CN111772159B - Oil-water composition - Google Patents
Oil-water composition Download PDFInfo
- Publication number
- CN111772159B CN111772159B CN201910265761.2A CN201910265761A CN111772159B CN 111772159 B CN111772159 B CN 111772159B CN 201910265761 A CN201910265761 A CN 201910265761A CN 111772159 B CN111772159 B CN 111772159B
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- Prior art keywords
- oil
- water composition
- phase
- water
- composition
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
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- A—HUMAN NECESSITIES
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- A23B2/00—Preservation of foods or foodstuffs, in general
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- A—HUMAN NECESSITIES
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- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/10—Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/105—Plant extracts, their artificial duplicates or their derivatives
- A23L33/11—Plant sterols or derivatives thereof, e.g. phytosterols
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P10/00—Shaping or working of foodstuffs characterised by the products
- A23P10/30—Encapsulation of particles, e.g. foodstuff additives
- A23P10/35—Encapsulation of particles, e.g. foodstuff additives with oils, lipids, monoglycerides or diglycerides
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
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Abstract
本发明提供一种油水组合物,以所述油水组合物的总质量计,所述油水组合物包含5‑80%的油相和20‑95%的水相,所述油相为至少含有稻米油的油脂组合物,以所述油相的总质量计,谷维素含量为小于20000ppm。所述油水组合物用于调理酱,使得调理酱不近氧化稳定性好,而且具有良好的冻融稳定性和热稳定性。The invention provides an oil-water composition, based on the total mass of the oil-water composition, the oil-water composition comprises 5-80% of an oil phase and 20-95% of a water phase, and the oil phase contains at least rice In the oil composition, the oryzanol content is less than 20000ppm based on the total mass of the oil phase. The oil-water composition is used for cooking sauce, so that the cooking sauce not only has good oxidation stability, but also has good freeze-thaw stability and thermal stability.
Description
技术领域technical field
本发明涉及油脂领域,尤其涉及一种水包油型组合物。The invention relates to the field of fats and oils, in particular to an oil-in-water composition.
背景技术Background technique
沙拉酱是一种用途非常广泛的酱料,可以用在烘焙品夹心、馅料、各种沙拉中。基本的原料包括油、蛋黄、醋酸等。沙拉酱一般使用的油为大豆油,但是由于大豆油中多不饱和脂肪酸比较多,容易氧化,产生豆腥味。另外由于沙拉酱开封后需要冷藏储存,在温度波动过程中可能会破乳,油水分离,所以冻融稳定性好也是评价沙拉酱的一个关键指标。Salad dressing is a very versatile sauce that can be used in baked goods sandwiches, fillings, and various salads. The basic raw materials include oil, egg yolk, acetic acid, etc. The oil generally used in salad dressing is soybean oil, but because soybean oil contains more polyunsaturated fatty acids, it is easy to oxidize and produces a beany smell. In addition, since salad dressing needs to be refrigerated after opening, it may break emulsion and separate oil and water during temperature fluctuations, so good freeze-thaw stability is also a key indicator for evaluating salad dressing.
US1998143817A保护一种沙拉酱油脂组合物,所述组合物中的添加甾醇,但是该体系需要添加结晶抑制剂,而且其解决的是冷冻稳定性,对于冻融稳定性未记载。US1998143817A protects a salad dressing oil composition, in which sterols are added, but this system needs to add crystallization inhibitors, and it solves the freezing stability, and there is no record about the freezing-thawing stability.
发明内容Contents of the invention
为了克服以上缺陷,本发明的发明人通过采用稻米油与特殊乳化剂复配得到一种水包油型组合物,将该组合物不仅抗氧化,而且用于水包油酱中风味浓郁。In order to overcome the above defects, the inventors of the present invention obtained an oil-in-water composition by compounding rice oil and a special emulsifier. The composition not only resists oxidation, but also has a strong flavor when used in oil-in-water sauce.
本发明的第一方面,提供一种油水组合物,以所述油水组合物的总质量计,所述油水组合物包含5-80%的油相和20-95%的水相,所述油相为至少含有稻米油的油脂组合物,以所述油相的总质量计,谷维素含量为小于20000 ppm。The first aspect of the present invention provides an oil-water composition, based on the total mass of the oil-water composition, the oil-water composition comprises 5-80% of the oil phase and 20-95% of the water phase, the oil The phase is an oil composition containing at least rice oil, and the content of oryzanol is less than 20000 ppm based on the total mass of the oil phase.
在一个或多个优选方案中,所述油水组合物中,以所述油相的总质量计,植物甾醇含量小于20000 ppm。In one or more preferred solutions, in the oil-water composition, based on the total mass of the oil phase, the content of phytosterol is less than 20000 ppm.
在一个或多个优选方案中,所述油相还包含大豆油、葵花籽油、高油酸葵花籽油、玉米油、椰子油、菜籽油、低芥酸菜籽油、花生油、芝麻油、橄榄油、核桃油、棉籽油,亚麻油、红花籽油、油茶籽油、米糠油、核桃油、南瓜子油、葡萄籽油、月见草油、花椒籽油、杏仁油、小麦胚芽油、紫苏籽油和乳木果油。可使用这些液体植物油中的任意一种或任意多种的混合物。In one or more preferred versions, the oil phase further comprises soybean oil, sunflower oil, high oleic sunflower oil, corn oil, coconut oil, rapeseed oil, canola oil, peanut oil, sesame oil, Olive oil, walnut oil, cottonseed oil, linseed oil, safflower oil, camellia oil, rice bran oil, walnut oil, pumpkin seed oil, grape seed oil, evening primrose oil, pepper seed oil, almond oil, wheat germ oil , Perilla Seed Oil and Shea Butter. Any one or a mixture of any of these liquid vegetable oils may be used.
在一个或多个优选方案中,以所述油水组合物的总质量计,所述油水组合物中包含0.5-30%的蛋黄,优选0.5-25%蛋黄,更优选0.5-20%蛋黄。In one or more preferred versions, based on the total mass of the oil-water composition, the oil-water composition contains 0.5-30% egg yolk, preferably 0.5-25% egg yolk, more preferably 0.5-20% egg yolk.
