CN112940169B - Organic glass material for perfume bottle and preparation method thereof - Google Patents
Organic glass material for perfume bottle and preparation method thereof Download PDFInfo
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- 239000002304 perfume Substances 0.000 title claims abstract description 33
- 239000000463 material Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000011521 glass Substances 0.000 title abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 238000000465 moulding Methods 0.000 claims abstract description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 33
- 229920005372 Plexiglas® Polymers 0.000 claims description 22
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 14
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 13
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 11
- 239000003063 flame retardant Substances 0.000 claims description 11
- 239000003999 initiator Substances 0.000 claims description 11
- 239000011787 zinc oxide Substances 0.000 claims description 11
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 claims description 10
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 10
- 239000007822 coupling agent Substances 0.000 claims description 10
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 10
- XESZUVZBAMCAEJ-UHFFFAOYSA-N 4-tert-butylcatechol Chemical compound CC(C)(C)C1=CC=C(O)C(O)=C1 XESZUVZBAMCAEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000008029 phthalate plasticizer Substances 0.000 claims description 7
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 6
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 6
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000004014 plasticizer Substances 0.000 claims description 5
- DMTRWFMFBIMXBX-UHFFFAOYSA-L lead(2+);6-methylheptanoate Chemical compound [Pb+2].CC(C)CCCCC([O-])=O.CC(C)CCCCC([O-])=O DMTRWFMFBIMXBX-UHFFFAOYSA-L 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 8
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 5
- 239000004926 polymethyl methacrylate Substances 0.000 description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- -1 UV-91.0 parts Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
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- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
Abstract
Description
技术领域technical field
本发明涉及玻璃制品加工技术领域，尤其涉及一种香水瓶用有机玻璃材料及其制备方法。The invention relates to the technical field of glass product processing, in particular to an organic glass material for perfume bottles and a preparation method thereof.
背景技术Background technique
有机玻璃(PMMA)是由甲基丙烯酸甲酯聚合而成的高分子化合物材料。有机玻璃具有表面光滑、色彩艳丽，比重小，强度较大，耐腐蚀，耐湿，耐晒，绝缘性能好的特点，因此有机玻璃的应用十分广泛。Plexiglass (PMMA) is a polymer compound material polymerized from methyl methacrylate. Plexiglass has the characteristics of smooth surface, bright colors, small specific gravity, high strength, corrosion resistance, moisture resistance, light resistance, and good insulation performance, so plexiglass is widely used.
有机玻璃的主要性能包括以下几个方面：The main properties of plexiglass include the following aspects:
(1)光学性能(1) Optical properties
PMMA的折射率为1.49，透光率高于常规硅酸盐玻璃。由此可见，有机玻璃具有优异的光学性能，使得其具有上述光学性能的主要原因是有机玻璃为无定形聚合物，质地均匀，其内部分子排列方式不会影响进入内部的光线在各个部分通过时的速度，光纤能够以同样的速度前进，不会四面分散，互相干扰。The refractive index of PMMA is 1.49, and the light transmittance is higher than that of conventional silicate glass. It can be seen that plexiglass has excellent optical properties, and the main reason for its above-mentioned optical properties is that plexiglass is an amorphous polymer with uniform texture, and its internal molecular arrangement will not affect the light entering the interior when it passes through various parts. The optical fiber can advance at the same speed without being scattered in all directions and interfering with each other.
(2)力学性能(2) Mechanical properties
有机玻璃的拉伸强度、弹性模量以及冲击强度均高于无机玻璃；但是有机玻璃的表面硬度不足，易被硬物擦伤，擦毛而失去光泽。The tensile strength, elastic modulus and impact strength of plexiglass are higher than those of inorganic glass; however, the surface hardness of plexiglass is insufficient, and it is easy to be scratched by hard objects, and it will lose its luster due to brushing.
(3)热性能(3) thermal performance
PMMA比大多数热塑型塑料低，其可在-60～65℃范围内使用，且为易燃材料。PMMA is lower than most thermoplastics, it can be used in the range of -60 ~ 65 ℃, and it is a flammable material.
