的厚度为5um。In this embodiment, the PET film is purchased from Yihua Toray Polyester Film Co., Ltd., and its thickness is 150 um. Conductive carbon black was purchased from Cabot Company, and carbon nanotubes were purchased from Zhenjiang Tiannai Company. The mass ratio of conductive carbon black and carbon nanotubes was 1:1, and the thickness of the thermal imaging patterned electric heating layer was 5um.
将上述制备的得到的电热器件通电后进行热成像测试,其结果如图8所示。从中我们可以发现,本实施例的电热器件具有热成像图案化功能。The thermal imaging test was performed after the electrothermal device prepared above was energized, and the results are shown in FIG. 8 . From this we can find that the electrothermal device of this embodiment has a thermal imaging patterning function.
实施例4Example 4
一种热成像图案化电热器件,以环氧树脂板作为保护层,石墨烯材料作为发热层材质,具体制备步骤如下:A thermal imaging patterned electric heating device, using an epoxy resin plate as a protective layer, and a graphene material as a heating layer material, the specific preparation steps are as follows:
使用环氧树脂板为基材,使用石墨烯导电油墨,采用圆网印刷的方式印刷拉伸样条状条纹图案,其中,网孔密度为200目。制得发热图案部分5比普通部分4印刷更窄的热成像图案化电热层,如图9所示。Using an epoxy resin board as a base material, using graphene conductive ink, printing stretched spline stripe pattern by rotary screen printing, wherein the mesh density is 200 mesh. A thermographic patterned electrothermal layer with a narrower thermal imaging pattern printed on the heating pattern part 5 than the ordinary part 4 is obtained, as shown in FIG. 9 .
在该实施例中,环氧树脂板购于建材市场,其厚度为3mm。石墨烯购于宁波墨西科技有限公司,热成像图案化电热层的厚度为5um。In this embodiment, the epoxy resin plate is purchased from the building materials market, and its thickness is 3 mm. Graphene was purchased from Ningbo Moxi Technology Co., Ltd., and the thickness of the thermal imaging patterned electric heating layer was 5um.
将上述制备的得到的电热器件通电后进行热成像测试,其结果如图10所示。从中我们可以发现,本实施例的电热器件具有热成像图案化功能。The thermal imaging test was performed after the electrothermal device prepared above was energized, and the results are shown in FIG. 10 . From this we can find that the electrothermal device of this embodiment has a thermal imaging patterning function.
实施例5Example 5
一种热成像图案化电热器件,以布作为保护层,石墨烯材料作为发热层材质,具体制备步骤如下:A thermal imaging patterned electrothermal device, using cloth as a protective layer and graphene material as a heating layer material, the specific preparation steps are as follows:
使用布作为基材,使用石墨烯导电油墨,采用圆网印刷的方式印刷斜十字网纹状图案,其中,网孔密度为200目,普通部分4发热线条宽度为5mm,发热图案部分5线条宽度为2mm。制得发热图案部分5比普通部分4印刷更窄的热成像图案化电热层,结构如图11所示。Use cloth as the base material, use graphene conductive ink, and use rotary screen printing to print oblique cross pattern patterns, in which the mesh density is 200 mesh, the width of the common part 4 heating lines is 5 mm, and the heating pattern part 5 lines The width is 2mm. A thermographic patterned electrothermal layer with a narrower thermal imaging pattern printed on the heating pattern part 5 than the ordinary part 4 is obtained, and the structure is shown in FIG. 11 .
在该实施例中,布的材质为无纺布,购于建材市场,其厚度为2mm。石墨烯购于宁波墨西科技有限公司,热成像图案化电热层的厚度为5um。In this embodiment, the cloth is made of non-woven fabric, purchased from the building material market, and its thickness is 2 mm. Graphene was purchased from Ningbo Moxi Technology Co., Ltd., and the thickness of the thermal imaging patterned electric heating layer was 5um.
将上述制备的得到的电热器件通电后进行热成像测试,其结果如图12所示。从中我们可以发现,本实施例的电热器件具有热成像图案化功能。The thermal imaging test was performed after the electrothermal device prepared above was energized, and the results are shown in FIG. 12 . From this we can find that the electrothermal device of this embodiment has a thermal imaging patterning function.