在一个或多个优选方案中,所述蛋黄为新鲜蛋黄液、巴氏杀菌蛋黄液、冷冻蛋黄液、蛋黄粉等,优选巴氏杀菌蛋黄液和冷冻蛋黄液。In one or more preferred versions, the egg yolk is fresh egg yolk liquid, pasteurized egg yolk liquid, frozen egg yolk liquid, egg yolk powder, etc., preferably pasteurized egg yolk liquid and frozen egg yolk liquid.
在一个或多个优选方案中,所述油水组合物的pH为3-6.5。In one or more preferred solutions, the pH of the oil-water composition is 3-6.5.
在一个或多个优选方案中,所述油水组合物中还包含食盐、甜味剂、食用添加剂、食品原辅料中的一种或多种。In one or more preferred solutions, the oil-water composition further includes one or more of salt, sweeteners, food additives, and food raw materials.
在一个或多个优选方案中,所述食用添加剂选自香精香料、乳化剂、抗氧化剂、 食用色素、食用胶体中的一种或多种。在一个或多个优选方案中,所述乳化剂为磷脂,以所述油水组合物的总质量计,所述磷脂用量为0.1-0.5%。In one or more preferred versions, the food additive is selected from one or more of flavors and fragrances, emulsifiers, antioxidants, food colorings, and food colloids. In one or more preferred versions, the emulsifier is phospholipid, and the amount of phospholipid is 0.1-0.5% based on the total mass of the oil-water composition.
在一个或多个优选方案中,所述食品原辅料中包含风味物质。In one or more preferred solutions, the food raw materials contain flavor substances.
在一个或多个优选方案中,风味物质选自:水果类、坚果类、蔬菜类、药草类、乳制品、蛋黄、巧克力、咖啡、茶中的一种或多种。In one or more preferred embodiments, the flavoring substances are selected from one or more of fruits, nuts, vegetables, herbs, dairy products, egg yolks, chocolate, coffee, and tea.
在一个或多个优选方案中,所述水果类为苹果、桔子、草莓、桃、菠萝、柚子、西瓜中的一种或多种。In one or more preferred versions, the fruit is one or more of apples, oranges, strawberries, peaches, pineapples, grapefruits, and watermelons.
在一个或多个优选方案中,所述坚果类为栗子、杏仁、核桃、松仁、花生、瓜子、榛子、腰果、开心果中的一种或多种。In one or more preferred versions, the nuts are one or more of chestnuts, almonds, walnuts, pine nuts, peanuts, melon seeds, hazelnuts, cashews, and pistachios.
在一个或多个优选方案中,所述水果类为番茄、胡萝卜、甘薯、菠菜中的一种或多种。In one or more preferred versions, the fruit is one or more of tomatoes, carrots, sweet potatoes, and spinach.
在一个或多个优选方案中,所述药草类为金银花、野菊花、香草、薄荷中的一种或多种。In one or more preferred versions, the herbs are one or more of honeysuckle, wild chrysanthemum, vanilla, mint.
在一个或多个优选方案中,所述乳制品为牛奶、炼乳、全脂奶粉、脱脂奶粉、半脱脂奶粉、酪蛋白酸钠、乳清、干酪中的一种或多种。In one or more preferred versions, the dairy product is one or more of milk, condensed milk, whole milk powder, skimmed milk powder, semi-skimmed milk powder, sodium caseinate, whey, and cheese.
在一个或多个优选方案中,所述油水组合物为水包油型。In one or more preferred embodiments, the oil-water composition is an oil-in-water type.
本发明的第二方面,提供一种油水组合物的制备方法,所述方法包括步骤:A second aspect of the present invention provides a method for preparing an oil-water composition, said method comprising the steps of:
(1)准备油相:至少含有稻米油的油脂组合物;(1) Prepare the oil phase: a grease composition containing at least rice oil;
(2)准备水相;(2) Prepare the aqueous phase;
(3)将油相和水相按照质量比5-80:20-95进行混合。(3) The oil phase and the water phase are mixed according to the mass ratio of 5-80:20-95.
在一个或多个优选方案中,所述步骤(3)为在不断搅拌剪切过程中将油相倒入至水相中。In one or more preferred schemes, the step (3) is pouring the oil phase into the water phase during continuous stirring and shearing.
在一个或多个优选方案中,所述水相的制备:包括将水、蛋黄与甜味剂混合均匀的步骤,其中以油水组合物的总质量计,蛋黄的用量为0.5-30%。In one or more preferred versions, the preparation of the water phase includes the step of uniformly mixing water, egg yolk and sweetener, wherein the amount of egg yolk is 0.5-30% based on the total mass of the oil-water composition.
在一个或多个优选方案中,所述水相的制备还包括添加乳化剂的步骤。In one or more preferred solutions, the preparation of the aqueous phase further includes the step of adding an emulsifier.
在一个或多个优选方案中,所述乳化剂为磷脂,优选地,以所述油水组合物的总质量计,所述磷脂用量为0.1-0.5%。In one or more preferred versions, the emulsifier is phospholipid, preferably, based on the total mass of the oil-water composition, the amount of phospholipid is 0.1-0.5%.
在一个或多个优选方案中,以油水组合物的总质量计,所述甜味剂的用量为0.5-40%,优选0.5-20%,更优选0.5-15%。In one or more preferred versions, based on the total mass of the oil-water composition, the sweetener is used in an amount of 0.5-40%, preferably 0.5-20%, more preferably 0.5-15%.
本发明的第三方面,提供一种调理酱,所述调理酱包含本发明所述油水组合物。The third aspect of the present invention provides a seasoning sauce, which comprises the oil-water composition of the present invention.
在一个或多个优选方案中,所述调理酱为沙拉酱、蛋黄酱、涂抹酱、餐桌用酱的用途。In one or more preferred versions, the seasoning sauce is the application of salad dressing, mayonnaise, spread, and table sauce.