(4)化学性能(4) Chemical properties
PMMA耐水溶性盐、弱酸或某些稀酸，但不耐氧化性酸和强碱。同时介质溶度越大，温度越高，其稳定性越低；PMMA is resistant to water-soluble salts, weak acids or some dilute acids, but not to oxidizing acids and strong alkalis. At the same time, the greater the solubility of the medium, the higher the temperature, and the lower its stability;
在有机化合物中，PMMA对长链烷烃、简单的醚类、油脂较为稳定，不耐短链烷烃、醇、酮等。Among organic compounds, PMMA is relatively stable to long-chain alkanes, simple ethers, and oils, but not resistant to short-chain alkanes, alcohols, and ketones.
香水是一种混合了香精油、固定剂与酒精和乙酸乙酯的液体，用来让物体拥有持久、悦人的气味。香水多盛放在香水瓶中，香水瓶多由玻璃制成，存在易碎的问题。因此，需要提供一种制作香水瓶的有机玻璃，满足盛放香水的要求。Perfume is a liquid mixture of essential oils and fixatives with alcohol and ethyl acetate, used to impart a long-lasting, pleasing odor to objects. Perfume is mostly contained in perfume bottles, and perfume bottles are mostly made of glass, which is fragile. Therefore, need provide a kind of plexiglass that makes perfume bottle, satisfy the requirement of holding perfume.
发明内容Contents of the invention
有鉴于此，本发明提供了一种香水瓶用有机玻璃材料，通过调整有机玻璃材料中的原料组成，使得所制备的有机玻璃具有较高的强度以及透明度，耐温性也得到了显著提高，便于加工成型。In view of this, the present invention provides a kind of plexiglass material for perfume bottles. By adjusting the composition of raw materials in the plexiglass material, the prepared plexiglass has higher strength and transparency, and the temperature resistance is also significantly improved. Easy to process and shape.
本发明的香水瓶用有机玻璃材料，包括以下重量份的原料：Perfume bottle of the present invention uses organic glass material, comprises the raw material of following weight portion:
优选地，所述纳米氧化锌的粒径为10-50nm，所述纳米氧化钛的粒径为1-5nm。Preferably, the particle size of the nano-zinc oxide is 10-50 nm, and the particle size of the nano-titanium oxide is 1-5 nm.
优选地，所述紫外线吸收剂为紫外线吸收剂UV-9、紫外线吸收剂UV-P或紫外线吸收剂531中的一种。Preferably, the ultraviolet absorber is one of ultraviolet absorber UV-9, ultraviolet absorber UV-P or ultraviolet absorber 531.
优选地，所述偶联剂为KH550或KH570中的一种。Preferably, the coupling agent is one of KH550 or KH570.
优选地，所述塑化剂为邻苯二甲酸二丁酯或邻苯二甲酸二辛酯。Preferably, the plasticizer is dibutyl phthalate or dioctyl phthalate.
优选地，所述阻燃剂为对叔丁基邻苯二酚。Preferably, the flame retardant is p-tert-butylcatechol.
优选地，所述引发剂为过氧化苯甲酰或偶氮二异丁腈中的一种。Preferably, the initiator is one of benzoyl peroxide or azobisisobutyronitrile.
本发明的另一目的是提供了一种香水瓶的制备方法，即利用本发明所述的有机玻璃材料制备而成，包括以下步骤：Another object of the present invention is to provide a kind of preparation method of perfume bottle, promptly utilize the plexiglass material described in the present invention to form, comprise the following steps:
S1、按比例称取甲基丙烯酸甲酯、甲基丙烯酸、氯乙醇在温度为70-120℃下搅拌混合；S1. Weigh methyl methacrylate, methacrylic acid, and chloroethanol in proportion and stir and mix at a temperature of 70-120°C;
S2、将异辛酸铅、甲基丙烯酸铅、纳米二氧化钛、纳米氧化锌、紫外线吸收剂、偶联剂按比例混合均匀；S2, mixing lead isooctanoate, lead methacrylate, nano-titanium dioxide, nano-zinc oxide, ultraviolet absorber, and coupling agent in proportion;
S3、将步骤S2混合后的物料倒入到S1中，在温度为100-150℃下进行搅拌混合30-60min，然后冷却至50-80℃；S3. Pour the mixed material in step S2 into S1, stir and mix at a temperature of 100-150°C for 30-60min, and then cool to 50-80°C;
S4、依次将塑化剂、阻燃剂、引发剂按比例倒入到步骤S3混合后的物料中，在温度50-80℃下进行混合；S4. Pour the plasticizer, flame retardant, and initiator in proportion to the mixed material in step S3 in sequence, and mix at a temperature of 50-80°C;
S5、将步骤S4混合后的物料倒入成型机中加工成型，并迅速经冷水定型，即得到香水瓶。S5. Pour the material mixed in step S4 into a molding machine for processing and molding, and quickly set it in cold water to obtain a perfume bottle.