实施例6Example 6
一种热成像图案化电热器件,具体制备步骤如下:A thermal imaging patterned electrothermal device, the specific preparation steps are as follows:
(1)在第一绝缘层9上印刷一层散热涂层7,散热涂层7的涂布形状为一个正方形、一个圆形和一个三角形,形成散热层8,如图13所示;(1) Print a layer of heat dissipation coating 7 on the first insulating layer 9, and the coating shape of heat dissipation coating 7 is a square, a circle and a triangle to form a heat dissipation layer 8, as shown in Figure 13;
(2)在散热层8上依次覆盖均匀的发热层10、第二绝缘层11和普通保温层12,其剖视图如图14所示。(2) A uniform heating layer 10 , a second insulating layer 11 and a common insulating layer 12 are sequentially covered on the heat dissipation layer 8 , the cross-sectional view of which is shown in FIG. 14 .
在该实施例中,散热涂层的材质为石墨烯散热涂料,购于宁波墨西科技有限公司,散热涂层的厚度为3um,第一绝缘层的材质为PET膜,购于仪化东丽聚酯薄膜有限公司,第一绝缘层的厚度为150um,第二绝缘层的材质为PET膜,购于仪化东丽聚酯薄膜有限公司,第二绝缘层的厚度为150um,发热层的材质为石墨烯,购于宁波墨西科技有限公司,发热层的厚度为10um,普通保温层的材质为环氧板,购于建材市场,普通保温层的厚度为10mm。In this embodiment, the heat dissipation coating is made of graphene heat dissipation coating, purchased from Ningbo Moxi Technology Co., Ltd., the thickness of the heat dissipation coating is 3um, and the material of the first insulating layer is PET film, purchased from Yihua Toray Polyester Film Co., Ltd., the thickness of the first insulating layer is 150um, the material of the second insulating layer is PET film, purchased from Yihua Dongli Polyester Film Co., Ltd., the thickness of the second insulating layer is 150um, the material of the heating layer It is graphene, purchased from Ningbo Moxi Technology Co., Ltd., the thickness of the heating layer is 10um, and the material of the ordinary insulation layer is epoxy board, purchased from the building materials market, and the thickness of the ordinary insulation layer is 10mm.
将上述制备的得到的电热器件通电后进行热成像测试,其结果如图15所示。从中我们可以发现,本实施例的电热器件具有热成像图案化功能。The thermal imaging test was performed after the electrothermal device prepared above was energized, and the results are shown in FIG. 15 . From this we can find that the electrothermal device of this embodiment has a thermal imaging patterning function.
实施例7Example 7
一种热成像图案化电热器件,具体制备步骤如下:A thermal imaging patterned electrothermal device, the specific preparation steps are as follows:
(1)在普通保温板13上粘附若干导热系数不同的保温膜14,保温膜14的形状为一个正方形、一个圆形和一个三角形,形成保温层15,如图16所示;(1) Adhere some thermal insulation films 14 with different thermal conductivity on common thermal insulation board 13, the shape of thermal insulation film 14 is a square, a circle and a triangle, forms thermal insulation layer 15, as shown in Figure 16;
(2)在保温层15上依次覆盖第二绝缘层11、均匀的发热层10、第三绝缘层6、和均匀的普通散热层16,如图17所示。(2) Cover the second insulating layer 11 , the uniform heating layer 10 , the third insulating layer 6 , and the uniform common heat dissipation layer 16 sequentially on the insulating layer 15 , as shown in FIG. 17 .
在该实施例中,保温膜的材质为PET预涂膜,购于温州康发包装材料有限公司,保温膜的厚度为50um,第一绝缘层的材质为PET膜,购于仪化东丽聚酯薄膜有限公司,第一绝缘层的厚度为100um,第二绝缘层的材质为PET膜,购于仪化东丽聚酯薄膜有限公司,第二绝缘层的厚度为100um,发热层的材质为石墨烯,购于宁波墨西科技有限公司,发热层的厚度为10um,保温层的材质为环氧板,购于建材市场,普通散热层的厚度为3mm。In this embodiment, the material of the thermal insulation film is PET pre-coated film, purchased from Wenzhou Kangfa Packaging Material Co., Ltd., the thickness of the thermal insulation film is 50um, and the material of the first insulating layer is PET film, purchased from Yihua Toray Polymer Co., Ltd. Ester Film Co., Ltd., the thickness of the first insulating layer is 100um, the material of the second insulating layer is PET film, purchased from Yihua Dongli Polyester Film Co., Ltd., the thickness of the second insulating layer is 100um, and the material of the heating layer is Graphene, purchased from Ningbo Moxi Technology Co., Ltd., the thickness of the heating layer is 10um, and the material of the insulation layer is epoxy board, which is purchased from the building materials market. The thickness of the ordinary heat dissipation layer is 3mm.
