CN111264518A - Chlorine dioxide composition with bactericidal effect - Google Patents
Chlorine dioxide composition with bactericidal effect Download PDFInfo
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- CN111264518A CN111264518A CN202010207911.7A CN202010207911A CN111264518A CN 111264518 A CN111264518 A CN 111264518A CN 202010207911 A CN202010207911 A CN 202010207911A CN 111264518 A CN111264518 A CN 111264518A
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- chlorine dioxide
- lozenge
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- sodium chlorite
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 84
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 42
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 42
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 16
- 239000007937 lozenge Substances 0.000 claims abstract description 15
- 239000000126 substance Substances 0.000 claims abstract description 14
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims abstract description 13
- 229960002218 sodium chlorite Drugs 0.000 claims abstract description 13
- 230000002378 acidificating effect Effects 0.000 claims abstract description 12
- 230000004913 activation Effects 0.000 claims abstract description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000314 lubricant Substances 0.000 claims abstract description 8
- 235000015393 sodium molybdate Nutrition 0.000 claims abstract description 8
- 239000011684 sodium molybdate Substances 0.000 claims abstract description 8
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000001954 sterilising effect Effects 0.000 claims abstract description 8
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 8
- 239000007884 disintegrant Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 5
- 238000005260 corrosion Methods 0.000 claims abstract description 4
- 230000007797 corrosion Effects 0.000 claims abstract description 4
- 230000005764 inhibitory process Effects 0.000 claims abstract description 4
- 230000009965 odorless effect Effects 0.000 claims abstract description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000000694 effects Effects 0.000 claims description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 4
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical group [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 235000017550 sodium carbonate Nutrition 0.000 claims description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 230000001737 promoting effect Effects 0.000 claims description 2
- 230000002070 germicidal effect Effects 0.000 claims 3
- 125000003827 glycol group Chemical group 0.000 claims 1
- 235000010603 pastilles Nutrition 0.000 claims 1
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 abstract description 2
- 239000000443 aerosol Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 2
- 229960002715 nicotine Drugs 0.000 abstract description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 abstract description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000003826 tablet Substances 0.000 description 10
- 230000001590 oxidative effect Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 3
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable
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- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
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Abstract
本发明提供一种具杀菌作用的二氧化氯组合物，其特征在于：以其总重量计，包括亚氯酸钠20～50％、钼酸钠10～20％、酸性物质10～20％、崩解剂10～20％、及润滑剂5～25％，以有效提供一种具杀菌及方便使用的二氧化氯锭剂；其中:亚氯酸钠，为产生二氧化氯的主要材料；钼酸钠，为二氧化氯锭剂产生缓蚀作用；酸性物质，主要是用来与亚氯酸钠反应以释出二氧化氯；崩解剂，能帮助锭剂充分崩解；润滑剂，为乙二醇，具有使锭剂粘结且无色无臭，并促进锭剂活化。本发明组合物使用时，能具有除臭，同时控制空气菌落数与挥发性化合物(如：甲醛，尼古丁)，以及可利用气雾式灭菌而可广泛运用各产业。The invention provides a chlorine dioxide composition with bactericidal effect, which is characterized in that: based on its total weight, it comprises 20-50% of sodium chlorite, 10-20% of sodium molybdate, 10-20% of acidic substances, Disintegrant 10～20% and lubricant 5～25%, to effectively provide a kind of chlorine dioxide lozenge with sterilization and convenient use; Wherein: sodium chlorite, is the main material that produces chlorine dioxide; Sodium, which produces corrosion inhibition for chlorine dioxide lozenges; acidic substances, which are mainly used to react with sodium chlorite to release chlorine dioxide; disintegrants, which can help the lozenges to fully disintegrate; lubricants, which are used for Glycol, which makes the lozenge cohesive, colorless and odorless, and facilitates lozenge activation. When the composition of the present invention is used, it can deodorize, control the number of air colonies and volatile compounds (such as formaldehyde, nicotine), and can be sterilized by aerosol, so it can be widely used in various industries.
Description
技术领域technical field
本发明涉及一种具杀菌作用的二氧化氯组合物，其以亚氯酸钠和钼酸钠为主要材料制成，除可增加二氧化氯氧化能力，并使其活化，且同样具有杀菌、分解有毒化学物质之功效。The present invention relates to a chlorine dioxide composition with bactericidal effect. The effect of decomposing toxic chemicals.
背景技术Background technique
一般以二氧化氯组合物所制之产品，如中国大陆发明专利CN101595891A所述，其系由亚氯酸钠23～70％、乙二胺四乙酸二钠5～15％、酸性物质5～15％、崩解剂5～15％、及碱性物质5～15％所组成，且不须现场调制，并具有方便保存与使用功能之锭剂、粉剂产品。Generally, the product made of chlorine dioxide composition, as described in Chinese mainland invention patent CN101595891A, is composed of 23-70% sodium chlorite, 5-15% disodium EDTA, 5-15% acidic substance %, 5-15% of disintegrating agent, and 5-15% of alkaline substance, and it does not need to be prepared on site, and is a tablet and powder product with convenient storage and use functions.