优选地，步骤S1中的混合温度为80-90℃，混合时间为10-30min。Preferably, the mixing temperature in step S1 is 80-90° C., and the mixing time is 10-30 min.
优选地，步骤S3中的混合温度为120-150℃。Preferably, the mixing temperature in step S3 is 120-150°C.
与现有技术相比，本发明具有以下有益效果：Compared with the prior art, the present invention has the following beneficial effects:
(1)本发明香水瓶用的有机玻璃材料所选用的原料易得且价格低廉；(1) the selected raw material of the plexiglass material that perfume bottle of the present invention is used is easy to get and cheap;
(2)本发明有机玻璃材料加工成型率高，且加工设备要求不高，适合规模化生产；(2) The molding rate of organic glass material of the present invention is high, and the requirements for processing equipment are not high, so it is suitable for large-scale production;
(3)本发明所加工成香水瓶透明度高、稳定性好，同时强度相对于传统有机玻璃材料得到了显著提高，耐高温性更优异。(3) The perfume bottle processed by the present invention has high transparency and good stability, and at the same time, its strength has been significantly improved compared with traditional plexiglass materials, and its high temperature resistance is more excellent.
具体实施方式Detailed ways
下面结合实施例对本发明作进一步说明。The present invention will be further described below in conjunction with embodiment.
实施例1Example 1
一种香水瓶用有机玻璃材料，由以下重量份的原料构成：A kind of plexiglass material for perfume bottle, is made of the raw material of following parts by weight:
甲基丙烯酸甲酯95份、甲基丙烯酸6份、异辛酸铅5份、甲基丙烯酸铅2份、氯乙醇10份、3.5nm纳米二氧化钛1.5份、28nm纳米氧化锌2份、紫外线吸收剂UV-91.0份、KH550偶联剂1.5份、邻苯二甲酸二丁酯塑化剂1份、对叔丁基邻苯二酚阻燃剂0.5份、过氧化苯甲酰引发剂0.5份。95 parts of methyl methacrylate, 6 parts of methacrylic acid, 5 parts of lead methacrylate, 2 parts of lead methacrylate, 10 parts of chloroethanol, 1.5 parts of 3.5nm nano titanium dioxide, 2 parts of 28nm nano zinc oxide, ultraviolet absorber UV -91.0 parts, 1.5 parts of KH550 coupling agent, 1 part of dibutyl phthalate plasticizer, 0.5 parts of p-tert-butylcatechol flame retardant, and 0.5 parts of benzoyl peroxide initiator.
利用上述原料加工成香水瓶，步骤如下：Utilize above-mentioned raw material to be processed into perfume bottle, steps are as follows:
S1、按比例称取甲基丙烯酸甲酯、甲基丙烯酸、氯乙醇在温度为85℃下搅拌混合20min；S1. Weigh methyl methacrylate, methacrylic acid, and chloroethanol in proportion and stir and mix for 20 minutes at a temperature of 85°C;
S2、将异辛酸铅、甲基丙烯酸铅、纳米二氧化钛、纳米氧化锌、紫外线吸收剂、偶联剂按比例混合均匀；S2, mixing lead isooctanoate, lead methacrylate, nano-titanium dioxide, nano-zinc oxide, ultraviolet absorber, and coupling agent in proportion;
S3、将步骤S2混合后的物料倒入到S1中，在温度为130℃下进行搅拌混合50min，然后冷却至60℃；S3. Pour the mixed material in step S2 into S1, stir and mix at a temperature of 130°C for 50 minutes, and then cool to 60°C;
S4、依次将塑化剂、阻燃剂、引发剂按比例倒入到步骤S3混合后的物料中，在温度60℃下进行混合；S4. Pour the plasticizer, flame retardant, and initiator in proportion to the mixed material in step S3 in sequence, and mix at a temperature of 60° C.;
S5、将步骤S4混合后的物料倒入成型机中加工成型，并迅速经冷水定型，即得到香水瓶。S5. Pour the material mixed in step S4 into a molding machine for processing and molding, and quickly set it in cold water to obtain a perfume bottle.