将上述制备的得到的电热器件通电后进行热成像测试,其结果如图18所示。从中我们可以发现,本实施例的电热器件具有热成像图案化功能。The thermal imaging test was performed after the electrothermal device prepared above was energized, and the results are shown in FIG. 18 . From this we can find that the electrothermal device of this embodiment has a thermal imaging patterning function.
实施例8Example 8
一种热成像图案化电热器件,具体制备步骤如下:A thermal imaging patterned electrothermal device, the specific preparation steps are as follows:
(1)取一普通保温板13,并在该普通保温板13粘附若干导热系数不同的保温膜14,形成保温层15,如图16所示;(1) Get a common thermal insulation board 13, and adhere some thermal insulation films 14 with different thermal conductivity to the common thermal insulation board 13 to form a thermal insulation layer 15, as shown in Figure 16;
(2)在第一绝缘层上印刷一层散热涂层7,形成散热层8,其中,散热层8中散热涂层7所在区域与保温层15中保温膜14所在区域相对应,如图13所示;(2) Print one deck of heat dissipation coating 7 on the first insulating layer to form heat dissipation layer 8, wherein, the area where heat dissipation coating 7 is located in heat dissipation layer 8 corresponds to the area where heat insulation film 14 is located in insulation layer 15, as shown in Figure 13 shown;
(3)在保温层15表面印刷网格状的热成像图案化电热层3,其中,印刷用的油墨为石墨烯,在保温层15中普通保温板13对应区域,热成像图案化电热层3的目数为40目,厚度为5um,在保温层15中保温膜14对应区域的厚度为50um,热成像图案化电热层3的结构如图19所示。(3) Print a grid-shaped thermal imaging patterned electrothermal layer 3 on the surface of the thermal insulation layer 15, wherein the printing ink is graphene, and in the corresponding area of the ordinary thermal insulation board 13 in the thermal insulation layer 15, the thermal imaging patterned electrothermal layer 3 The mesh number is 40 mesh, the thickness is 5um, and the thickness of the corresponding area of the heat preservation film 14 in the heat preservation layer 15 is 50um. The structure of the thermal imaging patterned electric heating layer 3 is shown in FIG. 19 .
(4)将散热层8固定在热成像图案化电热层3的另一侧,使散热涂层7与保温膜14所在区域重合,形成如图20所示的电热器件。(4) Fix the heat dissipation layer 8 on the other side of the thermal imaging patterned electrothermal layer 3, make the area where the heat dissipation coating 7 overlaps with the thermal insulation film 14, and form an electrothermal device as shown in FIG. 20 .
在该实施例中,普通保温板的材质为环氧板,购于建材市场,其厚度为3mm。保温膜的材质为PET预涂膜,购于温州康发包装材料有限公司,保温膜的厚度为50um。散热涂层的材质为石墨烯,购于宁波墨西科技有限公司,散热涂料的厚度为3um,石墨烯购于宁波墨西科技有限公司。In this embodiment, the common insulation board is made of epoxy board, purchased from the building material market, and its thickness is 3 mm. The material of the thermal insulation film is PET pre-coated film, purchased from Wenzhou Kangfa Packaging Materials Co., Ltd., and the thickness of the thermal insulation film is 50um. The heat dissipation coating is made of graphene, which was purchased from Ningbo Moxi Technology Co., Ltd. The thickness of the heat dissipation coating is 3um, and the graphene was purchased from Ningbo Moxi Technology Co., Ltd.
将上述制备的得到的电热器件通电后进行热成像测试,其结果如图21所示。从中我们可以发现,本实施例的电热器件具有热成像图案化功能。The thermal imaging test was performed after the electrothermal device prepared above was energized, and the results are shown in FIG. 21 . From this we can find that the electrothermal device of this embodiment has a thermal imaging patterning function.
上述对实施例的描述是为了便于本技术领域的普通技术人员能理解和应用本申请。熟悉本领域技术的人员显然可以容易地对这些实施例做出各种修改,并把在此说明的一般原理应用到其它实施例中而不必付出创造性的劳动。因此,本申请不限于这里的实施例,本领域技术人员根据本申请披露的内容,在不脱离本申请范围和精神的情况下做出的改进和修改都本申请的范围之内。The above description of the embodiments is for those of ordinary skill in the art to understand and apply the present application. It will be apparent to those skilled in the art that various modifications to these embodiments can be easily made, and the general principles described here can be applied to other embodiments without creative efforts. Therefore, the present application is not limited to the embodiments here, and improvements and modifications made by those skilled in the art based on the contents disclosed in the present application without departing from the scope and spirit of the present application are within the scope of the present application.
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