但是，其中乙二胺四乙酸二钠(EDTA)属于螯合剂，反而对二氧化氯氧化能力有抑制作用，易造成二氧化氯活性不足。再者，碱性物质将会拉高溶液的酸度，则易使活化率降低。However, disodium ethylenediaminetetraacetate (EDTA) is a chelating agent, but has an inhibitory effect on the oxidative ability of chlorine dioxide, which is easy to cause insufficient activity of chlorine dioxide. Furthermore, the alkaline substance will increase the acidity of the solution, which will easily reduce the activation rate.
因此，如何使二氧化氯氧化能力不受影响，且使其活化率增加，实有再研发改良的必要。Therefore, how to keep the chlorine dioxide oxidizing ability unaffected and increase its activation rate requires further research and improvement.
发明内容SUMMARY OF THE INVENTION
本发明提供具杀菌作用的二氧化氯组合物。The present invention provides a chlorine dioxide composition with bactericidal effect.
本发明的主要目的，旨在提供一种具杀菌作用的二氧化氯组合物，其为一种可维持二氧化氯氧化能力，且具方便保存与使用功能的锭剂、粉剂产品。The main purpose of the present invention is to provide a chlorine dioxide composition with bactericidal effect, which is a tablet and powder product that can maintain the chlorine dioxide oxidizing ability and has functions of convenient storage and use.
本发明的次一目的，旨在提供一种具杀菌作用的二氧化氯组合物，其为一种使二氧化氯其活化率增加的锭剂、粉剂产品。The second object of the present invention is to provide a chlorine dioxide composition with bactericidal effect, which is a tablet or powder product that increases the activation rate of chlorine dioxide.
本发明解决其技术问题所采用的技术方案是：The technical scheme adopted by the present invention to solve its technical problems is:
一种具杀菌作用的二氧化氯组合物，其特征在于：A chlorine dioxide composition with bactericidal effect is characterized in that:
以其总重量计，包括亚氯酸钠20～50％、钼酸钠10～20％、酸性物质10～20％、崩解剂10～20％、及润滑剂5～25％，以有效提供一种具杀菌及方便使用的二氧化氯锭剂；其中:Based on its total weight, it includes 20-50% of sodium chlorite, 10-20% of sodium molybdate, 10-20% of acidic substance, 10-20% of disintegrant, and 5-25% of lubricant, so as to effectively provide A kind of chlorine dioxide lozenge of sterilization and convenient use; Wherein:
亚氯酸钠，为产生二氧化氯的主要材料；Sodium chlorite, the main material for generating chlorine dioxide;
钼酸钠，为二氧化氯锭剂产生缓蚀作用；Sodium molybdate, which produces corrosion inhibition for chlorine dioxide lozenges;
酸性物质，主要是用来与亚氯酸钠反应以释出二氧化氯；Acidic substances, mainly used to react with sodium chlorite to release chlorine dioxide;
崩解剂，能帮助锭剂充分崩解；Disintegrant, which can help the lozenge fully disintegrate;
润滑剂，为乙二醇，具有使锭剂粘结且无色无臭，并促进锭剂活化。The lubricant, which is glycol, has the effect of making the tablet cohesive, colorless and odorless, and facilitating tablet activation.
酸性物质选自柠檬酸、酒石酸其中之一，或其它酸性之化合物或混合物。The acidic substance is selected from one of citric acid, tartaric acid, or other acidic compounds or mixtures.
崩解剂选自羧甲基纤维素钠、碳酸氢钠、碳酸钠其中之一。The disintegrant is selected from one of sodium carboxymethyl cellulose, sodium bicarbonate, and sodium carbonate.
本发明的组合物，其混水使用时的有效加入量范围在0.3～700mg/L内，均具有良好的杀菌效果。The composition of the present invention has a good bactericidal effect when the effective addition amount ranges from 0.3 to 700 mg/L when it is mixed with water.
本发明的有益之处在于：The benefits of the present invention are:
本发明组合物使用时，能具有除臭，同时控制空气菌落数与挥发性化合物(如：甲醛，尼古丁)，以及可利用气雾式灭菌而可广泛运用各产业。具有增加二氧化氯氧化能力；二氧化氯的活化率增加；亦不需任何器械辅助而可达到空间净化之杀菌效果；而其活性不受酸、碱浓度影响，pH值较稳定；应用范围广泛的诸多优点。When the composition of the present invention is used, it can deodorize, control the number of air colonies and volatile compounds (such as formaldehyde, nicotine), and can be sterilized by aerosol, so it can be widely used in various industries. It has the ability to increase the oxidation of chlorine dioxide; the activation rate of chlorine dioxide is increased; it can achieve the sterilization effect of space purification without any equipment assistance; its activity is not affected by acid and alkali concentration, and its pH value is relatively stable; it has a wide range of applications many advantages.