本发明的第四方面,提供提高调理酱冻融稳定性的方法,所述方法为采用本发明的油水组合物。The fourth aspect of the present invention provides a method for improving the freeze-thaw stability of the sauce, the method is to use the oil-water composition of the present invention.
本发明的油脂组合物技术效果:Grease composition technical effect of the present invention:
1、富含植物甾醇和谷维素,更加营养。1. Rich in phytosterols and oryzanol, more nutritious.
2、抗氧化性更好,冻融稳定性和热稳定性好,货架期更稳定。2. Better oxidation resistance, good freeze-thaw stability and thermal stability, and more stable shelf life.
3、风味更浓郁。3. Stronger flavor.
具体实施方式Detailed ways
应理解,在本发明范围内中,本发明的上述各技术特征和在下文(如实施例)中具体描述的各技术特征之间都可以互相组合,从而构成优选的技术方案。It should be understood that within the scope of the present invention, the above-mentioned technical features of the present invention and the technical features specifically described in the following (such as embodiments) can be combined with each other to form a preferred technical solution.
本发明的第一方面提供了一种油水组合物,本发明的油水组合物可广泛用作烘焙品夹心、馅料、各种沙拉中。The first aspect of the present invention provides an oil-water composition, and the oil-water composition of the present invention can be widely used in sandwiches of baked goods, fillings, and various salads.
本发明的油水组合物,以所述油水组合物的总量计,所述油水组合物包含5-80%的油相和20-95%的水相,所述油相为至少含有稻米油的油脂组合物。The oil-water composition of the present invention, based on the total amount of the oil-water composition, the oil-water composition comprises 5-80% of an oil phase and 20-95% of a water phase, and the oil phase is at least rice oil-containing Grease composition.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总量计,所述油水组合物中包含30-80%的油相和20-70%的水相。In one or more specific embodiments of the present invention, based on the total amount of the oil-water composition, the oil-water composition includes 30-80% of the oil phase and 20-70% of the water phase.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总量计,所述油水组合物中包含40-75%的油相和25-60%的水相。In one or more specific embodiments of the present invention, based on the total amount of the oil-water composition, the oil-water composition includes 40-75% of the oil phase and 25-60% of the water phase.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总量计,所述油水组合物中包含50-75%的油相和25-50%的水相。In one or more specific embodiments of the present invention, based on the total amount of the oil-water composition, the oil-water composition comprises 50-75% of the oil phase and 25-50% of the water phase.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总量计,所述油水组合物中包含60-75%的油相和25-40%的水相。In one or more specific embodiments of the present invention, based on the total amount of the oil-water composition, the oil-water composition includes 60-75% of the oil phase and 25-40% of the water phase.
尤其优选的是,以所述油相的总质量计,谷维素含量为小于20000 ppm。Especially preferably, based on the total mass of the oil phase, the content of oryzanol is less than 20000 ppm.
在本发明的一个或多个具体实施方案中,以所述油相的总质量计,谷维素含量为3000-20000ppm。In one or more specific embodiments of the present invention, based on the total mass of the oil phase, the content of oryzanol is 3000-20000ppm.
在本发明的一个或多个具体实施方案中,以所述油相的总质量计,谷维素含量为8000-20000ppm。In one or more specific embodiments of the present invention, based on the total mass of the oil phase, the content of oryzanol is 8000-20000ppm.
在本发明的一个或多个具体实施方案中,以所述油相的总质量计,谷维素含量为8300-20000ppm。In one or more specific embodiments of the present invention, based on the total mass of the oil phase, the oryzanol content is 8300-20000ppm.
在本发明的一个或多个具体实施方案中,以所述油相的总质量计,谷维素含量为3000-10000ppm。In one or more specific embodiments of the present invention, based on the total mass of the oil phase, the content of oryzanol is 3000-10000ppm.
在本发明的一个或多个具体实施方案中,以所述油相的总质量计,谷维素含量为8000-10000ppm。尤其优选的是,以所述油相的总质量计,植物甾醇含量小于20000 ppm。In one or more specific embodiments of the present invention, based on the total mass of the oil phase, the content of oryzanol is 8000-10000ppm. Especially preferably, based on the total mass of the oil phase, the phytosterol content is less than 20000 ppm.
本发明油水组合物中的油相还包含棕榈油、大豆油、葵花籽油、高油酸葵花籽油、乳木果油、棕榈仁油、玉米油、椰子油、菜籽油、低芥酸菜籽油、花生油、芝麻油、橄榄油、核桃油、棉籽油、亚麻油、红花籽油、油茶籽油、米糠油、核桃油、南瓜子油、葡萄籽油、月见草油、花椒籽油、杏仁油、小麦胚芽油、紫苏籽油和乳木果油。可使用这些植物油中的任意一种或任意多种的混合物。也可使用这些植物油的分提产物或者酯交换油脂中的一种或任意多种的混合物。The oil phase in the oil-water composition of the present invention also includes palm oil, soybean oil, sunflower oil, high oleic sunflower oil, shea butter, palm kernel oil, corn oil, coconut oil, rapeseed oil, low erucic acid Canola oil, peanut oil, sesame oil, olive oil, walnut oil, cottonseed oil, linseed oil, safflower oil, camellia oil, rice bran oil, walnut oil, pumpkin seed oil, grape seed oil, evening primrose oil, pepper seeds Oil, Almond Oil, Wheat Germ Oil, Perilla Seed Oil and Shea Butter. Any one or a mixture of any of these vegetable oils may be used. One or a mixture of any of these vegetable oil fractions or transesterified oils can also be used.
可采用本领域周知的方法实施酯交换,包括化学酯交换和酶法酯交换。化学酯交换包括将催化剂加到60~120℃的油脂中,在真空下反应15~60分钟,终止反应后水洗至pH呈中性,然后干燥,即可获得所述酯交换油脂。催化剂可以是甲醇钠,或是NaOH或碱金属与甘油的混合物。催化剂的用量通常为油脂总重的0.1~2wt%,例如0.1~0.5%。The transesterification can be carried out by methods well known in the art, including chemical transesterification and enzymatic transesterification. The chemical transesterification includes adding a catalyst to the oil at 60-120°C, reacting under vacuum for 15-60 minutes, terminating the reaction, washing with water until the pH is neutral, and then drying to obtain the transesterified oil. The catalyst can be sodium methoxide, or NaOH or a mixture of alkali metals and glycerol. The amount of the catalyst is usually 0.1-2 wt%, for example 0.1-0.5%, of the total weight of the oil.