实施例2Example 2
一种香水瓶用有机玻璃材料，由以下重量份的原料构成：A kind of plexiglass material for perfume bottle, is made of the raw material of following parts by weight:
甲基丙烯酸甲酯95份、甲基丙烯酸6份、异辛酸铅5份、甲基丙烯酸铅2份、氯乙醇5份、3.5nm纳米二氧化钛1份、28nm纳米氧化锌1份、紫外线吸收剂5311.5份、KH570偶联剂1份、邻苯二甲酸二辛酯塑化剂1份、对叔丁基邻苯二酚阻燃剂1份、偶氮二异丁腈引发剂0.5份。95 parts of methyl methacrylate, 6 parts of methacrylic acid, 5 parts of lead methacrylate, 2 parts of lead methacrylate, 5 parts of chloroethanol, 1 part of 3.5nm nano-titanium dioxide, 1 part of 28nm nano-zinc oxide, UV absorber 5311.5 1 part, 1 part of KH570 coupling agent, 1 part of dioctyl phthalate plasticizer, 1 part of p-tert-butylcatechol flame retardant, 0.5 part of azobisisobutyronitrile initiator.
将上述原料利用实施例1的制备方法加工成香水瓶。Utilize the preparation method of embodiment 1 above-mentioned raw material to be processed into perfume bottle.
实施例3Example 3
一种香水瓶用有机玻璃材料，由以下重量份的原料构成：A kind of plexiglass material for perfume bottle, is made of the raw material of following parts by weight:
甲基丙烯酸甲酯100份、甲基丙烯酸5份、异辛酸铅5份、甲基丙烯酸铅5份、氯乙醇10份、3.5nm纳米二氧化钛2份、28nm纳米氧化锌3份、紫外线吸收剂UV-P 0.5份、KH550偶联剂2.5份、邻苯二甲酸二丁酯塑化剂2份、对叔丁基邻苯二酚阻燃剂1份、过氧化苯甲酰引发剂0.5份。100 parts of methyl methacrylate, 5 parts of methacrylic acid, 5 parts of lead methacrylate, 5 parts of lead methacrylate, 10 parts of chloroethanol, 2 parts of 3.5nm nano titanium dioxide, 3 parts of 28nm nano zinc oxide, ultraviolet absorber UV -P 0.5 parts, KH550 coupling agent 2.5 parts, dibutyl phthalate plasticizer 2 parts, p-tert-butylcatechol flame retardant 1 part, benzoyl peroxide initiator 0.5 parts.
将上述原料利用实施例1的制备方法加工成香水瓶。Utilize the preparation method of embodiment 1 above-mentioned raw material to be processed into perfume bottle.
实施例4Example 4
一种香水瓶用有机玻璃材料，由以下重量份的原料构成：A kind of plexiglass material for perfume bottle, is made of the raw material of following parts by weight:
甲基丙烯酸甲酯80份、甲基丙烯酸8份、异辛酸铅8份、甲基丙烯酸铅3份、氯乙醇8份、5nm纳米二氧化钛1.5份、50nm纳米氧化锌1.5份、紫外线吸收剂UV-91.2份、KH570偶联剂1.5份、邻苯二甲酸二丁酯塑化剂1.8份、对叔丁基邻苯二酚阻燃剂0.5份、偶氮二异丁腈引发剂0.1份。80 parts of methyl methacrylate, 8 parts of methacrylic acid, 8 parts of lead methacrylate, 3 parts of lead methacrylate, 8 parts of chloroethanol, 1.5 parts of 5nm nano-titanium dioxide, 1.5 parts of 50nm nano-zinc oxide, ultraviolet absorber UV- 91.2 parts, 1.5 parts of KH570 coupling agent, 1.8 parts of dibutyl phthalate plasticizer, 0.5 parts of p-tert-butylcatechol flame retardant, and 0.1 part of azobisisobutyronitrile initiator.
将上述原料利用实施例1的制备方法加工成香水瓶。Utilize the preparation method of embodiment 1 above-mentioned raw material to be processed into perfume bottle.