具体实施方式Detailed ways
本发明所述的一种具杀菌作用的二氧化氯组合物，以其总重量计，其包括亚氯酸钠20～50％、钼酸钠10～20％、酸性物质10～20％、崩解剂10～20％、及润滑剂5～25％，以有效提供一种具杀菌作用及方便使用功能的二氧化氯消毒锭剂；其中，The chlorine dioxide composition with bactericidal effect of the present invention, based on its total weight, comprises 20-50% of sodium chlorite, 10-20% of sodium molybdate, 10-20% of acidic substances, 10-20% of the solution agent and 5-25% of the lubricant, so as to effectively provide a chlorine dioxide disinfection tablet with bactericidal effect and convenient use function; wherein,
亚氯酸钠，为产生二氧化氯的主要材料；Sodium chlorite, the main material for generating chlorine dioxide;
钼酸钠，为二氧化氯锭剂产生缓蚀作用；Sodium molybdate, which produces corrosion inhibition for chlorine dioxide lozenges;
酸性物质选自柠檬酸、酒石酸其中之一，或其它酸性之化合物或混合物，主要是用来与亚氯酸钠反应以释出二氧化氯；Acidic substances are selected from one of citric acid, tartaric acid, or other acidic compounds or mixtures, which are mainly used to react with sodium chlorite to release chlorine dioxide;
崩解剂，选自羧甲基纤维素钠、碳酸氢钠、碳酸钠其中之一，羧甲基纤维素钠、碳酸氢钠、碳酸钠与酸性物质反应能使锭剂在水中可迅充分崩解；The disintegrant is selected from one of sodium carboxymethyl cellulose, sodium bicarbonate, and sodium carbonate. The reaction of sodium carboxymethyl cellulose, sodium bicarbonate, and sodium carbonate with acidic substances can make the tablet disintegrate quickly and fully in water. untie;
润滑剂，为乙二醇，具有使锭剂粘结且无色无臭，并促进锭剂活化，能帮助二氧化氯达到充分杀菌的功效。The lubricant, which is ethylene glycol, has the function of making the tablet sticky, colorless and odorless, promoting the activation of the tablet, and helping the chlorine dioxide to achieve the effect of fully sterilizing.
据上述的成分组合，本发明能以该组合物与水或空气接触时所释放出来的二氧化氯及钼酸钠的成分，可达到消毒杀菌工作；又，本发明的组合物，其混水使用时的有效加入量范围在0.3～700mg/L内，均具有良好的杀菌效果。According to the above-mentioned combination of components, the present invention can achieve disinfection and sterilization with the components of chlorine dioxide and sodium molybdate released when the composition is in contact with water or air; The effective addition amount during use is in the range of 0.3 to 700 mg/L, all of which have good bactericidal effect.
使用时，可直接投入水中使其自然崩解而溶于水中，可达到水质净化功效，或将该锭剂置于空气中主动吸聚空气中的湿气，藉此达到自然挥发而达到净化空气的功效，故本发明在使用上极为方便。When in use, it can be directly put into water to make it disintegrate naturally and dissolve in water, which can achieve the effect of water purification, or the tablet can be placed in the air to actively absorb the moisture in the air, thereby achieving natural volatilization and purifying the air. , so the present invention is extremely convenient to use.
综上所述，本发明的一种具杀菌作用的二氧化氯组合物确实能保有杀菌、分解化学物质的功效外，且同时增加二氧化氯氧化能力，并二氧化氯其活化率增加，进而增加该项产品的实用性与经济价值。To sum up, the chlorine dioxide composition with bactericidal effect of the present invention can indeed retain the effect of sterilizing and decomposing chemical substances, and at the same time increase the chlorine dioxide oxidizing ability, and increase the activation rate of chlorine dioxide, and then Increase the practicality and economic value of the product.
如以上所揭露的实施例组合物的各成分的百分比，可随使用需求而在本案所述的百分比范围内自由调制，或添加其他的色料或香料使用，故本发明的申请专利范围并不局限于此，凡在不偏离本发明构思的条件下，在所属技术领域人员了解的相似或等同成分来替换。As disclosed above, the percentage of each component of the composition of the embodiment can be freely adjusted within the percentage range described in this case according to the needs of use, or other colorants or fragrances can be added for use. Therefore, the scope of the patent application of the present invention does not apply. Limited thereto, any similar or equivalent components known to those skilled in the art can be replaced without departing from the inventive concept.
以上说明对本发明而言只是说明性的，而非限制性的，本领域普通技术人员理解，在不脱离权利要求所限定的精神和范围的情况下，可作出许多修改、变化或等效，但都将落入本发明的保护范围之内。The above description is only illustrative rather than restrictive for the present invention. Those skilled in the art understand that many modifications, changes or equivalents can be made without departing from the spirit and scope defined by the claims. All will fall within the protection scope of the present invention.
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