或者,可在酯交换酶的存在下进行酶法酯交换。例如,可使用填充有酯交换酶的填充柱。或者,可将原料油脂升温至40~60℃,加入占油脂总重0.1~2wt%的酯交换酶,在真空下反应30~120分钟,终止反应,水洗所得产物至pH值呈中性,离心分离得酯交换油脂。合适的酯交换酶包括各种市售获得的固定化酶或者其发酵液。比如来自诺维信(Novozymes)公司的lipozyme TL IM、Lopozyme RM等、日本天野酶制品株式会社(AMANO Enzyme)的固定化酶或其发酵液。Alternatively, enzymatic transesterification can be performed in the presence of transesterification enzymes. For example, a packed column packed with an ester exchange enzyme can be used. Alternatively, the raw oil can be heated to 40-60°C, add 0.1-2wt% ester exchange enzyme accounting for the total weight of the oil, and react under vacuum for 30-120 minutes to terminate the reaction, wash the obtained product with water until the pH value is neutral, and centrifuge Separation of transesterified oil. Suitable transesterification enzymes include various commercially available immobilized enzymes or fermentation broths thereof. For example, lipozyme TL IM and Lopozyme RM from Novozymes, immobilized enzymes from AMANO Enzyme or their fermentation broths.
酯交换结束后,可按常规的油脂精炼程序进一步处理酯交换油脂,例如进行脱臭处理等。After the transesterification, the transesterified oil can be further processed according to conventional oil refining procedures, such as deodorization treatment, etc.
可采用已知的酯交换方法自行制备用于本发明的酯交换油脂,也可直接使用市售的符合本发明要求的酯交换油脂用于本发明。The transesterified grease used in the present invention can be prepared by a known transesterification method, or the commercially available transesterified grease that meets the requirements of the present invention can be directly used in the present invention.
在本发明的一个或多个具体实施方式中,以所述油水组合物的总质量计,所述油水组合物的油相包含15%-75%的稻米油和25-30%的豆油。In one or more specific embodiments of the present invention, based on the total mass of the oil-water composition, the oil phase of the oil-water composition contains 15%-75% rice oil and 25-30% soybean oil.
本发明的油水组合物中,以所述油水组合物的总质量计,所述油水组合物还可包含0.5-30%的蛋黄。In the oil-water composition of the present invention, based on the total mass of the oil-water composition, the oil-water composition may further comprise 0.5-30% egg yolk.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总质量计,所述油水组合物中包含0.5-25%蛋黄。In one or more specific embodiments of the present invention, based on the total mass of the oil-water composition, the oil-water composition contains 0.5-25% egg yolk.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总质量计,所述油水组合物中包含0.5-20%蛋黄。In one or more specific embodiments of the present invention, based on the total mass of the oil-water composition, the oil-water composition contains 0.5-20% egg yolk.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总质量计所述油水组合物中包含5-20%蛋黄。In one or more specific embodiments of the present invention, the oil-water composition contains 5-20% egg yolk based on the total mass of the oil-water composition.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总质量计所述油水组合物中包含10-15%蛋黄。In one or more specific embodiments of the present invention, the oil-water composition contains 10-15% egg yolk based on the total mass of the oil-water composition.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总质量计所述油水组合物中包含4%或14%蛋黄。In one or more specific embodiments of the present invention, the oil-water composition contains 4% or 14% egg yolk based on the total mass of the oil-water composition.
在本发明的一个或多个具体实施方案中,所述蛋黄为新鲜蛋黄液、巴氏杀菌蛋黄液、冷冻蛋黄液、蛋黄粉等,In one or more specific embodiments of the present invention, the egg yolk is fresh egg yolk liquid, pasteurized egg yolk liquid, frozen egg yolk liquid, egg yolk powder, etc.
在本发明的一个或多个具体实施方案中,所述蛋黄为巴氏杀菌蛋黄液和/或冷冻蛋黄液。In one or more specific embodiments of the present invention, the egg yolk is pasteurized liquid egg yolk and/or frozen liquid egg yolk.
在本发明的一个或多个具体实施方案中,所述油水组合物的pH为3-6.5。本发明的油水组合物的pH值可以用食用醋、冰乙酸、柠檬酸、苯甲酸、乳酸、酒石酸、偏酒石酸、苹果酸、磷酸、延胡索酸、葡萄糖酸、琥珀酸等酸性物质中的一种或多种调节。In one or more specific embodiments of the present invention, the pH of the oil-water composition is 3-6.5. The pH value of the oil-water composition of the present invention can be used in one or more acidic substances such as edible vinegar, glacial acetic acid, citric acid, benzoic acid, lactic acid, tartaric acid, metatartaric acid, malic acid, phosphoric acid, fumaric acid, gluconic acid, succinic acid, etc. Various adjustments.
本发明的油水组合物中还可包含食盐、甜味剂、食用添加剂、食品原辅料中的一种或多种。The oil-water composition of the present invention may also contain one or more of salt, sweetener, edible additives, and food raw materials.
在本发明的一个或多个具体实施方案中,所述食用添加剂选自香精香料、乳化剂、抗氧化剂、食用色素、食用胶体、淀粉中的一种或多种。In one or more specific embodiments of the present invention, the food additive is selected from one or more of flavors and fragrances, emulsifiers, antioxidants, food coloring, food colloid, and starch.
在本发明的一个或多个优选方案中,所述乳化剂为磷脂,以所述油水组合物的总质量计,所述磷脂用量为0.1-0.5%。In one or more preferred versions of the present invention, the emulsifier is phospholipid, and the amount of phospholipid is 0.1-0.5% based on the total mass of the oil-water composition.