对比例1Comparative example 1
一种香水瓶采用如下重量份的原料按照实施例1的方法加工而成：A kind of perfume bottle adopts the raw material of following weight portion to process according to the method for embodiment 1:
甲基丙烯酸甲酯95份、甲基丙烯酸6份、甲基丙烯酸铅2份、氯乙醇10份、20nm纳米二氧化钛1.5份、28nm纳米氧化锌2份、紫外线吸收剂UV-91.0份、KH550偶联剂1.5份、邻苯二甲酸二丁酯塑化剂1份、对叔丁基邻苯二酚阻燃剂0.5份、过氧化苯甲酰引发剂0.5份。95 parts of methyl methacrylate, 6 parts of methacrylic acid, 2 parts of lead methacrylate, 10 parts of chloroethanol, 1.5 parts of 20nm nano-titanium dioxide, 2 parts of 28nm nano-zinc oxide, 1.0 parts of ultraviolet absorber UV-9, KH550 coupling 1.5 parts of plasticizer, 1 part of dibutyl phthalate plasticizer, 0.5 parts of p-tert-butylcatechol flame retardant, and 0.5 parts of benzoyl peroxide initiator.
对比例2Comparative example 2
一种香水瓶采用如下重量份的原料按照实施例1的方法加工而成：A kind of perfume bottle adopts the raw material of following weight portion to process according to the method for embodiment 1:
甲基丙烯酸甲酯95份、甲基丙烯酸6份、甲基丙烯酸铅2份、氯乙醇10份、3.5nm纳米二氧化钛1.5份、3.5nm纳米氧化锌2份、紫外线吸收剂UV-91.0份、KH550偶联剂1.5份、邻苯二甲酸二丁酯塑化剂1份、对叔丁基邻苯二酚阻燃剂0.5份、过氧化苯甲酰引发剂0.5份。95 parts of methyl methacrylate, 6 parts of methacrylic acid, 2 parts of lead methacrylate, 10 parts of chloroethanol, 1.5 parts of 3.5nm nano-titanium dioxide, 2 parts of 3.5nm nano-zinc oxide, UV-91.0 parts, KH550 1.5 parts of coupling agent, 1 part of dibutyl phthalate plasticizer, 0.5 parts of p-tert-butylcatechol flame retardant, and 0.5 parts of benzoyl peroxide initiator.
将实施例1-4以及对比文件1-2制备的香水瓶进行检测，检测结果如表1所示。The perfume bottles prepared in Examples 1-4 and Comparative Document 1-2 were tested, and the test results are shown in Table 1.
表1Table 1
从表1中可以看出，采用本发明的有机玻璃材料所加工出的香水瓶具有较高的强度、透光率、稳定性以耐高温性能。As can be seen from Table 1, the perfume bottle processed by the plexiglass material of the present invention has higher strength, light transmittance, stability and high temperature resistance.
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention, it should be pointed out that, for those of ordinary skill in the art, without departing from the principle of the present invention, some improvements and modifications can also be made, and these improvements and modifications can also be made. It should be regarded as the protection scope of the present invention.
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| WO2000073370A1 (en) * | 1999-05-28 | 2000-12-07 | Hi-Tech Environmental Products, Llc. | Synthetic thermoplastic compositions and articles made therefrom |
| RU2277105C1 (en) * | 2005-01-13 | 2006-05-27 | Федеральное государственное унитарное предприятие "Научно-исследовательский институт химии и технологии полимеров имени академика В.А. Каргина с опытным заводом" (ФГУП "НИИ полимеров") | Compound for production of organic glass |
| WO2017037366A1 (en) * | 2015-09-04 | 2017-03-09 | Arkema France | Photopolymerisable adhesive composition |
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| CN109053948A (en) * | 2018-08-16 | 2018-12-21 | 天长市瑞慈有机玻璃有限公司 | A kind of X-ray-preventing ultraviolet light lucite tube and preparation method |
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| WO2000073370A1 (en) * | 1999-05-28 | 2000-12-07 | Hi-Tech Environmental Products, Llc. | Synthetic thermoplastic compositions and articles made therefrom |
| RU2277105C1 (en) * | 2005-01-13 | 2006-05-27 | Федеральное государственное унитарное предприятие "Научно-исследовательский институт химии и технологии полимеров имени академика В.А. Каргина с опытным заводом" (ФГУП "НИИ полимеров") | Compound for production of organic glass |
| WO2017037366A1 (en) * | 2015-09-04 | 2017-03-09 | Arkema France | Photopolymerisable adhesive composition |
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Denomination of invention: Organic glass material for perfume bottle and its preparation method Granted publication date: 20230407 Pledgee: Mingguang Company limited by guarantee financing Pledgor: GOLD ONYX PERFUME (MINGGUANG) Co.,Ltd. Registration number: Y2024980052413 |
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