在本发明的一个或多个优选方案中,所述乳化剂为磷脂,以所述油水组合物的总质量计,所述磷脂用量为0.1%、0.2%、0.3%、0.4%、0.5%。In one or more preferred versions of the present invention, the emulsifier is phospholipid, and the amount of phospholipid is 0.1%, 0.2%, 0.3%, 0.4%, 0.5% based on the total mass of the oil-water composition.
胶体可以是各种食用胶体,可选自:卡拉胶、刺槐豆胶、黄原胶、果胶、琼脂、阿拉伯胶、结冷胶和明胶中的一种或多种。以油水组合物总重计,胶体的含量可为0.01~5%,如0.02~5%或0.05~5%。The colloid can be various edible colloids, which can be selected from one or more of carrageenan, locust bean gum, xanthan gum, pectin, agar, gum arabic, gellan gum and gelatin. Based on the total weight of the oil-water composition, the content of the colloid may be 0.01-5%, such as 0.02-5% or 0.05-5%.
在本发明的一个或多个具体实施方案中,所述胶体为黄原胶。In one or more specific embodiments of the present invention, the colloid is xanthan gum.
在本发明的一个或多个具体实施方案中,以油水组合物总重计,所述胶体的用量为0.05-3%。In one or more specific embodiments of the present invention, based on the total weight of the oil-water composition, the colloid is used in an amount of 0.05-3%.
在本发明的一个或多个具体实施方案中,以油水组合物总重计,所述胶体的用量为0.05-2%,或0.05-1%,或0.1-1%,或0.2-1%。In one or more specific embodiments of the present invention, based on the total weight of the oil-water composition, the colloid is used in an amount of 0.05-2%, or 0.05-1%, or 0.1-1%, or 0.2-1%.
甜味剂可以是各种形式的糖,如麦芽糖浆、果葡糖浆、白砂糖等。甜味剂的含量通常为油包水型乳液油水组合物总重的0.5~30%。Sweeteners can be various forms of sugar, such as malt syrup, fructose syrup, white granulated sugar, etc. The content of the sweetener is usually 0.5-30% of the total weight of the oil-water composition of the water-in-oil emulsion.
在本发明的一个或多个具体实施方案中,以油水组合物总重计,所述甜味剂的用量为0.5-20%,或1-20%或5-20%,或10-20%。In one or more specific embodiments of the present invention, based on the total weight of the oil-water composition, the sweetener is used in an amount of 0.5-20%, or 1-20% or 5-20%, or 10-20% .
在本发明的一个或多个具体实施方案中,所述食品原辅料中包含风味物质。In one or more specific embodiments of the present invention, the food raw materials contain flavor substances.
在本发明的一个或多个具体实施方案中,风味物质选自:水果类、坚果类、蔬菜类、药草类、乳制品、蛋黄、巧克力、咖啡、茶中的一种或多种。In one or more specific embodiments of the present invention, the flavoring substance is selected from one or more of fruits, nuts, vegetables, herbs, dairy products, egg yolk, chocolate, coffee, and tea.
在本发明的一个或多个具体实施方案中,所述水果类为苹果、桔子、草莓、桃、菠萝、柚子、西瓜中的一种或多种。In one or more specific embodiments of the present invention, the fruits are one or more of apples, oranges, strawberries, peaches, pineapples, grapefruits, and watermelons.
在本发明的一个或多个具体实施方案中,所述坚果类为栗子、杏仁、核桃、松仁、花生、瓜子、榛子、腰果、开心果中的一种或多种。In one or more specific embodiments of the present invention, the nuts are one or more of chestnuts, almonds, walnuts, pine nuts, peanuts, melon seeds, hazelnuts, cashews, and pistachios.
在本发明的一个或多个具体实施方案中,所述水果类为番茄、胡萝卜、甘薯、菠菜中的一种或多种。In one or more specific embodiments of the present invention, the fruits are one or more of tomatoes, carrots, sweet potatoes, and spinach.
在本发明的一个或多个具体实施方案中,所述药草类为金银花、野菊花、香草、薄荷中的一种或多种。In one or more specific embodiments of the present invention, the medicinal herb is one or more of honeysuckle, wild chrysanthemum, vanilla, mint.
在本发明的一个或多个具体实施方案中,所述乳制品为牛奶、炼乳、全脂奶粉、脱脂奶粉、半脱脂奶粉、酪蛋白酸钠、乳清、干酪中的一种或多种。In one or more specific embodiments of the present invention, the dairy product is one or more of milk, condensed milk, whole milk powder, skimmed milk powder, semi-skimmed milk powder, sodium caseinate, whey, and cheese.
在本发明的一个或多个具体实施方案中,所述油水组合物为水包油型。In one or more specific embodiments of the present invention, the oil-water composition is oil-in-water type.
本发明的第二方面提供了一种油水组合物的制备方法,所述方法包括步骤:The second aspect of the present invention provides a kind of preparation method of oil-water composition, described method comprises steps:
(1)准备油相:至少含有稻米油的油脂组合物;(1) Prepare the oil phase: a grease composition containing at least rice oil;
(2)准备水相;(2) Prepare the aqueous phase;
(3)将油相和水相按照质量比5-80:20-95进行混合。(3) The oil phase and the water phase are mixed according to the mass ratio of 5-80:20-95.
在本发明的一个或多个具体实施方案中,以所述油相的总质量计,谷维素含量为小于20000 ppm;优选3000-20000 ppm;更优选8000-20000 ppm或8300-20000ppm或3000-10000ppm或8000-10000ppm。In one or more specific embodiments of the present invention, based on the total mass of the oil phase, the oryzanol content is less than 20000 ppm; preferably 3000-20000 ppm; more preferably 8000-20000 ppm or 8300-20000 ppm or 3000-10000 ppm Or 8000-10000ppm.
在本发明的一个或多个具体实施方案中,以所述油相的总质量计,植物甾醇含量含量为小于20000 ppm;优选3000-20000 ppm;更优选8000-20000 ppm或8300-20000ppm或3000-10000ppm或8000-10000ppm。In one or more specific embodiments of the present invention, based on the total mass of the oil phase, the phytosterol content is less than 20000 ppm; preferably 3000-20000 ppm; more preferably 8000-20000 ppm or 8300-20000 ppm or 3000 -10000ppm or 8000-10000ppm.
在本发明的一个或多个具体实施方案中,所述油相的制备:将稻米油与其他油脂混合。In one or more specific embodiments of the present invention, the preparation of the oil phase: rice oil is mixed with other fats and oils.
所述其他油脂包括棕榈油、大豆油、葵花籽油、高油酸葵花籽油、乳木果油、棕榈仁油、玉米油、椰子油、菜籽油、低芥酸菜籽油、花生油、芝麻油、橄榄油、核桃油、棉籽油、亚麻油、红花籽油、油茶籽油、米糠油、核桃油、南瓜子油、葡萄籽油、月见草油、花椒籽油、杏仁油、小麦胚芽油、紫苏籽油和乳木果油。可使用这些植物油中的任意一种或任意多种的混合物。也可使用这些植物油的分提产物或者酯交换油脂中的一种或任意多种的混合物。Said other oils include palm oil, soybean oil, sunflower oil, high oleic sunflower oil, shea butter, palm kernel oil, corn oil, coconut oil, canola oil, canola oil, peanut oil, Sesame oil, olive oil, walnut oil, cottonseed oil, linseed oil, safflower oil, camellia oil, rice bran oil, walnut oil, pumpkin seed oil, grape seed oil, evening primrose oil, pepper seed oil, almond oil, wheat Germ Oil, Perilla Seed Oil and Shea Butter. Any one or a mixture of any of these vegetable oils may be used. One or a mixture of any of these vegetable oil fractions or transesterified oils can also be used.
在本发明的一个或多个具体实施方案中,所述油相中还包含乳化剂。In one or more specific embodiments of the present invention, the oil phase further includes an emulsifier.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总质量计,所述磷脂用量为0.1-0.5%。In one or more specific embodiments of the present invention, based on the total mass of the oil-water composition, the amount of the phospholipid is 0.1-0.5%.
在本发明的一个或多个具体实施方案中,以所述油水组合物的总质量计,所述磷脂用量为0.1%、0.2%、0.3%、0.4%、0.5%。In one or more specific embodiments of the present invention, based on the total mass of the oil-water composition, the amount of the phospholipid is 0.1%, 0.2%, 0.3%, 0.4%, 0.5%.
在本发明的一个或多个具体实施方案中,所述水相的制备:包括将水、蛋黄混合均匀的步骤,其中以油水组合物的总质量计,蛋黄的用量为0.5-30%。In one or more specific embodiments of the present invention, the preparation of the water phase includes the step of uniformly mixing water and egg yolk, wherein the amount of egg yolk is 0.5-30% based on the total mass of the oil-water composition.
在本发明的一个或多个具体实施方案中,所述步骤(3)为在不断搅拌剪切过程中将油相倒入至水相中。In one or more specific embodiments of the present invention, the step (3) is pouring the oil phase into the water phase during continuous stirring and shearing.
具体地,把蛋黄和甜味剂剪切均匀,一边剪切一边缓慢少量的加油,每次等前一次的油完全乳化后再添加。剪切至酱体变得粘稠,添加适量的醋,剪切均匀后继续加油。重复添加油和醋的动作,直到油和醋全部添加完成。Specifically, cut the egg yolk and sweetener evenly, slowly add a small amount of oil while cutting, and add each time after the previous oil is completely emulsified. Cut until the sauce becomes viscous, add an appropriate amount of vinegar, cut evenly and continue to add oil. Repeat adding the oil and vinegar until all the oil and vinegar are added.
本发明的第三方面提供了一种调理酱,所述调理酱包含本发明所述油水组合物。The third aspect of the present invention provides a seasoning sauce, which comprises the oil-water composition of the present invention.
在本发明的一个或多个具体实施方案中,所述调理酱为沙拉酱、蛋黄酱、涂抹酱、餐桌用酱。In one or more specific embodiments of the present invention, the seasoning sauce is salad dressing, mayonnaise, spread, table sauce.
本发明的第四方面提供了一种改善调理酱冻融稳定性的方法,所述方法为采用本发明的油水组合物。The fourth aspect of the present invention provides a method for improving the freeze-thaw stability of the sauce, the method is to use the oil-water composition of the present invention.
原料来源:Raw material source:
3000谷维素稻米油(谷维素含量为3000ppm):来自上海嘉里食品工业有限公司3000 oryzanol rice oil (3000ppm oryzanol content): from Shanghai Kerry Food Industry Co., Ltd.
双一万谷维素稻米油(谷维素含量为20000ppm): 来自上海嘉里食品工业有限公司Double 10,000 oryzanol rice oil (oryzanol content 20,000ppm): from Shanghai Kerry Food Industry Co., Ltd.
豆油:来自上海嘉里食品工业有限公司Soybean oil: from Shanghai Kerry Food Industry Co., Ltd.
蛋黄、糖粉、淀粉、醋、食盐等其他原料:市售Egg yolk, powdered sugar, starch, vinegar, salt and other raw materials: commercially available
设备:equipment:
氧化稳定仪:ML OXIPRES,北京迪索仪器有限公司Oxidation Stabilizer: ML OXIPRES, Beijing DISO Instruments Co., Ltd.
剪切机:L5M,厂家SilversonShearing machine: L5M, manufacturer Silverson
检测方法:Detection method:
谷维素含量的测定:Determination of oryzanol content:
稻米油中植物甾醇和谷维素的含量测定:采用ENISO 12228-1-2014气相色谱法测定甾醇的含量、采用紫外分光光度法测定谷维素的含量。Determination of phytosterols and oryzanol in rice oil: ENISO 12228-1-2014 gas chromatography was used to determine the content of sterols, and UV spectrophotometry was used to determine the content of oryzanol.
油水组合物的制备工艺:Preparation process of oil-water composition:
水相制备:把鸡蛋黄、水、糖粉或糖浆、盐混合,剪切均匀(10000 rpm,2 min)。Water phase preparation: Mix egg yolk, water, powdered sugar or syrup, and salt, and shear evenly (10,000 rpm, 2 min).
油相制备:将油脂混合,胶体、乳化剂和淀粉等分散在少量的油中,余下的油相备用。Preparation of oil phase: Mix oils and fats, disperse colloid, emulsifier and starch in a small amount of oil, and use the remaining oil phase for later use.
油水相混合:水相一边剪切(10000 rpm)一边缓慢少量的加入油相,剪切至酱体变得粘稠,添加少量的醋,剪切均匀;每次等前一次的油相完全乳化后再添加;重复上述添加油相和醋的动作,直至油相和醋全部添加完成。Oil-water phase mixing: water phase is sheared (10000 rpm) while slowly adding a small amount of oil phase, shear until the sauce becomes viscous, add a small amount of vinegar, shear evenly; each time wait for the previous oil phase to be completely emulsified Add again; repeat the above action of adding the oil phase and vinegar until all the oil phase and vinegar are added.
实施例:Example:
按照表1所示的配方称取各原料,然后按照以下的步骤制备油水组合物:Weigh each raw material according to the formula shown in Table 1, and then prepare the oil-water composition according to the following steps:
(1)水相制备:把鸡蛋黄、水、糖粉或糖浆、盐混合,剪切均匀(10000 rpm,2 min);(1) Water phase preparation: mix egg yolk, water, powdered sugar or syrup, and salt, and shear evenly (10000 rpm, 2 min);
(2)油相制备:将油脂混合,然后将胶体、乳化剂磷脂和淀粉等分散在少量的油中,余下的油相备用;(2) Preparation of the oil phase: mix the oils, then disperse the colloid, emulsifier phospholipid and starch, etc. in a small amount of oil, and use the remaining oil phase for later use;
(3)油水相混合:水相一边剪切(10000 rpm)一边缓慢少量的加入油相,剪切至酱体变得粘稠,添加少量的醋,剪切均匀;每次等前一次的油相完全乳化后再添加;重复上述添加油相和醋的动作,直至油相和醋全部添加完成。(3) Oil-water phase mixing: water phase is sheared (10000 rpm) while slowly adding a small amount of oil phase, shear until the sauce body becomes viscous, add a small amount of vinegar, and shear evenly; wait for the previous oil phase each time After the phase is completely emulsified, add it again; repeat the above action of adding the oil phase and vinegar until all the oil phase and vinegar are added.
表1 实施例的油水组合物配方(表中数值为百分比 %)The oil-water composition formula of table 1 embodiment (value in the table is percentage %)
对比例:Comparative example:
按照表2所示的配方称取各原料,然后按照以下的步骤制备油水组合物:Weigh each raw material according to the formula shown in Table 2, and then prepare the oil-water composition according to the following steps:
(1)水相制备:把鸡蛋黄、水、糖粉或糖浆、盐混合,剪切均匀(10000 rpm,2 min);(1) Water phase preparation: mix egg yolk, water, powdered sugar or syrup, and salt, and shear evenly (10000 rpm, 2 min);
(2)油相制备:将油脂混合,然后将胶体、乳化剂(磷脂或单甘脂或蔗糖脂肪酸酯)和淀粉等分散在少量的油中,余下的油相备用;(2) Oil phase preparation: mix the oils and fats, then disperse colloids, emulsifiers (phospholipids or monoglycerides or sucrose fatty acid esters) and starch in a small amount of oil, and use the remaining oil phase for later use;
(3)油水相混合:水相一边剪切(10000 rpm)一边缓慢少量的加入油相,剪切至酱体变得粘稠,添加少量的醋,剪切均匀;每次等前一次的油相完全乳化后再添加;重复上述添加油相和醋的动作,直至油相和醋全部添加完成。(3) Oil-water phase mixing: water phase is sheared (10000 rpm) while slowly adding a small amount of oil phase, shear until the sauce body becomes viscous, add a small amount of vinegar, and shear evenly; wait for the previous oil phase each time After the phase is completely emulsified, add it again; repeat the above action of adding the oil phase and vinegar until all the oil phase and vinegar are added.
表2 对比例的油水组合物的配方(表中数值为百分比 %)The formula of the oil-water composition of table 2 comparative example (the value in the table is percentage %)
测试方法:Test Methods:
氧化稳定性:使用油脂氧化稳定仪对实施例和对比例的油水组合物进行测试(100℃,5bar),开始氧化的时间越长,表示样品越稳定。结果如表3所示。Oxidation stability: The oil-water compositions of the examples and the comparative examples were tested with an oil oxidation stability meter (100°C, 5 bar). The longer the time to start oxidation, the more stable the sample. The results are shown in Table 3.
表3 实施例及对比例的油水组合物的氧化稳定性测试结果Table 3 Oxidation Stability Test Results of the Oil-Water Compositions of Examples and Comparative Examples
注:氧化稳定性大于等于10,即表示该产品的氧化稳定性符合要求。Note: Oxidation stability greater than or equal to 10 means that the oxidation stability of the product meets the requirements.
从表3的结果可以看出,对比例1和2的氧化稳定性都比实施例的氧化稳定性差。It can be seen from the results in Table 3 that the oxidation stability of Comparative Examples 1 and 2 is worse than that of Examples.
感官评价Sensory evaluation
冻融稳定性测试:把实施例及对比例获得油水组合物样品密封放在-18℃冷冻18小时,取出,在25℃放置6小时;反复冻融操作6次,观察油脂的析出量,并进行打分。“10”分表示冻融稳定性好,没有油脂析出。“9”分表示冻融稳定性较好,略有油脂析出;“8”分表示冻融稳定性一般,样品边缘有一点油析出;“7”分表示冻融稳定性略差,有一些油脂析出;“6”分表示冻融稳定性较差,有比较多的油析出;“5”分表示冻融稳定性差,有大量的油析出;“4”分表示冻融稳定性不好,有很多的油析出,不能保持样品形态;“3”分表示冻融稳定性不好,有大量的油析出,但还未完全油水分离; “2”分表示冻融稳定性不好,完全油水分离,不能保持样品形态。Freeze-thaw stability test: Seal the oil-water composition samples obtained in the examples and comparative examples and freeze them at -18°C for 18 hours, take them out, and place them at 25°C for 6 hours; repeat the freeze-thaw operation for 6 times, observe the amount of grease precipitated, and Make a score. A score of "10" means that the freeze-thaw stability is good, and there is no oil precipitation. "9" indicates good freeze-thaw stability with slight oil precipitation; "8" indicates average freeze-thaw stability with a little oil precipitation at the edge of the sample; "7" indicates poor freeze-thaw stability with some oil "6" means that the freeze-thaw stability is poor, and there is a lot of oil precipitation; "5" means that the freeze-thaw stability is poor, and there is a large amount of oil precipitation; "4" means that the freeze-thaw stability is not good, there is A lot of oil precipitated out and the shape of the sample could not be maintained; "3" points indicated that the freeze-thaw stability was not good, a large amount of oil precipitated out, but the oil-water separation was not complete; "2" points indicated that the freeze-thaw stability was not good, and the oil-water separation was complete , the shape of the sample cannot be maintained.
热稳定性:将实施例及对比例获得油水组合物样品在60℃下加热4小时,观察4小时内析油的快慢和多少打分,“10”分表示3小时后有少量的油脂析出,样品稳定;“9”分表示2.5小时后略有少量的油脂析出,样品稳定;“8”分表示2小时后有少量的油脂析出,样品较稳定;“7”分表示1.5小时后有少量的油脂析出,样品较稳定;“6”分表示1小时后有少量油脂析出,样品稳定性一般;“5”分表示1小时内有少量油脂析出,样品稳定性一般;“4”分表示1小时内有较多的油脂析出,样品稳定性不好;“2”分表示1小时内有大量的油脂析出,样品稳定性不好。冻融稳定性和热稳定性的结果如表4所示。Thermal stability: heat the oil-water composition samples obtained in the examples and comparative examples at 60°C for 4 hours, observe the speed and number of oil separation within 4 hours, and score "10" means that a small amount of oil precipitates after 3 hours. Stable; "9" means that a small amount of oil precipitates after 2.5 hours, and the sample is stable; "8" means that a small amount of oil precipitates after 2 hours, and the sample is relatively stable; "7" means that there is a small amount of oil after 1.5 hours The sample is relatively stable; "6" means that a small amount of oil precipitates after 1 hour, and the sample stability is average; "5" means that a small amount of oil precipitates within 1 hour, and the sample stability is average; There is a lot of grease precipitation, and the stability of the sample is not good; "2" means that there is a large amount of grease precipitation within 1 hour, and the stability of the sample is not good. The results of freeze-thaw stability and thermal stability are shown in Table 4.
综合喜好度:由测试者根据喜好度从风味、口感、颜色三个维度打分,最后取3个维度所得分数的总分。总分为10分,“10”分表示非常喜欢;“9”分表示介于非常喜欢和一般喜欢之间;“8”分表示一般喜欢。“7”分表示介于一般喜欢与中立之间;“6”分表示既不喜欢也不讨厌;“5”分表示中立和一般讨厌之间;“4”分表示一般讨厌,“3”分表示一般讨厌和非常讨厌之间;“2”分表示非常讨厌;结果如表5所示。Comprehensive liking degree: The tester will score according to the liking degree from the three dimensions of flavor, taste and color, and finally take the total score of the scores obtained from the three dimensions. The total score is 10 points, "10" indicates that I like it very much; "9" indicates that I like it very much and generally like it; "8" indicates that I like it generally. A score of "7" means between generally liking and neutral; "6" means neither liking nor disliking; "5" means neutral and generally dislike; "4" means generally disliking; "3" Indicates between general dislike and very dislike; "2" means very dislike; the results are shown in Table 5.
表4 实施例及对比例的油水组合物的稳定性评价结果Table 4 Stability Evaluation Results of the Oil-Water Compositions of Examples and Comparative Examples
注:冻融稳定性和热稳定性大于等于9分,即表示可以接受。Note: The freeze-thaw stability and thermal stability are greater than or equal to 9 points, which means it is acceptable.
从表4中可以看到,实施例的冻融稳定性和热稳定性都满足产品要求,对比例3-10都不符合要求。As can be seen from Table 4, the freeze-thaw stability and thermal stability of the examples all meet the product requirements, while Comparative Examples 3-10 do not meet the requirements.
表5实施例及对比例的油水组合物综合喜好度评价结果Table 5 embodiment and the oil-water composition comprehensive preference evaluation result of comparative example
注:风味、口感和颜色分数都大于等于8分,即表示可以接受。Note: Flavor, taste and color scores are all greater than or equal to 8 points, which means it is acceptable.
从表5所示的结果可以看出,实施例的风味、口感和颜色都满足产品要求,而对比例1和2在风味、口感和颜色方面都不满足要求;对比例3-10在口感方面都很差。As can be seen from the results shown in table 5, the flavor, mouthfeel and color of the embodiment all meet the product requirements, while comparative examples 1 and 2 do not meet the requirements in terms of flavor, mouthfeel and color; comparative examples 3-10 are in terms of mouthfeel Both are poor.
以上所述仅为本发明的较佳实施例而已,并非用以限定本发明的实质技术内容范围,本发明的实质技术内容是广义地定义于申请的权利要求范围中,任何他人完成的技术实体或方法,若是与申请的权利要求范围所定义的完全相同,也或是一种等效的变更,均将被视为涵盖于该权利要求范围之中。The above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the essential technical content of the present invention. The essential technical content of the present invention is broadly defined in the scope of the claims of the application, and any technical entity completed by others or method, if it is exactly the same as that defined in the scope of the claims of the application, or an equivalent change, it will be deemed to be included in the scope of the claims.
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